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The crevice corrosion behavior of N80 carbon steel in acidic NaCl solution: The effect of O2 N80碳钢在酸性NaCl溶液中的缝隙腐蚀行为:O2的影响
Pub Date : 2021-10-19 DOI: 10.1002/maco.202112595
Yizhou Li, Jie Mu, Zhongyu Cui, Xin Wang
The effect of O2 on crevice corrosion of N80 carbon steel in acidic NaCl solution is investigated. Crevice corrosion of N80 carbon steel could be initiated with or without O2 in acidic NaCl solution. A deep corrosion groove could be formed near the crevice mouth after crevice corrosion. The crevice corrosion of N80 carbon steel is ascribed to the increased pH inside the crevice in acidic NaCl solution. The presence of O2 in the solution could enhance the cathodic reaction processes outside the crevice, but it is not significant for the cathodic reaction processes inside the crevice. The galvanic corrosion effect between inner and outer steels could be enhanced by O2 and then promote crevice corrosion.
研究了氧对N80碳钢在酸性NaCl溶液中缝隙腐蚀的影响。在酸性NaCl溶液中,有氧或无氧均可引起N80碳钢的缝隙腐蚀。裂缝腐蚀后,在裂缝口附近可形成较深的腐蚀槽。N80碳钢的缝隙腐蚀主要是由于在酸性NaCl溶液中,缝隙内pH值升高所致。溶液中O2的存在对缝隙外的阴极反应过程有促进作用,但对缝隙内的阴极反应过程没有促进作用。O2可增强内外钢之间的电偶腐蚀作用,进而促进缝隙腐蚀。
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引用次数: 3
Electrochemical noise studies on complex galvanic corrosion of submarine cable armor layer in artificial seawater 海底电缆护层在人工海水中复杂电蚀的电化学噪声研究
Pub Date : 2021-10-19 DOI: 10.1002/maco.202112803
Rui Guo, Pengyvan Yang, F. Mao, Jinlong Li, Lei Chen, Guojun Yu, D. Macdonald
This paper aims at studying the complex galvanic corrosion of galvanized steel/red copper of submarine cable armor layer in simulated seawater environments. The variation of the galvanic corrosion rate of the cable armor layer as a function of time under different environmental factors (pH, [Cl−], dissolved oxygen, etc.) has been explored. The surface morphology of the galvanized steel after galvanic corrosion was observed by scanning electron microscopy. The results indicate that galvanized steel and red copper are susceptible to galvanic corrosion when ohmically coupled in NaCl solution. Red copper, with the more positive electromotive potential, acts as the cathode in the galvanized steel/red copper galvanic couple and accelerates the corrosion of the galvanized steel. The galvanic effect of red copper on galvanized steel in NaCl solution increases with the increasing [H+] and dissolved oxygen. However, with increasing [Cl−], the galvanic effect of red copper on galvanized steel initially increases but then decreases, resulting in a maximum in the corrosion rate.
