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The Impact of Sample Insulation on Estimating the Heating Power of Magnetic Nanoparticles by AC Calorimetry 样品绝缘对交流量热法估算磁性纳米粒子加热功率的影响
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-03-30 DOI: 10.1109/LMAG.2023.3279778
Lise G. Hanson;Bianca L. Hansen;Thomas Veile;Mathias Zambach;Niels B. Christensen;Cathrine Frandsen
Correct estimation of the heating power of magnetic nanoparticles is important for magnetic hyperthermia treatment. This letter investigates the impact of sample insulation in ac calorimetry. We show that a temperature increase in the insulation can lead to systematic errors when estimating the heating power by the corrected slope method. The errors arise if the temperature of the sample environment is kept fixed at its initial temperature in the data analysis. To correct this, the local temperature difference between the sample and the sample environment should be used.
正确估计磁性纳米颗粒的加热功率对于磁热疗治疗是重要的。这封信调查了交流量热法中样品绝缘的影响。我们表明,当用修正斜率法估计加热功率时,绝缘层的温度升高会导致系统误差。如果在数据分析中样品环境的温度保持固定在其初始温度,则会出现误差。为了纠正这种情况,应使用样品和样品环境之间的局部温差。
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引用次数: 1
Preparation of Temperature-Sensitive Rare-Earth–Iron Alloy Fine Particles Using Mechanical Alloying and Sintering 用机械合金化和烧结法制备对温度敏感的稀土-铁合金细颗粒
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-03-29 DOI: 10.1109/LMAG.2023.3281158
Jiatong Pan;Jianfei Shentu;Chunlin He;Deqian Zeng;Feng Gao;Gjergj Dodbiba;Toyohisa Fujita
Fine magnetic particles with high saturation magnetization and a large temperature-sensitive magnetization in the temperature range 300–400 K were prepared for use in temperature-sensitive magnetorheological fluids. Two methods, namely high-energy ball milling (HEBM) and sintering followed by HEBM to produce mechanochemical alloys, were used to produce R2Fe17 component particles. The prepared particles were submicrometer- to micrometer-sized and contained rare-earth–iron alloys and α-Fe phases. Among the prepared particles, Sm2Fe17 composition powder exhibited the highest temperature sensitivity of −0.02 A m2 kg−1 K−1 at 400 K. Furthermore, powders with varying Fe and Sm composition ratios were prepared by sintering and ball milling. The powder prepared from the initial SmFe5 composition exhibited the highest temperature sensitivity of −0.32 A m2 kg−1 K−1 at 400 K and saturation magnetization was ∼90 A m2 kg−1. The powder was composed of SmFe5 and Sm2Fe17 in crystalline, α-Fe phase, and amorphous phase, as revealed by X-ray diffraction analysis and a scanning electron microscope, as well as high-resolution transmission electron microscopy with selected area electron diffraction.
制备了在300–400 K温度范围内具有高饱和磁化强度和大温敏磁化强度的精细磁性颗粒,用于温敏磁流变流体。使用两种方法,即高能球磨(HEBM)和烧结,然后用HEBM生产机械化学合金,来生产R2Fe17组分颗粒。制备的颗粒尺寸为亚微米至微米,含有稀土-铁合金和α-Fe相。在制备的颗粒中,Sm2Fe17组成的粉末在400 K下表现出最高的温度敏感性,为−0.02 A m2 kg−1 K−1。此外,通过烧结和球磨制备了不同Fe和Sm组成比的粉末。由初始SmFe5成分制备的粉末在400 K下表现出最高的温度敏感性,为−0.32 A m2 kg−1 K−1,饱和磁化强度为~90 A m2 kg-1。X射线衍射分析和扫描电子显微镜以及选区电子衍射的高分辨率透射电子显微镜显示,该粉末由结晶相、α-Fe相和非晶相的SmFe5和Sm2Fe17组成。
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引用次数: 0
Crystal Structure and Magnetic Properties of Hexagonal FeCo Nitrides Prepared Using Ammonia Gas Nitrification 氨气氮化制备六方氮化铁钴的晶体结构和磁性能
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-03-27 DOI: 10.1109/LMAG.2023.3262452
Chihiro Kodaka;Mikio Kishimoto;Eiji Kita;Hideto Yanagihara
Single-phase $varepsilon$-(FeCo)xN compound particles with $x$ = 2.25–2.48 were synthesized using ammonia gas nitrification. The mass magnetization $M$ at 10 K under a magnetic field of 9 T was 77 A$cdot$m$^{2}$/kg, and Curie temperature $T$C was 100 K for $x$ = 2.48. These values decreased with increasing nitrogen content. Compared with $varepsilon$-FexN, (FeCo)xN had significantly lower $M$ and $T$C values, even at comparable nitrogen content. Mössbauer spectroscopy suggests that the magnetic moment of Co decreases with increasing nitrogen content and disappears at approximately $x$ = 2.35, even at the lowest measurement temperature of $T$ = 3 K. Griffiths phaselike magnetic behavior was observed in the temperature dependence of magnetic susceptibility. The experimental results indicate that the Fe–Fe interaction may change from ferromagnetic to antiferromagnetic at $x$ = 2.25 when the nitrogen content is low.
