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Nonequilibrium quantum transport properties of tetragonal zinc chalcogenide monolayers 四方硫系锌单分子层的非平衡量子输运性质
Pub Date : 2023-06-01 DOI: 10.1016/j.mtelec.2023.100041
Yaoyun Zhu , Shuang Meng , Jia Zhou

Tetragonal zinc chalcogenide monolayers (TZCM) are emerging as interesting electronic materials with a direct band gap and relatively high carrier mobility. In this work, we report a theoretical investigation of electronic transport properties and photoelectric response properties of TZCM with gold contacts by density functional theory (DFT) and non-equilibrium Green's function (NEGF) methods. When there is no gate voltage applied, the current increases nonlinearly as bias voltage increases. Among the four proposed devices, the Au(100)/ZnS/Au(100) device has the best electronic transport performance and is most sensitive to the adjustment of bias voltage and gate voltage. The photocurrent calculation results indicate that the low-frequency oscillatory photocurrent of the Au(100)/ZnSe/Au(100) device in the high photon energy region may have potential applications in ultraviolet light-emitting diodes. The Au(100)/Zn2SeS/Au(100) device has more stable photoelectric response and polarization sensitivity than the Au(100)/Zn2SSe/Au(100) device. The Au(100)/TZCM/Au(100) devices exhibit considerable photocurrent and good extinction ratios. This work could pave the way for the future application of TZCM in the field of optoelectronics and so on.

四方硫族化锌单层(TZCM)是一种有趣的电子材料,具有直接的带隙和相对高的载流子迁移率。在这项工作中,我们采用密度泛函理论(DFT)和非平衡格林函数(NEGF)方法对具有金接触的TZCM的电子输运特性和光电响应特性进行了理论研究。当没有施加栅极电压时,电流随着偏置电压的增加而非线性地增加。在提出的四种器件中,Au(100)/ZnS/Au(100)器件具有最好的电子传输性能,并且对偏置电压和栅极电压的调节最敏感。光电流计算结果表明,Au(100)/ZnSe/Au(10 0)器件在高光子能量区的低频振荡光电流可能在紫外线发光二极管中具有潜在的应用。Au(100)/Zn2Se/Au(100)器件比Au(100%)/Zn2SSe/Au(100%)器件具有更稳定的光电响应和偏振灵敏度。Au(100)/TZCM/Au(100)器件表现出相当大的光电流和良好的消光比。这项工作为TZCM在光电子等领域的应用铺平了道路。
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引用次数: 0
Magnetization switching in van der Waals systems by spin-orbit torque 基于自旋轨道转矩的范德华体系磁化开关
Pub Date : 2023-06-01 DOI: 10.1016/j.mtelec.2023.100037
Xin Lin , Lijun Zhu

Electrical switching of magnetization via spin-orbit torque is of great potential in fast, dense, energy-efficient nonvolatile magnetic memory and logic technologies. Recently, enormous efforts have been stimulated to investigate switching of perpendicular magnetization in van der Waals systems that have unique, strong tunability and spin-orbit coupling effect compared to conventional metals. In this review, we first give a brief, generalized introduction to the spin-orbit torque and van der Waals materials. We will then discuss the recent advances in magnetization switching by the spin current generated from van der Waals materials and summary the progress in the switching of van der Waals magnetization by the spin-orbit torque.

通过自旋轨道转矩实现磁化的电气切换在快速、密集、节能的非易失性磁存储器和逻辑技术中具有巨大潜力。最近,人们做出了巨大的努力来研究范德华系统中垂直磁化的切换,与传统金属相比,范德华系统具有独特、强的可调谐性和自旋轨道耦合效应。在这篇综述中,我们首先简要、概括地介绍了自旋轨道力矩和范德华材料。然后,我们将讨论利用范德华材料产生的自旋电流进行磁化切换的最新进展,并总结利用自旋轨道转矩进行范德华磁化切换的进展。
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引用次数: 2
Stable Hybrid Perovskite Materials for Photovoltaics Under Real-World Conditions 实际条件下用于光伏发电的稳定杂化钙钛矿材料
Pub Date : 2023-06-01 DOI: 10.1016/j.mtelec.2023.100038
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引用次数: 1
Cross-shape reconfigurable field effect transistor for flexible signal routing 用于灵活信号路由的十字形状可重构场效应晶体管
Pub Date : 2023-06-01 DOI: 10.1016/j.mtelec.2023.100040
Cigdem Cakirlar , Maik Simon , Giulio Galderisi , Ian O'Connor , Thomas Mikolajick , Jens Trommer

