首页 > 最新文献

Earth-Science Reviews最新文献

英文 中文
Guidelines for producing integrated 210Pb and 14C age-models 制作综合210Pb和14C年龄模型的指南
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-17 DOI: 10.1016/j.earscirev.2025.105301
Joan-Albert Sanchez-Cabeza , Marco A. Aquino-López , Maarten Blaauw , Ana Carolina Ruiz-Fernández , Johanna L.J. Jupin , Lysanna Anderson , Clarke A. Knight , Marie Rhondelle Champagne , Nicole K. Sanderson , Simon Goring , J. Andrés Christen
<div><div>Accurate reconstructions of past environmental changes are crucial in paleoecological research and require reliable chronologies of sedimentary archives. Establishing robust age-models and obtaining the most appropriate proxies for analysis is a complex scientific endeavor, requiring extensive resources and collaboration among specialists, including radiochronologists. Radiometric dating methods, such as <sup>210</sup>Pb and radiocarbon (<sup>14</sup>C), are frequently employed to establish chronologies in aquatic sedimentary deposits and peat bogs. In this study, we review key aspects of sampling, analysis, and the principles underlying <sup>210</sup>Pb and <sup>14</sup>C age-models, focusing on methods for developing robust joint chronologies for paleoenvironmental research. Drawing largely from the authors' experiences and group discussions during and after a scientific workshop in 2022, we discuss important considerations for site selection, sampling strategies, and radiometric dating to construct integrated <sup>210</sup>Pb −<sup>14</sup>C age-models. Using expert consensus, this group – called Paleostats – aims to provide a set of best practices for other geochronologists with this methods paper. Among our conclusions, we emphasize the importance of accounting for site-specific factors such as prior information on sedimentation rates to establish appropriate sampling and analytical strategies. The use of appropriate coring devices can minimize disturbance to sediments and ensure the core surface remains intact and preserved until sectioning. Where excess <sup>210</sup>Pb (<sup>210</sup>Pb<sub>ex</sub>) is expected, sectioning at intervals of ≤1 cm provides an adequate sampling resolution for <sup>210</sup>Pb dating. Exceptions are possible, allowing for ∼2–3 cm sections in areas with confirmed high sedimentation rates (e.g., > 1 cm yr<sup>−1</sup>). Recovering deeper core sections for <sup>14</sup>C dating with sufficient overlap allows for accounting errors in depth estimates made in the field. Special attention is advised during time intervals where validation proxies, such as the human-made radionuclides <sup>137</sup>Cs or post-bomb <sup>14</sup>C, are expected, and to determine the depth of secular equilibrium between <sup>210</sup>Pb and <sup>226</sup>Ra. Radiocarbon analyses are commonly performed by accelerator mass spectrometry, and age models are constructed mainly using Bayesian statistics with Markov Chain Monte Carlo techniques (e.g., <em>Bacon</em>). A Bayesian approach (<em>Plum</em>) is now available for producing <sup>210</sup>Pb age-models, which infers the <sup>210</sup>Pb<sub>ex</sub> flux, eliminates the need for selecting an equilibrium depth, and allows dating cores with incomplete <sup>210</sup>Pb<sub>ex</sub> inventory. <em>Plum</em> offers improved chronologies by integrating raw <sup>210</sup>Pb and <sup>14</sup>C data, and these age-models can be enriched with other dating methodologies, such as iden
准确地重建过去的环境变化在古生态学研究中是至关重要的,并且需要可靠的沉积档案年表。建立可靠的年龄模型并获得最合适的分析代理是一项复杂的科学努力,需要广泛的资源和专家之间的合作,包括放射年代学家。放射性测年方法,如210Pb和放射性碳(14C),经常用于确定水生沉积物和泥炭沼泽的年代学。在这项研究中,我们回顾了采样、分析的关键方面,以及210Pb和14C年龄模型的基本原理,重点介绍了开发用于古环境研究的可靠联合年表的方法。根据作者在2022年科学研讨会期间和之后的经验和小组讨论,我们讨论了建立综合210Pb−14C年龄模型时选址、采样策略和放射性定年的重要考虑因素。利用专家共识,这个被称为古统计学家的小组旨在通过这篇方法论文为其他地质年代学家提供一套最佳实践。在我们的结论中,我们强调了考虑特定地点因素的重要性,如沉积速率的先验信息,以建立适当的采样和分析策略。使用合适的取心设备可以最大限度地减少对沉积物的干扰,并确保岩心表面在切片前保持完整和保存。在预计超过210Pb (210Pbex)的地方,间隔≤1 cm的切片为210Pb定年提供了足够的采样分辨率。例外是可能的,允许在已确认的高沉积速率(例如,> 1 cm yr - 1)的地区进行~ 2-3 cm的剖面。恢复更深的岩心剖面进行14C测年,有足够的重叠,这允许在现场进行的深度估计中出现会计错误。在预计会有验证代理的时间间隔内,如人造放射性核素137Cs或原子弹爆炸后的14C,建议特别注意,并确定210Pb和226Ra之间的长期平衡深度。放射性碳分析通常由加速器质谱法进行,年龄模型主要使用贝叶斯统计和马尔可夫链蒙特卡罗技术(例如Bacon)构建。现在,贝叶斯方法(Plum)可用于生成210Pb年龄模型,该模型推断210Pbex通量,无需选择平衡深度,并允许在210Pbex库存不完整的情况下确定岩心的年代。Plum通过整合原始的210Pb和14C数据提供了改进的年表,并且这些年龄模型可以通过其他定年方法来丰富,例如确定tephras和其他记录良好的历史事件。统一报告将有助于使辐射年龄模型具有可重复性,这将受益于国际努力。利用210Pb和14C生成综合年龄模型可以更好地了解自然和近期人为强迫对生态系统的相互作用。这可以增强我们对环境过程及其对气候变化的影响的理解,最终支持基于科学的评估和决策。
{"title":"Guidelines for producing integrated 210Pb and 14C age-models","authors":"Joan-Albert Sanchez-Cabeza ,&nbsp;Marco A. Aquino-López ,&nbsp;Maarten Blaauw ,&nbsp;Ana Carolina Ruiz-Fernández ,&nbsp;Johanna L.J. Jupin ,&nbsp;Lysanna Anderson ,&nbsp;Clarke A. Knight ,&nbsp;Marie Rhondelle Champagne ,&nbsp;Nicole K. Sanderson ,&nbsp;Simon Goring ,&nbsp;J. Andrés Christen","doi":"10.1016/j.earscirev.2025.105301","DOIUrl":"10.1016/j.earscirev.2025.105301","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Accurate reconstructions of past environmental changes are crucial in paleoecological research and require reliable chronologies of sedimentary archives. Establishing robust age-models and obtaining the most appropriate proxies for analysis is a complex scientific endeavor, requiring extensive resources and collaboration among specialists, including radiochronologists. Radiometric dating methods, such as &lt;sup&gt;210&lt;/sup&gt;Pb and radiocarbon (&lt;sup&gt;14&lt;/sup&gt;C), are frequently employed to establish chronologies in aquatic sedimentary deposits and peat bogs. In this study, we review key aspects of sampling, analysis, and the principles underlying &lt;sup&gt;210&lt;/sup&gt;Pb and &lt;sup&gt;14&lt;/sup&gt;C age-models, focusing on methods for developing robust joint chronologies for paleoenvironmental research. Drawing largely from the authors' experiences and group discussions during and after a scientific workshop in 2022, we discuss important considerations for site selection, sampling strategies, and radiometric dating to construct integrated &lt;sup&gt;210&lt;/sup&gt;Pb −&lt;sup&gt;14&lt;/sup&gt;C age-models. Using expert consensus, this group – called Paleostats – aims to provide a set of best practices for other geochronologists with this methods paper. Among our conclusions, we emphasize the importance of accounting for site-specific factors such as prior information on sedimentation rates to establish appropriate sampling and analytical strategies. The use of appropriate coring devices can minimize disturbance to sediments and ensure the core surface remains intact and preserved until sectioning. Where excess &lt;sup&gt;210&lt;/sup&gt;Pb (&lt;sup&gt;210&lt;/sup&gt;Pb&lt;sub&gt;ex&lt;/sub&gt;) is expected, sectioning at intervals of ≤1 cm provides an adequate sampling resolution for &lt;sup&gt;210&lt;/sup&gt;Pb dating. Exceptions are possible, allowing for ∼2–3 cm sections in areas with confirmed high sedimentation rates (e.g., &gt; 1 cm yr&lt;sup&gt;−1&lt;/sup&gt;). Recovering deeper core sections for &lt;sup&gt;14&lt;/sup&gt;C dating with sufficient overlap allows for accounting errors in depth estimates made in the field. Special attention is advised during time intervals where validation proxies, such as the human-made radionuclides &lt;sup&gt;137&lt;/sup&gt;Cs or post-bomb &lt;sup&gt;14&lt;/sup&gt;C, are expected, and to determine the depth of secular equilibrium between &lt;sup&gt;210&lt;/sup&gt;Pb and &lt;sup&gt;226&lt;/sup&gt;Ra. Radiocarbon analyses are commonly performed by accelerator mass spectrometry, and age models are constructed mainly using Bayesian statistics with Markov Chain Monte Carlo techniques (e.g., &lt;em&gt;Bacon&lt;/em&gt;). A Bayesian approach (&lt;em&gt;Plum&lt;/em&gt;) is now available for producing &lt;sup&gt;210&lt;/sup&gt;Pb age-models, which infers the &lt;sup&gt;210&lt;/sup&gt;Pb&lt;sub&gt;ex&lt;/sub&gt; flux, eliminates the need for selecting an equilibrium depth, and allows dating cores with incomplete &lt;sup&gt;210&lt;/sup&gt;Pb&lt;sub&gt;ex&lt;/sub&gt; inventory. &lt;em&gt;Plum&lt;/em&gt; offers improved chronologies by integrating raw &lt;sup&gt;210&lt;/sup&gt;Pb and &lt;sup&gt;14&lt;/sup&gt;C data, and these age-models can be enriched with other dating methodologies, such as iden","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105301"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145615570","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multiparameter insights into the months-long evolution of Mt. Etna discharge system prior to the December 2018 eruption 对2018年12月喷发前埃特纳火山喷发系统数月演变的多参数洞察
