Pub Date : 2024-08-29DOI: 10.1134/S1063785023170194
A. I. Mullayanov, R. Sh. Osipova, A. A. Musin, L. A. Kovaleva
Abstract—The behavior of a “water-in-oil” emulsion stabilized with asphaltenes under the action of an inhomogeneous alternating electric field has been studied. The experimental technique was based on the use of microfluidics, optical microscopy, and high-speed video filming. The dependences of quantitative estimates of the parameters characterizing the dynamics of the emulsion destruction on the frequency and amplitude of the applied field have been obtained. The technique will be useful in developing efficient methods for breaking emulsions and modifying the existing technologies for separating oil emulsions into phases.
{"title":"Investigation of the Process of Emulsion Droplets Coalescence in an Inhomogeneous Alternating Electric Field in the Presence of an Asphaltene Interfacial Film at the Oil–Water Interface","authors":"A. I. Mullayanov, R. Sh. Osipova, A. A. Musin, L. A. Kovaleva","doi":"10.1134/S1063785023170194","DOIUrl":"10.1134/S1063785023170194","url":null,"abstract":"<p><b>Abstract</b>—The behavior of a “water-in-oil” emulsion stabilized with asphaltenes under the action of an inhomogeneous alternating electric field has been studied. The experimental technique was based on the use of microfluidics, optical microscopy, and high-speed video filming. The dependences of quantitative estimates of the parameters characterizing the dynamics of the emulsion destruction on the frequency and amplitude of the applied field have been obtained. The technique will be useful in developing efficient methods for breaking emulsions and modifying the existing technologies for separating oil emulsions into phases.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"153 - 156"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023180074
S. A. Korolyov, A. V. Goryunov, V. V. Parshin
A new approach to the creation of millimeter-wave radio imaging systems is proposed. This approach is based on the use of an array receiver consisting of a densely packed (pixel size of 4 mm) array of planar mixers located in the focal plane of a quasi-optical objective, with application of the frequency-modulated continuous-wave radar technique. It has been demonstrated that the implementation of the heterodyne type of reception makes it possible to increase the distance range of the array radio imaging system up to ~100 m while maintaining the angular resolution at the previous level.
{"title":"Array Radio Imaging Based on Heterodyne Detection with Application of the Continuous-Wave Radar Technique","authors":"S. A. Korolyov, A. V. Goryunov, V. V. Parshin","doi":"10.1134/S1063785023180074","DOIUrl":"10.1134/S1063785023180074","url":null,"abstract":"<p>A new approach to the creation of millimeter-wave radio imaging systems is proposed. This approach is based on the use of an array receiver consisting of a densely packed (pixel size of 4 mm) array of planar mixers located in the focal plane of a quasi-optical objective, with application of the frequency-modulated continuous-wave radar technique. It has been demonstrated that the implementation of the heterodyne type of reception makes it possible to increase the distance range of the array radio imaging system up to ~100 m while maintaining the angular resolution at the previous level.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"194 - 197"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023180190
R. R. Zinnatullin, A. I. Iskandarov, L. A. Kovaleva
The dynamics of the interfacial tension coefficient at the interface between water and model solutions of asphaltenes of different concentrations in toluene has been studied. It has been shown that, over time, the interfacial tension decreases due to the adsorption of asphaltene molecules at the interface. With an increase in the concentration of asphaltenes in the solution, the decrease in interfacial tension occurs more intensively. The results of a study of the elongation of a water drop in a solution under the influence of an electric field are presented. It is shown that after the formation of an adsorption film, a higher electric field must be applied to stretch the droplet, and the relative elongation depends nonlinearly on the applied voltage.
