Pub Date : 2024-09-03DOI: 10.1016/j.earscirev.2024.104915
Lucas V. Warren , Bruno Becker-Kerber , Lucas Inglez , Filipe G. Varejão , Luana P.C. Morais , Marcello G. Simões , Bernardo T. Freitas , Julia M. Arrouy , Lucía E. Gómez-Peral , Daniel G. Poiré , Juliana Okubo , Fabrício Caxito , Gabriel J. Uhlein , Gabriel C. Antunes , Ilana Lehn , Guilherme R. Romero , Thomas R. Fairchild
South America figures as one of the most fruitful continents for paleontological research on the Ediacaran-Cambrian transition, with almost 100 years of studies on organisms preserved in carbonates and siliciclastic successions deposited during the birth of the Gondwana supercontinent. However, this scientific record is often scattered among local publications which is part of the reason for the unfamiliarity of geoscientists with the Ediacaran paleontology of this continent. To address this issue, this paper provides a comprehensive overview of Ediacaran paleontology in South America. It achieves this by conducting a thorough assessment of existing research alongside presenting ample new data concerning fossil discoveries. Following current efforts to add new pieces to the complex puzzle on metazoan evolution, this contribution resumes our understanding of the variety and diversity of Ediacaran assemblages in this part of the planet. Positioning South American successions in space and time and comparing them with occurrences worldwide helps us understand the different pulses of extinctions, and their forcings and consequences for life diversification during the Ediacaran. Lastly, by definitively adding the paleontological record of SW Gondwana to the global picture, we seek to contribute to current discussions on the subdivision of the Ediacaran, perhaps the most emblematic period in the geological record.
{"title":"The Ediacaran paleontological record in South America","authors":"Lucas V. Warren , Bruno Becker-Kerber , Lucas Inglez , Filipe G. Varejão , Luana P.C. Morais , Marcello G. Simões , Bernardo T. Freitas , Julia M. Arrouy , Lucía E. Gómez-Peral , Daniel G. Poiré , Juliana Okubo , Fabrício Caxito , Gabriel J. Uhlein , Gabriel C. Antunes , Ilana Lehn , Guilherme R. Romero , Thomas R. Fairchild","doi":"10.1016/j.earscirev.2024.104915","DOIUrl":"10.1016/j.earscirev.2024.104915","url":null,"abstract":"<div><p>South America figures as one of the most fruitful continents for paleontological research on the Ediacaran-Cambrian transition, with almost 100 years of studies on organisms preserved in carbonates and siliciclastic successions deposited during the birth of the Gondwana supercontinent. However, this scientific record is often scattered among local publications which is part of the reason for the unfamiliarity of geoscientists with the Ediacaran paleontology of this continent. To address this issue, this paper provides a comprehensive overview of Ediacaran paleontology in South America. It achieves this by conducting a thorough assessment of existing research alongside presenting ample new data concerning fossil discoveries. Following current efforts to add new pieces to the complex puzzle on metazoan evolution, this contribution resumes our understanding of the variety and diversity of Ediacaran assemblages in this part of the planet. Positioning South American successions in space and time and comparing them with occurrences worldwide helps us understand the different pulses of extinctions, and their forcings and consequences for life diversification during the Ediacaran. Lastly, by definitively adding the paleontological record of SW Gondwana to the global picture, we seek to contribute to current discussions on the subdivision of the Ediacaran, perhaps the most emblematic period in the geological record.</p></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"258 ","pages":"Article 104915"},"PeriodicalIF":10.8,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142162901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-31DOI: 10.1016/j.earscirev.2024.104904
Grzegorz Racki , Christian Koeberl
<div><div>Despite several, sometimes prominent propagators, meteorite impact research had a long period of peripheral status until the 1980s. Since then, there has been an intense search for impact-extinction pairs, driven by the rapid acceptance of Alvarez's hypothesis of a catastrophic Chicxulub impact at the end of the Mesozoic era. However, substantial errors have occurred for incompletely identified and/or indirectly dated impact craters in the context of purportedly coeval mass extinctions. For example, supposed giant craters based only on geophysical studies, such as those alleged as evidence of impact-driven end-Permian and Late Ordovician extinctions, are not supported by any real impact evidence (e.g., catastrophic sedimentation) in adjacent areas.</div><div>The updated three-step methodology presents an accurate approach to cause-effect inference in impact catastrophism. It begins with (1) conclusive recognition of impact craters and ejecta, followed by (2) their precise radiometric or biostratigraphic dating, and concludes with (3) assessing the impact's “kill” potential. The impact contribution to widely defined mass extinctions has been falsified based on the latest crater information from the global database and the updated ages of stratigraphic boundaries. In the Phanerozoic, two contrasting collision phenomena occurred: the Chicxulub asteroid mega-impact and a prolonged asteroid shower from a shattered chondritic body in the Middle to Late Ordovician. Accordingly, a distinction has been proposed between steady background conditions (impacts occurring singly and rarely in clusters) and perturbation (bombardment) intervals. Current evidence for an impact trigger has been reviewed in detail for the other four Big Five mass extinctions, but no confirmation has been found. The probability of a prolonged impact-enhanced Late Eocene to Early Oligocene crisis, caused by an asteroid shower, is considered, as well as biotic changes accompanying other major cratering events: the mid-Norian Manicouagan and the end-Jurassic Morokweng structures. In particular, for the Popigai asteroid swarm, implied from paired 100-km-sized craters, and the possible Morokweng-Mjølnir coincidence, the relationships between impact signatures and likely stepwise biotic events are far from conclusive. Even if medium-sized bolide impacts, recorded in ∼40-km-diameter craters, may have initiated near-global climatic hazards, the killing effect is unpredictable due to the diversity of cataclysm severity controls. Also the Ordovician cosmic bombardment did not have any negative influence on the great biodiversification. However, the asteroid swarms may have (by unusual dustiness of the inner Solar System) ultimately triggered or accelerated ice ages in the Late Ordovician and Oligocene, respectively. Overall, this implies a continuum in the biosphere's response to extraterrestrial stimuli.</div><div>Furthermore, a first attempt was made to explain the hidden record of
