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Conversion of xylose into D-xylitol using catalytic transfer hydrogenation with formic acid as H-donor 甲酸为h供体催化转移加氢木糖制d -木糖醇的研究
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-31 DOI: 10.15376/biores.18.4.8631-8652
Danuta Joanna Aigner, Lena Hinterholzer, Lukas Almhofer, Robert H. Bischof, Tanja Wrodnigg
d-Xylitol, a biomass-derived sweetener, is increasingly used in cosmetics and pharmaceutical products. The raw material for d-xylitol production, d-xylose, is easily accessible from dissolving pulp production. d-xylitol production involves the heterogeneously catalyzed hydrogenation of d-xylose; this process is energy intensive, as the use of H2 requires high pressure and temperature. This work examined catalytic transfer hydrogenation for xylose conversion into xylitol. Formic acid (FA) was used to replace H2 as the H-donor, as it is easily available, inexpensive, may be obtained from renewable sources, and it avoids the risks associated with the use of high-pressure inflammable gas. A variety of commercially available catalysts were screened to reveal the one enabling the highest yield. The experiments were performed at 40, 80, and 140 °C, with pure xylose as a model compound. Triethylamine (Et3N) was added to ensure sufficient conversion rates. Based on the preliminary studies an experimental design was created (Design Expert®), including the two best performing catalysts Ru/Al2O3 and Ru/C, to investigate the influence of temperature and H-donor and base concentration on xylitol yield. Ru/C resulted in maximum d-xylitol yield of 73.2 % at 100 °C, FA to d-xylose ratio 5:1 and Et3N to FA ratio 0.4.
d-木糖醇是一种生物来源的甜味剂,越来越多地用于化妆品和制药产品。d-木糖醇生产的原料d-木糖很容易从溶解纸浆生产中获得。d-木糖醇的生产涉及d-木糖的多相催化加氢;这个过程是能源密集型的,因为使用H2需要高压和高温。研究了木糖转化为木糖醇的催化转移加氢反应。采用甲酸(FA)代替H2作为氢供体,因为它容易获得,价格低廉,可以从可再生资源中获得,并且避免了使用高压可燃性气体的风险。筛选了多种市售催化剂,以确定产率最高的催化剂。实验分别在40、80和140°C下进行,以纯木糖为模型化合物。加入三乙胺(Et3N)以保证足够的转化率。在初步研究的基础上,采用设计专家(design Expert®)设计了两种性能最佳的催化剂Ru/Al2O3和Ru/C,考察了温度、h给体浓度和碱浓度对木糖醇收率的影响。在100℃、FA与d-木糖比为5:1、Et3N与FA比为0.4的条件下,Ru/C的d-木糖醇收率最高为73.2%。
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引用次数: 0
Thermal-degradation characteristics of mechanically nanofibrillated bleached pulps from hardwood and softwood 硬木和软木机械纳米纤化漂白纸浆的热降解特性
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-30 DOI: 10.15376/biores.18.4.8573-8584
Akihiro Hideno
Nanofibrillated cellulose (NFC) consists of ultrafine cellulose structures in which the fibrils can have widths in the range from about 5 to 100 nm. NFC has been studied and developed in the paper industry, using bleached pulp from wood as the raw material. One of the issues in the application of NFC is their heat resistance to thermal degradation. The production process of NFC results in a decrease in their pyrolysis temperature during the nanofibrillation of bleached pulp; however, the details behind the reason and mechanisms are still unclear. In this study, NFC was prepared from bleached hardwood and softwood pulp by mechanical nanofibrillation using a grinder, and the pyrolysis behavior was investigated. For both bleached pulps, a decrease in the pyrolysis temperature was observed after nanofibrillation. The results suggest that the decrease in the pyrolysis temperature from nanofibrillation is not due to damage of the crystalline cellulose by nano fibrillation, but the damage of the hemicellulose components in the surface of the cellulose microfibrils or the interface between the crystalline cellulose and hemicellulose. If the hemicellulose on the surface of crystalline cellulose could be removed from the NFC, then the decrease in the pyrolysis temperature could be suppressed.
