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Improving performance of cathode NMC-811 by CeO2-coating for Li-ion battery 通过 CeO2 涂层提高锂离子电池正极 NMC-811 的性能
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-04 DOI: 10.1016/j.mee.2024.112169
Muhammad Fakhrudin , Evvy Kartini , Anne Zulfia

The high energy density layered oxide LiNi0.8Mn0.1Co0.1O2 (NMC811) holds great promise as a cathode material for future Li-ion batteries. However, its application in electric vehicles is hindered by issues such as inadequate cycle performance and rate capability. Additionally, the corrosion caused by the electrolyte poses limitations on high voltage operation. In this study, Cerium Oxide (CeO2) was used to coat NMC811 using wet chemical method followed by heat treatment. Distilled water was used to dissolve Ce salt instead of ethanol so that it can reduce coating costs and is more environmentally friendly. XRD analysis showed no significant change in the hexagonal crystal structure of NMC811 material but the appearance of small CeO2 peaks in patterns. Electrochemical test of CeO2 coated NMC811 exhibited 18% and 9% higher cyclic and rate performance, respectively in comparison to pristine material.

高能量密度层状氧化物 LiNi0.8Mn0.1Co0.1O2(NMC811)有望成为未来锂离子电池的正极材料。然而,其在电动汽车中的应用却因循环性能和速率能力不足等问题而受到阻碍。此外,电解液造成的腐蚀也限制了其高压运行。本研究采用湿化学方法对 NMC811 进行氧化铈(CeO2)涂层,然后进行热处理。使用蒸馏水而不是乙醇来溶解 Ce 盐,这样可以降低涂层成本,而且更加环保。XRD 分析表明,NMC811 材料的六方晶体结构没有明显变化,但图案中出现了小的 CeO2 峰。电化学测试显示,与原始材料相比,涂有 CeO2 的 NMC811 的循环性能和速率性能分别提高了 18% 和 9%。
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引用次数: 0
Review of the pressure sensor based on graphene and its derivatives 基于石墨烯及其衍生物的压力传感器综述
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-29 DOI: 10.1016/j.mee.2024.112167
Yuwei Guo, Simei Zeng, Qi Liu, Jingye Sun, Mingqiang Zhu, Linan Li, Tao Deng

Pressure sensors are widely used in a variety of industrial automatic control environments and in everyday life, including production automatic control, aerospace, healthcare, electronic skin and many other industries. Different structural designs are suitable for different application scenarios. With the development of technology, the demand for high sensitivity and wide range pressure sensors is increasing. The appearance of graphene-based materials has pushed the performance of pressure sensors to new heights. In this paper, the research progress of pressure sensors in the past ten years based on graphene and its derivatives is deeply discussed. According to the classification of application directions based on different substrate structures, the current pressure sensors based on graphene and its derivatives are reviewed. Finally, the current development status of pressure sensing technology based on graphene and its derivatives is summarized, and the development prospect in this field is prospected.

Index Terms.

Pressure sensor, Graphene, Graphene derivatives.

压力传感器广泛应用于各种工业自动控制环境和日常生活中,包括生产自动控制、航空航天、医疗保健、电子皮肤和许多其他行业。不同的结构设计适用于不同的应用场景。随着科技的发展,人们对高灵敏度、宽量程压力传感器的需求越来越大。石墨烯基材料的出现将压力传感器的性能推向了新的高度。本文深入探讨了近十年来基于石墨烯及其衍生物的压力传感器的研究进展。根据不同基底结构的应用方向分类,综述了当前基于石墨烯及其衍生物的压力传感器。最后,总结了基于石墨烯及其衍生物的压力传感技术的发展现状,并展望了该领域的发展前景。
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引用次数: 0
Recent advances in micro- and bio- electromechanical system architectures for energy efficient chemiresistors 用于高能效化学电阻器的微型和生物机电系统架构的最新进展
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-28 DOI: 10.1016/j.mee.2024.112168
Bharat Sharma , Mukesh Kumar , Ashutosh Sharma