{"title":"Impact catastrophism versus mass extinctions in retrospective, perspective and prospective: Toward a Phanerozoic impact event stratigraphy","authors":"Grzegorz Racki , Christian Koeberl","doi":"10.1016/j.earscirev.2024.104904","DOIUrl":"10.1016/j.earscirev.2024.104904","url":null,"abstract":"<div><div>Despite several, sometimes prominent propagators, meteorite impact research had a long period of peripheral status until the 1980s. Since then, there has been an intense search for impact-extinction pairs, driven by the rapid acceptance of Alvarez's hypothesis of a catastrophic Chicxulub impact at the end of the Mesozoic era. However, substantial errors have occurred for incompletely identified and/or indirectly dated impact craters in the context of purportedly coeval mass extinctions. For example, supposed giant craters based only on geophysical studies, such as those alleged as evidence of impact-driven end-Permian and Late Ordovician extinctions, are not supported by any real impact evidence (e.g., catastrophic sedimentation) in adjacent areas.</div><div>The updated three-step methodology presents an accurate approach to cause-effect inference in impact catastrophism. It begins with (1) conclusive recognition of impact craters and ejecta, followed by (2) their precise radiometric or biostratigraphic dating, and concludes with (3) assessing the impact's “kill” potential. The impact contribution to widely defined mass extinctions has been falsified based on the latest crater information from the global database and the updated ages of stratigraphic boundaries. In the Phanerozoic, two contrasting collision phenomena occurred: the Chicxulub asteroid mega-impact and a prolonged asteroid shower from a shattered chondritic body in the Middle to Late Ordovician. Accordingly, a distinction has been proposed between steady background conditions (impacts occurring singly and rarely in clusters) and perturbation (bombardment) intervals. Current evidence for an impact trigger has been reviewed in detail for the other four Big Five mass extinctions, but no confirmation has been found. The probability of a prolonged impact-enhanced Late Eocene to Early Oligocene crisis, caused by an asteroid shower, is considered, as well as biotic changes accompanying other major cratering events: the mid-Norian Manicouagan and the end-Jurassic Morokweng structures. In particular, for the Popigai asteroid swarm, implied from paired 100-km-sized craters, and the possible Morokweng-Mjølnir coincidence, the relationships between impact signatures and likely stepwise biotic events are far from conclusive. Even if medium-sized bolide impacts, recorded in ∼40-km-diameter craters, may have initiated near-global climatic hazards, the killing effect is unpredictable due to the diversity of cataclysm severity controls. Also the Ordovician cosmic bombardment did not have any negative influence on the great biodiversification. However, the asteroid swarms may have (by unusual dustiness of the inner Solar System) ultimately triggered or accelerated ice ages in the Late Ordovician and Oligocene, respectively. Overall, this implies a continuum in the biosphere's response to extraterrestrial stimuli.</div><div>Furthermore, a first attempt was made to explain the hidden record of","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"259 ","pages":"Article 104904"},"PeriodicalIF":10.8,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142655603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-30DOI: 10.1016/j.earscirev.2024.104911
Clarence Edward Choi, Jiantao Yu, Jiaqi Zhang
Submarine debris flows occur under the cloak of the sea and are giants among other types of landslides on planet Earth. They pose a significant threat to sustainable offshore development and marine ecosystems. Existing research on these flows mainly rely on back-analyzing field events and conducting miniaturized experiments. However, it is unclear whether the dynamics of miniaturized flows are similar to field ones. In this review, dimensional analysis is used to evaluate laboratory and field data collated from the literature to compare the dynamics of submarine debris flows at different scales. Miniaturized flows are demonstrated to have disproportionately low yield stress and viscosity compared to field flows. The low yield stress is caused by the need to reduce the clay content of a model debris mixture so that it can flow under substantially reduced gravitational driving stresses in laboratory conditions. Consequently, some proposed scaling relationships in the literature derived from laboratory experiments need to be used with caution. Specifically, both the Reynolds and Bingham numbers cannot independently provide a scale-invariant criterion for distinguishing between laminar and turbulent flows. Instead, the Hampton number, with a threshold >0.001, is proposed for the design of the yield stress and clay contents of laboratory flows. Moreover, reduced model viscous stress drastically reduces erosion potential, which limits the existing understanding of the excess fluid pressures generated at the flow-bed interface, and thus flow mobility. The mobility of field flows is generally attributed to hydroplaning. However, this conjecture mainly stems from experiments with impervious boundaries. Such an idealization exaggerates the effects of excess fluid pressures that develop during hydroplaning. An enhanced understanding of the differences in dynamics between field and modeled flows can improve the design of future experiments to model submarine debris flows.
