首页 > 最新文献

Journal of the Turkish Chemical Society Section A: Chemistry最新文献

英文 中文
Investigation of Radiation-Heterogeneous and Catalytic Processes In The Surface Of (RaO)x(SiO2)y +H2O System (RaO)x(SiO2)y +H2O体系表面辐射非均相及催化过程的研究
Pub Date : 2023-04-25 DOI: 10.18596/jotcsa.1118855
Z. Mansimov, G. Imanova, A. Garibov, T. Agayev
In the study, heterogeneous radiolysis of water in adsorption and liquid form was studied in the (RaO)x(SiO2)y+H2O system. The effect of radioactivity of radium cations and process temperature on the release of molecular hydrogen was determined (T=300‒673K). The mechanism of heterogeneous radiolysis of water with the participation of the studied system (RaO)x(SiO2)y+H2O has been proposed.
研究了水在(RaO)x(SiO2)y+H2O体系中的吸附和液态非均相辐射分解。测定了镭离子的放射性和工艺温度对氢分子释放的影响(T= 300-673K)。提出了研究体系(RaO)x(SiO2)y+H2O参与水非均相辐射分解的机理。
{"title":"Investigation of Radiation-Heterogeneous and Catalytic Processes In The Surface Of (RaO)x(SiO2)y +H2O System","authors":"Z. Mansimov, G. Imanova, A. Garibov, T. Agayev","doi":"10.18596/jotcsa.1118855","DOIUrl":"https://doi.org/10.18596/jotcsa.1118855","url":null,"abstract":"In the study, heterogeneous radiolysis of water in adsorption and liquid form was studied in the (RaO)x(SiO2)y+H2O system. The effect of radioactivity of radium cations and process temperature on the release of molecular hydrogen was determined (T=300‒673K). The mechanism of heterogeneous radiolysis of water with the participation of the studied system (RaO)x(SiO2)y+H2O has been proposed.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81804637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Probing the Electro-Chemical and Thermal Properties of Polyaniline/MWCNT Nanocomposites 聚苯胺/MWCNT纳米复合材料的电化学和热性能研究
Pub Date : 2023-04-24 DOI: 10.18596/jotcsa.1177040
S. J. Paul, Sarvesh Kumar Singh, Jaya Tuteja, A. Sand, P. Chandra
The tremendous interest for robust, clean energy storage devices to comprehend the growing needs of modern gadgets has led to exploration of materials having unprecedented electrochemical and interfacial properties. Here, the present study deals with the synergistic effects of multi walled carbon nanotubes and polyaniline nanocomposites on the electro-chemical and thermal properties for wide-range of applications. The microstructural, structural, and optical characterizations have been evaluated through scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and UV-Vis spectrophotometry. The thermal stability of the product was also studied through thermal gravimetric analysis (TGA) and the room temperature electrical conductivity was also measured. An exceptional enhancement in thermal stability and conductivity has been observed apparently due to interfacial properties of polyaniline (PANI) and multiwalled carbon nanotubes (MWCNTs). Further, in present study we are going to report a comparative analysis of thermal and electrical properties of PANI/MWCNT nanocomposites with different loadings of MWCNTs. The room temperature conductivity as calculated for 1%, 2%, 4% and 8% MWCNT loading is around 2.019, 3.075, 4.48, 8.73 S/cm respectively. The mechanism for thermal and electrical enhancements in PANI-coated MWCNT nanocomposites is also expounded.
为了满足现代设备日益增长的需求,人们对强大的清洁能源存储设备产生了巨大的兴趣,这导致了对具有前所未有的电化学和界面特性的材料的探索。本文研究了多壁碳纳米管和聚苯胺纳米复合材料在电化学和热性能方面的协同效应,具有广泛的应用前景。通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、x射线衍射(XRD)、傅里叶变换红外光谱(FTIR)和紫外可见分光光度法对其微观结构、结构和光学特性进行了评价。通过热重分析(TGA)研究了产物的热稳定性,并测定了产物的室温电导率。聚苯胺(PANI)和多壁碳纳米管(MWCNTs)的界面特性明显增强了材料的热稳定性和导电性。此外,在本研究中,我们将对不同MWCNTs负载的聚苯胺/MWCNT纳米复合材料的热学和电学性能进行比较分析。在1%、2%、4%和8% MWCNT负载下,室温电导率分别约为2.019、3.075、4.48和8.73 S/cm。并阐述了聚苯胺包覆MWCNT纳米复合材料的热学和电学增强机理。
{"title":"Probing the Electro-Chemical and Thermal Properties of Polyaniline/MWCNT Nanocomposites","authors":"S. J. Paul, Sarvesh Kumar Singh, Jaya Tuteja, A. Sand, P. Chandra","doi":"10.18596/jotcsa.1177040","DOIUrl":"https://doi.org/10.18596/jotcsa.1177040","url":null,"abstract":"The tremendous interest for robust, clean energy storage devices to comprehend the growing needs of modern gadgets has led to exploration of materials having unprecedented electrochemical and interfacial properties. Here, the present study deals with the synergistic effects of multi walled carbon nanotubes and polyaniline nanocomposites on the electro-chemical and thermal properties for wide-range of applications. The microstructural, structural, and optical characterizations have been evaluated through scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and UV-Vis spectrophotometry. The thermal stability of the product was also studied through thermal gravimetric analysis (TGA) and the room temperature electrical conductivity was also measured. An exceptional enhancement in thermal stability and conductivity has been observed apparently due to interfacial properties of polyaniline (PANI) and multiwalled carbon nanotubes (MWCNTs). Further, in present study we are going to report a comparative analysis of thermal and electrical properties of PANI/MWCNT nanocomposites with different loadings of MWCNTs. The room temperature conductivity as calculated for 1%, 2%, 4% and 8% MWCNT loading is around 2.019, 3.075, 4.48, 8.73 S/cm respectively. The mechanism for thermal and electrical enhancements in PANI-coated MWCNT nanocomposites is also expounded.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"4 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87463184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Molecular docking studies and biological activities of benzenesulfonamide-based thiourea and thiazolidinone derivatives targeting cholinesterases, α-glucosidase, and α-amylase enzymes 针对胆碱酯酶、α-葡萄糖苷酶和α-淀粉酶的苯磺酰胺基硫脲和噻唑烷酮衍生物的分子对接研究及其生物活性