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-23 DOI: 10.1016/j.earscirev.2025.105341
Daniele Carbone , Flavio Cannavò , Marco Liuzzo , Giovanni Bruno Giuffrida , Filippo Greco
The 24–27 December 2018 Mt. Etna's flank eruption was one of the most important from this volcano in the last 20 years, especially in terms of the associated pre-, syn- and post-eruptive dynamics, as testified by the impressive ground deformation and release of seismic energy. Here, we build on existing literature and integrate it with previously unpublished findings, retrieved from the analysis of gravity time series, to gain unprecedented insight into the deep processes that determined the conditions for the breakout of the December 2018 eruption.
Pre-eruptive emplacement of magma at shallow depth (∼2 km b.s.l.) did not occur progressively over the months preceding the eruption, but, rather, within a one-month timeframe (early October to early November 2018), as revealed by a marked gravity increase. This magma transfer was favored by enhanced permeability of the central discharge system, which also led to a decrease in the peripheral CO2 flux. Ground deformation data point to a volume change at deeper depth, suggesting that the shallower magma influx was mostly accommodated (and “hid”) by compression of pre-existing magma. Since early November, further overpressurization could no more be buffered by the compressibility of the magma at 2 km depth, due to the decrease in the volume fraction of exsolved gas, and was more effectively transmitted to the host rock, which enhanced transfer of gas and magma through the uppermost part of the discharge system, accompanied by growing unrest.
In our view, the important amount of magma which accumulated at relatively shallow depth during early October to early November pushed the plumbing system of Mt. Etna under disequilibrium conditions, ultimately favoring the emplacement of the dike which fed the December 2018 eruption.
Besides establishing a long-term framework to consistently explain the geophysical and geochemical observations related to the December 2018 eruption, we come to the more general conclusion that multiparameter evaluation is essential to properly understand the behavior of a complex volcano, like Mt. Etna. We also highlight the important role played by magma compressibility in controlling pre-eruptive processes and shaping the characteristics of certain observables used to monitor and study active volcanoes.
2018年12月24日至27日的埃特纳火山侧翼喷发是该火山近20年来最重要的一次喷发,特别是在喷发前后和喷发前后的动力学方面,令人印象深刻的地面变形和地震能量的释放证明了这一点。在这里,我们以现有文献为基础,将其与以前未发表的研究结果相结合,从重力时间序列分析中检索到,以获得对决定2018年12月爆发条件的深层过程的前所未有的深入了解。喷发前,岩浆在浅层深度(约2公里b.s.l.)的就位并不是在喷发前的几个月里逐渐发生的,而是在一个月的时间框架内(2018年10月初至11月初)发生的,这一点由重力明显增加所揭示。这种岩浆转移有利于中央排放系统的渗透性增强,这也导致了外围CO2通量的减少。地面变形数据表明,较深层的岩浆流发生了体积变化,这表明浅层岩浆流主要是通过压缩原有岩浆而被容纳(并“隐藏”)的。11月初以来,由于溶蚀气体体积分数的降低,岩浆在2 km深度的可压缩性不再能够缓冲进一步的超压,而更有效地向寄主岩石传递,这使得气体和岩浆通过排出系统的最上部传递增强,同时伴随着不稳定的加剧。我们认为,10月初至11月初在相对较浅的深度积累的大量岩浆在不平衡条件下推动了埃特纳火山的管道系统,最终有利于岩脉的就位,从而引发了2018年12月的喷发。除了建立一个长期框架,以一致地解释与2018年12月喷发有关的地球物理和地球化学观测外,我们还得出了一个更普遍的结论,即多参数评估对于正确理解像埃特纳火山这样的复杂火山的行为至关重要。我们还强调了岩浆可压缩性在控制喷发前过程和形成用于监测和研究活火山的某些观测特征方面所起的重要作用。
{"title":"Multiparameter insights into the months-long evolution of Mt. Etna discharge system prior to the December 2018 eruption","authors":"Daniele Carbone ,&nbsp;Flavio Cannavò ,&nbsp;Marco Liuzzo ,&nbsp;Giovanni Bruno Giuffrida ,&nbsp;Filippo Greco","doi":"10.1016/j.earscirev.2025.105341","DOIUrl":"10.1016/j.earscirev.2025.105341","url":null,"abstract":"<div><div>The 24–27 December 2018 Mt. Etna's flank eruption was one of the most important from this volcano in the last 20 years, especially in terms of the associated pre-, <em>syn</em>- and post-eruptive dynamics, as testified by the impressive ground deformation and release of seismic energy. Here, we build on existing literature and integrate it with previously unpublished findings, retrieved from the analysis of gravity time series, to gain unprecedented insight into the deep processes that determined the conditions for the breakout of the December 2018 eruption.</div><div>Pre-eruptive emplacement of magma at shallow depth (∼2 km b.s.l.) did not occur progressively over the months preceding the eruption, but, rather, within a one-month timeframe (early October to early November 2018), as revealed by a marked gravity increase. This magma transfer was favored by enhanced permeability of the central discharge system, which also led to a decrease in the peripheral CO<sub>2</sub> flux. Ground deformation data point to a volume change at deeper depth, suggesting that the shallower magma influx was mostly accommodated (and “hid”) by compression of pre-existing magma. Since early November, further overpressurization could no more be buffered by the compressibility of the magma at 2 km depth, due to the decrease in the volume fraction of exsolved gas, and was more effectively transmitted to the host rock, which enhanced transfer of gas and magma through the uppermost part of the discharge system, accompanied by growing unrest.</div><div>In our view, the important amount of magma which accumulated at relatively shallow depth during early October to early November pushed the plumbing system of Mt. Etna under disequilibrium conditions, ultimately favoring the emplacement of the dike which fed the December 2018 eruption.</div><div>Besides establishing a long-term framework to consistently explain the geophysical and geochemical observations related to the December 2018 eruption, we come to the more general conclusion that multiparameter evaluation is essential to properly understand the behavior of a complex volcano, like Mt. Etna. We also highlight the important role played by magma compressibility in controlling pre-eruptive processes and shaping the characteristics of certain observables used to monitor and study active volcanoes.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105341"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145583848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The supercontinent cycle seen from a hafnium isotope perspective in the Mongolian Accretionary Collage 从蒙古增生拼贴带的铪同位素角度看超大陆旋回
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-04 DOI: 10.1016/j.earscirev.2025.105320
Arnaud Broussolle , Min Sun , Yingde Jiang , Karel Schulmann , Carmen Aguilar , Yang Yu , Jérémie Soldner , Jean Wong
<div><div>Traditionally, the Wilson cycle is regarded as a convincing theory to explain plate tectonics; however, the links between long-lived accretionary orogens and supercontinent assemblies remain unclear. Long-lived accretionary orogens are proposed to have evolved around external oceans, potentially persisting for up to two billion years. In this paper, we revisit the supercontinent cycle based on hafnium isotope trends of the Precambrian Mongolian Ribbon (PMR) and the Mongolian Accretionary Collage (MAC), which possibly highlight the evolution of two consecutive external oceans in the Central Asian Orogenic Belt (CAOB). By considering these proposed external oceans, we suggest that extroversion, rather than orthoversion or introversion, could be the dominant mechanism for the formation of supercontinents. Compilation of 5706 Hf zircon isotopes from magmatic and detrital data from subduction-related rocks in the PMR and MAC reveals two distinct external advancing and retreating modes of subduction trends that switch at the assembly of each presumed supercontinent (2000, 1000, 540 and 260 Ma; millions of years ago). The subduction-related Hf trends connected to external geodynamics record the