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Capillary flow printing of submicrometre carbon nanotube transistors 亚微米碳纳米管晶体管的毛细管流动印刷
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-17 DOI: 10.1038/s41928-025-01470-7
Brittany N. Smith, Faris M. Albarghouthi, James L. Doherty, Xuancheng Pei, Quentin Macfarlane, Matthew Salfity, Daniel Badia, Marc Pascual, Pascal Boncenne, Nathan Bigan, Amin M’Barki, Aaron D. Franklin
Printed transistors have a wide range of applications, but the limited resolution of printing techniques (10–30 µm) has been a barrier to utility and scalability. Printed submicrometre channel lengths have previously been achieved. However, this has required chemical processes or tedious post-processing, which limits applicability. Here we show that capillary flow printing can create submicrometre carbon nanotube thin-film transistors without chemical modification or physical manipulation after printing. We show that the approach can be used to print conducting, semiconducting and insulating inks on different types of substrate (silicon, Kapton and paper), and can be used to fabricate various thin-film transistor device architectures. The printed carbon nanotube thin-film transistors exhibit on-currents of 1.12 mA mm−1 when back gated on Si/SiO2 and 490 µA mm−1 when side gated through ion gel on Kapton. We also show that devices printed on Kapton offer mechanical bending and sweep rate resilience, illustrating the potential of these printed devices for flexible applications. A capillary flow printing technique can be used to fabricate printed carbon nanotube thin-film transistors with submicrometre channel lengths on rigid or flexible substrates.
印刷晶体管具有广泛的应用,但印刷技术的有限分辨率(10-30 μ m)一直是实用性和可扩展性的障碍。印刷亚微米通道长度以前已经实现。然而,这需要化学过程或繁琐的后处理,这限制了适用性。在这里,我们证明了毛细管流动印刷可以在印刷后不需要化学修饰或物理操作的情况下制造亚微米碳纳米管薄膜晶体管。我们证明,该方法可用于在不同类型的衬底(硅、卡普顿和纸)上印刷导电、半导体和绝缘油墨,并可用于制造各种薄膜晶体管器件结构。在Si/SiO2上背门控时,碳纳米管薄膜晶体管的导通电流为1.12 mA mm−1,在Kapton上通过离子凝胶侧门控时,导通电流为490µA mm−1。我们还表明,在Kapton上印刷的设备具有机械弯曲和扫描速率弹性,说明了这些印刷设备在灵活应用方面的潜力。毛细管流动印刷技术可用于在刚性或柔性衬底上制备通道长度为亚微米的碳纳米管薄膜晶体管。
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引用次数: 0
Non-volatile methylammonium chloride substitution for tin halide perovskite transistors 非挥发性甲基氯化铵取代卤化锡钙钛矿晶体管
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-17 DOI: 10.1038/s41928-025-01467-2
Hansol Park, Cheong Beom Lee, Jongmin Lee, Seon-Jeong Lim, Bum Ho Jeong, Hakjun Kim, Seong Jae Lee, Hayoung Oh, Hyungju Ahn, Do Hwan Kim, Kyeounghak Kim, Hui Joon Park
Tin halide perovskites are a potential p-type channel material for thin-film transistors due to their high room-temperature hole mobility and easy processability. However, creating a high-quality thin film with a three-dimensional tin halide perovskite is challenging due to its inherent instability and defect density. Here we show that the coordinated control of A-site cations and X-site anions in a three-dimensional perovskite, formamidinium tin iodide (FASnI3), using methylammonium chloride (MACl) can stabilize the crystal structure. Unlike lead halide perovskites, where MACl functions only as a volatile intermediate-phase stabilizer, we show that MACl is incorporated into the FASnI3 crystal structure through the substitution of FA and I components with MA and Cl, which enhances its stability. The resulting uniform thin films offer improved crystallinity and larger grain sizes. A MACl-substituted FASnI3 transistor exhibits a field-effect hole mobility of over 80 cm2 V−1 s−1, an on/off current ratio over 3.0 × 109 and a threshold voltage of around 0 V, as well as high operational reliability and hysteresis-free behaviour. A three-dimensional tin halide perovskite can be stabilized by incorporating methylammonium chloride into the perovskite structure and used to create p-type thin-film transistors with a hole mobility of over 80 cm2 V−1 s−1.