The recent evolution of microelectromechanical systems (MEMSs) presents a more mature technology that expands from pure research towards multidisciplinary nanoelectromechanical systems (NEMS) research. The smaller size of NEMS makes them multifunctional, fast, energy-saving, and sensitive to any external stimuli. The extreme sensitivity of these NEMS opens new avenues to the various industrial sector of applications in biosensing, gas sensing, and medical implants which won't be possible with traditional MEMS counterparts. Most of the resistive-gas sensors are more popular than others but their elevated working temperatures consume more energy and limit their real-world applications. Various self-heating, embedded MEMS microheaters, and materials have been explored to improve the sensing performance. Thus, there is an urgent need of the hour to review the associated manufacturing techniques and evolution of MEMS fabrication for energy-saving gas sensors and new developments in this area. We overview the various manufacturing process and developments in MEMS/NEMS for gas sensor applications, and their historical perspectives, and provide future guidelines to meet the existing challenges for real-world gas sensing applications.

近年来,微机电系统(MEMS)的发展呈现出一种更加成熟的技术,从纯粹的研究扩展到多学科纳米机电系统(NEMS)研究。NEMS 的尺寸较小,因此具有多功能、快速、节能以及对任何外部刺激敏感的特点。这些 NEMS 的极高灵敏度为生物传感、气体传感和医疗植入等各种工业领域的应用开辟了新途径,而这些应用是传统 MEMS 无法实现的。大多数电阻式气体传感器比其他传感器更受欢迎,但它们的工作温度较高,能耗较大,限制了它们在现实世界中的应用。为了提高传感性能,人们探索了各种自加热、嵌入式 MEMS 微加热器和材料。因此,当务之急是回顾节能气体传感器的相关制造技术和微机电系统制造的演变以及该领域的新发展。我们概述了用于气体传感器应用的 MEMS/NEMS 的各种制造工艺和发展及其历史前景,并提供了未来的指导方针,以应对现实世界中气体传感应用所面临的现有挑战。
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引用次数: 0
Exploring statistical approaches for accessing the reliability of Y2O3-based memristive devices 探索获取基于 Y2O3 的记忆器件可靠性的统计方法
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-24 DOI: 10.1016/j.mee.2024.112166
Dhananjay D. Kumbhar , Sanjay Kumar , Mayank Dubey , Amitesh Kumar , Tukaram D. Dongale , Somanath D. Pawar , Shaibal Mukherjee

Memristive devices have emerged as promising alternatives to traditional complementary metal-oxide semiconductor (CMOS)-based circuits in the field of neuromorphic systems. These two-terminal electronic devices, known for their non-volatile memory properties, can emulate synaptic behavior within artificial neural networks, offering remarkable advantages, including scalability, energy efficiency, rapid operation, compact size, and ease of fabrication. They hold the potential to serve as fundamental components for artificial neurons, revolutionizing neuromorphic computing systems by closely mimicking biological neurons. However, the integration of resistive random-access memory (RRAM) into commercial production faces challenges due to substantial variations in resistive switching (RS) parameters, which include cycle-to-cycle (C2C) and device-to-device (D2D) fluctuations. These variations are rooted in the stochastic nature of RS, linked to physical mechanisms like diffusion and redox reactions. Nonetheless, limitations exist in the current analytical approaches, emphasizing the need for more standardized tools to assess memristive device reliability consistently. Weibull distribution is widely used to analyze RRAM variability and many further studies are based on it. However, this distribution may not work well for some memristive devices. In such cases, one can use other statistical distributions available in the literature. In the present work, statistical distributions, namely Weibull, Exponential, Log-Normal, Gamma, and Logistic distributions, are employed to scrutinize memristive devices device parameters, shedding light on their performance and reliability. Also, analytical methods namely maximum likelihood estimates for parameter estimation and Kolmogorov-Smirnov test for assessing goodness of fit of the distributions are used. This study aims to provide an approach with a deeper understanding of memristive device parameters and analysis techniques.