evolution of the PMR from ca. 2500 to 550 Ma and the MAC from ca. 550 to 300 Ma. Two phases of the retreating mode are observed ca. 2000 Ma to 1000 Ma and ca. 400 Ma to 300 Ma, while three phases of the advancing mode occurred ca. 2500 Ma to 2000 Ma, ca. 750 Ma to 550 Ma and ca. 550 Ma to 400 Ma. Therefore, we propose a cycle of extroversion modulated by alternating periods of advancing and retreating modes of subduction between the assemblies of Columbia, Rodinia, and Gondwana, which terminated with the assembly of Pangea. While the Cryogenian–Ediacaran period is characterised by a snowball Earth, the Ediacaran to Cambrian transition is not marked by a change in subduction mode despite the assembly of Gondwana. The Gondwana supercontinent was stable after ca. 540 Ma, and a subduction girdle developed in advancing mode. The stability of this supercontinent is supported by well-known evidence, such as the formation of a slab graveyard after assembly. Nonetheless, no explanation exists for why the advancing/advancing mode phenomenon occurred. Our hafnium model suggests that an interconnected cycle may govern the Earth's evolution and speculates that a feedback loop exists between advancing and retreating modes and between “top-down” and “bottom-up” processes, leading to a fully operative supercontinent cycle. In addition, tectonic switching from these processes might control extreme magmatism and metamorphism during supercontinent assembly. For instance, these two latter extreme proxies are observed in the assembly of Eurasia within the collisional belts as well as in the subduction girdle of the external ocean at ∼40 Ma to ∼20 Ma. Our model not only predicts future plate movements but also speculates their eventual amalgamation into a supercontinent, Pan
传统上,威尔逊旋回被认为是解释板块构造的一个令人信服的理论;然而,长寿命的增生造山带和超大陆组合之间的联系仍然不清楚。长寿的增生造山带被认为是在外部海洋周围进化而来的,可能持续长达20亿年。基于前寒武纪蒙古带(PMR)和蒙古增生拼贴带(MAC)的铪同位素趋势,我们重新审视了超大陆旋回,这可能突出了中亚造山带(CAOB)两个连续的外部海洋的演化。通过考虑这些被提出的外部海洋,我们认为外倾性,而不是正倾性或内倾性,可能是超级大陆形成的主要机制。从PMR和MAC中俯冲相关岩石的岩浆和碎屑资料中收集的5706 Hf锆石同位素汇编显示,在每个假定的超大陆(2000、1000、540和260 Ma,数百万年前)的组合中,俯冲趋势的两种不同的外部进退模式切换。与外部地球动力学相关的俯冲Hf趋势记录了PMR从约2500 ~ 550 Ma和MAC从约550 ~ 300 Ma的演化。在2000 Ma至1000 Ma和400 Ma至300 Ma时出现了两个阶段的撤退模式,而在2500 Ma至2000 Ma、750 Ma至550 Ma和550 Ma至400 Ma时出现了三个阶段的前进模式。因此,我们提出了一个由哥伦比亚组合、罗迪尼亚组合和冈瓦纳组合之间的交替进退俯冲模式所调节的外向循环,该循环以盘古大陆组合结束。寒冰纪-埃迪卡拉纪的特征是雪球地球,而埃迪卡拉纪到寒武纪的过渡,虽然有冈瓦纳板块的组合,但并没有以俯冲方式的变化为标志。约540 Ma以后冈瓦纳超大陆稳定,俯冲带以推进方式发育。这个超大陆的稳定性得到了众所周知的证据的支持,例如在组合后形成了一个板墓地。然而,对于前进/前进模式现象发生的原因没有解释。我们的铪模型表明,一个相互关联的循环可能支配着地球的演化,并推测在前进和后退模式之间以及“自上而下”和“自下而上”过程之间存在反馈循环,从而导致一个完全有效的超大陆循环。此外,这些过程的构造转换可能控制了超大陆组合过程中的极端岩浆作用和变质作用。例如,在碰撞带内的欧亚大陆组合以及外洋在~ 40 Ma至~ 20 Ma的俯冲带中观察到后两种极端代用物。我们的模型不仅预测了未来的板块运动,而且还推测了它们最终通过外倾性合并成一个超大陆——比邻泛大陆。因此,有人建议太平洋将会关闭。主要信息是,自古元古代以来,超大陆旋回对长寿命的增生造山带的演化施加了一级控制。
{"title":"The supercontinent cycle seen from a hafnium isotope perspective in the Mongolian Accretionary Collage","authors":"Arnaud Broussolle ,&nbsp;Min Sun ,&nbsp;Yingde Jiang ,&nbsp;Karel Schulmann ,&nbsp;Carmen Aguilar ,&nbsp;Yang Yu ,&nbsp;Jérémie Soldner ,&nbsp;Jean Wong","doi":"10.1016/j.earscirev.2025.105320","DOIUrl":"10.1016/j.earscirev.2025.105320","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Traditionally, the Wilson cycle is regarded as a convincing theory to explain plate tectonics; however, the links between long-lived accretionary orogens and supercontinent assemblies remain unclear. Long-lived accretionary orogens are proposed to have evolved around external oceans, potentially persisting for up to two billion years. In this paper, we revisit the supercontinent cycle based on hafnium isotope trends of the Precambrian Mongolian Ribbon (PMR) and the Mongolian Accretionary Collage (MAC), which possibly highlight the evolution of two consecutive external oceans in the Central Asian Orogenic Belt (CAOB). By considering these proposed external oceans, we suggest that extroversion, rather than orthoversion or introversion, could be the dominant mechanism for the formation of supercontinents. Compilation of 5706 Hf zircon isotopes from magmatic and detrital data from subduction-related rocks in the PMR and MAC reveals two distinct external advancing and retreating modes of subduction trends that switch at the assembly of each presumed supercontinent (2000, 1000, 540 and 260 Ma; millions of years ago). The subduction-related Hf trends connected to external geodynamics record the evolution of the PMR from ca. 2500 to 550 Ma and the MAC from ca. 550 to 300 Ma. Two phases of the retreating mode are observed ca. 2000 Ma to 1000 Ma and ca. 400 Ma to 300 Ma, while three phases of the advancing mode occurred ca. 2500 Ma to 2000 Ma, ca. 750 Ma to 550 Ma and ca. 550 Ma to 400 Ma. Therefore, we propose a cycle of extroversion modulated by alternating periods of advancing and retreating modes of subduction between the assemblies of Columbia, Rodinia, and Gondwana, which terminated with the assembly of Pangea. While the Cryogenian–Ediacaran period is characterised by a snowball Earth, the Ediacaran to Cambrian transition is not marked by a change in subduction mode despite the assembly of Gondwana. The Gondwana supercontinent was stable after ca. 540 Ma, and a subduction girdle developed in advancing mode. The stability of this supercontinent is supported by well-known evidence, such as the formation of a slab graveyard after assembly. Nonetheless, no explanation exists for why the advancing/advancing mode phenomenon occurred. Our hafnium model suggests that an interconnected cycle may govern the Earth's evolution and speculates that a feedback loop exists between advancing and retreating modes and between “top-down” and “bottom-up” processes, leading to a fully operative supercontinent cycle. In addition, tectonic switching from these processes might control extreme magmatism and metamorphism during supercontinent assembly. For instance, these two latter extreme proxies are observed in the assembly of Eurasia within the collisional belts as well as in the subduction girdle of the external ocean at ∼40 Ma to ∼20 Ma. Our model not only predicts future plate movements but also speculates their eventual amalgamation into a supercontinent, Pan","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105320"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145441353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Global patterns of shore platform evolution and cliff retreat: Insights from cosmogenic radionuclides 海岸台地演化和悬崖退缩的全球模式:来自宇宙形成放射性核素的见解
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-08 DOI: 10.1016/j.earscirev.2025.105323
Ara Jeong , Yeong Bae Seong , Kwang Hee Choi , Zuzanna M. Swirad
Rocky coasts are actively evolving geomorphic features whose long-term evolution is critically influenced by Relative Sea Level (RSL) change. Cosmogenic radionuclides (CRNs) offer a powerful tool to quantify these millennial-scale rates of shore platform evolution and cliff retreat. This study synthesizes global CRN research on rocky coasts and presents a detailed case study of the Korean Peninsula, a unique natural laboratory with distinct RSL end-members: the actively uplifting East Coast and the tectonically stable West Coast. Our analysis, incorporating new and re-evaluated 10Be data, reveals contrasting evolutionary patterns. East Coast platforms predominantly show Holocene formation with varied site-specific cliff retreat rates (e.g., Jangsa: 1.4 to 7.0 mm/yr acceleration; Ayajin/Jukbyeon-ri: deceleration). In stark contrast, West Coast platforms exhibit significantly higher 10Be concentrations and “stair-step” profiles, providing strong evidence for widespread interglacial relict surfaces. These findings underscore RSL change as a fundamental long-term boundary condition, interacting with regional tectonics and oceanographic forcing. While CRNs offer invaluable insights, challenges remain in model assumptions and accounting for complex shielding. Future research necessitates enhanced data acquisition, refined process-based modeling, and integrated datasets to improve predictions of rocky coast responses to accelerating sea-level rise.