{"title":"Investigation of the Interfacial Tension at the Interface Between Water and Asphaltene Solution in Toluene","authors":"R. R. Zinnatullin, A. I. Iskandarov, L. A. Kovaleva","doi":"10.1134/S1063785023180190","DOIUrl":"10.1134/S1063785023180190","url":null,"abstract":"<p>The dynamics of the interfacial tension coefficient at the interface between water and model solutions of asphaltenes of different concentrations in toluene has been studied. It has been shown that, over time, the interfacial tension decreases due to the adsorption of asphaltene molecules at the interface. With an increase in the concentration of asphaltenes in the solution, the decrease in interfacial tension occurs more intensively. The results of a study of the elongation of a water drop in a solution under the influence of an electric field are presented. It is shown that after the formation of an adsorption film, a higher electric field must be applied to stretch the droplet, and the relative elongation depends nonlinearly on the applied voltage.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"244 - 246"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023180219
A. M. Zyuzin, A. A. Karpeev, N. V. Yantsen
It was found that in the region of the percolation threshold, depending on the dominance of one or another conduction mechanism, the temperature dependence of the specific volume resistivity ρ(T) of the polymer composite based on a matrix of ethylene vinyl acetate is significantly transformed. With an increase in the CB content, there is a decrease by several orders of magnitude in the maximum value of the relative resistivity ρ(T)max/ρ20 in its temperature dependence. Peroxide crosslinking of matrix macromolecules leads to a change in the nature of the temperature dependence of resistivity.
{"title":"The Influence of Carbon Black Content on Temperature Dependences of Electrical Conductivity of Polymer Composite","authors":"A. M. Zyuzin, A. A. Karpeev, N. V. Yantsen","doi":"10.1134/S1063785023180219","DOIUrl":"10.1134/S1063785023180219","url":null,"abstract":"<p>It was found that in the region of the percolation threshold, depending on the dominance of one or another conduction mechanism, the temperature dependence of the specific volume resistivity ρ(<i>T</i>) of the polymer composite based on a matrix of ethylene vinyl acetate is significantly transformed. With an increase in the CB content, there is a decrease by several orders of magnitude in the maximum value of the relative resistivity ρ(<i>T</i>)<sub>max</sub>/ρ<sub>20</sub> in its temperature dependence. Peroxide crosslinking of matrix macromolecules leads to a change in the nature of the temperature dependence of resistivity.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"250 - 254"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023170029
S. N. Antonov, Yu. G. Rezvov, V. A. Podolsky, O. D. Sivkova
Abstract—To form a multibeam radiation pattern, it is proposed to use the axial geometry of acousto-optic interaction in paratellurite. In the single frequency mode, the use of this geometry for angular scanning is characterized by a dip in the frequency response. Optimization of a multifrequency radio signal makes it possible to efficiently divide laser radiation into several beams with maintaining the fundamental advantages of axial geometry: minimum crystal size and power consumption.
{"title":"Acousto-Optic MultiBeam Axial Diffraction in Paratellurite","authors":"S. N. Antonov, Yu. G. Rezvov, V. A. Podolsky, O. D. Sivkova","doi":"10.1134/S1063785023170029","DOIUrl":"10.1134/S1063785023170029","url":null,"abstract":"<p><b>Abstract</b>—To form a multibeam radiation pattern, it is proposed to use the axial geometry of acousto-optic interaction in paratellurite. In the single frequency mode, the use of this geometry for angular scanning is characterized by a dip in the frequency response. Optimization of a multifrequency radio signal makes it possible to efficiently divide laser radiation into several beams with maintaining the fundamental advantages of axial geometry: minimum crystal size and power consumption.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"90 - 94"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023180098
S. V. Likhomanova, N. V. Kamanina
The main results of non-linear optical, spectral and current–voltage characteristics research of pyridine organic conjugated molecule-carbon nanoparticles combined system have been presented. The perspective of these materials further study in global trends of modern search of materials for optical limiting has been demonstrated also in the present paper.