在神经形态系统领域,存储器件已成为传统互补金属氧化物半导体(CMOS)电路的有前途的替代品。这些双端电子器件以其非易失性存储器特性而闻名,可以模拟人工神经网络中的突触行为,具有显著的优势,包括可扩展性、能效、快速运行、体积小巧和易于制造。它们有可能成为人工神经元的基本组件,通过近似模拟生物神经元彻底改变神经形态计算系统。然而,将电阻式随机存取存储器(RRAM)集成到商业生产中面临着挑战,原因是电阻式开关(RS)参数变化很大,包括周期到周期(C2C)和器件到器件(D2D)波动。这些变化源于 RS 的随机性,与扩散和氧化还原反应等物理机制有关。尽管如此,目前的分析方法仍存在局限性,因此需要更多标准化工具来一致地评估忆阻器的可靠性。Weibull 分布被广泛用于分析 RRAM 的变异性,许多进一步的研究都以它为基础。然而,这种分布对于某些忆阻器可能效果不佳。在这种情况下,可以使用文献中提供的其他统计分布。在本研究中,我们采用了统计分布,即 Weibull 分布、指数分布、对数正态分布、伽马分布和对数分布,来仔细研究忆阻器的器件参数,从而揭示其性能和可靠性。此外,还采用了分析方法,即用于参数估计的最大似然估计和用于评估分布拟合度的 Kolmogorov-Smirnov 检验。本研究旨在提供一种更深入了解忆阻器参数和分析技术的方法。
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引用次数: 0
Negative capacitance FET based dual-split control 6T-SRAM cell design for energy efficient and robust computing-in memory architectures 基于负电容场效应晶体管的双分路控制 6 T-SRAM 单元设计,适用于高能效和稳健的计算型内存架构
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-23 DOI: 10.1016/j.mee.2024.112165
Birudu Venu, Tirumalarao Kadiyam, Koteswararao Penumalli, Sivasankar Yellampalli, Ramesh Vaddi

A Negative Capacitance Field effet transistor (NCFET) based Dual split control (DSC) 6T-SRAM cell has been designed and explored with Computing-in memory (CiM) architecture for energy efficient demonstration of Deep neural networks (DNN) basic operation such as Input-Weight (Dot) Product. The impact of ferro electric layer thickness (Tfe) on the SRAM cell perfomance metrics such as read noise margin (RNM), write noise margin (WNM) and energy efficiency for read and write operations have been analyzed at supply voltages of 0.3 V and 0.5 V. It has been observed that due to the steep slope characteristics, the NCFET based DSC 6T-SRAM cell design exhibits better RM, WM, and energy efficiency as compared to the baseline CMOS DSC SRAM cell design at VDD = 0.3 V and 0.5 V respectively (with Tfe range of 1 nm to 3 nm). Further, NCFET dual split control scheme for 6T-SRAM cell demonstrate improved read stability and write ability when compared with NCFET 6 T-SRAM cell design along with improved energy efficiency. NCFET based DSC 6T-SRAM CiM cell design has ∼22.77× and 12.41× lower energy consumption compared to the équivalent baseline 40 nm CMOS/baseline SRAM CiM design and ∼ 25.80× and 22.76× lower energy consumption compared to the NCFET based SRAM CiM at VDD = 0.3 V and 0.5 V respectively. NCFETs have improved steep subthreshold slope characteristics at an optimal Tfe value and NCFET SRAM based CiM circuits are expected to have higher noise margins and lower energy consumption compared to the baseline CMOS designs and are effective for NCFET based computing in-memory architectures with reduced read disturb issues in combination with DSC concept.

