Pub Date : 2024-05-01DOI: 10.1007/s11249-024-01861-5
Zing Siang Lee, Raman Maiti, Matt Carré, Roger Lewis
This study investigates the frictional and surface strain behaviour of silicone hemispherical finger pad simulants with different stiffness during tribological interactions with a smooth glass plate. A novel contact area and strain measurement method employing a digital image correlation technique was employed to give new understanding of the pad behaviour during sliding. The frictional behaviour of the sliding finger pad simulant is dominated by the adhesion mechanism, with a small overall contribution from deformation, as suggested by the high principal strains at the edge of the contact area. The strain behaviour is also influenced by the magnitude of the normal force and the stiffness of the samples.
{"title":"The Effect of Stiffness on Friction, Surface Strain and Contact Area of a Sliding Finger Pad Simulant","authors":"Zing Siang Lee, Raman Maiti, Matt Carré, Roger Lewis","doi":"10.1007/s11249-024-01861-5","DOIUrl":"10.1007/s11249-024-01861-5","url":null,"abstract":"<div><p>This study investigates the frictional and surface strain behaviour of silicone hemispherical finger pad simulants with different stiffness during tribological interactions with a smooth glass plate. A novel contact area and strain measurement method employing a digital image correlation technique was employed to give new understanding of the pad behaviour during sliding. The frictional behaviour of the sliding finger pad simulant is dominated by the adhesion mechanism, with a small overall contribution from deformation, as suggested by the high principal strains at the edge of the contact area. The strain behaviour is also influenced by the magnitude of the normal force and the stiffness of the samples.</p></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 2","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01861-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140833994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nickel acetyl acetonate (Ni(acac)2), a metal-organic compound, was directly dispersed in base oils alkylated naphthalene (AN-5), diisooctyl sebacate (DIOS), poly-α-olefin (PAO6), and mineral oil (liquid hydrocarbon mixtures:150 N) in the presence of commercial dispersant RF1151 (monoallyl poly(isobutylene succinimide). The tribological properties of the lubricants were tested with a four-ball friction and wear tester. The friction-induced in-situ formation of carbon films on rubbed steel surfaces under the catalysis of Ni(acac)2 was investigated, and the as-formed carbon films were characterized by scanning electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. The results show that Ni(acac)2 added in the base oils can decompose to form metallic nickel to form nickel layer on the rubbed metal sub-surfaces and catalyze the degradation of the base oil molecules adsorbed to form carbon-based tribofilms. The carbon film formed from AN-5 with aromatic ring structure has a high degree of graphitization and the best friction-reducing and antiwear abilities, and those formed from PAO6 and 150 N with linear structure have a low degree of graphitization as well as good tribological properties. Under the lubrication of DIOS with Ni(acac)2, however, there is no carbon film formation while the tribological properties of the lubricant are relatively poor, due to the absence of the catalytic metallic nickel and nickel oxide layer on the rubbed metal sub-surface. Thanks to the catalytic effect of metallic nickel released from Ni(acac)2 for the degradation of various base oils with different molecular structure, the present approach could provide a rational pathway to tune the in-situ formation of carbon-based tribofilm on rubbed steel surfaces so as to effectively reduce the friction and wear of steel-steel sliding pair.
{"title":"Effect of Nickel Acetyl Acetonate as Lubricant Additive in Base Oils with Different Molecular Structure on In-Situ Formation and Tribomechanism of Carbon-Based Tribofilms of Steel-Steel Sliding Pair","authors":"Feng Peng, Shuguang Fan, Ningning Song, Chuanping Gao, Shengmao Zhang, Yujuan Zhang","doi":"10.1007/s11249-024-01859-z","DOIUrl":"10.1007/s11249-024-01859-z","url":null,"abstract":"<div><p>Nickel acetyl acetonate (Ni(acac)<sub>2</sub>), a metal-organic compound, was directly dispersed in base oils alkylated naphthalene (AN-5), diisooctyl sebacate (DIOS), poly-α-olefin (PAO6), and mineral oil (liquid hydrocarbon mixtures:150 N) in the presence of commercial dispersant RF1151 (monoallyl poly(isobutylene succinimide). The tribological properties of the lubricants were tested with a four-ball friction and wear tester. The friction-induced in-situ formation of carbon films on rubbed steel surfaces under the catalysis of Ni(acac)<sub>2</sub> was investigated, and the as-formed carbon films were characterized by scanning electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. The results show that Ni(acac)<sub>2</sub> added in the base oils can decompose to form metallic nickel to form nickel layer on the rubbed metal sub-surfaces and catalyze the degradation of the base oil molecules adsorbed to form carbon-based tribofilms. The carbon film formed from AN-5 with aromatic ring structure has a high degree of graphitization and the best friction-reducing and antiwear abilities, and those formed from PAO6 and 150 N with linear structure have a low degree of graphitization as well as good tribological properties. Under the lubrication of DIOS with Ni(acac)<sub>2</sub>, however, there is no carbon film formation while the tribological properties of the lubricant are relatively poor, due to the absence of the catalytic metallic nickel and nickel oxide layer on the rubbed metal sub-surface. Thanks to the catalytic effect of metallic nickel released from Ni(acac)<sub>2</sub> for the degradation of various base oils with different molecular structure, the present approach could provide a rational pathway to tune the in-situ formation of carbon-based tribofilm on rubbed steel surfaces so as to effectively reduce the friction and wear of steel-steel sliding pair.