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Scaling Up AFM Friction Studies: Tailored Probes for Cross-Scale Measurements on Single-Crystal MoS2 扩大AFM摩擦研究:单晶MoS2的跨尺度测量定制探针
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-24 DOI: 10.1007/s11249-025-02058-0
Tianci Chen, Qingrui Song, Zitong Huang, Kun Liu, Jiaxin Ye

This study introduces a new type of cantilever-probe system that extends atomic force microscopy to high-load, large-contact-area measurements, supporting friction studies from nano to millimeter scales. By using polymer cantilevers with colloidal microspheres, this customizable probe system (8–25 N/m cantilever stiffness; 0.08–2.5 mm probe radius) allows friction measurements on single-crystal MoS₂ under loads of 0.5–120 μN, contact areas of 0.02–10 μm2, and contact pressures from 2 to 150 MPa, bridging nanoscale and microscale observations. Our findings reveal a novel scale effect, where the friction coefficient increases by a factor of 34 with a 30-fold increase in probe radius. This affordable alternative to commercial cantilevers also simplifies calibration and enhances accessibility for tribological studies in nanocomposites, MEMS/NEMS, and biological materials, offering a scalable tool for cross-scale friction research.

Graphical abstract

这项研究介绍了一种新型的悬臂探针系统,将原子力显微镜扩展到高负载、大接触面积的测量,支持从纳米到毫米尺度的摩擦研究。通过使用带有胶体微球的聚合物悬臂梁,这种可定制的探针系统(8-25 N/m悬臂梁刚度,0.08-2.5 mm探针半径)可以在0.5-120 μN的载荷,0.02-10 μm2的接触面积和2 - 150 MPa的接触压力下测量单晶MoS 2,桥接纳米尺度和微观尺度的观测。我们的研究结果揭示了一种新的尺度效应,其中摩擦系数增加了34倍,探针半径增加了30倍。这种经济实惠的商业悬臂替代方案还简化了校准,提高了纳米复合材料、MEMS/NEMS和生物材料摩擦学研究的可及性,为跨尺度摩擦研究提供了可扩展的工具。图形抽象
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引用次数: 0
Tribological Behaviour of Cuo@Rgo Nanoparticles Under Different Slide-To-Roll Cuo@Rgo纳米颗粒在不同滑动滚转下的摩擦学行为
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-12 DOI: 10.1007/s11249-025-02054-4
S. M. Alves, R. D. Cunha, A. Morina

This paper aims to develop core–shell nanoparticles by combining CuO (core) and reduced graphene oxide (shell) as lubricant additives and understand their action under different slide-to-roll ratios. The SRRs evaluated were 50 and 200%, with nanoparticles concentrations of 0.05 and 0.1wt%. The worn tracks were characterized through WLI, SEM, TEM and Raman Spectroscopy. The results showed that the lubrication mechanism and tribofilm formation are strongly associated with the type of contact. At SRR 200%, nanolubricant reduced friction and wear; it was observed exfoliation of nanoparticles, the CuO acted as rolling, and the rGO sheet was deposited on a worn surface. On the other hand, for SRR 50% doesn´t decrease the friction coefficient; however, a thicker tribofilm was produced with nanoparticles.

以氧化铜(芯)和还原氧化石墨烯(壳)为润滑剂添加剂,制备核-壳纳米颗粒,并研究其在不同滑滚比下的作用。纳米颗粒浓度分别为0.05 wt%和0.1wt%, srr分别为50%和200%。通过WLI、SEM、TEM和拉曼光谱对磨损轨迹进行了表征。结果表明,摩擦膜的形成和润滑机理与接触类型密切相关。在SRR为200%时,纳米润滑剂减少了摩擦和磨损;观察到纳米颗粒脱落,CuO起滚动作用,氧化石墨烯薄片沉积在磨损表面。另一方面,50%的SRR不降低摩擦系数;然而,纳米颗粒产生了更厚的摩擦膜。
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引用次数: 0
Intelligent Current-Controlled Behavior of Intercalated MXene@Triethanolamine Borate Nanocomposite as Lubricant Additives 插层MXene@Triethanolamine硼酸盐纳米复合材料作为润滑油添加剂的智能电流控制行为
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-11 DOI: 10.1007/s11249-025-02053-5
Bingchun Li, Guoliang Zhang, Wenxuan Zheng, Duo Yang, Yang Li

