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Synthesis, characterizations and technological prospects of nickel tellurides: a review 碲化镍的合成、表征及技术展望
Pub Date : 2026-01-07 DOI: 10.1016/j.nwnano.2026.100180
Deevanshi Bhatt, Naeem Mohammad, Pawan K. Khanna
Nickel tellurides is one of the representative materials amongst transition metal chalcogenides and is generally recognized for its structural, electronic features, and multifunctional behaviour that suits the requirement of a wide spectrum of modern applications. Progress in synthetic strategies over the last two decades has allowed precise control on morphology and stoichiometry, enabling the development of i.e., nanoparticles, nanosheets, nanorods and thin films with thickness in nanometres. A variety of fabrication techniques-including hydrothermal/solvothermal methods, chemical vapor deposition, electrodeposition, and ion-exchange processes-have been extensively applied to obtain nickel telluride with tailored properties. To understand structural, electronic, and physico-chemical characteristics, researchers has opted for characterization of nickel telluride(s) by various spectroscopic and electro-analytical techniques such as X-ray analysis, Raman spectroscopy, transmission electron microscopy. Due to their excellent electrical conductivity (950 mSm−1), thermal conductivity (2.5 Wm−1K−1) intrinsic chemical robustness, and catalytic efficiency, nickel tellurides have demonstrated potential across multiple domains. Nevertheless, challenges such as phase purity (hexagonal and trigonal), stability of their shape and size vis-a-vis commercial viability still hinder their widespread utility. This review integrates recent findings to provide an overview of the synthesis approaches, structural and functional characterizations, and state-of-the-art technological applications of nickel tellurides.
碲化镍是过渡金属硫族化合物中的代表性材料之一,因其结构、电子特性和多功能特性而受到普遍认可,适合广泛的现代应用要求。在过去的二十年里,合成策略的进步使得对形态和化学计量学的精确控制成为可能,从而开发出纳米颗粒、纳米片、纳米棒和纳米厚度的薄膜。各种制备技术——包括水热/溶剂热法、化学气相沉积、电沉积和离子交换工艺——已被广泛应用于获得具有定制性能的碲化镍。为了了解结构、电子和物理化学特性,研究人员选择了通过各种光谱和电分析技术(如x射线分析、拉曼光谱、透射电子显微镜)来表征碲化镍。由于其优异的导电性(950 mSm−1),导热性(2.5 Wm−1K−1),固有的化学稳健性和催化效率,碲化镍在多个领域都显示出潜力。然而,诸如相纯度(六边形和三角形)、形状和尺寸相对于商业可行性的稳定性等挑战仍然阻碍了它们的广泛应用。本文综述了碲化镍的合成方法、结构和功能表征以及最新技术应用。
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引用次数: 0
Self-powered sensors and wearables: Energy harvesting with nanomaterials for the IoT era 自供电传感器和可穿戴设备:物联网时代的纳米材料能量收集
Pub Date : 2026-01-03 DOI: 10.1016/j.nwnano.2026.100179
Kanaka Durga Devi Nelluri , Manne Anupama Ammulu , Bhavana Alaparthi , Minakshi Kommoju , Padamata Sai Rohith , Anil Kumar Kakani , Vaishnavi Grandhi
The rise in the application of autonomous sensors and wearable technology is transforming modern life by offering real-time monitoring around the clock, irrespective of the presence of external power sources. Nanomaterials are at the center of driving this transformation by enabling the creation of light, portable, and efficient energy harvesting devices from ambient sources such as mechanical movement, body heat, and sunlight. Triboelectric, piezoelectric, thermoelectric, and photovoltaic nanogenerators are at the forefront of providing scalable alternatives for wearable sensing and IoT applications. These are increasingly being integrated with multifunctional sensors to enable battery-free, seamless sensing in remote, on-body, or hostile environments. The development of nanomaterials including, nanowires, quantum dots, and 2D materials, has enhanced energy conversion efficiency, flexibility, and device integration while also offering desirable properties such as biocompatibility and transparency, which are beneficial for health monitoring and biosensing applications. Long-term reliability, efficient energy storage integration, and mass fabrication remain challenging. To enhance these, multimodal hybrid energy harvesting systems are being produced with the integration of multiple mechanisms to enhance sustained performance and reliability across varying environmental conditions. These technologies are being deployed in smart healthcare, fitness monitoring, environmental sensing, and industrial diagnostics. Interdisciplinary collaboration between materials science, electronics, and analytics is paving the way for innovation and adoption. As growth in the IoT ecosystem continues to grow, the demand for sustainable, self-sustaining technologies will also rise, and nanomaterial-based energy harvesting will prove to be a key enabler for miniaturized, smart, and autonomous sensing platforms that will drive the vision of pervasive computing and wearable intelligence.