纳米纤维化纤维素(NFC)由超细纤维素结构组成,其中原纤维的宽度范围约为5至100纳米。以漂白过的木浆为原料,在造纸工业中进行了NFC的研究和开发。近距离通信技术应用中的一个问题是其耐热性。NFC的产生导致漂白纸浆纳米纤化过程中热解温度降低;然而,原因和机制背后的细节仍不清楚。本研究以漂白后的硬木和软木浆为原料,采用机械纳米纤颤法制备了NFC,并对其热解行为进行了研究。两种漂白纸浆经过纳米纤颤后,热解温度均有所降低。结果表明,纳米纤维的热解温度降低不是由于纳米纤维损伤了结晶纤维素,而是由于纳米纤维损伤了纤维素微原表面的半纤维素成分或晶体纤维素与半纤维素的界面。如果能将结晶纤维素表面的半纤维素从NFC中去除,则可以抑制热解温度的降低。
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引用次数: 0
Changes in the physical and mechanical properties of Pinus taeda and Eucalyptus bosistoana wood modified by contact charring 接触炭化改性松木和桉树木材物理力学性能的变化
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-30 DOI: 10.15376/biores.18.4.8614-8630
Claudia Marcela Ibanez, S. Nami Kartal, Ekim Elçin Soytürk, Fatih Kurul, Sedanur Şeker, M. Serdar Önses, Nusret Çelik, Adem Berke Temiz
Physical and mechanical properties were evaluated for all-sided charred Pinus taeda and Eucalyptus bosistoana wood by hot plate contact heating system followed by treatment with linseed oil. The water absorption, volumetric swelling, wettability, hardness, modulus of rupture, and modulus of elasticity in bending strength and compression strength parallel to grain were determined. The water absorption and volumetric swell were determined after immersion in water, as measured at various intervals of water immersion up to 120 h. The results suggested that the contact charring process with the addition of a linseed oil application improved water absorption and volumetric swell properties of charred specimens compared to un-charred controls. Hardness of the charred wood decreased by 38% and 43% in P. taeda and E. bosistoana specimens, respectively, compared with their respective controls. The highest reductions were seen in modulus of elasticity and compression strength values in charred P. taeda specimens, while modulus of rupture (MOR) values decreased more in charred E. bosistoana specimens than in charred P. taeda specimens. These results suggested that charring of P. taeda and E. bosistoana wood does improve the moisture-related characteristics; however, their mechanical behavior and hardness decreased.
采用热板接触加热和亚麻油处理的方法,对全焦红松和桉树木材的物理力学性能进行了研究。测定了材料的吸水率、体积膨胀率、润湿性、硬度、断裂模量、平行于晶粒的抗折强度和抗压强度中的弹性模量。浸水后的吸水率和体积膨胀率在浸水至120 h的不同时间间隔内进行测量。结果表明,与未炭化的对照相比,添加亚麻籽油的接触炭化过程改善了炭化样品的吸水率和体积膨胀率。炭化木材的硬度与对照相比分别下降38%和43%。炭化黄檀试样的弹性模量和抗压强度下降幅度最大,而炭化黄檀试样的断裂模量(MOR)下降幅度更大。这些结果表明,炭化处理确实改善了紫檀和野檀木材的水分相关特性;但其力学性能和硬度均有所下降。
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引用次数: 0
Integrated management practices against an emerging Bakanae disease of rice under the hot-humid climate of Indo-Gangetic plains of India 印度恒河平原湿热气候下水稻新发Bakanae病的综合管理措施
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-30 DOI: 10.15376/biores.18.4.8585-8600
Bishnu Maya Bashyal, Ashish Kumar Gupta, Dhiraj Singh, Dinesh Singh, Rohan Raman, Gaurav Kumar Yadav, S. Gopalakrishnan, Rashmi Aggarwal