我们设计并探索了一种基于负电容场效应晶体管(NCFET)的双分割控制(DSC)6T-SRAM 单元,该单元采用内存中计算(CiM)架构,用于高效演示深度神经网络(DNN)的基本操作,如输入-重量(Dot)乘积。在 0.3 V 和 0.5 V 电源电压下,分析了铁电层厚度 (Tfe) 对 SRAM 单元性能指标的影响,如读取噪声余量 (RNM)、写入噪声余量 (WNM) 以及读写操作的能效。结果表明,由于具有陡坡特性,基于 NCFET 的 DSC 6T-SRAM 单元设计与基线 CMOS DSC SRAM 单元设计相比,在 VDD = 0.3 V 和 0.5 V 条件下(Tfe 范围为 1 nm 至 3 nm),分别表现出更好的 RM、WM 和能效。此外,与 NCFET 6 T-SRAM 单元设计相比,NCFET 6 T-SRAM 单元的 NCFET 双分割控制方案在提高能效的同时,还改善了读取稳定性和写入能力。在 VDD = 0.3 V 和 0.5 V 条件下,基于 NCFET 的 DSC 6T-SRAM CiM 单元设计的能耗分别比同等基线 40 nm CMOS/基线 SRAM CiM 设计低 22.77 倍和 12.41 倍,比基于 NCFET 的 SRAM CiM 低 25.80 倍和 22.76 倍。在最佳Tfe值下,NCFET具有更好的陡峭阈下斜率特性,与基线CMOS设计相比,基于NCFET的SRAM CiM电路有望具有更高的噪声裕度和更低的能耗。
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引用次数: 0
Investigation of thermal stress effects during annealing of hafnia-made thin film using molecular dynamics simulations 利用分子动力学模拟研究霞石薄膜退火过程中的热应力效应
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-21 DOI: 10.1016/j.mee.2024.112158
Kiran Raj, Yongwoo Kwon

Hafnia or hafnium oxide is a high-κ dielectric material with paramount importance in the realm of semiconductor devices. Recent advancements in 3D device structures require a few nanometer-thick conformal films on non-planar substrates. During the fabrication stage, the annealing process of thin films has been discovered to mitigate delamination issues at the film-substrate interface. However, it has been observed that the residual stress, which emerges as the film cools to room temperature, may lead to delamination. In this study, we propose an idealized atomistic model to mimic the critical region of a 3D-NAND structure, to get insights into the effect of thermal stress and delamination during the annealing of hafnia-made thin film. We employ molecular dynamics simulation using charge-optimized many-body potential (COMB) to perform heating and cooling simulations for different thicknesses of the hafnia layer. Our results suggest that, during heating, as the annealing temperature increases, the severity of delamination decreases. At extremely low thickness of the hafnia layer, delamination does not occur. However, significant delamination is observed during the cooling process, especially when the high temperature gradient is high.

铪或氧化铪是一种高κ介电材料,在半导体器件领域具有极其重要的地位。三维器件结构的最新进展要求在非平面基底上形成几纳米厚的共形薄膜。在制造阶段,人们发现薄膜的退火过程可以缓解薄膜-基底界面的分层问题。然而,人们发现,薄膜冷却至室温时产生的残余应力可能会导致分层。在本研究中,我们提出了一个理想化的原子模型来模拟三维-NAND 结构的临界区域,以深入了解铪制薄膜退火过程中热应力和分层的影响。我们利用电荷优化多体势能(COMB)进行分子动力学模拟,对不同厚度的霞糠层进行加热和冷却模拟。结果表明,在加热过程中,随着退火温度的升高,分层的严重程度会降低。在哈夫纳层厚度极低的情况下,分层不会发生。然而,在冷却过程中,尤其是高温梯度较大时,会出现严重的分层现象。
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引用次数: 0
A current mode capacitance multiplier employing a single active element based on Arbel-Goldminz cells for low frequency applications 基于 Arbel-Goldminz 单元的电流模式电容乘法器,采用单一有源元件,适用于低频应用
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-16 DOI: 10.1016/j.mee.2024.112157
Burak Sakacı, Deniz Özenli

In this work, a capacitor multiplier based on a Multiple Output-Voltage Difference Transconductance Amplifier (MO-VDTA) is built by using Arbel-Goldminz cells with extensive performance analysis. Considering the large chip area occupation of capacitors, capacitor multipliers are one of the most required analog building blocks in most of low frequency applications. In this respect, the obtained capacitor multiplier is tested in a 2nd order low-pass filter by changing the cut-off frequency from 2 kHz to around 12.4 kHz. The multiplication factor (denoted as “k”) of the proposed architecture can be adjusted electronically from 120 to 750 for approximately two decades, while the structure contains only a single active element with a base capacitance. Additionally, the multiplication factor can be safely increased by using additional transconductance stages in the MO-VDTA active block. In the performance analysis, post-layout results are provided in conjunction with process corners, Monte-Carlo analyses and experimental verifications on the basis of commercial off-the-shelf elements such as AD844 and LM13700s.

