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Emerging Optoelectronic Devices for Brain-Inspired Computing 用于脑启发计算的新兴光电设备
IF 6.2 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1002/aelm.202400482
Lingxiang Hu, Xia Zhuge, Jingrui Wang, Xianhua Wei, Li Zhang, Yang Chai, Xiaoyong Xue, Zhizhen Ye, Fei Zhuge
Brain-inspired neuromorphic computing is recognized as a promising technology for implementing human intelligence in hardware. Neuromorphic devices, including artificial synapses and neurons, are regarded as essential components for the construction of neuromorphic hardware systems. Recently, optoelectronic neuromorphic devices are increasingly highlighted due to their potential applications in next-generation artificial visual systems, attributed to their integrated sensing, computing, and memory capabilities. In this review, recent advancements in optoelectronic synapses and neurons are examined, with an emphasis on their structural characteristics, operational principles, and the replication of neuromorphic functions. For optoelectronic synaptic devices, such as memristor- and transistor-based ones, attention is given to the two primary weight update modes: the light-electricity synergistic mode and the all-optical mode. Optoelectronic neurons are discussed in terms of different device types, including threshold switch neurons and semiconductor laser neurons. Last, the challenges that impede the progress of optoelectronic neuromorphic devices are identified, and potential future directions are suggested.
受大脑启发的神经形态计算被认为是在硬件中实现人类智能的一项前景广阔的技术。神经形态设备,包括人工突触和神经元,被视为构建神经形态硬件系统的重要组成部分。最近,光电神经形态器件因其集成的传感、计算和记忆能力,在下一代人工视觉系统中的潜在应用日益受到重视。本综述将探讨光电突触和神经元的最新进展,重点关注其结构特征、工作原理以及神经形态功能的复制。对于光电突触设备,如基于忆阻器和晶体管的设备,重点关注两种主要的权重更新模式:光电协同模式和全光模式。此外,还讨论了不同器件类型的光电神经元,包括阈值开关神经元和半导体激光神经元。最后,指出了阻碍光电神经形态设备发展的挑战,并提出了潜在的未来发展方向。
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引用次数: 0
Enhanced-Resolution Learning-Based Direction of Arrival Estimation by Programmable Metasurface 通过可编程元面进行基于增强分辨率学习的到达方向估计
IF 6.2 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-09 DOI: 10.1002/aelm.202400476
Nawel Meftah, Badreddine Ratni, Mohammed Nabil El Korso, Shah Nawaz Burokur
Due to its growing importance and wide range of applications, direction-of-arrival (DOA) estimation has become a major research topic, particularly in the field of communication systems. While traditional DOA estimation methods rely on antenna arrays and complex algorithms, recent progress achieved in the design and implementation of metasurfaces has proved their effectiveness as promising alternatives. This study presents a distinct approach for DOA estimation that combines the use of a programmable metasurface with deep learning. The programmable metasurface together with a radio-frequency power detector placed at the focal point, acts as a parabolic reflector antenna with an adjustable pointing direction, which scans the azimuth plane in 5° increments to receive the power level of incoming signals. The collected data is then fed into a pre-trained multilayer neural network to enable DOA estimation with a resolution of lower than 1° without requiring fine-tuning of the scanning procedure. This approach ensures accurate and fast estimations, paving the way for advanced solutions in detection and localization for various applications.