Friction and lubrication of components in mechanical transmission systems are crucial to their transmission efficiency. As for the extreme conditions, the performance of traditional liquid lubricants would be degraded, which causes significant harm to the safe and reliable operation of equipment. Therefore, the development of a high-efficiency composite lubricant is particularly important. In this study, MXene@Triethanolamine borate nanocomposite were prepared via the ultrasonic intercalation method. Furthermore, the composites were characterized by scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. The tribological properties of intercalated MXene@TB in the BMIMPF6 ionic liquid were evaluated under current using a ball-on-disk tribometer. The average friction coefficient of lubricant with 0.3% intercalated MXene@TB-1 was reduced by 9.8%, and its wear volume was also decreased by 36.1%. Additionally, the application of current can enhance the tribological performance of lubricant. Specifically, the wear volume of int-MXene@TB-2 was decreased by 52% due to the current-induced ion migration and lubricating film repair. Moreover, the application of current promotes the movement of nanoparticles within the ionic liquid, minimizing aggregation and further enhancing the formation of the lubrication film. The lubricant nanocomposite with high-efficiency friction reduction and anti-wear properties can be further applied in current-carrying friction field.

Graphical abstract

机械传动系统中部件的摩擦和润滑对其传动效率至关重要。在极端条件下,传统液体润滑剂的性能会下降,对设备的安全可靠运行造成重大危害。因此,开发一种高效的复合润滑剂就显得尤为重要。本研究采用超声插层法制备了MXene@Triethanolamine硼酸盐纳米复合材料。利用扫描电镜、x射线衍射和傅里叶变换红外光谱对复合材料进行了表征。利用球盘式摩擦计测试了嵌入MXene@TB在BMIMPF6离子液体中的摩擦学性能。掺入0.3% MXene@TB-1的润滑油平均摩擦系数降低了9.8%,磨损量降低了36.1%。此外,电流的施加可以提高润滑油的摩擦学性能。其中,由于电流诱导离子迁移和润滑膜修复,int-MXene@TB-2的磨损体积减小了52%。此外,电流的施加促进了离子液体内纳米颗粒的运动,减少了聚集,进一步促进了润滑膜的形成。该润滑纳米复合材料具有高效减摩抗磨性能,可进一步应用于载流摩擦领域。图形抽象
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引用次数: 0
Tribological Properties and Lubrication Mechanism of New Phosphorus-Free Benzothiazole Organomolybdenum Friction Modifiers 新型无磷苯并噻唑类有机钼摩擦改进剂的摩擦学性能及润滑机理
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-11 DOI: 10.1007/s11249-025-02055-3
Jing Qin, Sujie Jia, Hualin Lin, Sheng Han

Benzothiazole is widely used in biomedical applications in recent studies, in this study we coordinated it with organic molybdenum to prepare three phosphorus-free benzothiazole-organic molybdenum friction modifiers with different structures and evaluated the lubrication performance in base oil PAO6. The results showed that the three additives exhibited different friction reduction and anti-wear effects due to their different molecular structures, with benzothiazole-molybdenum oleate amide (YSMo) showing the most significant lubrication performance. At 1.00 wt%, YSMo reduced the average coefficient of friction by 30.8% and the wear volume by 95.86%. The combination of sulfur-containing nitrogen heterocyclic compounds with molybdenum source significantly enhanced the lubrication performance and effectively reduced friction and wear through physical adsorption and the formation of a dense composite chemical friction protective film (containing components such as FeS, MoO3, and MoS2), which further confirmed that friction-generated MoS2 has a positive effect on the tribological performance. The lubrication performance of YSMo was superior to that of the other two additives, which depended on the polar groups and chain lengths, which provides an important theoretical basis for further optimizing the design of lubricating additives.