{"title":"Review of the missing link between field and modeled submarine debris flows: Scale effects of physical modeling","authors":"Clarence Edward Choi, Jiantao Yu, Jiaqi Zhang","doi":"10.1016/j.earscirev.2024.104911","DOIUrl":"10.1016/j.earscirev.2024.104911","url":null,"abstract":"<div><p>Submarine debris flows occur under the cloak of the sea and are giants among other types of landslides on planet Earth. They pose a significant threat to sustainable offshore development and marine ecosystems. Existing research on these flows mainly rely on back-analyzing field events and conducting miniaturized experiments. However, it is unclear whether the dynamics of miniaturized flows are similar to field ones. In this review, dimensional analysis is used to evaluate laboratory and field data collated from the literature to compare the dynamics of submarine debris flows at different scales. Miniaturized flows are demonstrated to have disproportionately low yield stress and viscosity compared to field flows. The low yield stress is caused by the need to reduce the clay content of a model debris mixture so that it can flow under substantially reduced gravitational driving stresses in laboratory conditions. Consequently, some proposed scaling relationships in the literature derived from laboratory experiments need to be used with caution. Specifically, both the Reynolds and Bingham numbers cannot independently provide a scale-invariant criterion for distinguishing between laminar and turbulent flows. Instead, the Hampton number, with a threshold >0.001, is proposed for the design of the yield stress and clay contents of laboratory flows. Moreover, reduced model viscous stress drastically reduces erosion potential, which limits the existing understanding of the excess fluid pressures generated at the flow-bed interface, and thus flow mobility. The mobility of field flows is generally attributed to hydroplaning. However, this conjecture mainly stems from experiments with impervious boundaries. Such an idealization exaggerates the effects of excess fluid pressures that develop during hydroplaning. An enhanced understanding of the differences in dynamics between field and modeled flows can improve the design of future experiments to model submarine debris flows.</p></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"258 ","pages":"Article 104911"},"PeriodicalIF":10.8,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142162900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
<div><p>The formation of abyssal serpentinites leads to deep changes of the oceanic lithosphere rheology and geochemistry, hence playing a key role on geodynamic and geochemical cycles. Here we review and discuss the geochemical diversity of serpentinites collected on abyssal floors (i.e., abyssal serpentinites) from different geodynamical settings, namely passive margin, forearc and oceanic spreading ridges. We further divided abyssal serpentinites from spreading ridges according to the tectonic contexts in which they were exhumed, differentiating slow-spreading centres (exhumed within the axial valleys and at oceanic detachments), ultra-slow spreading centres (from amagmatic axial valleys and smooth seafloor), fast spreading axis (mostly from deeps) and large transform faults (all spreading rates).</p><p>The major and trace element composition of abyssal serpentinites is first controlled by melt extraction and melt/rock interaction processes occurring prior to serpentinization. Slow-, fast- spreading ridges and forearc serpentinites are distinguished by low Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> ratios and depleted REE signatures when compared to abyssal serpentinites recovered from ultra-slow spreading ridges, transform faults and passive margins, where magmatic extraction is likely more limited or/and melt/rock reaction prominent. Ultra-slow spreading ridge serpentinites have high Fe<sup>3+</sup>/∑Fe when compared to passive margin and forearc serpentinites, while slow spreading ridge and transform fault serpentinites have intermediate Fe<sup>3+</sup>/∑Fe, close to that of magnetite. This distribution is correlated with MgO/SiO<sub>2</sub> ratios, suggesting that high MgO contents could thwart Fe oxidation, and thus H<sub>2</sub> production, in abyssal environments.</p><p>The presence of mafic units at depth affects the chemical properties (e.g., sulfur activity [<em>a</em>H<sub>2</sub>S], oxygen fugacity (<em>f</em>O<sub>2</sub>)) of the serpentinizing fluids leading to contrasting enrichments of redox sensitive elements (S, U, Eu, Ce, As, Sb) and metals (Zn, Cu) in abyssal serpentinites. At slow-spreading ridges, the circulation of high <em>a</em>H<sub>2</sub>S and low <em>f</em>O<sub>2</sub> fluids, equilibrated with gabbroic rocks, leads to the formation of serpentinites with pronounced Eu anomalies, enrichments of LREE over M-HREE and of As over Sb, and to the storage of metal (Zn, Cu) and sulfide in serpentinites. In contrast, at ultra-slow spreading ridges and at transform faults, the absence of an active magmatic system limits changes in seawater composition prior to serpentinization. The oxidizing conditions favours Ce(IV) (Ce anomalies on REE patterns), and the preferential mobility of Sb(V) over Sb(III) (coupled behaviour between Sb and As), as well as the storage of sulfate over sulfides in rocks. Fast spreading ridge serpentinites present both features with samples having negative Ce anomaly (Ce (IV)) and others with positiv
深海蛇绿岩的形成导致了海洋岩石圈流变学和地球化学的深层变化,因此对地球动力和地球化学循环起着关键作用。在此,我们回顾并讨论了从被动边缘、前弧和大洋扩张脊等不同地球动力学环境中采集的深海海底蛇绿岩(即深海蛇绿岩)的地球化学多样性。我们根据深海蛇绿岩出露的构造背景,进一步划分了扩张脊的深海蛇绿岩,将其分为慢扩张中心(在轴谷内和大洋脱离处出露)、超慢扩张中心(来自变形轴谷和光滑海底)、快速扩张轴(主要来自深海)和大型转换断层(所有扩张速率)。深海蛇绿岩的主要元素和微量元素组成首先受蛇绿岩化之前发生的熔体萃取和熔体/岩石相互作用过程的控制。与从超慢速扩张海脊、转换断层和被动边缘回收的深海蛇绿岩相比,慢速、快速扩张海脊和前弧蛇绿岩的Al2O3/SiO2比率较低,REE特征贫乏,而在超慢速扩张海脊、转换断层和被动边缘,岩浆萃取可能更为有限,或/和熔体/岩石反应更为突出。与被动边缘和前弧蛇纹岩相比,超慢速扩张海脊蛇纹岩具有较高的 Fe3+/∑Fe,而慢速扩张海脊和转换断层蛇纹岩具有中等的 Fe3+/∑Fe,接近磁铁矿的 Fe3+/∑Fe。这种分布与 MgO/SiO2 比率相关,表明在深海环境中,高 MgO 含量可能会阻碍铁的氧化,从而阻碍 H2 的产生、在深海蛇绿岩中,氧化还原敏感元素(S、U、Eu、Ce、As、Sb)和金属(Zn、Cu)的富集形成了鲜明对比。在缓慢扩张的海脊,高 aH2S 和低 fO2 流体与辉长岩平衡循环,形成了具有明显 Eu 异常的蛇绿岩,LREE 元素富集于 M-HREE 元素,As 元素富集于 Sb 元素,金属(Zn、Cu)和硫化物储存在蛇绿岩中。相反,在超慢速扩张海脊和转换断层,由于缺乏活跃的岩浆系统,限制了蛇纹岩化之前海水成分的变化。氧化条件有利于Ce(IV)(REE图案上的Ce异常),有利于Sb(V)而不是Sb(III)的移动(Sb和As之间的耦合行为),以及有利于硫酸盐而不是硫化物在岩石中的储存。快速扩张脊蛇纹岩具有这两种特征,其中一些样品具有负的铈异常(铈(IV)),而另一些样品则具有正的Eu*(Eu(II))。在大洋扩张脊,深海蛇绿岩中的流体移动元素(FME)和非氧化还原敏感元素(如 Cs、Ba、Rb、B 或 Li)是均匀的。被动边缘和弧前蛇绿岩均无 Ce 异常,只有少数弧前样品显示 Eu 异常和中等程度的 LREE 富集。前弧蛇绿岩是地球化学的终成体。在那里,板块衍生流体的影响增强了富含 FME 的蛇绿岩的形成,这些蛇绿岩与富含 CO2 的沉积物衍生流体有很强的亲缘关系(即相对于 Rb 和 Sb,Cs 和 As 分别富集)。
{"title":"A review of abyssal serpentinite geochemistry and geodynamics","authors":"Baptiste Debret , Muriel Andreani , Marguerite Godard","doi":"10.1016/j.earscirev.2024.104910","DOIUrl":"10.1016/j.earscirev.2024.104910","url":null,"abstract":"<div><p>The formation of abyssal serpentinites leads to deep changes of the oceanic lithosphere rheology and geochemistry, hence playing a key role on geodynamic and geochemical cycles. Here we review and discuss the geochemical diversity of serpentinites collected on abyssal floors (i.e., abyssal serpentinites) from different geodynamical settings, namely passive margin, forearc and oceanic spreading ridges. We further divided abyssal serpentinites from spreading ridges according to the tectonic contexts in which they were exhumed, differentiating slow-spreading centres (exhumed within the axial valleys and at oceanic detachments), ultra-slow spreading centres (from amagmatic axial valleys and smooth seafloor), fast spreading axis (mostly from deeps) and large transform faults (all spreading rates).