Pub Date : 2023-04-19 DOI: 10.18596/jotcsa.1111172
Mehtap Tugrak Sakarya, H. I. Gül, C. Yamali, Parham Taslimi, Tuğba Taşkın Tok
Alzheimer's disease (AD) and diabetes mellitus (DM) are related to abnormal changes in enzyme activity. While acetylcholinesterase (AChE) and butyrylcholinesterase (BChE) are the primary targets in the treatment of Alzheimer's disease (AD), α-glucosidase (α-Gly) and α-amylase (α-Amy) enzymes are known for diabetes mellitus (DM). Here, benzenesulfonamide-based thiourea and thiazolidinone derivatives such as AChE, BChE, α-Gly, and α-Amy inhibitors were reported. The results revealed that compounds 1d and 2c showed promising AChE and BChE inhibition effects. Compound 2a was the most potent inhibitor against α-glycosidase and α-amylase, respectively. Molecular docking studies indicated that the lead compounds' binding energy values and molecular interactions were better than that of tacrine and acarbose. The most bioactive compounds may be considered potent leads for further studies.
阿尔茨海默病(AD)和糖尿病(DM)与酶活性异常变化有关。乙酰胆碱酯酶(AChE)和丁基胆碱酯酶(BChE)是治疗阿尔茨海默病(AD)的主要靶点,而α-葡萄糖苷酶(α-Gly)和α-淀粉酶(α-Amy)酶是治疗糖尿病(DM)的已知靶点。本文报道了基于苯磺酰胺的硫脲和噻唑烷酮衍生物,如AChE、BChE、α-Gly和α-Amy抑制剂。结果表明,化合物1d和2c具有良好的AChE和BChE抑制作用。化合物2a对α-糖苷酶和α-淀粉酶的抑制作用最强。分子对接研究表明,先导化合物的结合能值和分子相互作用优于他克林和阿卡波糖。最具生物活性的化合物可能被认为是进一步研究的有力线索。
{"title":"Molecular docking studies and biological activities of benzenesulfonamide-based thiourea and thiazolidinone derivatives targeting cholinesterases, α-glucosidase, and α-amylase enzymes","authors":"Mehtap Tugrak Sakarya, H. I. Gül, C. Yamali, Parham Taslimi, Tuğba Taşkın Tok","doi":"10.18596/jotcsa.1111172","DOIUrl":"https://doi.org/10.18596/jotcsa.1111172","url":null,"abstract":"Alzheimer's disease (AD) and diabetes mellitus (DM) are related to abnormal changes in enzyme activity. While acetylcholinesterase (AChE) and butyrylcholinesterase (BChE) are the primary targets in the treatment of Alzheimer's disease (AD), α-glucosidase (α-Gly) and α-amylase (α-Amy) enzymes are known for diabetes mellitus (DM). Here, benzenesulfonamide-based thiourea and thiazolidinone derivatives such as AChE, BChE, α-Gly, and α-Amy inhibitors were reported. The results revealed that compounds 1d and 2c showed promising AChE and BChE inhibition effects. Compound 2a was the most potent inhibitor against α-glycosidase and α-amylase, respectively. Molecular docking studies indicated that the lead compounds' binding energy values and molecular interactions were better than that of tacrine and acarbose. The most bioactive compounds may be considered potent leads for further studies.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76777149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of New Azo Compounds and Their Application for a Simple Spectrophotometric Determination of Methyldopa Drug Using Anthranilic Acid and 2-Aminopyrimidine as Reagents 新型偶氮化合物的合成及其在以邻氨基苯甲酸和2-氨基嘧啶为试剂分光光度法测定甲基多巴药物中的应用
Pub Date : 2023-04-18 DOI: 10.18596/jotcsa.1234028
Ekhlas ABD ALKAREEM, Nuha FARHAN ABD AL-KARİM, Israa I Mahmoud
The goal of the current work is to synthesize methyldopa derivatives. Based on these reactions, two easy, speedy, accurate, inexpensive, and sensitive spectrophotometric approaches have been established for determining methyldopa (MED) in both pure and pharmaceutical forms. The proposed azo-coupling method depends on forming an azo compound between methyldopa drug and 2-AMPY or ANTH to produce two compounds of MED-2AMPY and MED-ANTH in the alkaline medium. The characterization of synthesized compounds utilizing UV-Visible and FT-IR spectra. FT-IR spectra of 2AMPY-MED confirm the existence of OH, C-Hor, C-Hal, NH, N=N, C=O, and C=C vibration at 3455, 3059, 2973, 3100, 1476,1692, and 1560 cm-1, and FT-IR spectra of ANTH-MED confirm the existence of OH, C-Hor, NH, C=O and N=N vibration at 3490, 3050, 3100, 1701 and 1462 cm-1, correspondingly. The obtained color of azo compounds is spectrophotometrically measured for the previously mentioned azo compounds at 450 and 455 nm, respectively. Under perfect conditions, the azo compound solutions exhibited molar absorptivities of 1563.0058 and 2091.0285 L.mol-1.cm-1, Sandell's sensitivity of 0.135 and 0.10 µg.cm-1, and Beer-Lambert's law are obeyed over the ranges 6.25- 62.5 mg. L-1 for the two developed procedures, respectively.
