首页 > 最新文献

Food and Bioproducts Processing最新文献

英文 中文
Comparative analysis of RSM and ANN-GA based modeling for protein extraction from cotton seed meal: Effect of extraction parameters on amino acid profile and nutritional characteristics
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-12-26 DOI: 10.1016/j.fbp.2024.12.016
Kavita Ware , Piyush Kashyap , Pratik Madhukar Gorde , Rahul Yadav , Vipasha Sharma
Cottonseed meal (CSM), a residual biomass and valuable by-product, serves as a sustainable protein source, yielding approximately 10 million metric tons globally, enough to meet the annual protein requirements of over half a billion people. In this context, the study aimed to optimize protein extraction from CSM using response surface methodologies (RSM) and artificial neural networks with genetic algorithms (ANN-GA), while also examining its amino nutritional characteristics. The independent variables, pH (8.5–10.5), temperature (25–45 °C), solvent-solid ratio (10–30 mL/g) and time (1–3 h) were designed to optimize the responses protein yield and purity. Various statistical measures were computed to evaluate the errors and coefficients of determination for the projected models. The ANN model shows better results in forecasting protein production and purity, demonstrating superior accuracy and precision. The average mean percentage error (MPE) of the ANN model was lower for protein yield and purity as 0.673 % and 0.182 % compared to RSM 2.56 % and 0.685 % respectively. Under optimal conditions, ANN achieved higher protein yield and purity (28.03 %, 88.69 %) compared to RSM (23.24 %, 87.17 %). The CSM protein isolate contained all essential amino acids with high biological value (70.33) and essential amino acid score (75.26), indicating high-quality protein. This study offers significant insights into effective modeling approaches for protein extraction, highlights utility of ANN-GA in predictive assessments, and underscores the potential of agricultural waste as a cost-effective substrate for high-quality protein supplements in food products.
{"title":"Comparative analysis of RSM and ANN-GA based modeling for protein extraction from cotton seed meal: Effect of extraction parameters on amino acid profile and nutritional characteristics","authors":"Kavita Ware ,&nbsp;Piyush Kashyap ,&nbsp;Pratik Madhukar Gorde ,&nbsp;Rahul Yadav ,&nbsp;Vipasha Sharma","doi":"10.1016/j.fbp.2024.12.016","DOIUrl":"10.1016/j.fbp.2024.12.016","url":null,"abstract":"<div><div>Cottonseed meal (CSM), a residual biomass and valuable by-product, serves as a sustainable protein source, yielding approximately 10 million metric tons globally, enough to meet the annual protein requirements of over half a billion people. In this context, the study aimed to optimize protein extraction from CSM using response surface methodologies (RSM) and artificial neural networks with genetic algorithms (ANN-GA), while also examining its amino nutritional characteristics. The independent variables, pH (8.5–10.5), temperature (25–45 °C), solvent-solid ratio (10–30 mL/g) and time (1–3 h) were designed to optimize the responses protein yield and purity. Various statistical measures were computed to evaluate the errors and coefficients of determination for the projected models. The ANN model shows better results in forecasting protein production and purity, demonstrating superior accuracy and precision. The average mean percentage error (MPE) of the ANN model was lower for protein yield and purity as 0.673 % and 0.182 % compared to RSM 2.56 % and 0.685 % respectively. Under optimal conditions, ANN achieved higher protein yield and purity (28.03 %, 88.69 %) compared to RSM (23.24 %, 87.17 %). The CSM protein isolate contained all essential amino acids with high biological value (70.33) and essential amino acid score (75.26), indicating high-quality protein. This study offers significant insights into effective modeling approaches for protein extraction, highlights utility of ANN-GA in predictive assessments, and underscores the potential of agricultural waste as a cost-effective substrate for high-quality protein supplements in food products.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"150 ","pages":"Pages 63-77"},"PeriodicalIF":3.5,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143136379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Drying of orange juice waste in a mechanically stirred spouted bed
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-12-24 DOI: 10.1016/j.fbp.2024.12.017
Guilherme Henrique Alves Pinto , Xabier Sukunza , Martin Olazar , José Teixeira Freire , Fábio Bentes Freire
Orange juice waste is an agro-industrial bio-waste produced on large-scale, which may be transformed into a source of raw material through drying. Drying of orange juice solid residue was carried out in a mechanically stirred spouted bed equipped with four sets of equally spaced blades placed around the stirrer shaft. The experiments were conducted at temperatures between 40 and 80°C with air flow rates of 1–5 times the minimum spouting velocity. Mechanical agitation has proven to increase the movement of solids, especially in areas close to the internal wall. The pseudo-fluidized regime allowed improving both bed uniformity and process stability. The drying energy demand was 12.6–23.4 % of that of the conventional bed. During much of the drying time of the solid orange juice residue, the air was saturated at the exit due to the low air flow rates used in the process.