卤化锡钙钛矿具有较高的室温空穴迁移率和易加工性,是一种潜在的p型薄膜晶体管沟道材料。然而,由于其固有的不稳定性和缺陷密度,用三维卤化锡钙钛矿制造高质量的薄膜是具有挑战性的。本研究表明,使用甲基氯化铵(MACl)协调控制三维钙钛矿甲脒碘化锡(FASnI3)中的a位阳离子和x位阴离子可以稳定晶体结构。与卤化铅钙钛矿不同,MACl仅作为挥发性中间相稳定剂起作用,我们发现MACl通过MA和Cl取代FA和I组分加入到FASnI3晶体结构中,从而增强了其稳定性。所得的均匀薄膜提供了更好的结晶度和更大的晶粒尺寸。macl取代的FASnI3晶体管具有超过80 cm2 V−1 s−1的场效应空穴迁移率,超过3.0 × 109的开/关电流比和约0 V的阈值电压,以及高工作可靠性和无迟滞行为。通过在钙钛矿结构中加入甲基氯化铵,可以稳定三维卤化锡钙钛矿,并用于制造空穴迁移率超过80 cm2 V−1 s−1的p型薄膜晶体管。
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引用次数: 0
Third-party certification of high mobility values in perovskite transistors 钙钛矿晶体管中高迁移率值的第三方认证
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-17 DOI: 10.1038/s41928-025-01415-0
Yuanyuan Hu, Lang Jiang
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引用次数: 0
Three-dimensional integrated hybrid complementary circuits for large-area electronics 用于大面积电子学的三维集成混合互补电路
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-17 DOI: 10.1038/s41928-025-01469-0
Saravanan Yuvaraja, Mohamad Insan Nugraha, Qiao He, Leo Raj Solay, Patsy Arely Miranda Cortez, Na Xiao, Martin Heeney, Thomas D. Anthopoulos, Xiaohang Li
The development of low-power computing sectors requires compact, power-efficient and high-performance integrated circuits. Hybrid technology that combines n-type metal oxide thin-film transistors and p-type organic thin-film transistors offers a potential solution. However, increasing the transistor density of these systems through vertical stacking is challenging due to issues related to thermal budget and interface roughness. Here we report a six-stack hybrid complementary transistor technology that has 41 layers and uses n-type indium oxide (In2O3) and a p-type organic semiconductor (C16IDT-BT) as channel materials. We test 600 transistors and show that n-type oxide devices and p-type organic devices exhibit comparable field-effect mobilities and saturation currents. We also create 300 hybrid inverters by integrating the oxide and organic transistors; the circuits exhibit a gain of 94.84 V V−1 and a power consumption of 0.47 µW. We also fabricate NAND and NOR gates comprising transistors from four stacks. Thermal stability analysis shows that device characteristics begin to degrade above 50 °C, a known limitation of low-thermal-budget processes. Such performance is sufficient for many large-area electronics applications, but further thermal optimization will be necessary to extend operational robustness towards standard industrial conditions. A six-stack hybrid complementary transistor technology that uses n-type indium oxide and a p-type organic semiconductor as channel materials can be used to build inverters that exhibit a gain of 94.84 V V−1 and a power consumption of 0.47 µW.
低功耗计算领域的发展需要紧凑、节能和高性能的集成电路。结合n型金属氧化物薄膜晶体管和p型有机薄膜晶体管的混合技术提供了一个潜在的解决方案。然而,由于与热预算和界面粗糙度相关的问题,通过垂直堆叠来增加这些系统的晶体管密度是具有挑战性的。在这里,我们报告了一种六层混合互补晶体管技术,该技术有41层,使用n型氧化铟(In2O3)和p型有机半导体(C16IDT-BT)作为通道材料。我们测试了600个晶体管,并表明n型氧化物器件和p型有机器件具有相当的场效应迁移率和饱和电流。我们还通过集成氧化物和有机晶体管创造了300个混合逆变器;电路增益为94.84 V V−1,功耗为0.47µW。我们还制造由四层晶体管组成的NAND和NOR门。热稳定性分析表明,器件特性在50°C以上开始退化,这是已知的低热预算工艺的限制。这样的性能对于许多大面积的电子应用来说已经足够了,但是进一步的热优化将是必要的,以扩展在标准工业条件下的操作稳健性。采用n型氧化铟和p型有机半导体作为沟道材料的六叠混合互补晶体管技术可用于构建增益为94.84 V V−1,功耗为0.47 μ W的逆变器。
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引用次数: 0
A terahertz nonlinear diode chain based on an asymmetric double-layer topology 基于非对称双层拓扑结构的太赫兹非线性二极管链
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-16 DOI: 10.1038/s41928-025-01460-9
Hongji Zhou, Tianchi Zhou, Yaxin Zhang, Hongxin Zeng, Shixiong Liang, Jun Zhou, Huajie Liang, Lin Huang, Sen Gong, Yazhou Dong, Jingrui Liang, Hailong Guo, Zhihong Feng, Ziqiang Yang, Daniel M. Mittleman
Frequency multiplier devices based on Schottky barrier diodes can be used to generate terahertz radiation, offering high power output and potential integration into all-solid-state systems. However, the scaling of the output power of such devices is often limited by the power handling capacity of a single diode. A connected chain of Schottky barrier diodes, together with a power combining approach, can be used to increase the terahertz output power. However, the uneven field distribution among the diodes—which is related to the similarity between the terahertz wavelength and the physical dimensions of the diodes themselves—leads to lower efficiency and premature breakdown. Here we report an asymmetric double-layer C-shaped diode chain structure that can adjust the local electromagnetic field distribution and enhance the conversion efficiency of the diode chain. Our resulting device has a frequency doubling efficiency of 38%, with an output exceeding 300 mW at 170 GHz. An asymmetric double-layer C-shaped diode chain structure that can adjust the local electromagnetic field distribution can be used to create a terahertz device with a frequency doubling efficiency of 38%.
