Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912319
V. Mykhaylyk, R. Duman, A. Wagner
The beamline I23 at Diamond Light Source will be the first dedicated beamline for long-wavelength phasing experiments from macromolecular crystals (MX). The challenges of in-vacuum long-wavelength macromolecular crystallography and the opportunities by extending the wavelength range towards the sulfur and phosphorous K-absorption edges will be discussed and an overview on the current status of the project will be given.
{"title":"Challenges and advances of long-wavelength macromolecular crystallography at Diamond Light Source","authors":"V. Mykhaylyk, R. Duman, A. Wagner","doi":"10.1109/OMEE.2014.6912319","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912319","url":null,"abstract":"The beamline I23 at Diamond Light Source will be the first dedicated beamline for long-wavelength phasing experiments from macromolecular crystals (MX). The challenges of in-vacuum long-wavelength macromolecular crystallography and the opportunities by extending the wavelength range towards the sulfur and phosphorous K-absorption edges will be discussed and an overview on the current status of the project will be given.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129937701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912436
Y. Zorenko, V. Gorbenko, T. Zorenko, J. Mares, A. Beitlerová, R. Kučerková, M. Nikl, A. Fedorov, Y. Vasyl’kiv, K. Fabisiak, K. Matuszewski
The report presents the results of investigations of the growth processes by the Liquid Phase Epitaxy (LPE) method and luminescent properties of the single crystalline films (SCF) of Ce doped (Lu,Tb)3Al5O12:Ce garnets.
{"title":"Growth, luminescent properties and energy transfer processes in (Lu,Tb)3Al5O12:Ce single crystalline films","authors":"Y. Zorenko, V. Gorbenko, T. Zorenko, J. Mares, A. Beitlerová, R. Kučerková, M. Nikl, A. Fedorov, Y. Vasyl’kiv, K. Fabisiak, K. Matuszewski","doi":"10.1109/OMEE.2014.6912436","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912436","url":null,"abstract":"The report presents the results of investigations of the growth processes by the Liquid Phase Epitaxy (LPE) method and luminescent properties of the single crystalline films (SCF) of Ce doped (Lu,Tb)<sub>3</sub>Al<sub>5</sub>O<sub>12</sub>:Ce garnets.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"96 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130372090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912385
L. Kostyk, A. Luchechko, S. Novosad, O. Tsvetkova
Eu3+ activated Ca3Ga2Ge3O12 ceramics were prepared by solid-state reaction, and characterized with XRD, UV-VIS and UV-VUV spectroscopy at temperature range 10-300K. Structural analysis revealed only garnet phase. The results have shown that Eu3+ activated Ca3Ga2Ge3O12 exhibit efficient red emitting due to the 5D0 → 7F1,2,4 transitions under 393 nm (7F0 → 5L6 transition of Eu3+) or 250 nm (the broad O2-→Eu3+ charge transfer band) excitations. A strong activator emission of Ca3Ga2Ge3O12:Eu3+ ceramics can also be obtained upon excitation with the synchrotron radiation in the long-wavelength fundamental absorption edge region and in the region of photon multiplication, where energy transfer from the host to the Eu3+ ions takes place.
{"title":"Luminescence of Eu3+ activated Ca3Ga2Ge3O12 garnet under UV-VIS and UV-VUV excitations","authors":"L. Kostyk, A. Luchechko, S. Novosad, O. Tsvetkova","doi":"10.1109/OMEE.2014.6912385","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912385","url":null,"abstract":"Eu<sup>3+</sup> activated Ca<sub>3</sub>Ga<sub>2</sub>Ge<sub>3</sub>O<sub>12</sub> ceramics were prepared by solid-state reaction, and characterized with XRD, UV-VIS and UV-VUV spectroscopy at temperature range 10-300K. Structural analysis revealed only garnet phase. The results have shown that Eu<sup>3+</sup> activated Ca<sub>3</sub>Ga<sub>2</sub>Ge<sub>3</sub>O<sub>12</sub> exhibit efficient red emitting due to the <sup>5</sup>D<sub>0</sub> → <sup>7</sup>F<sub>1,2,4</sub> transitions under 393 nm (<sup>7</sup>F<sub>0</sub> → <sup>5</sup>L<sub>6</sub> transition of Eu<sup>3+</sup>) or 250 nm (the broad O<sup>2-</sup>→Eu<sup>3+</sup> charge transfer band) excitations. A strong activator emission of Ca<sub>3</sub>Ga<sub>2</sub>Ge<sub>3</sub>O<sub>12</sub>:Eu<sup>3+</sup> ceramics can also be obtained upon excitation with the synchrotron radiation in the long-wavelength fundamental absorption edge region and in the region of photon multiplication, where energy transfer from the host to the Eu<sup>3+</sup> ions takes place.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"30 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126005397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912440
A. Twardak, P. Bilski, B. Marczewska, W. Gieszczyk, M. Kłosowski, M. Perzanowski
Selected optically stimulated luminescence properties of lithium aluminate crystals are presented within this work. Crystals were grown using Micro-Pulling-Down technique. The growth parameters and XRD analysis of obtained samples are demonstrated. OSL decay curves, thermal stability and fading of samples prepared under different conditions are compared.