自主传感器和可穿戴技术应用的兴起正在改变现代生活,无论外部电源是否存在,它们都可以提供全天候的实时监控。纳米材料是推动这一转变的核心,它使人们能够从机械运动、人体热量和阳光等环境源中创造出轻便、高效的能量收集设备。摩擦电、压电、热电和光伏纳米发电机在为可穿戴传感和物联网应用提供可扩展替代品方面处于领先地位。这些传感器越来越多地与多功能传感器集成在一起,从而在远程、身体或恶劣环境中实现无电池、无缝传感。纳米材料的发展,包括纳米线、量子点和二维材料,提高了能量转换效率、灵活性和设备集成,同时也提供了理想的特性,如生物相容性和透明度,这有利于健康监测和生物传感应用。长期可靠性、高效储能集成和大规模制造仍然具有挑战性。为了提高这些性能,正在生产多模式混合能量收集系统,该系统集成了多种机制,以提高在不同环境条件下的持续性能和可靠性。这些技术被部署在智能医疗保健、健身监测、环境传感和工业诊断中。材料科学、电子学和分析学之间的跨学科合作为创新和采用铺平了道路。随着物联网生态系统的持续增长,对可持续、自我维持技术的需求也将上升,基于纳米材料的能量收集将被证明是小型化、智能和自主传感平台的关键推动者,这些平台将推动普及计算和可穿戴智能的愿景。
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引用次数: 0
Intelligent micro- and nano-robots for next-generation photobiomodulation and adaptive photomedicine 用于下一代光生物调节和自适应光医学的智能微纳米机器人
Pub Date : 2025-12-21 DOI: 10.1016/j.nwnano.2025.100177
Hossein Chamkouri
Photobiomodulation (PBM) devices have emerged as powerful non-invasive tools that utilize specific light wavelengths to modulate cellular functions, enhance tissue repair, and restore physiological homeostasis. To the best of our knowledge, most current PBM research and device development focus primarily on light emitting diode (LED) or micro-LED systems, emphasizing light delivery rather than intelligent and dynamic control at the nanoscale. Here, we propose the potential of micro- and nano-robots as transformative platforms for the next generation of photomedicine and PBM. In this review, we discuss their advanced fabrication strategies, including photolithography, self-assembly, and biohybrid integration, enabling precise motion control and targeted navigation within biological environments. We highlight how these micro/nano-robots could overcome critical physiological barriers, such as the blood–brain barrier (BBB), through active propulsion and selective permeability mechanisms. The integration of photonic systems into micro-and nanodevices enable these robots to achieve autonomous decision-making, adaptive illumination, and spatiotemporal control of light–cell interactions. This convergence represents a paradigm shift with significant potential to revolutionize the future of photomedicine, offering precise, personalized, and intelligent therapeutic interventions at cellular and subcellular levels.
光生物调节(PBM)装置已经成为一种强大的非侵入性工具,它利用特定的光波长来调节细胞功能,增强组织修复,恢复生理稳态。据我们所知,目前大多数PBM研究和设备开发主要集中在发光二极管(LED)或微型LED系统上,强调光传输而不是纳米级的智能和动态控制。在这里,我们提出了微型和纳米机器人作为下一代光医学和PBM的变革平台的潜力。在这篇综述中,我们讨论了他们的先进制造策略,包括光刻,自组装和生物混合集成,实现精确的运动控制和目标导航在生物环境中。我们强调了这些微/纳米机器人如何通过主动推进和选择性渗透机制克服关键的生理屏障,如血脑屏障(BBB)。将光子系统集成到微纳米器件中,使这些机器人能够实现自主决策、自适应照明和光电池相互作用的时空控制。这种融合代表了一种范式的转变,具有革新光医学未来的巨大潜力,在细胞和亚细胞水平上提供精确、个性化和智能的治疗干预。
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引用次数: 0
Measurement of charge carrier mobilities in thin films via the space-charge limited current (SCLC) method; A practical example 空间电荷限制电流法测量薄膜中载流子迁移率一个实际的例子
Pub Date : 2025-12-20 DOI: 10.1016/j.nwnano.2025.100178
Marzieh Rabiei , Sohrab Nasiri , Juozas Padgurskas , Raimundas Rukuiza
Study of space charge limited current (SCLC) transport in charge carrier injection is presented. It is shown that the accurate and convenient calculation of carrier mobility, which has been neglected in many previous studies on transport in optical and electrical devices, is essential to obtain physically meaningful spatial carrier densities and field distributions. In this work, the SCLC technique to accurately determine the mobility of holes and electrons in organic semiconductors is investigated in detail. Recognizing the importance of balanced charge transport to the performance of optical and electronic devices, the fundamentals of SCLC, including Mott-Gurney's law, are discussed and its advantages over alternative methods are highlighted. A carbazole-based compound is used as a practical example, with single-carrier devices fabricated to selectively measure hole-only and electron-only transport. The current-voltage characteristics were analysed in the trap-free SCLC regime (slope ≈ 2 in log-log plots), and yielded mobilities of μe =4.02 × 10−5 cm2V-1s-1 and μh = 1.84 × 10–3 cm2V-1s-1. This study not only demonstrates a clear and reproducible method for mobility extraction, but also highlights the importance of SCLC measurements under device-like conditions for material selection and performance optimization in optoelectronic applications.