</p><p>The major and trace element composition of abyssal serpentinites is first controlled by melt extraction and melt/rock interaction processes occurring prior to serpentinization. Slow-, fast- spreading ridges and forearc serpentinites are distinguished by low Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> ratios and depleted REE signatures when compared to abyssal serpentinites recovered from ultra-slow spreading ridges, transform faults and passive margins, where magmatic extraction is likely more limited or/and melt/rock reaction prominent. Ultra-slow spreading ridge serpentinites have high Fe<sup>3+</sup>/∑Fe when compared to passive margin and forearc serpentinites, while slow spreading ridge and transform fault serpentinites have intermediate Fe<sup>3+</sup>/∑Fe, close to that of magnetite. This distribution is correlated with MgO/SiO<sub>2</sub> ratios, suggesting that high MgO contents could thwart Fe oxidation, and thus H<sub>2</sub> production, in abyssal environments.</p><p>The presence of mafic units at depth affects the chemical properties (e.g., sulfur activity [<em>a</em>H<sub>2</sub>S], oxygen fugacity (<em>f</em>O<sub>2</sub>)) of the serpentinizing fluids leading to contrasting enrichments of redox sensitive elements (S, U, Eu, Ce, As, Sb) and metals (Zn, Cu) in abyssal serpentinites. At slow-spreading ridges, the circulation of high <em>a</em>H<sub>2</sub>S and low <em>f</em>O<sub>2</sub> fluids, equilibrated with gabbroic rocks, leads to the formation of serpentinites with pronounced Eu anomalies, enrichments of LREE over M-HREE and of As over Sb, and to the storage of metal (Zn, Cu) and sulfide in serpentinites. In contrast, at ultra-slow spreading ridges and at transform faults, the absence of an active magmatic system limits changes in seawater composition prior to serpentinization. The oxidizing conditions favours Ce(IV) (Ce anomalies on REE patterns), and the preferential mobility of Sb(V) over Sb(III) (coupled behaviour between Sb and As), as well as the storage of sulfate over sulfides in rocks. Fast spreading ridge serpentinites present both features with samples having negative Ce anomaly (Ce (IV)) and others with positiv","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"258 ","pages":"Article 104910"},"PeriodicalIF":10.8,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S001282522400237X/pdfft?md5=2510cc0120060dbc7fb50ca53ba321ae&pid=1-s2.0-S001282522400237X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142229442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-28DOI: 10.1016/j.earscirev.2024.104909
Sérgio P. Neves
<div><p>In a pre-Mesozoic drift reconstitution, the Borborema Province in northeastern Brazil connects with the Central African Fold belt to the East and with the Nigerian and Tuareg shields to the North. Therefore, the Borborema Province is an important component to consider in the context of the amalgamation of western Gondwana. The tectonic setting of the Borborema Province has been debated, with some workers advocating for the accretion of allochthonous terranes and others arguing for the decratonization of a large continental landmass followed by the re-accretion of the fragments, either involving or not involving formation of large oceanic domains between them. Resolving the tectonic setting of the Borborema Province has implications for correlations with other Brasiliano-Pan-African belts and supercontinent reconstructions. This paper discusses proposed evidence for oceanic subduction, arc magmatism, and oceanic basin closure based on a comprehensive literature review. This information is integrated with data from the African counterparts of the Borborema Province to provide a geodynamic model for the Neoproterozoic evolution of this portion of western Gondwana. The main evidence for subduction is provided by ultra-high-pressure rocks and c. 660–640 Ma-old intermediate metaigneous rocks with relatively young (1.4–1.0 Ga) whole-rock Sm<img>Nd and zircon Hf model ages in the northwestern part of the Borborema Province. However, a key aspect of the Brasiliano Orogeny in most of the Borborema Province is its synchronous nature. Deposition of predominantly siliciclastic sediments throughout the province ended slightly before or partly coeval with c. 640–610 Ma tectonothermal activity and early orogenic magmatism. Plutons and batholiths emplaced during this age interval comprise predominantly alkali-calcic monzogranites and syenogranites with a large contribution of Paleoproterozoic sources. Together with the absence of juvenile oceanic crust remnants and calc-alkaline metavolcanic rocks, it is thus concluded that (i) widespread crustal extension was almost immediately followed by contractional deformation and regional metamorphism, and (ii) crustal reworking was the dominant process, with limited formation and consumption of oceanic lithosphere. A similar conclusion applies to the Nigerian Shield and the central and southern parts of the Central African Fold Belt. In contrast, large volumes of juvenile crust are found in the Tuareg Shield and in the northern part of the Central African Fold Belt. The model envisions that no large oceanic domain separated the São Francisco/Congo Craton from the Amazonian/West Africa Craton in the middle Neoproterozoic, which were part of the Atlantica paleocontinent since c. 2.0 Ga. Extensional conditions in the Borborema Province and its African counterparts are attributed to far-field stresses transmitted to the interior of Atlantica by an outwardly, N-dipping subduction system. The onset of the contractional
在前中生代漂移重组过程中,巴西东北部的博博雷马省与东部的中非褶皱带以及北部的尼日利亚和图阿雷格地盾相连。因此,博尔博雷马省是冈瓦纳西部合并背景下需要考虑的一个重要组成部分。关于博尔博雷马省的构造背景一直存在争议,一些学者主张异生地块的增生,而另一些学者则认为是一个大的大陆地块的解克拉化,然后碎片重新增生,在碎片之间形成或不形成大的洋域。解决博博雷马省的构造环境问题对与其他巴西-泛非带和超大陆重建的相关性有影响。本文根据全面的文献综述,讨论了大洋俯冲、弧岩浆作用和大洋盆地封闭的拟议证据。这些信息与博博雷马省非洲对应地区的数据相结合,为冈瓦纳西部这部分地区的新近新生代演化提供了一个地球动力学模型。博博雷马省西北部的超高压岩石和约 660-640 兆年前的中元古代岩石提供了俯冲作用的主要证据,这些岩石具有相对年轻(1.4-1.0 Ga)的全岩 SmNd 和锆石 Hf 模型年龄。然而,在博博雷马省的大部分地区,巴西造山运动的一个重要方面是其同步性。整个博博雷马省以硅质沉积物为主的沉积略早于或部分与约 640-610 Ma 的构造热活动和早期造山岩浆活动同时结束。在这一时代区间内沉积的岩浆岩和浴积岩主要由碱钙质单斜花岗岩和正长花岗岩组成,其中有大量的古新生代岩浆岩。再加上没有幼年大洋地壳残余和钙碱性变质岩,因此得出结论:(i) 广泛的地壳延伸几乎紧随收缩变形和区域变质作用之后;(ii) 地壳再加工是主要过程,大洋岩石圈的形成和消耗有限。尼日利亚地盾和中非褶皱带中部和南部也得出了类似的结论。相反,在图阿雷格地盾和中部非洲褶皱带北部发现了大量幼壳。根据该模型的设想,在新元古代中期,圣弗朗西斯科/刚果克拉通与亚马孙/西非克拉通之间没有大洋域的分隔,自约 2.0 Ga 以来,这两个克拉通一直是亚特兰蒂斯古陆的一部分。博博雷马省及其非洲同类地区的延伸条件归因于一个向外、N倾的俯冲系统向亚特兰蒂斯内部传递的远场应力。收缩阶段的开始是由于图阿雷格地盾的不同组成部分向亚特兰提卡北部(其东西向缝合带现在被撒哈拉沙漠所掩盖)的增生,以及西非和撒哈拉火山口分别向东南方向和向西南方向的联合缩进。