采用氨气硝化法合成了$x$=2.25–2.48的单相$varepsilon$-(FeCo)xN化合物颗粒。在9T磁场下10K下的质量磁化强度$M$为77A$cdot$M$^{2}$/kg,居里温度$T$C为100K,$x$=2.48。这些数值随着氮含量的增加而降低。与$varepsilon$-FexN相比,(FeCo)xN的$M$和$T$C值显著较低,即使在氮含量相当的情况下也是如此。Mössbauer谱表明,Co的磁矩随着氮含量的增加而减小,并且在大约$x$=2.35时消失,即使在最低测量温度$T$=3K时也是如此。在磁化率的温度依赖性中观察到Griffiths类相磁行为。实验结果表明,当氮含量较低时,在$x$=2.25时,Fe–Fe相互作用可能从铁磁变为反铁磁。
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引用次数: 0
Analysis of Skyrmion Shuffling Chamber Stochasticity for Neuromorphic Computing Applications 用于神经形态计算应用的Skyrmion Shuffling腔Stocurity分析
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-03-25 DOI: 10.1109/LMAG.2023.3280120
Zulfidin Khodzhaev;Emrah Turgut;Jean Anne C. Incorvia
In this study, micromagnetic simulations of a magnetic skyrmion reshuffling chamber for probabilistic computing applications are performed. The skyrmion shuffling chamber is modeled with a custom current density masking technique to capture current density variation, grain boundary variations, and anisotropy changes. The results show that the skyrmion oscillatory dynamics contribute to the system's stochasticity, allowing uncorrelated signals to be achieved with a single chamber. Our findings indicate that uncorrelated signals are generally achieved at all temperatures simulated, with the skyrmion diameter playing a role in the resulting stochasticity. Furthermore, we find that local temperature control has the benefit of not affecting the overall skyrmion diameter, while still perturbing the skyrmion trajectory. The results from varying chamber size, global temperature, and local temperature are analyzed using Pearson correlation coefficient and p-value. This research contributes to the development of tunable probabilistic computing devices and artificial synapses using magnetic skyrmions.
在这项研究中,对用于概率计算应用的磁性skyrmion改组室进行了微磁模拟。skyrmion混洗室采用定制的电流密度掩蔽技术建模,以捕捉电流密度变化、晶界变化和各向异性变化。结果表明,skyrmion振荡动力学有助于系统的随机性,允许用单个腔室获得不相关的信号。我们的研究结果表明,在模拟的所有温度下,通常都能获得不相关的信号,skyrmion直径在由此产生的随机性中发挥了作用。此外,我们发现局部温度控制的好处是不影响skyrmion的整体直径,同时仍然干扰skyrmion轨迹。使用Pearson相关系数和p值分析了不同腔室大小、全局温度和局部温度的结果。这项研究有助于开发可调谐的概率计算设备和使用磁性skyrmions的人工突触。
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引用次数: 0
A Deep Dive Into the Computational Fidelity of High-Variability Low Energy Barrier Magnet Technology for Accelerating Optimization and Bayesian Problems 高变率低能量势垒磁体加速优化技术的计算保真度与贝叶斯问题
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-03-08 DOI: 10.1109/LMAG.2023.3274051
Md Golam Morshed;Samiran Ganguly;Avik W. Ghosh
Low energy barrier magnet (LBM) technology has recently been proposed as a candidate for accelerating algorithms based on energy minimization and probabilistic graphs because their physical characteristics have a one-to-one mapping onto the primitives of these algorithms. Many of these algorithms have a much higher tolerance for error compared to high-accuracy numerical computation. LBM, however, is a nascent technology, and devices show high sample-to-sample variability. In this letter, we take a deep dive into the overall fidelity afforded by this technology in providing computational primitives for these algorithms. We show, that while the computed results show finite deviations from zero-variability devices, the margin of error is almost always certifiable to a certain percentage. This suggests that LBM technology could be a viable candidate as an accelerator for popular emerging paradigms of computing.