研究了载流子注入过程中空间电荷限流输运问题。研究表明,准确、方便地计算载流子迁移率对于获得物理上有意义的空间载流子密度和场分布是至关重要的,而在以往许多光学和电子器件的输运研究中,载流子迁移率一直被忽视。本文详细研究了利用SCLC技术精确测定有机半导体中空穴和电子迁移率的方法。认识到平衡电荷输运对光学和电子器件性能的重要性,讨论了SCLC的基本原理,包括莫特-格尼定律,并强调了其相对于其他方法的优势。以咔唑类化合物为例,制备了单载流子器件来选择性地测量空穴和电子输运。在无陷阱的SCLC模式下(对数-对数图斜率≈2)分析了电流-电压特性,得到迁移率μe =4.02 × 10−5 cm2V-1s-1和μh = 1.84 × 10 - 3 cm2V-1s-1。该研究不仅展示了一种清晰、可重复的迁移率提取方法,而且强调了在类似器件的条件下进行SCLC测量对光电应用中材料选择和性能优化的重要性。
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引用次数: 0
Alginate embedded 1-D nanocomposite for environmental remediation: AI modeling, kinetics and thermodynamics 海藻酸盐嵌入一维纳米复合材料用于环境修复:人工智能建模,动力学和热力学
Pub Date : 2025-12-18 DOI: 10.1016/j.nwnano.2025.100175
Monika Dubey , Ashish Kumar Singh , Vandana Saxena
Manganese oxide (α-MnO2) molecular sieves exhibiting promising oxidative capabilities have been embedded into novel alginate (AG) beads. AG (a biopolymer matrix) is known for its effective and practical support adsorber. α-MnO2 nanorods embedded AG beads (100 mg/g) demonstrated complete catalytic removal of 2,4 dichlorophenol (2,4-DCP) within 30 min at ambient temperature. Further, α-MnO2 was thoroughly characterized via SEM and XRD. α-MnO2 has one-dimensional nanorod structure of 200±30 nm (length) x 20±10 nm (diameter) with a high surface-to-volume ratio suitable for catalytic applications. The point-of-zero-charge of the α-MnO2 embedded alginate beads was determined as pHpzc ≈ 6.8, indicating near-neutral surface charge and explaining the observed optimum removal at pH ≈ 7. The adsorption kinetics were investigated using Pseudo first order and well fitted Runge-Kutta mathematical modeling (for R2=0.99). The thermodynamic behavior has been studied via Arrhenius plot based on different temperature experiments. The activation energy (Ea) calculated from the Arrhenius plot was 34.7 kJ mol⁻¹, confirming the endothermic nature of the degradation process. Additionally, machine learning (ML) assisted Adaptive Neuro Fuzzy Interference System (ANFIS) logics were applied to a dataset of 380 experimental points to predict adsorption process accurately along with effects of pH, concentration, catalyst amount, reaction time and effect of temperature. Overall, this study opens a pathway of effective artificial intelligence (AI) and mathematical modeling collaboration to scale up environmental remediation.
氧化锰(α-MnO2)分子筛具有良好的氧化性能,被嵌入到新型海藻酸盐(AG)微球中。AG(一种生物聚合物基质)以其有效和实用的载体吸附剂而闻名。α-MnO2纳米棒包埋银珠(100 mg/g),在室温下30 min内完全催化去除2,4-二氯苯酚(2,4- dcp)。通过SEM和XRD对α-MnO2进行了表征。α-MnO2具有200±30 nm(长)× 20±10 nm(直径)的一维纳米棒结构,具有较高的表面体积比,适合于催化应用。α-MnO2包埋藻酸珠的零电荷点为pHpzc≈6.8,表明其表面电荷接近中性,并解释了pH≈7时所观察到的最佳去除效果。采用拟一阶拟合的龙格-库塔数学模型(R2=0.99)研究了吸附动力学。利用阿伦尼乌斯图研究了不同温度下的热力学行为。根据阿伦尼乌斯图计算出的活化能(Ea)为34.7 kJ mol(⁻¹),证实了降解过程的吸热性质。利用机器学习(ML)辅助的自适应神经模糊干扰系统(ANFIS)逻辑对380个实验点的数据集进行预测,准确预测了pH、浓度、催化剂用量、反应时间和温度对吸附过程的影响。总的来说,本研究开辟了一条有效的人工智能(AI)和数学建模协同扩大环境修复的途径。
{"title":"Alginate embedded 1-D nanocomposite for environmental remediation: AI modeling, kinetics and thermodynamics","authors":"Monika Dubey ,&nbsp;Ashish Kumar Singh ,&nbsp;Vandana Saxena","doi":"10.1016/j.nwnano.2025.100175","DOIUrl":"10.1016/j.nwnano.2025.100175","url":null,"abstract":"<div><div>Manganese oxide (α-MnO<sub>2</sub>) molecular sieves exhibiting promising oxidative capabilities have been embedded into novel alginate (AG) beads. AG (a biopolymer matrix) is known for its effective and practical support adsorber. α-MnO<sub>2</sub> nanorods embedded AG beads (100 mg/g) demonstrated complete catalytic removal of 2,4 dichlorophenol (2,4-DCP) within 30 min at ambient temperature. Further, α-MnO<sub>2</sub> was thoroughly characterized via SEM and XRD. α-MnO<sub>2</sub> has one-dimensional nanorod structure of 200±30 nm (length) x 20±10 nm (diameter) with a high surface-to-volume ratio suitable for catalytic applications. The point-of-zero-charge of the α-MnO<sub>2</sub> embedded alginate beads was determined as pH<sub>pzc</sub> ≈ 6.8, indicating near-neutral surface charge and explaining the observed optimum removal at pH ≈ 7. The adsorption kinetics were investigated using Pseudo first order and well fitted Runge-Kutta mathematical modeling (for R<sup>2</sup>=0.99). The thermodynamic behavior has been studied via Arrhenius plot based on different temperature experiments. The activation energy (E<sub>a</sub>) calculated from the Arrhenius plot was 34.7 kJ mol⁻¹, confirming the endothermic nature of the degradation process. Additionally, machine learning (ML) assisted Adaptive Neuro Fuzzy Interference System (ANFIS) logics were applied to a dataset of 380 experimental points to predict adsorption process accurately along with effects of pH, concentration, catalyst amount, reaction time and effect of temperature. Overall, this study opens a pathway of effective artificial intelligence (AI) and mathematical modeling collaboration to scale up environmental remediation.