本文旨在研究模拟海水环境下镀锌钢/紫铜海底电缆护层的复杂电偶腐蚀问题。探讨了不同环境因素(pH、[Cl−]、溶解氧等)下电缆铠装层电腐蚀速率随时间的变化规律。用扫描电镜观察了镀锌钢经电偶腐蚀后的表面形貌。结果表明:镀锌钢与红铜在NaCl溶液中欧姆耦合时易发生电偶腐蚀;红铜电动势更正,在镀锌钢/红铜电偶中充当阴极,加速镀锌钢的腐蚀。在NaCl溶液中,红铜对镀锌钢的电偶效应随着[H+]和溶解氧的增加而增强。随着[Cl−]的增加,红铜对镀锌钢的电偶效应先增大后减小,腐蚀速率达到最大值。
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引用次数: 4
Assessing bioorganic gum performance as a corrosion inhibitor in phosphoric acid medium: Electrochemical and computational analysis 评估生物有机胶在磷酸介质中作为缓蚀剂的性能:电化学和计算分析
Pub Date : 2021-10-18 DOI: 10.1002/maco.202112742
Sathiyapriya T., M. Dhayalan, Jagadeeswari R., Rathika Govindasamy, Mohammed Riyaz S. U., Moonis Ali Khan, M. Sillanpää
The present investigation was aimed at exploring the anticorrosive behavior of bio‐organic Auraucaria heterophylla gum exudate (AHGE) on mild steel (MS) corrosion in 1 M phosphoric acid solution by weight loss technique, electrochemical studies, and computational analysis. Additionally, the performance was analyzed by morphological and quantum chemical analyses. The weight loss data revealed that AHGE showed 80% of inhibition efficiency at 303 K temperature. Inhibitor adsorption on MS was in line with Langmuir and Tempkin adsorption isotherms. Potentiodynamic studies showed that the investigated AHGE performed as a mixed‐type inhibitor. Electrochemical parameters like charge transfer resistance, double‐layer capacitance, and inhibition efficiency were determined and presented. Results obtained through computational analysis, scanning electron microscopy/energy dispersive X‐ray analysis, and atomic force microscopy studies were well supported by the inhibitive potential of AHGE.
采用失重法、电化学研究和计算分析等方法,研究了生物有机异叶金auraucaria heterophylla gum渗出液(AHGE)在1m磷酸溶液中对低碳钢(MS)的腐蚀行为。此外,通过形态学和量子化学分析对其性能进行了分析。失重数据显示,在303 K温度下,AHGE的缓蚀率为80%。抑制剂在质谱上的吸附符合Langmuir和Tempkin等温线。电位动力学研究表明,所研究的AHGE表现为混合型抑制剂。测定并给出了电荷转移电阻、双层电容和抑制效率等电化学参数。通过计算分析、扫描电镜/能量色散X射线分析和原子力显微镜研究得到的结果得到了AHGE抑制潜力的很好支持。
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引用次数: 0
Roles of the micro‐arc oxidation coating on the corrosion resistance and mechanical properties of extruded Mg–2Zn–0.5Zr–1.5Dy (mass%) alloy 微弧氧化涂层对挤压Mg-2Zn-0.5Zr-1.5Dy(质量%)合金耐腐蚀性能和力学性能的影响
Pub Date : 2021-10-18 DOI: 10.1002/maco.202112762
Huan Li, J. Wen, Jie Jin, Ya Liu, Jun-guang He
Aiming to enhance the biodegradable magnesium alloys' poor mechanical properties and corrosion resistance in aggressive chloride mediums, micro‐arc oxidation coatings with oxidation times range from 3 to 15 min were prepared on the surface of extruded Mg–2Zn–0.5Zr–1.5Dy (mass%) alloy. Assessments were carried out using electrochemical experiments, hydrogen evolution experiments, and tensile tests, respectively. The results show that the micro‐arc oxidation coating is porous and mainly consists of the MgO phase. When the oxidation time increases from 3 to 15 min, the thickness and the pore size of the coating increase, while the coating's porosity decreases. The coating with the oxidation time of 15 min can effectively prevent the formation of pitting holes on the surface of the alloy, which remarkably reduces the decay rate of ultimate tensile strength, yield strength, and elongation of the alloy after immersion in simulated body fluid for 0–28 days, and keep the alloy with higher and more stable corrosion resistance. This increases the application possibility of extruded Mg–2Zn–0.5Zr–1.5Dy alloy as a biodegradable material.
