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Fermentative Production of MCL Poly(3-hydroxyalkanoate) MCL聚3-羟基烷酸酯的发酵生产
Pub Date : 2002-11-29 DOI: 10.1002/3527600035.BPOL3A10
R. Weusthuis, B. Kessler, M. Dielissen, B. Witholt, G. Eggink
Introduction Historical Outline Occurrence Functions Biochemistry β-Oxidation Fatty Acid Synthesis Unsaturated Fatty Acids Physiology and Process Development Fermentation Process Development Control of MCL-Poly(3HA) Monomer Composition Oxygen Transfer and Heat Production Byproducts Molecular Genetics Recombinant Pseudomonads Recombinant E. coli Downstream Processing Production MCL-Poly(3HA) Production versus SCL-Poly(3HA) Production Producers Applications Patents Outlook and Perspectives Acknowledgements Keywords: medium-chain-length poly(3-hydroxyalkanoate); polyester; fermentation; fluorescent Pseudomonads; Pseudomonas oleovorans; Pseudomonas putida; MCL-Poly(3HA) synthesis; fatty acid synthesis; β-oxidation; genetic modification; Escherichia coli; continuous cultivation; fed-batch cultivation; two-phase cultivation; oxygen transfer; heat transfer; down-stream processing
历史概述发生功能生化β-氧化脂肪酸合成不饱和脂肪酸生理及工艺发展发酵工艺发展控制MCL-Poly(3HA)单体组成氧转移产热副产物分子遗传学重组假单胞菌重组大肠杆菌下游加工生产MCL-Poly(3HA)生产与SCL-Poly(3HA)生产生产商应用专利展望与展望关键词:中链长聚3-羟基烷酸酯;聚酯纤维;发酵;荧光假单胞菌;假单胞菌oleovorans;假单胞菌putida;MCL-Poly(3公顷)合成;脂肪酸合成;β氧化;基因改造;大肠杆菌;连续培养;馈料式栽培;两相培养;氧转移;传热;加处理
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引用次数: 1
Biological Susceptibility of Polystyrene 聚苯乙烯的生物敏感性
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9016
A. Tsuchii, Y. Hiraguri, Y. Tokiwa
Introduction Historical Outline Microbial Degradation of Styrene Oligomers Biological Susceptibility of Polystyrene Enzymatic Hydrolysis of Styrene Copolymers Biological Disintegration of Polystyrene Blends Production Outlook and Perspectives Keywords: biological susceptibility; polystyrene; styrene dimer; styrene copolymer; polystyrene blend
苯乙烯低聚物微生物降解聚苯乙烯生物敏感性聚苯乙烯酶解共聚物生物分解聚苯乙烯共混物生产展望与展望关键词:生物敏感性;聚苯乙烯;苯乙烯二聚体;苯乙烯共聚物;聚苯乙烯混合
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引用次数: 0
Biodegradable Plastics from Cellulose and Lignocellulosics 由纤维素和木质纤维素制成的可生物降解塑料
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9010
M. Yoshioka
Introduction Historical Outline Plastics from Cellulose Acetate Plasticization of CA with Dibasic Acid Anhydrides and Monoepoxides during Melt-processing, and Their Biodegradabilities Cellulose Acetate Plasticized by Grafting with Cyclic Esters Plastics from Lignocellulose and Applications to Biodegradable Polymers Plasticization of Wood by Benzylation and Blending with Polycaprolactone Bio- and Photo-degradabilities of BzW and BzW/PCL Composites Production Outlook and Perspectives Patents Keywords: biodegradable polymers from biomass; cellulose; lignocellulose; thermoplasticization; wood plasticization; external plasticization; blend; compatibilizer; plasticizer; bleeding; internal plasticization; cellulose derivatives; nitrocellulose; cellulose acetate; graft copolymerization; graft polymer; homopolymer; melt-processing; molding; biodegradation; mineralization; polyurethane; regenerated cellulose; interpenetrating polymer network
醋酸纤维素制塑料的历史概况:在熔融加工过程中,CA与二酸酐和单环氧化物共塑木质纤维素环酯接枝增塑醋酸纤维素及其在生物降解聚合物中的应用木质苄酰化和聚己内酯共混增塑BzW和BzW/PCL复合材料的生物降解性和光降解性生产前景与展望专利关键词:生物质可降解聚合物;纤维素;木质纤维素;thermoplasticization;木塑化;外部增塑作用;混合;增容剂;塑化剂;出血;内增塑作用;纤维素衍生物;硝化纤维素;醋酸纤维素;接枝共聚;接枝聚合物;均聚物;melt-processing;成型;生物降解;矿化;聚氨酯;再生纤维素;互穿聚合物网络
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引用次数: 4
Biodegradation of Polyanhydrides 聚酸酐的生物降解
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9020
Neeraj Kumar, M. Ravikumar, Raia Slivniak, Michal Y. Krasko, A. Domb
