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EPR and optical spectroscopy of the V-doped borate glasses 掺v硼酸盐玻璃的EPR和光谱学
B. Padlyak, V. Protsiuk, I. Kindrat, A. Drzewiecki, V. Adamiv, Y. Burak, I. Teslyuk
The series of V-doped glasses with Li2O-2B2O3 (Li2B4O7), 1/2(Li2O-K2O-4B2O3), (LiKB4O7), CaO-2B2O3 (CaB4O7) and 1/2(Li2O-2CaO-B2O3) (LiCaBO3) composition containing 0.5 and 1.0 mol. % V2O5 oxide were obtained by standard glass technology. The electron paramagnetic resonance (EPR) and optical absorption spectra of the obtained glasses were investigated at T = 300 K. The spin Hamiltonian parameters for observed EPR spectra in the Li2B4O7:V, LiKB4O7:V, CaB4O7:V and LiCaBO3:V glasses were determined and electron and local structure of impurity V centres were proposed. The optical absorption bands, observed in the investigated glasses have been interpreted.
采用标准玻璃工艺制备了含有0.5和1.0 mol. % V2O5氧化物的Li2O-2B2O3 (Li2B4O7)、1/2(Li2O-K2O-4B2O3)、(LiKB4O7)、CaO-2B2O3 (CaB4O7)和1/2(Li2O-2CaO-B2O3) (LiCaBO3)的v掺杂玻璃系列。在T = 300 K时,研究了所得玻璃的电子顺磁共振(EPR)和光吸收光谱。测定了Li2B4O7:V、LiKB4O7:V、CaB4O7:V和LiCaBO3:V玻璃中EPR光谱的自旋哈密顿参数,并提出了杂质V中心的电子和局部结构。在所研究的玻璃中观察到的光学吸收带已被解释。
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引用次数: 2
X-ray luminescence of ZnMoO4 crystals developed in the framework of the LUMINEU program 在LUMINEU程序框架内开发的ZnMoO4晶体的x射线发光
V. Degoda, F. Danevich, N. Coron, I. Ivanov, Y. Kogut, E. Makarov, P. de Marcillac, S. G. Nasonov, L. Torres, V. Tretyak, V. Shlegel, Y. Vasiliev, M. Velázquez, V. N. Zhdankov
Luminescence of ZnMoO4 crystals developed in the framework of the LUMINEU double beta decay project under X-ray irradiation of different doses was studied in the temperature interval from 1.4 K to 295 K. We have found that concentration of shallow traps in ZnMoO4 crystals is much greater than the concentration of deep traps, and only shallow traps absorb a small part of the luminescence.
在LUMINEU双β衰变项目框架内制备的ZnMoO4晶体在1.4 ~ 295 K温度区间内不同剂量x射线照射下的发光特性进行了研究。我们发现ZnMoO4晶体中浅层陷阱的浓度远大于深层陷阱的浓度,并且只有浅层陷阱吸收了一小部分发光。
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引用次数: 0
Solid-state compositions for low-temperature sulphur dioxide oxidation consisting of natural clinoptilolite, copper(II) and halide ions 低温二氧化硫氧化的固态成分由天然斜沸石、铜(II)和卤化物离子组成
T. Rakitskaya, E. V. Kameneva, T. Kiose, V. Volkova
Solid-state compositions containing copper(II) chloride, halide ions (X-), and natural clinoptilolite (N-CLI) were obtained. N-CLI and CuCl2-KX/N-CLI samples were characterized by X-ray diffraction phase analysis, IR spectroscopy, thermogravimetry, water vapor adsorption, and pH-metry. In addition, they were tested in the reaction of sulfur dioxide oxidation with air oxygen. As found, N-CLI has no protective properties against sulfur dioxide and the protective time of CuCl2-KX/N-CLI increases in the order Cl- <; Br- <; I-.
得到了含有氯化铜(II)、卤化物离子(X-)和天然斜沸石(N-CLI)的固态组合物。采用x射线衍射、物相分析、红外光谱、热重、水蒸气吸附和ph法对N-CLI和CuCl2-KX/N-CLI样品进行了表征。此外,还在二氧化硫与空气氧的氧化反应中进行了测试。结果表明,N-CLI对二氧化硫无保护作用,CuCl2-KX/N-CLI的保护时间按Cl- - -的顺序递增。
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引用次数: 1
Structural and electro-physical properties of ZnO films, obtained by nonvacuum chemical method 用非真空化学方法获得ZnO薄膜的结构和电物理性质
K. Avramenko, N. Roshchina, G. Olkhovik, P. Smertenko, L. V. Zavyalova
This paper reports on the ZnO film structures obtained by MOCVD method from acetylacetonate of zinc on silicon substrates at 280-320 °C substrate. The structural, emitting and transport properties of the ZnO films were examined by X-ray diffraction, Scanning electronic microscopy, Photoluminescent microscopy and Current-Voltage methods. The electrical transport mechanisms were analyzed on the base of differential and injection approaches. The ZnO/Si structure with ZnO film obtained was found to be appropriate for use in electronic devices due to their structural and electrical properties.
