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Crack initiation and early propagation in case hardened sintered PM steels under cyclic load 循环载荷作用下表面硬化烧结PM钢的裂纹萌生和早期扩展
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-07-12 DOI: 10.1080/00325899.2022.2096194
A. Holmberg, U. Wiklund, P. Isaksson, Å. Kassman Rudolphi
ABSTRACT In the present study, crack propagation through the case hardened region of two different PM steels manufactured with different powder size distributions and sintered at different temperatures has been investigated. EBSD was used to study the microstructure before and after case hardening, revealing the relationship between powder particle grains after sintering and prior austenite grains after case hardening. A novel approach was used to achieve short cracks (10–20 µm) with high repeatability. The cracks were then analysed using EBSD and SEM, revealing detailed and novel information about the crack propagation route in the materials. Both tested materials show the same crack propagation behaviour. If a prior grain/prior austenite boundary is present within an angle from the crack initiation site, the cracks will follow the boundary and thus propagate intergranular, suggesting that the preferred route of crack propagation in case hardened sintered steel is along these boundaries.
本文研究了两种粉末粒度分布不同、烧结温度不同的PM钢在淬火区的裂纹扩展情况。利用EBSD对淬火前后的组织进行了研究,揭示了烧结后的粉末颗粒与淬火后的奥氏体晶粒之间的关系。采用了一种新颖的方法来获得短裂纹(10-20µm),具有高重复性。然后使用EBSD和SEM对裂纹进行分析,揭示了材料中裂纹扩展路径的详细和新颖信息。两种材料均表现出相同的裂纹扩展行为。如果在裂纹起始点的一个角度内存在晶粒/奥氏体边界,则裂纹将沿着边界扩展,从而沿晶扩展,这表明硬化烧结钢的裂纹扩展的首选路线是沿着这些边界。
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引用次数: 0
Growth inhibiting during ultra-high temperature sintering of injection moulded 17-4 PH stainless steel through the dispersion of ZrO2 particle as a thermal stabiliser 通过分散ZrO2颗粒作为热稳定剂在注射成型17-4PH不锈钢的超高温烧结过程中抑制生长
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-31 DOI: 10.1080/00325899.2022.2069076
Masoud Moradjoy, H. Khorsand
ABSTRACT The present work deals with the metal injection moulding and ultra-high temperature sintering of 17-4 PH powder. Purposefully, 5 mass% ZrO2 particles were dispersed by applying high shear stress during feedstock preparation. Uniformly distributed particles effectively hindered the powder boundary migration and limited their growth during ultra-high sintering temperatures. The achieved thermal stability provided a proper condition for reducing the final porosity to 3% and significantly improved the ultimate strength to 1070 MPa after sintering at 1380°C. Also, the ZrO2 particles acted as facilitators of sliding between solid powders and substantially reduced the required pressure for injecting to 700 Bar. Through introducing such a new approach in the field of powder injection moulding by ZrO2 particles, the amount of anisotropic shrinkage was reduced to 2%.
本文研究了17-4PH粉末的金属注射成型和超高温烧结。有目的地,通过在原料制备过程中施加高剪切应力来分散5质量%的ZrO2颗粒。在超高烧结温度下,均匀分布的颗粒有效地阻碍了粉末边界的迁移并限制了它们的生长。所获得的热稳定性为将最终孔隙率降低至3%提供了合适的条件,并显著提高了极限强度至1070 在1380°C下烧结后的MPa。此外,ZrO2颗粒起到促进固体粉末之间滑动的作用,并显著降低了注射所需的压力至700巴。通过在ZrO2颗粒粉末注射成型领域引入这种新方法,各向异性收缩量减少到2%。
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引用次数: 0
Performance improvement and microstructure evolution of powder metallurgy high silicon steel with phosphorus addition 添加磷对粉末冶金高硅钢性能的改善及组织演变
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-26 DOI: 10.1080/00325899.2022.2080156
Q. Qin, Fang Yang, Cun-guang Chen, Junjie Hao, Zhimeng Guo
ABSTRACT In this study, phosphorus-containing Fe-5 wt.% Si silicon steel sheet was prepared by powder loose sintering followed by hot rolling. Defect-free sheet with high P content was achieved. The study found that P effects on sintering promotion and processing deterioration were significantly suppressed by the presence of Si in steel. Appropriate P content would significantly improve the mechanical and magnetic properties of the sample. Under a comprehensive consideration, P content of 0.3-0.5 wt.% was suitable for silicon steel. Compared with P-free silicon steel, with 0.3 wt.% P addition, the tensile strength of silicon steel increased from 521 MPa to 680 MPa. As to the magnetic performance, the sample with 0.5 wt.% P had B8 of 1370.5 mT, and W10/50 0f 1.16 W·kg−1, while those for P-free sample were 1332.3 mT, and 1.46 W·kg−1, respectively. FeP phase with special morphology would be precipitated in samples with P addition.