</div></div>","PeriodicalId":100942,"journal":{"name":"Nano Trends","volume":"13 ","pages":"Article 100175"},"PeriodicalIF":0.0,"publicationDate":"2025-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145926623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of montmorillonite/Cu-Cd-Al layered triple oxide (MMT/Cu-Cd-Al-LTO) nanocomposite for a highly efficient removal of organic pollutant from aqueous solution for wastewater treatment 蒙脱土/Cu-Cd-Al层状三氧化物(MMT/Cu-Cd-Al- lto)纳米复合材料的合成及其在废水处理中的应用
Pub Date : 2025-12-17 DOI: 10.1016/j.nwnano.2025.100176
Angita Sarkar , Deba Raj Basumatary , Bipul Das , Samuel Lalthazuala Rokhum , Sanjay Basumatary
Industrial activities release large volumes of wastewater containing various dye compounds, posing a major environmental hazard that threatens ecosystems and human health. To address this issue, the current work seeks to boost the adsorption efficiency of Montmorillonite (MMT) through its modification by integrating Cu-Cd-Al-layered triple oxide (Cu-Cd-Al-LTO) in the clay matrix for the purpose of eliminating Malachite Green (MG) dye. The modified materials were examined using methods viz. HRTEM, FT-IR, FESEM, and PXRD. This study thoroughly investigates the influence of various parameters of adsorption. The study produced the best results when the adsorbent dose (0.4 g/L), initial dye concentration (180 mg/L), agitation time (180 min), temperature (40 °C), and dye's natural pH were all optimized. The findings indicate that newly synthesised MMT/Cu-Cd-Al-LTO nanocomposite is effective in removing MG dye from wastewater, achieving an impressive maximum monolayer adsorption capacity of 1174 mg/g. The Langmuir model of isotherm and kinetic model of PSO provided optimal fit for the adsorption studies. The negative ΔGo value indicates a spontaneous adsorption process as per thermodynamics study. Additionally, reusability of the nanocomposite up to 4th cycle with 66.3 ± 0.27 % capacity retention, makes it a cost-effective choice in the field of adsorption.
工业活动释放大量含有各种染料化合物的废水,构成威胁生态系统和人类健康的重大环境危害。为了解决这一问题,目前的工作旨在通过将cu - cd - al层状三氧化物(Cu-Cd-Al-LTO)整合到粘土基体中来提高蒙脱土(MMT)的吸附效率,以去除孔雀石绿(MG)染料。采用HRTEM、FT-IR、FESEM和PXRD等方法对改性后的材料进行了表征。本研究深入探讨了各种吸附参数对吸附性能的影响。当吸附剂用量(0.4 g/L)、染料初始浓度(180 mg/L)、搅拌时间(180 min)、温度(40℃)、染料自然pH值均为最佳。结果表明,新合成的MMT/Cu-Cd-Al-LTO纳米复合材料可有效去除废水中的MG染料,其最大单层吸附容量为1174 MG /g。等温线Langmuir模型和PSO的动力学模型最适合于吸附研究。负ΔGo值表示根据热力学研究自发吸附过程。此外,纳米复合材料的可重复使用性高达4次循环,容量保留率为66.3±0.27%,使其成为吸附领域的经济高效选择。
{"title":"Synthesis of montmorillonite/Cu-Cd-Al layered triple oxide (MMT/Cu-Cd-Al-LTO) nanocomposite for a highly efficient removal of organic pollutant from aqueous solution for wastewater treatment","authors":"Angita Sarkar ,&nbsp;Deba Raj Basumatary ,&nbsp;Bipul Das ,&nbsp;Samuel Lalthazuala Rokhum ,&nbsp;Sanjay Basumatary","doi":"10.1016/j.nwnano.2025.100176","DOIUrl":"10.1016/j.nwnano.2025.100176","url":null,"abstract":"<div><div>Industrial activities release large volumes of wastewater containing various dye compounds, posing a major environmental hazard that threatens ecosystems and human health. To address this issue, the current work seeks to boost the adsorption efficiency of Montmorillonite (MMT) through its modification by integrating Cu-Cd-Al-layered triple oxide (Cu-Cd-Al-LTO) in the clay matrix for the purpose of eliminating Malachite Green (MG) dye. The modified materials were examined using methods viz. HRTEM, FT-IR, FESEM, and PXRD. This study thoroughly investigates the influence of various parameters of adsorption. The study produced the best results when the adsorbent dose (0.4 g/L), initial dye concentration (180 mg/L), agitation time (180 min), temperature (40 °C), and dye's natural pH were all optimized. The findings indicate that newly synthesised MMT/Cu-Cd-Al-LTO nanocomposite is effective in removing MG dye from wastewater, achieving an impressive maximum monolayer adsorption capacity of 1174 mg/g. The Langmuir model of isotherm and kinetic model of PSO provided optimal fit for the adsorption studies. The negative ΔG<sup>o</sup> value indicates a spontaneous adsorption process as per thermodynamics study. Additionally, reusability of the nanocomposite up to 4<sup>th</sup> cycle with 66.3 ± 0.27 % capacity retention, makes it a cost-effective choice in the field of adsorption.</div></div>","PeriodicalId":100942,"journal":{"name":"Nano Trends","volume":"13 ","pages":"Article 100176"},"PeriodicalIF":0.0,"publicationDate":"2025-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145926621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design and analysis of RbBeBr3−xIx (x=0–3) lead-free perovskites: Tunable mechanical and optoelectronic properties via iodine substitution RbBeBr3−xIx (x= 0-3)无铅钙钛矿的设计与分析:通过碘取代可调节机械和光电性能
Pub Date : 2025-12-10 DOI: 10.1016/j.nwnano.2025.100172
Ismail Benaicha , Imane Laazizi , Youness Ait Alla , Jaouad Mhalla , Hafsa Diyagh , Khalid Nouneh , Smail Amraoui , Atika Fahmi , Marouan Karam , Ahmed Qachaou , Mounir Fahoume
This study presents a first-principles analysis of the structural, mechanical, and optoelectronic properties of the lead-free perovskite series RbBeBr3xIx (x=0, 1, 2, 3) using density functional theory. We investigate the trade-offs between property tuning and stability. While all compositions satisfy the Goldschmidt tolerance factor, formation energy calculations reveal that the mixed-halide phases (x=1,2) are thermodynamically unstable relative to the pure-halide end members (RbBeBr3 and RbBeI3). Mechanical analysis confirms the stability of RbBeBr3, RbBeBr1I2, and RbBeI3, but crucially identifies RbBeBr2I1 as elastically unstable, evidenced by a negative elastic eigenvalue of 1.7171 GPa. Progressive iodine substitution induces systematic lattice softening, reducing the Hill-averaged Young’s modulus from 26.6 GPa (x=0) to 19.7 GPa (x=3). Optoelectronically, iodine substitution effectively tunes the bandgap from 2.106 eV (indirect) for RbBeBr3 to 0.495 eV (direct) for RbBeI3. This is driven by the I-5p orbitals elevating the valence band maximum. Consequently, the optical absorption edge redshifts, enhancing visible-light harvesting. Our findings demonstrate that RbBeBr3xIx offers significant optoelectronic tunability but highlights critical thermodynamic and elastic instabilities in the mixed-halide compositions, suggesting non-equilibrium synthesis routes are necessary for their practical realization.
本研究利用密度泛函理论对无铅钙钛矿系列RbBeBr3−xIx (x= 0,1,2,3)的结构、力学和光电性能进行了第一性原理分析。我们研究了属性调整和稳定性之间的权衡。虽然所有成分都满足Goldschmidt容差系数,但地层能量计算表明,相对于纯卤化物端元(RbBeBr3和RbBeI3),混合卤化物相(x=1,2)在热力学上是不稳定的。力学分析证实了RbBeBr3、RbBeBr1I2和RbBeI3的稳定性,但关键是确定RbBeBr2I1具有弹性不稳定性,其弹性特征值为- 1.7171 GPa。逐步碘取代引起系统的晶格软化,使希尔平均杨氏模量从26.6 GPa (x=0)降低到19.7 GPa (x=3)。光电性能方面,碘取代有效地将RbBeBr3的带隙从2.106 eV(间接)调整到0.495 eV(直接)。这是由I-5p轨道提高价带最大值所驱动的。因此,光学吸收边红移,增强可见光捕获。我们的研究结果表明,RbBeBr3−xIx具有显著的光电可调性,但在混合卤化物组合物中突出了关键的热力学和弹性不稳定性,这表明非平衡合成路线对于其实际实现是必要的。
{"title":"Design and analysis of RbBeBr3−xIx (x=0–3) lead-free perovskites: Tunable mechanical and optoelectronic properties via iodine substitution","authors":"Ismail Benaicha ,&nbsp;Imane Laazizi ,&nbsp;Youness Ait Alla ,&nbsp;Jaouad Mhalla ,&nbsp;Hafsa Diyagh ,&nbsp;Khalid Nouneh ,&nbsp;Smail Amraoui ,&nbsp;Atika Fahmi ,&nbsp;Marouan Karam ,&nbsp;Ahmed Qachaou ,&nbsp;Mounir Fahoume","doi":"10.1016/j.nwnano.2025.100172","DOIUrl":"10.1016/j.nwnano.2025.100172","url":null,"abstract":"<div><div>This study presents a first-principles analysis of the structural, mechanical, and optoelectronic properties of the lead-free perovskite series RbBeBr<span><math><msub><mrow></mrow><mrow><mn>3</mn><mo>−</mo><mi>x</mi></mrow></msub></math></span>I<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span> (<span><math><mrow><mi>x</mi><mo>=</mo><mn>0</mn></mrow></math></span>, 1, 2, 3) using density functional theory. We investigate the trade-offs between property tuning and stability. While all