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A Comprehensive Review of Phase Change Memory for Neuromorphic Computing: Advancements, Challenges, and Future Directions 面向神经形态计算的相变记忆研究综述:进展、挑战和未来方向
Pub Date : 2025-09-23 DOI: 10.1002/est2.70272
Vikas Bhatnagar, Adesh Kumar

The human brain functions as a highly efficient control center, inspiring the field of neuromorphic computing, which seeks to replicate its structure and behavior through hardware systems. Neuromorphic computing integrates processing and memory functions using artificial neurons and synapses designed with electronic circuits, enabling parallel, energy-efficient data handling. One of the leading technologies supporting this paradigm is phase change memory (PCM), a non-volatile memory that stores data through reversible transitions between amorphous (high resistance) and crystalline (low resistance) states of chalcogenide materials, particularly Ge2Sb2Te5 (GST225). PCM exhibits fast read/write speeds, excellent data retention, and scalability, making it ideal for neuromorphic architectures. This review highlights recent advancements in PCM for neuromorphic computing, including innovations in doping strategies and device engineering. Notable developments include arsenic-doped ovonic threshold switches (OTS) for enhanced selector performance, monolayer Sb2Te3 for atomic-scale devices, and heater-all-around (HAA) 3D architectures for reduced energy consumption. Integration with machine learning tools enables precise atomistic modeling, accelerating material and device optimization. Furthermore, emerging variants like ovonic unified memory (OUM) and interfacial PCM (IPCM) offer unique performance advantages. While PCM promises significant benefits, key challenges such as resistance drift, endurance limits, and thermal crosstalk must be addressed. The global neuromorphic computing market is poised for exponential growth, driven by innovations in materials, algorithms, and architectures. The PCM and neuromorphic computing represent a transformative leap toward intelligent, adaptive, and energy-efficient computing systems.

人脑是一个高效的控制中心,激发了神经形态计算领域的发展,该领域寻求通过硬件系统复制人脑的结构和行为。神经形态计算利用设计有电子电路的人工神经元和突触集成处理和记忆功能,实现并行、节能的数据处理。支持这种范式的领先技术之一是相变存储器(PCM),这是一种非易失性存储器,通过硫系材料(特别是Ge2Sb2Te5 (GST225))的非晶态(高电阻)和晶体(低电阻)状态之间的可逆转换来存储数据。PCM具有快速的读/写速度,出色的数据保留和可扩展性,使其成为神经形态架构的理想选择。本文综述了神经形态计算中PCM的最新进展,包括掺杂策略和设备工程方面的创新。值得注意的发展包括用于增强选择器性能的砷掺杂椭圆阈值开关(OTS),用于原子尺度器件的单层Sb2Te3,以及用于降低能耗的加热器全能(HAA) 3D架构。与机器学习工具的集成可实现精确的原子建模,加速材料和设备优化。此外,像椭圆统一存储器(OUM)和接口PCM (IPCM)这样的新兴变体提供了独特的性能优势。虽然PCM具有显著的优势,但必须解决诸如电阻漂移、耐用性限制和热串扰等关键挑战。在材料、算法和架构创新的推动下,全球神经形态计算市场将呈指数级增长。PCM和神经形态计算代表了向智能、自适应和节能计算系统的转型飞跃。
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引用次数: 0
Advanced Battery Thermal Management: A Review of Materials, Cooling Systems, and Intelligent Control for Safety and Performance 先进电池热管理:材料、冷却系统和安全性能智能控制综述
Pub Date : 2025-09-23 DOI: 10.1002/est2.70273
Alberto Boretti