由于到达方向(DOA)估计的重要性和广泛应用,它已成为一个重要的研究课题,尤其是在通信系统领域。传统的 DOA 估计方法依赖于天线阵列和复杂的算法,而最近在元表面设计和实现方面取得的进展证明了元表面作为有前途的替代方法的有效性。本研究提出了一种独特的 DOA 估算方法,将可编程元面的使用与深度学习相结合。可编程元面与放置在焦点处的射频功率检测器一起,就像一个抛物面反射天线,其指向方向可调,以 5° 为增量扫描方位平面,以接收传入信号的功率水平。然后将收集到的数据输入预先训练好的多层神经网络,以实现分辨率低于 1° 的 DOA 估计,而无需对扫描程序进行微调。这种方法确保了估算的准确性和快速性,为各种应用的探测和定位的先进解决方案铺平了道路。
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引用次数: 0
Self-Powered Cs3Bi2I9/ZnO Heterojunction Photodetector with Dual-Band Photoresponse 具有双波段光响应的自供电 Cs3Bi2I9/ZnO 异质结光电探测器
IF 6.2 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-08 DOI: 10.1002/aelm.202400514
Weixin Ouyang
Cs3Bi2I9/ZnO heterostructures are constructed by the growth of Cs3Bi2I9 layer onto the spin-coated ZnO films by a modified antisolvent recrystallization method, a series of Cs3Bi2I9/ZnO heterojunction photodetectors (PDs) with varied growth times of Cs3Bi2I9 layer are fabricated. The construction of Cs3Bi2I9/ZnO heterojunction contributes to their improved photoelectric performance compared to ZnO-based PD, and the Cs3Bi2I9 layer thickness plays an important role in tuning the photoelectric performance of these PDs. At 405 nm and 0 V bias, the optimized 6-Cs3Bi2I9/ZnO PD generates a high photocurrent of −3.03 µA, a medium on/off ratio of 144.3, and a short response time of 16.4 ms/16.8 ms. It also exhibits superior dual-band self-powered photoresponse with two responsivity and detectivity peaks at 380 nm in the UV region and at 430 nm in the visible light region. At 380 nm, this PD presents the highest responsivity of 33.2 mA W−1 and detectivity of 1.07 × 1010 Jones. It is believed that the optimized growth of the Cs3Bi2I9 layer generates a depletion layer with suitable thickness near the interface, and the as-promoted charge-carrier separation and transport result in improved self-powered properties. The rational construction of perovskite-based heterojunction has proved as an efficient way to achieve self-powered photodetection.
通过改良的反溶剂重结晶法在旋涂氧化锌薄膜上生长 Cs3Bi2I9 层,构建了 Cs3Bi2I9/氧化锌异质结构,并制造了一系列 Cs3Bi2I9 层生长时间不同的 Cs3Bi2I9/ 氧化锌异质结光电探测器(PD)。与基于 ZnO 的光电探测器相比,Cs3Bi2I9/ZnO 异质结的构造有助于提高其光电性能,而 Cs3Bi2I9 层的厚度在调整这些光电探测器的光电性能方面起着重要作用。在 405 纳米和 0 V 偏压条件下,优化的 6-Cs3Bi2I9/ZnO PD 可产生 -3.03 µA 的高光电流、144.3 的中等导通/关断比和 16.4 ms/16.8 ms 的短响应时间。它还具有出色的双波段自供电光响应,在紫外区 380 纳米和可见光区 430 纳米处有两个响应和检测峰值。在 380 nm 波长处,这种 PD 的响应率最高,达到 33.2 mA W-1,检测率为 1.07 × 1010 Jones。我们认为,Cs3Bi2I9 层的优化生长在界面附近产生了具有合适厚度的耗尽层,电荷载流子的分离和传输促进了自供电特性的改善。事实证明,合理构建基于包晶石的异质结是实现自供电光电探测的有效途径。
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引用次数: 0
Enhanced Electro-Resistance and Tunable Asymmetric Depolarization Behavior in Hf0.5Zr0.5O2 Ferroelectric Tunnel Junction by Bottom Oxide Interfacial Layer 底层氧化物界面层增强 Hf0.5Zr0.5O2 铁电隧道结的电阻抗和可调谐不对称去极化行为
IF 6.2 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-08 DOI: 10.1002/aelm.202400466
Shuxian Lyu, Xiao Long, Yang Yang, Wei Wei, Yuanxiang Chen, Hong Xie, Bowen Nie, Boping Wang, Yuan Wang, Pengfei Jiang, Tiancheng Gong, Yan Wang, Qing Luo
Electro-resistance (ER) plays a crucial role in the application of hafnia-based ferroelectric tunnel junctions (FTJs), pivotal devices widely acknowledge for their potential in non-volatile memory and neuromorphic networks. Leveraging atomic layer deposition (ALD) enhances the flexibility in fabricating bilayer FTJs by combining a ferroelectric layer with another oxide layer. Introducing additional layers is necessary to achieve a sufficient storage window for implementing intriguing functions, albeit at the risk of increased depolarization field strength. Hence, selecting a suitable inserted layer becomes paramount. In this study, a novel strategy to enhance the performance of Ge-based Hf0.5Zr0.5O2 FTJs is presented by incorporating bottom interfacial layers (ILs) with distinct band energy characteristics. The optimized FTJs exhibit significantly improved endurance, lower coercive voltage, and enhanced retention properties. Notably, an intriguing asymmetric retention behavior driven by the imprint field (Eimp) is observed, which can be mitigated by integrating TiO2 ILs. Most importantly, an effective method to manipulate depolarization behavior in hafnia-based devices through ILs is introduced, leading to enhanced non-volatility and synaptic behavior in FTJs.