</p></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 2","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140657778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-25DOI: 10.1007/s11249-024-01850-8
Yun Dong, Bo Shi, Yi Tao, Xinyi Tang, Jinguang Wang, Yifan Liu, Futian Yang
This paper decodes the dependence of phononic superlubricity on commensurability caused by relative rotation between molybdenum disulfide (MoS2) layers. Results show that under commensurate state, due to the strong interfacial potential, the sliding probe exhibits obvious stick–slip phenomenon; the vibration frequencies of the probe and the substrate are coupled, constructing effective energy transfer channels. As the rotation angle increases, the stick–slip phase and probe inherent oscillation are coupled owing to the decreasing interfacial potential. Once the contacting state reaches to completely incommensurability, the probe only undergoes inherent oscillation. More importantly, we further find that the potential period is determined by the lattice period, which causes the frequency distribution of the excited phonons to remain unchanged although changes in rotation angle. In addition, the contribution of atoms adjacent to friction interface to frictional energy dissipation becomes more significant with the rotation angle increasing. These findings reveal the phononic mechanism of angle-dependent superlubricity between MoS2 layers and provide a viable approach for friction regulation.
{"title":"Commensurability-Dependent Phononic Superlubricity Between Molybdenum Disulfide Layers","authors":"Yun Dong, Bo Shi, Yi Tao, Xinyi Tang, Jinguang Wang, Yifan Liu, Futian Yang","doi":"10.1007/s11249-024-01850-8","DOIUrl":"10.1007/s11249-024-01850-8","url":null,"abstract":"<p>This paper decodes the dependence of phononic superlubricity on commensurability caused by relative rotation between molybdenum disulfide (MoS<sub>2</sub>) layers. Results show that under commensurate state, due to the strong interfacial potential, the sliding probe exhibits obvious stick–slip phenomenon; the vibration frequencies of the probe and the substrate are coupled, constructing effective energy transfer channels. As the rotation angle increases, the stick–slip phase and probe inherent oscillation are coupled owing to the decreasing interfacial potential. Once the contacting state reaches to completely incommensurability, the probe only undergoes inherent oscillation. More importantly, we further find that the potential period is determined by the lattice period, which causes the frequency distribution of the excited phonons to remain unchanged although changes in rotation angle. In addition, the contribution of atoms adjacent to friction interface to frictional energy dissipation becomes more significant with the rotation angle increasing. These findings reveal the phononic mechanism of angle-dependent superlubricity between MoS<sub>2</sub> layers and provide a viable approach for friction regulation.</p>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 2","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140655537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-24DOI: 10.1007/s11249-024-01862-4
Mohamad Taufiqurrakhman, Thawhid Khan, Michael G. Bryant
Previous investigation has established the formation of tribofilm is influenced by tribochemical reactions between the electrolyte and the articulating surface of cobalt alloy through sliding tests in various simulated fluids. Although it has successfully characterized the film composition via spectroscopy analysis and indicated to have impact on material loss, a comprehensive understanding of the material degradation mechanism in tribocorrosion condition was still lacking. Therefore, this study aims to investigate the role of protein in the tribocorrosive degradation of cobalt-chromium-molybdenum (CoCrMo) alloy in different simulated physiological electrolytes. Using a similar testing protocol, tribocorrosion tests were conducted with reciprocating ceramic ball against CoCrMo samples immersed in saline and culture medium, compared to both electrolytes diluted with 25% fetal bovine serum (FBS). Synergistic and mechanistic approaches were employed to model the tribocorrosive degradation. Results reveal that protein plays a beneficial role in reducing corrosive (electrochemical) surface degradation under tribocorrosion condition, whilst increasing mechanical wear degradation in the process. Despite studies have shown that tribocorrosion behavior in metal alloys is highly influenced by the presence of organic matter, this study provides a more clarity of the roles played by protein in tribocorrosive degradation on CoCrMo surface as its novel finding.