Bakanae disease caused by Fusarium fujikuroi is emerging in India. In this work, fungicides and biocontrol agents were evaluated as seed, seedling treatment, and foliar spray(s) against bakanae disease in rice under field conditions. Carbendazim (50% WP) was found to be the most effective fungicide for seed and seedling root dip treatments. Soil drenching with 0.25% carbendazim (50% WP) 5 days before transplanting of seedlings was effective for large scale treatments. Foliar spray of 0.1% tebuconazole 50%+ trifloxystrobin 25% w/w (75 WG) significantly reduced the percentage of infected seeds (7.17%) compared with the control (32.50%). The minimum disease incidence (31%) was observed when seeds were treated with Talaromyces flavus. Individual treatments were integrated in the form of six management modules and evaluated under the field conditions of New Delhi (India) and Pusa Bihar (India) with the susceptible cultivars ‘Pusa Basmati 1121’ and ‘Pusa 1176’. Bakanae disease incidence was lower in the modules tested compared with the inoculated control or the individual treatment. The most favorable results at two locations achieved the lowest disease incidence of 7% and 2.41%.
由藤黑镰刀菌引起的Bakanae病正在印度出现。在田间条件下,研究了杀菌剂和生物防治剂在水稻种子、幼苗和叶面喷雾剂中的防治效果。多菌灵(50% WP)是种子和幼苗根浸处理最有效的杀菌剂。苗期移栽前5 d进行0.25%多菌灵(50% WP)土壤淋水处理效果较好。叶面喷施0.1%戊唑唑50%+三氟虫酯25% w/w (75 WG)可显著降低种子侵染率(7.17%),显著低于对照(32.50%)。用黄Talaromyces flavus处理种子时,发病率最低(31%)。以“Pusa Basmati 1121”和“Pusa 1176”为敏感品种,在印度新德里和印度普萨比哈尔邦的田间条件下,以6个管理模块的形式对单个处理进行综合评价。与接种对照或单独处理相比,所测模块的白僵菌病发病率较低。结果最有利的两个地点的发病率最低,分别为7%和2.41%。
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引用次数: 0
Formaldehyde emission pattern of melamine impregnated paper decorated medium density fiberboard and its furniture products 三聚氰胺浸渍纸装饰中密度纤维板及其家具产品的甲醛释放规律
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-30 DOI: 10.15376/biores.18.4.8601-8613
Chen Chen, Yan Qiu, Yueqian Yang, Wei Xu
Melamine-impregnated paper decorated medium-density fiberboard (MIP-MDF) is the main board used for wooden furniture materials in China, and the formaldehyde released from the board and furniture products is harmful to human beings and is a wide concern. This paper aimed to pay attention to the formaldehyde emission of MIP-MDF and its furniture products. This study utilized a 1 m³climatic chamber to measure the formaldehyde emission of MIP-MDF and nightstand made of MIP-MDF in relation to the time and load factors. According to the results, in the 2 to 24 h stage, the emission of formaldehyde in the nightstand made of MIP-MDF materials changed significantly, and the overall trend showed a changing trend of first increasing and then declining. The formaldehyde emission of MIP-MDF stabilized after 40 h, while the formaldehyde emission of the nightstand stabilized after 60 h. As time passed, the formaldehyde emission changes of MIP-MDF and nightstand were almost the same. The formaldehyde emission of MIP-MDF and nightstand has a specific positive correlation with the carrying load. With increased carrying loads, the formaldehyde emission tends to increase, but the degree of influence gradually decreases with the addition of the carrying loads.