在这项工作中,通过使用 Arbel-Goldminz 单元和广泛的性能分析,建立了基于多输出电压差跨导放大器 (MO-VDTA) 的电容乘法器。考虑到电容器占用较大的芯片面积,电容器乘法器是大多数低频应用中最需要的模拟构件之一。为此,我们在一个二阶低通滤波器中测试了所获得的电容乘法器,将截止频率从 2 kHz 改为 12.4 kHz 左右。拟议结构的乘法系数(用 "k "表示)可以通过电子方式从 120 调整到 750,持续时间约为 20 年,而该结构只包含一个具有基底电容的有源元件。此外,通过在 MO-VDTA 有源块中使用额外的跨导级,还可以安全地提高倍增因子。在性能分析中,结合工艺角、蒙特卡洛分析和基于 AD844 和 LM13700 等现成商用元件的实验验证,提供了布局后结果。
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引用次数: 0
Design of multi-scroll chaotic attractor based on a novel multi-segmented memristor and its application in medical image encryption 基于新型多分段忆阻器的多卷混沌吸引子设计及其在医学图像加密中的应用
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-09 DOI: 10.1016/j.mee.2024.112156
Jiangang Zuo , Meng Wang , Jie Zhang

Medical images contain rich individual health information, making the protection of their privacy and security crucial. This study first proposes a novel multi-segment memristor based on a multi-segment linear function. Then, building upon the Sprott-B chaotic system, a mirror-symmetric memristor multi-scroll chaotic attractor (MMSCAs) is introduced by incorporating logic pulse signals and the novel multi-segment memristor. Dynamic analysis of MMSCAs is conducted from four aspects: equilibrium points, Lyapunov exponents and bifurcations, coexisting attractors, and complexity. Lyapunov exponents and bifurcation diagram analysis reveal rich dynamical behaviors in MMSCAs, including inverse period-doubling bifurcations, burst chaotic, transient chaotic, and offset boosting. MMSCAs exhibit periodic and chaotic attractors co-existing under different initial conditions, along with multi-stability and super multi-stability. Complexity analysis results indicate that MMSCAs possess higher complexity and better randomness compared to other memristor chaotic systems. The accuracy of the MMSCAs mathematical model is verified through circuit design and simulation, and the implementation of MMSCAs in the embedded domain is extended using the STM32 microcontroller. Finally, a new cryptographic system is designed by integrating MMSCAs with RNA computation and applied to medical image encryption. The security of the cryptographic system is evaluated through key space and sensitivity, histogram, and correlation, while its robustness is evaluated through resistance to cropping and noise. The analysis results demonstrate high security and strong robustness of the cryptographic system, offering a novel solution for the protection of medical image information.

医学图像包含丰富的个人健康信息,因此保护其隐私和安全至关重要。本研究首先提出了一种基于多段线性函数的新型多段忆阻器。然后,在 Sprott-B 混沌系统的基础上,结合逻辑脉冲信号和新型多段忆阻器,引入了镜像对称忆阻器多卷积混沌吸引子(MMSCAs)。从平衡点、Lyapunov指数和分岔、共存吸引子和复杂性四个方面对MMSCAs进行了动态分析。Lyapunov指数和分岔图分析揭示了MMSCAs中丰富的动力学行为,包括反周期加倍分岔、猝发混沌、瞬态混沌和偏移提升。在不同的初始条件下,MMSCA 呈现出周期吸引子和混沌吸引子并存的现象,同时还表现出多重稳定性和超多重稳定性。复杂性分析结果表明,与其他忆阻器混沌系统相比,MMSCAs具有更高的复杂性和更好的随机性。通过电路设计和仿真验证了 MMSCAs 数学模型的准确性,并利用 STM32 微控制器扩展了 MMSCAs 在嵌入式领域的实现。最后,通过将 MMSCAs 与 RNA 计算相结合,设计了一种新的加密系统,并将其应用于医学图像加密。通过密钥空间和灵敏度、直方图和相关性评估了加密系统的安全性,同时通过抗裁剪和抗噪声评估了其鲁棒性。分析结果表明,该加密系统安全性高、鲁棒性强,为保护医学图像信息提供了一种新的解决方案。
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引用次数: 0
A new characterization model of FinFET self-heating effect based on FinFET characteristic parameter 基于 FinFET 特征参数的 FinFET 自热效应新表征模型
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-08 DOI: 10.1016/j.mee.2024.112155
Yue Wang, Huaguo Liang, Hong Zhang, Danqing Li, Yingchun Lu, Maoxiang Yi, Zhengfeng Huang