{"title":"How many oceans closed during the Brasiliano Cycle in northeastern Brazil? Implications for the amalgamation of western Gondwana","authors":"Sérgio P. Neves","doi":"10.1016/j.earscirev.2024.104909","DOIUrl":"10.1016/j.earscirev.2024.104909","url":null,"abstract":"<div><p>In a pre-Mesozoic drift reconstitution, the Borborema Province in northeastern Brazil connects with the Central African Fold belt to the East and with the Nigerian and Tuareg shields to the North. Therefore, the Borborema Province is an important component to consider in the context of the amalgamation of western Gondwana. The tectonic setting of the Borborema Province has been debated, with some workers advocating for the accretion of allochthonous terranes and others arguing for the decratonization of a large continental landmass followed by the re-accretion of the fragments, either involving or not involving formation of large oceanic domains between them. Resolving the tectonic setting of the Borborema Province has implications for correlations with other Brasiliano-Pan-African belts and supercontinent reconstructions. This paper discusses proposed evidence for oceanic subduction, arc magmatism, and oceanic basin closure based on a comprehensive literature review. This information is integrated with data from the African counterparts of the Borborema Province to provide a geodynamic model for the Neoproterozoic evolution of this portion of western Gondwana. The main evidence for subduction is provided by ultra-high-pressure rocks and c. 660–640 Ma-old intermediate metaigneous rocks with relatively young (1.4–1.0 Ga) whole-rock Sm<img>Nd and zircon Hf model ages in the northwestern part of the Borborema Province. However, a key aspect of the Brasiliano Orogeny in most of the Borborema Province is its synchronous nature. Deposition of predominantly siliciclastic sediments throughout the province ended slightly before or partly coeval with c. 640–610 Ma tectonothermal activity and early orogenic magmatism. Plutons and batholiths emplaced during this age interval comprise predominantly alkali-calcic monzogranites and syenogranites with a large contribution of Paleoproterozoic sources. Together with the absence of juvenile oceanic crust remnants and calc-alkaline metavolcanic rocks, it is thus concluded that (i) widespread crustal extension was almost immediately followed by contractional deformation and regional metamorphism, and (ii) crustal reworking was the dominant process, with limited formation and consumption of oceanic lithosphere. A similar conclusion applies to the Nigerian Shield and the central and southern parts of the Central African Fold Belt. In contrast, large volumes of juvenile crust are found in the Tuareg Shield and in the northern part of the Central African Fold Belt. The model envisions that no large oceanic domain separated the São Francisco/Congo Craton from the Amazonian/West Africa Craton in the middle Neoproterozoic, which were part of the Atlantica paleocontinent since c. 2.0 Ga. Extensional conditions in the Borborema Province and its African counterparts are attributed to far-field stresses transmitted to the interior of Atlantica by an outwardly, N-dipping subduction system. The onset of the contractional ","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"257 ","pages":"Article 104909"},"PeriodicalIF":10.8,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142096106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-23DOI: 10.1016/j.earscirev.2024.104905
Oussama Moutbir , El Mostafa Aarab , Nasrrddine Youbi , Abdelhak Ait Lahna , Colombo Celso Gaeta Tassinari , João Mata , Ross N. Mitchell , Andreas Gärtner , Alvar Soesoo , Mohamed Khalil Bensalah , Abderrahmane Soulaimani , Moulay Ahmed Boumehdi , Ulf Linnemann
<div><p>The migration and composition of magmatism over time can provide important insights into the tectonic evolution of an orogen like the Variscan Belt. To identify Large Igneous Provinces (LIPs), key criteria include large magmatic volume, intraplate-origin volcanic geochemistry, and significant plumbing systems. Based on such criteria, we present evidence of ca. 347–330 Ma LIP “fragments” in the South-Western Branch of the Variscan Belt (Morocco), exemplified by the Variscan Central Jebilet Massif. The interpretations are based on four new zircon U–Pb ages obtained by sensitive high-resolution ion microprobe (SHRIMP), a geochemical database of Carboniferous mafic sills, dykes, and gabbroic intrusions together, with subordinate layered ultramafic intrusions, silicic intrusive and volcanic rocks of Central Jebilet Massif, combined with previously published and unpublished data including Sr–Nd isotope analyses. Geochemistry data indicate that the early Carboniferous magmatism of the Jebilet Massif is plume-related. Furthermore, primary magmas of the mafic rocks were generated in an intraplate setting and derived by partial melting of complex sources involving asthenosphere, lithospheric mantle, and subducting slab components (dead subduction slabs), and were modified by crustal contamination during ascent. Magmatic rocks in the same stratigraphic position also occur in other Carboniferous basins including Western Meseta (Rehamna and Moroccan Central Massif). The newly obtained and compiled zircon U–Pb ages from Western Meseta rocks, encompassing an area of ∼400,000 km<sup>2</sup>, indicate that magmatism occurred between ca. 347–330 Ma, coeval with volcanic activity in the Eastern Meseta in northeastern Morocco. The similar emplacement ages, in combination with the tectonic reconstruction of northwestern Gondwana at ca. 330 Ma, suggest that the igneous subprovinces of the Jebilet, Rehamna, and Moroccan Central Massif in Western Meseta, along with Tazekka, Debdou, and Mekkam in Eastern Meseta, the igneous rocks of the Maritimes (Magdalen) Basin, the St. Jean du Doigt bimodal layered intrusion (Brittany, France), and other equivalents such as the Iberian Pyrite Belt and the Southern Vosges magmatism, may represent the eroded and/or deformed remnants of a Large Igneous Province (LIP), which we name here the North Gondwana–Avalonia (NGA) LIP. We argue that this newly identified LIP was formed by a mantle plume that may have played a role in the breakup along the northwestern margin of the precursor megacontinent Gondwana and the assembly of Pangea. The plume was likely centered under the thick lithosphere of Avalonia. The large-scale sublithospheric plume-flow channeling from the plume head led to the development of widespread tholeiitic/alkaline magmatism in the thinned lithosphere of Western Meseta, interpreted here as a large thin-spot domain, and calc-alkaline/alkaline magmatism in the thickened lithosphere of the Eastern Meseta. The mantle pl