本文报道了以锌的乙酰丙酮酸盐为原料,在280 ~ 320℃的硅衬底上用MOCVD法制备的ZnO薄膜结构。采用x射线衍射、扫描电镜、光致发光显微镜和电流-电压法研究了ZnO薄膜的结构、发射和输运特性。在微分法和注入法的基础上,分析了电输运机理。所获得的ZnO/Si结构和ZnO薄膜具有良好的结构和电学性能,适合用于电子器件。
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引用次数: 0
3D computer models reference book “T-x-y diagrams of oxide systems” 三维计算机模型参考书《氧化物系统的T-x-y图》
V. Lutsyk, V. Vorob’eva
The Reference Book of ternary systems phase diagrams computer models for molybdenum and tungsten compounds is presented. Its models give a possibility to calculate the mass balances in any temperature intervals, to observe crystallization history and the process of microstructure forming at different crystallization stages.
介绍了钼、钨化合物三元体系相图计算机模型参考书。该模型为计算任意温度区间的质量平衡、观察结晶历史和不同结晶阶段的微观结构形成过程提供了可能。
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引用次数: 0
Spectroscopy of the alkali-metal nitrite and nitrate incorporated into cellulose host matrix 光谱学的碱金属亚硝酸盐和硝酸盐纳入纤维素宿主基质
S. Revo, S. Nedilko, K. Ivanenko, V. Scherbatskii, T. Avramenko, M. Nedielko
Morphology and photoluminescence (PL) properties for microcrystalline cellulose (MCC), microcrystalline nitrite, MNO2, or nitrate, MNO3, (MCN) powders of common formulae MNOn (n = 2, 3) (M = Na. K, Cs) and two-component materials composed of MCC and MCN have been studied and characterized.
常用配方MNOn (n = 2,3) (M = Na)的微晶纤维素(MCC)、微晶亚硝酸盐(MNO2)或硝酸盐(MNO3) (MCN)粉末的形貌和光致发光(PL)性能。对K、Cs和MCC、MCN组成的双组分材料进行了研究和表征。
{"title":"Spectroscopy of the alkali-metal nitrite and nitrate incorporated into cellulose host matrix","authors":"S. Revo, S. Nedilko, K. Ivanenko, V. Scherbatskii, T. Avramenko, M. Nedielko","doi":"10.1109/OMEE.2014.6912339","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912339","url":null,"abstract":"Morphology and photoluminescence (PL) properties for microcrystalline cellulose (MCC), microcrystalline nitrite, MNO<sub>2</sub>, or nitrate, MNO<sub>3</sub>, (MCN) powders of common formulae MNO<sub>n</sub> (n = 2, 3) (M = Na. K, Cs) and two-component materials composed of MCC and MCN have been studied and characterized.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"25 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134157561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Growth, structure and characterization of solid solution Ca9Y(VO4)7-x(PO4)x single crystals 固溶体Ca9Y(VO4)7-x(PO4)x单晶的生长、结构和表征
V. Baumer, M. Kosmyna, P. Mateichenko, B. P. Nazarenko, V. Puzikov, I. Ogorodnyk, N. Slobodyanik, A. N. Shekhovtsov, N. Strutynska, I. Zatovsky
The Ca9Y(VO4)7-x(PO4)x (X=0-7) solid solution samples of synthesized ceramics and single crystals grown by the Czochralski method were characterized by powder and single crystal X-ray diffraction and optical spectroscopy. The microhardness Hv and fracture toughness K1c of solid solution single crystals were investigated.
