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Phenolphthalein Indicator in Titrimetric Estimation of Benzoic Acid Solubility and Distribution in Water and Benzene-Buffer Solutions 苯甲酸在水和苯缓冲溶液中的溶解度和分布的滴定测定中的酚酞指示剂
Pub Date : 2022-06-04 DOI: 10.9734/ajocs/2022/v11i419128
S. Mishra
In solubility and partitioning process of benzoic acid, the various factors are involved such as temperature, solute-solvent interaction and dissociation of acid into ionic state in taking solvents. Here, we reported the benzoic acid (solute) solubility in gram/100gram of solvent in different pH benzene-buffer solutions which are analyzed by using of titration method and partition study of these acid into solvents like water and benzene layer by shake-flask acid-base titration method, at room temperature (25°C) for 24 hours. In titrimetric estimation the solute benzoic acid solubility and their partition in between of water and in different pH buffer solutions as in medium of acidic, neutral and basic, a phenolphthalein indicator have been used well. The solvents and benzene-buffer solutions having different pH 4.0, 7.0 and 9.0 is titrated against as 0.01, 0.05 and 0.1N NaOH solutions by using phenolphthalein as indicator, where the end point show a pink color for each reading. Concentration of benzoic acid into water and solvent benzene layers is being calculated as by applying the equation of normality determination and distribution coefficient as from Nernst distribution law equation.
在苯甲酸的溶解度和配分过程中,温度、溶媒相互作用以及酸在溶剂中解离成离子态等因素都是影响其溶解度和配分的重要因素。本文报道了在不同pH的苯缓冲溶液中,苯甲酸(溶质)在克/100g溶剂中的溶解度,用滴定法分析了不同pH的苯缓冲溶液,并用摇瓶酸碱滴定法研究了苯甲酸在室温(25℃)下24小时在水和苯层等溶剂中的分配。在滴定测定溶质苯甲酸在水和不同pH缓冲溶液中的溶解度及其在酸性、中性和碱性介质中的分配时,酚酞指示剂得到了很好的应用。以酚酞为指示剂,分别对pH值为4.0、7.0、9.0的溶剂和苯缓冲溶液分别以0.01、0.05、0.1N的NaOH溶液进行滴定,每次读数终点显示为粉红色。应用能斯特分布方程中的正态性测定方程和分布系数,计算了苯甲酸在水和溶剂苯层中的浓度。
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引用次数: 1
Adsorbents Used for the Adsorptive Removal of Highly Hazardous Arsenic from Aqueous Solution: A Review 用于吸附去除水溶液中高浓度砷的吸附剂:综述
Pub Date : 2022-05-26 DOI: 10.9734/ajocs/2022/v11i319124
N. Alamrani, Yazeed Alotaibi, Fahad Oudah Eid Alhawiti, Theyab Ali T. Almutairi, Essa Almutairi, Mashree Mohammad M. Albalawi, Hatem A. Al-Aoh, Syed Khalid Mustafa
Millions of people worldwide are adversely affected by Arsenic continuing exposure, so providing arsenic-free consumption of water is an immense task for the researchers. The chemistry, content of arsenic-contaminated water as well as adsorption play a big role in arsenic elimination. The mechanism of adsorption technology's elimination of As (V) from the water was simply presented as the elements that govern various adsorption paths. The effects of a variety of adsorbents on As (V) elimination from aquatic were explored in the present research, which classified the materials used as adsorbents based on physical, chemical, and biological processes. When choosing an adsorbent, adsorption capability is an important factor to consider. As a result, developing As (V) elimination from aquatic adsorption strategies includes developing environmentally acceptable materials with effectual adsorption abilities, refining the preparation and alteration procedures of recent adsorbents, and boosting renewal effectiveness. After choosing a particular adsorbent for As (V) elimination from water, regional features of arsenic-polluted water, applied viability of the adsorption process, besides suitable environments of respectively material must be extensively reviewed and analyzed. The current study gives an outline of the adsorption technique to remove arsenic from wastewater, as well as the adsorption capacity of various adsorbents.