为了改善可生物降解镁合金在腐蚀性氯离子介质中较差的力学性能和耐腐蚀性,在挤压成型的Mg-2Zn-0.5Zr-1.5Dy(质量%)合金表面制备了氧化时间为3 ~ 15 min的微弧氧化涂层。分别通过电化学实验、析氢实验和拉伸试验进行了评估。结果表明:微弧氧化膜具有多孔性,主要由MgO相组成;当氧化时间从3 min增加到15 min时,涂层的厚度和孔径增大,而涂层的孔隙率减小。氧化时间为15 min的涂层可有效防止合金表面形成点孔,显著降低合金在模拟体液中浸泡0 ~ 28天后的极限抗拉强度、屈服强度和伸长率的衰减率,使合金具有更高、更稳定的耐腐蚀性。这增加了挤压Mg-2Zn-0.5Zr-1.5Dy合金作为生物降解材料的应用可能性。
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引用次数: 4
Distribution of sulfate‐reducing bacteria in the crevice and its effect on the initial corrosion behavior of 2205 stainless steel in artificial seawater 2205不锈钢在人工海水中裂缝中硫酸盐还原菌的分布及其对初始腐蚀行为的影响
Pub Date : 2021-10-15 DOI: 10.1002/maco.202112759
Zhan Zhang, T. Fang, Jiuyang Xia, Bowei Zhang, Junsheng Wu
In the present study, the distribution and vitality of the sulfate‐reducing bacteria (SRB) inside the crevice were characterized by scanning electron microscopy and confocal laser scanning microscopy. Potentiodynamic polarization curve tests and electrochemical impedance spectroscopy were used to evaluate the corrosion resistance. Furthermore, a starvation experiment was conducted by controlling nutrients to investigate the effects of the crevices on the transportation of nutrients and the vitality of the SRB. The results demonstrate that it was more difficult for the SRB to enter the crevice, resulting in an incomplete biofilm formed on the surface. In addition, the insufficient supply of nutrients was also the reason for the low vitality of the SRB inside the crevice. Based on these results, it was inferred that the incomplete biofilm inside the crevice acted as a micro‐galvanic, thus making the corrosion rate of 2205 stainless steel in the initial crevice corrosion much more serious than that in the open system.
本文采用扫描电镜和激光共聚焦扫描显微镜对裂缝内硫酸盐还原菌(SRB)的分布和活力进行了研究。采用动电位极化曲线试验和电化学阻抗谱法对其耐蚀性进行了评价。此外,通过控制营养物质的饥饿试验,研究了裂缝对SRB营养物质运输和活力的影响。结果表明,SRB更难进入缝隙,导致表面形成不完整的生物膜。此外,营养物质供给不足也是裂缝内SRB活力低的原因。由此可以推断,裂缝内不完整的生物膜作为微电源,使得2205不锈钢在裂缝初始腐蚀中的腐蚀速率比在开放体系中的腐蚀速率要严重得多。
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引用次数: 3
Synthesis and characterisation of an iron‐ion‐responsive coating with core–shell electrospun fibres containing a chelation agent 含螯合剂的核-壳电纺纤维铁离子响应涂层的合成与表征
Pub Date : 2021-10-14 DOI: 10.1002/maco.202112459
Liying Song, Hao Shi, Peng Han, X. Ji, Q. Cheng
A self‐healing coating containing an electrospun nanofibre encapsulating 3,4,5‐trihydroxy benzoic acid cyclohexyl ester (GACE) was prepared. Scanning electron microscopy and transmission electron microscopy demonstrated that the nanofibre had a core–shell structure. The shell thickness of the electrospun fibre was approximately 270 nm, while the core thickness was approximately 380 nm. The self‐healing process of the coating containing GACE nanofibres over a carbon steel surface was simulated in a 3.5 wt% NaCl solution for 30 days. Fourier‐transform infrared spectroscopy analysis revealed that the synthesised GACE reacted with iron ions and formed a stable Fe–O–C compound, which could repair the scratched coating. The self‐repair performance was evaluated through electrochemical measurements, and then a healing model was developed.