摘要在本研究中,含磷的Fe-5 通过粉末松散烧结然后热轧制备wt.%Si硅钢片。实现了具有高P含量的无缺陷片材。研究发现,钢中Si的存在显著抑制了P对烧结促进和工艺劣化的影响。适当的P含量将显著改善样品的机械和磁性能。综合考虑,P含量为0.3-0.5 wt.%适用于硅钢。与无磷硅钢相比,添加0.3wt.%P后,硅钢的抗拉强度从521MPa提高到680MPa。关于磁性性能,0.5 wt.%P的B8为1370.5 mT和W10/50 0f 1.16 Wõkg−1,而无磷样品为1332.3 mT和1.46 Wõkg−1。在添加磷的样品中会析出具有特殊形态的FeP相。
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引用次数: 0
In situ TEM observation of the microstructure characteristics of the vacuum sintering, sub-zero and heat treatments of Vanadis 23 high-speed steel by adding Cr3C2–TaC–TiC powders 添加Cr3C2–TaC–TiC粉末对钒23高速钢真空烧结、亚零度和热处理组织特征的原位TEM观察
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-26 DOI: 10.1080/00325899.2022.2080157
Shih-Hsien Chang, C. Chang, K. Huang
ABSTRACT This research added different ratios of chromium carbides, tantalum carbide, and titanium carbide powders to Vanadis 23 high-speed steel powders. The composite powders utilised vacuum sintering at 1230, 1245, 1260, and 1275°C for 1 h, respectively, and the experimental results show that good mechanical properties were obtained by the addition of 0.6 mass% Cr3C2–0.2 mass% TaC–0.2 mass% TiC sintered at 1245°C for 1 h. Meanwhile, the apparent porosity was decreased to 0.23%, and the transverse rupture strength and hardness reached 2470.7 MPa and 78.5 HRA, respectively. When optimally sintered Vanadis 23 composites (0.2 T) underwent a series of heat treatments, the transverse rupture strength and hardness values were obviously enhanced to 2693.6 MPa and 84.0 HRA after quenching, and sub-zero and tempering treatments. The EBSD and TEM results confirm that the MC, M 6C, M 7C3, and M 23C6-type carbides appeared in the 0.2 T specimen after vacuum sintering and sub-zero heat treatments.
摘要本研究在钒23高速钢粉末中添加了不同比例的碳化铬、碳化钽和碳化钛粉末。复合粉末在1230、1245、1260和1275°C下使用真空烧结1 h、 实验结果表明,添加0.6质量%Cr3C2–0.2质量%TaC–0.2质量%TiC在1245°C下烧结1 h.同时,表观孔隙率降至0.23%,横向断裂强度和硬度达到2470.7 MPa和78.5 HRA。最佳烧结的钒23复合材料(0.2 T) 经过一系列的热处理,横向断裂强度和硬度值明显提高到2693.6 MPa和84.0HRA。EBSD和TEM结果证实,在0.2 真空烧结和亚零度热处理后的T试样。
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引用次数: 1
Microstructure, mechanical and wear property correlation of Al bronze alloys 铝青铜合金的显微组织、力学性能和磨损性能的相关性
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-23 DOI: 10.1080/00325899.2022.2079183
Mahammad Ali Shaik, Brahma Raju Golla
ABSTRACT In the present work, the effect of Al content (0, 3, 5, 10, 15 wt-%) on the microstructure, mechanical and wear properties of Cu was systematically studied. Interestingly, the core–shell microstructure was observed in the Cu–Al alloys or Al bronzes with different layers of α-Cu, and intermetallic phases. The Cu–Al alloys displayed good compressive yield strength of 174–653 MPa, in particular, the Cu samples with Al (upto 10 wt-%) did not show fracture upto strain of 40%. Abrasion wear was the predominant wear mechanism in pure Cu and Cu–Al alloys after sliding against SiC. The Al addition to Cu drastically decreased the wear rate (198 ×10−3 to 3.8 ×10−3 mm3 N–1m–1) of Cu–Al alloys. The present work demonstrates the advantage of the addition of (5–10 wt-%) Al to Cu in achieving good combination of mechanical and wear properties of Cu–Al alloys.