低能势垒磁体(LBM)技术最近被提出作为基于能量最小化和概率图的加速算法的候选者,因为它们的物理特性对这些算法的基元具有一对一的映射。与高精度数值计算相比,这些算法中的许多具有高得多的误差容限。然而,LBM是一项新兴技术,设备显示出高样本间的可变性。在这封信中,我们深入探讨了这项技术在为这些算法提供计算原语时所提供的整体保真度。我们表明,虽然计算结果显示与零可变性设备的偏差是有限的,但误差幅度几乎总是可以证明为一定的百分比。这表明LBM技术可能是一种可行的候选者,可以作为流行的新兴计算范式的加速器。
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引用次数: 1
Possible Ground States and Magnetic-Field-Tuned Phase Transitions of a Geometrically Frustrated Ising Antiferromagnet on a Triangular Lattice 三角晶格上几何抑制的Ising反铁磁体的可能基态和磁场调谐相变
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-03-08 DOI: 10.1109/LMAG.2023.3274049
Thao Huong Pham
Possible average alignments of the spins in the ground state and the phase transitions of a geometrically frustrated Ising antiferromagnet in the presence of magnetic fields on a triangular lattice are studied in a mean field approximation. Starting from a zero-field clock phase, we can determine the phase boundaries from the curves of magnetic moments and their derivatives as functions of the fields. We also analyze the behavior of sublattice magnetic moments under the effect of the fields. The experimental relevances for TmMgGaO4 and SrEr2O4 are discussed. Besides, using a functional integral method, we have calculated a functional for free energy to obtain the contribution of spin fluctuations. From this, we can find that the role of the quantum spin fluctuations at very low temperatures is only prominent in the vicinity of the transition points. It can therefore be seen that the results, although given in the mean field approximation, describe quite well the phase transitions and rearrangements of the magnetic moment per spin under the effect of both the transverse and longitudinal fields.
在平均场近似下,研究了在三角形晶格上存在磁场的情况下,几何受抑的伊辛反铁磁体基态自旋的可能平均排列和相变。从零场时钟相位开始,我们可以根据磁矩及其导数作为场函数的曲线来确定相位边界。我们还分析了场作用下亚晶格磁矩的行为。讨论了TmMgGaO4和SrEr2O4的实验相关性。此外,利用泛函积分方法,我们计算了自由能的泛函,得到了自旋涨落的贡献。由此,我们可以发现,在非常低的温度下,量子自旋涨落的作用只在跃迁点附近突出。因此可以看出,尽管这些结果是在平均场近似中给出的,但它们很好地描述了在横向场和纵向场的影响下每自旋磁矩的相变和重排。
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引用次数: 0
Magnetic-Particle-Discrimination Method Using Difference of Relaxation Time for Magnetic Particle Imaging 基于弛豫时间差的磁粉成像鉴别方法
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-02-09 DOI: 10.1109/LMAG.2023.3243493
Kota Nomura;Masaomi Washino;Tetsuya Matsuda;Shun Tonooka;Seino Satoshi;H. Yoshida;K. Nishigaki;Takashi Nakagawa;Toshihiko Kiwa
Magnetic particle imaging (MPI) is an imaging modality that directly detects the nonlinear responses of magnetic nanoparticles (MNPs). Spatial encoding is achieved by saturating the magnetic moment of MNPs almost everywhere except in a special point called the field-free region in which a magnetic field vanishes. Recently, MPI sensitivity was improved using a field-free line (FFL) in which a field-free region was formed as a line. An MPI with an FFL device was developed using a neodymium magnet and an iron yoke to image objects with a small amount of MNPs, such as in biological systems. We have been developing MPI equipment for detecting amyloid-β, a causative agent of Alzheimer's disease. We attached amyloid-β probes to nanoparticles. In our development, we discriminated between magnetic particles that are bound to biological tissue from those that are suspended in the brain. We focused on the differences in relaxation times due to the change in the hydrodynamic diameter between the bound and unbound particles. Because the bound particles have a larger apparent particle size and do not rotate when an ac magnetic field is applied, the relaxation time is different from the unbound particles. Since the differences in the responses to the ac magnetic field appear as relaxation times, we investigated a particle-discrimination method using these differences and studied the magnetization response of MNPs using our developed MPI device.