Reconfigurable field effect transistors are one of the most promising emerging device concepts for future computing systems, due to their dynamic p- and n-channel behavior. Over the past decade, there have been significant advances on electrical characteristics and circuit designs, but there are still many additional options to explore. In this letter, a disruptive common-channel reconfigurable filed effect transistor concept is presented experimentally for the first time. A cross-shape integrated nanowire structure is fabricated on a silicon-on-insulator wafer using top-down methods for higher reproducibility. The fabricated cross-shape reconfigurable field effect transistor is composed of a doping-free common channel with four independent silicided source and drain junctions, a silicon dioxide dielectric layer and four independent gates aligned on top of the silicide junctions. By assembling this unique common-channel structure, device level current routing was provided. A detailed comprehensive study of the cross-shape reconfigurable field effect transistor electrical characteristics are presented. The fabricated device demonstrates nearly equal transistor characteristics for each branch, which enables new complementary circuit designs to be introduced. We demonstrated an inverter and a multiplexer circuit both built from the same two transistors with enhanced functionality when compared to a single source configuration.

可重构场效应晶体管由于其动态p沟道和n沟道行为,是未来计算系统中最有前途的新兴器件概念之一。在过去的十年里,在电气特性和电路设计方面取得了重大进展,但仍有许多其他选择需要探索。在这封信中,首次通过实验提出了一种破坏性公共沟道可重构场效应晶体管的概念。使用自上而下的方法在绝缘体上硅晶片上制造十字形集成纳米线结构,以获得更高的再现性。所制造的十字形可重构场效应晶体管由具有四个独立硅化物源极和漏极结的无掺杂公共沟道、二氧化硅介电层和在硅化物结顶部排列的四个独立栅极组成。通过组装这种独特的公共通道结构,提供了器件级电流路由。对十字形可重构场效应晶体管的电学特性进行了详细而全面的研究。所制造的器件显示出每个分支几乎相等的晶体管特性,这使得能够引入新的互补电路设计。我们展示了一个反相器和一个多路复用器电路,这两个电路都是由相同的两个晶体管构建的,与单源配置相比,具有增强的功能。
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引用次数: 1
Tactile perception in hydrogel-based robotic skins using data-driven electrical impedance tomography 基于数据驱动的电阻抗断层扫描的基于水凝胶的机器人皮肤的触觉感知
Pub Date : 2023-06-01 DOI: 10.1016/j.mtelec.2023.100032
David Hardman , Thomas George Thuruthel , Fumiya Iida

Combining functional soft materials with electrical impedance tomography is a promising method for developing continuum sensorized soft robotic skins with high resolutions. However, reconstructing the tactile stimuli from surface electrode measurements is a challenging ill-posed modelling problem, with FEM and analytic models facing a reality gap. To counter this, we propose and demonstrate a model-free superposition method which uses small amounts of real-world data to develop deformation maps of a soft robotic skin made from a self-healing ionically conductive hydrogel, the properties of which are affected by temperature, humidity, and damage. We demonstrate how this method outperforms a traditional neural network for small datasets, obtaining an average resolution of 12.1 mm over a 170 mm circular skin. Additionally, we explore how this resolution varies over a series of 15,000 consecutive presses, during which damages are continuously propagated. Finally, we demonstrate applications for functional robotic skins: damage detection/localization, environmental monitoring, and multi-touch recognition - all using the same sensing material.

将功能性软材料与电阻抗断层扫描相结合是开发高分辨率连续传感软机器人皮肤的一种很有前途的方法。然而,从表面电极测量重建触觉刺激是一个具有挑战性的不适定建模问题,FEM和分析模型面临着现实差距。为了应对这种情况,我们提出并演示了一种无模型叠加方法,该方法使用少量真实世界数据来开发由自修复离子导电水凝胶制成的柔软机器人皮肤的变形图,其特性受温度、湿度和损伤的影响。我们展示了这种方法如何在小数据集上优于传统的神经网络,获得12.1的平均分辨率 170以上mm mm圆形表皮。此外,我们还探讨了在连续15000次冲压过程中,这种分辨率是如何变化的,在这一过程中,损伤会不断传播。最后,我们展示了功能性机器人皮肤的应用:损伤检测/定位、环境监测和多点触摸识别——所有这些都使用相同的传感材料。
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引用次数: 2
Investigation of deep defects and their effects on the properties of NiO/β-Ga2O3 heterojuncion diodes NiO/β-Ga2O3异质结二极管深度缺陷及其性能影响研究
Pub Date : 2023-06-01 DOI: 10.1016/j.mtelec.2023.100042
Abdulaziz Almalki , Labed Madani , Nouredine Sengouga , Sultan Alhassan , Saud Alotaibi , Amra Alhassni , Amjad Almunyif , Jasbinder S. Chauhan , Mohamed Henini , Helder Vinicius Avanço Galeti , Yara Galvão Gobato , Marcio Peron Franco de Godoy , Marcelo B. Andrade , Sérgio Souto , Hong Zhou , Boyan Wang , Ming Xiao , Yuan Qin , Yuhao Zhang