compositions satisfy the Goldschmidt tolerance factor, formation energy calculations reveal that the mixed-halide phases (<span><math><mrow><mi>x</mi><mo>=</mo><mn>1</mn><mo>,</mo><mn>2</mn></mrow></math></span>) are thermodynamically unstable relative to the pure-halide end members (RbBeBr<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> and RbBeI<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span>). Mechanical analysis confirms the stability of RbBeBr<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span>, RbBeBr<span><math><msub><mrow></mrow><mrow><mn>1</mn></mrow></msub></math></span>I<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>, and RbBeI<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span>, but crucially identifies RbBeBr<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>I<span><math><msub><mrow></mrow><mrow><mn>1</mn></mrow></msub></math></span> as elastically unstable, evidenced by a negative elastic eigenvalue of <span><math><mo>−</mo></math></span>1.7171 GPa. Progressive iodine substitution induces systematic lattice softening, reducing the Hill-averaged Young’s modulus from 26.6 GPa (<span><math><mrow><mi>x</mi><mo>=</mo><mn>0</mn></mrow></math></span>) to 19.7 GPa (<span><math><mrow><mi>x</mi><mo>=</mo><mn>3</mn></mrow></math></span>). Optoelectronically, iodine substitution effectively tunes the bandgap from 2.106 eV (indirect) for RbBeBr<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span> to 0.495 eV (direct) for RbBeI<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span>. This is driven by the I-5<span><math><mi>p</mi></math></span> orbitals elevating the valence band maximum. Consequently, the optical absorption edge redshifts, enhancing visible-light harvesting. Our findings demonstrate that RbBeBr<span><math><msub><mrow></mrow><mrow><mn>3</mn><mo>−</mo><mi>x</mi></mrow></msub></math></span>I<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span> offers significant optoelectronic tunability but highlights critical thermodynamic and elastic instabilities in the mixed-halide compositions, suggesting non-equilibrium synthesis routes are necessary for their practical realization.</div></div>","PeriodicalId":100942,"journal":{"name":"Nano Trends","volume":"13 ","pages":"Article 100172"},"PeriodicalIF":0.0,"publicationDate":"2025-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145738621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study analysis of consuming computer vision approaches for calculating the particle size of NiO- Al2O3 nanocomposite 使用计算机视觉方法计算NiO- Al2O3纳米复合材料粒度的研究分析
Pub Date : 2025-12-10 DOI: 10.1016/j.nwnano.2025.100173
Sinan S. Hamdi , Zinah N. Alabdali , Farah F. Alkalid
As a rapid development in the field of nanocomposite materials, sol-gel is considered one of the most accurate ways for preparation nanocomposite. Nanocomposite is usually characterized by scanning electron microscopy (SEM) for measuring the nano particle size. The major drawbacks of using scanning electron microscopy are the focus on small areas of the image. It takes a long time to measure a small area and depends on human skill, which involves manually drawing a line over each particle to calculate the average. Therefore, it is reliable, easy, fast, and simple way to computing program. A computing program refers to a set of instructions designed to achieve specific objectives, commonly known as algorithms. In this research, sol-gel was used to prepare NiO-Al2O3 nanocomposite, then scanning electron microscope (SEM) was used to estimate the particle size of the SEM image. Afterward, an algorithm was proposed for calculating the particle size of NiO-Al2O3 nanocomposite by applying computer vision. Eight of the preprocessing approaches are used for image enhancement: Histogram Equalization, CLAHE, Gaussian Blurred, Median Blurred, Bilateral Filter, Unsharp filter, Sobel and Wavelet. The results of particle size measured manually from the SEM image was 42 nm while the computer vision using CLAHE was 38 nm with particle detection of 86 % and Median Blurred is 42 nm with particle detection is 71 %. Therefore, the CLAHE algorithm shows the most accurate because it detects more particles than the other algorithms.