对Czochralski法制备的Ca9Y(VO4)7-x(PO4)x (x =0-7)固溶体和单晶样品进行了粉末和单晶x射线衍射及光谱学表征。研究了固溶体单晶的显微硬度Hv和断裂韧性K1c。
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引用次数: 0
Stability and applications of high-temperature piezoelectric crystals 高温压电晶体的稳定性及应用
H. Fritze, M. Schulz, D. Richter
High-temperature piezoelectric crystals such as gallium phosphate (GaPO4) and langasite (La3Ga5SiO14) have been demonstrated to show piezoelectric properties at fairly high temperatures. For example, langasite can be exited piezoelectrically up to temperatures close to its melting point at about 1470 °C. The resonance behavior including damping and temperature dependent frequency of resonators made of these crystals are investigated and reviewed to evaluate the applicability of such devices as high-temperature gas sensors or film deposition monitors.
高温压电晶体如磷酸镓(GaPO4)和langasite (La3Ga5SiO14)已被证明在相当高的温度下表现出压电特性。例如,在接近其熔点(约1470°C)的温度下,langasite可以以压电方式析出。研究和回顾了由这些晶体制成的谐振器的谐振行为,包括阻尼和温度相关频率,以评估这些设备作为高温气体传感器或薄膜沉积监视器的适用性。
{"title":"Stability and applications of high-temperature piezoelectric crystals","authors":"H. Fritze, M. Schulz, D. Richter","doi":"10.1109/OMEE.2014.6912420","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912420","url":null,"abstract":"High-temperature piezoelectric crystals such as gallium phosphate (GaPO4) and langasite (La3Ga5SiO14) have been demonstrated to show piezoelectric properties at fairly high temperatures. For example, langasite can be exited piezoelectrically up to temperatures close to its melting point at about 1470 °C. The resonance behavior including damping and temperature dependent frequency of resonators made of these crystals are investigated and reviewed to evaluate the applicability of such devices as high-temperature gas sensors or film deposition monitors.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134382656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Iron borate based monocrystals for research in magneto-ordered state physics 磁有序态物理研究中的硼酸铁单晶
S. Yagupov, E. Maksimova, I. Nayhatsky, V. Yagupov, E. Milyukova, K. Seleznyova, M. Strugatsky
Elemental composition and crystal structure of synthesized monocrystal series FexGa1-xBO3, which is model object for fundamental research of magneto-ordered state physics, was investigated. It was established that the crystal lattice parameters weakly grow with magnetic ion concentration increase.
对合成的单晶系列FexGa1-xBO3的元素组成和晶体结构进行了研究,该单晶系是磁有序态物理基础研究的模型对象。结果表明,晶体晶格参数随磁性离子浓度的增加呈弱增长。
{"title":"Iron borate based monocrystals for research in magneto-ordered state physics","authors":"S. Yagupov, E. Maksimova, I. Nayhatsky, V. Yagupov, E. Milyukova, K. Seleznyova, M. Strugatsky","doi":"10.1109/OMEE.2014.6912415","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912415","url":null,"abstract":"Elemental composition and crystal structure of synthesized monocrystal series FexGa1-xBO3, which is model object for fundamental research of magneto-ordered state physics, was investigated. It was established that the crystal lattice parameters weakly grow with magnetic ion concentration increase.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"28 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121965464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Solar sintering and characterization of ZnO-TiO2-based photo-anode applicable for water splitting 用于水分解的zno - tio2基光阳极的太阳烧结及表征
J. Fidelus, R. Minikayev, W. Paszkowicz, Y. Suhak, M. Berkowski, I. Cañadas Martinez, J. Rodríguez Garcia, A. Suchocki
This paper reports on the ZnO-TiO2 ceramics sintered under solar radiation. The phase composition, structure, morphology and functional properties of ZnO-TiO2 photo-anodes (used in photoelectrochemical cells for hydrogen generation from water splitting) were investigated.
本文报道了在太阳辐射下烧结的ZnO-TiO2陶瓷。研究了ZnO-TiO2光阳极的物相组成、结构、形貌和功能特性。
{"title":"Solar sintering and characterization of ZnO-TiO2-based photo-anode applicable for water splitting","authors":"J. Fidelus, R. Minikayev, W. Paszkowicz, Y. Suhak, M. Berkowski, I. Cañadas Martinez, J. Rodríguez Garcia, A. Suchocki","doi":"10.1109/OMEE.2014.6912354","DOIUrl":"https://doi.org/10.1109/OMEE.2014.6912354","url":null,"abstract":"This paper reports on the ZnO-TiO2 ceramics sintered under solar radiation. The phase composition, structure, morphology and functional properties of ZnO-TiO2 photo-anodes (used in photoelectrochemical cells for hydrogen generation from water splitting) were investigated.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"99 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127142229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)
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