岩浆活动随时间的迁移和组成可以为了解像瓦里肯带这样的造山带的构造演化提供重要信息。要识别大火成岩带(LIPs),关键标准包括岩浆量大、板块内起源的火山地球化学和重要的管道系统。根据这些标准,我们提出了在瓦利斯坎带西南分支(摩洛哥)发现的约 347-330 Ma LIP "碎片 "的证据,瓦利斯坎中央杰比勒特丘陵就是一个例子。解释的依据是通过灵敏高分辨率离子微探针(SHRIMP)获得的四个新的锆石 U-Pb 年龄,石炭纪岩浆岩、岩体和辉长岩侵入体的地球化学数据库,以及中央杰比勒特山丘的附属层状超基性侵入体、硅侵入体和火山岩,并结合以前发表和未发表的数据(包括锶钕同位素分析)。地球化学数据表明,杰比勒特山丘的石炭纪早期岩浆活动与羽岩有关。此外,岩浆岩的原生岩浆是在板内环境中产生的,由涉及星体层、岩石圈地幔和俯冲板块成分(死俯冲板块)的复杂来源部分熔化而成,并在上升过程中受到地壳污染的改变。地层位置相同的岩浆岩也出现在其他石炭纪盆地,包括西梅塞塔(雷哈姆纳和摩洛哥中央丘)。新近从西梅塞塔(Western Meseta)岩石中获得并汇编的锆石 U-Pb 年龄表明,岩浆活动发生在约 347-330 Ma 之间,与摩洛哥东北部东梅塞塔(Eastern Meseta)的火山活动同时发生。类似的火山喷发年龄与冈瓦纳西北部约 330 Ma 的构造重建相结合,表明火成岩活动发生在约 347-330 Ma 之间。330 Ma,表明西梅塞塔的 Jebilet、Rehamna 和摩洛哥中央丘陵的火成岩子产区,以及东梅塞塔的 Tazekka、Debdou 和 Mekkam,Maritimes(马格达林)盆地的火成岩,St.Jean du Doigt双峰层状侵入体(法国布列塔尼),以及伊比利亚黄铁矿带和南孚日山岩浆岩等其他类似岩体,可能代表了一个大型火成岩省(LIP)的侵蚀和/或变形遗迹,我们在此将其命名为北冈瓦纳-阿瓦鲁尼亚(NGA)LIP。我们认为,这个新发现的大火成岩带是由一个地幔羽流形成的,该羽流可能在前巨型大陆冈瓦纳西北边缘的断裂和潘加大陆的形成过程中发挥了作用。该地幔柱可能位于阿瓦鲁尼亚厚岩石圈的中心。来自羽流头部的大尺度岩石圈下羽流通道,导致在西梅塞塔变薄的岩石圈(这里被解释为一个大的薄点域)中形成了广泛的沸石/碱性岩浆活动,并在东梅塞塔变厚的岩石圈中形成了钙碱性/碱性岩浆活动。地幔羽流可能在大约 390-330 Ma(Maritimes 事件)、大约 370-338 Ma(Iberia 事件)、大约 347-330 Ma(Meseta 事件)以及大约 300 Ma、290-275 Ma 和 250 Ma 的欧洲西北非岩浆省(EUNWA 或 EUNWAMP)时期最为活跃,这些时期是这些地区产生大部分瓦利斯坎岩浆岩的时期。
{"title":"Evidence of a large igneous province at ca. 347–330 Ma along the northern Gondwana margin linked to the assembly of Pangea: Insights from U–Pb zircon geochronology and geochemistry of the South-Western Branch of the Variscan Belt (Morocco)","authors":"Oussama Moutbir , El Mostafa Aarab , Nasrrddine Youbi , Abdelhak Ait Lahna , Colombo Celso Gaeta Tassinari , João Mata , Ross N. Mitchell , Andreas Gärtner , Alvar Soesoo , Mohamed Khalil Bensalah , Abderrahmane Soulaimani , Moulay Ahmed Boumehdi , Ulf Linnemann","doi":"10.1016/j.earscirev.2024.104905","DOIUrl":"10.1016/j.earscirev.2024.104905","url":null,"abstract":"<div><p>The migration and composition of magmatism over time can provide important insights into the tectonic evolution of an orogen like the Variscan Belt. To identify Large Igneous Provinces (LIPs), key criteria include large magmatic volume, intraplate-origin volcanic geochemistry, and significant plumbing systems. Based on such criteria, we present evidence of ca. 347–330 Ma LIP “fragments” in the South-Western Branch of the Variscan Belt (Morocco), exemplified by the Variscan Central Jebilet Massif. The interpretations are based on four new zircon U–Pb ages obtained by sensitive high-resolution ion microprobe (SHRIMP), a geochemical database of Carboniferous mafic sills, dykes, and gabbroic intrusions together, with subordinate layered ultramafic intrusions, silicic intrusive and volcanic rocks of Central Jebilet Massif, combined with previously published and unpublished data including Sr–Nd isotope analyses. Geochemistry data indicate that the early Carboniferous magmatism of the Jebilet Massif is plume-related. Furthermore, primary magmas of the mafic rocks were generated in an intraplate setting and derived by partial melting of complex sources involving asthenosphere, lithospheric mantle, and subducting slab components (dead subduction slabs), and were modified by crustal contamination during ascent. Magmatic rocks in the same stratigraphic position also occur in other Carboniferous basins including Western Meseta (Rehamna and Moroccan Central Massif). The newly obtained and compiled zircon U–Pb ages from Western Meseta rocks, encompassing an area of ∼400,000 km<sup>2</sup>, indicate that magmatism occurred between ca. 347–330 Ma, coeval with volcanic activity in the Eastern Meseta in northeastern Morocco. The similar emplacement ages, in combination with the tectonic reconstruction of northwestern Gondwana at ca. 330 Ma, suggest that the igneous subprovinces of the Jebilet, Rehamna, and Moroccan Central Massif in Western Meseta, along with Tazekka, Debdou, and Mekkam in Eastern Meseta, the igneous rocks of the Maritimes (Magdalen) Basin, the St. Jean du Doigt bimodal layered intrusion (Brittany, France), and other equivalents such as the Iberian Pyrite Belt and the Southern Vosges magmatism, may represent the eroded and/or deformed remnants of a Large Igneous Province (LIP), which we name here the North Gondwana–Avalonia (NGA) LIP. We argue that this newly identified LIP was formed by a mantle plume that may have played a role in the breakup along the northwestern margin of the precursor megacontinent Gondwana and the assembly of Pangea. The plume was likely centered under the thick lithosphere of Avalonia. The large-scale sublithospheric plume-flow channeling from the plume head led to the development of widespread tholeiitic/alkaline magmatism in the thinned lithosphere of Western Meseta, interpreted here as a large thin-spot domain, and calc-alkaline/alkaline magmatism in the thickened lithosphere of the Eastern Meseta. The mantle pl","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"258 ","pages":"Article 104905"},"PeriodicalIF":10.8,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142238573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-23DOI: 10.1016/j.earscirev.2024.104908
Regina Katsman
Methane (CH4) is a potent greenhouse gas that has a major impact on Earth's climate. CH4 is accommodated in discrete bubbles in aquatic muds, whose sizes greatly exceed the pore size of the hosting sediment. This critical review examines the mechanics of CH4 gas in consolidated aquatic muds at the scale of a single bubble and at a macroscale of gassy sediments, obtained from lab experiments, field observations, and numerical and analytical modeling. Linear elastic fracture mechanics (LEFM) theory is shown to control the single bubble shape, size, morphology, and inner pressure evolution over its entire life cycle. Reviewed implications focus on the effects of the inner bubble pressure on its solute exchange with ambient pore waters; on the dynamic water load effect (e.g., waves, tides) on the bubble growth rate and its release from sediment into the water column; and on competitive bubble pair growth in the aquatic muds, the process that presumably shapes the bubble size distribution pattern in muds. Alternatively, gassy sediment effective mechanical and physical characteristics and effective gassy media theories are examined at the macroscale, which makes them suitable for remote sensing acoustic applications. This review indicates, however, that most of the developed macroscale effective medium theories rely on the cumulative sediment gas content. Moreover, no theory for proper upscaling of the entire set of the microscale single bubble descriptors addressed in this review – bubble size distribution, their orientations and spatial locations, and inner bubble pressures – to the effective medium mechanical properties of gassy muds, exists. This review will serve, therefore, as a basis for the improved upscaling, while preserving the basic microscale bubble descriptors, their growth physics, and controls. Laying this foundation will enhance the accuracy of the acoustic applications. Improved assessment of sediment gas retention based on this upscaling will contribute to geohazard prediction and should reduce a long-persisting uncertainty related to CH4 fluxes from the aquatic sediments.