本研究的目的是合成甲基多巴衍生物。基于这些反应,建立了两种简便、快速、准确、廉价、灵敏的分光光度法测定纯甲基多巴和药物甲基多巴。本文提出的偶氮偶联方法是在甲基多巴药物与2-AMPY或ANTH之间形成偶氮化合物,在碱性介质中产生MED-2AMPY和MED-ANTH两种化合物。利用紫外可见光谱和红外光谱对合成化合物进行表征。2AMPY-MED的FT-IR光谱证实了3455、3059、2973、3100、1476、1692和1560 cm-1处OH、C- hor、C- hal、NH、N=N、C=O和C=C振动的存在,ANTH-MED的FT-IR光谱分别证实了3490、3050、3100、1701和1462 cm-1处OH、C- hor、NH、C=O和N=N振动的存在。所得到的偶氮化合物的颜色分别在450和455nm处用分光光度法测量。在理想条件下,偶氮化合物溶液的摩尔吸收率分别为1563.0058和2091.0285 l mol-1。cm-1, Sandell灵敏度为0.135和0.10µg。在6.25- 62.5 mg范围内,均符合比尔-朗伯定律。L-1分别为两个开发的程序。
{"title":"Synthesis of New Azo Compounds and Their Application for a Simple Spectrophotometric Determination of Methyldopa Drug Using Anthranilic Acid and 2-Aminopyrimidine as Reagents","authors":"Ekhlas ABD ALKAREEM, Nuha FARHAN ABD AL-KARİM, Israa I Mahmoud","doi":"10.18596/jotcsa.1234028","DOIUrl":"https://doi.org/10.18596/jotcsa.1234028","url":null,"abstract":"The goal of the current work is to synthesize methyldopa derivatives. Based on these reactions, two easy, speedy, accurate, inexpensive, and sensitive spectrophotometric approaches have been established for determining methyldopa (MED) in both pure and pharmaceutical forms. The proposed azo-coupling method depends on forming an azo compound between methyldopa drug and 2-AMPY or ANTH to produce two compounds of MED-2AMPY and MED-ANTH in the alkaline medium. The characterization of synthesized compounds utilizing UV-Visible and FT-IR spectra. FT-IR spectra of 2AMPY-MED confirm the existence of OH, C-Hor, C-Hal, NH, N=N, C=O, and C=C vibration at 3455, 3059, 2973, 3100, 1476,1692, and 1560 cm-1, and FT-IR spectra of ANTH-MED confirm the existence of OH, C-Hor, NH, C=O and N=N vibration at 3490, 3050, 3100, 1701 and 1462 cm-1, correspondingly. The obtained color of azo compounds is spectrophotometrically measured for the previously mentioned azo compounds at 450 and 455 nm, respectively. Under perfect conditions, the azo compound solutions exhibited molar absorptivities of 1563.0058 and 2091.0285 L.mol-1.cm-1, Sandell's sensitivity of 0.135 and 0.10 µg.cm-1, and Beer-Lambert's law are obeyed over the ranges 6.25- 62.5 mg. L-1 for the two developed procedures, respectively.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89031959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Biological Potential and Synthetic Diversity of 1,3,4-Oxadiazole Multiplexed with Various Heterocyclic Compounds 1,3,4-恶二唑与各种杂环化合物复合的生物学潜力和合成多样性
Pub Date : 2023-04-18 DOI: 10.18596/jotcsa.1202640
R. K, Deevan Paul Amarnath, Hariraj Narayanan, Adhya Das
Countless bioactive compounds are having the oxadiazole nucleus showing clinical and biological applications. Oxadiazole is a heterocyclic compound of the azole family that has gained increasing attention due to its wide therapeutic potential. Many significant synthetic medicinal compounds have the oxadiazole scaffold, which provided a good treatment idea and binds with high affinity to a variety of receptors to aid in the development of novel beneficial derivatives. Numerous researchers have worked to create novel oxadiazole compounds and evaluate them for how they affect inflammation, tumor, epilepsy, microbial infections, and analgesic properties. The present review article summarizes some of the oxadiazole derivatives synthesized and their biological activities and can be a useful guide for researchers working on this scaffold.
