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Catalyst innovations and mechanism in photocatalytic dry reforming of methane: Recent advances and perspectives 甲烷光催化干重整催化剂创新及其机理研究进展与展望
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-03 DOI: 10.1016/j.psep.2026.108550
Osarieme Uyi Osazuwa , Kim Hoong Ng , Dai-Viet N. Vo , Yoke Wang Cheng
Dry reforming of methane (DRM) converts CH4 and CO2 into valuable syngas, offering environmental benefits and a practical route to exploit carbon capture streams. However, its endothermic nature and coking severely limit scalability. To overcome this, photocatalytic dry reforming of methane (PDRM) harnesses photon energy, boosting activity and stability under milder conditions. In pursuit of effective PDRM catalysts, a wide range of catalyst designs have been explored, such as metal‑on‑mixed‑oxide, metal‑on‑oxide, metal‑on‑mixed‑support, metal‑on‑oxide heterojunctions, encapsulated‑metal/zeolite (core‑shell) structures, engineered support structures, multi‑metallic alloys on 2‑D heterostructures, perovskites, metal‑on‑perovskite, 2D‑2D carbon‑based hybrids, metal‑free porous organic polymers, morphology‑controlled oxide supports, and bimetallic catalysts on carbon‑oxide composites. Building on this design diversity, case studies show impressive results. For instance, a Rh#CeO2 nanocomposite with an intertwined ≈ 5 nm Rh‑CeO2 network and a 2.7 eV bandgap achieved >60 % CH4 conversion, remained stable for >100 h, and showed no side reactions under UV light. Further reviews uncovered a range of pathways such as oxygen-vacancy mediation, charge-separated redox, dual-site charge-separated redox, Z‑scheme charge transfer, Schottky-barrier assistance, dual-site push‑pull charge transfer, hot‑carrier/near-field enhancement, carbonate-mediated bifunctional route, and HCOO-intermediate pathway highlighting how these mechanisms collectively enable efficient, sustainable syngas production under mild conditions and paving the way for further PDRM advances.
甲烷干重整(DRM)将CH4和CO2转化为有价值的合成气,提供了环境效益和开发碳捕获流的实用途径。然而,它的吸热性质和结焦严重限制了可扩展性。为了克服这个问题,光催化甲烷干重整(PDRM)利用光子能量,在较温和的条件下提高活性和稳定性。为了追求有效的PDRM催化剂,已经探索了各种各样的催化剂设计,例如金属- on -混合氧化物、金属- on -氧化物、金属- on -混合载体、金属- on -氧化物异质结、封装金属/沸石(核壳)结构、工程支撑结构、2D异质结构上的多金属合金、钙钛矿、金属- on -钙钛矿、2D - 2D碳基杂化物、无金属多孔有机聚合物、形态控制的氧化物载体、以及碳氧化物复合材料上的双金属催化剂。基于这种设计多样性,案例研究显示了令人印象深刻的结果。例如,具有缠绕≈ 5 nm的Rh - CeO2网络和2.7 eV带隙的Rh#CeO2纳米复合材料实现了>;60 %的CH4转化率,在>;100 h内保持稳定,并且在紫外光下没有副反应。进一步的综述揭示了一系列的途径,如氧空位介导、电荷分离氧化还原、双位点电荷分离氧化还原、Z - scheme电荷转移、schottkey势垒辅助、双位点推拉电荷转移、热载流子/近场增强、碳化物介导的双功能途径和hco -中间体途径,强调了这些机制如何共同实现在温和条件下高效、可持续的合成气生产,并为PDRM的进一步发展铺平了道路。
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引用次数: 0
Improved remediation mechanism of groundwater circulation wells based on ultrasonic permeability enhancement 基于超声增渗的地下水循环井改进修复机制
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-03 DOI: 10.1016/j.psep.2026.108530
Yan Zhao , Liu Yang , Siyuan Li , Mingxiu Ji , Ruipeng Dong