制备了一种包覆3,4,5 -三羟基苯甲酸环己基酯(GACE)的电纺丝纳米纤维自愈涂层。扫描电镜和透射电镜分析表明,该纳米纤维具有核-壳结构。电纺丝纤维的壳厚约为270 nm,芯厚约为380 nm。在3.5 wt% NaCl溶液中模拟了含GACE纳米纤维涂层在碳钢表面的自愈过程。傅里叶变换红外光谱分析表明,合成的GACE与铁离子反应形成稳定的Fe-O-C化合物,可以修复划伤的涂层。通过电化学测量评价了材料的自修复性能,并建立了修复模型。
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引用次数: 1
Effect of aging temperature on corrosion resistance and antibacterial ability of 0Cu2Cr carbon steel 时效温度对0Cu2Cr碳钢耐蚀性和抗菌性能的影响
Pub Date : 2021-10-13 DOI: 10.1002/maco.202112796
Jing Guo, K. Fu, Y. Teng, Jia-ji Wang, Q. Pang, Fengya Hu, Hongyu Liu
The effect of heat treatment on the corrosion resistance and antibacterial ability of 0Cu2Cr carbon steel was studied using scanning electron microscopy, transmission electron microscopy, laser scanning confocal microscopy, and electrochemistry. The results showed that the peak aging state with complete crystal growth and uniform precipitate phase distribution was attained at the aging temperature of 850°C. Both the Cu‐rich phase with an approximately spherical structure and the dispersive Cu‐ordered phase with a B2 structure were observed in the grain boundary and internal crystal and effectively improved the hardness of the steel because of precipitation strengthening. Thus, the corrosion resistance and antibacterial ability of the 0Cu2Cr carbon steel could be improved by aging it at 850°C.
采用扫描电镜、透射电镜、激光扫描共聚焦显微镜和电化学等方法研究了热处理对0Cu2Cr碳钢耐腐蚀性能和抗菌性能的影响。结果表明:在850℃时效时,合金达到了晶体生长完整、析出相分布均匀的峰值时效状态;在晶界和内部晶中发现了具有近似球形结构的富Cu相和具有B2结构的分散Cu有序相,由于析出强化而有效地提高了钢的硬度。因此,通过850℃时效处理可以提高0Cu2Cr碳钢的耐蚀性和抗菌性能。
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引用次数: 0
Influence of reversed austenite on the properties of a 13Cr4NiMo ultra‐low carbon martensitic stainless steel in different environments 不同环境下反奥氏体对13Cr4NiMo超低碳马氏体不锈钢性能的影响
Pub Date : 2021-10-12 DOI: 10.1002/maco.202112775
Shenghua Zhang, Yanning Huang, Yanli Wang
In this study, the influence of reversed austenite on the mechanical and corrosion resistance properties of 13Cr4NiMo martensitic stainless steel was investigated. The results reveal that the reversed austenite content in the sample increases with the increase of tempering times. The presence of an appropriate amount of reversed austenite not only improves the comprehensive mechanical properties of martensitic stainless steel but also reduces the susceptibility to pitting corrosion.
研究了反奥氏体对13Cr4NiMo马氏体不锈钢力学性能和耐腐蚀性能的影响。结果表明,随着回火次数的增加,试样中的反奥氏体含量增加。适量的反奥氏体的存在不仅提高了马氏体不锈钢的综合力学性能,而且降低了其对点蚀的敏感性。
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引用次数: 1
Effect of pulse cathodic protection on corrosion mitigation and electrochemical conditions under a simulated coating disbondment on pipeline steel 脉冲阴极保护对管道钢模拟涂层剥离的缓蚀和电化学条件的影响
Pub Date : 2021-09-16 DOI: 10.1002/maco.202112490
Hossein Najafi, A. Eslami, M. Golozar, A. Kavian, Mehdi Ahmadi
Coating disbondments on pipeline steels are regions with high resistivity where conventional cathodic protection (CP) could not fully protect. Therefore, in an attempt to mitigate this challenge, this study investigates the effect of pulse CP on corrosion mitigation and electrochemical conditions under a simulated coating disbondment on X‐52 pipeline steel. In this regard, conventional and pulse CP of −870 mVSCE were applied to the open mouth of a simulated coating disbondment. For pulse CP, frequencies of 1, 5, and 10 kHz were used. Results showed while the conventional CP was not able to fully protect the 20 cm simulated coating disbondment, for the pulse CP with increase in frequency from 1 to 5 kHz, and from 5 to 10 kHz, improve in CP potential protection under the simulated coating disbondment was achieved. This was accompanied by considerably lower corrosion and a more uniform pH distribution under the simulated coating disbondment.