{"title":"Investigating the Roles of Protein on the Cobalt Alloy Surface Degradation for Biomedical Implant Through Tribocorrosion Mechanisms","authors":"Mohamad Taufiqurrakhman, Thawhid Khan, Michael G. Bryant","doi":"10.1007/s11249-024-01862-4","DOIUrl":"10.1007/s11249-024-01862-4","url":null,"abstract":"<div><p>Previous investigation has established the formation of tribofilm is influenced by tribochemical reactions between the electrolyte and the articulating surface of cobalt alloy through sliding tests in various simulated fluids. Although it has successfully characterized the film composition via spectroscopy analysis and indicated to have impact on material loss, a comprehensive understanding of the material degradation mechanism in tribocorrosion condition was still lacking. Therefore, this study aims to investigate the role of protein in the tribocorrosive degradation of cobalt-chromium-molybdenum (CoCrMo) alloy in different simulated physiological electrolytes. Using a similar testing protocol, tribocorrosion tests were conducted with reciprocating ceramic ball against CoCrMo samples immersed in saline and culture medium, compared to both electrolytes diluted with 25% fetal bovine serum (FBS). Synergistic and mechanistic approaches were employed to model the tribocorrosive degradation. Results reveal that protein plays a beneficial role in reducing corrosive (electrochemical) surface degradation under tribocorrosion condition, whilst increasing mechanical wear degradation in the process. Despite studies have shown that tribocorrosion behavior in metal alloys is highly influenced by the presence of organic matter, this study provides a more clarity of the roles played by protein in tribocorrosive degradation on CoCrMo surface as its novel finding.</p></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 2","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01862-4.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140662127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-24DOI: 10.1007/s11249-024-01851-7
Jonas Kühlmann, Sebastian A. Kaiser
Repeated single cavitation bubble experiments were performed primarily on 316L stainless steel, and some on nickel–aluminum–bronze (NAB) and pure aluminum. The bubble dynamics were recorded with two high-speed cameras and correlated with surface images, also acquired in situ. These experiments were performed for a range of stand-off distances γ (the ratio of the distance of the solid surface from the bubble to the bubble’s maximum radius) from 0.3 to 2.15. For all stand-off distances, single pits were the only surface change detected at the beginning of damage formation. Later phases of the collapse are not axisymmetric but show regions of “stronger” collapse, and the pits occur on the material underneath those regions. For γ < 0.4, the damage is attributed to the second collapse. For γ > 0.4, the first bubble collapse is most likely responsible for pitting. Shock-wave emission was detected from the collapse regions that were linked to the damage. On 316L, the pitting rate was found to be linearly dependent on the bubble radius, indicating a non-zero lower limit for the bubble radius below which pits do not occur. In terms of stand-off distance, the pitting rate (defined here as average pits per bubble) was non-monotonic, with maxima for bubbles initiated closest to the sample (γ = 0.3) and at γ = 1.4.
{"title":"Single-Bubble Cavitation-Induced Pitting on Technical Alloys","authors":"Jonas Kühlmann, Sebastian A. Kaiser","doi":"10.1007/s11249-024-01851-7","DOIUrl":"10.1007/s11249-024-01851-7","url":null,"abstract":"<div><p>Repeated single cavitation bubble experiments were performed primarily on 316L stainless steel, and some on nickel–aluminum–bronze (NAB) and pure aluminum. The bubble dynamics were recorded with two high-speed cameras and correlated with surface images, also acquired in situ. These experiments were performed for a range of stand-off distances <i>γ</i> (the ratio of the distance of the solid surface from the bubble to the bubble’s maximum radius) from 0.3 to 2.15. For all stand-off distances, single pits were the only surface change detected at the beginning of damage formation. Later phases of the collapse are not axisymmetric but show regions of “stronger” collapse, and the pits occur on the material underneath those regions. For <i>γ</i> < 0.4, the damage is attributed to the second collapse. For <i>γ</i> > 0.4, the first bubble collapse is most likely responsible for pitting. Shock-wave emission was detected from the collapse regions that were linked to the damage. On 316L, the pitting rate was found to be linearly dependent on the bubble radius, indicating a non-zero lower limit for the bubble radius below which pits do not occur. In terms of stand-off distance, the pitting rate (defined here as average pits per bubble) was non-monotonic, with maxima for bubbles initiated closest to the sample (<i>γ</i> = 0.3) and at <i>γ</i> = 1.4.</p></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 2","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01851-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140665901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-22DOI: 10.1007/s11249-024-01857-1
Yi Huang, Liang Liang, Puhua Tang, Zhiming Guo, Yu Liu, Guanyu Hu
In previous works, when studying the frictional behaviour of the small intestine, the small intestine was always in a natural state. However, when a capsule endoscope is travelling through the small intestine, since the diameter of the capsule endoscope may larger than the small intestine, the small intestine is then expanded in circumferential direction, which implies that previous works are not sufficient. This work uses flat–flat contact to simulate a capsule travelling through the small intestine, comparing the frictional behaviour of the small intestine in its natural and circumferentially expanding states, analysing the effects of other factors such as load, velocity and lubrication, which provides a realistic basis for the optimisation and control of magnetically controlled endoscopes.