岩质海岸是积极演化的地貌特征,其长期演化受到相对海平面变化的重要影响。宇宙形成的放射性核素(crn)提供了一个强大的工具来量化这些千年尺度的海岸平台演化和悬崖退缩率。本研究综合了全球岩石海岸的CRN研究,并提出了朝鲜半岛的详细案例研究,朝鲜半岛是一个独特的自然实验室,具有明显的RSL末端成员:积极隆起的东海岸和构造稳定的西海岸。我们的分析结合了新的和重新评估的10Be数据,揭示了截然不同的进化模式。东海岸台地主要显示全新世形成,具有不同地点的悬崖后退率(例如,长沙:1.4至7.0 mm/年加速;阿亚津/竹边里:减速)。与此形成鲜明对比的是,西海岸平台显示出明显更高的10Be浓度和“阶梯”剖面,为广泛存在的间冰期遗迹表面提供了强有力的证据。这些发现强调RSL变化是一个基本的长期边界条件,与区域构造和海洋强迫相互作用。虽然crn提供了宝贵的见解,但在模型假设和复杂屏蔽的计算方面仍然存在挑战。未来的研究需要加强数据采集、改进基于过程的建模和集成数据集,以改进对岩石海岸对海平面加速上升的反应的预测。
{"title":"Global patterns of shore platform evolution and cliff retreat: Insights from cosmogenic radionuclides","authors":"Ara Jeong ,&nbsp;Yeong Bae Seong ,&nbsp;Kwang Hee Choi ,&nbsp;Zuzanna M. Swirad","doi":"10.1016/j.earscirev.2025.105323","DOIUrl":"10.1016/j.earscirev.2025.105323","url":null,"abstract":"<div><div>Rocky coasts are actively evolving geomorphic features whose long-term evolution is critically influenced by Relative Sea Level (RSL) change. Cosmogenic radionuclides (CRNs) offer a powerful tool to quantify these millennial-scale rates of shore platform evolution and cliff retreat. This study synthesizes global CRN research on rocky coasts and presents a detailed case study of the Korean Peninsula, a unique natural laboratory with distinct RSL end-members: the actively uplifting East Coast and the tectonically stable West Coast. Our analysis, incorporating new and re-evaluated <sup>10</sup>Be data, reveals contrasting evolutionary patterns. East Coast platforms predominantly show Holocene formation with varied site-specific cliff retreat rates (e.g., Jangsa: 1.4 to 7.0 mm/yr acceleration; Ayajin/Jukbyeon-ri: deceleration). In stark contrast, West Coast platforms exhibit significantly higher <sup>10</sup>Be concentrations and “stair-step” profiles, providing strong evidence for widespread interglacial relict surfaces. These findings underscore RSL change as a fundamental long-term boundary condition, interacting with regional tectonics and oceanographic forcing. While CRNs offer invaluable insights, challenges remain in model assumptions and accounting for complex shielding. Future research necessitates enhanced data acquisition, refined process-based modeling, and integrated datasets to improve predictions of rocky coast responses to accelerating sea-level rise.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105323"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145473289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Regimes of bedforms created by down-slope density currents 下坡密度流形成的河床
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-11 DOI: 10.1016/j.earscirev.2025.105322
Octavio E. Sequeiros , Benoit Spinewine , Gary Parker , Carlos Pirmez , Enrica Viparelli , Juan J. Fedele , Marcelo H. García , Débora Koller , Michele Bolla Pittaluga , Miwa Yokokawa
Bedforms in rivers have been extensively studied for decades. Turbidite outcrops also display bedforms emplaced subaqueously by turbidity currents. Recent breakthroughs in the attainable resolution of deep underwater bathymetric/seismic mapping have revealed that bedforms in submarine environments may be as widespread and diverse as those associated with fluvial flows. Turbidity currents that emplace subaqueous bedforms run down submarine canyons, traverse and overflow leveed channels on submarine fans, or manifest themselves as sheet turbidity currents along continental margins. Submarine bedforms present features that appear to be analogous to their fluvial counterparts. Submarine bedforms have traditionally been interpreted with the use of tools, and in particular phase diagrams, that were developed solely for fluvial bedforms. The use of such tools is motivated by the fact that simultaneous observation of the bedforms as they evolve in the field and the turbidity currents that create them remains at the edge of present capabilities. We fill this gap in part with a technique that has been successfully implemented for fluvial bedforms, i.e. experimentation. We present observations of bedforms emplaced by saline and turbidity currents in laboratory flumes. The experimental flows span a wide range of densimetric Froude numbers, including both subcritical and supercritical regimes, and produced various bedform types including subcritical and supercritical-regime ripples/dunes, upstream-migrating and downstream-migrating antidunes, and cyclic steps. We have gathered a comprehensive set of fluvial and submarine field bedforms worldwide from multiple environments including submarine canyons, levees, slopes, and fans; some of which include associated flow observations. The data are summarized in a set of bedform dimensions and regime diagrams, which are applicable to saline and/or turbidity currents, and generally to any down-slope moving bottom flow. The regimes for submarine bedforms show both similarities and differences with fluvial regimes. Our diagrams and guidelines constitute a new tool for the interpretation of field-scale bedforms generated by turbidity currents.