Thermal management systems have become increasingly important in addressing the critical challenges associated with lithium-ion battery operation. Proper temperature regulation is essential for maintaining safety, optimizing electrochemical performance, and extending cycle life. This review provides a comprehensive and structured analysis of the latest developments in battery thermal management systems (BTMS), encompassing foundational commercial systems and advanced active, passive, and hybrid cooling strategies. The discussion integrates insights from materials science, thermodynamics, systems engineering, and artificial intelligence-based control strategies. Among the most significant advancements are phase change materials (PCMs) with enhanced thermal conductivity, such as graphene-reinforced paraffin composites, which improve heat absorption and dissipation. Another key innovation is the use of microchannel liquid cooling systems, particularly those optimized through advanced topological design techniques, enabling more efficient heat transfer. Additionally, intelligent control mechanisms, including digital twin-assisted thermal management systems, allow for real-time monitoring and adaptive cooling strategies. The review critically examines the trade-offs between cooling performance, energy efficiency, and cost considerations, evaluating technologies based on key performance indicators. It also highlights several transformative developments, including self-healing thermal interface materials, 3D-printed microchannel cold plates, radiative cooling surfaces, and smart, self-regulating materials. Looking ahead, emerging frontiers such as digital twin-assisted thermal control, blockchain for lifecycle management, and quantum-optimized design are identified as promising next-generation solutions with potential to enhance scalability and sustainability. These innovations have the potential to significantly improve thermal management in both electric vehicles and grid-scale energy storage applications, ensuring safer and more reliable battery operation.

热管理系统在解决与锂离子电池运行相关的关键挑战方面变得越来越重要。适当的温度调节对于维持安全、优化电化学性能和延长循环寿命至关重要。本文对电池热管理系统(BTMS)的最新发展进行了全面和结构化的分析,包括基本的商业系统和先进的主动、被动和混合冷却策略。讨论整合了材料科学,热力学,系统工程和基于人工智能的控制策略的见解。其中最显著的进步是具有增强导热性的相变材料(PCMs),如石墨烯增强石蜡复合材料,可以改善吸热和散热。另一个关键的创新是使用微通道液体冷却系统,特别是那些通过先进的拓扑设计技术进行优化的系统,从而实现更有效的传热。此外,智能控制机制,包括数字双辅助热管理系统,允许实时监控和自适应冷却策略。该评论严格审查了冷却性能,能源效率和成本考虑之间的权衡,并根据关键性能指标评估技术。它还强调了几个变革性的发展,包括自修复热界面材料,3d打印微通道冷板,辐射冷却表面和智能,自我调节材料。展望未来,数字双辅助热控制、区块链生命周期管理和量子优化设计等新兴领域被认为是有前景的下一代解决方案,具有增强可扩展性和可持续性的潜力。这些创新有可能显著改善电动汽车和电网规模储能应用的热管理,确保电池更安全、更可靠地运行。
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引用次数: 0
Comparative Evaluation of Phase Change Materials and Fins in Battery Thermal Management During High Discharge 相变材料与散热片在高放电条件下电池热管理中的比较评价
Pub Date : 2025-09-19 DOI: 10.1002/est2.70271
Sk Mohammad Shareef, G. Amba Prasad Rao

The rise of electric vehicles (EVs), driven by pollution-control policies, relies on lithium-ion batteries that face performance issues from temperature fluctuations. Thermal runaway remains a major safety risk, highlighting the need for efficient battery thermal management systems (BTMS). The present work numerically investigates the effectiveness of phase change materials (PCMs) and fins in BTMS performance. An 8-cell module operating at an 8C discharge rate was selected for analysis. ANSYS-based simulations were conducted to analyze the thermal behavior of prismatic battery modules under high discharge conditions. Both organic and inorganic PCMs were evaluated, alongside fins of varied geometry, orientation, and number. Results show that high thermal conductivity PCM, such as capric acid, lowered peak battery temperatures by 36 K compared to modules without cooling. Under natural convection, vertical fins were more effective than horizontal fins, whereas under elevated convective heat transfer coefficients (50 W/m2·K), horizontal fins achieved a 31 K reduction relative to no cooling. The combined effects of high thermal conductivity and specific heat capacity of PCMs were found to be critical for thermal regulation. Optimized PCM thickness outperformed fin-only configurations in overall effectiveness. However, achieving the right balance between fins and PCM remains essential for compactness and practical design integration. The advanced thermal management strategies improve battery safety and reliability and effectively address the United Nations Sustainable Development Goals.