{"title":"Drying of orange juice waste in a mechanically stirred spouted bed","authors":"Guilherme Henrique Alves Pinto ,&nbsp;Xabier Sukunza ,&nbsp;Martin Olazar ,&nbsp;José Teixeira Freire ,&nbsp;Fábio Bentes Freire","doi":"10.1016/j.fbp.2024.12.017","DOIUrl":"10.1016/j.fbp.2024.12.017","url":null,"abstract":"<div><div>Orange juice waste is an agro-industrial bio-waste produced on large-scale, which may be transformed into a source of raw material through drying. Drying of orange juice solid residue was carried out in a mechanically stirred spouted bed equipped with four sets of equally spaced blades placed around the stirrer shaft. The experiments were conducted at temperatures between 40 and 80°C with air flow rates of 1–5 times the minimum spouting velocity. Mechanical agitation has proven to increase the movement of solids, especially in areas close to the internal wall. The pseudo-fluidized regime allowed improving both bed uniformity and process stability. The drying energy demand was 12.6–23.4 % of that of the conventional bed. During much of the drying time of the solid orange juice residue, the air was saturated at the exit due to the low air flow rates used in the process.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"150 ","pages":"Pages 89-97"},"PeriodicalIF":3.5,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143105210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable cultivation of Gracilaria edulis in poultry manure-derived media: Evaluating growth, biochemical properties, and agar quality
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-12-22 DOI: 10.1016/j.fbp.2024.12.015
G. Suriya narayanan, D. Ruben Sudhakar
Present study investigates the potential of Gracilaria edulis, a red seaweed and a valuable source of food grade agar, to mass generate seedlings without stimulants, to grow and produce biomass in poultry manure derived nutrients, and to possess industry standard physico-chemical & proximate compositional biochemical attributes post-cultivation. From this study, for the purpose of producing clonal planting material, G. edulis explants showed near 100 % regeneration in seedling development in incubation in PES medium. Simple and yet efficient water-sonicate method extracted substantial amount of nutrients from the poultry manure, and the resultant formulated poultry manure aqueous-sonicate extract supplemented seawater, in short PMES, was enriched with significant levels of micronutrients (Cu–5.3 µM, Zn–11.7 µM and Mn–28.4 µM), and macronutrients (N: 311–1555 µM and P: 12–63 µM) compared to sole seawater. In incubation with various concentration of PMES (1–5 %, v/v), G. edulis seedlings exhibited robust growth characteristics across all the PMES, with the highest daily growth rate (9.9 ± 0.9 % day⁻¹) and biomass yield (202.5 ± 12.6 mg dry weight L⁻¹) observed in 2 % PMES, which significantly surpassing the growth characteristics of G. edulis seedlings grown in sole seawater as growth medium. Resultant G. edulis produced biomass from this study had superior oil-holding capacity (3.60 g/g dry weight), substantial soluble polysaccharide content (31.47 % of dry weight), and ash content (44.93 % of dry weight), alongside considerable crude fibre content (7.73 % of dry weight) compared to wild G. edulis and other commercially important seaweeds. Moreover, the biomass had 26 % agar which was substantial and higher than that of its wild counterparts, with the extracted agar displaying characteristic functionalities, as confirmed by infrared spectroscopy and thermal analysis, comparable to commercial agar. These findings demonstrate that G. edulis as novel macroalgae and PMES as a sustainable cost-effective growth medium for seaweed cultivation, offering promising implications in agar and seaweed food industry.
{"title":"Sustainable cultivation of Gracilaria edulis in poultry manure-derived media: Evaluating growth, biochemical properties, and agar quality","authors":"G. Suriya narayanan,&nbsp;D. Ruben Sudhakar","doi":"10.1016/j.fbp.2024.12.015","DOIUrl":"10.1016/j.fbp.2024.12.015","url":null,"abstract":"<div><div>Present study investigates the potential of <em>Gracilaria edulis</em>, a red seaweed and a valuable source of food grade agar, to mass generate seedlings without stimulants, to grow and produce biomass in poultry manure derived nutrients, and to possess industry standard physico-chemical &amp; proximate compositional biochemical attributes post-cultivation. From this study, for the purpose of producing clonal planting material, <em>G. edulis</em> explants showed near 100 % regeneration in seedling development in incubation in PES medium. Simple and yet efficient water-sonicate method extracted substantial amount of nutrients from the poultry manure, and the resultant formulated poultry manure aqueous-sonicate extract supplemented seawater, in short PMES, was enriched with significant levels of micronutrients (Cu–5.3 µM, Zn–11.7 µM and Mn–28.4 µM), and macronutrients (N: 311–1555 µM and P: 12–63 µM) compared to sole seawater. In incubation with various concentration of PMES (1–5 %, v/v), <em>G. edulis</em> seedlings exhibited robust growth characteristics across all the PMES, with the highest daily growth rate (9.9 ± 0.9 % day⁻¹) and biomass yield (202.5 ± 12.6 mg dry weight L⁻¹) observed in 2 % PMES, which significantly surpassing the growth characteristics of <em>G. edulis</em> seedlings grown in sole seawater as growth medium. Resultant <em>G. edulis</em> produced biomass from this study had superior oil-holding capacity (3.60 g/g dry weight), substantial soluble polysaccharide content (31.47 % of dry weight), and ash content (44.93 % of dry weight), alongside considerable crude fibre content (7.73 % of dry weight) compared to wild <em>G. edulis</em> and other commercially important seaweeds. Moreover, the biomass had 26 % agar which was substantial and higher than that of its wild counterparts, with the extracted agar displaying characteristic functionalities, as confirmed by infrared spectroscopy and thermal analysis, comparable to commercial agar. These findings demonstrate that <em>G. edulis</em> as novel macroalgae and PMES as a sustainable cost-effective growth medium for seaweed cultivation, offering promising implications in agar and seaweed food industry.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"150 ","pages":"Pages 78-88"},"PeriodicalIF":3.5,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143136384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of fish gelatin hydrogels for enhanced biopolymer applications