几十年来,人们对河流的河床形态进行了广泛的研究。浊积岩露头也显示出被浊积流置于水下的河床。最近在深海测深/地震测绘可达到的分辨率方面取得的突破表明,海底环境中的地形可能与与河流流动有关的地形一样广泛和多样。沉积在水下河床上的浊流沿着海底峡谷流下,穿过并溢出海底扇上的平整河道,或者沿着大陆边缘表现为片状浊流。海底的地形呈现出与河流相似的特征。传统上,海底的床型是用工具来解释的,特别是相图,这些工具是专门为河流床型而开发的。使用这些工具的动机是,同时观察在野外演变的床型和产生它们的浊度流仍然处于目前能力的边缘。我们在一定程度上用一种技术填补了这一空白,这种技术已经成功地应用于河流河床,即实验。我们提出了在实验室水槽中由盐水和浊度流放置的床型观察。实验流动跨越了广泛的密度弗劳德数范围,包括亚临界和超临界状态,并产生了各种床型类型,包括亚临界和超临界状态的波纹/沙丘,上游迁移和下游迁移的反沙丘,以及循环台阶。我们收集了一套全面的河流和海底野外地形,来自世界各地的多种环境,包括海底峡谷,堤防,斜坡和扇;其中一些包括相关的流量观测。这些数据总结为一组床型尺寸和状态图,适用于盐水和/或浊度流,通常适用于任何下坡移动的底流。海底河床形态与河流形态既有相似之处,也有不同之处。我们的图表和指南构成了解释由浊度流产生的场尺度河床的新工具。
{"title":"Regimes of bedforms created by down-slope density currents","authors":"Octavio E. Sequeiros ,&nbsp;Benoit Spinewine ,&nbsp;Gary Parker ,&nbsp;Carlos Pirmez ,&nbsp;Enrica Viparelli ,&nbsp;Juan J. Fedele ,&nbsp;Marcelo H. García ,&nbsp;Débora Koller ,&nbsp;Michele Bolla Pittaluga ,&nbsp;Miwa Yokokawa","doi":"10.1016/j.earscirev.2025.105322","DOIUrl":"10.1016/j.earscirev.2025.105322","url":null,"abstract":"<div><div>Bedforms in rivers have been extensively studied for decades. Turbidite outcrops also display bedforms emplaced subaqueously by turbidity currents. Recent breakthroughs in the attainable resolution of deep underwater bathymetric/seismic mapping have revealed that bedforms in submarine environments may be as widespread and diverse as those associated with fluvial flows. Turbidity currents that emplace subaqueous bedforms run down submarine canyons, traverse and overflow leveed channels on submarine fans, or manifest themselves as sheet turbidity currents along continental margins. Submarine bedforms present features that appear to be analogous to their fluvial counterparts. Submarine bedforms have traditionally been interpreted with the use of tools, and in particular phase diagrams, that were developed solely for fluvial bedforms. The use of such tools is motivated by the fact that simultaneous observation of the bedforms as they evolve in the field and the turbidity currents that create them remains at the edge of present capabilities. We fill this gap in part with a technique that has been successfully implemented for fluvial bedforms, i.e. experimentation. We present observations of bedforms emplaced by saline and turbidity currents in laboratory flumes. The experimental flows span a wide range of densimetric Froude numbers, including both subcritical and supercritical regimes, and produced various bedform types including subcritical and supercritical-regime ripples/dunes, upstream-migrating and downstream-migrating antidunes, and cyclic steps. We have gathered a comprehensive set of fluvial and submarine field bedforms worldwide from multiple environments including submarine canyons, levees, slopes, and fans; some of which include associated flow observations. The data are summarized in a set of bedform dimensions and regime diagrams, which are applicable to saline and/or turbidity currents, and generally to any down-slope moving bottom flow. The regimes for submarine bedforms show both similarities and differences with fluvial regimes. Our diagrams and guidelines constitute a new tool for the interpretation of field-scale bedforms generated by turbidity currents.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105322"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145510006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tectonic controls on volcanism in transfer fault zones: Insights from the Catalan Volcanic Zone (Northeastern Iberia) 构造对转移断裂带火山作用的控制:来自加泰罗尼亚火山带(伊比利亚东北部)的启示
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-24 DOI: 10.1016/j.earscirev.2025.105342
David Cruset , Jaume Vergés , Marc Viaplana-Muzas , Xavier Bolós , Adelina Geyer , Jordi Díaz , Mahdi Najafi , Mar Moragas , Leo J. Millonig , Axel Gerdes , Estefanía Bravo-Gutiérrez , Montserrat Torné , Ivone Jiménez-Munt , Daniel García-Castellanos
Transfer fault zones are commonly associated with volcanic activity. While geochronological methods such as the UPb and ArAr dating have been traditionally used to establish the absolute timing of volcanism, recent advances allow us the dating of fracture-filling minerals. However, integrated tectono-volcanic and geochronological studies of fault zones are scarce, limiting our ability to constrain accurately the evolution of fault-controlled volcanic zones.
This paper reviews the tectono-volcanic history of northeastern Iberia through the geochronological and kinematic analysis of well-known examples of Neogene to Quaternary fault zones with associated volcanism along the Transverse Ranges. These fault zones are located at the northwestern tip of a NW-SE transfer zone that segmented the Liguro-Provençal Rift. We integrate available geological and geophysical data with new structural analysis of meter scale fractures across three fault zones and UPb dating of fracture-filling carbonates.
The UPb dating of fracture-filling calcite reveals early Eocene strike-slip faulting at ∼49 Ma, during the Alpine compression, and synchronous strike-slip and extensional dip-slip faulting from ∼22 to ∼2 Ma, coinciding with the Liguro-Provençal rifting. We propose a new lithospheric-scale model in which faults acted as sub-vertical conduits for the ascent of magmas sourced from the lithosphere-asthenosphere boundary, based on the composition of recovered xenoliths. Our geochronological dataset supports the hypothesis that fault reactivation governs the timing, location and migration of volcanism in the Neogene to Quaternary Catalan Volcanic Zone, which was additionally influenced by lithospheric thinning and the development of transfer fault zones that potentially reflect the reactivation of Mesozoic structures. These processes share striking similarities with those observed in the western Mediterranean Region, the European Cenozoic Rift System, and other extensional systems worldwide, highlighting the role of inherited transfer fault zones in the evolution of volcanism.
转移断裂带通常与火山活动有关。虽然像UPb和ArAr测年这样的地质年代学方法传统上被用来确定火山活动的绝对时间,但最近的进展使我们能够确定裂缝填充矿物的年代。然而,对断裂带的综合构造-火山和地质年代学研究很少,这限制了我们精确约束断裂控制的火山带演化的能力。本文通过对沿横向山脉新近纪至第四纪带伴生火山作用的著名断裂带的年代学和运动学分析,回顾了伊比利亚东北部的构造火山史。这些断裂带位于利古罗-普罗旺帕拉裂谷的NW-SE转移带的西北端。我们将现有的地质和地球物理数据与三个断裂带的米级裂缝的新结构分析和裂缝填充碳酸盐的UPb定年相结合。裂缝充填方解石UPb定年显示,早始新世走滑断裂发生在~ 49 Ma的阿尔卑斯挤压期,同步走滑和伸展倾滑断裂发生在~ 22 ~ ~ 2 Ma,与利古罗-普罗旺帕拉裂谷作用一致。根据回收的捕虏体组成,提出了一种新的岩石圈尺度模型,其中断层作为岩石圈-软流圈边界岩浆上升的次垂直通道。我们的年代学数据支持这样的假设,即断层重新激活控制了新近纪至第四纪加泰罗尼亚火山带的火山活动的时间、位置和迁移,此外,岩石圈变薄和转移断裂带的发展可能反映了中生代构造的重新激活。这些过程与西地中海地区、欧洲新生代裂谷系以及世界范围内的其他伸展系统具有惊人的相似性,突出了继承转移断裂带在火山作用演化中的作用。
{"title":"Tectonic controls on volcanism in transfer fault zones: Insights from the Catalan Volcanic Zone (Northeastern Iberia)","authors":"David Cruset ,&nbsp;Jaume Vergés ,&nbsp;Marc Viaplana-Muzas ,&nbsp;Xavier Bolós ,&nbsp;Adelina Geyer ,&nbsp;Jordi Díaz ,&nbsp;Mahdi Najafi ,&nbsp;Mar Moragas ,&nbsp;Leo J. Millonig ,&nbsp;Axel Gerdes ,&nbsp;Estefanía Bravo-Gutiérrez ,&nbsp;Montserrat Torné ,&nbsp;Ivone Jiménez-Munt ,&nbsp;Daniel García-Castellanos","doi":"10.1016/j.earscirev.2025.105342","DOIUrl":"10.1016/j.earscirev.2025.105342","url":null,"abstract":"<div><div>Transfer fault zones are commonly associated with volcanic activity. While geochronological methods such as the U<img>Pb and Ar<img>Ar dating have been traditionally used to establish the absolute timing of volcanism, recent advances allow us the dating of fracture-filling minerals. However, integrated tectono-volcanic and geochronological studies of fault zones are scarce, limiting our ability to constrain accurately the evolution of fault-controlled volcanic zones.</div><div>This paper reviews the tectono-volcanic history of northeastern Iberia through the geochronological and kinematic analysis of well-known examples of Neogene to Quaternary fault zones with associated volcanism along the Transverse Ranges. These fault zones are located at the northwestern tip of a NW-SE transfer zone that segmented the Liguro-Provençal Rift. We integrate available geological and geophysical data with new structural analysis of meter scale fractures across three fault zones and U<img>Pb dating of fracture-filling carbonates.