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High-efficiency thin-film AlGaAs-GaAs double heterostructure solar cells 高效薄膜AlGaAs-GaAs双异质结构太阳能电池
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105741
R. Gale, R. McClelland, B. King, J. V. Gormley
AlGaAs-GaAs double-heterostructure solar cells were fabricated in 10 mu m-thick films and exhibited one-sun, total-area conversion efficiencies up to 19.5% AM0, and 22.4% AM1.5. The cell structure consisted on an n-doped GaAs emitter and p-doped GaAs base interposed between AlGaAs layers. The cell structure was deposited by organometallic vapor-phase epitaxy on a GaAs CLEFT substrate, and later mechanically separated from the substrate during cell fabrication. A single-layer antireflection coating was used without a coverglass. The cells, fabricated on 2 in diameter wafers, had areas of either 1 or 4 cm/sup 2/. Reuse of the substrate was successfully demonstrated. For comparison, cells fabricated with a conventional process from double heterostructures deposited on bulk GaAs substrates exhibited one-sun AM1.5 efficiencies as high as 23.7%. The impact of these high efficiencies on space and terrestrial applications is discussed.<>
在10 μ m厚的薄膜上制备了AlGaAs-GaAs双异质结构太阳能电池,其单太阳总面积转换效率高达19.5% AM0, 22.4% AM1.5。该电池结构由氮掺杂GaAs发射极和p掺杂GaAs基底组成。该电池结构通过有机金属气相外延沉积在GaAs CLEFT衬底上,然后在电池制造过程中与衬底机械分离。采用单层增透涂层,不加盖玻璃。在直径为2英寸的晶圆上制造的细胞,具有1或4厘米/sup /的面积。成功地演示了基板的重用。相比之下,在大块GaAs衬底上沉积双异质结构的传统工艺制备的电池显示出高达23.7%的单太阳AM1.5效率。讨论了这些高效率对空间和地面应用的影响。
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引用次数: 24
Proposed acceptance, qualification, and characterization tests for thin-film PV modules 提出薄膜光伏组件的验收、鉴定和特性测试
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105902
D. Waddington, L. Mrig, R. Deblasio, R. Ross
Details of a proposed test program for PV thin-film modules which the Department of Energy has directed SERI to prepare are presented. Results of one of the characterization tests that SERI has performed are also presented. The objective is to establish a common approach to testing modules that will be acceptable to both users and manufacturers. The tests include acceptance, qualification, and characterization tests. Acceptance tests verify that randomly selected modules have similar characteristics. Qualification tests are based on accelerated test methods designed to simulate adverse conditions. Characterization tests provide data on performance in a predefined environment.<>
介绍了能源部指示SERI准备的光伏薄膜模块拟议测试计划的细节。还介绍了SERI进行的一项表征测试的结果。目标是建立一种通用的方法来测试用户和制造商都能接受的模块。测试包括验收、鉴定和特性测试。验收测试验证随机选择的模块具有相似的特性。鉴定试验基于旨在模拟不利条件的加速试验方法。特性测试提供有关预定义环境中的性能的数据。
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引用次数: 1
Electro-optical properties of Cd/sub 1-x/Zn/sub x/S films and fabrication of Cd/sub 1-x/Zn/sub x/S/InP heterojunctions Cd/sub - 1-x/Zn/sub x/S薄膜的电光特性及Cd/sub - 1-x/Zn/sub x/S/InP异质结的制备
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105991
A. Pal, A. Dhar, A. Mondal, R. Basak, S. Chaudhuri
Cd/sub 1-x/Zn/sub x/S films (0
通过电学和光学测量对Cd/sub 1-x/Zn/sub x/S薄膜(0
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引用次数: 0
High-efficiency GaAs solar cells from a multiwafer OMVPE reactor 基于多晶片OMVPE反应器的高效砷化镓太阳能电池
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105807
K. Bertness, M. Ristow, H. C. Hamaker
A p/n GaAs solar cell with 24.0% efficiency under 1-sun global illumination (AM1.5, 1000 W/m/sup 2/) has been grown in a multiwafer organometallic vapor-phase epitaxy (OMVPE) reactor. This reactor has demonstrated good uniformity both from run to run and within a single run as part of a pilot line for the batch production of high-efficiency GaAs cells. The 24% efficiency value represents the highest efficiency reported to date for any solar cell under these conditions. The improved performance of these cells is believed to be mostly due to careful control of the emitter doping.<>
在多晶片有机金属气相外延(OMVPE)反应器中,在1太阳全局光照(AM1.5, 1000 W/m/sup 2/)下,生长出了效率为24.0%的p/n GaAs太阳能电池。作为批量生产高效砷化镓电池的中试生产线的一部分,该反应器在每次运行和单次运行中都表现出良好的均匀性。24%的效率值代表了迄今为止报道的在这些条件下任何太阳能电池的最高效率。这些电池性能的提高被认为主要是由于对发射极掺杂的仔细控制
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引用次数: 5
A novel design for amorphous silicon alloy solar cells 非晶硅合金太阳能电池的新设计
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105659