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-12-20 DOI: 10.1016/j.fbp.2024.12.014
Wen-Long Cheng , Shan Shan , Sheng Shu , Guang-Xian Liu , Lin-Feng Yuan , Xiao-Mei Sha , Zong-Cai Tu
In this work, a novel fish gelatin (FG)-based hydrogel was synthesized, and various properties of the FG/Polyacrylamide (PAM) hydrogel were characterized including the properties of precursor, gelling process, mechanical and physical. With the FG mass ratio increased from 0 % to 10 %, the particle size of the solution increased from 0 nm to 673.67 nm, as well as the zeta potential shifted from negative (-1.57 mV) to positive (exceeds 11.0 mV). Moreover, the apparent viscosity of FG/Acrylamide (AAm) precursor solutions became more stable than that of the pure AAm solution. Eventually, during the gelling process, the gelation temperature of the FG/PAM hydrogel increased from 39.17°C to 64.19°C. The hydrogel exhibited over a 5-fold increase in compressive fatigue resistance at an 80 % strain level, with a maximum stress of 1.225 MPa (FG:AAm = 1.0:9.0) under various strain conditions. The microstructure of various FG/PAM hydrogels formed a spatially structured network and pores in the hydrogel. When FG content increased, the pores density became intensive and then loose. Additionally, the experiment results showed FG/PAM hydrogels exhibited excellent biodegradability. The findings of this study provide a foundation and promising prospect for further exploration and application of hydrogels incorporated with FG.
{"title":"Synthesis and characterization of fish gelatin hydrogels for enhanced biopolymer applications","authors":"Wen-Long Cheng ,&nbsp;Shan Shan ,&nbsp;Sheng Shu ,&nbsp;Guang-Xian Liu ,&nbsp;Lin-Feng Yuan ,&nbsp;Xiao-Mei Sha ,&nbsp;Zong-Cai Tu","doi":"10.1016/j.fbp.2024.12.014","DOIUrl":"10.1016/j.fbp.2024.12.014","url":null,"abstract":"<div><div>In this work, a novel fish gelatin (FG)-based hydrogel was synthesized, and various properties of the FG/Polyacrylamide (PAM) hydrogel were characterized including the properties of precursor, gelling process, mechanical and physical. With the FG mass ratio increased from 0 % to 10 %, the particle size of the solution increased from 0 nm to 673.67 nm, as well as the zeta potential shifted from negative (-1.57 mV) to positive (exceeds 11.0 mV). Moreover, the apparent viscosity of FG/Acrylamide (AAm) precursor solutions became more stable than that of the pure AAm solution. Eventually, during the gelling process, the gelation temperature of the FG/PAM hydrogel increased from 39.17°C to 64.19°C. The hydrogel exhibited over a 5-fold increase in compressive fatigue resistance at an 80 % strain level, with a maximum stress of 1.225 MPa (FG:AAm = 1.0:9.0) under various strain conditions. The microstructure of various FG/PAM hydrogels formed a spatially structured network and pores in the hydrogel. When FG content increased, the pores density became intensive and then loose. Additionally, the experiment results showed FG/PAM hydrogels exhibited excellent biodegradability. The findings of this study provide a foundation and promising prospect for further exploration and application of hydrogels incorporated with FG.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"150 ","pages":"Pages 25-34"},"PeriodicalIF":3.5,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143136389","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailored production of butyric acid from mixed culture fermentation of food waste
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-12-20 DOI: 10.1016/j.fbp.2024.12.013
Reema Kumar , Guneet Kaur , Satinder Kaur Brar
Volatile fatty acids (VFA) are high-value-added products obtained from the fermentation of waste feedstock. These are generally produced as a VFA mixture of C2 - C6 acids through mixed culture fermentation. The prospect of tailoring the process conditions in mixed culture fermentation is attractive since it can produce a predominance of a target VFA without the need for a sterile, pure culture-based process. Among VFAs, butyric acid has a wide range of industrial applications which are currently met by chemical synthesis. This study showed a targeted production of butyric acid in a mixed culture VFA fermentation under psychrophilic temperature. Compared to mesophilic conditions, the butyric acid produced at 17°C accumulated to up to 7 days at 0.5 g/L compared to in 37°C where it was not detected after day 1. The microbial community study showed the increased abundance of Sporosarcina and Solibacillus genus which degrades proteins, aiding the Clostridium_sensu_stricto spp. in producing butyric acid potentially through protein degradation. Within the detected bacterial diversity showing a lower Shannon index of 0.84 at 17ºC, these genera also showed a higher abundance. For further enhancing the hydrolysis, thermal-alkaline pretreatment of food waste was performed. However, it reduced the subsequent production of butyric acid as compared to untreated food waste. Under 17ºC, butyric acid’s concentration was 0.06 g/L, while at 37ºC, it was 0.12 g/L. This showed that intrinsic microflora of food waste was essential for its production. This selective accumulation of butyric acid over other VFAs offers a means of targeted VFA production using mixed culture fermentation under psychrophilic temperature.