</div><div>The U<img>Pb dating of fracture-filling calcite reveals early Eocene strike-slip faulting at ∼49 Ma, during the Alpine compression, and synchronous strike-slip and extensional dip-slip faulting from ∼22 to ∼2 Ma, coinciding with the Liguro-Provençal rifting. We propose a new lithospheric-scale model in which faults acted as sub-vertical conduits for the ascent of magmas sourced from the lithosphere-asthenosphere boundary, based on the composition of recovered xenoliths. Our geochronological dataset supports the hypothesis that fault reactivation governs the timing, location and migration of volcanism in the Neogene to Quaternary Catalan Volcanic Zone, which was additionally influenced by lithospheric thinning and the development of transfer fault zones that potentially reflect the reactivation of Mesozoic structures. These processes share striking similarities with those observed in the western Mediterranean Region, the European Cenozoic Rift System, and other extensional systems worldwide, highlighting the role of inherited transfer fault zones in the evolution of volcanism.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105342"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145593687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Atmospheric mercury stable isotopes: Advances in mercury cycle tracing and projections of future trends 大气汞稳定同位素:汞循环追踪和未来趋势预测的进展
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-25 DOI: 10.1016/j.earscirev.2025.105348
Chao Zhang, Ruoyu Sun
Mercury (Hg) stable isotopes have emerged as a powerful tracer to resolve the sources, transformations, and deposition pathways of atmospheric Hg. Beyond conventional mass-dependent fractionation (MDF), atmospheric reactions can induce unique Hg mass-independent fractionation (MIF). This review synthesizes current sampling strategies and pretreatment protocols for gaseous Hg(0) and reactive Hg(II) in particulates and precipitation, and compiles their isotope compositions (δ202Hg for MDF, Δ199Hg for odd-MIF and Δ200Hg for even-MIF) across terrestrial background, urban-industrial, marine boundary layer, and polar regions. Terrestrial background Hg(0) typically exhibits positive δ202Hg with negative Δ199Hg and Δ200Hg, whereas reactive Hg(II) shows negative δ202Hg with positive Δ199Hg and Δ200Hg. These complementary patterns reflect predominant roles of photoreduction of Hg(II) and vegetation uptake of Hg(0). Urban-industrial Hg(0) tends to have low δ202Hg and elevated Δ199Hg and Δ200Hg, consistent with anthropogenic influence. However, post-emission transformations frequently obscure primary isotope signatures of Hg(II), complicating source-receptor relationships. In polar regions, reactive Hg (II) bears strong imprints of photoredox reactions at the snow-atmosphere interface, typically exhibiting very negative Δ199Hg values. Integrating isotope observations with deposition pathways indicates that dry deposition of Hg(0) often dominates fluxes to both terrestrial and marine surfaces. Scenario analysis under Shared Socioeconomic Pathways project notable increases in δ202Hg and Δ199Hg under low-emission futures. To better implement the Minamata Convention in a changing climate, future research should prioritize species-specific Hg sampling, better mechanistic understanding of isotope fractionation, and expanded isotope monitoring in underrepresented regions.
汞(Hg)稳定同位素已成为一种强大的示踪剂,可用于解析大气中汞的来源、转化和沉积途径。除了传统的质量依赖分馏(MDF)外,大气反应还可以诱导独特的汞质量无关分馏(MIF)。本文综述了目前颗粒和降水中气态汞(0)和活性汞(II)的采样策略和预处理方案,并编制了它们在陆地背景、城市-工业、海洋边界层和极地地区的同位素组成(MDF为δ202Hg,奇数mif为Δ199Hg,偶数mif为Δ200Hg)。陆地背景汞(0)δ202Hg典型表现为正,Δ199Hg和Δ200Hg为负,而活性汞(II) δ202Hg典型表现为负,Δ199Hg和Δ200Hg为正。这些互补模式反映了Hg(II)的光还原和Hg(0)的植被吸收的主导作用。城市工业Hg(0) δ202Hg低,Δ199Hg和Δ200Hg升高,与人为影响一致。然而,发射后的转变经常模糊Hg(II)的主要同位素特征,使源-受体关系复杂化。在极地地区,活性Hg (II)在雪-大气界面具有很强的光氧化还原反应印记,通常表现出非常负的Δ199Hg值。将同位素观测与沉积路径相结合表明,汞(0)的干沉积往往主导着陆地和海洋表面的通量。共享社会经济路径下的情景分析预测低排放未来δ202Hg和Δ199Hg显著增加。为了在气候变化的背景下更好地实施《水俣公约》,未来的研究应优先考虑特定物种的汞采样,更好地了解同位素分异的机制,并在代表性不足的地区扩大同位素监测。
{"title":"Atmospheric mercury stable isotopes: Advances in mercury cycle tracing and projections of future trends","authors":"Chao Zhang,&nbsp;Ruoyu Sun","doi":"10.1016/j.earscirev.2025.105348","DOIUrl":"10.1016/j.earscirev.2025.105348","url":null,"abstract":"<div><div>Mercury (Hg) stable isotopes have emerged as a powerful tracer to resolve the sources, transformations, and deposition pathways of atmospheric Hg. Beyond conventional mass-dependent fractionation (MDF), atmospheric reactions can induce unique Hg mass-independent fractionation (MIF). This review synthesizes current sampling strategies and pretreatment protocols for gaseous Hg(0) and reactive Hg(II) in particulates and precipitation, and compiles their isotope compositions (δ<sup>202</sup>Hg for MDF, Δ<sup>199</sup>Hg for odd-MIF and Δ<sup>200</sup>Hg for even-MIF) across terrestrial background, urban-industrial, marine boundary layer, and polar regions. Terrestrial background Hg(0) typically exhibits positive δ<sup>202</sup>Hg with negative Δ<sup>199</sup>Hg and Δ<sup>200</sup>Hg, whereas reactive Hg(II) shows negative δ<sup>202</sup>Hg with positive Δ<sup>199</sup>Hg and Δ<sup>200</sup>Hg. These complementary patterns reflect predominant roles of photoreduction of Hg(II) and vegetation uptake of Hg(0). Urban-industrial Hg(0) tends to have low δ<sup>202</sup>Hg and elevated Δ<sup>199</sup>Hg and Δ<sup>200</sup>Hg, consistent with anthropogenic influence. However, post-emission transformations frequently obscure primary isotope signatures of Hg(II), complicating source-receptor relationships. In polar regions, reactive Hg (II) bears strong imprints of photoredox reactions at the snow-atmosphere interface, typically exhibiting very negative Δ<sup>199</sup>Hg values. Integrating isotope observations with deposition pathways indicates that dry deposition of Hg(0) often dominates fluxes to both terrestrial and marine surfaces. Scenario analysis under Shared Socioeconomic Pathways project notable increases in δ<sup>202</sup>Hg and Δ<sup>199</sup>Hg under low-emission futures. To better implement the Minamata Convention in a changing climate, future research should prioritize species-specific Hg sampling, better mechanistic understanding of isotope fractionation, and expanded isotope monitoring in underrepresented regions.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105348"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145598747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Differential impacts of multi-scale natural fractures on hydraulic fracture network formation 多尺度天然裂缝对水力裂缝网形成的差异性影响
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-30 DOI: 10.1016/j.earscirev.2025.105315
Jizhou Tang , Jiayu Li , Zhuo Zhang , Yu Fan , Wenya Jiang , Siwei Meng , Xianzheng Zhao
Natural fractures critically influence stimulation efficiency and fluid transport in continental shale reservoirs, yet their scale-dependent behavior under varying tectonic regimes remains insufficiently understood. This study investigates the Cangdong Sag (Bohai Bay Basin) and Gulong Sag (Songliao Basin) through a multi-scale approach. At the core scale, three primary fracture types—bedding, tectonic, and diagenetic—are characterized in terms of geometry and mechanics. Outcrop-scale simulations assess fracture propagation under different injection conditions. At the seismic scale, statistical analyses quantify fracture length, density, and orientation across the two regions. These data support fully coupled 3D models to evaluate stimulated rock volume (SRV). To integrate geometric and mechanical attributes across scales, a novel Natural Fracture Activation–Probabilistic Fractal Dimension Method (NF-AP-FDM) is developed, introducing the Ddp index to describe activation potential and fracture complexity. The method is validated through SRV comparisons and applied to analyze operational parameters. Results reveal significant differences in fracture networks between the two sags, shaped by distinct tectonic histories. This work provides new insights into fracture evolution mechanisms and enhances hydraulic fracturing design in complex continental shale systems.