无数具有恶二唑核的生物活性化合物显示出临床和生物学上的应用。恶二唑是一种杂环化合物,由于其广泛的治疗潜力而受到越来越多的关注。许多重要的合成药物化合物都含有恶二唑支架,它提供了一个很好的治疗思路,并且与多种受体具有高亲和力结合,有助于开发新的有益衍生物。许多研究人员致力于创造新的恶二唑化合物,并评估它们如何影响炎症、肿瘤、癫痫、微生物感染和镇痛特性。本文综述了一些恶二唑类衍生物的合成及其生物活性,以期对该支架的研究有一定的指导意义。
{"title":"The Biological Potential and Synthetic Diversity of 1,3,4-Oxadiazole Multiplexed with Various Heterocyclic Compounds","authors":"R. K, Deevan Paul Amarnath, Hariraj Narayanan, Adhya Das","doi":"10.18596/jotcsa.1202640","DOIUrl":"https://doi.org/10.18596/jotcsa.1202640","url":null,"abstract":"Countless bioactive compounds are having the oxadiazole nucleus showing clinical and biological applications. Oxadiazole is a heterocyclic compound of the azole family that has gained increasing attention due to its wide therapeutic potential. Many significant synthetic medicinal compounds have the oxadiazole scaffold, which provided a good treatment idea and binds with high affinity to a variety of receptors to aid in the development of novel beneficial derivatives. Numerous researchers have worked to create novel oxadiazole compounds and evaluate them for how they affect inflammation, tumor, epilepsy, microbial infections, and analgesic properties. The present review article summarizes some of the oxadiazole derivatives synthesized and their biological activities and can be a useful guide for researchers working on this scaffold.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73700885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of extraction condition of Gynura procumbens extract enriched with flavonoid and antioxidant compounds using Response Surface Methodology 响应面法优化富含黄酮类化合物和抗氧化成分的原春草提取物的提取条件
Pub Date : 2023-04-18 DOI: 10.18596/jotcsa.1172970
Devi Permatasari, Anisyah IS PURWATİ, Hismiaty Bahua, A. Supriyono
Gynura procumbens is known as one of the herbal medicinal plants found in Indonesia and has been used from time to time. It is claimed to have various efficacy such as anti-hyperglycemic, anti-hypertension, anti-microbial, anti-cancer, and antioxidant. Other studies mention that G. procumbens possessed high antioxidant compounds and had been used as a natural-based medicinal supplement. However, further studies on optimizing the extraction process of Gynura procumbens in Indonesia have yet to be reported. Therefore, this study aimed to optimize the extraction condition of G. procumbens leaves by maceration with three variables: solvent concentration, extraction time, and the ratio of solid-liquid used. Each of those variables contained three different levels. Determination of total flavonoid and antioxidant activity was measured using aluminium chloride colourimetric assay and 2, 2-diphenyl-1-picryl-hydrazil (DPPH) assay, respectively. In the optimization process, Response Surface Methodology (RSM) was used to explore the main effects and interaction between parameters and their correlations with dependent variables. The results were analyzed using the Box-Behnken method using Minitab software 17. This study shows that the most significant effect of the variable for both flavonoid and antioxidant activity was solvent concentration, with a P<0.05. The results showed that the extraction process to obtain G. procumbens extract with optimal flavonoid content and antioxidant activity (IC50) was predicted at 70% solvent concentration, 1 h maceration time, and a solid-liquid ratio of 1:9.8 w/v, with results of 17.599 mg QE/g extract and 0.211 mg/mL, respectively. This study was expected to complement other studies and can be used as an additional reference for the development of the extraction process on a larger scale.