S. Guha, J. Yang, A. Pawlikiewicz, T. Glatfelter, R. Ross, S. Ovshinsky
The authors have developed an amorphous silicon alloy-based solar cell with a novel structure. Computer simulation studies show that for a given short-circuit current, it is possible to obtain a higher open-circuit voltage and fill factor than in a conventional cell design. For a nominal 1.5 eV a-SiGe alloy, the fill factor under red illumination can be improved from 0.55 to 0.64 for the same short-circuit current. Experimental cell structures confirm the theoretical prediction. The novel cell design shows a considerable improvement in efficiency. Dynamic internal collection efficiency measurements show reduced recombination in these cells, which gives rise to the observed higher fill factors. Incorporation of this structure in the bottom cell of a triple device has resulted in the achievement of 13.7% efficiency under global AM1.5 illumination.<>
作者开发了一种结构新颖的非晶硅基太阳能电池。计算机仿真研究表明,对于给定的短路电流,可以获得比传统电池设计更高的开路电压和填充因子。对于标称1.5 eV的a- sige合金,在相同的短路电流下,红色照明下的填充因子可以从0.55提高到0.64。实验细胞结构证实了理论预测。这种新颖的电池设计在效率上有了相当大的提高。动态内部收集效率测量表明,这些细胞中的重组减少了,这导致了观察到的更高的填充因子。将这种结构结合到三联器件的底部电池中,在全局AM1.5照明下,效率达到13.7%
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引用次数: 15
Photoluminescence quenching by electric fields in hydrogenated amorphous silicon 氢化非晶硅的电场致光猝灭
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105686
T. Muschik, R. Schwarz, H. Curtins, M. Favre
The decrease of photoluminescence (PL) intensity at low temperature was measured as a function of external fields (up to 3*10/sup 5/ V/cm) in hydrogenated amorphous silicon (a-Si:H). The results are discussed within the framework of the recombination of geminate pairs together with basic physical phenomena such as carrier separation during thermalization trapping of photoexcited carriers in band tails, and possible subsequent reemission or tunneling out of traps. It is concluded that separation of carriers during relaxation in extended and flat tail states is the dominant process for the field quenching of PL intensity. But other processes such as Poole-Frenkel emission and tunneling out of traps cannot be ruled out totally. The basic idea of carrier separation is supported by consistent values for the average mobility from both the quenching of PL intensity with electric fields and the concomitant energy shift of the maximum in the PL spectra.<>
测量了氢化非晶硅(a- si:H)在低温下的光致发光(PL)强度随外加电场(高达3*10/sup 5/ V/cm)的变化规律。讨论了这些结果,并结合了一些基本的物理现象,如光激发载流子在带尾的热化捕获过程中的载流子分离,以及随后可能的再发射或隧穿出陷阱。结果表明,在扩展尾和平尾弛豫状态下载流子的分离是导致PL强度场猝灭的主要原因。但也不能完全排除其他过程,如普尔-弗伦克尔发射和隧道出陷阱。载流子分离的基本思想得到了电场对PL强度的猝灭和PL光谱中最大值的伴随能量位移的平均迁移率的一致值的支持。
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引用次数: 2
Antimony-doped dendritic web silicon solar cells 掺锑树突状网状硅太阳能电池
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105735
D. Meier, J. Spitznagel, J. Greggi, R. Campbell
Antimony has been explored as a dopant in dendritic web silicon in an attempt to achieve uniformity in resistivity through the thickness and along the length of the web ribbon, and to inhibit the formation of deleterious oxide precipitates. The desired uniformity was achieved, making possible the fabrication of efficient, n-base bifacial cells using high-resistivity (10-100 Omega -cm) web and the growth of web over long periods of time (five days) without replenishing the dopant in the melt. Antimony-doped web cells were fabricated with measured hole diffusion lengths up to 333 mu m and hole lifetimes up to 66 mu s. Such diffusion lengths significantly exceed the typical web thickness (100-125 mu m), thereby satisfying an important requirement for high-efficiency cells. Web cell efficiencies up to 16.7% were measured. It is concluded that the superior electrical properties obtained for some cells may be associated more with appropriate growth conditions (few dislocations) than with the action of antimony in inhibiting the formation of SiO/sub x/ precipitates.<>
在树突网状硅中,锑作为掺杂剂进行了探索,试图通过厚度和沿网状带的长度实现电阻率的均匀性,并抑制有害氧化物沉淀的形成。实现了所需的均匀性,使得使用高电阻率(10-100 Omega -cm)的网状结构制造高效的n基双面电池成为可能,并且网状结构的生长需要很长一段时间(5天),而无需补充熔体中的掺杂剂。制备的掺锑网状电池的孔扩散长度可达333 μ m,孔寿命可达66 μ s,这种扩散长度大大超过了典型的网状厚度(100-125 μ m),从而满足了高效电池的重要要求。网络电池效率高达16.7%。由此得出结论,某些细胞的优异电学性能可能更多地与适当的生长条件(很少的位错)有关,而不是与锑抑制SiO/sub x/沉淀形成的作用有关