{"title":"Tailored production of butyric acid from mixed culture fermentation of food waste","authors":"Reema Kumar ,&nbsp;Guneet Kaur ,&nbsp;Satinder Kaur Brar","doi":"10.1016/j.fbp.2024.12.013","DOIUrl":"10.1016/j.fbp.2024.12.013","url":null,"abstract":"<div><div>Volatile fatty acids (VFA) are high-value-added products obtained from the fermentation of waste feedstock. These are generally produced as a VFA mixture of C2 - C6 acids through mixed culture fermentation. The prospect of tailoring the process conditions in mixed culture fermentation is attractive since it can produce a predominance of a target VFA without the need for a sterile, pure culture-based process. Among VFAs, butyric acid has a wide range of industrial applications which are currently met by chemical synthesis. This study showed a targeted production of butyric acid in a mixed culture VFA fermentation under psychrophilic temperature. Compared to mesophilic conditions, the butyric acid produced at 17°C accumulated to up to 7 days at 0.5 g/L compared to in 37°C where it was not detected after day 1. The microbial community study showed the increased abundance of <em>Sporosarcina</em> and <em>Solibacillus</em> genus which degrades proteins, aiding the <em>Clostridium_sensu_stricto</em> spp. in producing butyric acid potentially through protein degradation. Within the detected bacterial diversity showing a lower Shannon index of 0.84 at 17ºC, these genera also showed a higher abundance. For further enhancing the hydrolysis, thermal-alkaline pretreatment of food waste was performed. However, it reduced the subsequent production of butyric acid as compared to untreated food waste. Under 17ºC, butyric acid’s concentration was 0.06 g/L, while at 37ºC, it was 0.12 g/L. This showed that intrinsic microflora of food waste was essential for its production. This selective accumulation of butyric acid over other VFAs offers a means of targeted VFA production using mixed culture fermentation under psychrophilic temperature.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"150 ","pages":"Pages 1-11"},"PeriodicalIF":3.5,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143095678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Extraction of brewer’s spent grain protein using natural deep eutectic solvent compared to alkaline extraction: Evaluating their yields, physicochemical characteristics, and functionalities
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-12-19 DOI: 10.1016/j.fbp.2024.12.012
Kunn Hadinoto , Jordy Kim-Ung Ling , Jin-Won Park , The-Thien Tran , Siyu Pu
The present study compared the effectiveness of natural deep eutectic solvent (NADES) and alkaline in extracting proteins from brewer’s spent grain (BSG). The extraction effectiveness was examined by the (i) yield, (ii) physicochemical characteristics (i.e., molecular weight, protein secondary structures, amino acid compositions, thermal stability), and (iii) food-relevant functionalities (i.e., water/oil holding capacities, emulsifying, foaming properties) of BSG protein extracts. Choline chloride-trehalose (3:1 mol/mol) known for its protein stabilizing effect was used as the model NADES. The ideal NADES extraction conditions to optimize the yield were first determined at 60, 1:15 (w/v) BSG-to-solvent ratio, and 75:25 (v/v) NADES-to-water ratio. At their respective optimal conditions, NADES extraction produced a higher yield than alkaline extraction (42 vs. 34 wt%). Minimal variations were observed between NADES and alkaline-extracted proteins in their molecular weight, protein secondary structures, amino acid profiles, and water/oil holding capacities. Nevertheless, NADES-extracted protein exhibited superior (1) thermal stability, hence reaffirming the protein stabilizing effect of NADES, and (2) emulsifying/foaming properties postulated due to their distinct amino acid compositions. The present results demonstrated NADES extraction achieved outcomes comparable to alkaline extraction in most aspects, while surpassing it in yield and proteins’ thermal stability, emulsifying/foaming properties. Future studies should focus on optimizing the yield of NADES extraction to improve its techno-economic viability.