苯并噻唑在近年来的研究中广泛应用于生物医学领域,本研究将其与有机钼配合制备了三种不同结构的无磷苯并噻唑-有机钼摩擦改性剂,并对其在基础油PAO6中的润滑性能进行了评价。结果表明,三种添加剂由于其分子结构的不同,表现出不同的减摩抗磨效果,其中以苯并噻唑-油酸钼酰胺(YSMo)的润滑效果最为显著。在1.00 wt%时,YSMo的平均摩擦系数降低了30.8%,磨损体积降低了95.86%。含硫氮杂环化合物与钼源结合,通过物理吸附,形成致密的复合化学摩擦保护膜(含FeS、MoO3、MoS2等成分),显著提高了润滑性能,有效降低了摩擦磨损,进一步证实了摩擦产生的MoS2对摩擦学性能有积极作用。YSMo的润滑性能优于其他两种添加剂,这取决于极性基团和链长,为润滑添加剂的进一步优化设计提供了重要的理论依据。
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引用次数: 0
Graphene Oxide-Reinforced Copper Matrix Composites: Microstructural Enhancements and Tribological Performance Via Hot Pressing 氧化石墨烯增强铜基复合材料:热压增强微观结构和摩擦学性能
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-05 DOI: 10.1007/s11249-025-02050-8
Cevher Kursat Macit, Bunyamin Aksakal, Merve Horlu

This study investigates the effects of graphene oxide (GO) reinforcement on the microstructural, mechanical, and tribological properties of copper (Cu) matrix composites produced via powder metallurgy and hot pressing. GO nanoparticles synthesized by the Hummers method were incorporated into Cu at different weight ratios (0.5, 0.75, and 1 wt %), and the composites were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). The results revealed that GO was homogeneously distributed within the Cu matrix without forming new detectable crystalline phases, and its presence led to grain refinement and improved interfacial bonding. Hardness measurements showed that the composite containing 1 wt % GO exhibited a 109.97% increase compared to pure Cu, while tribological tests under dry sliding conditions demonstrated significant enhancements in wear resistance and reductions in the coefficient of friction. Notably, the 1 wt % GO composite achieved an 82.88% reduction in wear loss and a 51.33% decrease in friction coefficient. Post-wear SEM analysis confirmed the formation of a protective tribofilm, reduced microcrack formation, and minimized wear-induced damage. These findings highlight the effectiveness of GO as a multifunctional reinforcement for the development of high-performance Cu-based composites with superior wear resistance, making them suitable candidates for applications in electrical contact systems and other tribologically demanding environments.

Graphical abtsract

本研究探讨了氧化石墨烯(GO)增强剂对粉末冶金和热压法制备的铜基复合材料的微观组织、力学和摩擦学性能的影响。将Hummers方法合成的氧化石墨烯纳米颗粒以不同的重量比(0.5、0.75和1 wt %)掺入Cu中,利用x射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、扫描电镜(SEM)和能量色散x射线能谱(EDX)对复合材料进行表征。结果表明,氧化石墨烯在Cu基体内均匀分布,没有形成新的可检测的晶相,其存在导致晶粒细化和界面结合改善。硬度测量表明,与纯Cu相比,含有1wt %氧化石墨烯的复合材料的硬度提高了109.97%,而在干滑动条件下的摩擦学测试表明,其耐磨性显著增强,摩擦系数显著降低。值得注意的是,1 wt %的氧化石墨烯复合材料的磨损损失降低了82.88%,摩擦系数降低了51.33%。磨损后的SEM分析证实了保护性摩擦膜的形成,减少了微裂纹的形成,并将磨损引起的损伤降至最低。这些发现强调了氧化石墨烯作为一种多功能增强剂的有效性,可用于开发具有优异耐磨性的高性能铜基复合材料,使其适合应用于电接触系统和其他摩擦学要求高的环境。图形abtsract
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引用次数: 0
A Physics-Based Contact Model for Analyzing the Contact Behavior and State of Joint Surfaces 基于物理的接触模型分析结合面接触行为和状态
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-04 DOI: 10.1007/s11249-025-02039-3
Jian Chen, Zeteng Tong, Xiaohui Zhao, Linbo Zhu, Jun Hong