基于铪的铁电隧道结(FTJ)是一种关键器件,因其在非易失性存储器和神经形态网络中的潜力而得到广泛认可。利用原子层沉积(ALD)技术,通过将铁电层与另一层氧化物相结合,提高了制造双层铁电隧道结的灵活性。为了获得足够的存储窗口以实现复杂的功能,有必要引入额外的层,但这有可能增加去极化场强。因此,选择合适的插入层变得至关重要。本研究提出了一种新策略,通过加入具有不同带能特性的底部界面层(IL)来提高 Ge 基 Hf0.5Zr0.5O2 FTJ 的性能。优化后的 FTJs 具有明显改善的耐久性、更低的矫顽力电压和更强的保持特性。值得注意的是,在印记场(Eimp)的驱动下,观察到了一种有趣的非对称保持行为,通过整合 TiO2 IL,这种行为可以得到缓解。最重要的是,该研究引入了一种有效的方法,通过IL操纵基于铪的器件中的去极化行为,从而增强了FTJ的非挥发性和突触行为。
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引用次数: 0
Electrical Sensing of Molecular Spin State Switching in a Spin Crossover Complex Using an Organic Field-Effect Transistor 利用有机场效应晶体管对自旋交叉复合物中的分子自旋态切换进行电传感
IF 6.2 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-08 DOI: 10.1002/aelm.202400590
Yuteng Zhang, Seyed Ehsan Alavi, Ion Soroceanu, Dennis Wanyoike Kamau, Aurelian Rotaru, Isabelle Séguy, Lionel Salmon, Gábor Molnár, Azzedine Bousseksou
An organic semiconductor – spin crossover polymer composite heterostructure is fabricated, and it is integrated into an organic field-effect transistor (OFET) with the aim to achieve electrical sensing of molecular spin state switching events. The OFETs display ≈50–70% increase in drain-source current intensity when going from the low spin (LS) to the high spin (HS) state. This phenomenon is reversible without apparent fatigue and the application of a gate voltage significantly enhances the sensing sensitivity. Capacitance measurements and finite element calculations allow identifying mechanical stress, induced by the spin state switching, at the origin of the transistor response. These results open up appealing perspectives for the integration of spin crossover molecules into technological applications, such as soft robotics.