Gynura procumbens被称为印度尼西亚发现的草药植物之一,经常被使用。据称,它具有降糖、降压、抗菌、抗癌、抗氧化等多种功效。其他研究提到,原藜草含有高抗氧化化合物,已被用作天然药物补充剂。然而,对印尼产原甘露提取工艺的优化研究尚未见报道。因此,本研究拟通过溶剂浓度、提取时间、料液比3个变量优化浸渍法提取杜仲叶的工艺条件。每一个变量都包含三个不同的层次。分别用氯化铝比色法和2,2 -二苯基-1-苦酰肼(DPPH)法测定其总黄酮和抗氧化活性。在优化过程中,采用响应面法(Response Surface Methodology, RSM)探讨了各参数之间的主效应、交互作用及其与因变量的相关性。使用Minitab软件17对结果进行Box-Behnken法分析。本研究表明,溶剂浓度对黄酮类化合物和抗氧化活性的影响最为显著,P<0.05。结果表明,在溶剂浓度为70%、浸渍时间为1 h、料液比为1:8 .8 w/v的条件下,原藜提取物的总黄酮含量为17.599 mg QE/g,抗氧化活性(IC50)为0.211 mg/mL。本研究有望对其他研究起到补充作用,并可作为开发更大规模提取工艺的额外参考。
{"title":"Optimization of extraction condition of Gynura procumbens extract enriched with flavonoid and antioxidant compounds using Response Surface Methodology","authors":"Devi Permatasari, Anisyah IS PURWATİ, Hismiaty Bahua, A. Supriyono","doi":"10.18596/jotcsa.1172970","DOIUrl":"https://doi.org/10.18596/jotcsa.1172970","url":null,"abstract":"Gynura procumbens is known as one of the herbal medicinal plants found in Indonesia and has been used from time to time. It is claimed to have various efficacy such as anti-hyperglycemic, anti-hypertension, anti-microbial, anti-cancer, and antioxidant. Other studies mention that G. procumbens possessed high antioxidant compounds and had been used as a natural-based medicinal supplement. However, further studies on optimizing the extraction process of Gynura procumbens in Indonesia have yet to be reported. Therefore, this study aimed to optimize the extraction condition of G. procumbens leaves by maceration with three variables: solvent concentration, extraction time, and the ratio of solid-liquid used. Each of those variables contained three different levels. Determination of total flavonoid and antioxidant activity was measured using aluminium chloride colourimetric assay and 2, 2-diphenyl-1-picryl-hydrazil (DPPH) assay, respectively. In the optimization process, Response Surface Methodology (RSM) was used to explore the main effects and interaction between parameters and their correlations with dependent variables. The results were analyzed using the Box-Behnken method using Minitab software 17. This study shows that the most significant effect of the variable for both flavonoid and antioxidant activity was solvent concentration, with a P<0.05. The results showed that the extraction process to obtain G. procumbens extract with optimal flavonoid content and antioxidant activity (IC50) was predicted at 70% solvent concentration, 1 h maceration time, and a solid-liquid ratio of 1:9.8 w/v, with results of 17.599 mg QE/g extract and 0.211 mg/mL, respectively. This study was expected to complement other studies and can be used as an additional reference for the development of the extraction process on a larger scale.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74623218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correlation between chemical characteristics and optical spectra of Spirulina commercially available on the Bulgarian market 保加利亚市场上可买到的螺旋藻的化学特性和光谱之间的相关性
Pub Date : 2023-04-17 DOI: 10.18596/jotcsa.1207682
K. Nikolova, T. Eftimov, Aleksandar Pashev, M. Karadjov, Christina Tzvetkova, G. Gentscheva, D. Brabant, Fouzar Samia
The aggregate of various chemical substances useful for the functioning of the human body are known as nutrients. Spirulina has been present in human nutrition since ancient times, but in recent years the interest in it has been particularly increased due to the emergence of numerous alternative methods of nutrition. This study aimed to compare the functional and elemental composition as well as the optical properties of commercial Spirulina products available on the Bulgarian market. For this purpose, fluorescence spectroscopy in the ultraviolet and visible range, fourier transform infrared spectroscopy and inductively coupled plasma optical emission spectroscopy were used. The basic components of the analyzed Spirulina samples are proteins (1657 and 1537 cm-1) and carbohydrates (1069 and 1054 cm-1) and no meaningful differences between the IR spectra of the samples. Concentrations of important microelements Mg, Fe, Cu, Zn, and Mn varies with the manufacturer. The highest levels for Mg (6.69 g kg-1) were measured in samples from USA, while the Spirulina fabricated in Bulgaria exhibits the highest contents of Zn (242 mg kg-1) and Cu (25.4 mg kg-1). All samples followed the tendency Mg>Fe>Mn>Zn>Cu. Making use of a fiber optic spectrometer the fluorescence spectra of the studied samples of Spirulina platensis for an excitation wavelength of 380 nm were measured. In these spectra we observe three fluorescence maxima: at 465 nm – nicotinamide dinucleotide phosphate, 640 nm chlorophyll a, and 736 nm due to similar to chlorophyll pigments. A strong positive correlation between the contents of Zn and Cu on the one side and the second fluorescence peak (λ=640 nm) for excitation wavelength at 380 nm. In contrast, a high negative correlation for Fe and the third fluorescence maximum (λ= 736nm) is observed for all excitation wavelengths. The correlation dependencies were obtained with the least squares method with a significance level of p ≤ 0.05.