Introduction Degradation: A Real Meaning Mechanisms Involved in Degradation Historical Outline Polymer Erosion Changes in Polymer Structure During Erosion Factors Affecting Degradation Synthesis Structures Surface Analysis Polyanhydride Degradation: In-vitro and In-vivo Approaches In-vitro Degradation and Drug Release In-vivo Degradation and Drug Release Modeling of Polymer Erosion Production of Polyanhydrides World Market Applications Patents Outlook and Perspectives Keywords: polyanhydrides; biodegradation; surface erosion; bulk erosion; surface analysis; modeling; drug release; biocompatible polymer
降解:真正的意义降解机制历史概述聚合物侵蚀侵蚀过程中聚合物结构的变化影响降解的因素合成结构表面分析聚酸酐降解:体外和体内方法体外降解和药物释放体内降解和药物释放聚合物侵蚀建模聚酸酐生产世界市场应用专利前景与展望关键词:polyanhydrides;生物降解;表面侵蚀;大量流失;表面分析;建模;药物释放;生物相容性的聚合物
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引用次数: 1
Biodegradation of Silicones (Organosiloxanes) 有机硅(有机硅氧烷)的生物降解
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9024
J. Lukasiak, A. Dorosz, M. Prokopowicz, P. Rosciszewski, B. Falkiewicz
Introduction Historical Outline Chemical Structures Occurrence and Functions Properties, Degradation and Biodegradation Degradation and Biodegradation In vitro Biodegradation In vivo Silicone Industry Production of Silicones Main Commercial Silicone Producers Patents Outlook and Perspectives Keywords: bacteria; biodegradation; clays; decamethylcyclopentasiloxane; dimethylsilanediol; dodecamethylcyclohexasiloxane; environmental degradation; environmental fate; fungi; intestinal absorption; metabolism; methylsilanetriol; octamethylcyclotetrasiloxane; organosiloxane; photolytic degradation; polydimethylcyclosiloxane; polydimethylsiloxane; sewage; silicone; silicone prostheses; silicone rubber; siloxane; soil; soil amendment; trimethylsilanol; volatile methylsiloxanes
引言历史概述化学结构发生与功能性质降解与生物降解降解与生物降解体外生物降解体内有机硅工业有机硅生产主要商业有机硅生产商专利展望关键词:细菌;生物降解;粘土;decamethylcyclopentasiloxane;dimethylsilanediol;dodecamethylcyclohexasiloxane;环境恶化;环境的命运;真菌;肠道吸收;新陈代谢;methylsilanetriol;octamethylcyclotetrasiloxane;硅氧烷;光解的退化;polydimethylcyclosiloxane;聚二甲硅氧烷;污水;有机硅;硅胶假体;硅橡胶;硅氧烷;土壤;土壤改良剂;trimethylsilanol;不稳定的甲基硅氧烷
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引用次数: 5
Biodegradation of Nylon and other Synthetic Polyamides 尼龙和其他合成聚酰胺的生物降解
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9018
S. Negoro
Introduction Historical Outline Chemical Structures, and Preparation of Nylon Oligomers Cyclic Oligomers of 6-Aminohexanoate Linear Oligomers of 6-Aminohexanoate and their Related Compounds Production and Main Applications of Nylon Biodegradation Biodegradation of Polyamides Biodegradation of ɛ-Caprolactam Biodegradation of Nylon Oligomer Outlook and Perspectives Patents Keywords: nylon; polyamide; nylon oligomer; 6-aminohexanoate; degradative plasmid; pOAD2; enzyme evolution; hybrid enzyme; adaptation
简介历史概述、化学结构、尼龙低聚物的制备及6-氨基己酸环低聚物、6-氨基己酸线性低聚物及其相关化合物尼龙生物降解的生产及主要应用聚酰胺生物降解-己内酰胺生物降解尼龙低聚物展望专利关键词:尼龙;聚酰胺;尼龙低聚物;6-aminohexanoate;使下降的质粒;pOAD2;酶进化;混合酶;适应
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引用次数: 27
Biodegradation of Poly(alkylcyanoacrylates) 聚烷基氰基丙烯酸酯的生物降解
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9021
C. Vauthier, P. Couvreur
Introduction Historical Outline Synthesis and Purification of Alkylcyanoacrylate Monomers Polymer Synthesis General Considerations Bulk Polymerization Polymerization in Organic Solvents Emulsion Polymerization: Preparation of Matricial PACA Nanoparticles (Nanospheres) Interfacial Polymerization: Preparation of Reservoir-Type PACA Nanoparticles (Nanocapsules) Synthesis of Amphiphilic Block Copolymers Containing PACA Segments World Market Characterization and Methods of Analysis Stability and Mechanism of Degradation Toxicity Application of PACA in the Design of Drug Delivery Systems Use of “Conventional” PACA Nanoparticles From “Conventional” to Targeted Systems Patent Overview Outlook and Perspectives Keywords: alkylcyanoacrylate; anionic polymerization; cancer; copolymer; degradation; drug delivery system; nanocapsule; nanoparticle; nanosphere; ocular; oligonucleotide; peptide; poly(alkylcyanoacrylate); poly(ethylene glycol); protein; radical polymerization; toxicity; zwitterionic polymerization