{"title":"Extraction of brewer’s spent grain protein using natural deep eutectic solvent compared to alkaline extraction: Evaluating their yields, physicochemical characteristics, and functionalities","authors":"Kunn Hadinoto ,&nbsp;Jordy Kim-Ung Ling ,&nbsp;Jin-Won Park ,&nbsp;The-Thien Tran ,&nbsp;Siyu Pu","doi":"10.1016/j.fbp.2024.12.012","DOIUrl":"10.1016/j.fbp.2024.12.012","url":null,"abstract":"<div><div>The present study compared the effectiveness of natural deep eutectic solvent (NADES) and alkaline in extracting proteins from brewer’s spent grain (BSG). The extraction effectiveness was examined by the (i) yield, (ii) physicochemical characteristics (i.e., molecular weight, protein secondary structures, amino acid compositions, thermal stability), and (iii) food-relevant functionalities (i.e., water/oil holding capacities, emulsifying, foaming properties) of BSG protein extracts. Choline chloride-trehalose (3:1 mol/mol) known for its protein stabilizing effect was used as the model NADES. The ideal NADES extraction conditions to optimize the yield were first determined at 60<span><math><mi>℃</mi></math></span>, 1:15 (w/v) BSG-to-solvent ratio, and 75:25 (v/v) NADES-to-water ratio. At their respective optimal conditions, NADES extraction produced a higher yield than alkaline extraction (42 vs. 34 wt%). Minimal variations were observed between NADES and alkaline-extracted proteins in their molecular weight, protein secondary structures, amino acid profiles, and water/oil holding capacities. Nevertheless, NADES-extracted protein exhibited superior (1) thermal stability, hence reaffirming the protein stabilizing effect of NADES, and (2) emulsifying/foaming properties postulated due to their distinct amino acid compositions. The present results demonstrated NADES extraction achieved outcomes comparable to alkaline extraction in most aspects, while surpassing it in yield and proteins’ thermal stability, emulsifying/foaming properties. Future studies should focus on optimizing the yield of NADES extraction to improve its techno-economic viability.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"150 ","pages":"Pages 12-24"},"PeriodicalIF":3.5,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143105208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Robust optimization of regional biomass supply chain system design and operation with data-driven uncertainties 利用数据驱动的不确定性对区域生物质供应链系统的设计和运营进行稳健优化
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-11-23 DOI: 10.1016/j.fbp.2024.11.021
Xianling Huang , Ling Ji , Yulei Xie , Zhiwei Luo
To address climate change and ensure energy security, biomass energy has become a popular renewable energy alternative to traditional fossil fuels. This study focuses on the strategic planning and tactical management problem of a regional biomass supply chain system with multiple feedstock and final products. A novel SVC-based data-driven robust optimization model is developed to provide the tradeoff solutions under uncertainties. Compared with the traditional robust optimization model, it can better depict the uncertain sets, reduce data redundancy, and provide less conservative strategies for decision makers according to their risk preferences. The proposed model is validated through a case study, Meizhou city in China. The results suggested the optimal investment scale and site for biorefineries and biomass power plants at the strategic planning level, as well as the feedstock supply network, inventory management, and production arrangement at the tactic management level. The optimal robust solutions can be derived by varying the envelope level of the uncertain sets. Moreover, sensitivity analysis is performed to investigate the influences of the variations of key parameters. It is found that the produced bioethanol and electricity lack cost advantages in the current situation, even with a 30 % reduction in main cost parameters. Insufficient biomass yield may require extra capital investment to satisfy bioenergy demand but with a higher supply cost. Thus, a high and long-term subsidy is necessary to facilitate the sustainable development of biomass and the low-carbon transition of the energy sector.
为应对气候变化和确保能源安全,生物质能源已成为替代传统化石燃料的热门可再生能源。本研究重点关注具有多种原料和最终产品的区域生物质供应链系统的战略规划和战术管理问题。研究开发了一种基于 SVC 数据驱动的新型鲁棒优化模型,以提供不确定条件下的权衡解决方案。与传统的稳健优化模型相比,该模型能更好地描述不确定集合,减少数据冗余,并根据决策者的风险偏好为其提供不太保守的策略。通过对中国梅州市的案例研究,对所提出的模型进行了验证。结果从战略规划层面提出了生物精炼厂和生物质发电厂的最佳投资规模和选址,并从战术管理层面提出了原料供应网络、库存管理和生产安排。通过改变不确定集合的包络水平,可以得出最佳稳健解决方案。此外,还进行了敏感性分析,以研究关键参数变化的影响。研究发现,在当前情况下,即使主要成本参数降低 30%,生产的生物乙醇和电力也缺乏成本优势。生物质产量不足可能需要额外的资本投资来满足生物能源需求,但供应成本较高。因此,有必要提供长期的高额补贴,以促进生物质能的可持续发展和能源行业的低碳转型。
{"title":"Robust optimization of regional biomass supply chain system design and operation with data-driven uncertainties","authors":"Xianling Huang ,&nbsp;Ling Ji ,&nbsp;Yulei Xie ,&nbsp;Zhiwei Luo","doi":"10.1016/j.fbp.2024.11.021","DOIUrl":"10.1016/j.fbp.2024.11.021","url":null,"abstract":"<div><div>To address climate change and ensure energy security, biomass energy has become a popular renewable energy alternative to traditional fossil fuels. This study focuses on the strategic planning and tactical management problem of a regional biomass supply chain system with multiple feedstock and final products. A novel SVC-based data-driven robust optimization model is developed to provide the tradeoff solutions under uncertainties. Compared with the traditional robust optimization model, it can better depict the uncertain sets, reduce data redundancy, and provide less conservative strategies for decision makers according to their risk preferences. The proposed model is validated through a case study, Meizhou city in China. The results suggested the optimal investment scale and site for biorefineries and biomass power plants at the strategic planning level, as well as the feedstock supply network, inventory management, and production arrangement at the tactic management level. The optimal robust solutions can be derived by varying the envelope level of the uncertain sets. Moreover, sensitivity analysis is performed to investigate the influences of the variations of key parameters. It is found that the produced bioethanol and electricity lack cost advantages in the current situation, even with a 30 % reduction in main cost parameters. Insufficient biomass yield may require extra capital investment to satisfy bioenergy demand but with a higher supply cost. Thus, a high and long-term subsidy is necessary to facilitate the sustainable development of biomass and the low-carbon transition of the energy sector.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"149 ","pages":"Pages 176-189"},"PeriodicalIF":3.5,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142702099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Use of liquid nitrogen as pistachio peeling agent: quality parameters of kernel and skins (testa) 使用液氮作为开心果去皮剂:果仁和果皮(种皮)的质量参数