溶胶-凝胶法是纳米复合材料领域发展最快的一种方法,被认为是制备纳米复合材料最精确的方法之一。纳米复合材料通常通过扫描电子显微镜(SEM)来测量纳米颗粒的大小。使用扫描电子显微镜的主要缺点是聚焦于图像的小区域。测量一小块区域需要花费很长时间,并且依赖于人类的技能,这需要手动在每个粒子上画一条线来计算平均值。因此,它是一种可靠、方便、快速、简单的程序计算方法。计算程序指的是为实现特定目标而设计的一组指令,通常称为算法。在本研究中,采用溶胶-凝胶法制备了NiO-Al2O3纳米复合材料,然后利用扫描电子显微镜(SEM)估计了SEM图像的粒度。随后,提出了一种应用计算机视觉计算NiO-Al2O3纳米复合材料粒径的算法。图像增强使用了8种预处理方法:直方图均衡化、CLAHE、高斯模糊、中值模糊、双边滤波、非锐化滤波、Sobel和小波。人工扫描电镜测得的颗粒大小为42 nm,计算机视觉CLAHE测得的颗粒大小为38 nm,颗粒检出率为86%,Median Blurred测得的颗粒大小为42 nm,颗粒检出率为71%。因此,clhe算法比其他算法检测到更多的粒子,显示出最准确的结果。
{"title":"Study analysis of consuming computer vision approaches for calculating the particle size of NiO- Al2O3 nanocomposite","authors":"Sinan S. Hamdi ,&nbsp;Zinah N. Alabdali ,&nbsp;Farah F. Alkalid","doi":"10.1016/j.nwnano.2025.100173","DOIUrl":"10.1016/j.nwnano.2025.100173","url":null,"abstract":"<div><div>As a rapid development in the field of nanocomposite materials, sol-gel is considered one of the most accurate ways for preparation nanocomposite. Nanocomposite is usually characterized by scanning electron microscopy (SEM) for measuring the nano particle size. The major drawbacks of using scanning electron microscopy are the focus on small areas of the image. It takes a long time to measure a small area and depends on human skill, which involves manually drawing a line over each particle to calculate the average. Therefore, it is reliable, easy, fast, and simple way to computing program. A computing program refers to a set of instructions designed to achieve specific objectives, commonly known as algorithms. In this research, sol-gel was used to prepare NiO-Al<sub>2</sub>O<sub>3</sub> nanocomposite, then scanning electron microscope (SEM) was used to estimate the particle size of the SEM image. Afterward, an algorithm was proposed for calculating the particle size of NiO-Al<sub>2</sub>O<sub>3</sub> nanocomposite by applying computer vision. Eight of the preprocessing approaches are used for image enhancement: Histogram Equalization, CLAHE, Gaussian Blurred, Median Blurred, Bilateral Filter, Unsharp filter, Sobel and Wavelet. The results of particle size measured manually from the SEM image was 42 nm while the computer vision using CLAHE was 38 nm with particle detection of 86 % and Median Blurred is 42 nm with particle detection is 71 %. Therefore, the CLAHE algorithm shows the most accurate because it detects more particles than the other algorithms.</div></div>","PeriodicalId":100942,"journal":{"name":"Nano Trends","volume":"13 ","pages":"Article 100173"},"PeriodicalIF":0.0,"publicationDate":"2025-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145739269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Functional nanomaterials in combating antimicrobial resistance: Innovations in wound dressings and biomedical implants 抗微生物耐药性的功能纳米材料:伤口敷料和生物医学植入物的创新
Pub Date : 2025-12-09 DOI: 10.1016/j.nwnano.2025.100174
Mansi Agarwal , Ramakrishnan Ganesan , Jayati Ray Dutta
The rapid escalation of antimicrobial resistance (AMR) has rendered conventional antibiotics increasingly ineffective, particularly in chronic wound management and implant-associated infections where biofilm formation impedes drug penetration and fosters multidrug-resistant pathogens. Functional nanomaterials—encompassing metallic and metal-oxide nanoparticles, carbon-based nanostructures, polymeric and hybrid nanocomposites, and stimuli-responsive systems—offer transformative solutions by enabling localized, sustained, and multimodal antimicrobial action. These nanoscale platforms disrupt bacterial membranes, generate reactive oxygen species (ROS), release therapeutic ions or payloads in a controlled manner, and integrate regenerative cues to accelerate tissue repair. In wound dressings, nanomaterial integration enhances antimicrobial efficacy, angiogenesis, and moisture balance, while advanced implant coatings deliver biofilm-resistant, osteoinductive, and infection-responsive surfaces without systemic toxicity. This review synthesizes advances from 2010 to 2025, emphasizing biofilm-disruption mechanisms, smart drug-release strategies, and the clinical translation of nanomaterial-enabled therapies. It critically evaluates biosafety, regulatory, and scalability challenges, while outlining future directions including AI-guided material design, personalized nanomedicine, and sustainable synthesis approaches. By uniting antimicrobial potency with regenerative functionality, functional nanomaterials represent a paradigm shift in combating AMR at the interface of infection control and tissue engineering.