Global groundwater systems face escalating organic contamination crises, threatening ecological security and human health. Groundwater circulation well (GCW) technology, an innovative in-situ remediation approach, uses hydraulic circulation to mobilize contaminants and synergizes with chemical oxidation for enhanced degradation. However, its practical application faces critical challenges, including a restricted remediation radius of influence, uneven oxidant distribution, and persistent contamination residues caused by preferential flow bypassing low-permeability zones. Theoretical evidence suggests that ultrasound technology could overcome these limitations through cavitation and mechanical vibrations, resulting in the restructuring of pore structure. While proven effective in enhancing the permeability of consolidated rock formations, the synergistic mechanisms between ultrasound and GCW systems, particularly in sandy aquifers, remain systematically unverified. This study systematically elucidates the mechanisms underlying ultrasound-enhanced GCW remediation through an integrated multi-scale experimental framework: (1) Microstructural characterization through NMR-coupled column experiments quantifying porosity and hydraulic conductivity enhancement; (2) Mesoscale transport analysis employing 2D sandbox simulations to investigate the expansion mechanisms of remediation radius under ultrasound-GCW coupled operation; and (3) Synergistic investigation through an innovative ultrasound-GCW-chemical oxidation system evaluating degradation efficiency and interaction mechanisms. This study confirms the permeability enhancement effect of ultrasonic stimulation in unconsolidated aquifers and demonstrates the improved contaminant remediation effectiveness of the GCW-ultrasound coupled system. These findings not only significantly expand the engineering application prospects of GCW-coupled remediation technology but also provide theoretical and technical support for the effective treatment of organic pollution in low-permeability zone aquifers.
全球地下水系统面临着不断升级的有机污染危机,威胁着生态安全和人类健康。地下水循环井(GCW)技术是一种创新的原位修复方法,利用水力循环来调动污染物,并与化学氧化协同作用以增强降解。然而,它的实际应用面临着严峻的挑战,包括修复影响半径有限,氧化剂分布不均匀,以及由于优先流绕过低渗透层而导致的持久性污染残留。理论证据表明,超声技术可以通过空化和机械振动来克服这些限制,从而导致孔隙结构的重组。虽然已被证明在提高固结岩层的渗透率方面是有效的,但超声波和GCW系统之间的协同机制,特别是在砂质含水层中,仍未得到系统的验证。本研究通过集成的多尺度实验框架,系统阐明超声增强GCW修复的机制:(1)通过核磁共振耦合柱实验表征微观结构,量化孔隙度和水力导率的增强;(2)利用二维沙盒模拟中尺度输运分析,探讨超声- gcw耦合作用下修复半径的扩展机制;(3)通过创新的超声- gcw -化学氧化系统进行协同研究,评估降解效率和相互作用机制。本研究证实了超声刺激在疏松含水层中的增渗效果,证明了超声-超耦合系统对污染物的修复效果有所提高。这些发现不仅显著拓展了gcw耦合修复技术的工程应用前景,也为有效治理低渗透带含水层有机污染提供了理论和技术支持。
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引用次数: 0
Data-driven multi-objective optimization for process-safe and sustainable finish milling of P20 tool steel P20工具钢工艺安全可持续精铣多目标优化
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-08 DOI: 10.1016/j.psep.2026.108556
Van-Canh Nguyen , Ngoc-Linh Pham , The-Anh Cao , Nhat-Tan Nguyen , Nguyen Anh Thang , Nhu-Trang Le , Thuy-Duong Nguyen
This study proposes a hybrid data-driven framework for multi-objective optimization in finish milling of P20 tool steel molds, with focus on both process safety and environmental protection. The proposed framework combines Gaussian Process Regression (GPR) surrogate modeling, resampling-based data augmentation, and Bayesian multi-objective optimization to simultaneously minimize surface roughness (Ra, Rz) and specific cutting energy (SCE). The resampling-based data augmentation expanded the original experimental dataset (n = 16) to about six times, which significantly improve the accuracy and robustness of surrogate models. As a result, the GPR models achieved high prediction performance with R² values of 0.8680 for Ra, 0.9211 for Rz, and 0.9888 for SCE, while the corresponding MAPE values were 3.25 %, 4.45 %, and 14.73 %, respectively. In