{"title":"The Intermolecular Interaction Influence on Non-Linear Optical Properties in COANP–Carbon Nanoparticles System","authors":"S. V. Likhomanova, N. V. Kamanina","doi":"10.1134/S1063785023180098","DOIUrl":"10.1134/S1063785023180098","url":null,"abstract":"<p>The main results of non-linear optical, spectral and current–voltage characteristics research of pyridine organic conjugated molecule-carbon nanoparticles combined system have been presented. The perspective of these materials further study in global trends of modern search of materials for optical limiting has been demonstrated also in the present paper.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"202 - 204"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023180189
T. A. Shalygina, M. S. Rudenko, I. V. Nemtsev, V. A. Parfenov, S. Yu. Voronina
A plasma-chemical method for the modification of silicon carbide particles is presented, which makes it possible to obtain particles with a controlled surface morphology. The variable parameter of particle processing was the ratio of the fraction of plasma-forming (Ar) and additional (H) gases. It was shown that at Ar/H = 100/0, the formation of a carbon shell is observed; at Ar/H ratios of 91/9 and 84/16, the particles are characterized by a carbon shell decorated with silicon nanoparticles or nanowires, respectively. The modified particles were analyzed using scanning electron microscopy and Raman spectroscopy.
{"title":"Plasma-Chemical Method of Silicon Carbide Modification to Obtain Particles with Controlled Surface Morphology","authors":"T. A. Shalygina, M. S. Rudenko, I. V. Nemtsev, V. A. Parfenov, S. Yu. Voronina","doi":"10.1134/S1063785023180189","DOIUrl":"10.1134/S1063785023180189","url":null,"abstract":"<p>A plasma-chemical method for the modification of silicon carbide particles is presented, which makes it possible to obtain particles with a controlled surface morphology. The variable parameter of particle processing was the ratio of the fraction of plasma-forming (Ar) and additional (H) gases. It was shown that at Ar/H = 100/0, the formation of a carbon shell is observed; at Ar/H ratios of 91/9 and 84/16, the particles are characterized by a carbon shell decorated with silicon nanoparticles or nanowires, respectively. The modified particles were analyzed using scanning electron microscopy and Raman spectroscopy.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"239 - 243"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023170133
A. A. Koryakin, Yu. A. Eremeev, S. V. Fedina, V. V. Fedorov
Abstract—The growth mechanism of monolayer on the top facet of Ga-catalyzed GaAs and GaP nanowires is investigated. Within the framework of a theoretical model, the maximal monolayer coverage due to the material in the catalyst droplet, the nanowire growth rate and the content of group V atoms in the droplet are found depending on the growth conditions. The estimates of the phosphorus re-evaporation coefficient from neighboring nanowires and substrate are obtained by comparing the theoretical and experimental growth rate of Ga-catalyzed GaP nanowires.
摘要 研究了镓催化砷化镓和磷化镓纳米线顶面单层的生长机理。在理论模型的框架内,发现了催化剂液滴中材料导致的最大单层覆盖率、纳米线生长速率以及液滴中 V 族原子的含量取决于生长条件。通过比较镓催化 GaP 纳米线的理论生长率和实验生长率,得到了邻近纳米线和基底磷再蒸发系数的估计值。
{"title":"Growth Mechanism of Monolayer on the Top Facet of Ga-Catalyzed GaAs and GaP Nanowires","authors":"A. A. Koryakin, Yu. A. Eremeev, S. V. Fedina, V. V. Fedorov","doi":"10.1134/S1063785023170133","DOIUrl":"10.1134/S1063785023170133","url":null,"abstract":"<p><b>Abstract</b>—The growth mechanism of monolayer on the top facet of Ga-catalyzed GaAs and GaP nanowires is investigated. Within the framework of a theoretical model, the maximal monolayer coverage due to the material in the catalyst droplet, the nanowire growth rate and the content of group V atoms in the droplet are found depending on the growth conditions. The estimates of the phosphorus re-evaporation coefficient from neighboring nanowires and substrate are obtained by comparing the theoretical and experimental growth rate of Ga-catalyzed GaP nanowires.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"129 - 132"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023180037
V. V. Bolotov, E. V. Knyazev, S. N. Nesov
The functionalization of multi-walled carbon nanotubes in He:O plasma is investigated. It is shown that plasma treatment leads to the removal of defective outer graphene layers and their fragments due to oxidation. It is established that the surface of functionalized multi-walled carbon nanotubes contains numerous uncoordinated carbon atoms and oxygen-containing functional groups. The preservation of the structure of the internal graphene layers of nanotubes and the formation of broken chemical bonds ensure a decrease in electrical resistance. At the same time, there is a narrowing of the distribution of electrical resistance values of nanotube ensembles.