全世界数百万人因持续接触砷而受到不利影响,因此提供无砷饮用水对研究人员来说是一项艰巨的任务。砷污染水的化学性质、含量以及吸附对砷的消除起着很大的作用。将吸附技术去除水中As (V)的机理简单地描述为控制各种吸附路径的元素。本文从物理、化学和生物三个方面对吸附剂进行了分类,探讨了各种吸附剂对水中As (V)去除的影响。在选择吸附剂时,吸附能力是一个重要的考虑因素。因此,从水生吸附策略中发展As (V)消除包括开发具有有效吸附能力的环境可接受材料,改进最近吸附剂的制备和改变程序,以及提高更新有效性。在选择特定的吸附剂去除水中砷(V)后,除了对各自材料的适宜环境进行广泛的审查和分析外,还必须对砷污染水的区域特征、吸附过程的应用可行性进行广泛的审查和分析。本文概述了废水中砷的吸附技术,以及各种吸附剂的吸附能力。
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引用次数: 0
Fractionation, Mobility and Environmental Risk of Trace Metals in the Sediments from N’zi River, Côte d’Ivoire N 'zi河沉积物中微量金属的分异、迁移率及环境风险Côte d '科特迪瓦
Pub Date : 2022-05-26 DOI: 10.9734/ajocs/2022/v11i319125
Ahbeauriet Ahmed Ouattara, Koffi Pierre dit Adama N’goran, M. Soro, H. Koné, Kouassi Beranger N’guessan, K. M. Yao
Despite increasing human activities, such as agriculture, little information is available on the status of trace metals contamination in rivers in developing countries including Côte d’Ivoire (West Africa). The aim of this study was study chemical fractions of Cu, Pb, Zn, and Ni, to identify mobility, sources and to evaluate ecological risks of traces metal in sediment of N’zi River using modified BCR sequential extraction procedure. The results showed that all metal were dominated by residual fractions. Labile fractions of Pb accounted for 0.0 – 68% of total contents indicating significant anthropogenic sources for Pb, while for Cu, Ni and Zn results suggesting natural sources. The potential mobility of the metals manifested following order:  Ni > Zn > Cu > Pb. Risk assessment code indicated low to medium risk for Pb and low risk for other metals in the sediments. Cluster analysis (CA) and Matrix correlation were used to detect the relationship between the studied sampling sites and to see if some of the parameters interrelated with each trace metal concentration in exchangeable fraction. Results indicated high anthropogenic contamination at stations near to urban and agricultural areas.
尽管农业等人类活动日益增多,但发展中国家(包括Côte科特迪瓦(西非))河流中微量金属污染状况的信息却很少。本研究采用改进的BCR序贯提取方法,对N’zi River沉积物中Cu、Pb、Zn和Ni的化学组分进行了研究,以确定其迁移率、来源并评价其生态风险。结果表明,所有金属均以残余组分为主。Pb的不稳定组分占总含量的0.0 ~ 68%,表明Pb有明显的人为来源,而Cu、Ni和Zn的结果表明自然来源。金属的潜在迁移率依次为Ni > Zn > Cu > Pb。风险评估代码显示沉积物中Pb为中低风险,其他金属为低风险。采用聚类分析(CA)和矩阵相关(Matrix correlation)来检测采样点之间的关系,并观察某些参数是否与交换分数中各痕量金属浓度相关。结果表明,靠近城市和农业区的监测站的人为污染程度较高。
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引用次数: 0
Chromium (VI) Removal from Wastewater by Batch Adsorption Mode using Date Nut Carbon 枣核炭间歇吸附法去除废水中的铬(ⅵ
Pub Date : 2022-04-29 DOI: 10.9734/ajocs/2022/v11i319123
S. Sophie Beulah, K. Muthukumaran
Water pollution has great impact on environmental degradation. Release of untreated wastewater containing toxic metal ions into natural waters is a threat to aquatic ecosystem and is attributed to affect the health of living things. Date nut carbon was analysed as an adsorbent for extracting Cr(VI) ions from wastewater using batch method. Investigations were done by varying the pH from 1 to 6, carbon dose from 0.1 g to 0.5 g and equilibration time from 1 to 24 hours. Cr(VI) removal of 93% occurred at an optimal pH of 2, carbon dose of 0.3 g/100mL, and equilibration time of 3 hours. The adsorption of Cr(VI) on Date nut carbon followed first order kinetics. The kinetic process of Cr(VI) adsorption onto Date nut carbon was tested by applying first order kinetics.