对人体功能有用的各种化学物质的集合被称为营养物质。螺旋藻自古以来就存在于人类营养中,但近年来,由于许多替代营养方法的出现,对螺旋藻的兴趣尤其增加。本研究的目的是比较功能和元素组成,以及在保加利亚市场上提供的商业螺旋藻产品的光学性质。为此,使用了紫外和可见光范围内的荧光光谱、傅里叶变换红外光谱和电感耦合等离子体发射光谱。所分析的螺旋藻样品的基本成分为蛋白质(1657和1537 cm-1)和碳水化合物(1069和1054 cm-1),样品的红外光谱之间无显著差异。重要微量元素Mg、Fe、Cu、Zn和Mn的浓度因制造商而异。来自美国的螺旋藻样品中Mg含量最高(6.69 g kg-1),而保加利亚制造的螺旋藻样品中Zn含量最高(242 Mg kg-1), Cu含量最高(25.4 Mg kg-1)。Mg>Fe>Mn>Zn>Cu。利用光纤光谱仪测量了所研究的螺旋藻样品在激发波长为380 nm处的荧光光谱。在这些光谱中,我们观察到三个荧光最大值:在465 nm -烟酰胺二核苷酸磷酸,640 nm叶绿素a和736 nm由于类似于叶绿素色素。在激发波长为380 nm时,一侧的Zn和Cu含量与第二个荧光峰(λ=640 nm)呈正相关。相反,在所有激发波长下,铁与第三个荧光最大值(λ= 736nm)呈高度负相关。相关依赖关系采用最小二乘法计算,显著性水平p≤0.05。
{"title":"Correlation between chemical characteristics and optical spectra of Spirulina commercially available on the Bulgarian market","authors":"K. Nikolova, T. Eftimov, Aleksandar Pashev, M. Karadjov, Christina Tzvetkova, G. Gentscheva, D. Brabant, Fouzar Samia","doi":"10.18596/jotcsa.1207682","DOIUrl":"https://doi.org/10.18596/jotcsa.1207682","url":null,"abstract":"The aggregate of various chemical substances useful for the functioning of the human body are known as nutrients. Spirulina has been present in human nutrition since ancient times, but in recent years the interest in it has been particularly increased due to the emergence of numerous alternative methods of nutrition. This study aimed to compare the functional and elemental composition as well as the optical properties of commercial Spirulina products available on the Bulgarian market. For this purpose, fluorescence spectroscopy in the ultraviolet and visible range, fourier transform infrared spectroscopy and inductively coupled plasma optical emission spectroscopy were used. The basic components of the analyzed Spirulina samples are proteins (1657 and 1537 cm-1) and carbohydrates (1069 and 1054 cm-1) and no meaningful differences between the IR spectra of the samples. Concentrations of important microelements Mg, Fe, Cu, Zn, and Mn varies with the manufacturer. The highest levels for Mg (6.69 g kg-1) were measured in samples from USA, while the Spirulina fabricated in Bulgaria exhibits the highest contents of Zn (242 mg kg-1) and Cu (25.4 mg kg-1). All samples followed the tendency Mg>Fe>Mn>Zn>Cu. Making use of a fiber optic spectrometer the fluorescence spectra of the studied samples of Spirulina platensis for an excitation wavelength of 380 nm were measured. In these spectra we observe three fluorescence maxima: at 465 nm – nicotinamide dinucleotide phosphate, 640 nm chlorophyll a, and 736 nm due to similar to chlorophyll pigments. A strong positive correlation between the contents of Zn and Cu on the one side and the second fluorescence peak (λ=640 nm) for excitation wavelength at 380 nm. In contrast, a high negative correlation for Fe and the third fluorescence maximum (λ= 736nm) is observed for all excitation wavelengths. The correlation dependencies were obtained with the least squares method with a significance level of p ≤ 0.05.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84998365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the Structural, Near-Infrared Luminescence, and Radioluminescence Properties of Nd3+ Activated TTB-Lead Metatantalate Phosphors Nd3+活化ttb -铅偏钽酸盐荧光粉的结构、近红外发光和辐射发光性能评价
Pub Date : 2023-04-15 DOI: 10.18596/jotcsa.1216564
M. İlhan, İ. Keskin
The study reports the structural and spectroscopic properties of Nd3+ doped lead metatantalate phosphor series fabricated by conventional solid state method. XRD results of the PbTa2O6 phase confirm the tungsten bronze symmetry and single-phase structure between 0.5 and 10 mol% Nd3+ concentrations. The lead decrease in the structure can be associated with maintaining the charge balance and single phase due to evaporation during sintering. In SEM micrographs, the grains exhibited shapeless morphology, and the grain sizes varied from 0.5 to 7 m. In EDS results, the increase of Ta/Pb ratio in grain surfaces indicated some lead evaporation, as reported in previous studies. The absorption spectrum of PbTa2O6 host peaked around 275-280 nm, and the band gap was found to be 3.7±0.2 eV. The absorptions of Nd3+ doped phophors shifted the high wavelenght or the low band gap, where the band gaps were found between 3.1±0.2 and 3.3±0.2 eV. The PL emissions of the phosphors in near-inrared region were observed with the transitions of 4F3/2→4I9/2 (at 875 nm) and 4F3/2→4I11/2 (at 1060 nm) of Nd3+. The RL emissions or X-ray excited luminescence were monitored with the transitions of 4F3/2→4I9/2 (at 875 nm), 4F3/2→4I11/2 (at 1065 nm) in the infrared region, and the transitions of 2F(2)5/2→4F9/2, 2F(2)5/2→2H(2)11/2, 2F(2)5/2→4G5/2, 2F(2)5/2→4G7/2, 2F(2)5/2→4G9/2 in the visible region corresponding to at around 430, 455, 490, 525, and 570 nm, respectively. PL and RL emissions of the phosphors exhibited the decreasing emission intensity over 5 mol% due to the concentration quenching which may be associated with cross-relaxing mechanism. In the PL and RL spectral profiles, the similarity of splitting levels was attributed to the similarity of the local symmetry of the ligand ions surrounding the Nd3+ ion. The CIE coordinates obtained using RL emissions were found close to the blue region due to visible region transitions.