{"title":"Mechanics of methane bubbles in consolidated aquatic muds","authors":"Regina Katsman","doi":"10.1016/j.earscirev.2024.104908","DOIUrl":"10.1016/j.earscirev.2024.104908","url":null,"abstract":"<div><p>Methane (CH<sub>4</sub>) is a potent greenhouse gas that has a major impact on Earth's climate. CH<sub>4</sub> is accommodated in discrete bubbles in aquatic muds, whose sizes greatly exceed the pore size of the hosting sediment. This critical review examines the mechanics of CH<sub>4</sub> gas in consolidated aquatic muds at the scale of a single bubble and at a macroscale of gassy sediments, obtained from lab experiments, field observations, and numerical and analytical modeling. Linear elastic fracture mechanics (LEFM) theory is shown to control the single bubble shape, size, morphology, and inner pressure evolution over its entire life cycle. Reviewed implications focus on the effects of the inner bubble pressure on its solute exchange with ambient pore waters; on the dynamic water load effect (e.g., waves, tides) on the bubble growth rate and its release from sediment into the water column; and on competitive bubble pair growth in the aquatic muds, the process that presumably shapes the bubble size distribution pattern in muds. Alternatively, gassy sediment effective mechanical and physical characteristics and effective gassy media theories are examined at the macroscale, which makes them suitable for remote sensing acoustic applications. This review indicates, however, that most of the developed macroscale effective medium theories rely on the cumulative sediment gas content. Moreover, no theory for proper upscaling of the entire set of the microscale single bubble descriptors addressed in this review – bubble size distribution, their orientations and spatial locations, and inner bubble pressures – to the effective medium mechanical properties of gassy muds, exists. This review will serve, therefore, as a basis for the improved upscaling, while preserving the basic microscale bubble descriptors, their growth physics, and controls. Laying this foundation will enhance the accuracy of the acoustic applications. Improved assessment of sediment gas retention based on this upscaling will contribute to geohazard prediction and should reduce a long-persisting uncertainty related to CH<sub>4</sub> fluxes from the aquatic sediments.</p></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"257 ","pages":"Article 104908"},"PeriodicalIF":10.8,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-22DOI: 10.1016/j.earscirev.2024.104907
Haiyang Zhang, Muhammad Arif
Geological storage of CO2 is a promising technique to mitigate anthropogenic CO2 emissions. The effectiveness of CO2 storage in the subsurface formations relies on various trapping mechanisms that immobilize the injected CO2. Among these mechanisms, residual trapping has been identified as a critical factor, closely associated with residual CO2 saturation. The extent of residual CO2 saturation is strongly influenced by the petrophysical physicochemical and hydrodynamic properties of CO2/fluid/rock systems and operational conditions, thereby governing the overall residual trapping efficiency.
This article reviews the published experimental datasets on the initial and residual CO2 saturation and analyzes the corresponding trapping efficiency for a range of in-situ CO2/fluid/rock systems. We explore the factors that influence trapping efficiency, including wettability, rock type, rock properties, and flow rate. The gas saturations and trapping efficiencies of different gas types (i.e., CO2, N2, and H2) are also discussed. Finally, we present the knowledge gaps and outline prospects for future research. This review establishes a state-of-art data repository of gas saturations in different conditions, enhancing our understanding of residual trapping in subsurface gas storage.
二氧化碳的地质封存是减少人为二氧化碳排放的一项前景广阔的技术。在地下地层中封存二氧化碳的有效性取决于各种固定注入的二氧化碳的捕集机制。在这些机制中,残余捕集被认为是一个关键因素,与残余二氧化碳饱和度密切相关。残余 CO2 饱和度受 CO2/流体/岩石系统的岩石物理化学和流体力学性质以及作业条件的影响很大,从而制约着整体残余捕集效率。本文回顾了已发表的关于初始和残余 CO2 饱和度的实验数据集,并分析了一系列原位 CO2/流体/岩石系统的相应捕集效率。我们探讨了影响捕集效率的因素,包括润湿性、岩石类型、岩石性质和流速。我们还讨论了不同气体类型(即 CO2、N2 和 H2)的气体饱和度和捕集效率。最后,我们提出了知识差距,并概述了未来研究的前景。本综述建立了不同条件下气体饱和度的最新数据资源库,加深了我们对地下储气库残余气体捕集的理解。
{"title":"Reply to Discussion: “Haiyang Zhang and Muhammad Arif. Residual trapping capacity of subsurface systems for geological storage of CO2: Measurement techniques, meta-analysis of influencing factors, and future outlook. Earth-Science Reviews (2024): 104764.”","authors":"Haiyang Zhang, Muhammad Arif","doi":"10.1016/j.earscirev.2024.104907","DOIUrl":"10.1016/j.earscirev.2024.104907","url":null,"abstract":"<div><p>Geological storage of CO<sub>2</sub> is a promising technique to mitigate anthropogenic CO<sub>2</sub> emissions. The effectiveness of CO<sub>2</sub> storage in the subsurface formations relies on various trapping mechanisms that immobilize the injected CO<sub>2</sub>. Among these mechanisms, residual trapping has been identified as a critical factor, closely associated with residual CO<sub>2</sub> saturation. The extent of residual CO<sub>2</sub> saturation is strongly influenced by the petrophysical physicochemical and hydrodynamic properties of CO<sub>2</sub>/fluid/rock systems and operational conditions, thereby governing the overall residual trapping efficiency.</p><p>This article reviews the published experimental datasets on the initial and residual CO<sub>2</sub> saturation and analyzes the corresponding trapping efficiency for a range of in-situ CO<sub>2</sub>/fluid/rock systems. We explore the factors that influence trapping efficiency, including wettability, rock type, rock properties, and flow rate. The gas saturations and trapping efficiencies of different gas types (i.e., CO<sub>2</sub>, N<sub>2</sub>, and H<sub>2</sub>) are also discussed. Finally, we present the knowledge gaps and outline prospects for future research. This review establishes a state-of-art data repository of gas saturations in different conditions, enhancing our understanding of residual trapping in subsurface gas storage.</p></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"257 ","pages":"Article 104907"},"PeriodicalIF":10.8,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142049758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-22DOI: 10.1016/j.earscirev.2024.104903
Huifang Guo , Xi Chen , Hanwei Yao , Yinggang Zhang , Benjamin J.W. Mills , Kaibo Han , Shujuan Wu , Yida Yang , Zihao Wang , David B. Kemp
The Cenomanian-Turonian Oceanic Anoxic Event 2 (OAE 2, ca. 94 Ma) is characterized by a marked positive carbon isotope excursion (CIE) recorded in global marine basins. This CIE results from a global-scale increase in organic matter burial, facilitated by high productivity and seawater deoxygenation. To date, however, the precise pattern of changes in the burial rate of organic matter through the event has not been well constrained. In this work, we present a compilation of data from 42 globally distributed OAE 2 sites, as well as organic carbon isotope (13Corg), total organic carbon (TOC), and trace element concentration data from a new OAE 2 interval in southern Tibet, China. In southern Tibet, the absence of redox-sensitive trace element enrichment through OAE 2 indicates prevailing oxic conditions. Organic carbon (OC) mass accumulation rate (MAR) at this site decreased from the lower part of the CIE to the upper part, in contrast to an approximate doubling of organic carbon MAR in the upper part observed globally. This result, coupled with detailed analysis of the compilation, shows that redox was a key factor controlling organic burial rates during OAE 2, with OC MAR scaling positively with increasing deoxygenation. Leveraging a biogeochemical model to simulate these data suggets that 5–20% of the seafloor became anoxic during OAE 2, and that this deoxygenation was accompanied by 100% to 200% increase in global seawater P concentration. Our findings indicate that during OAE 2, elevated nutrient levels may have resulted from enhanced recycling from sediments under reducing conditions, sustaining intensified primary production and subsequent organic carbon export and burial.