水污染对环境退化的影响很大。含有有毒金属离子的未经处理的废水排放到自然水体中对水生生态系统构成威胁,并影响生物的健康。采用间歇法对枣子碳作为吸附剂萃取废水中的铬(VI)离子进行了研究。通过改变pH从1到6,碳剂量从0.1 g到0.5 g,平衡时间从1到24小时来进行研究。在最佳pH为2、碳投加量为0.3 g/100mL、平衡时间为3小时的条件下,Cr(VI)去除率为93%。枣核碳对Cr(VI)的吸附符合一级动力学。采用一级动力学方法研究了枣核碳吸附Cr(VI)的动力学过程。
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引用次数: 0
Synthesis and Spectral Characterization of Chalcone dervived from 6-Acetyl-2H-1,4-benzoxazin-(4H)-3-one: Single-crystal XRD, Hirshfeld Surface Analysis and DFT Calculations 6-乙酰基- 2h -1,4-苯并恶嗪-(4H)-3-酮查尔酮的合成及光谱表征:单晶XRD、Hirshfeld表面分析和DFT计算
Pub Date : 2022-04-16 DOI: 10.9734/ajocs/2022/v11i319122
R. Rajalakshmi, S. Ramkumar, A. Sripriya
Compound (E)- 6-(3-(p-tolyl)acryloyl)- 2H-benzo[b][1,4]oxazin-3(4H)- one [6TABO] with molecular formula C18H15NO3 was synthesized utilizing Claisen-Schmidt condensation technique. FT-IR and 1H NMR spectra were recorded to recognize the different utilitarian gatherings present in the compound and affirm the synthetic construction. The UV-Visible range study uncovers that the visible is straightforward in the whole apparent locale and the retention is seen at 325.40 nm. Single-crystal XRD concentrates on show that the compound takes shape in the monoclinic framework with a space bunch P 1 21/c 1. The corresponding lattice parameters of the crystal are a = 13.0723 (7) Å, b = 7.1789 (4) Å, c = 16.1812 (9) Å, α=900, β = 109.148 (2)0, γ = 900.
利用Claisen-Schmidt缩合技术合成了分子式为C18H15NO3的化合物(E)- 6-(3-(对甲苯基)丙烯酰)- 2h -苯并[b][1,4]恶嗪-3(4H)- 1 [6TABO]。记录了FT-IR和1H NMR光谱,以识别化合物中存在的不同实用基团,并确定了合成结构。紫外可见范围研究发现,可见光在整个视区域是直接的,并且在325.40 nm处可见保留。单晶XRD集中表明,化合物呈单斜骨架结构,空间束为p21 / c1。晶体相应的晶格参数为a = 13.0723 (7) Å, b = 7.1789 (4) Å, c = 16.1812 (9) Å, α=900, β = 109.148 (2)0, γ =900。
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引用次数: 1
Metal Pollution, Ecological and Health Risks Status of the Open Waters from the Lagoon Area II of Ébrié System (Côte d'Ivoire) Ébrié系统泻湖II区开放水域金属污染、生态和健康风险状况(Côte科特迪瓦)
Pub Date : 2022-04-05 DOI: 10.9734/ajocs/2022/v11i319121
Agole Mahi ARTHUR MAHI, Yao Marcel Konan, Claon Jean Stephane, Trokourey Albert
The assessments of the seasonal metal pollution, as well as the subsequent likely ecological and health risks, of the open waters from the lagoon area II of Ébrié system were the subject of this study. For this purpose, the seasonal mean of As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, and Zn contents of these waters determined over the period from June 2020 to May 2021 were used. The water quality guidelines SEQ-Eau (version 2) and NQE DCE-UE 2018/240 were used to assess the seasonal ecological quality of these waters. As for the seasonal biota health risks, they have been assessed with the water quality guidelines of NYSDEC, US-EPA and SAVEX. Those concerning to Human health risks, they were with WQSSW of Port Gamble S'Klallam tribe. The results showed an important ecological degradation of these waters in all seasons. This has been due to As, Cd, Hg, Ni, and Pb. The likely biota health risks are also significant in all seasons, due to As, Hg, Ni, and Pb. As for the likely Human health risks, they are also important in all seasons. They are due to As, Hg, and Ni over the study period.