本文系统地研究了Al含量(0,3,5,10,15wt%)对Cu组织、力学性能和磨损性能的影响。有趣的是,在具有不同α-Cu层和金属间相的Cu–Al合金或Al青铜中观察到了核壳微观结构。Cu–Al合金显示出174–653的良好压缩屈服强度 MPa,特别是含Al(高达10wt%)的Cu样品在高达40%的应变下没有显示出断裂。磨损是纯Cu和Cu–Al合金在与SiC滑动后的主要磨损机制。在Cu中添加Al显著降低了磨损率(198×10−3至3.8×10−3mm3 N–1m–1)的Cu–Al合金。目前的工作证明了在Cu中添加(5–10wt%)Al在实现Cu–Al合金的机械性能和磨损性能的良好结合方面的优势。
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引用次数: 1
Influence of different binder metals in high entropy carbide based hardmetals 不同粘结剂对高熵碳化物基硬质合金的影响
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-21 DOI: 10.1080/00325899.2022.2076311
J. Pötschke, A. Vornberger, T. Gestrich, L. Berger, A. Michaelis
ABSTRACT High-entropy carbides (HEC) are a class of promising new hard phases for a sustainable improvement of hardmetal properties. In this work, hardmetals of the HEC (Ta,Nb,Ti,V,W)C were studied with two typical binder volume fractions of 16 and 24 vol-% consisting of Co, Ni and FeNi. The sintering behaviour, microstructure, phase composition, magnetic and mechanical properties are discussed and are compared to a conventional WC-Co hardmetal. It was shown that the HEC has a high-phase stability and that dense hardmetals with promising mechanical properties were obtained.
摘要高熵碳化物(HEC)是一类有前途的新型硬质相,可用于可持续改善硬质合金的性能。在这项工作中,研究了HEC(Ta,Nb,Ti,V,W)C的硬质合金,其两种典型的粘结剂体积分数分别为16和24 由Co、Ni和FeNi组成的体积百分比。讨论了WC-Co硬质合金的烧结行为、微观结构、相组成、磁性和机械性能,并与传统WC-Co硬金属进行了比较。结果表明,HEC具有较高的相稳定性,并获得了具有良好力学性能的致密硬质合金。
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引用次数: 8
Preparation and characterisation of nickel-based brazing powder: cobalt and chromium addition effects 镍基钎焊粉末的制备和表征:钴和铬的添加效应
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-12 DOI: 10.1080/00325899.2022.2073013
E. Hosseini, M. Amirjan, N. Parvin
ABSTRACT In the present work, three novel brazing powders were produced, in addition to a commercial composition, by the mechanical alloying (MA) method. Cobalt and chromium’s effects on the properties of brazing powder and related joints were investigated. The results showed that; with the addition of cobalt, the powder morphology went to a rounded and near-spherical shape after 15 milling hours, and the solidus significantly raised. Also, chromium shifted the melting range to higher temperatures. The powder with 6% cobalt and 14% chromium had more than 100°C higher solidus and a melting range of 20°C than the commercial BNi-2, ideal for working temperature of more than 1000°C. The shear strength results revealed that the addition of chromium and cobalt significantly promotes joint strength owing to the activation of the solid solution strengthening mechanism. Therefore, the novel synthesized brazing powders can be an excellent candidate for high temperature and corrosive operating environments.
在本工作中,采用机械合金化(MA)方法制备了三种新型钎焊粉。研究了钴、铬对钎焊粉及相关接头性能的影响。结果表明:;随着钴的加入,粉末形貌在铣削15 h后趋于圆润和接近球形,固相度显著提高。此外,铬将熔化范围转移到更高的温度。含有6%钴和14%铬的粉末比商用BNi-2的固相度高100°C以上,熔化范围为20°C,理想的工作温度超过1000°C。抗剪强度结果表明,铬和钴的加入激活了固溶强化机制,显著提高了接头强度。因此,新型合成的钎焊粉可以作为高温和腐蚀性工作环境的优良候选者。
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引用次数: 1
Microstructure control of Additively manufactured IN718 By L-PBF process L-PBF法添加IN718的微观结构控制
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-11 DOI: 10.1080/00325899.2022.2069540
L. Lacoste, A. Sakly, S. Dépinoy, S. Lebel, B. Vayre, C. Colin
ABSTRACT Additively manufactured (AM) parts generally exhibit large columnar grains and a preferential crystallographic texture. While this microstructure may have beneficial effects, for instance on creep properties, the resulting mechanical anisotropy remains a key issue for most critical in-service applications. The relationship between the solidification conditions and the melt pool morphology of the Inconel 718 fabricated by laser powder bed fusion (L-PBF) was investigated to adapt the microstructural characteristics of the parts to their intended applications. By optimising the length of the scanned vectors, it is possible to reduce both the texture index and the grain size by a factor 2 based on EBSD analyses. In addition, the aspect ratio and the grain density can be increased by a factor 1.1 and 2.2, respectively, compared to a conventional L-PBF scanning strategy. These achievements pave the way for the production of fully isotropic parts and/or anisotropic parts controlled by the L-PBF process.