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引用次数: 3
Development in silicon sheet technologies 硅片技术的发展
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105932
A. Goetzberger, A. Rauber
The status of techniques for the production of sheets, ribbons, and foils of silicon for solar cells is reviewed. Technical problems and economic constraints are analyzed. The horizontal support web technique relies on a wedge-shaped growth interface which decouples the pulling velocity and the growth velocity which are nearly perpendicular to each other. The growing ribbon floats on a silicon melt that is contained in a long silicon crucible and is withdrawn to one side. In the ramp assistant foil technique, the silicon melt is contained in a relatively flat crucible that is open on one side. A preheated substrate is moved across this opening, and some of the melt solidifies on the surface. The silicon-sheets-from-powder technique starts from Si powder or granular silicon (grain size: 50-500 mu m). Three steps are needed to obtain the final ribbon. It is concluded that although the basic ideas as well as the results of these three methods are very distinct, evaluation of their respective merits is difficult.<>
综述了太阳能电池用硅片、硅带和硅箔的生产技术现状。分析了技术问题和经济制约因素。水平支撑腹板技术依赖于一个楔形生长界面,该界面解耦了几乎相互垂直的拉拔速度和生长速度。生长的条带漂浮在硅熔体上,硅熔体包含在一个长硅坩埚中,并向一侧收缩。在斜坡辅助箔技术中,硅熔体被包含在一个相对平坦的坩埚中,坩埚在一侧打开。预热过的基材穿过这个开口,一些熔体在表面凝固。硅片制粉技术从硅粉或颗粒硅(粒度50-500 μ m)开始,需要三步才能得到最终的硅带。结果表明,虽然这三种方法的基本思想和结果非常不同,但很难对它们各自的优点进行评价。
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引用次数: 3
Characterization and modeling of InP solar cells InP太阳能电池的表征与建模
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105834
G. Augustine, A.W. Smith, A. Rohatgi, C. Keavney
InP solar cells were modeled before and after proton irradiation using a PC-1D computer model. It was necessary to include bandgap narrowing in the n/sup +/ emitter to match the calculated and measured quantum efficiency, leakage current, and cell data simultaneously. A high-efficiency ( approximately=18.2%, AM0) InP solar cell was fabricated and modeled successfully. Guidelines are provided for achieving greater than 22% efficiency for InP cells. A 10 MeV proton irradiation with a dose of 2*10/sup 13/ cm/sup -2/ reduces the cell performance of a 16.3% cell to 11% by introducing the deep levels at an E/sub v/ of +0.29 eV and an E/sub v/ of +0.52 eV. Modeling showed that this performance degradation is associated with a decrease in bulk lifetime from 0.75 to 0.028 ns with no appreciable change in front surface recombination velocity.<>
利用PC-1D计算机模型对质子辐照前后的InP太阳能电池进行建模。有必要在n/sup +/发射器中包括带隙缩小,以同时匹配计算和测量的量子效率,泄漏电流和电池数据。制备了一种高效(约=18.2%,AM0)的InP太阳能电池,并成功地建立了模型。为实现大于22%的InP电池效率提供了指南。以2*10/sup 13/ cm/sup -2/的剂量进行10 MeV质子辐照,通过引入E/sub v/ +0.29 eV和E/sub v/ +0.52 eV的深层能级,将16.3%的电池性能降低到11%。建模表明,这种性能下降与整体寿命从0.75 ns减少到0.028 ns有关,而前表面复合速度没有明显变化。
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引用次数: 6
Photon degradation of AlGaAs/GaAs solar cells AlGaAs/GaAs太阳能电池的光子降解
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105852
B. Anspaugh, R. Kachare, P. Iles
The behavior of GaAs solar cells after photon illumination for a prolonged exposure time is presented. More than 55 OMCVD AlGaAs/GaAs solar cells were exposed for over 400 h to AM0 photons at 29 degrees C in three separate, well-controlled runs. Significant degradation of solar cell efficiency was observed in two out of three runs. Although noticeable losses in the open-circuit voltage, fill factor, and maximum power were observed, no change in the short-circuit current was found. In one of the runs, no change was seen in either the test cells or the control cells. Each cell in this run was protected with a coverglass. The cells in this run had thicker buffer layers and thinner window layers than the cells in the other two runs.<>
研究了砷化镓太阳能电池在长时间曝光后的发光特性。超过55个OMCVD AlGaAs/GaAs太阳能电池在29摄氏度的温度下,在三个独立的、控制良好的运行中暴露在AM0光子下超过400小时。在三次运行中有两次观察到太阳能电池效率显著下降。虽然开路电压、填充系数和最大功率有明显的损失,但短路电流没有变化。在其中一次运行中,在测试细胞或控制细胞中都没有看到变化。这一趟的每个牢房都用玻璃罩保护着。与其他两次运行的细胞相比,这次运行的细胞具有更厚的缓冲层和更薄的窗口层
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引用次数: 4
期刊
Conference Record of the Twentieth IEEE Photovoltaic Specialists Conference
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