管线钢的涂层脱落是常规阴极保护不能完全保护的高电阻率区域。因此,为了缓解这一挑战,本研究研究了脉冲CP对X‐52管道钢在模拟涂层剥离下的缓蚀和电化学条件的影响。在这方面,常规和脉冲CP - 870 mVSCE分别应用于模拟涂层剥离的开口。对于脉冲CP,使用频率为1、5和10 kHz。结果表明,常规CP不能完全保护20 cm模拟涂层剥离,而频率从1 ~ 5 kHz和5 ~ 10 kHz增加的脉冲CP在模拟涂层剥离下的CP电位保护得到了改善。在模拟的涂层剥离下,腐蚀程度明显降低,pH分布更均匀。
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引用次数: 4
A comparison of methods for corrosion inhibitor assessment: Mild steel protected by disubstituted aromatics 缓蚀剂评价方法的比较:用双取代芳烃保护低碳钢
Pub Date : 2021-09-15 DOI: 10.1002/maco.202112551
Jessica Roscher, Dan Liu, R. Holze
Both thermodynamic and kinetic corrosion process parameters are determined with electrochemical methods. Results are used for a deeper understanding of the established interfacial structures and ongoing processes and of the effects of experimental parameters. Frequently data are used for the evaluation of corrosion inhibitor efficiencies. In case data from just one electrochemical method are used, the validity of the method and data should be verified and critical points must be identified. In this study, we have compared results from three standard electrochemical methods obtained with a common steel sample in an acidic environment and in the presence of three representative aromatic inhibitors. We have noticed significant differences between the results; therefore we suggest rationalization and practical consequences.
用电化学方法确定了腐蚀过程的热力学和动力学参数。结果用于更深入地了解已建立的界面结构和正在进行的过程以及实验参数的影响。数据经常被用来评估缓蚀剂的效率。如果只使用一种电化学方法的数据,则必须验证方法和数据的有效性,并确定临界点。在这项研究中,我们比较了在酸性环境和三种代表性芳香抑制剂存在下,用普通钢样品获得的三种标准电化学方法的结果。我们注意到结果之间的显著差异;因此,我们建议合理化和实际后果。
{"title":"A comparison of methods for corrosion inhibitor assessment: Mild steel protected by disubstituted aromatics","authors":"Jessica Roscher, Dan Liu, R. Holze","doi":"10.1002/maco.202112551","DOIUrl":"https://doi.org/10.1002/maco.202112551","url":null,"abstract":"Both thermodynamic and kinetic corrosion process parameters are determined with electrochemical methods. Results are used for a deeper understanding of the established interfacial structures and ongoing processes and of the effects of experimental parameters. Frequently data are used for the evaluation of corrosion inhibitor efficiencies. In case data from just one electrochemical method are used, the validity of the method and data should be verified and critical points must be identified. In this study, we have compared results from three standard electrochemical methods obtained with a common steel sample in an acidic environment and in the presence of three representative aromatic inhibitors. We have noticed significant differences between the results; therefore we suggest rationalization and practical consequences.","PeriodicalId":18223,"journal":{"name":"Materials and Corrosion","volume":"29 1","pages":"254 - 258"},"PeriodicalIF":0.0,"publicationDate":"2021-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81833348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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Materials and Corrosion
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