{"title":"The Effect of He:O Plasma Treatment on the Structure of Multi-Walled Carbon Nanotubes","authors":"V. V. Bolotov, E. V. Knyazev, S. N. Nesov","doi":"10.1134/S1063785023180037","DOIUrl":"10.1134/S1063785023180037","url":null,"abstract":"<p>The functionalization of multi-walled carbon nanotubes in He:O plasma is investigated. It is shown that plasma treatment leads to the removal of defective outer graphene layers and their fragments due to oxidation. It is established that the surface of functionalized multi-walled carbon nanotubes contains numerous uncoordinated carbon atoms and oxygen-containing functional groups. The preservation of the structure of the internal graphene layers of nanotubes and the formation of broken chemical bonds ensure a decrease in electrical resistance. At the same time, there is a narrowing of the distribution of electrical resistance values of nanotube ensembles.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"178 - 181"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179513","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1134/S1063785023180050
D. A. Kiselev, A. V. Pavlenko, S. P. Zinchenko
The properties of c-oriented thin films of Sr0.5Ba0.5Nb2O6 grown on a Si(001) (p-type) substrate with a pre-deposited Ba0.2Sr0.8TiO3 layer were studied using scanning probe microscopy and dielectric spectroscopy. It is established that the Sr0.5Ba0.5Nb2O6 films are characterized by low surface roughness (less than 6 nm) and average crystallite size of ~93 nm. It is shown that there is spontaneous polarization in the film directed from its surface to the substrate, which causes the manifestation of the field effect for the case of the Si substrate with p-type conductivity without the external field effect. Differences in the magnitudes of the surface potential signal for regions polarized by an external electric field of different polarities (+10 and –10 V), as well as in their relaxation to the initial state, are revealed. The reasons for the established patterns are discussed.
摘要 使用扫描探针显微镜和介电光谱法研究了在带有预沉积 Ba0.2Sr0.8TiO3 层的 Si(001)(p 型)基底上生长的 Sr0.5Ba0.5Nb2O6 c 型薄膜的特性。结果表明,Sr0.5Ba0.5Nb2O6 薄膜表面粗糙度低(小于 6 纳米),平均结晶尺寸约为 93 纳米。研究表明,薄膜中存在从其表面指向基底的自发极化,这导致了在硅基底具有 p 型导电性而没有外部场效应的情况下的场效应。在不同极性(+10 V 和 -10 V)的外部电场作用下,极化区域的表面电势信号大小不同,其弛豫到初始状态的过程也不同。本文讨论了形成这些模式的原因。
{"title":"Ferroelectric Properties of Heterostructure Sr0.5Ba0.5Nb2O6/Ba0.2Sr0.8TiO3/Si(001)","authors":"D. A. Kiselev, A. V. Pavlenko, S. P. Zinchenko","doi":"10.1134/S1063785023180050","DOIUrl":"10.1134/S1063785023180050","url":null,"abstract":"<p>The properties of <b><i>c</i></b>-oriented thin films of Sr<sub>0.5</sub>Ba<sub>0.5</sub>Nb<sub>2</sub>O<sub>6</sub> grown on a Si(001) (<i>p</i>-type) substrate with a pre-deposited Ba<sub>0.2</sub>Sr<sub>0.8</sub>TiO<sub>3</sub> layer were studied using scanning probe microscopy and dielectric spectroscopy. It is established that the Sr<sub>0.5</sub>Ba<sub>0.5</sub>Nb<sub>2</sub>O<sub>6</sub> films are characterized by low surface roughness (less than 6 nm) and average crystallite size of ~93 nm. It is shown that there is spontaneous polarization in the film directed from its surface to the substrate, which causes the manifestation of the field effect for the case of the Si substrate with <i>p</i>-type conductivity without the external field effect. Differences in the magnitudes of the surface potential signal for regions polarized by an external electric field of different polarities (+10 and –10 V), as well as in their relaxation to the initial state, are revealed. The reasons for the established patterns are discussed.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 2","pages":"186 - 189"},"PeriodicalIF":0.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142179515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}