{"title":"Quantifying the pattern of organic carbon burial through Cretaceous Oceanic Anoxic Event 2","authors":"Huifang Guo , Xi Chen , Hanwei Yao , Yinggang Zhang , Benjamin J.W. Mills , Kaibo Han , Shujuan Wu , Yida Yang , Zihao Wang , David B. Kemp","doi":"10.1016/j.earscirev.2024.104903","DOIUrl":"10.1016/j.earscirev.2024.104903","url":null,"abstract":"<div><p>The Cenomanian-Turonian Oceanic Anoxic Event 2 (OAE 2, ca. 94 Ma) is characterized by a marked positive carbon isotope excursion (CIE) recorded in global marine basins. This CIE results from a global-scale increase in organic matter burial, facilitated by high productivity and seawater deoxygenation. To date, however, the precise pattern of changes in the burial rate of organic matter through the event has not been well constrained. In this work, we present a compilation of data from 42 globally distributed OAE 2 sites, as well as organic carbon isotope (<span><math><mi>δ</mi></math></span><sup>13</sup>C<sub>org</sub>), total organic carbon (TOC), and trace element concentration data from a new OAE 2 interval in southern Tibet, China. In southern Tibet, the absence of redox-sensitive trace element enrichment through OAE 2 indicates prevailing oxic conditions. Organic carbon (OC) mass accumulation rate (MAR) at this site decreased from the lower part of the CIE to the upper part, in contrast to an approximate doubling of organic carbon MAR in the upper part observed globally. This result, coupled with detailed analysis of the compilation, shows that redox was a key factor controlling organic burial rates during OAE 2, with OC MAR scaling positively with increasing deoxygenation. Leveraging a biogeochemical model to simulate these data suggets that 5–20% of the seafloor became anoxic during OAE 2, and that this deoxygenation was accompanied by 100% to 200% increase in global seawater P concentration. Our findings indicate that during OAE 2, elevated nutrient levels may have resulted from enhanced recycling from sediments under reducing conditions, sustaining intensified primary production and subsequent organic carbon export and burial.</p></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"257 ","pages":"Article 104903"},"PeriodicalIF":10.8,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-18DOI: 10.1016/j.earscirev.2024.104901
Andrea Sembroni , Claudio Faccenna , Thorsten W. Becker , Paola Molin
The East Africa - Arabia topographic swell is an anomalously high-elevation region of ∼4000 km long (from southern Ethiopia to Jordan) and ∼ 1500 km wide (from Egypt to Saudi Arabia) extent. The swell is dissected by the Main Ethiopian, Red Sea, and Gulf of Aden rifts, and characterized by widespread basaltic volcanic deposits emplaced from the Eocene to the present. Geochemical and geophysical data confirm the involvement of mantle processes in swell formation; however, they have not been able to fully resolve some issues, e.g., regarding the number and location of plumes and uplift patterns. This study addresses these questions and provides a general evolutionary model of the region by focusing on the present topographic configuration through a quantitative analysis and correlating long and intermediate wavelength features with mantle and rifting processes. Moreover, the isostatic and dynamic components of topography have been evaluated considering a range of seismic tomographic models for the latter. When interpreted jointly with geological data including volcanic deposits, the constraints do imply causation by a single process which shaped the past and present topography of the study area: the upwelling of the Afar superplume. Once hot mantle material reached the base of the lithosphere below the Horn of Africa during the Late Eocene, the plume flowed laterally toward the Levant area guided by pre-existing discontinuities in the Early Miocene. Plume material reached the Anatolian Plateau in the Late Miocene after slab break-off and the consequent formation of a slab window. During plume material advance, buoyancy forces led to the formation of the topographic swell and tilting of the Arabia Peninsula. The persistence of mantle support beneath the study area for tens of million years also affected the formation and evolution of the Nile and Euphrates-Tigris fluvial networks. Subsequently, surface processes, tectonics, and volcanism partly modified the initial topography and shaped the present-day landscape.
{"title":"The uplift of the East Africa - Arabia swell","authors":"Andrea Sembroni , Claudio Faccenna , Thorsten W. Becker , Paola Molin","doi":"10.1016/j.earscirev.2024.104901","DOIUrl":"10.1016/j.earscirev.2024.104901","url":null,"abstract":"<div><p>The East Africa - Arabia topographic swell is an anomalously high-elevation region of ∼4000 km long (from southern Ethiopia to Jordan) and ∼ 1500 km wide (from Egypt to Saudi Arabia) extent. The swell is dissected by the Main Ethiopian, Red Sea, and Gulf of Aden rifts, and characterized by widespread basaltic volcanic deposits emplaced from the Eocene to the present. Geochemical and geophysical data confirm the involvement of mantle processes in swell formation; however, they have not been able to fully resolve some issues, e.g., regarding the number and location of plumes and uplift patterns. This study addresses these questions and provides a general evolutionary model of the region by focusing on the present topographic configuration through a quantitative analysis and correlating long and intermediate wavelength features with mantle and rifting processes. Moreover, the isostatic and dynamic components of topography have been evaluated considering a range of seismic tomographic models for the latter. When interpreted jointly with geological data including volcanic deposits, the constraints do imply causation by a single process which shaped the past and present topography of the study area: the upwelling of the Afar superplume. Once hot mantle material reached the base of the lithosphere below the Horn of Africa during the Late Eocene, the plume flowed laterally toward the Levant area guided by pre-existing discontinuities in the Early Miocene. Plume material reached the Anatolian Plateau in the Late Miocene after slab break-off and the consequent formation of a slab window. During plume material advance, buoyancy forces led to the formation of the topographic swell and tilting of the Arabia Peninsula. The persistence of mantle support beneath the study area for tens of million years also affected the formation and evolution of the Nile and Euphrates-Tigris fluvial networks. Subsequently, surface processes, tectonics, and volcanism partly modified the initial topography and shaped the present-day landscape.</p></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"257 ","pages":"Article 104901"},"PeriodicalIF":10.8,"publicationDate":"2024-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0012825224002289/pdfft?md5=c84fbe63fb920ffba7310b61e0499016&pid=1-s2.0-S0012825224002289-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142043746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}