天然裂缝对陆相页岩储层的增产效率和流体输运有重要影响,但在不同构造条件下,天然裂缝的尺度依赖性仍未得到充分认识。本文采用多尺度方法对渤海湾盆地沧东凹陷和松辽盆地古龙凹陷进行了研究。在岩心尺度上,层理裂缝、构造裂缝和成岩裂缝三种主要裂缝类型在几何和力学上具有明显的特征。露头尺度模拟评估了不同注入条件下的裂缝扩展。在地震尺度上,统计分析量化了两个区域的裂缝长度、密度和方向。这些数据支持完全耦合的3D模型来评估受激岩石体积(SRV)。为了跨尺度整合几何和力学属性,开发了一种新的自然裂缝激活概率分形维数方法(NF-AP-FDM),引入Ddp指数来描述激活电位和裂缝复杂性。通过SRV对比验证了该方法的有效性,并将其应用于运行参数分析。结果表明,由于不同的构造历史,两个凹陷的裂缝网络存在显著差异。这项工作为裂缝演化机制提供了新的见解,并提高了复杂陆相页岩系统的水力压裂设计水平。
{"title":"Differential impacts of multi-scale natural fractures on hydraulic fracture network formation","authors":"Jizhou Tang ,&nbsp;Jiayu Li ,&nbsp;Zhuo Zhang ,&nbsp;Yu Fan ,&nbsp;Wenya Jiang ,&nbsp;Siwei Meng ,&nbsp;Xianzheng Zhao","doi":"10.1016/j.earscirev.2025.105315","DOIUrl":"10.1016/j.earscirev.2025.105315","url":null,"abstract":"<div><div>Natural fractures critically influence stimulation efficiency and fluid transport in continental shale reservoirs, yet their scale-dependent behavior under varying tectonic regimes remains insufficiently understood. This study investigates the Cangdong Sag (Bohai Bay Basin) and Gulong Sag (Songliao Basin) through a multi-scale approach. At the core scale, three primary fracture types—bedding, tectonic, and diagenetic—are characterized in terms of geometry and mechanics. Outcrop-scale simulations assess fracture propagation under different injection conditions. At the seismic scale, statistical analyses quantify fracture length, density, and orientation across the two regions. These data support fully coupled 3D models to evaluate stimulated rock volume (SRV). To integrate geometric and mechanical attributes across scales, a novel Natural Fracture Activation–Probabilistic Fractal Dimension Method (NF-AP-FDM) is developed, introducing the <span><math><msub><mi>D</mi><mi>dp</mi></msub></math></span> index to describe activation potential and fracture complexity. The method is validated through SRV comparisons and applied to analyze operational parameters. Results reveal significant differences in fracture networks between the two sags, shaped by distinct tectonic histories. This work provides new insights into fracture evolution mechanisms and enhances hydraulic fracturing design in complex continental shale systems.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105315"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145404646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crustal architecture controls on porphyry Cu and Mo fertility: constraints from zircon Hf isotopic mapping in the Great Xing’an Range, NE China 地壳构造对斑岩铜钼富性的控制:来自大兴安岭锆石Hf同位素填图的约束
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-04 DOI: 10.1016/j.earscirev.2025.105319
Lijun Liu , Qihai Shu , Kai Xing , Jinyu Liu , Litian Zhang , Qingfei Wang , Jun Deng
Porphyry deposits are the major source of copper and molybdenum of the world. The Great Xing’an Range in northeastern China is widely known for its abundant Mo deposits, some of which have giant sizes (i.e., >0.5 Mt Mo). In total, there are 27 porphyry Mo (-Cu) deposits and 14 porphyry Cu (-Mo) deposits in the region. Whether and how the formation of these deposits was controlled by the regional crust architecture remains unclear. Here, we integrated geologic and geochemical data (including zircon U-Pb dating results and Lu-Hf isotopic compositions) for the Paleozoic-Mesozoic felsic rocks and porphyry Cu (-Mo) and Mo (-Cu) deposits in the Great Xing’an Range, and imaged the crustal architecture by zircon Hf isotopic mapping. The results indicate that most of the study area is of juvenile crustal domains, with a significant mantle contribution in their formation. The northern Erguna Block and the southwestern Songliao Accretionary Terrane are characterized by ancient and reworked crustal domains, respectively. Porphyry Cu (-Mo) deposits are predominantly located in these juvenile crustal domains with high εHf(t) (>+3) values, and their distribution was controlled by the NE-trending tectonic systems. High Sr/Y and high oxygen fugacity arc magmas are associated with the formation of the subduction-related porphyry Cu (-Mo) deposits during the Early-Paleozoic and Triassic. By contrast, fault zones or the intersection of faults are favorable sites for the formation of the Jurassic to Early-Cretaceous Cu (-Mo) deposits. Porphyry Mo (-Cu) deposits in the Great Xing’an Range, however, are located in both juvenile and reworked crustal domains. The Permian to Triassic Mo (-Cu) deposits have different magmatic sources under different tectonic settings. During the Jurassic to Early-Cretaceous, a transition of the tectonic regime from compression to extension is conducive to the large-scale porphyry Mo mineralization event. This study demonstrates the usefulness of Hf isotopic mapping as a tool in characterizing the relationship between crustal architecture and porphyry deposits’ locations and types, and provides a better focus for further exploration for porphyry deposits regionally.