In this study, the effect of rapid thermal annealing (RTA) on the electrical and optical properties of NiO/ β-Ga2O3 heterojunction diodes was investigated using capacitance-voltage, current-voltage, Deep Level Transient Spectroscopy (DLTS), Laplace DLTS, photoluminescence and micro-Raman spectroscopy techniques, and SILVACO-TCAD numerical simulator. The NiO is designed to be lowly-doped, allowing for the NiO full depletion at zero bias and the study of properties of β-Ga2O3 and its interface with NiO. Micro-Raman results revealed good agreement with the theoretical and experimental results reported in the literature. The photoluminescence intensity of the sample after RTA is five times higher than the fresh sample due to a rise in the density of gallium and oxygen vacancies (VGa + VO) in the annealed β-Ga2O3 samples. The current-voltage characteristics showed that annealed devices exhibited a lower ideality factor at room temperature and higher barrier height compared with fresh samples. The DLTS measurements demonstrated that the number of electrically active traps were different for the two samples. In particular, three and one electron traps were detected in fresh samples and annealed samples, respectively. SILVACO-TCAD was used to understand the distribution of the detected electron E2 trap (Ec-0.15 eV) in the fresh sample and the dominant transport mechanisms. A fairly good agreement between simulation and measurements was achieved considering a surface NiO acceptor density of about 1 × 1019 cm−3 and E2 trap depth into the surface of β-Ga2O3 layer of about 0.220 µm and the effect of the most observed Ec-0.75 eV trap level in β-Ga2O3. These results unveil comprehensive physics in NiO/β-Ga2O3heterojunction and suggest that RTA is an essential process for realizing high-performance NiO/β-Ga2O3devices.

在本研究中,利用电容电压、电流电压、深能级瞬态光谱(DLTS)、拉普拉斯DLTS、光致发光和微拉曼光谱技术以及SILVACO-TCD数值模拟,研究了快速热退火(RTA)对NiO/β-Ga2O3异质结二极管电学和光学性能的影响。NiO被设计为低掺杂,允许在零偏压下完全耗尽NiO,并研究β-Ga2O3及其与NiO的界面的性质。显微拉曼光谱结果与文献报道的理论和实验结果吻合良好。RTA后样品的光致发光强度是新鲜样品的五倍,这是由于退火的β-Ga2O3样品中镓和氧空位(VGa+VO)密度的增加。电流-电压特性表明,与新鲜样品相比,退火器件在室温下表现出较低的理想因子和较高的势垒高度。DLTS测量表明,两个样品的电活性陷阱的数量不同。特别是,在新鲜样品和退火样品中分别检测到三个和一个电子陷阱。SILVACO-TCD用于了解新鲜样品中检测到的电子E2陷阱(Ec-0.15eV)的分布和主要的传输机制。考虑到表面NiO受体密度约为1×1019 cm−3,进入β-Ga2O3层表面的E2陷阱深度约为0.220µm,以及β-Ga22O3中观察到的最大Ec-0.75 eV陷阱能级的影响,模拟和测量之间取得了相当好的一致性。这些结果揭示了NiO/β-Ga2O3异质结的综合物理性质,并表明RTA是实现高性能NiO/。
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引用次数: 0
From fundamentals to applications: The development of magnetoplasmonics for next-generation technologies 从基础到应用:下一代磁等离子体学技术的发展
Pub Date : 2023-06-01 DOI: 10.1016/j.mtelec.2023.100033
Rahulkumar Sunil Singh, Prashant K Sarswat

Magnetoplasmonics is an emerging interdisciplinary field that studies the interaction between magnetism and plasmonics, and has great promise for the development of novel optical, magnetic, and spintronic devices. The goal of this review is to provide a comprehensive overview of the current state-of-the-art in magnetoplasmonics, including the fundamentals, materials, and applications. The review first presents an introduction to the basic concepts of magnetoplasmonics, magneto-optical and plasmonic materials, and the various ways in which they can be combined to create novel hybrid systems. The review then examines the influence of surface plasmon resonances on the magneto-optical properties of a system as well as the achievement of balance of magneto-optical and surface plasmon properties to maximize the overall magnetoplasmonic properties. Selected major applications in biomedicine, biomedical technologies, optoelectronics and telecommunications are then discussed. Finally, it concludes with key challenges in the use of magnetoplasmonics in these applications, the need for new materials, new fabrication approaches, and further understanding to control the complex interactions between magnetism and plasmonics.