addition, Random Forest regression combined with SHAP analysis showed that cutting speed (Vc) is the most influential parameter for Ra prediction (43.4 % importance), whereas depth of cut (ap, 30.4 %) and width of cut (ae, 33.6 %) mainly control SCE, which provide useful guidance for parameter selection. Bayesian multi-objective optimization identified Pareto-optimal cutting conditions (Vc = 40 m/min, fz = 0.07–0.13 mm/tooth, ap = 0.5–2.0 mm, ae = 5.1–8.5 mm) that achieved fine surface quality (Ra = 0.55–0.65 µm) while reducing SCE by up to 92.4 % compared to baseline conditions. Experimental validation confirmed good predictive accuracy, with mean absolute errors below 5 % for surface roughness and about 7 % for energy consumption. For a typical P20 mold cavity with 500 cm³ material removal, the optimized parameters can save 0.099 kWh energy and reduce 0.056 kg CO₂ per part, leading to significant annual saving for industrial production. Process safety analysis also indicated that the optimized conditions maintain spindle load below 5 % of rated capacity, increase tool safety factor above 2.0–5.0, and reduce thermal load by 85–92 %, therefore reducing risks of tool failure, machine damage, and fire hazard. Overall, this study provides a practical and data-efficient optimization approach for sustainable and safe mold manufacturing.
本研究提出了一种混合数据驱动的P20工具钢模具精铣多目标优化框架,同时关注工艺安全和环境保护。该框架结合高斯过程回归(GPR)代理建模、基于重采样的数据增强和贝叶斯多目标优化,同时最小化表面粗糙度(Ra, Rz)和比切削能量(SCE)。基于重采样的数据增强将原始实验数据集(n = 16)扩展到约6倍,显著提高了代理模型的准确性和鲁棒性。结果表明,GPR模型对Ra、Rz和SCE的R²值分别为0.8680、0.9211和0.9888,对应的MAPE值分别为3.25 %、4.45 %和14.73 %,具有较好的预测效果。此外,随机森林回归结合SHAP分析表明,切割速度(Vc)对Ra预测的影响最大(43.4 %),而切割深度(ap, 30.4 %)和切割宽度(ae, 33.6 %)主要控制SCE,为参数选择提供了有益的指导。贝叶斯多目标优化确定了帕累托最优切削条件(Vc = 40 m/min, fz = 0.07-0.13 mm/齿,ap = 0.5-2.0 mm, ae = 5.1-8.5 mm),获得了良好的表面质量(Ra = 0.55-0.65 µm),与基线条件相比,SCE降低了92.4 %。实验验证证实了良好的预测精度,表面粗糙度的平均绝对误差低于5 %,能量消耗的平均绝对误差约为7 %。对于一个典型的P20模腔,材料去除量为500 cm³ ,优化后的参数可以节省0.099千瓦时的能源,每个零件减少0.056 kg的CO₂,为工业生产带来显著的年度节省。工艺安全分析还表明,优化后的工艺条件使主轴负荷保持在额定容量的5% %以下,刀具安全系数提高到2.0 ~ 5.0以上,热负荷降低85 ~ 92% %,从而降低了刀具失效、机床损坏和火灾危险的风险。总体而言,本研究为可持续和安全的模具制造提供了一种实用且数据高效的优化方法。
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引用次数: 0
A cloud–edge–device collaboration based propagation path identification framework for faults in nonlinear dynamic industrial processes 基于云-边缘设备协同的非线性动态工业过程故障传播路径识别框架
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-12 DOI: 10.1016/j.psep.2026.108603
Liang Ma, Yifei Peng, Kaixiang Peng
Propagation path identification is an important part of fault diagnosis. It is often used to identify the propagation paths and locate the root causes of faults, which provides information supports for safety assurance and operating maintenance of industrial processes. Nonlinear causalities are common in dynamic industrial processes due to the strong couplings among subsystems and physical properties. When a fault occurs suddenly, its impact is often propagated with delay along causalities, resulting in lags of abnormal responses for related subsystems or control loops. Meanwhile, in high-dimensional industrial processes, traditional methods are prone to the problems of poor efficiency and accuracy, thus compromising process safety. Inspired by those problems, in this paper, a new cloud–edge–device collaboration based propagation path identification framework is proposed for faults in nonlinear dynamic