在污染控制政策的推动下,电动汽车(ev)的兴起依赖于锂离子电池,而锂离子电池面临着温度波动带来的性能问题。热失控仍然是一个主要的安全风险,突出了对高效电池热管理系统(BTMS)的需求。本文对相变材料(PCMs)和翅片对BTMS性能的影响进行了数值研究。选择在8C放电速率下工作的8电池模块进行分析。采用ansys软件对柱形电池模块在高放电条件下的热行为进行了仿真分析。评估了有机和无机pcm,以及不同几何形状,方向和数量的鳍。结果表明,与没有冷却的组件相比,高导热PCM(如癸酸)可将电池峰值温度降低36 K。在自然对流条件下,垂直翅片比水平翅片更有效,而在对流换热系数提高(50 W/m2·K)的情况下,水平翅片相对于无冷却可以减少31 K。发现高导热系数和比热容的综合效应对PCMs的热调节至关重要。优化后的PCM厚度在整体效率上优于仅鳍的配置。然而,在翅片和PCM之间取得适当的平衡对于紧凑性和实际设计集成仍然至关重要。先进的热管理战略提高了电池的安全性和可靠性,有效地实现了联合国可持续发展目标。
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引用次数: 0
Thermal Performance of Erythritol-Based Biochar Composites for Medium-Temperature Energy Storage Applications 中温储能应用中赤藓糖醇基生物炭复合材料的热性能
Pub Date : 2025-09-19 DOI: 10.1002/est2.70276
G. Suresh Babu, A. Saikiran, K. Ravi Kumar, Chigilipalli Bharat Kumar, Ramakrishna Raghutu, Seepana Praveenkumar, Damodara Reddy Annapureddy, G. V. Krishna Pradeep, B. Devaraj Naik

The present study focuses on the development of erythritol-based activated biochar composite phase change materials (PCMs) targeting medium-temperature energy storage applications, including waste heat recovery, solar desalination, and solar thermal energy storage. The activated biochar composites were produced from coconut shell using pyrolysis. The fabricated samples were characterized using X-ray diffraction (XRD), differential scanning calorimetry (DSC), and Fourier-transform infrared spectroscopy (FTIR) to evaluate the phase composition, thermal properties, and functional group analysis of the composites. Biochar composites exhibited enhanced thermal energy storage properties and thermal stability compared to pure PCM. TGA was employed to assess weight changes during controlled temperature increase to analyze thermal stability and decomposition. The degradation kinetics for both materials were evaluated to determine the activation energy needed for degradation processes using Kissinger–Akahira–Sunose (KAS), Flynn–Wall–Ozawa (FWO), and Starink models. The results indicate that the activation energies for pure PCM, determined using the KAS, FWO, and Starink methods, are 82.81, 88.04, and 83.54 kJ/mol, respectively. For PCM + 0.25% G + 20% BC, activation energies varied between 325.67 and 347.37 kJ/mol. For PCM + 0.5% G + 20% BC, activation energies varied between 235.05 and 256.94 kJ/mol. For PCM + 20% BC, activation energies varied between 13.83 and 24.10 kJ/mol. Overall, the findings highlight the impact of graphene with biochar on the thermal properties of both pure and composite biochar PCMs. The 20% biochar composite with 0.25% graphene demonstrated improved thermal stability, highlighting its potential for effective medium-temperature energy storage solutions.