This study proposes a physics-based model for characterizing the contact behavior and state of joint surfaces. Based on the microcontact mechanics model, surface topography, material properties, loads, and asperity interactions were combined to construct a normal contact model. Subsequently, the sticking and sliding behaviors of a single asperity were characterized with the Jenkins element from the Iwan model. Conversely, a parallel arrangement of multiple Jenkins elements represented the overall stick–slip behavior. A distribution function incorporating non-Gaussian distribution and asperity interactions was derived to describe the tangential yield force distribution, thereby constructing a physically explicit tangential contact model. Finally, the results of the predictive model were validated against the experimental data. A slip ratio was introduced to quantifiably evaluate the surface contact states—full stick, stick–slip, and gross slip micromotion, and the factors influencing the contact characteristics of the joint surface were investigated.

本研究提出了一个基于物理的模型来表征关节表面的接触行为和状态。基于微接触力学模型,结合表面形貌、材料特性、载荷和凹凸面相互作用,构建了法向接触模型。随后,利用Iwan模型中的Jenkins单元对单个粗糙体的粘滞和滑动行为进行表征。相反,多个Jenkins元素的平行排列代表了整体的粘滑行为。推导了一个包含非高斯分布和粗糙相互作用的分布函数来描述切向屈服力分布,从而构建了物理显式的切向接触模型。最后,用实验数据对预测模型的结果进行了验证。引入滑移率定量评价关节表面接触状态(全粘、粘滑、总滑移微动),研究了影响关节表面接触特性的因素。
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引用次数: 0
Velocity-Dependent Dynamics of Friction and Wear 与速度相关的摩擦和磨损动力学
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-02 DOI: 10.1007/s11249-025-02045-5
Even Nordhagen, Henrik Andersen Sveinsson, Anders Malthe-Sørenssen

Understanding the relationship between sliding velocity, temperature, friction, and wear is of fundamental importance in materials science and engineering. Here, we explore sliding friction and wear of a silicon carbide nano-asperity sliding over a silicon carbide substrate for a broad range of temperatures and velocities using molecular dynamics simulations. Our study reveals three distinct friction regimes over four velocity decades: velocity-weakening at moderate velocities, velocity-strengthening at high velocities, and an additional velocity-strengthening behavior at very low velocities and elevated temperatures. We theoretically describe these findings with physics-based friction models. For the low-velocity regime, we refine the Prandtl-Tomlinson model by incorporating a logarithmic aging mechanism that accounts for surface diffusion-driven contact evolution. For the high-velocity regime, we introduce a linear viscous friction model with an Arrhenius temperature dependence. These models demonstrate strong agreement with the molecular dynamics simulation results in their respective velocity regimes. We then explore wear mechanisms, distinguishing between atomic attrition at low velocities and collective material removal at high velocities, thus providing a comprehensive framework for understanding the velocity and temperature dependence of nanoscale friction and wear of silicon carbide.

理解滑动速度、温度、摩擦和磨损之间的关系在材料科学和工程中是至关重要的。在这里,我们使用分子动力学模拟来探索在广泛的温度和速度范围内在碳化硅衬底上滑动的碳化硅纳米粗糙度的滑动摩擦和磨损。我们的研究揭示了四十年来三种不同的摩擦机制:中速时的速度减弱,高速时的速度增强,以及极低速度和高温下的额外速度增强行为。我们用基于物理的摩擦模型从理论上描述了这些发现。对于低速状态,我们通过纳入对数老化机制来改进Prandtl-Tomlinson模型,该机制解释了表面扩散驱动的接触演化。对于高速区域,我们引入了一个与阿累尼乌斯温度相关的线性粘性摩擦模型。这些模型在各自的速度范围内与分子动力学模拟结果非常吻合。然后,我们探索了磨损机制,区分了低速下的原子磨损和高速下的集体材料去除,从而为理解碳化硅纳米尺度摩擦和磨损的速度和温度依赖性提供了一个全面的框架。
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引用次数: 0
Rolling Contact Fatigue Performance of a Newly Developed Wheel Steel for 400 km/h High-Speed Trains 新型400 km/h高速列车车轮钢滚动接触疲劳性能研究
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-01 DOI: 10.1007/s11249-025-02036-6
Hai Zhao, Ting-wei Zhou, Tao An, Zhen-lin Xu, Yi-zhu He, Shi-huai Su, Dong-fang Zeng