industrial processes. Firstly, the multi-order lag encoder based graph convolutional network is proposed to extract the lag causality features of variables, and thus realizing nonlinear causality analysis by the spatial–temporal information. Secondly, the time-varying dynamic Bayesian network is constructed to identify the propagation paths and predict the future propagation directions of faults by combining the above algorithm and Bayesian estimation. Then, static Bayesian networks of edges and time-varying dynamic Bayesian network of cloud are constructed by the cloud–edge–device collaborative framework for causality analysis of high-dimensional time series and efficiency improvement of propagation path identification. Finally, three datasets from hot rolling process and Tennessee Eastman process are used to verify the accuracy and efficiency of the proposed framework.
传播路径识别是故障诊断的重要组成部分。它通常用于识别故障的传播路径和定位故障的根本原因,为工业过程的安全保障和运行维护提供信息支持。由于子系统和物理特性之间的强耦合,非线性因果关系在动态工业过程中很常见。当故障突然发生时,其影响往往随因果关系的延迟而传播,导致相关子系统或控制回路的异常响应滞后。同时,在高维工业过程中,传统的方法容易出现效率和精度不高的问题,从而影响了过程的安全性。受这些问题的启发,本文提出了一种新的基于云-边缘设备协同的非线性动态工业过程故障传播路径识别框架。首先,提出了基于多阶滞后编码器的图卷积网络,提取变量的滞后因果关系特征,利用时空信息实现非线性因果关系分析;其次,将上述算法与贝叶斯估计相结合,构建时变动态贝叶斯网络,识别故障的传播路径,预测故障未来的传播方向;然后,通过云-边缘-设备协同框架构建静态边缘贝叶斯网络和时变动态云贝叶斯网络,实现高维时间序列因果分析和传播路径识别效率提升;最后,利用热轧过程和田纳西伊士曼过程的三个数据集验证了所提框架的准确性和有效性。
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引用次数: 0
A safety analysis of the cryo-compressed effect on hydrogen leakage behavior in hydrogen refueling station 低温压缩对加氢站氢气泄漏行为影响的安全性分析
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-17 DOI: 10.1016/j.psep.2026.108628
Hao Wang , Chaoya Guo , Hao Wang , Kun Liu , Tianjiao Bi , Chunjie Sui , Bin Zhang , Feng Zhu , Jieyu Jiang
Cryo-compressed hydrogen (CcH2) storage technology is a promising method for storing hydrogen on a large scale, but once accidental leak occurs, it will cause significant risks such as fire, explosion and secondary disasters. This study investigates the safety risks of CcH2 leakage in hydrogen refueling stations, emphasizing the unique safety implications of cryogenic hydrogen including cryogenic injuries, fire and explosion risks, and other thermal hazards. Numerical simulations are carried out considering different storage temperatures from 70 K to 300 K and pressures from 40 MPa to 80 MPa. Results show that a larger flammable cloud is formed in the case of CcH2 leakage, and the cryogenic injury area (CIA) below 233 K near blast wall is prolonged, exacerbating frostbite risks. This is attributed to the decreased thermal kinetic energy and increased density of CcH2. In the event of explosion, the duration time of high temperature near the blast wall increases with decreasing hydrogen storage temperature. This indicates dual risks of frostbite and high temperature by combustion in CcH2 systems. Additionally, a lower explosion overpressure peak (0.4475 bar at 70 K) is generated and multiple pressure peaks are observed near blast wall. It is worth noting that the pressure peak of a cryogenic hydrogen explosion is only 0.02 times that at normal temperature, which is below the lethal pressure, significantly reducing lethal injury risks. Based on the consequences and risk analysis, the corresponding protective measures are recommended, such as installing exhaust fans on blast wall to accelerate cryogenic hydrogen dispersion and reduce explosion risks.