{"title":"OSL properties of lithium aluminate crystals grown with Micro-Pulling-Down technique","authors":"A. Twardak, P. Bilski, B. Marczewska, W. Gieszczyk, M. Kłosowski, M. Perzanowski","doi":"10.1109/OMEE.2014.6912440","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912440","url":null,"abstract":"Selected optically stimulated luminescence properties of lithium aluminate crystals are presented within this work. Crystals were grown using Micro-Pulling-Down technique. The growth parameters and XRD analysis of obtained samples are demonstrated. OSL decay curves, thermal stability and fading of samples prepared under different conditions are compared.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"138 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122140334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912365
M. Bondarenko, N. Strutynska, I. Zatovsky, R. Kuzmin, N. Slobodyanik
The vitreous samples of MIxNa4-xCoFe(PO4)3 (x = 0, 0.2 and 1.0, MI - Li, K) composition were prepared by melt method. Formation of Nasicon-related crystalline samples was caused by the annealing at 600 °C. The cell parameters calculation showed that its evolution along two series agrees with the substitution of Na+ by smaller Li+ and bigger K+ cations. The electrical properties were investigated by the impedance method.
{"title":"Synthesis, characterization and electrical properties of glass-ceramic samples of MIxNa4−xCoFe(PO4)3 (MI - Li, K) composition","authors":"M. Bondarenko, N. Strutynska, I. Zatovsky, R. Kuzmin, N. Slobodyanik","doi":"10.1109/OMEE.2014.6912365","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912365","url":null,"abstract":"The vitreous samples of M<sup>I</sup><sub>x</sub>Na<sub>4-x</sub>CoFe(PO<sub>4</sub>)<sub>3</sub> (x = 0, 0.2 and 1.0, M<sup>I</sup> - Li, K) composition were prepared by melt method. Formation of Nasicon-related crystalline samples was caused by the annealing at 600 °C. The cell parameters calculation showed that its evolution along two series agrees with the substitution of Na<sup>+</sup> by smaller Li<sup>+</sup> and bigger K<sup>+</sup> cations. The electrical properties were investigated by the impedance method.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115875460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912391
P. Potera, T. Lukasiewicz, Y. Zhydachevskii
The present work is devoted to investigation of stable additional absorption that is induced by gamma radiation in pure Ca0.28Ba0.72Nb2O6 single crystals.
本文研究了纯Ca0.28Ba0.72Nb2O6单晶中伽马辐射诱导的稳定附加吸收。
{"title":"Stable absorption induced in Ca0.28Ba0.72Nb2O6 crystals by gamma quanta irradiation","authors":"P. Potera, T. Lukasiewicz, Y. Zhydachevskii","doi":"10.1109/OMEE.2014.6912391","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912391","url":null,"abstract":"The present work is devoted to investigation of stable additional absorption that is induced by gamma radiation in pure Ca<sub>0.28</sub>Ba<sub>0.72</sub>Nb<sub>2</sub>O<sub>6</sub> single crystals.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"23 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123293392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912398
H. Klym, A. Ingram, O. Shpotyuk, E. Petracovschi, L. Calvez
Positron annihilation lifetime spectroscopy combined with Doppler broadening of annihilation radiation was applied to study free-volume entities in Ge-Ga-S glasses having different amount of CsCl additives. These results serve as a basis for new direction in the characterization of inner free-volume structure of chalcohalide glass-ceramics conditionally declared as Positronics.