基于肖特基势垒二极管的倍频器件可用于产生太赫兹辐射,提供高功率输出和集成到全固态系统的潜力。然而,这种器件的输出功率的缩放通常受到单个二极管的功率处理能力的限制。连接的肖特基势垒二极管链,加上功率组合方法,可以用来增加太赫兹输出功率。然而,二极管之间不均匀的场分布——这与太赫兹波长和二极管本身的物理尺寸之间的相似性有关——导致效率较低和过早击穿。本文报道了一种非对称双层c型二极管链结构,该结构可以调节局部电磁场分布,提高二极管链的转换效率。我们得到的器件具有38%的倍频效率,在170 GHz下的输出超过300 mW。采用可调节局域电磁场分布的非对称双层c型二极管链结构,可制成倍频效率为38%的太赫兹器件。
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引用次数: 0
A lossless and fully parallel spintronic compute-in-memory macro for artificial intelligence chips 用于人工智能芯片的无损和完全并行的自旋电子内存中计算宏
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-16 DOI: 10.1038/s41928-025-01479-y
Humiao Li, Zheng Chai, Weirong Dong, Junjie He, Ruijie Peng, Shiheng Li, Zhen Kong, Xihui Yuan, Xianwang Wang, Zhengke Yang, Haoran Lyu, Haofeng Yu, Xue Zhou, Jiamin Li, Feichi Zhou, Yida Li, Zongben Xu, Tai Min, Longyang Lin
Non-volatile compute-in-memory macros can reduce data transfer between processing and memory units, providing fast and energy-efficient artificial intelligence computations. However, the non-volatile compute-in-memory architecture typically relies on analogue computing, which is limited in terms of accuracy, scalability and robustness. Here we report a 64-kb non-volatile digital compute-in-memory macro based on 40-nm spin-transfer torque magnetic random-access memory technology. Our macro features in situ multiplication and digitization at the bitcell level, precision-reconfigurable digital addition and accumulation at the macro level and a toggle-rate-aware training scheme at the algorithm level. The macro supports lossless matrix–vector multiplications with flexible input and weight precisions (4, 8, 12 and 16 bits), and can achieve a software-equivalent inference accuracy for a residual network at 8-bit precision and physics-informed neural networks at 16-bit precision. Our non-volatile compute-in-memory macro has computation latencies of 7.4–29.6 ns and energy efficiencies of 7.02–112.3 tera-operations per second per watt for fully parallel matrix–vector multiplications across precision configurations ranging from 4 to 16 bits. A 64-kb non-volatile digital compute-in-memory macro that is based on 40-nm spin-transfer torque magnetic random-access memory technology can achieve a software-equivalent inference accuracy for a residual network at 8-bit precision and physics-informed neural networks at 16-bit precision.
非易失性内存宏可以减少处理和存储单元之间的数据传输,提供快速和节能的人工智能计算。然而,非易失性内存计算架构通常依赖于模拟计算,这在准确性、可扩展性和鲁棒性方面受到限制。本文报道了一个基于40纳米自旋转移转矩磁随机存取存储器技术的64 kb非易失性数字内存宏。我们的宏具有位元级的原位乘法和数字化,宏观级的精度可重构数字加法和累加,以及算法级的切换率感知训练方案。该宏支持具有灵活输入和权值精度(4,8,12和16位)的无损矩阵向量乘法,并且可以为8位精度的残差网络和16位精度的物理信息神经网络实现软件等效的推理精度。我们的非易失性内存中计算宏的计算延迟为7.4-29.6 ns,能量效率为7.02-112.3万亿次/秒/瓦,用于4到16位精度配置的完全并行矩阵向量乘法。基于40纳米自旋转移扭矩磁随机存取存储器技术的64 kb非易失性数字内存计算宏可以实现8位精度的残余网络和16位精度的物理信息神经网络的软件等效推理精度。
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引用次数: 0
Hybrid memory to empower edge AI 混合内存增强边缘人工智能
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-15 DOI: 10.1038/s41928-025-01483-2
Dashan Shang, Qing Luo
An energy-efficient hybrid memory that incorporates both ferroelectric capacitors and analogue memristors can accelerate on-chip inference and training.