本研究的重点是开发以赤藓糖醇为基础的活性生物炭复合相变材料(PCMs),以实现废热回收、太阳能脱盐和太阳能热能储存等中温储能应用。以椰壳为原料,采用热解法制备活性炭复合材料。利用x射线衍射(XRD)、差示扫描量热法(DSC)和傅里叶变换红外光谱(FTIR)对制备的样品进行表征,评估复合材料的物相组成、热性能和官能团分析。与纯PCM相比,生物炭复合材料具有更强的储热性能和热稳定性。采用热重热分析(TGA)对其在控制升温过程中的重量变化进行评价,分析其热稳定性和分解情况。采用Kissinger-Akahira-Sunose (KAS)、Flynn-Wall-Ozawa (FWO)和Starink模型对两种材料的降解动力学进行了评估,以确定降解过程所需的活化能。结果表明,采用KAS法、FWO法和Starink法测定纯PCM的活化能分别为82.81、88.04和83.54 kJ/mol。PCM + 0.25% G + 20% BC的活化能为325.67 ~ 347.37 kJ/mol。PCM + 0.5% G + 20% BC的活化能在235.05 ~ 256.94 kJ/mol之间变化。PCM + 20% BC的活化能在13.83 ~ 24.10 kJ/mol之间变化。总的来说,研究结果强调了石墨烯与生物炭对纯生物炭和复合生物炭pcm的热性能的影响。含有0.25%石墨烯的20%生物炭复合材料表现出更好的热稳定性,突出了其作为有效中温储能解决方案的潜力。
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引用次数: 0
A Review on Battery and Energy Management for Redox Flow Batteries 氧化还原液流电池及其能量管理研究进展
Pub Date : 2025-09-18 DOI: 10.1002/est2.70267
Anshul Kumar Yadav,  Dhiraj, Anil Kumar Saini

Battery technology has been a hot spot in the research community, owing to the radical unification of renewable sources into the electric power industry. Redox flow batteries (RFBs), which are electrolyte-based, are preferred and have found viable applications in microgrids (MGs) due to their scalable nature, operational flexibility, and environmental friendliness. Acknowledging the complexity of the MG system and the importance of effective battery operation, this paper presents a systematic and comprehensive review on battery and energy management for RFBs. Utilizing the bibliographical analysis, this research critically examines the existing literature on battery and energy management, their research trends, and associated challenges. The summary reveals that existing approaches lack the implementation of advanced techniques that enable experiential learning and tailored operational strategies required for safer, reliable operation in convergence with other energy sources. Considering the challenges, the paper emphasizes emerging technology, including artificial intelligence (AI), system modeling, and digital twins (DTs), for effective development, monitoring, and furthering reliability in RFB. IoT-integrated BMS and Energy Management System (EMS) systems can aid data collection, allowing integration of intelligence systems performing accurate forecasting and system optimization, whereas AI agents can help with cybersecurity and fault response, realizing state-of-the-art battery/EMS. Subsequently, existing drawbacks and future prospects are presented for the research community and are expected to act as a catalyst to advance EMS and BMS research, tailored for RFB.

由于可再生能源与电力工业的彻底统一,电池技术一直是研究界的热点。氧化还原液流电池(rfb)是一种基于电解质的电池,由于其可扩展性、操作灵活性和环境友好性,在微电网(mg)中已经找到了可行的应用。考虑到MG系统的复杂性和电池有效运行的重要性,本文对rfb的电池和能量管理进行了系统和全面的综述。利用文献分析,本研究批判性地考察了电池和能源管理的现有文献,他们的研究趋势,以及相关的挑战。总结表明,现有的方法缺乏先进的技术,无法实现经验学习和量身定制的操作策略,从而无法与其他能源融合,实现更安全、可靠的操作。考虑到这些挑战,本文强调了新兴技术,包括人工智能(AI)、系统建模和数字孪生(DTs),以有效地开发、监测和进一步提高RFB的可靠性。物联网集成的BMS和能源管理系统(EMS)系统可以帮助数据收集,允许智能系统集成,执行准确的预测和系统优化,而人工智能代理可以帮助网络安全和故障响应,实现最先进的电池/EMS。随后,对研究界提出了现有的缺点和未来的展望,并期望作为促进针对RFB的EMS和BMS研究的催化剂。
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引用次数: 0
Resilient Photovoltaic-Battery Systems for Urban Households in Grid-Interrupted Environments: A Baghdad Case Study 电网中断环境下城市家庭弹性光伏电池系统:巴格达案例研究
Pub Date : 2025-09-16 DOI: 10.1002/est2.70264
Raghad Ali Mejeed