磁等离子体是一个新兴的跨学科领域,研究磁性和等离子体之间的相互作用,对开发新型光学、磁性和自旋电子器件有很大的前景。这篇综述的目的是全面概述磁等离子体的最新技术,包括基本原理、材料和应用。这篇综述首先介绍了磁等离子体、磁光和等离子体材料的基本概念,以及将它们结合起来创建新型混合系统的各种方式。然后,该综述考察了表面等离子体共振对系统磁光性质的影响,以及实现磁光和表面等离子体性质的平衡,以最大限度地提高整体磁等离子体性质。然后讨论了生物医学、生物医学技术、光电子和电信领域的一些主要应用。最后,它总结了在这些应用中使用磁等离子体的关键挑战,对新材料的需求,新的制造方法,以及对控制磁性和等离子体之间复杂相互作用的进一步理解。
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引用次数: 2
Bistable Resistive Memory Switches fabricated by Floating Thin Films of Conjugated Polymers 用共轭聚合物漂浮薄膜制备双稳态电阻式记忆开关
Pub Date : 2023-06-01 DOI: 10.1016/j.mtelec.2023.100043
Shubham Sharma , Nikita Kumari , Shuichi Nagamatsu , Masakazu Nakamura , Shyam S. Pandey

The layer-by-layer (LBL) fabrication of conjugated polymer (CPs) thin films while preserving their microstructural features by solution processing is highly desired for compact and flexible electronic circuits. However, it is cumbersome and challenging owing to the unavoidable damage to the underlying layers. To circumvent this issue, the unidirectional floating-film transfer method (UFTM) was utilized for the LBL fabrication of oriented CP thin films on the orthogonal liquid surfaces. Further, resistive bistable memory switches were fabricated by sandwiching a layer of metal nanostructures between the LBL-fabricated oriented CP thin films. The resistive switching phenomena were realized by utilizing the applied bias-dependent charge trapping, holding, and recombination on the available states at vacuum-deposited aluminum nanostructures. The effect of CP backbone conformation on the vertical charge transport was also analyzed via a comparative study of three thiophene-based polymers namely RR-P3HT, PBTTT, and PTB-7. It was revealed that CPs with relatively fewer hydrophobic side chains was more favorable for the facile vertical charge transport due to its preferred face-on conformation on the hydrophilic liquid substrate used in UFTM. It was demonstrated that a non-volatile bistable resistive memory switch fabricated using UFTM-processed oriented thin films of PTB-7 exhibited a remarkably high on-off ratio of 1.5 × 106 with high durability.

共轭聚合物(CP)薄膜的逐层(LBL)制造同时通过溶液处理保持其微观结构特征是紧凑和柔性电子电路非常需要的。然而,由于对底层不可避免的损坏,这是一种麻烦和挑战。为了解决这个问题,采用单向浮膜转移法(UFTM)在正交液体表面上LBL制备定向CP薄膜。此外,通过将金属纳米结构层夹在LBL制造的定向CP薄膜之间来制造电阻双稳态存储器开关。电阻开关现象是通过利用在真空沉积铝纳米结构的可用状态上施加的依赖于偏压的电荷捕获、保持和复合来实现的。通过对三种噻吩基聚合物RR-P3HT、PBTTT和PTB-7的比较研究,还分析了CP骨架构象对垂直电荷传输的影响。结果表明,具有相对较少疏水侧链的CPs由于其在UFTM中使用的亲水性液体基质上的优选面上构象而更利于容易的垂直电荷传输。结果表明,采用UFTM工艺制备的PTB-7取向薄膜制备的非易失性双稳态电阻存储开关具有1.5×106的高通断比和高耐久性。
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引用次数: 0
Neural network approach for ferroelectric hafnium oxide phase identification at the atomistic scale 原子尺度下铁电性氧化铪相识别的神经网络方法
Pub Date : 2023-05-01 DOI: 10.1016/j.mtelec.2023.100027
Zhiheng Cheng, Xingran Xie, Yimin Yang, Chaolun Wang, Chen Luo, Hengchang Bi, Yan Wang, Junhao Chu, Xing Wu