我们制作了一种有机半导体-自旋交叉聚合物复合异质结构,并将其集成到有机场效应晶体管(OFET)中,以实现对分子自旋态切换事件的电学感应。当从低自旋(LS)状态切换到高自旋(HS)状态时,OFET 的漏源电流强度会增加 ≈50-70%。这种现象是可逆的,不会产生明显的疲劳,而且施加栅极电压可显著提高传感灵敏度。通过电容测量和有限元计算,可以确定自旋态切换引起的机械应力是晶体管响应的根源。这些结果为自旋交叉分子融入软机器人等技术应用开辟了极具吸引力的前景。
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引用次数: 0
Reversible Switching of Light-Gated Organic Transistors Employing Dihydroazulene/Vinylheptafulvene Photo-/Thermochromic Molecules 采用二氢偶氮烯/乙烯基七富烯光致/热致变色分子的光门控有机晶体管的可逆切换
IF 6.2 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-08 DOI: 10.1002/aelm.202400455
Sten Gebel, Oumaima Aiboudi, Vladimir Grigorescu, Zhitian Ling, Tomasz Marszalek, Paul W. M. Blom, Charusheela Ramanan, Franziska Lissel, Ulrike Kraft
An innovative possibility to introduce additional functionality to organic field-effect transistors (OFETs) is to employ photochromic molecules, which undergo reversible isomerization under applied stimuli such as irradiation with specific wavelengths. As a result, the transistors not only can be switched on/off by the applied voltages, they can also be programmed by alternate triggers, such as light. Here, reversible switching of OFETs is presented by blending various dihydroazulene/vinylheptafulvene photoswitches into polythiophene-based conjugated polymers. In result, the transfer characteristics of the transistors are altered significantly through UV irradiation. In contrast to current literature on different photoswitches such as spiropyrans or diarylethenes, the backreaction is induced thermally and not via visible light irradiation and reproducibly yields the pristine transistor characteristics. This reversible switching upon alternating UV irradiation and thermal annealing is quantified by figures of merit such as the magnitude of drain current, threshold voltage, and subthreshold swing. Irradiating the devices with different doses of UV light shows that the magnitude of switching directly depends on the respective UV dose, hence enabling a multi-level electronic system. Furthermore, long-term cyclability over 100 steps of repeated UV light exposure and thermal annealing is demonstrated.
为有机场效应晶体管(OFET)引入额外功能的一种创新可能性是采用光致变色分子,这种分子在特定波长照射等外加刺激下会发生可逆异构化。因此,晶体管不仅可以通过外加电压开关,还可以通过光等交替触发器进行编程。在这里,通过将各种二氢氮杂环戊烯/七氟乙烯光开关与聚噻吩基共轭聚合物混合,介绍了 OFET 的可逆开关。结果,晶体管的传输特性在紫外线照射下发生了显著变化。与目前有关螺吡喃或二元乙烯等不同光开关的文献相比,这种反向反应是通过热诱导而非可见光照射引起的,并能重复产生原始晶体管特性。这种交替紫外线辐照和热退火后的可逆开关可通过漏极电流大小、阈值电压和阈下摆动等性能指标进行量化。用不同剂量的紫外线照射器件,结果表明开关的大小直接取决于各自的紫外线剂量,从而实现了多级电子系统。此外,在重复紫外光照射和热退火的 100 个步骤中,还证明了器件的长期可循环性。
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引用次数: 0
Intrinsically Stretchable Polymer Semiconductor with Regional Conjugation for Stretchable Electronics (Adv. Electron. Mater. 9/2024) 用于可拉伸电子器件的具有区域共轭的本征可拉伸聚合物半导体(Adv.)
IF 5.3 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-07 DOI: 10.1002/aelm.202470030
Sichun Wang, Liangjie Wang, Shiwei Ren, Wenhao Li, Zhihui Wang, Zhengran Yi, Yunqi Liu

Intrinsically Stretchable Polymer Semiconductor

In article number 2300816, Zhihui Wang, Zhengran Yi, and co-workers propose a novel “regional conjugation” strategy to design an intrinsically stretchable high-performance polymer semiconductor. It enables excellent charge transport performance of fully stretchable transistors under large mechanical strain. This strategy provides a promising methodology for developing mechanically robust stretchable polymer thin film electronics.

本征可拉伸聚合物半导体在文章编号 2300816 中,王志辉、易正然及其合作者提出了一种新颖的 "区域共轭 "策略,用于设计一种本征可拉伸的高性能聚合物半导体。它使完全可拉伸晶体管在大机械应变下具有优异的电荷传输性能。这一策略为开发具有机械稳健性的可拉伸聚合物薄膜电子器件提供了一种前景广阔的方法。
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引用次数: 0
Masthead: (Adv. Electron. Mater. 9/2024) 刊头:(Adv.)
