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Proceedings of ISAF-ECAPD-PFM 2012最新文献

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Observation of nonlinear magnetoelectric response to magnetic pulses in layered magnetostrictive-piezoelectric structures 层状磁致伸缩压电结构对磁脉冲非线性磁电响应的观察
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297739
F. Kreitmeier, I. Schulz, G. Monkman, M. Shamonin, Y. Fetisov, D. Chashin, L. Fetisov
A detailed experimental study of the magnetoelectric response of planar bi- and symmetric trilayer composite structures to magnetic field pulses is reported. The structures consist of layers of commercially available piezoelectric (lead zirconate titanate) and magnetostrictive (permendur or nickel) materials. The magnetic-field pulses have the form of a half-wave sine function with duration of 450 μs and amplitude from 500 Oe up to 38 kOe. The measurement method is explained and the measured time dependence of the resulting voltage is presented. The most interesting case, when pulse amplitudes are sufficiently large (~ 1-10 kOe) and various types of acoustic oscillation with frequencies much larger than the reciprocal pulse length are excited in the structures, is considered. The dependencies of the magnetoelectric voltage coefficient on the excitation frequency and the applied magnetic field are calculated. By digital signal processing the results are compared with those obtained by the method of harmonic field modulation (HFM). The findings are of interest for developing magnetoelectric sensors for pulsed magnetic fields as well as for rapid characterization of magnetoelectric composite structures.
本文报道了平面双、对称三层复合材料结构对磁场脉冲的磁电响应的详细实验研究。该结构由商业上可用的压电(锆钛酸铅)和磁致伸缩(永动机或镍)材料层组成。磁场脉冲为半波正弦函数,持续时间为450 μs,振幅为500 ~ 38 μ e。说明了测量方法,并给出了测量电压的时间依赖性。最有趣的情况是,当脉冲幅值足够大(~ 1-10 kOe),并且在结构中激发了频率远大于脉冲倒数长度的各种类型的声波振荡。计算了磁电电压系数与励磁频率和外加磁场的关系。通过数字信号处理,将所得结果与谐波调制(HFM)方法所得结果进行了比较。这些发现对于开发用于脉冲磁场的磁电传感器以及快速表征磁电复合结构具有重要意义。
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引用次数: 2
Calorimetric study of field-induced ferroelectric transition in Pb(Mg1/3Nb2/3)O3 relaxor ferroelectrics Pb(Mg1/3Nb2/3)O3弛豫铁电体中场致铁电跃迁的量热研究
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297770
N. Novak, Z. Kutnjak
The electric field induced ferroelectric transition was studied by heat capacity measurements in relaxor Pb(Mg1/3Nb2/3)O3 (PMN) single crystal oriented in [110] direction. The modified relaxation measurements allow us to study the thermal response of sample at glassy to ferroelectric transition at isothermal condition. The thermal response of sample show a temperature anomaly at field induced transition as a consequence of the released latent heat.
通过对[110]取向弛豫Pb(Mg1/3Nb2/3)O3 (PMN)单晶的热容测量,研究了电场诱导铁电跃迁。修正的弛豫测量使我们能够研究样品在等温条件下从玻璃到铁电转变的热响应。样品的热响应表明,由于释放的潜热,在场致转变处存在温度异常。
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引用次数: 1
Mapping nanoscale domain patterns in ferroelectric ceramics by atomic force acoustic microscopy and piezoresponse force microscopy 用原子力声显微镜和压响应力显微镜在铁电陶瓷中绘制纳米级畴图
Pub Date : 2012-07-09 DOI: 10.1063/1.4801976
Faxin Li, Xilong Zhou, H. Zeng
In this paper, nanoscale domain patterns of ferroelectric ceramics were investigated by both piezoelectric force microscopy (PFM) and atomic force acoustic microscopy (AFAM) in the same scanning area. The domain patterns imaged by both the single-frequency AFAM and resonance-tracking AFAM are comparable to that by PFM. Meanwhile, using AFAM, the subsurface domain structures can be observed and quantitative nanomechanical mapping of domains was also realized. Finally, we suggest that PFM plus AFAM should be the best choice for characterization of ferroelectric domains.
利用压电力显微镜(PFM)和原子力声显微镜(AFAM)在同一扫描区域内研究了铁电陶瓷的纳米结构。单频AFAM和共振跟踪AFAM成像的畴图与PFM成像的畴图相当。同时,利用AFAM可以观察到表面下的畴结构,并实现了畴的定量纳米力学制图。最后,我们认为PFM + AFAM应该是表征铁电畴的最佳选择。
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引用次数: 11
MOD deposited thin film BST based bulk acoustic wave resonators MOD沉积了基于薄膜BST的体声波谐振器
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297726
T. Kalkur, N. Sbrockey, G. Tompa
A tunable BST solidly mounted bulk resonator has been designed, fabricated and characterized using vector network analyzer. The solidly mounted resonator was implemented using an acoustic Bragg reflector of alternating high impedance tantalum oxide and low impedance silicon layers. The films were deposited using spin-on MOD technique. The resonator demonstrated a frequency tunability of 1% for an applied bias voltage from 3V to 10V with a shift in resonance frequency from 4.232179 GHz to 4.184941 GHz. The quality factor of the resonator was found to depend on the applied bias and a maximum quality factor of 97 was obtained at a DC bias voltage of 10 volts.