The characterization of the self-heating effect (SHE) has been an important research topic in advanced technology, but the existing characterizations are few and the characterization process is relatively complex. In this research, a SHE characterization model is established based on the relationship between output transconductance variation (gm), gate source voltage (VGS) and temperature variation (T) caused by SHE through machine learning, and then the model is validated by theoretical analyses and experimental simulation. The characterization model is capable of directly calculating the T caused by SHE during I - V testing and simplifying the SHE characterization steps while ensuring characterization accuracy (T difference < 1 °C), thus saving costs. It is also found that the model can expand the characterization range (VGS: 0.3–0.7 V) of SHE and conducts quantitative characterization with model calculation under different VGS, realizing a high characterization resolution of VGS: 0.01 V. The circuit level application proves that the method can be effectively applied to the characterization of the SHE and solves the problem of the characterization of the circuit level SHE.

自热效应(SHE)的表征一直是先进技术领域的重要研究课题,但现有的表征方法较少,表征过程也相对复杂。本研究通过机器学习,根据 SHE 引起的输出跨导变化(Δgm)、栅源电压(VGS)和温度变化(ΔT)之间的关系建立了 SHE 表征模型,然后通过理论分析和实验仿真对模型进行了验证。该表征模型能够直接计算 I - V 测试期间由 SHE 引起的 ∆T 值,简化了 SHE 表征步骤,同时确保了表征精度(∆T 值相差 < 1 °C),从而节约了成本。研究还发现,该模型可以扩展 SHE 的表征范围(VGS:0.3-0.7 V),并在不同 VGS 下通过模型计算进行定量表征,实现了 VGS. 0.01 V 的高表征分辨率:电路级应用证明该方法可有效应用于 SHE 的表征,解决了电路级 SHE 表征的难题。
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引用次数: 0
Silicon microresonator arrays: A comprehensive study on fabrication techniques and pH-controlled stress-induced variations in cantilever stiffness 硅微谐振器阵列:关于制造技术和 pH 值控制应力引起的悬臂刚度变化的综合研究
IF 2.3 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-02-05 DOI: 10.1016/j.mee.2024.112154
G. Brunetti , A. De Pastina , C. Rotella , V. Usov , G. Villanueva , M. Hegner

We introduce a detailed design and fabrication process of Silicon microcantilever arrays for biomolecular detection in liquid environment, utilized with laser readout. We present typical fabrication problems and provide related solutions to obtain high quality resonators via a robust, reproducible and high-yield process. Sensors in these arrays are individually functionalized with self-assembled chemical monolayers exposing various pH-active end-groups into solution. Dynamic-mode controlled frequency measurements in varying pH solutions result in stress-induced change of the sensor spring constant. pH changes in the solution lead to deprotonation of exposed functional chemical groups at high pH and the repulsive charges induced strain is proportional to the quantity and confinement of charges at the sensor interface. These built-up strains that affect the mechanical stiffness can be reversibly relaxed when exposed again to low pH environments.

我们介绍了用于液体环境中生物分子检测的硅微悬臂阵列的详细设计和制造过程,并利用激光读出。我们介绍了典型的制造问题,并提供了相关解决方案,以便通过稳健、可重复和高产出的工艺获得高质量的谐振器。这些阵列中的传感器分别通过自组装化学单层进行功能化,将各种 pH 活性末端基团暴露在溶液中。溶液中的 pH 值变化会导致暴露在高 pH 值下的功能化学基团发生去质子化反应,而排斥电荷引起的应变与传感器界面上的电荷数量和限制成正比。当再次暴露在低 pH 值环境中时,这些影响机械刚度的累积应变可以可逆地放松。
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引用次数: 0
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Microelectronic Engineering
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