The hafnia-based ferroelectric oxides with excellent negative-capacitance properties offer a great opportunity to develop high-performance integrated circuits. The nanosized multiphase distribution of Hf0.5Zr0.5O2 (HZO) has a significant influence on its ferroelectric properties. Transmission electron microscope (TEM) with an atomistic resolution could establish the structure-property relationship and guide the performance improvement of HZO by identifying its phase structures. However, the high throughput TEM data and its complexity of interpretation make the quantitatively extracting the physical and chemical information from the TEM images challenging and low-efficiency. Here, we develop an automatic work flow for the TEM data analysis, which greatly enhances the efficiency of TEM data processing. By extracting the interest area and training the neural network with ResNet18, the accuracy of phase determination reaches 95.82% with low computational cost. Theoretical analysis is conducted to unveil the advantages of the ResNet18 network. The approach provided in this work could promote the quantitative analysis of the high-throughput TEM images and pave the way for future on-line analysis of the TEM image stream in real-time.

具有优良负电容性能的铁电氧化物为高性能集成电路的开发提供了良好的契机。Hf0.5Zr0.5O2 (HZO)的纳米多相分布对其铁电性能有显著影响。原子分辨率的透射电子显微镜(TEM)可以通过识别HZO的相结构,建立HZO的结构-性能关系,指导其性能的提高。然而,TEM数据的高通量和解释的复杂性使得从TEM图像中定量提取物化信息具有挑战性和低效率。在此,我们开发了一个TEM数据分析的自动化工作流程,大大提高了TEM数据处理的效率。通过提取感兴趣区域并使用ResNet18对神经网络进行训练,相位确定准确率达到95.82%,计算成本低。通过理论分析,揭示了ResNet18网络的优势。该方法可促进高通量TEM图像的定量分析,为今后TEM图像流的实时在线分析奠定基础。
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引用次数: 1
The structural, optical and electrical properties of sodium titanate nanotubes sensitized with nitrogen/sulfur co-doped graphene quantum dots as potential materials for quantum dots sensitized solar cells 氮/硫共掺杂石墨烯量子点敏化钛酸钠纳米管的结构、光学和电学性能作为量子点敏化太阳能电池的潜在材料
Pub Date : 2023-05-01 DOI: 10.1016/j.mtelec.2023.100029
Martin Esteves , Dominique Mombrú , Mariano Romero , Luciana Fernández-Werner , Ricardo Faccio , Alvaro W. Mombrú

In this work, we present the synthesis of nanoscale heterostructures of sodium titanate nanotubes Na2Ti2O5.H2O (NaNT) decorated with N- and S- co-doped graphene quantum dots (NS-GQD) for quantum dots sensitized solar cells (QDSSC). The study was mainly focused on the structural, microstructural, electrical and optical characterization of these nanoscale heterostructures by means of X ray diffraction, transmission electron microscopy, atomic force microscopy, Raman, UV–vis and impedance spectroscopies. Our nanoscale heterostructures yielded a significant enhancement in the electric conductivity interpreted in terms of favorable interactions between the NS-GQD and the NaNT acting as proper connectors. Finally, our QDSSC prototype exhibits promising values for diffusion coefficient and recombination times as evidenced by means of impedance modulated photocurrent and photovoltage spectroscopies. Also, we consider that these materials could be further explored for electron transport layers applications in order to exploit the advantages regarding electron transport properties.

本文介绍了钛酸钠纳米管Na2Ti2O5的纳米异质结构的合成。用N-和S-共掺杂石墨烯量子点(NS-GQD)修饰H2O (NaNT)用于量子点敏化太阳能电池(QDSSC)。通过X射线衍射、透射电子显微镜、原子力显微镜、拉曼光谱、紫外可见光谱和阻抗光谱等手段对这些纳米异质结构进行了结构、微观结构、电学和光学表征。我们的纳米异质结构在电导率方面产生了显著的增强,这可以解释为NS-GQD和NaNT之间作为适当连接器的有利相互作用。最后,通过阻抗调制光电流和光电压谱,我们的QDSSC原型在扩散系数和复合次数方面表现出了很好的价值。此外,我们认为这些材料可以进一步探索电子传输层的应用,以利用其在电子传输特性方面的优势。
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引用次数: 2
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Materials Today Electronics
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