磁粉成像(MPI)是一种直接检测磁性纳米颗粒(MNP)非线性响应的成像方式。空间编码是通过使MNP的磁矩几乎在任何地方饱和来实现的,除了在一个被称为磁场消失的无场区域的特殊点。最近,使用其中无场区域形成为线的无场线(FFL)来提高MPI灵敏度。使用钕磁体和铁轭开发了一种带有FFL设备的MPI,用于对具有少量MNP的物体进行成像,例如在生物系统中。我们一直在开发MPI设备来检测淀粉样蛋白-β,一种阿尔茨海默病的病原体。我们将淀粉样蛋白-β探针连接到纳米颗粒上。在我们的发展过程中,我们区分了与生物组织结合的磁性粒子和悬浮在大脑中的磁性粒子。我们重点研究了由于结合粒子和未结合粒子之间流体动力学直径的变化而导致的弛豫时间的差异。由于结合粒子具有较大的表观粒径,并且在施加交流磁场时不旋转,因此弛豫时间与未结合粒子不同。由于对交流磁场的响应差异表现为弛豫时间,我们研究了一种利用这些差异的粒子判别方法,并使用我们开发的MPI设备研究了MNP的磁化响应。
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引用次数: 0
Magnetic Structural Analysis of Nanocrystalline Soft Magnets by Small-Angle Neutron Scattering 用小角度中子散射法分析纳米晶软磁体的磁结构
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-02-03 DOI: 10.1109/LMAG.2023.3242108
Hiroaki Mamiya;Yojiro Oba;Kosuke Hiroi;Takayuki Miyatake;Ravi Gautam;Hossein Sepehri-Amin;Tadakatsu Ohkubo
Nanocrystalline soft magnets have attracted significant attention for their improvement of energy conversion devices. It has been considered that the partial nanocrystallization of amorphous structures is a key to macroscopic magnetic softness. However, the mechanism has not been clarified because of inadequate knowledge of the magnetic nanostructures connecting microscopic crystalline structures and macroscopic magnetic properties. Here, we performed small-angle neutron scattering (SANS) for Fe85Si2B8P4Cu1 alloy ribbons (NANOMETs). Rapidly quenched ribbons were annealed at 375 °C and 400 °C for 5 min. The X-ray diffraction pattern for the as-quenched ribbons did not exhibit peaks. Therefore, their atomic structure can be considered amorphous. Oppositely, evident α-iron peaks were observed for the ribbons annealed at 375 °C and 400 °C. The nuclear scattering contribution in SANS indicates that the precipitations were formed with sizes in the nanoscale. The magnetic scattering contribution in SANS for the as-quenched ribbon, whose intensity decreased with an increase in the scattering vector q in proportion to q−4, disappeared when magnetic fields were applied. This behavior is consistent with the conventional magnetic domain picture. Oppositely, the reduction rates of the magnetic scattering contribution for q were nonmonotonous for the nanocrystallized ribbons. Furthermore, strong magnetic scattering was observed in the directions inclined to the magnetic field. This feature is similar to that reported for Fe–(Nb, Zr)–B alloy ribbons (NANOPERMs). The knowledge on the magnetic nanostructures characterized by the unusual angular dependence of magnetic scattering would be helpful to considering the relationship between partially nanocrystallized structure and macroscopic soft magnetic properties.
纳米晶体软磁体由于其对能量转换器件的改进而引起了人们的极大关注。非晶结构的部分纳米化被认为是宏观磁柔软度的关键。然而,由于对连接微观晶体结构和宏观磁性的磁性纳米结构了解不足,该机制尚未阐明。在这里,我们对Fe85Si2B8P4Cu1合金带(NANOMETs)进行了小角度中子散射(SANS)。快淬薄带在375℃退火 °C和400 持续5分钟。淬火后的带状物的X射线衍射图没有显示出峰值。因此,它们的原子结构可以被认为是无定形的。相反,在375℃退火的薄带上观察到明显的α-铁峰 °C和400 °C。SANS中的核散射贡献表明沉淀是以纳米级的尺寸形成的。当施加磁场时,淬火带的SANS中的磁散射贡献消失了,其强度随着散射矢量q的增加而降低,与q−4成比例。这种行为与传统的磁畴图像一致。相反,对于纳米晶体带,q的磁散射贡献的降低率是非单调的。此外,在倾斜于磁场的方向上观察到强磁散射。该特征与报道的Fe–(Nb,Zr)–B合金带(NANOPERM)的特征相似。关于以磁散射的异常角度依赖性为特征的磁性纳米结构的知识将有助于考虑部分纳米化结构与宏观软磁性能之间的关系。
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引用次数: 0
Hybrid MTJ/CNTFET-Based Binary Synapse and Neuron for Process-in-Memory Architecture 基于混合MTJ/CNTFET的二元突触和神经元在存储器结构中的处理
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-01-19 DOI: 10.1109/LMAG.2023.3238271
Milad Tanavardi Nasab;Arefe Amirany;Mohammad Hossein Moaiyeri;Kian Jafari
This letter develops a reliable, integrated binary synapse and neuron model for hardware implementation of binary neural networks. Thanks to the nonvolatile nature of magnetic tunnel junctions and the unique features of carbon nanotube field-effect transistors, the modeled design does not require external memory to store weights and also consumes low static power. Also, due to the circuit structure, which did not use sequential parts, the developed circuit is immune to soft error. Because, in binary neural networks, weights are limited to two values of −1 and 1, the occurrence of soft errors dramatically reduces the accuracy of the network. Simulation results indicate that the design in this work consumes at least 9% lower power, occupies 34% lower area, and offers a 49% lower power delay area product. Also, Monte Carlo simulations have been performed to study the effect of the process variation on the network. The result of the Monte Carlo simulations shows that the proposed neuron has no logical error in 10 000 simulations. Consequently, the accuracy of the network utilization by the neuron is equal to the software-implemented network and does not decrease even in the presence of process variations.