概述氰基丙烯酸烷基酯单体的合成与纯化聚合物的合成一般注意事项本体聚合有机溶剂聚合乳液聚合制备PACA纳米颗粒(纳米球)界面聚合储层型PACA纳米颗粒(纳米胶囊)的制备含PACA段的两亲性嵌段共聚物的合成世界市场表征及分析方法稳定性及降解毒性机理PACA在药物传递系统设计中的应用“常规”PACA纳米颗粒从“常规”到“靶向”系统专利概述前景展望关键词:氰基丙烯酸烷基酯;阴离子聚合;癌症;共聚物;退化;给药系统;nanocapsule;纳米颗粒;nanosphere;眼;寡核苷酸;肽;保利(alkylcyanoacrylate);聚(乙二醇);蛋白质;自由基聚合;毒性;两性离子聚合
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引用次数: 4
Biodegradation of Polyphosphazenes 聚磷腈的生物降解
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9022
K. Zhu, L. Qiu
Introduction Historical Outline Chemical Structures Occurrence Functions Controlled Drug Release Temporary Replacement of Body Parts Physiology Biodegradation Hydrophobic Matrix Water-soluble Matrix Polyphosphazene–Drug Conjugation Products Outlook and Perspectives Patents Keywords: polyphosphazene; biodegradation; biocompatibility; hydrophobic matrices; water-soluble polymers; hydrogel; polymer conjugates; drug controlled release; temporary body displacement
简介历史概述化学结构发生功能控释药物暂时替代身体部位生理生物降解疏水基质水溶性基质聚磷腈-药物偶联产物展望专利关键词:聚磷腈;生物降解;生物相容性;疏水矩阵;水溶性聚合物;水凝胶;使共轭聚合物;药物控释;临时体位移
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引用次数: 1
Biodegradation of Synthetic Water‐Soluble Polymers 合成水溶性聚合物的生物降解
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9011
G. Swift
Introduction Historical Outline Definitions Disposal Options for Biodegradable Water-Soluble Polymers Test Methods for Biodegradable Water-Soluble Polymers Biodegradable Water-Soluble Polymers Carbon-Chain Polymers Poly(Vinyl Alcohol) Polycarboxylates Heteroatom Chain Polymers Polyesters and Polyamides Polyethers Modified Natural Polymers Graft Polymers Chemical Modification of Polysaccharides Summary Keywords: polymeric carboxylic acid; detergent; condensation polymers; test methodology
生物可降解水溶性聚合物的试验方法生物可降解水溶性聚合物碳链聚合物聚(乙烯醇)聚羧酸杂原子链聚合物聚酯和聚酰胺聚醚改性天然聚合物接枝聚合物多糖的化学改性洗涤剂;缩合聚合物;测试方法
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引用次数: 0
Biodegradation of Poly(vinyl alcohol) and its Copolymers 聚乙烯醇及其共聚物的生物降解
Pub Date : 2002-10-30 DOI: 10.1002/3527600035.BPOL9015
S. Matsumura
Introduction Historical Outline Chemical Structures Functions Physical Properties Properties of PVA film Properties of Aqueous PVA Solution Chemical Properties of PVA Physiology and Biochemistry Biodegradation Microbial Degradation of PVA and Related Enzymes PVA Biodegradation Mechanism and Related Enzymes Polymer Structure and Biodegradation Biodegradation of PVA-based Polymer Design of Biodegradable Polymer using Vinyl Alcohol Block Production Outlook and Perspectives Patents Acknowledgments Keywords: aerobic biodegradation; anaerobic biodegradation; aldolase; Alcaligenes faecalis; atactic PVA; biodegradation; blend polymer; design of biodegradable polymer; β-diketone hydrolase; β-dihydroxy monoketone; β-diketone; graft polymer; isotactic PVA; oxidized PVA hydrolase; microbe; poly(vinyl alcohol); PVA; poly(vinyl acetate); poly(vinyl butyral); poly(vinyloxy acetate); Pseudomonas; PVA copolymer; PVA dehydrogenase; PVA oxidase; secondary alcohol oxidase; symbiotic mixed culture; syndiotactic PVA; tacticity; sewage treatment plant; water-soluble polymer
简介历史概述化学结构功能物理性质PVA膜性质PVA水溶液性质PVA化学性质生理生化生物降解微生物降解PVA及相关酶PVA生物降解机理及相关酶聚合物结构与生物降解PVA基聚合物生物降解设计利用乙烯醇块生产生物降解聚合物专利展望与展望关键词:好氧生物降解;厌氧生物降解;醛缩酶;粪产碱杆菌属;无规立构的PVA;生物降解;混合聚合物;可生物降解聚合物的设计;β二酮水解酶;β二羟monoketone;β二酮;接枝聚合物;全同立构的PVA;氧化PVA水解酶;微生物;聚(乙烯醇);PVA;聚醋酸乙烯酯);聚(乙烯基缩丁醛);保利(醋酸vinyloxy);假单胞菌;PVA共聚物;PVA脱氢酶;PVA氧化酶;次生醇氧化酶;共生混合培养;间同立构PVA;立构规整度;污水处理厂;水溶性聚合物
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引用次数: 11
期刊
Biopolymers Online
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