{"title":"Positronics of IR transmitting chalcohalide glass-ceramics","authors":"H. Klym, A. Ingram, O. Shpotyuk, E. Petracovschi, L. Calvez","doi":"10.1109/OMEE.2014.6912398","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912398","url":null,"abstract":"Positron annihilation lifetime spectroscopy combined with Doppler broadening of annihilation radiation was applied to study free-volume entities in Ge-Ga-S glasses having different amount of CsCl additives. These results serve as a basis for new direction in the characterization of inner free-volume structure of chalcohalide glass-ceramics conditionally declared as Positronics.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"89 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124586851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912379
I. Kindrat, B. Padlyak, V. Protsiuk, A. Drzewiecki, V. Adamiv, Y. Burak, I. Teslyuk
The high optical quality glasses with Li2B4O7:Eu, CaB4O7:Eu, and LiCaBO3:Eu compositions containing 0.5 and 1.0 mol. % Eu2O3 have been obtained by standard glass technology. Using electron paramagnetic resonance (EPR) and optical spectroscopy it was shown that the Eu impurity is incorporated into the Li2B4O7, CaB4O7, and LiCaBO3 glasses network as Eu3+ (4f6, 7F0) ions, exclusively. All observed f - f transitions of the Eu3+ centres in optical absorption, luminescence excitation and emission spectra were identified. Luminescence kinetic shows single exponential decay with different lifetimes for Eu3+ centres in the Li2B4O7, CaB4O7, and LiCaBO3 glasses.
{"title":"Optical spectroscopy of borate glasses, doped with europium","authors":"I. Kindrat, B. Padlyak, V. Protsiuk, A. Drzewiecki, V. Adamiv, Y. Burak, I. Teslyuk","doi":"10.1109/OMEE.2014.6912379","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912379","url":null,"abstract":"The high optical quality glasses with Li<sub>2</sub>B<sub>4</sub>O<sub>7</sub>:Eu, CaB<sub>4</sub>O<sub>7</sub>:Eu, and LiCaBO<sub>3</sub>:Eu compositions containing 0.5 and 1.0 mol. % Eu<sub>2</sub>O<sub>3</sub> have been obtained by standard glass technology. Using electron paramagnetic resonance (EPR) and optical spectroscopy it was shown that the Eu impurity is incorporated into the Li<sub>2</sub>B<sub>4</sub>O<sub>7</sub>, CaB<sub>4</sub>O<sub>7</sub>, and LiCaBO<sub>3</sub> glasses network as Eu<sup>3+</sup> (4f<sup>6</sup>, <sup>7</sup>F<sub>0</sub>) ions, exclusively. All observed f - f transitions of the Eu<sup>3+</sup> centres in optical absorption, luminescence excitation and emission spectra were identified. Luminescence kinetic shows single exponential decay with different lifetimes for Eu<sup>3+</sup> centres in the Li<sub>2</sub>B<sub>4</sub>O<sub>7</sub>, CaB<sub>4</sub>O<sub>7</sub>, and LiCaBO<sub>3</sub> glasses.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114619712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912399
V. Gayvoronsky, M. Brodyn, A. Uklein, I. Filipov, A. Popov, V. Kononets, O. Sidletskiy
For the first time the diagnostics of oxyorthosilicates single crystals based on self-action of picosecond range laser pulses at 1064 nm has been performed. It was found high sensitivity of the photoinduced refractive index variation to the substitution of the Lu atoms by Gd as well as the admixture of Ce to the LSO/LGSO crystalline matrix. The effect could be attributed to the different electron detrapping-recombination processes efficiencies due to the oxygen vacancies excitation.
{"title":"Impact of composition modification of oxyorthosilicates single crystals on pulsed laser radiation self-action effect manifestation","authors":"V. Gayvoronsky, M. Brodyn, A. Uklein, I. Filipov, A. Popov, V. Kononets, O. Sidletskiy","doi":"10.1109/OMEE.2014.6912399","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912399","url":null,"abstract":"For the first time the diagnostics of oxyorthosilicates single crystals based on self-action of picosecond range laser pulses at 1064 nm has been performed. It was found high sensitivity of the photoinduced refractive index variation to the substitution of the Lu atoms by Gd as well as the admixture of Ce to the LSO/LGSO crystalline matrix. The effect could be attributed to the different electron detrapping-recombination processes efficiencies due to the oxygen vacancies excitation.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117009817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2014-05-26DOI: 10.1109/OMEE.2014.6912392
Z. Chorniy, I. Pirko, S. Kachan
The paper presents the results of a study of thermo- and photostimulated transformations of colour centres in doped fluorite crystals. By means of certain sequence of such operations one can double the concentration of working MA+-colour centres.
{"title":"Control of radiation sensitivity of fluorites doped with non-isovalent impurities","authors":"Z. Chorniy, I. Pirko, S. Kachan","doi":"10.1109/OMEE.2014.6912392","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912392","url":null,"abstract":"The paper presents the results of a study of thermo- and photostimulated transformations of colour centres in doped fluorite crystals. By means of certain sequence of such operations one can double the concentration of working MA+-colour centres.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"83 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126402285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}