Since 1991 to the present, both metropolitan districts and rural communities in Iraq have been reliant on gasoline or diesel generators to make up for the lack of grid energy. The combination of Photovoltaic (PV) and Battery Storage systems (BSS) as energy sources is widespread in the global energy industry. This case study is based on actual monthly electricity consumption statistics over 1 year for a home in the Al-Latifiya district, south of Baghdad, Iraq, to install a roof PV system instead of a Diesel Generator (DG) to compensate for the interruption of the public grid. Using computer modeling and simulation with the HOMER software, an optimal power generation system was designed. Two modeling scenarios were conducted, one for DG and the grid and the other for PV/BSS and the grid. Based on simulation findings, the PV/BSS and grid systems have been determined to be a technically and economically viable solution for mitigating DG and implementing this alternative power generation at a fair cost. The proposed system can meet the demand side with a penetration level of 60.4% and a PV energy share of 48.4%, resulting in a reduction in electricity bills to $108.58/year and a lower COE ($0.0772/kWh) than the current system (grid and diesel generator) ($0.0.126/kWh). The proposed system also achieved an annual emissions reduction of 5279 kg of CO2 per year due to displacing the fuel consumption of diesel generators and reducing the energy use of the public grid by 31%.

从1991年至今,伊拉克的大都市地区和农村社区都依赖汽油或柴油发电机来弥补电网能源的不足。光伏(PV)和电池储能系统(BSS)作为能源的结合在全球能源工业中得到广泛应用。本案例研究基于伊拉克巴格达南部Al-Latifiya地区一户家庭一年来每月实际用电量统计数据,该家庭安装了屋顶光伏系统,而不是柴油发电机(DG),以补偿公共电网的中断。利用HOMER软件进行计算机建模和仿真,设计了最优发电系统。分别对DG和电网、PV/BSS和电网进行了两种建模场景。根据模拟结果,PV/BSS和电网系统已被确定为技术上和经济上可行的解决方案,可以减少DG,并以合理的成本实施这种替代发电。拟议的系统能够以60.4%的渗透水平和48.4%的光伏能源份额满足需求方,从而将电费减少到108.58美元/年,COE(0.0772美元/千瓦时)低于当前系统(电网和柴油发电机)(0.0.126美元/千瓦时)。由于取代了柴油发电机的燃料消耗,并将公共电网的能源消耗减少了31%,拟议中的系统每年还减少了5279公斤的二氧化碳排放量。
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引用次数: 0
Co-Estimation of State of Health and State of Charge for Lithium-Ion Batteries via the Normalized State of Charge and Open Circuit Voltage Relationship 基于归一化充电状态和开路电压关系的锂离子电池健康状态和充电状态联合估计
Pub Date : 2025-09-16 DOI: 10.1002/est2.70270
Onur Kadem

The relationship between state of charge (SoC) and open circuit voltage (OCV) is fundamental to SoC estimation in equivalent circuit models (ECMs). While its dependency on temperature and aging is recognized, the influence of real-time capacity variations is often underexplored. This study investigates the impact of capacity degradation on the SoC–OCV relationship across different temperatures, aging levels, and OCV testing methods, using the CALCE and NASA battery datasets. Results show that when SoC is normalized by the degraded capacity, the SoC–OCV relationship remains nearly constant for SoC values above 20%. Leveraging this property, we propose a real-time algorithm capable of simultaneously estimating SoC and capacity throughout the battery lifecycle. The algorithm also estimates state of health (SoH) by independently quantifying resistance and capacity related degradation. A first-order ECM with a single resistor-capacitor branch models battery dynamics, while Kalman filtering enables real-time state updates. The method is validated under diverse conditions including partial and full discharges, varying temperatures, dynamic load profiles (e.g., US06, FUDS, BJDST, HPPC), and different aging states. Experimental results demonstrate robust performance, with SoC estimation errors within ±0.01 and capacity estimation errors within ±0.05 Ah, confirming the algorithm's effectiveness for real-world battery management system applications.