斑岩矿床是世界上铜、钼的主要来源。中国东北部的大兴安岭以其丰富的钼矿而闻名,其中一些钼矿规模巨大(如50万吨)。区内共发现斑岩型Mo (-Cu)矿床27个,斑岩型Cu (-Mo)矿床14个。这些矿床的形成是否以及如何受到区域地壳结构的控制尚不清楚。本文综合了大兴安岭古生代-中生代长英质岩和斑岩型Cu (-Mo)、Mo (-Cu)矿床的地质地球化学资料(包括锆石U-Pb测年结果和Lu-Hf同位素组成),并利用锆石Hf同位素填图对地壳结构进行了成像。结果表明,研究区大部分为幼年地壳域,地幔对其形成有重要贡献。额尔古纳地块北部和松辽增生地体西南部分别以古陆域和改造陆域为特征。斑岩型Cu (-Mo)矿床主要赋存于εHf(t) (>+3)值较高的幼龄地壳域中,其分布受北东向构造体系控制。高Sr/Y和高氧逸度弧岩浆与早古生代和三叠纪俯冲相关斑岩型Cu (-Mo)矿床的形成有关。断裂带或断交是侏罗纪至早白垩世铜(钼)矿床形成的有利部位。而大兴安岭的斑岩型钼(铜)矿床则分布在幼期和改造后的地壳域中。二叠系—三叠系钼(铜)矿床在不同的构造背景下具有不同的岩浆来源。侏罗纪至早白垩世,构造体制由挤压向伸展转变,有利于大规模斑岩钼矿化事件的发生。研究结果表明,Hf同位素填图可作为表征地壳结构与斑岩矿床位置和类型关系的有效工具,为斑岩矿床的进一步区域勘探提供了更好的重点。
{"title":"Crustal architecture controls on porphyry Cu and Mo fertility: constraints from zircon Hf isotopic mapping in the Great Xing’an Range, NE China","authors":"Lijun Liu ,&nbsp;Qihai Shu ,&nbsp;Kai Xing ,&nbsp;Jinyu Liu ,&nbsp;Litian Zhang ,&nbsp;Qingfei Wang ,&nbsp;Jun Deng","doi":"10.1016/j.earscirev.2025.105319","DOIUrl":"10.1016/j.earscirev.2025.105319","url":null,"abstract":"<div><div>Porphyry deposits are the major source of copper and molybdenum of the world. The Great Xing’an Range in northeastern China is widely known for its abundant Mo deposits, some of which have giant sizes (i.e., &gt;0.5 Mt Mo). In total, there are 27 porphyry Mo (-Cu) deposits and 14 porphyry Cu (-Mo) deposits in the region. Whether and how the formation of these deposits was controlled by the regional crust architecture remains unclear. Here, we integrated geologic and geochemical data (including zircon U-Pb dating results and Lu-Hf isotopic compositions) for the Paleozoic-Mesozoic felsic rocks and porphyry Cu (-Mo) and Mo (-Cu) deposits in the Great Xing’an Range, and imaged the crustal architecture by zircon Hf isotopic mapping. The results indicate that most of the study area is of juvenile crustal domains, with a significant mantle contribution in their formation. The northern Erguna Block and the southwestern Songliao Accretionary Terrane are characterized by ancient and reworked crustal domains, respectively. Porphyry Cu (-Mo) deposits are predominantly located in these juvenile crustal domains with high ε<sub>Hf</sub>(t) (&gt;+3) values, and their distribution was controlled by the NE-trending tectonic systems. High Sr/Y and high oxygen fugacity arc magmas are associated with the formation of the subduction-related porphyry Cu (-Mo) deposits during the Early-Paleozoic and Triassic. By contrast, fault zones or the intersection of faults are favorable sites for the formation of the Jurassic to Early-Cretaceous Cu (-Mo) deposits. Porphyry Mo (-Cu) deposits in the Great Xing’an Range, however, are located in both juvenile and reworked crustal domains. The Permian to Triassic Mo (-Cu) deposits have different magmatic sources under different tectonic settings. During the Jurassic to Early-Cretaceous, a transition of the tectonic regime from compression to extension is conducive to the large-scale porphyry Mo mineralization event. This study demonstrates the usefulness of Hf isotopic mapping as a tool in characterizing the relationship between crustal architecture and porphyry deposits’ locations and types, and provides a better focus for further exploration for porphyry deposits regionally.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105319"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145435069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tectonic influence on the characteristics of contourite systems 构造对轮廓岩体系特征的影响
IF 1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-13 DOI: 10.1016/j.earscirev.2025.105327
Zhi Lin Ng , Shan Liu , Hui Chen , Shaoru Yin , F. Javier Hernández-Molina , Débora F.P. Duarte , Xinyu Xue , Zhixuan Lin , Kunwen Luo , Ming Su
Tectonic influence on bottom current processes, particularly in active margin settings, may result in contourite deposits that are morphologically distinct from those developed along passive margins. Despite numerous works on the role of tectonics in the development of contourites deposits and the evolution of water mass circulation, there remains limited consensus on standardised criteria for the identification and characterisation of contourite drifts. The aim of our study is to distinguish the various tectonic controls on contourite deposition through a comprehensive review of existing knowledge, supported by morphologic characterisation, morphometric quantification, and statistical analysis of the dimensional relationship between structural and contourite features. We present three representative analogues from the South China Sea that illustrate depositional, erosional, and mixed features of both its modern and ancient contourite systems, and compare them with the well-known Gulf of Cádiz contourite systems.
Tectonically-influenced contourite systems can be classified into three categories based on structural control: confined, fault-controlled, and obstacle-controlled drifts. The associated tectonic structures and movements—such as uplift and subsidence—affect both the external geometry and internal configuration of the drifts. To better capture the complexity of tectonic influence on contourite deposition, several conceptual models are summarised for each type of structural control, and a revised classification framework for contourite drifts is proposed.
Regional tectonic evolution also plays a crucial role in contourite development, governing their evolutionary phases—onset, growth, and buried-stages. Their long-term evolution is further influenced by global events associated with reconfiguration of oceanic gateways and changes in circulation patterns, driven by the coupling of astronomical and tectonic processes and modulated by orbital-scale variations in bottom current activity. The role of tectonics in contourite deposition carries significant geological implications—contourite drift architecture, sedimentary facies distribution, sediment supply and accommodation, seafloor stability and geohazards—as well as economic relevance to the energy sector and marine ecosystems.
构造对底流过程的影响,特别是在活动边缘环境中,可能导致轮廓岩矿床在形态上与被动边缘发育的矿床不同。尽管有许多关于构造在等长岩沉积发育和水团循环演化中的作用的工作,但在等长岩漂移的识别和表征的标准化标准上仍然存在有限的共识。我们的研究目的是通过对现有知识的全面回顾,在形态表征、形态计量量化和构造与等高线特征之间的维度关系的统计分析的支持下,区分各种构造对等高线沉积的控制。本文提出了南海三个具有代表性的相似物,说明了其现代和古代轮廓岩体系的沉积、侵蚀和混合特征,并与著名的Cádiz轮廓岩体系海湾进行了比较。根据构造控制,构造影响的轮廓岩系统可分为三类:封闭、断层控制和障碍物控制的漂移。相关的构造构造和运动——如隆起和下沉——影响着漂流的外部几何形状和内部形态。为了更好地反映构造对轮廓岩沉积影响的复杂性,本文总结了不同类型构造控制的几种概念模型,并提出了一种修正的轮廓岩漂移分类框架。区域构造演化对等长岩的发育也起着至关重要的作用,控制着等长岩的发育阶段、生长阶段和埋藏阶段。它们的长期演变进一步受到与海洋门户重新配置和环流模式变化相关的全球事件的影响,这些事件是由天文和构造过程耦合驱动的,并受到底部洋流活动的轨道尺度变化的调节。构造在等长岩沉积中的作用具有重要的地质意义-等长岩漂移结构,沉积相分布,沉积物供应和容纳,海底稳定性和地质灾害-以及与能源部门和海洋生态系统的经济相关性。
{"title":"Tectonic influence on the characteristics of contourite systems","authors":"Zhi Lin Ng ,&nbsp;Shan Liu ,&nbsp;Hui Chen ,&nbsp;Shaoru Yin ,&nbsp;F. Javier Hernández-Molina ,&nbsp;Débora F.P. Duarte ,&nbsp;Xinyu Xue ,&nbsp;Zhixuan Lin ,&nbsp;Kunwen Luo ,&nbsp;Ming Su","doi":"10.1016/j.earscirev.2025.105327","DOIUrl":"10.1016/j.earscirev.2025.105327","url":null,"abstract":"<div><div>Tectonic influence on bottom current processes, particularly in active margin settings, may result in contourite deposits that are morphologically distinct from those developed along passive margins. Despite numerous works on the role of tectonics in the development of contourites deposits and the evolution of water mass circulation, there remains limited consensus on standardised criteria for the identification and characterisation of contourite drifts. The aim of our study is to distinguish the various tectonic controls on contourite deposition through a comprehensive review of existing knowledge, supported by morphologic characterisation, morphometric quantification, and statistical analysis of the dimensional relationship between structural and contourite features. We present three representative analogues from the South China Sea that illustrate depositional, erosional, and mixed features of both its modern and ancient contourite systems, and compare them with the well-known Gulf of Cádiz contourite systems.</div><div>Tectonically-influenced contourite systems can be classified into three categories based on structural control: <em>confined</em>, <em>fault-controlled</em>, and <em>obstacle-controlled drifts</em>. The associated tectonic structures and movements—such as uplift and subsidence—affect both the external geometry and internal configuration of the drifts. To better capture the complexity of tectonic influence on contourite deposition, several conceptual models are summarised for each type of structural control, and a revised classification framework for contourite drifts is proposed.</div><div>Regional tectonic evolution also plays a crucial role in contourite development, governing their evolutionary phases—<em>onset</em>, <em>growth</em>, and <em>buried</em>-stages. Their long-term evolution is further influenced by global events associated with reconfiguration of oceanic gateways and changes in circulation patterns, driven by the coupling of astronomical and tectonic processes and modulated by orbital-scale variations in bottom current activity. The role of tectonics in contourite deposition carries significant geological implications—contourite drift architecture, sedimentary facies distribution, sediment supply and accommodation, seafloor stability and geohazards—as well as economic relevance to the energy sector and marine ecosystems.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"272 ","pages":"Article 105327"},"PeriodicalIF":10.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145525060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Earth-Science Reviews
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1