抗菌素耐药性(AMR)的迅速升级使得传统抗生素越来越无效,特别是在慢性伤口处理和植入物相关感染中,生物膜的形成阻碍了药物渗透并促进了多重耐药病原体。功能纳米材料——包括金属和金属氧化物纳米颗粒、碳基纳米结构、聚合物和混合纳米复合材料以及刺激响应系统——通过实现局部、持续和多模态的抗菌作用,提供了变革性的解决方案。这些纳米级平台破坏细菌膜,产生活性氧(ROS),以可控的方式释放治疗离子或有效载荷,并整合再生信号以加速组织修复。在伤口敷料中,纳米材料的整合增强了抗菌效果、血管生成和水分平衡,而先进的植入物涂层提供了抗生物膜、骨诱导和感染反应表面,而没有全身毒性。本文综述了从2010年到2025年的研究进展,重点介绍了生物膜破坏机制、智能药物释放策略和纳米材料治疗的临床转化。它批判性地评估了生物安全、监管和可扩展性挑战,同时概述了未来的方向,包括人工智能指导的材料设计、个性化纳米医学和可持续合成方法。通过将抗菌效力与再生功能结合起来,功能纳米材料代表了在感染控制和组织工程界面对抗抗菌素耐药性的范式转变。
{"title":"Functional nanomaterials in combating antimicrobial resistance: Innovations in wound dressings and biomedical implants","authors":"Mansi Agarwal ,&nbsp;Ramakrishnan Ganesan ,&nbsp;Jayati Ray Dutta","doi":"10.1016/j.nwnano.2025.100174","DOIUrl":"10.1016/j.nwnano.2025.100174","url":null,"abstract":"<div><div>The rapid escalation of antimicrobial resistance (AMR) has rendered conventional antibiotics increasingly ineffective, particularly in chronic wound management and implant-associated infections where biofilm formation impedes drug penetration and fosters multidrug-resistant pathogens. Functional nanomaterials—encompassing metallic and metal-oxide nanoparticles, carbon-based nanostructures, polymeric and hybrid nanocomposites, and stimuli-responsive systems—offer transformative solutions by enabling localized, sustained, and multimodal antimicrobial action. These nanoscale platforms disrupt bacterial membranes, generate reactive oxygen species (ROS), release therapeutic ions or payloads in a controlled manner, and integrate regenerative cues to accelerate tissue repair. In wound dressings, nanomaterial integration enhances antimicrobial efficacy, angiogenesis, and moisture balance, while advanced implant coatings deliver biofilm-resistant, osteoinductive, and infection-responsive surfaces without systemic toxicity. This review synthesizes advances from 2010 to 2025, emphasizing biofilm-disruption mechanisms, smart drug-release strategies, and the clinical translation of nanomaterial-enabled therapies. It critically evaluates biosafety, regulatory, and scalability challenges, while outlining future directions including AI-guided material design, personalized nanomedicine, and sustainable synthesis approaches. By uniting antimicrobial potency with regenerative functionality, functional nanomaterials represent a paradigm shift in combating AMR at the interface of infection control and tissue engineering.</div></div>","PeriodicalId":100942,"journal":{"name":"Nano Trends","volume":"13 ","pages":"Article 100174"},"PeriodicalIF":0.0,"publicationDate":"2025-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145791776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanoparticle-enabled herbal therapeutics for wound healing: bridging traditional medicine and modern nanotechnology 纳米颗粒使草药治疗伤口愈合:连接传统医学和现代纳米技术
Pub Date : 2025-12-08 DOI: 10.1016/j.nwnano.2025.100170
Shrihari B. Patil , Priyanka P. Patil , Sourav D. Gore , Shashidhar C. Patil , Rahul Koli
Wound healing is a complex, multistage physiological process involving hemostasis, inflammation, proliferation, and remodeling. Despite progress in conventional therapies, chronic and infected wounds remain major global health burdens, necessitating advanced biomaterial-based interventions. In recent years, nanoparticle-based delivery systems have emerged as transformative platforms for accelerating tissue repair, preventing infection, and modulating inflammatory pathways. This review comprehensively explores the integration of metal-based nanoparticles—including silver (Ag), gold (Au), copper (Cu), titanium (Ti), zinc (Zn), manganese (Mn), and cerium (Ce)—and biopolymeric or lipid-based nanostructures, such as nanoemulsions, hydrogels, solid lipid nanoparticles, and polymeric composites, in modern wound-healing strategies. These nanosystems exhibit superior bioavailability, controlled release, and targeted delivery of therapeutic phytoconstituents and biomolecules. In parallel, the growing body of herbal formulation patents demonstrates how traditional phytotherapy and modern nanotechnology are converging to create multifunctional, eco-sustainable wound-healing products with enhanced clinical potential. Key innovations include synergistic antimicrobial–anti-inflammatory activity, improved collagen synthesis, angiogenesis, and re-epithelialization. Together, these advancements mark a paradigm shift toward nanostructured herbal therapeutics that are biocompatible, stable, and scalable for translational and industrial development. This review provides a critical synthesis of current trends, mechanistic insights, and emerging directions, underscoring how nanoparticle-enabled herbal formulations are redefining the future of regenerative wound care.
伤口愈合是一个复杂的、多阶段的生理过程,包括止血、炎症、增殖和重塑。尽管传统疗法取得了进展,但慢性伤口和感染伤口仍然是全球主要的健康负担,因此需要先进的基于生物材料的干预措施。近年来,基于纳米颗粒的递送系统已经成为加速组织修复、预防感染和调节炎症途径的变革性平台。本文全面探讨了金属基纳米颗粒(包括银(Ag)、金(Au)、铜(Cu)、钛(Ti)、锌(Zn)、锰(Mn)和铈(Ce))与生物聚合物或脂质纳米结构(如纳米乳液、水凝胶、固体脂质纳米颗粒和聚合物复合材料)在现代伤口愈合策略中的整合。这些纳米系统表现出优越的生物利用度、控释和靶向递送治疗性植物成分和生物分子。与此同时,越来越多的草药配方专利表明,传统的植物疗法和现代纳米技术如何融合在一起,创造出多功能、生态可持续的伤口愈合产品,具有更高的临床潜力。关键创新包括协同抗炎活性,改善胶原合成,血管生成和再上皮化。总之,这些进步标志着纳米结构草药疗法的范式转变,这些疗法具有生物相容性,稳定性和可扩展的转化和工业发展。这篇综述提供了当前趋势、机制见解和新兴方向的关键综合,强调了纳米颗粒使草药配方如何重新定义再生伤口护理的未来。
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