本研究的主题是评估Ébrié系统泻湖II区开放水域的季节性金属污染,以及随后可能的生态和健康风险。为此,使用了2020年6月至2021年5月期间测定的这些水域As、Cd、Cr、Cu、Fe、Hg、Mn、Ni、Pb和Zn含量的季节平均值。使用水质指南SEQ-Eau(第2版)和NQE DCE-UE 2018/240对这些水域的季节性生态质量进行评估。关于季节性生物群的健康风险,已根据NYSDEC、US-EPA和SAVEX的水质准则进行了评估。那些涉及人类健康风险的,是Port Gamble S'Klallam部落的WQSSW。结果表明,这些水域在所有季节都出现了严重的生态退化。这是由于砷,镉,汞,镍和铅。由于砷、汞、镍和铅,可能的生物群健康风险在所有季节都很显著。至于可能的人类健康风险,它们在所有季节都很重要。它们是由于研究期间的砷、汞和镍。
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引用次数: 1
Controlled Catalytic Reduction in Synthesising Pure Tetrahydrocurcumin 控制催化还原合成纯四氢姜黄素
Pub Date : 2022-03-25 DOI: 10.9734/ajocs/2022/v11i219120
Chandra Sekhara Rao Nethinti, Dhanraj T. S. S. Sundaram, Sarvesh Kumar, Sreenivasulu Boju, Raghu Babu Korupolu, Annapurna Nowduri, Uttam Kumar Ray
Pd-Catalyzed hydrogenation process has been developed to synthesize tetrahydrocurcumin from synthetic curcumin. Use of diphenyl sulphide as catalyst poison is crucial for lowering the activity of the catalyst and thus reduces impurity formation. The process avoids column chromatography to achieve good quality tetrahydrocurcumin in cost effective manner. All the prepared compounds are characterized by FT-IR, 1H NMR, mass and HPLC techniques.
以合成的姜黄素为原料,开发了pd催化加氢合成四氢姜黄素的工艺。使用二苯基硫化物作为催化剂毒药对于降低催化剂的活性,从而减少杂质的形成是至关重要的。该工艺避免了柱层析,以经济有效的方式获得高质量的四氢姜黄素。所有化合物都通过FT-IR、1H NMR、质谱和HPLC等技术进行了表征。
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引用次数: 1
Structural Characterization, DFT, Molecular Docking and Cytotoxic Studies of Metal (II) Complexes Derived from Thiosemicarbazide 巯基氨基脲类金属配合物的结构表征、DFT、分子对接及细胞毒性研究
Pub Date : 2022-03-25 DOI: 10.9734/ajocs/2022/v11i219119
T. Manjuraj, G. Krishnamurthy, T. C. M Yuvaraj, N. Jayanna, Mohammed Imadadulla
Co(II), Ni(II) and Cu(II) complexes of N and O donor ligand derived from ,5-dinitrosalicylicacid and thiosemicarbazide, the spectroscopy techniques like UV-Visible, FT-IR, NMR, mass spectrometry, p-XRD and SEM analysis were used to structurally characterize the metal complexes. From the analytical and spectral evidence, the square planar and octahedral geometry has been proposed to metal (II) complexes. In addition to this computational density functional theory (DFT) using B3LYP/6-31Gþ(d, p)/Lanl2dz(f) method in the ground state was performed, the calculations were done to confirm the geometry of the complexes and also HOMO-LUMO excitation energies levels were also calculated. Additionally, MTT test was used to perform cytotoxic assays on selected MCF-7 (estrogen receptor-positive human breast cancer cells) and HeLa (human cervical cancer cell line) cell lines. The antibacterial test was performed via the disc plate method against Escherichia coli and Staphylococcus aureus, and was further supported by molecular docking interactions using protein receptor SEC2 (PDB code: 1STE) in Staphylococcus aureus.