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-11-22 DOI: 10.1016/j.fbp.2024.11.023
Fabiola Pesce, Lucia Parafati, Biagio Fallico, Rosa Palmeri
Nuts peeling involves the use of high volumes of hot water (90–95°C), which results in a quality loss of the final product with a significant environmental impact. The present study exploits the use of cold nitrogen gases in order to perform an alternative technique of Liquid Nitrogen Peeling (LNP). Peeled pistachio (kernel) and skin (testa) obtained from LNP were compared with those obtained using the Traditional Blanching Peeling (TBP) method. Commercial pistachios present a peroxide value equal to 4.59±0.40 meq O2/kg of oil. After peeling process LNP sample showed a significantly (p < 0.05) lower peroxide value (PV), equal to 5.27±0.38 meq O2/kg of oil, in comparison to that subjected to TBP that registered the value of 10.47±1.07 meq O2/kg of oil. Moisture content is strictly connected to the stability of the final product. In our LNP samples, pistachio kernels recorded a moisture value significantly lower (p < 0.05) compared to TBP sample, and evidenced superior colorimetric characteristics. Moreover, the resulting pistachio skin from LNP had higher values of bioactive compounds and antioxidant activity. Total anthocyanins content was almost three times higher (26.03±1.61 mg Cyanidin-3-O-glucoside eq (Cya-GE) /g sample dry weight) than that recovered from skin obtained after TBP (8.33±0.70 mg Cya-GE/g sample dry weight). Results suggest this by-product could be a resource with healthy properties that can be used in food formulations.
坚果去皮需要使用大量热水(90-95°C),这会导致最终产品的质量下降,并对环境造成严重影响。本研究利用低温氮气来替代液氮去皮(LNP)技术。将通过液氮去皮法获得的开心果果核和果皮与通过传统焯水去皮法(TBP)获得的果核和果皮进行了比较。商用开心果的过氧化值为 4.59±0.40 meq O2/kg 油。经过去皮处理后,LNP 样品的过氧化值 (PV) 明显降低(p < 0.05),为 5.27±0.38 meq O2/kg,而 TBP 样品的过氧化值为 10.47±1.07 meq O2/kg。水分含量与最终产品的稳定性密切相关。在我们的 LNP 样品中,与 TBP 样品相比,开心果核仁的水分值明显较低(p < 0.05),而且色度特性也更好。此外,从 LNP 中提取的开心果皮具有更高的生物活性化合物值和抗氧化活性。花青素总含量(26.03±1.61 毫克花青素-3-O-葡萄糖苷当量(Cya-GE)/克样品干重)比从 TBP 后的皮中回收的含量(8.33±0.70 毫克花青素-3-O-葡萄糖苷当量/克样品干重)高出近三倍。结果表明,这种副产品可能是一种具有健康特性的资源,可用于食品配方中。
{"title":"Use of liquid nitrogen as pistachio peeling agent: quality parameters of kernel and skins (testa)","authors":"Fabiola Pesce,&nbsp;Lucia Parafati,&nbsp;Biagio Fallico,&nbsp;Rosa Palmeri","doi":"10.1016/j.fbp.2024.11.023","DOIUrl":"10.1016/j.fbp.2024.11.023","url":null,"abstract":"<div><div>Nuts peeling involves the use of high volumes of hot water (90–95°C), which results in a quality loss of the final product with a significant environmental impact. The present study exploits the use of cold nitrogen gases in order to perform an alternative technique of Liquid Nitrogen Peeling (LNP). Peeled pistachio (kernel) and skin (testa) obtained from LNP were compared with those obtained using the Traditional Blanching Peeling (TBP) method. Commercial pistachios present a peroxide value equal to 4.59±0.40 meq O<sub>2</sub>/kg of oil. After peeling process LNP sample showed a significantly (p &lt; 0.05) lower peroxide value (PV), equal to 5.27±0.38 meq O<sub>2</sub>/kg of oil, in comparison to that subjected to TBP that registered the value of 10.47±1.07 meq O<sub>2</sub>/kg of oil. Moisture content is strictly connected to the stability of the final product. In our LNP samples, pistachio kernels recorded a moisture value significantly lower (p &lt; 0.05) compared to TBP sample, and evidenced superior colorimetric characteristics. Moreover, the resulting pistachio skin from LNP had higher values of bioactive compounds and antioxidant activity. Total anthocyanins content was almost three times higher (26.03±1.61 mg Cyanidin-3-O-glucoside eq (Cya-GE) /g sample dry weight) than that recovered from skin obtained after TBP (8.33±0.70 mg Cya-GE/g sample dry weight). Results suggest this by-product could be a resource with healthy properties that can be used in food formulations.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"149 ","pages":"Pages 158-164"},"PeriodicalIF":3.5,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142702098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Process synthesis, design and techno-economic assessment of bio-succinic acid production 生物琥珀酸生产工艺合成、设计及技术经济评价
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-11-21 DOI: 10.1016/j.fbp.2024.11.020
George Melitos , Nikiforos Misailidis , Demetri Petrides , Michael C. Georgiadis
This work investigates the potential of different fermentation feedstocks towards succinic acid production. Three alternative flowsheets were constructed and modelled in SuperPro Designer™, utilizing different fermentation substrates: crude glycerol (a by-product of the biodiesel industry), a commercial 95 % glucose syrup and pure glycerol. Techno-economic analysis of the modelled plants showed that all three potential investments can be economically profitable, with the crude glycerol case as the most promising one. The succinic acid production cost for the crude glycerol scenario is estimated at 3.57 $/kg, while a thorough study of the capacity effect to the economics showed that it could drop as low as $2.6 $/kg. Parametric analysis and optimization performed on a flowsheet level, indicated opportunities for lowering the production cost down to 3 $/kg, a value that could pave the framework for a further potential decrease in the selling price of the product.