The progressive escalation of operational velocities in high-speed railways has intensified cyclic contact stresses at wheel–rail interfaces, leading to accelerated fatigue failure. Hence, it is essential to create new wheel–rail materials with superior performance to align with the requirements of high-speed railway systems. This paper introduces a newly developed high-speed wheel steel (CLD400) that demonstrates enhanced rolling contact fatigue (RCF) performance and the influence of running speed on RCF damage in wheel steel. The results reveal that the CLD400 wheel steel exhibits excellent RCF life, which is 5.9 times higher than that of ER8 wheel steel. The performance of wheel steel can be effectively enhanced by decreasing the size of the austenite grain, pearlite colony, and interlamellar spacing, while increasing the pearlite content. In situ observations indicate that under oil-lubricated conditions, cracks gradually develop on the contact surface of the wheel steel and eventually expand into noticeable peeling pits, leading to material failure. As the cycles increases, the area and perimeter of defects on the wheel steel contact surface gradually increase, whereas the shape factor gradually decreases. As running speed increases, the deterioration of the wheel's steel material begins sooner, although with a reduced level of severity. The force driving crack growth decreases with speed increases, resulting in smaller RCF crack sizes. These findings enable the targeted design of wheel materials for 400 km/h high-speed trains.

Graphical abstract

高速铁路运行速度的不断提高,加剧了轮轨界面的循环接触应力,导致疲劳破坏加速。因此,为了满足高速铁路系统的要求,必须创造出具有优越性能的新型轮轨材料。本文介绍了新研制的高速车轮钢CLD400,该钢具有较强的滚动接触疲劳性能,以及运行速度对车轮钢滚动接触疲劳损伤的影响。结果表明,CLD400车轮钢具有优异的RCF寿命,比ER8车轮钢提高了5.9倍。减小奥氏体晶粒尺寸,减小珠光体集落,减小片间间距,增加珠光体含量,可有效提高车轮钢的性能。现场观察表明,在油润滑条件下,车轮钢接触面逐渐出现裂纹,最终扩展成明显的剥落坑,导致材料失效。随着循环次数的增加,车轮钢接触面缺陷的面积和周长逐渐增大,形状因子逐渐减小。随着运行速度的增加,车轮钢材料的恶化开始得更快,尽管严重程度有所降低。随着速度的增加,驱动裂纹扩展的力减小,导致RCF裂纹尺寸变小。这些发现为400公里/小时高速列车车轮材料的针对性设计提供了可能。图形抽象
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引用次数: 0
Temperature‑Dependent Friction, Wear, and Life of MoS₂ Dry Film Lubricants for Space Mechanisms: A Comprehensive Review 空间机构用MoS 2干膜润滑油的温度依赖摩擦、磨损和寿命研究综述
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-08-01 DOI: 10.1007/s11249-025-02052-6
Abrar Faiyad, Daniel Miliate, Samuel Leventini, Jeffrey R. Lince, Ashlie Martini

Molybdenum Disulfide (MoS2) is the most widely used dry film lubricant (DFL) for moving mechanical assemblies that operate in space. For these applications, the MoS2 must provide low friction and wear across a range of temperatures. The temperature dependence of MoS2 tribological behavior has been studied previously. However, the number of temperatures and conditions that can be tested in a single study is necessarily limited, making it difficult to predict or understand the performance of DFLs more broadly. To address this, this review article summarizes and analyzes the results from prior studies of temperature-dependent tribological behavior of MoS2-based dry film lubricants. Friction, wear, and wear life data are compiled into a plot matrix and trends are identified. Then, the mechanisms that have been proposed to explain observed trends are summarized. Finally, gaps in the knowledge and opportunities for future work are discussed such that researchers can build on existing studies to enhance the reliability and performance of MoS2-based dry film lubricants in space environments.