结合铁电电容器和模拟忆阻器的节能混合存储器可以加速片上推理和训练。
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引用次数: 0
Sweat sensors that won’t catch your drift 汗液传感器不会领会你的意思
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-13 DOI: 10.1038/s41928-025-01478-z
Yizhou Zhong, Sahika Inal
A stretchable biosensor with a diode-connected extended-gate transistor pair design can avoid problems related to signal drift, providing reliable detection of biomarkers directly from sweat.
具有二极管连接的扩展栅晶体管对设计的可拉伸生物传感器可以避免与信号漂移相关的问题,直接从汗液中提供可靠的生物标志物检测。
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引用次数: 0
Precise and scalable analogue matrix equation solving using resistive random-access memory chips 精确和可扩展的模拟矩阵方程求解使用电阻随机存取存储器芯片
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-13 DOI: 10.1038/s41928-025-01477-0
Pushen Zuo, Qishen Wang, Yubiao Luo, Ruiqing Xie, Shiqing Wang, Zezhi Cheng, Lin Bao, Zongwei Wang, Yimao Cai, Ru Huang, Zhong Sun
Precision has long been the central bottleneck of analogue computing. Bit-slicing or analogue compensation can be used to perform matrix–vector multiplication with precision, but solving matrix equations using such techniques is challenging. Here we describe a precise and scalable analogue matrix inversion solver. Our approach uses an iterative algorithm that combines analogue low-precision matrix inversion and analogue high-precision matrix–vector multiplication operations. Both operations are implemented using 3-bit resistive random-access memory chips that are fabricated in a foundry. By combining these with a block matrix algorithm, inversion problems involving 16 × 16 real-valued matrices are experimentally solved with 24-bit fixed-point precision (comparable to 32-bit floating point; FP32). Applied to signal detection in massive multi-input and multi-output systems, our approach achieves performance comparable to FP32 digital processors in just three iterations. Benchmarking shows that our analogue computing approach could offer a 1,000 times higher throughput and 100 times better energy efficiency than state-of-the-art digital processors for the same precision. An analogue matrix solver that combines low-precision matrix inversion and high-precision matrix–vector multiplication can be used to solve inversion problems involving 16 × 16 real-valued matrices with precision comparable to 32-bit floating point.
精度一直是模拟计算的中心瓶颈。位切片或模拟补偿可用于精确地执行矩阵向量乘法,但使用此类技术求解矩阵方程具有挑战性。本文描述了一个精确的、可扩展的模拟矩阵反演求解器。我们的方法使用了一种迭代算法,结合了模拟低精度矩阵反演和模拟高精度矩阵向量乘法运算。这两种操作都是使用在代工厂制造的3位电阻随机存取存储器芯片实现的。通过将这些与分块矩阵算法相结合,涉及16 × 16实值矩阵的反演问题以24位定点精度(可与32位浮点相媲美;FP32)进行了实验解决。应用于大规模多输入和多输出系统中的信号检测,我们的方法只需三次迭代即可实现与FP32数字处理器相当的性能。基准测试表明,在相同的精度下,我们的模拟计算方法可以提供比最先进的数字处理器高1000倍的吞吐量和100倍的能源效率。模拟矩阵求解器结合了低精度矩阵反演和高精度矩阵向量乘法,可用于解决涉及16 × 16实值矩阵的反演问题,其精度可与32位浮点数相媲美。
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引用次数: 0
Lowering the barrier to organic tunnel transistors 降低有机隧道晶体管的障碍
IF 40.9 1区 工程技术 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-10-08 DOI: 10.1038/s41928-025-01466-3
Hans Kleemann
Organic thin-film tunnel transistors with subthreshold swings as low as 24.2 mV dec−1 can be created with the help of a molecular decoupling layer that lowers the energy barrier to tunnelling.
在分子去耦层的帮助下,可以创建具有低至24.2 mV dec−1的亚阈值振荡的有机薄膜隧道晶体管,从而降低隧道的能量势垒。
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引用次数: 0
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Nature Electronics
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