三聚氰胺浸渍纸装饰中密度纤维板(MIP-MDF)是中国木制家具材料中主要使用的板材,其板材和家具产品中释放的甲醛对人体有害,受到广泛关注。本文旨在关注MIP-MDF及其家具产品的甲醛释放量。本研究利用1 m³的气候室测量MIP-MDF和MIP-MDF床头柜的甲醛释放量与时间和负荷因素的关系。结果表明,在2 ~ 24 h阶段,MIP-MDF材料床头柜甲醛释放量变化明显,整体趋势呈现先上升后下降的变化趋势。MIP-MDF的甲醛释放量在40 h后趋于稳定,而床头柜的甲醛释放量在60 h后趋于稳定。随着时间的推移,MIP-MDF和床头柜的甲醛释放量变化几乎相同。MIP-MDF和床头柜的甲醛释放量与承载量呈显著正相关。随着承载负荷的增加,甲醛释放量有增加的趋势,但随着承载负荷的增加,影响程度逐渐降低。
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引用次数: 0
Preparation and physicochemical properties of biochar from the pyrolysis of pruning waste of typical fruit tree in north China 北方典型果树剪枝废弃物热解制备生物炭及其理化性质研究
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-30 DOI: 10.15376/biores.18.4.8536-8556
Xuelei Liu, Xueyong Ren, Jiangchuan Dong, Bowei Wang, Jianli Gao, Ruijiang Wang, Jingjing Yao, Wenbo Cao
Routine maintenance of fruit trees generates a substantial quantity of pruning waste each year. This waste is potential feedstock for producing energy, materials, and other products. The feasibility of making biochar from the waste via pyrolysis was evaluated. The effects of seven tree species, different pruning sites, and temperature on the pyrolysis process, and the physicochemical properties of the biochar were studied. Pyrolysis of different tree species at 500 °C yielded 27.5 to 33.3% biochar, with a high calorific value (approximately 30 MJ/kg), low ash content (approximately 4%), and capturing up to 60% of the carbon element present. Simultaneously, when the temperature was increased from 400 to 700 °C, the yield of biochar decreased from 35.8% to 24.3%, but the properties improved with the higher heating value rising from 29.2 to 31.3 MJ/kg and the iodine value from 234 to 252 mg/g. The biochar has a good pore structure with a specific surface area of 237 m2/g, total pore volume of 0.175 cm3/g, and average pore size of 2.96 nm. In general, biochar from the pyrolysis of fruitwood pruning waste generated here could be an ideal feedstock to produce high-value-added products, such as solid fuels, activated carbon, and electrode materials.
果树的日常维护每年都会产生大量的修剪废物。这种废物是生产能源、材料和其他产品的潜在原料。评价了利用该废弃物热解制生物炭的可行性。研究了7种树种、不同修剪位置和温度对生物炭热解过程和理化性质的影响。不同树种在500°C下热解产生27.5%至33.3%的生物炭,具有高热值(约30 MJ/kg),低灰分含量(约4%),并捕获高达60%的碳元素。同时,当温度从400℃升高到700℃时,生物炭的产率从35.8%下降到24.3%,但性能得到改善,热值从29.2 MJ/kg提高到31.3 MJ/kg,碘值从234提高到252 mg/g。该生物炭具有良好的孔隙结构,比表面积为237 m2/g,总孔体积为0.175 cm3/g,平均孔径为2.96 nm。一般来说,这里产生的水果修剪废弃物热解产生的生物炭可能是生产高附加值产品的理想原料,如固体燃料、活性炭和电极材料。
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引用次数: 0
Effects of nanoparticle applications on seedling survival and morphological characteristics in Scots pine afforestation 纳米颗粒对杉松造林幼苗成活及形态特征的影响
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-30 DOI: 10.15376/biores.18.4.8557-8572
Sezgin Ayan, Esra Nurten Yer Çelik, Orhan Gülseven, Batın Mehmet Yer, Muhammed Eskiömer
This study was conducted in the afforestation area, using bare-root 2+0-year-old Scots pine seedlings from Kastamonu. The study aimed to determine the impact of nanoparticle (NP) applications on seedling morphological characteristics and seedling survival success. Three different concentrations (low, medium, high) and four different nanoparticle types [Fe₃O₄, CuO, ZnO, TiO2] were applied to the plant root-dipping method in the study. The effects of NP treatments on seedling height (SH), root collar diameter (RCD), stem fresh weight (SFW), root new weight (RFW), seedling fresh weight (SEFW), root dry weight (RDW), stem dry weight (SDW), seedling dry weight (SEDW), sturdiness quotient (SI), root: shoot ratio (R/S), and seedling survival in the field were evaluated. The study results revealed that NP types significantly affected all seedling variables except RFW, SDW, RDW, and SEDW, and NP doses significantly affected all seedling variables except RFW. The binary interaction effects of NP types and doses had a significant effect on all seedling variables, and higher values were obtained compared to the control treatment. Medium and high NP doses were more effective in seedling growth than low doses; the percentage of seedling survival was 61.4% in the control treatment and 95% in the TiO2-Medium NP treatment combination.