摘要:二硫化钼(MoS2)是应用最广泛的用于空间移动机械组件的干膜润滑剂(DFL)。对于这些应用,MoS2必须在一定温度范围内提供低摩擦和磨损。前人对二硫化钼摩擦学行为的温度依赖性进行了研究。然而,在单一研究中可以测试的温度和条件的数量必然是有限的,这使得很难更广泛地预测或了解dfl的性能。为了解决这一问题,本文总结和分析了前人关于二硫化钼基干膜润滑剂的温度依赖摩擦学行为的研究结果。摩擦、磨损和磨损寿命数据被汇编成一个图表矩阵,并确定趋势。然后,总结了已经提出的解释观察到的趋势的机制。最后,讨论了知识的差距和未来工作的机会,以便研究人员可以在现有研究的基础上提高mos2基干膜润滑剂在空间环境中的可靠性和性能。图片摘要:补充资料:在线版本包含补充资料,网址为10.1007/s11249-025-02052-6。
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引用次数: 0
Linear Reciprocating Tribometer for In Situ Neutron Reflectometry of Soft Matter 用于软物质中子原位反射的直线往复摩擦计。
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-07-29 DOI: 10.1007/s11249-025-02049-1
Kathryn E. Shaffer, Brendan Louie Bagorio, Ahmed Al Kindi, Julia J. Ong, Andrew R. Rhode, Erik B. Watkins, Rebecca J. L. Welbourn, Roger Pynn, Juan Manuel Urueña, Angela A. Pitenis

Neutron reflectometry is a technique for measuring structure near planar interfaces that has been previously used to non-destructively characterize the polymer density of hydrated, dilute, and soft materials. Previous investigations have conducted neutron reflectometry measurements of liquids, gels, emulsion, and polymer solutions at rest, in compression, and subject to shear stress. However, correlating structure with tribological properties of soft materials presents significant experimental challenges for prior instruments due to wall slip, sample thickness, and structural heterogeneity (e.g., depth-wise gradients). A linear reciprocating tribometer offers several advantages for in situ neutron reflectometry studies, including uniform velocity profiles, constant shear stress over large regions of interest, and independent control of normal force and sliding velocity during measurements. This work outlines basic considerations for the design of a custom linear reciprocating tribometer that operates in a neutron beamline and includes commissioning measurements. The tribometer is designed to compress soft and hydrated materials against linearly reciprocating silicon disks. The three key design considerations for this tribometer are (1) safety, (2) neutron transmission, and (3) sample positioning. This instrument design will enable in situ studies of soft matter and illuminate the role of interfacial structure on tribological phenomena.

Graphical Abstract

中子反射法是一种测量平面界面附近结构的技术,以前用于非破坏性地表征水合、稀释和软材料的聚合物密度。以前的研究已经对液体、凝胶、乳液和聚合物溶液在静止、压缩和受剪切应力作用下进行了中子反射测量。然而,由于壁滑移、样品厚度和结构非均质性(例如深度梯度),将软材料的结构与摩擦学特性相关联给先前的仪器带来了重大的实验挑战。线性往复摩擦计为原位中子反射研究提供了几个优点,包括均匀的速度剖面,在大范围内的恒定剪切应力,以及在测量过程中独立控制法向力和滑动速度。这项工作概述了在中子束线中工作的定制线性往复摩擦计设计的基本考虑因素,包括调试测量。该摩擦计的设计目的是压缩软和水合材料对线性往复硅盘。该摩擦计的三个关键设计考虑因素是:(1)安全性,(2)中子透射,(3)样品定位。该仪器的设计将使软物质的原位研究成为可能,并阐明界面结构在摩擦学现象中的作用。
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引用次数: 0
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Tribology Letters
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