本研究探讨了不同发酵原料对琥珀酸生产的潜力。利用不同的发酵底物:粗甘油(生物柴油工业的副产品),商用95% %的葡萄糖浆和纯甘油,在SuperPro Designer™中构建和建模了三个可选的流程。模拟装置的技术经济分析表明,三种潜在的投资都具有经济效益,其中粗甘油是最有希望的投资。在粗甘油的情况下,琥珀酸的生产成本估计为3.57美元/公斤,而对产能效应的深入研究表明,成本可以降至2.6美元/公斤。在流程层面上进行的参数分析和优化表明,有机会将生产成本降至3美元/公斤,这一价值可以为进一步降低产品销售价格奠定基础。
{"title":"Process synthesis, design and techno-economic assessment of bio-succinic acid production","authors":"George Melitos ,&nbsp;Nikiforos Misailidis ,&nbsp;Demetri Petrides ,&nbsp;Michael C. Georgiadis","doi":"10.1016/j.fbp.2024.11.020","DOIUrl":"10.1016/j.fbp.2024.11.020","url":null,"abstract":"<div><div>This work investigates the potential of different fermentation feedstocks towards succinic acid production. Three alternative flowsheets were constructed and modelled in SuperPro Designer™, utilizing different fermentation substrates: crude glycerol (a by-product of the biodiesel industry), a commercial 95 % glucose syrup and pure glycerol. Techno-economic analysis of the modelled plants showed that all three potential investments can be economically profitable, with the crude glycerol case as the most promising one. The succinic acid production cost for the crude glycerol scenario is estimated at 3.57 $/kg, while a thorough study of the capacity effect to the economics showed that it could drop as low as $2.6 $/kg. Parametric analysis and optimization performed on a flowsheet level, indicated opportunities for lowering the production cost down to 3 $/kg, a value that could pave the framework for a further potential decrease in the selling price of the product.</div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"149 ","pages":"Pages 224-237"},"PeriodicalIF":3.5,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development and optimization of a two-step co-extraction process for the recovery of pumpkin seed oil and in-situ enrichment with β-carotene compounds from pumpkin peel 南瓜皮中β-胡萝卜素化合物的原位富集和两步萃取工艺的开发与优化
IF 3.5 2区 农林科学 Q2 BIOTECHNOLOGY & APPLIED MICROBIOLOGY Pub Date : 2024-11-21 DOI: 10.1016/j.fbp.2024.11.015
Lindah Phambala Chifomboti , Annie F.A. Chimphango
Vegetable oil industries are interested in producing healthy, high-quality, and cost-effective edible oils. This necessitates greener sources and effective oil enrichment strategies involving non-toxic and natural antioxidants. Thus, this study developed a novel one-pot vegetable oil natural pigmentation strategy to enable the in-situ cold press extraction and pigmentation of the vegetable oils while enhancing yields. The study co-pressed microwave pretreated pumpkin seeds and peels (PSP),3 producing pumpkin seed oil (PSO)4 which facilitated the co-extraction of lipophilic β-carotene compounds from the peels in a structured bed. The processing conditions were optimised for yields through Box-Behnken Design experiments, which varied seed-to-peel ratio (50 – 90 % w/w), microwave power (200 – 600 Watts), irradiation time (180 – 240 sec), and pressure (10 – 20 MPa). Optimal conditions (80 % w/w seeds,5 600 Watts, 240 sec, 20 MPa) recovered 73.58 % oil and 5.48 ± 0.33 mg β-carotene /100 g biomass. PSP oils with natural β-carotene (0.75±0.02 mg β-carotene/100 g oil) pigmentation was more oxidative stable (based on unsaturated fatty acids content) at elevated temperatures (180 °C, 6 h), outperforming unpigmented seed oils (0.47±0.01 mg/100 g oil) despite the reduced yield. Therefore, microwave pretreatment and one-pot co-extraction have the potential to produce high-quality edible oil from vegetable residues with reduced processing steps. Thus, promoting material circularity in food processing.

Industrial relevance

The utilization of a microwave-assisted mechanical processing scheme comprising a mixture of pumpkin seeds and peel provides a potential multi-product pathway for obtaining maximum value from pumpkin residues. This approach offers notable industrial benefits and applications:
  • I.
    Microwave heating shows promising potential in enhancing the extractability of pumpkin seed oil and β-carotene compounds from the peel. Thus, rendering it a viable pre-treatment method for vegetable oil production and in-situ recovery of natural antioxidants.
  • II.