这封信为二进制神经网络的硬件实现开发了一个可靠的、集成的二进制突触和神经元模型。由于磁性隧道结的非易失性和碳纳米管场效应晶体管的独特特性,建模设计不需要外部存储器来存储重量,并且还消耗低静态功率。此外,由于电路结构不使用顺序部件,所开发的电路不受软错误的影响。因为在二进制神经网络中,权重被限制为−1和1这两个值,所以软误差的出现大大降低了网络的精度。仿真结果表明,本文的设计功耗至少降低了9%,占用了34%的面积,并提供了49%的低功耗延迟面积产品。此外,还进行了蒙特卡罗模拟,以研究过程变化对网络的影响。蒙特卡罗模拟结果表明,所提出的神经元在10 000个模拟。因此,神经元利用网络的精度与软件实现的网络相同,并且即使在存在过程变化的情况下也不会降低。
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引用次数: 1
Impact of Array Length on Particle Attraction in Magnetic Drug Targeting: Investigation Using an Exponential Approximation of the Magnetic Field 阵列长度对磁性药物靶向中粒子吸引力的影响:利用磁场的指数近似研究
IF 1.2 4区 物理与天体物理 Q4 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-01-16 DOI: 10.1109/LMAG.2023.3237384
Angelika S. Thalmayer;Kilian Götz;Samuel Zeising;Georg Fischer
In magnetic drug targeting, special magnetic nanoparticles that carry the anticancer drug are injected into the cardiovascular system in the vicinity of the tumor and are navigated into the tumor using a magnetic field. Many researchers optimize single magnets for this purpose; however, magnetic arrays that are placed parallel to the vessel in order to increase the impact time of the magnetic force on the particles are also discussed. To the best of the authors' knowledge, the improvement by the increased impact time has not been studied in detail so far and, thus, will be addressed in this work. In this context, an artificial exponential magnetic field that approximates the field of a Halbach array and acts as an upper limit consideration is applied to different impact lengths within a predefined magnetic domain. To compare the impact of the field parameters, the total magnetic energetic effort is kept constant as a reference for studying variations of impact length. The results reveal that a longer impact length increases the attraction performance enormously. However, for the same magnetic effort, a longer impact length with a lower magnetic field strength leads to the same attraction of the particles as a shorter one with higher field strengths. Since it is easier to generate lower field strengths, the usage of arrays to realize a longer impact length is preferable.
在磁性药物靶向中,携带抗癌药物的特殊磁性纳米颗粒被注射到肿瘤附近的心血管系统中,并使用磁场导航到肿瘤中。许多研究人员为此优化了单个磁体;然而,为了增加磁力对粒子的冲击时间,还讨论了平行于容器放置的磁性阵列。据作者所知,到目前为止,还没有详细研究撞击时间增加带来的改善,因此,本工作将对此进行讨论。在这种情况下,近似于Halbach阵列的场并作为上限考虑的人工指数磁场被应用于预定义磁畴内的不同冲击长度。为了比较场参数的影响,总磁能作用力保持不变,作为研究冲击长度变化的参考。结果表明,较长的冲击长度会极大地提高吸引力。然而,对于相同的磁力,具有较低磁场强度的较长冲击长度会导致与具有较高磁场强度的较短冲击长度相同的粒子吸引力。由于更容易产生较低的场强,因此优选使用阵列来实现较长的冲击长度。
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引用次数: 0
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IEEE Magnetics Letters
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