本研究在造林区内进行,使用来自Kastamonu的2+0年裸根苏格兰松幼苗。本研究旨在确定纳米颗粒(NP)的施用对幼苗形态特征和幼苗成活率的影响。采用三种不同浓度(低、中、高)和四种不同纳米颗粒类型[Fe₃O₄,CuO, ZnO, TiO2]对植物进行浸根处理。评价了NP处理对大田幼苗高(SH)、根颈直径(RCD)、茎鲜重(SFW)、根新重(RFW)、幼苗鲜重(SEFW)、根干重(RDW)、茎干重(SDW)、幼苗干重(SEDW)、结实商(SI)、根冠比(R/S)和幼苗成活率的影响。结果表明,NP类型对除RFW、SDW、RDW和SEDW外的所有幼苗变量均有显著影响,NP剂量对除RFW外的所有幼苗变量均有显著影响。NP类型和剂量的二元互作效应对所有幼苗变量均有显著影响,且均高于对照处理。中、高剂量NP比低剂量对幼苗生长更有效;对照处理的幼苗成活率为61.4%,tio2 -培养基NP组合处理的幼苗成活率为95%。
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引用次数: 0
Evaluation and production of high-strength wood composite panels with polyethylene terephthalate (PET) 高强度聚对苯二甲酸乙二醇酯(PET)木复合板的评价与生产
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-27 DOI: 10.15376/biores.18.4.8528-8535
Pedro H. S. Campos, Antonio J. Santos Junior, Matheus V. de Souza, Marjorie P. Herradon, Vitória B. L. Libera, Lucas. E. Dezen, Élen V. da Silva, Ananda G. B. P. Silva, Felipe R. Rodrigues, Rodrigo A. Bispo, Pedro H.S. Cazella, Sérgio A.M. da Silva, André L. Christoforo
To reduce dependence on wood and deforestation, alternative materials have been considered. This research evaluated particleboards panels of Pinus elliotti mixed with residues of polyethylene terephthalate (PET) in flakes with 50% of each material, glued with 10% of castor oil-based polyurethane resin (PUR). The temperature during board production was varied to evaluate its influence on the physical and mechanical properties of the boards. The study concludes that the increase in temperature did not result in a significant improvement in the particleboard properties, but their results showed application potential according to the normative standards.