研究了传统固相法制备的Nd3+掺杂偏钽酸铅系列荧光粉的结构和光谱性质。PbTa2O6相的XRD结果证实了在0.5 ~ 10 mol% Nd3+浓度范围内具有钨青铜对称和单相结构。结构中铅的减少可能与烧结过程中由于蒸发而保持电荷平衡和单相有关。SEM显微图显示晶粒形态不规则,晶粒尺寸为0.5 ~ 7m。在EDS结果中,晶粒表面Ta/Pb比值的增加表明铅有一定的蒸发,这与之前的研究一致。PbTa2O6主体的吸收光谱峰值在275 ~ 280 nm处,带隙为3.7±0.2 eV。掺Nd3+的荧光团的吸收向高波长或低带隙偏移,带隙在3.1±0.2 ~ 3.3±0.2 eV之间。荧光体在近红外区域的发光表现为Nd3+的4F3/2→4I9/2 (875 nm)和4F3/2→4I11/2 (1060 nm)跃迁。红外区4F3/2→4I9/2 (875 nm), 4F3/2→4I11/2 (1065 nm),可见光区2F(2)5/2→4F9/2, 2F(2)5/2→4G5/2, 2F(2)5/2→4G5/2, 2F(2)5/2→4G7/2, 2F(2)5/2→4G5/2, 2F(2)5/2→4G7/2, 2F(2)5/2→4G7/2, 2F(2)5/2→4G9/2,分别对应于430,4555,490,525,570 nm。在5 mol%以上,荧光体的发光强度随浓度猝灭而降低,这可能与交叉弛豫机制有关。在PL和RL光谱剖面中,分裂能级的相似性归因于Nd3+离子周围配体离子的局部对称性的相似性。由于可见区域的过渡,使用RL发射获得的CIE坐标接近蓝色区域。
{"title":"Evaluation of the Structural, Near-Infrared Luminescence, and Radioluminescence Properties of Nd3+ Activated TTB-Lead Metatantalate Phosphors","authors":"M. İlhan, İ. Keskin","doi":"10.18596/jotcsa.1216564","DOIUrl":"https://doi.org/10.18596/jotcsa.1216564","url":null,"abstract":"The study reports the structural and spectroscopic properties of Nd3+ doped lead metatantalate phosphor series fabricated by conventional solid state method. XRD results of the PbTa2O6 phase confirm the tungsten bronze symmetry and single-phase structure between 0.5 and 10 mol% Nd3+ concentrations. The lead decrease in the structure can be associated with maintaining the charge balance and single phase due to evaporation during sintering. In SEM micrographs, the grains exhibited shapeless morphology, and the grain sizes varied from 0.5 to 7 m. In EDS results, the increase of Ta/Pb ratio in grain surfaces indicated some lead evaporation, as reported in previous studies. The absorption spectrum of PbTa2O6 host peaked around 275-280 nm, and the band gap was found to be 3.7±0.2 eV. The absorptions of Nd3+ doped phophors shifted the high wavelenght or the low band gap, where the band gaps were found between 3.1±0.2 and 3.3±0.2 eV. The PL emissions of the phosphors in near-inrared region were observed with the transitions of 4F3/2→4I9/2 (at 875 nm) and 4F3/2→4I11/2 (at 1060 nm) of Nd3+. The RL emissions or X-ray excited luminescence were monitored with the transitions of 4F3/2→4I9/2 (at 875 nm), 4F3/2→4I11/2 (at 1065 nm) in the infrared region, and the transitions of 2F(2)5/2→4F9/2, 2F(2)5/2→2H(2)11/2, 2F(2)5/2→4G5/2, 2F(2)5/2→4G7/2, 2F(2)5/2→4G9/2 in the visible region corresponding to at around 430, 455, 490, 525, and 570 nm, respectively. PL and RL emissions of the phosphors exhibited the decreasing emission intensity over 5 mol% due to the concentration quenching which may be associated with cross-relaxing mechanism. In the PL and RL spectral profiles, the similarity of splitting levels was attributed to the similarity of the local symmetry of the ligand ions surrounding the Nd3+ ion. The CIE coordinates obtained using RL emissions were found close to the blue region due to visible region transitions.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"57 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77877907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2) 新型anderson型多金属氧酸盐的合成与表征:[M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu)x = 1, 2)
Pub Date : 2023-04-14 DOI: 10.18596/jotcsa.1215066
Hülya Avcı Özbek
Five new Anderson-type polyoxometalate compounds [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3), Ni(4), Cu(5); x=1,2) were obtained from Na2MoO4∙2H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-.