荷电状态(SoC)与开路电压(OCV)之间的关系是等效电路模型(ecm)中荷电状态估计的基础。虽然它对温度和老化的依赖性是公认的,但实时容量变化的影响往往没有得到充分的探讨。本研究使用CALCE和NASA电池数据集,研究了不同温度、老化水平和OCV测试方法下容量退化对SoC-OCV关系的影响。结果表明,当SoC被退化容量归一化时,SoC - ocv关系在SoC值大于20%时基本保持不变。利用这一特性,我们提出了一种能够在整个电池生命周期中同时估计SoC和容量的实时算法。该算法还通过独立量化阻力和容量相关退化来估计健康状态(SoH)。一阶ECM与一个单一的电阻-电容分支模型电池动力学,而卡尔曼滤波实现实时状态更新。该方法在不同条件下进行了验证,包括部分放电和完全放电、不同温度、动态负载分布(例如US06、FUDS、BJDST、HPPC)和不同的老化状态。实验结果表明,该算法性能稳健,SoC估计误差在±0.01 Ah以内,容量估计误差在±0.05 Ah以内,验证了该算法在实际电池管理系统应用中的有效性。
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引用次数: 0
A Grid-Friendly Multi-Objective Approach for Energy Scheduling Optimization in Microgrids 微电网友好型多目标能源调度优化方法
Pub Date : 2025-09-16 DOI: 10.1002/est2.70254
Zhihua Chen, Ruochen Huang, Qiongbin Lin

This paper proposes a novel grid-friendly multi-objective approach to optimize energy management in an integrated source-grid-load-storage microgrid (MG). To enhance the MG's grid integration potential and cost-effectiveness, this approach develops a grid-friendly multi-timescale energy scheduling optimization (Gf-MtESO) strategy and a new evaluation metric (ωGf$$ {omega}_{mathrm{Gf}} $$). Gf-MtESO first establishes electricity market coordination by pre-submitting energy demand as subsequent scheduling constraints, effectively mitigating power exchange fluctuations between MGs and the main grid. Additionally, ωGf$$ {omega}_{mathrm{Gf}} $$, by holistically evaluating dependency and volatility, facilitates comprehensive assessment of MGs' grid integration potential. To resolve conflicting objectives and multi-constraints challenges in developing the Gf-MtESO strategy, this approach applies an improved elitist non-dominated sorting genetic algorithm based on stepwise-solving and rotating-population optimization (SRO-NSGA-II). SRO-NSGA-II first decouples the problem and updates the population using rotated binary crossovers to accelerate the search for feasible domains. Results indicate that SRO-NSGA-II concurrently maintains solution diversity and convergence speed, outperforming NSGA-II in hypervolume metrics. Particularly, the novel approach demonstrates faster scheduling plans development and improves grid-connection friendliness by 90.76% with a 4.86% cost variation compared to benchmark methods, which provide a systematic approach to realize friendly grid integration while ensuring economic viability in MGs' applications.