IF 5.3 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-07 DOI: 10.1002/aelm.202470031
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引用次数: 0
Short-Term and Long-Term Memory Functionality of a Brain-Like Device Built from Nanoparticle Atomic Switch Networks 由纳米粒子原子开关网络构建的类脑设备的短期和长期记忆功能
IF 6.2 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-07 DOI: 10.1002/aelm.202400360
Oradee Srikimkaew, Saman Azhari, Deep Banerjee, Yuki Usami, Hirofumi Tanaka
The synaptic plasticity of the Ag-Ag2S nanoparticle-based volatile memristor system is demonstrated. The nanoparticles self-assemble into a network with over 103 interconnected atomic switch interfaces. Short-term plasticity is identified by spontaneous conductance relaxation, attributed to the memristor's volatility. The conductance of the network is enhanced when a subsequent stimulus pulse arrives shortly after the previous one, analogous to the paired-pulse facilitation in biological synapses. Furthermore, repeated pulse stimulation is used to achieve the transition from short-term plasticity to long-term potentiation, a process related to learning and memory formation. Remarkably, the result reveals that the lifetime of long-term potentiation for 100-pulse stimulation is 40 min, indicating that the device can forget newly acquired information after prolonged storage, akin to human memories. The findings provide insight into the the learning and memory abilities of atomic switch network memristors, facilitating the development of hardware-implemented artificial neural networks.
演示了基于 Ag-Ag2S 纳米粒子的挥发性忆阻器系统的突触可塑性。纳米粒子自组装成一个网络,其中有超过 103 个相互连接的原子开关界面。自发的电导弛豫确定了短期可塑性,这归因于忆阻器的挥发性。当后一个刺激脉冲在前一个脉冲之后不久到达时,网络的电导就会增强,这类似于生物突触中的成对脉冲促进。此外,重复脉冲刺激可用于实现从短期可塑性到长期电位的过渡,这是一个与学习和记忆形成有关的过程。值得注意的是,研究结果表明,100 次脉冲刺激的长期延时寿命为 40 分钟,这表明该装置可以在长时间存储后遗忘新获得的信息,这与人类记忆类似。这些研究结果有助于深入了解原子开关网络忆阻器的学习和记忆能力,从而推动硬件实现的人工神经网络的发展。
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引用次数: 0
Capacitance and Conductance Compensation Methods for Efficient Computing-In-Memory Designs 用于高效内存计算设计的电容和电导补偿方法
IF 6.2 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-09-06 DOI: 10.1002/aelm.202400452
Yubiao Luo, Fei Qiao, Zhong Sun
Compensation has been a common while unacknowledged strategy in the design of computing-in-memory (CIM) schemes. It enables efficient CIM designs by intentionally letting the sum of capacitances or conductances of two or more rows or columns in the memory array equal, thus resulting in a concise mathematical formula regarding the memory cell data and the input data, which constitute computing primitives. Here, the capacitance and conductance compensation methods are reviewed that have been used for CIM designs based on static random-access memory (SRAM) in combination with capacitors and nonvolatile resistive memory, respectively, and uncover the underlying principles and their application to CIM. It is hoped this effort will help recognize the compensation methods as a building block for CIM designs, and will be an inspiration to developing more CIM schemes that are more compact in area, more efficient in energy consumption, and capable of solving more complicated problems.
在内存计算(CIM)方案的设计中,补偿一直是一种常见的策略,但却未得到认可。它通过有意让存储器阵列中两行或多行或多列的电容或电导之和相等来实现高效的 CIM 设计,从而产生有关存储器单元数据和输入数据的简明数学公式,这些数据构成了计算基元。在此,我们回顾了基于静态随机存取存储器(SRAM)结合电容器和非易失性电阻存储器的 CIM 设计中使用的电容和电导补偿方法,并揭示了其基本原理及其在 CIM 中的应用。希望这项工作有助于认识作为 CIM 设计基石的补偿方法,并对开发更多面积更紧凑、能耗更高效、能解决更复杂问题的 CIM 方案有所启发。
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引用次数: 0
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Advanced Electronic Materials
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