添加制造(AM)零件通常表现出大的柱状晶粒和优先的结晶织构。虽然这种微观结构可能具有有益的影响,例如对蠕变性能,但由此产生的机械各向异性仍然是大多数关键在役应用的关键问题。研究了通过激光粉末床熔融(L-PBF)制备的Inconel 718的凝固条件与熔池形态之间的关系,以使零件的微观结构特征适应其预期应用。通过优化扫描矢量的长度,可以根据EBSD分析将纹理指数和晶粒度都降低2倍。此外,与传统的L-PBF扫描策略相比,纵横比和晶粒密度可以分别增加1.1和2.2倍。这些成就为生产完全各向同性零件和/或由L-PBF工艺控制的各向异性零件铺平了道路。
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引用次数: 2
Influence of defects on damage tolerance of Metal-Injection-Molded β titanium alloys under static and dynamic loading 缺陷对金属注射成型β钛合金静态和动态损伤容限的影响
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-06 DOI: 10.1080/00325899.2022.2069077
P. Xu, T. Ebel, F. Pyczak, R. Willumeit-Römer, Sen Yu
ABSTRACT The β titanium alloys are key materials in lightweight and biomedical applications, due to the combination of excellent biocompatibility and mechanical properties. However, the Binder-based Powder Technologies such as Metal-Injection-Molding (MIM), Binder-Jetting and Fused-Filament-Fabrication, normally introduce three major processing-related defects in the as-sintered Ti-parts: (i) residual porosity, (ii) high impurity level and (iii) coarse-grained structure. The previous studies revealed that these processing defects invariably tend to be even more severe in β titanium alloys than in α/β Ti-6Al-4V alloy, all fabricated by powder metallurgical route. In this work, these processing defects and their likely origins in MIM β titanium alloys are analysed. Furthermore, the influence of these defects on damage tolerance and fracture mechanisms of MIM β titanium alloys under either static or dynamic loading is investigated. Based on the studies, strategic technical improvements in the processing to improve the reliability of MIM β titanium alloys products are proposed.
摘要β钛合金具有良好的生物相容性和力学性能,是轻量化和生物医学应用的关键材料。然而,基于粘结剂的粉末技术,如金属注射成型(MIM)、粘结剂喷射和熔丝制造,通常会在烧结后的Ti零件中引入三个主要的加工相关缺陷:(i)残余孔隙率,(ii)高杂质水平和(iii)粗粒结构。先前的研究表明,这些加工缺陷在β钛合金中总是比在α/βTi-6Al-4V合金中更严重,所有这些都是通过粉末冶金方法制造的。本文分析了MIMβ钛合金中的这些加工缺陷及其可能的来源。此外,还研究了这些缺陷对MIMβ钛合金在静态或动态载荷下的损伤容限和断裂机制的影响。在此基础上,提出了提高MIMβ钛合金产品可靠性的工艺技术改进策略。
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引用次数: 0
Friction and wear of cobalt–chromium–nickel–copper alloy in contact with tungsten-carbide-sintered balls 钴铬镍铜合金与碳化钨烧结球接触时的摩擦磨损
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-05-04 DOI: 10.1080/00325899.2022.2071194
Binghua Wu, Jie Wei, Jin-rong Wu, Mao-li Wang
ABSTRACT This paper describes a study of the influence of elemental nickel (Ni) and copper (Cu) elements on the tribological behaviour of a CoCr-based alloy. The tribology of CoCr-based alloys was examined by using a Bruker UMT-TriboLab machine with normal loads of 200 N, a frequency of 3 Hz, and a duration of 10 min. The Co70Cr20Ni5Cu5 alloy with 5wt-% Ni and 5wt-% Cu content showed the best wear property compared with other alloys, with a minimum friction coefficient of 0.147. The large improvement in wear resistance is related to the strongly inhibiting effect of crack initiation and growth in the worn surface, which reduces delamination wear. Because of the Co0.52Cu0.48 plastic deformation layer, hard phases like NiCoCr and CrCo can slip easily on the sliding interface and embed into the matrix, which may decrease delamination wear and reduce the crack growth rate.
本文研究了元素镍(Ni)和铜(Cu)对CoCr基合金摩擦学性能的影响。CoCr基合金的摩擦学是通过使用Bruker UMT TriboLab机器在200 N的正常负载下,频率为3 Hz,持续时间为10 与其他合金相比,Ni含量为5wt%、Cu含量为5wt-%的Co70Cr20Ni5Cu5合金表现出最佳的磨损性能,最小摩擦系数为0.147。耐磨性的大幅提高与磨损表面裂纹萌生和生长的强烈抑制作用有关,这减少了分层磨损。由于Co0.52Cu0.48塑性变形层的存在,像NiCoCr和CrCo这样的硬相可以很容易地在滑动界面上滑动并嵌入基体中,这可以减少分层磨损并降低裂纹扩展速率。
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引用次数: 0
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Powder Metallurgy
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