设计、制作了一种可调谐的BST实心体谐振器,并利用矢量网络分析仪对其进行了表征。该谐振器采用高阻抗氧化钽和低阻抗硅层交替的声学布拉格反射器。采用自旋MOD技术沉积薄膜。当施加的偏置电压从3V到10V时,谐振器的频率可调性为1%,谐振频率从4.232179 GHz移至4.184941 GHz。发现谐振器的质量因数取决于施加的偏置,在10伏直流偏置电压下获得的最大质量因数为97。
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引用次数: 2
The influence “heating-cooling” process rate on temperature hysteresis of ferroelectric capasitor structures “加热-冷却”过程速率对铁电电容器结构温度滞后的影响
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297838
A. Dedyk, Y. Pavlova, A. Semenov, A. Eskov, P. Beliavskiy, I. Mylnikov, O. Pakhomov, A. Starkov, I. Starkov
We have investigated the influence of the time mode of cooling, electric field and electroconductivity on the thermal hysteresis in capacitor structures based on ceramics Ba0.55Sr0,45TiO3 with 12 wt.% magnesium-containing supplements. Different mechanisms of the appearance of thermal hysteresis are discussed.
研究了在含镁量为12 wt.%的Ba0.55Sr0,45TiO3陶瓷材料中,冷却时间模式、电场和电导率对电容器结构热滞后的影响。讨论了热滞后产生的不同机理。
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引用次数: 0
Piezoelectric enhancement of relaxor-based lead-free piezoelectric ceramics by nanodomain engineering 基于纳米畴工程的弛豫基无铅压电陶瓷的压电增强
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297767
I. Fujii, R. Mitsui, K. Nakashima, N. Kumada, S. Wada, H. Yabuta, M. Shimada, T. Watanabe, K. Miura
0.3BaTiO3-0.1Bi(Mg1/2Ti1/2)O3-0.6BiFeO3 ceramics were either doped with vanadium or sintered in calcined powder with the same composition. Compared to an undoped ceramic sintered without the calcined powder, both ceramics showed reduced leakage current densities (lower than 1 × 10-7 A/cm2) and absence of dielectric relaxation behaviors observed in frequency-and temperature-dependent dielectric measurements. The Curie temperatures of both samples were higher than 460 °C. The maximum field-induced strain over the applied field, Smax/Emax, of 366 pm/V of the undoped ceramic sintered without the calcined powder increased to 455 and 799 pm/V for the V-doped sample and the sample sintered with the calcined powder, respectively. The increase was related to a reduced concentration of bismuth vacancy - oxygen vacancy defect dipoles.
batio3 -0.1 bi (Mg1/2Ti1/2)O3-0.6BiFeO3陶瓷分别掺杂钒或在相同成分的煅烧粉末中烧结。与没有煅烧粉末的未掺杂陶瓷相比,两种陶瓷的泄漏电流密度都降低(低于1 × 10-7 A/cm2),并且在频率和温度相关的介电测量中观察到没有介电弛豫行为。两种样品的居里温度均高于460℃。未掺V和掺V的烧结陶瓷的最大场致应变Smax/Emax分别从366 pm/V和799 pm/V增加到455 pm/V。这种增加与铋空位-氧空位缺陷偶极子的浓度降低有关。
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引用次数: 0
Soft mechanochemical synthesis and characterization of nanodimensional spinel ferrites 纳米尖晶石铁氧体的软机械化学合成与表征
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297730
Z. Lazarević, A. Milutinović, M. Romčević, N. Romčević, Č. Jovalekić, D. Sekulić, M. Slankamenac
NiFe2O4 and ZnFe2O4 ferrites have been prepared by soft mechanochemical synthesis. The sintered samples were analyzed by XRD and Raman spectroscopy. Investigation of the magnetization as a function of magnetic field confirms an expected change of the degree of inversion in the spinel structure with the sintering. Impedance spectroscopy on the sintered pellets of ferrites was performed in the wide frequency range (100 Hz-10 MHz) at different temperatures using an Impedance/Gain-Phase Analyzer (HP-4194).