本文提出了一种新型的电网友好型多目标方法来优化源-网-负荷-蓄集成微电网(MG)的能量管理。为了提高MG的电网整合潜力和成本效益,该方法开发了电网友好型多时间尺度能源调度优化(Gf- mteso)策略和新的评估指标(ω Gf $$ {omega}_{mathrm{Gf}} $$)。Gf-MtESO首先通过预先提交能源需求作为后续调度约束,建立电力市场协调,有效缓解了mg与主电网之间的电力交换波动。此外,ω Gf $$ {omega}_{mathrm{Gf}} $$通过整体评估依赖性和波动性,促进了对mg电网整合潜力的综合评估。为解决Gf-MtESO策略制定过程中的目标冲突和多约束问题,该方法采用一种改进的基于逐步求解和旋转种群优化的精英非支配排序遗传算法(SRO-NSGA-II)。SRO-NSGA-II首先解耦问题,并使用旋转二进制交叉更新种群,以加速对可行域的搜索。结果表明,SRO-NSGA-II同时保持了解决方案的多样性和收敛速度,在超容量指标上优于NSGA-II。特别地,该方法可加快调度计划的制定速度,并网友好度提高90.76% with a 4.86% cost variation compared to benchmark methods, which provide a systematic approach to realize friendly grid integration while ensuring economic viability in MGs' applications.
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引用次数: 0
Manufacturing Challenges in Advanced Cylindrical Composite Pressure Vessels for Hydrogen Storage: A Comprehensive Review 用于储氢的先进圆柱形复合压力容器的制造挑战:综合综述
Pub Date : 2025-09-13 DOI: 10.1002/est2.70263
Samid Khan, Ajay Kumar

Advances in cylindrical high-end hydrogen storage systems for aerospace, undersea vacuum enclosures, and automobiles use Type V composite pressure vessels (CPV) as the next generation of sustainable energy storage. The latest liner-less CPV (Type V) is most challenging. The basic need of this manufacturing aspect review on CPV is the transition toward a more sustainable hydrogen energy storage system. As analyzed through our review that Type IV pressure vessels optimized with this transition to Type V, where weight reduction is up to > 25%, higher load-bearing efficiency is reported in past studies for Type V in comparison to Type IV vessels, with increase in volumetric density up to > 15% and more, and most importantly, hydrogen barrier performance as permeability is reduced from 10−12 to < 10−16 mol m−1 s−1 Pa−1 addressed. Type V pressure vessels eliminate the polymer liner, causing nonuniform stresses, which hinders in Type III/IV COPVs. This results in more uniform stress distribution and high burst performance at reduced mass. Studies show higher burst pressure and improved structural efficiency. At cryogenic CcH2 hydrogen storage of up to 35 MPa pressure with improved epoxies is also explored. Mechanical characteristics of cross-linked composite laminates, including thin films of clay, sand, polyethylene, and polyurethane, were also analyzed in the CcH2 storage system. Strengthening (Type IV) composite pressure vessels with proper fiber/matrix alignment and polyethylene films instead of a polyethylene liner causes embrittlement and failure due to composite and plastic ties. Various stacking sequences related to flaws have been explored, Type IV (plastic liner) composite pressure vessels for improvement in Type V CPV. Filament winding techniques and automated fiber placements (AFP) used for winding sequence and stacking geometries of helical, hoop, and polar composite winding layers reveal that at 55° helical, followed by hoop winding, provides the highest strength. Based on our comprehensive review, we found that the fabrication and permeability challenges of liner-less (Type V) vessels need further study. While recent advances in materials (e.g., high-performance resins, nanoparticle reinforcement) and manufacturing techniques (e.g., AFP, out-of-autoclave curing) show promise, consistent and scalable solutions to address hydrogen permeation and structural integrity in liner-less designs are still under active investigation.