以5-二硝基水杨酸和硫代氨基脲为原料制备的Co(II)、Ni(II)和Cu(II)配合物,采用uv -可见、FT-IR、NMR、质谱、p-XRD和SEM等光谱技术对配合物进行了结构表征。从分析和光谱证据可以看出,金属(II)配合物具有方形平面和八面体的几何结构。除了利用B3LYP/6-31Gþ(d, p)/Lanl2dz(f)方法在基态下进行计算密度泛函理论(DFT)外,还计算了配合物的几何形状,并计算了HOMO-LUMO激发能级。此外,采用MTT试验对选定的MCF-7(雌激素受体阳性的人乳腺癌细胞)和HeLa(人宫颈癌细胞系)细胞株进行细胞毒性测定。通过圆盘平板法对大肠杆菌和金黄色葡萄球菌进行抑菌试验,并进一步通过金黄色葡萄球菌蛋白受体SEC2 (PDB代码:1STE)的分子对接相互作用进行支持。
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引用次数: 0
Minerals That Make Up the Montmorillonite Group 构成蒙脱石群的矿物
Pub Date : 2022-03-22 DOI: 10.9734/ajocs/2022/v11i219118
Khandamov Davron Abdikadirovich, Djumaniyazova Malokhat Rihsiyevna, Tursunova Dilnozakhon Isroiljon Qizi
Clays containing materials of regular structure are the most common inorganic sorbents for water purification in nature. Sorbents belonging to the type of expandable structural stratum minerals include montmorillonite and vermiculite, which form the basis of bentonite clays. Bentonites are clays which compose mainly of minerals belonging to the group of montmorillonite and sometimes called stonesoap. Navbahor alkaline bentonite deposit is located in Navbahr district of Navoi region of Uzbekistan Republic. The current proven reserves of the deposit are more than 7142.6 thousand tons. Montmorillonite is mainly the most effective adsorbent for various compounds and water purification. The surface area of montmorillonite is 450 m2/g, and vermiculite is 450-500 m2/g [1].
含规则结构物质的粘土是自然界中最常用的水净化无机吸附剂。吸附剂属于可膨胀结构地层矿物类型,包括蒙脱土和蛭石,它们构成膨润土粘土的基础。膨润土是一种粘土,主要由蒙脱土属的矿物组成,有时被称为石皂。纳夫巴赫碱性膨润土矿床位于乌兹别克斯坦共和国纳沃伊州纳夫巴赫地区。该矿床目前探明储量714.26万吨以上。蒙脱土主要是各种化合物和水净化最有效的吸附剂。蒙脱土的表面积为450 m2/g,蛭石的表面积为450-500 m2/g[1]。
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引用次数: 0
Optimization of Extraction Process Based on Neural Network 基于神经网络的提取过程优化
Pub Date : 2022-03-05 DOI: 10.9734/ajocs/2022/v11i219117
Jing Sun, Qiong Chen
Liquid-liquid extraction is a chemical unit operation that utilizes the difference in solubility or distribution ratio of target components in two immiscible solvents to achieve separation, extraction or purification. There are many factors that affect the extraction efficiency, and it is difficult to quickly optimize the process using traditional methods. Artificial neural network is a system structure composed of multiple artificial neuron models, with functions such as self-learning, associative storage and fault tolerance. It can be used for optimization or control of multi-variable complex systems, and has been successfully applied to the extraction process of various products. optimization. This paper discusses the basic situation of artificial neural network, and analyzes the research progress of extraction process optimization based on neural network.
液-液萃取是利用目标组分在两种不混溶溶剂中的溶解度或分布比的差异来实现分离、提取或纯化的一种化学单元操作。影响提取效率的因素很多,传统方法难以快速优化提取工艺。人工神经网络是由多个人工神经元模型组成的系统结构,具有自学习、联想存储和容错等功能。它可用于多变量复杂系统的优化或控制,并已成功应用于各种产品的提取过程。优化。论述了人工神经网络的基本情况,分析了基于神经网络的提取过程优化的研究进展。
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引用次数: 4
期刊
Asian Journal of Chemical Sciences
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