为了减少对木材和森林砍伐的依赖,已经考虑了替代材料。本研究评估了将油松刨花板与聚对苯二甲酸乙二醇酯(PET)残留物混合成薄片,每种材料各占50%,并用10%的蓖麻油基聚氨酯树脂(PUR)粘合。通过改变板料生产过程中的温度,评价其对板料物理力学性能的影响。研究认为,温度的升高并没有导致刨花板性能的显著改善,但根据规范标准,其结果显示出应用潜力。
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引用次数: 0
Characteristics of resonance sound in a circular saw enclosure 圆锯箱体内的共振声特性
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-27 DOI: 10.15376/biores.18.4.8473-8483
Ken Takeyama, Hideyuki Yokochi, Satoru Nishio, Satoru Tsuchikaw
Several studies have been conducted to reduce the idling noise of circular saws because the sound level is extremely high and harms the environment. However, conventional noise suppression technology only controls the vibrations of the circular saw itself, whereas idling noise can be generated when the air inside the enclosure is resonant. In this study, the relationship between the rotational speeds of the circular saw blade and the frequencies of the resonance sound when the circular saw blade is running idle in an enclosure was examined. Additionally, the sound pressure modes and frequencies of the air in the enclosure were analyzed using the finite element method of acoustic analysis. The results showed that resonance sound was generated only when the circular saw blade was enclosed. The frequencies of the resonance sound generated by a circular saw blade made of acrylic plastic were the same as those generated by a steel saw blade. The resonance sound was generated regardless of the outer diameter of the circular saw blade. The peak resonant frequencies formed a step-like line during the analysis in which the rotational speed of the saw blade was steadily increased.
由于圆锯空转噪音的声级非常高,对环境有害,因此人们对如何降低圆锯空转噪音进行了一些研究。然而,传统的噪声抑制技术只能控制圆锯本身的振动,而当外壳内的空气发生共振时,会产生空转噪声。本文研究了圆锯片在箱体内空转时,圆锯片转速与共振声频率之间的关系。此外,采用声学分析的有限元方法,对箱体内空气的声压模态和频率进行了分析。结果表明,圆锯片只有在封闭状态下才会产生共振声。由丙烯酸塑料制成的圆锯片产生的共振声音频率与钢锯片产生的共振声音频率相同。无论圆锯片的外径如何,都会产生共振声。在分析过程中,共振频率峰值呈阶梯状,其中锯片转速稳步增加。
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引用次数: 0
Influence of growth ring number and width on elastic constants of poplar 生长环数和宽度对杨树弹性常数的影响
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-10-27 DOI: 10.15376/biores.18.4.8484-8502
Murat Aydın, Tuğba Yılmaz Aydın
The objective of this work was to evaluate the effect of growth ring number (specimens including 2, 4, and 6 rings from the bark) and growth ring width on elastic constants in the radial direction of Populus x canadensis, which has not been revealed before. The longitudinal (2.25 MHz) and transverse (1 MHz) ultrasonic waves were propagated to calculate the longitudinal (VRR) and shear (VRL, VLR, VTR, and VRT) wave velocities and used to determine the elasticity modulus (ER), and shear moduli (GRL and GRT). The average growth ring widths of specimens including 2, 4, and 6 rings were 17.0 mm, 17.8 mm, and 18.2 mm, respectively. According to the results, only VRL steadily increased with increased ring number, while other velocities fluctuated. The same fluctuations were observed for moduli except for GLR, which constantly increased with ring number. The influence of ring number on velocity was statistically significant only for VRL and VRT. However, all moduli were significantly affected by ring number. Linear regression statistics revealed that there were significant relations between the ring width and density, VRL, VLR, VRT, GRL, and GRT.
本研究的目的是评估生长环数(包括树皮的2、4和6个环)和生长环宽度对加拿大杨树径向弹性常数的影响,这是以前没有发现的。传播纵向(2.25 MHz)和横向(1 MHz)超声波,计算纵向(VRR)和剪切(VRL, VLR, VTR和VRT)波速,并用于确定弹性模量(ER)和剪切模量(GRL和GRT)。2、4、6环标本的平均生长环宽度分别为17.0 mm、17.8 mm和18.2 mm。结果表明,随着环数的增加,只有VRL稳定增加,而其他速度都是波动的。除GLR随环数的增加而不断增大外,其余模量均有相同的波动。环数对速度的影响仅在VRL和VRT上有统计学意义。然而,环数对所有模量都有显著影响。线性回归统计显示,环宽与密度、VRL、VLR、VRT、GRL、GRT之间存在显著相关。
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引用次数: 0
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