用于航空航天、海底真空罩和汽车的圆柱形高端储氢系统的进展使用V型复合压力容器(CPV)作为下一代可持续储能。最新的无衬管CPV (V型)是最具挑战性的。对CPV制造方面的回顾的基本需求是向更可持续的氢储能系统过渡。通过我们的回顾分析,IV型压力容器经过优化后向V型转变,重量减轻了25%,与IV型容器相比,过去的研究报告显示V型压力容器的承载效率更高,体积密度增加了15%甚至更多,最重要的是,氢屏障性能从10−12 mol m−1 s−1 Pa−1降低到10−16 mol m−1。V型压力容器消除了聚合物衬垫,造成了不均匀的应力,这阻碍了III/IV型copv的开发。这导致更均匀的应力分布和高爆裂性能在减少质量。研究表明,爆破压力增大,结构效率提高。在低温CcH2下,改进环氧树脂的储氢压力可达35 MPa。研究了交联复合层压板(粘土、沙子、聚乙烯和聚氨酯薄膜)在CcH2储存系统中的力学特性。增强(IV型)复合压力容器采用适当的纤维/基体排列和聚乙烯薄膜代替聚乙烯衬垫,由于复合材料和塑料连接而导致脆化和失效。各种堆垛顺序与缺陷有关,IV型(塑料衬垫)复合压力容器在V型CPV上进行了改进。长丝缠绕技术和自动纤维放置(AFP)用于缠绕顺序和堆叠几何形状的螺旋、环向和极性复合缠绕层表明,在55°螺旋,然后是环向缠绕,提供最高的强度。基于我们的综合评估,我们发现无衬管(V型)容器的制造和渗透性挑战需要进一步研究。虽然材料(如高性能树脂、纳米颗粒增强)和制造技术(如AFP、非高压釜固化)的最新进展显示出前景,但解决无衬里设计中氢渗透和结构完整性的一致和可扩展的解决方案仍在积极研究中。
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引用次数: 0
Thermal Load and Carbon Emissions With Double Façade and BioPCM Configurations in Different Climates 不同气候条件下双farade和BioPCM配置的热负荷和碳排放
Pub Date : 2025-09-12 DOI: 10.1002/est2.70261
Merve Kılınç Gilisıralıoğlu, Neslihan Türkmenoğlu Bayraktar

Energy consumption and carbon emissions may be reduced by proper building envelope design. Innovative approaches such as PCM-integrated double-facade systems present an opportunity to increase energy efficiency. However, more scientific data is needed on the performance of these systems in different climate zones and various application scenarios for current local and global energy standards. Therefore, an annual simulation process on ten scenarios with Designbuilder is conducted to analyze the thermal load and carbon emission outputs of five locations with different heating–cooling degree days, varying due to PCMs and insulation layers on double façades. According to the study, the double façade system reduced the total energy load in the office building case in all climates. The double façade system mitigated the total load the most in Istanbul by 17%. BioPCM addition changed the carbon emissions and total loads depending on the building type and the conditions of its application, with or without insulation, in different climates. PCM usage reduced carbon emissions by 0.35% in Antalya while increasing the others. While the highest reduction rate of the total load, with 2.3%, occurred in Erzurum with the insulation and PCM combined case, the same occurred with only the PCM scenario in Antalya, by 1.9%. Accordingly, PCM integration without an insulation layer in hot climates significantly reduces total loads while applying insulation and PCM layers together in cold climates.

适当的建筑围护结构设计可减少能源消耗和碳排放。诸如pcm集成双立面系统等创新方法为提高能源效率提供了机会。然而,需要更多的科学数据来了解这些系统在不同气候带和不同应用场景下的性能,以满足当前的地方和全球能源标准。因此,利用Designbuilder进行了10种情景的年度模拟过程,分析了5个地点的热负荷和碳排放输出,这些地点的热负荷和碳排放输出由于双立面上的pcm和保温层的不同而不同。根据研究,双立面系统降低了办公大楼在所有气候条件下的总能量负荷。双farade系统在伊斯坦布尔最大程度上减轻了17%的总负荷。BioPCM的加入改变了碳排放量和总负荷,这取决于建筑类型及其应用条件,在不同的气候条件下,有或没有绝缘。在安塔利亚,PCM的使用减少了0.35%的碳排放,同时增加了其他碳排放。在绝缘和PCM结合的情况下,埃尔祖鲁姆的总负荷减减率最高,为2.3%,而安塔利亚的PCM情况相同,仅为1.9%。因此,在炎热气候下,不加保温层的PCM集成显著降低了总负荷,而在寒冷气候下,将保温层和PCM层一起应用。
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引用次数: 0
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Energy Storage
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