五种新型anderson型多金属氧酸化合物[M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3), Ni(4), Cu(5));x=1,2)分别由Na2MoO4∙2H2O和CrCl3∙6H2O在酸性水介质(pH=2-3)中得到。通过FT-IR、TGA、ICP-MS和元素分析等手段对化合物进行了表征。结构分析表明化合物(1 ~ 5)由anderson型聚阴离子[Cr(OH)6Mo6O18]3-组成。
{"title":"Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]·16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)","authors":"Hülya Avcı Özbek","doi":"10.18596/jotcsa.1215066","DOIUrl":"https://doi.org/10.18596/jotcsa.1215066","url":null,"abstract":"Five new Anderson-type polyoxometalate compounds [M((1,10-phen)(OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3), Ni(4), Cu(5); x=1,2) were obtained from Na2MoO4∙2H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"61 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72568196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Antibacterial and Antioxidant Activity Evaluation of Bis-Substituted İsovanillin Derivatives 双取代İsovanillin衍生物的抗菌和抗氧化活性评价
Pub Date : 2023-04-07 DOI: 10.18596/jotcsa.1196335
Zehra Tekin, Yener Tekeli̇, Zehra Küçükbay, Nebih Lolak, G. Yapar, Suleyman Akocak
Herein, a series of twelve bis-hydrazone substituted isovanilline derivatives 3(a-l), were freshly re-synthesized by the reaction of bis-aldehydes with substituted hydrazide derivatives since these compounds previously showed potent aldose reductase inhibition properties. The obtained compounds were tested for their potential antibacterial and antioxidant activities. In the present study, four different bacterial strains were used, including Gram-positive (Staphylococcus aureus ATCC 29213, Enterococcus faecalis ATCC 29212) and Gram-negative (Pseudomonas aeruginosa ATCC 10231, Escherichia coli ATCC 25912). On the other hand, the antioxidant capacities of freshly re-synthesized bis-hydrazone substituted isovanilline derivatives were determined by using several antioxidant methods, including DPPH free radical scanvenging, TEAC cupric reducing (CUPRAC) and metal chelating activity methods. Several lead molecules were discovered as a potential bacterial inhibitors against S. aureus and E. coli bacterial strains. More specifically, compounds 3g (R=-H) and 3j (R= -4Cl) showed great inhibition properties against E. coli bacterial strains by having MIC values of 1.56 and 6.25 µg/mL, respectively. Moreover, none of the compounds showed potent antioxidant activity against tested methods with respect to compared standards.
本文利用双醛类化合物与取代的肼类化合物的反应,重新合成了一系列12个双腙取代异香草碱衍生物3(a- 1),因为这些化合物先前表现出了强效的醛糖还原酶抑制作用。对所得化合物进行了潜在的抗菌和抗氧化活性测试。本研究采用革兰氏阳性菌株(金黄色葡萄球菌ATCC 29213、粪肠球菌ATCC 29212)和革兰氏阴性菌株(铜绿假单胞菌ATCC 10231、大肠杆菌ATCC 25912)。另一方面,采用DPPH自由基清除法、TEAC铜还原法和金属螯合活性法测定了新合成的双腙取代异香草碱衍生物的抗氧化能力。一些铅分子被发现是对金黄色葡萄球菌和大肠杆菌菌株的潜在细菌抑制剂。更具体地说,化合物3g (R=-H)和3j (R= -4Cl)对大肠杆菌菌株具有良好的抑制作用,其MIC值分别为1.56和6.25µg/mL。此外,与比较标准相比,没有一种化合物对测试方法显示出有效的抗氧化活性。
{"title":"Antibacterial and Antioxidant Activity Evaluation of Bis-Substituted İsovanillin Derivatives","authors":"Zehra Tekin, Yener Tekeli̇, Zehra Küçükbay, Nebih Lolak, G. Yapar, Suleyman Akocak","doi":"10.18596/jotcsa.1196335","DOIUrl":"https://doi.org/10.18596/jotcsa.1196335","url":null,"abstract":"Herein, a series of twelve bis-hydrazone substituted isovanilline derivatives 3(a-l), were freshly re-synthesized by the reaction of bis-aldehydes with substituted hydrazide derivatives since these compounds previously showed potent aldose reductase inhibition properties. The obtained compounds were tested for their potential antibacterial and antioxidant activities. In the present study, four different bacterial strains were used, including Gram-positive (Staphylococcus aureus ATCC 29213, Enterococcus faecalis ATCC 29212) and Gram-negative (Pseudomonas aeruginosa ATCC 10231, Escherichia coli ATCC 25912). On the other hand, the antioxidant capacities of freshly re-synthesized bis-hydrazone substituted isovanilline derivatives were determined by using several antioxidant methods, including DPPH free radical scanvenging, TEAC cupric reducing (CUPRAC) and metal chelating activity methods. Several lead molecules were discovered as a potential bacterial inhibitors against S. aureus and E. coli bacterial strains. More specifically, compounds 3g (R=-H) and 3j (R= -4Cl) showed great inhibition properties against E. coli bacterial strains by having MIC values of 1.56 and 6.25 µg/mL, respectively. Moreover, none of the compounds showed potent antioxidant activity against tested methods with respect to compared standards.","PeriodicalId":17299,"journal":{"name":"Journal of the Turkish Chemical Society Section A: Chemistry","volume":"43 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77358779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of the Turkish Chemical Society Section A: Chemistry
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1