    The layered structured-bed presents a co-extraction technique (for pumpkin seed oil and β-carotene) with fewer extraction steps compared to the multi-step, energy-intensive conventional oil enrichment processes.
植物油行业对生产健康、高质量、高性价比的食用油很感兴趣。这就需要更环保的资源和有效的石油富集策略,包括无毒和天然抗氧化剂。因此,本研究开发了一种新的一锅植物油天然色素沉着策略,可以在提高产量的同时实现植物油的原位冷压提取和色素沉着。本研究采用微波预处理南瓜籽和南瓜皮(PSP)共压,得到南瓜籽油(PSO)4,使其在结构床上从南瓜籽皮中共提取亲脂性β-胡萝卜素化合物。通过Box-Behnken设计实验,优化了种子与果皮比(50 - 90 % w/w)、微波功率(200 - 600瓦)、辐照时间(180 - 240 秒)和压力(10 - 20 MPa)的加工条件。最佳条件(80 % w/w种子,5 600瓦,240 秒,20 MPa)可回收73.58 %油和5.48±0.33 mg β-胡萝卜素/100 g生物量。含有天然β-胡萝卜素(0.75±0.02 mg β-胡萝卜素/100 g油)色素沉着的PSP油在高温(180°C, 6 h)下氧化稳定性更好(基于不饱和脂肪酸含量),尽管产量降低,但优于未着色的种子油(0.47±0.01 mg/100 g油)。因此,微波预处理和一锅共浸有可能减少加工步骤,从蔬菜残渣中生产出高质量的食用油。从而促进食品加工中的材料循环。利用微波辅助的机械加工方案,包括南瓜籽和瓜皮的混合物,为从南瓜残留物中获得最大价值提供了一个潜在的多产品途径。这种方法提供了显著的工业效益和应用:微波加热在提高南瓜籽油和β-胡萝卜素化合物的提取率方面显示出良好的潜力。因此,使其成为一种可行的植物油生产和天然抗氧化剂原位回收的预处理方法。ii .层状结构床提供了一种共提取技术(用于南瓜籽油和β-胡萝卜素),与多步骤、能源密集型的常规油富集工艺相比,提取步骤更少。
{"title":"Development and optimization of a two-step co-extraction process for the recovery of pumpkin seed oil and in-situ enrichment with β-carotene compounds from pumpkin peel","authors":"Lindah Phambala Chifomboti ,&nbsp;Annie F.A. Chimphango","doi":"10.1016/j.fbp.2024.11.015","DOIUrl":"10.1016/j.fbp.2024.11.015","url":null,"abstract":"<div><div>Vegetable oil industries are interested in producing healthy, high-quality, and cost-effective edible oils. This necessitates greener sources and effective oil enrichment strategies involving non-toxic and natural antioxidants. Thus, this study developed a novel one-pot vegetable oil natural pigmentation strategy to enable the <em>in-situ</em> cold press extraction and pigmentation of the vegetable oils while enhancing yields. The study co-pressed microwave pretreated pumpkin seeds and peels (PSP),<span><span><sup>3</sup></span></span> producing pumpkin seed oil (PSO)<span><span><sup>4</sup></span></span> which facilitated the co-extraction of lipophilic β-carotene compounds from the peels in a structured bed. The processing conditions were optimised for yields through Box-Behnken Design experiments, which varied seed-to-peel ratio (50 – 90 % w/w), microwave power (200 – 600 Watts), irradiation time (180 – 240 sec), and pressure (10 – 20 MPa). Optimal conditions (80 % w/w seeds,<span><span><sup>5</sup></span></span> 600 Watts, 240 sec, 20 MPa) recovered 73.58 % oil and 5.48 ± 0.33 mg β-carotene /100 g biomass. PSP oils with natural β-carotene (0.75±0.02 mg β-carotene/100 g oil) pigmentation was more oxidative stable (based on unsaturated fatty acids content) at elevated temperatures (180 °C, 6 h), outperforming unpigmented seed oils (0.47±0.01 mg/100 g oil) despite the reduced yield. Therefore, microwave pretreatment and one-pot co-extraction have the potential to produce high-quality edible oil from vegetable residues with reduced processing steps. Thus, promoting material circularity in food processing.</div></div><div><h3>Industrial relevance</h3><div>The utilization of a microwave-assisted mechanical processing scheme comprising a mixture of pumpkin seeds and peel provides a potential multi-product pathway for obtaining maximum value from pumpkin residues. This approach offers notable industrial benefits and applications:</div><div><ul><li><span>I.</span><span><div>Microwave heating shows promising potential in enhancing the extractability of pumpkin seed oil and β-carotene compounds from the peel. Thus, rendering it a viable pre-treatment method for vegetable oil production and <em>in-situ recovery of natural antioxidants.</em></div></span></li><li><span>II.</span><span><div>The layered structured-bed presents a co-extraction technique (for pumpkin seed oil and β-carotene) with fewer extraction steps compared to the multi-step, energy-intensive conventional oil enrichment processes.</div></span></li></ul></div></div>","PeriodicalId":12134,"journal":{"name":"Food and Bioproducts Processing","volume":"149 ","pages":"Pages 211-223"},"PeriodicalIF":3.5,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142745726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Food and Bioproducts Processing
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1