采用软机械化学合成方法制备了NiFe2O4和ZnFe2O4铁氧体。采用XRD和拉曼光谱对烧结样品进行了分析。磁化强度随磁场变化的研究证实了尖晶石结构反转程度随烧结的变化。利用阻抗/增益相位分析仪(HP-4194)对烧结铁氧体球团在不同温度下的宽频率范围(100 Hz-10 MHz)进行阻抗谱分析。
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引用次数: 1
Lithium niobate-tantalate mixed crystals electronic and optical properties calculated from first principles 从第一性原理计算铌酸锂-钽酸锂混合晶体的电子和光学性质
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297797
A. Riefer, S. Sanna, W. Schmidt
The electronic and optical properties of the mixed-crystal system lithium niobate-tantalate has been calculated from first principles. Based on density functional theory we calculate the electronic properties including quasiparticle effects within the GW approach. The optical response including electron-hole attraction effects is obtained from the solution of the Bethe-Salpeter equation. While the band gap increase with increasing tantalum content and shows some bowing, a nearly linear dependence of the optical birefringence on the stochiometry is calculated.
从第一性原理计算了铌酸锂-钽酸锂混合晶体体系的电子和光学性质。基于密度泛函理论,我们计算了包括准粒子效应在内的电子性质。由贝特-萨尔皮特方程的解得到了包含电子-空穴吸引效应的光学响应。虽然带隙随钽含量的增加而增加,并呈现一定的弯曲,但计算出光学双折射与化学计量的近似线性关系。
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引用次数: 0
Fabrication of Li-doped ZnO nanoparticles in aqueous solution and their ferroelectricity-like behavior 水溶液中掺锂氧化锌纳米颗粒的制备及其类铁电性
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297720
Jianbo Yin, Gengmin Zhang
Li-doped ZnO nanoparticles were fabricated in aqueous solution of zinc nitrate and hexamethylenetetramine (HMTA) to which lithium chloride was added. SEM, XRD and TEM results revealed that the as-synthesized nanoparticles were crystalline wurzite ZnO with hexagonal flake morphology. ICP analysis confirmed the existence of Li element in these ZnO nanoparticles. For the measurement on their dielectric properties, the nanoparticles were further annealed in air under 900°C for 1 hour and then pressed into tablets under a pressure of 5×103 kg/cm2. When voltage cycles with varying magnitude were applied to these tablets of the Li-doped ZnO nanoparticles, the dependence of the polarization versus the applied field turned out to be hysteresis loops. The remanent polarizations and coercive fields were measured to be 10-5 to 10-4 Cm-2 and 104 to 105 Vm-1 order of magnitude, respectively. Since a variety of phenomena other than ferroelectricity would also lead to hysteresis loops, similar measurements for comparison were further performed with a view to probing the origin of the observed loops. The dielectric behaviors of ZnO nanoparticles fabricated in the Li-free solutions and the commercial ZnO particles were also measured and the polarization-field plots both appeared to be straight lines instead of loops.
在硝酸锌和六亚甲基四胺(HMTA)的水溶液中加入氯化锂制备了li掺杂ZnO纳米颗粒。SEM、XRD和TEM结果表明,合成的纳米颗粒为六方鳞片状的纤锌矿ZnO晶体。ICP分析证实了ZnO纳米颗粒中Li元素的存在。为了测量其介电性能,将纳米颗粒在900℃空气中进一步退火1小时,然后在5×103 kg/cm2的压力下压成片剂。当不同幅度的电压循环作用于这些li掺杂ZnO纳米颗粒片时,极化与外加电场的依赖关系被证明是滞后回路。剩余极化和矫顽力场分别为10-5 ~ 10-4 Cm-2和104 ~ 105 Vm-1数量级。由于除铁电性以外的各种现象也会导致磁滞回线,因此进一步进行了类似的比较测量,以探测所观察到的磁滞回线的起源。测量了制备的ZnO纳米粒子在无锂溶液和商用ZnO粒子中的介电行为,极化场图都是直线而不是环路。
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引用次数: 0
Influence of additives with low melting temperatures on structure, microstructure, phase transitions and dielectric properties of BiScO3-PbTiO3 ceramics 低温添加剂对BiScO3-PbTiO3陶瓷结构、微观结构、相变和介电性能的影响
Pub Date : 2012-07-09 DOI: 10.1109/ISAF.2012.6297731
E. Politova, G. Kaleva, A. V. Mosunov, N. Sadovskaya, A. G. Segalla
Ceramic solid solutions on base of 0.36BiScO3 -0.64PbTiO3 compositions doped by additives Bi2O3, Ni2O3, MnO2, and LiF with low melting temperatures were prepared by the solid state reaction method. Phase formation, microstructure and dielectric properties of modified ceramics were studied. Dense single phase samples characterized by the average grain size varied from submicron till tens mm were obtained at lower temperatures. Influence of additives on dielectric properties and on the effects of dielectric relaxation was revealed.
采用固相反应法制备了0.36BiScO3 -0.64PbTiO3复合材料的陶瓷固溶体,其中Bi2O3、Ni2O3、MnO2和LiF等添加剂在低温下掺杂。研究了改性陶瓷的相形成、微观结构和介电性能。在较低温度下获得了平均晶粒尺寸从亚微米到几十毫米不等的致密单相样品。揭示了添加剂对介电性能和介电弛豫效应的影响。
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引用次数: 0
期刊
Proceedings of ISAF-ECAPD-PFM 2012
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