低温压缩氢(CcH2)储氢技术是一种很有前途的大规模储氢方法,但一旦发生意外泄漏,将造成火灾、爆炸和次生灾害等重大风险。本研究探讨了加氢站CcH2泄漏的安全风险,强调了低温氢气的独特安全含义,包括低温伤害、火灾和爆炸风险以及其他热危害。在70K ~ 300K的不同存储温度和40MPa ~ 80MPa的不同存储压力下进行了数值模拟。结果表明:CcH2泄漏时形成较大的可燃云,延长了233K以下近爆壁低温损伤区(CIA),加剧了冻伤风险;这是由于CcH2的热动能降低和密度增加所致。爆炸时,随着储氢温度的降低,爆炸壁附近高温持续时间增加。这表明在CcH2系统中燃烧会产生冻伤和高温的双重风险。此外,在70K时产生了较低的爆炸超压峰值(0.4475bar),并且在爆炸壁附近观察到多个压力峰值。值得注意的是,低温氢气爆炸的压力峰值仅为常温下的0.02倍,低于致死压力,显著降低了致死性伤害风险。根据后果和风险分析,建议采取相应的防护措施,如在爆炸壁上安装排风机,加速低温氢气的扩散,降低爆炸风险。
{"title":"A safety analysis of the cryo-compressed effect on hydrogen leakage behavior in hydrogen refueling station","authors":"Hao Wang ,&nbsp;Chaoya Guo ,&nbsp;Hao Wang ,&nbsp;Kun Liu ,&nbsp;Tianjiao Bi ,&nbsp;Chunjie Sui ,&nbsp;Bin Zhang ,&nbsp;Feng Zhu ,&nbsp;Jieyu Jiang","doi":"10.1016/j.psep.2026.108628","DOIUrl":"10.1016/j.psep.2026.108628","url":null,"abstract":"<div><div>Cryo-compressed hydrogen (CcH<sub>2</sub>) storage technology is a promising method for storing hydrogen on a large scale, but once accidental leak occurs, it will cause significant risks such as fire, explosion and secondary disasters. This study investigates the safety risks of CcH<sub>2</sub> leakage in hydrogen refueling stations, emphasizing the unique safety implications of cryogenic hydrogen including cryogenic injuries, fire and explosion risks, and other thermal hazards. Numerical simulations are carried out considering different storage temperatures from 70 K to 300 K and pressures from 40 MPa to 80 MPa. Results show that a larger flammable cloud is formed in the case of CcH<sub>2</sub> leakage, and the cryogenic injury area (CIA) below 233 K near blast wall is prolonged, exacerbating frostbite risks. This is attributed to the decreased thermal kinetic energy and increased density of CcH<sub>2</sub>. In the event of explosion, the duration time of high temperature near the blast wall increases with decreasing hydrogen storage temperature. This indicates dual risks of frostbite and high temperature by combustion in CcH<sub>2</sub> systems. Additionally, a lower explosion overpressure peak (0.4475 bar at 70 K) is generated and multiple pressure peaks are observed near blast wall. It is worth noting that the pressure peak of a cryogenic hydrogen explosion is only 0.02 times that at normal temperature, which is below the lethal pressure, significantly reducing lethal injury risks. Based on the consequences and risk analysis, the corresponding protective measures are recommended, such as installing exhaust fans on blast wall to accelerate cryogenic hydrogen dispersion and reduce explosion risks.</div></div>","PeriodicalId":20743,"journal":{"name":"Process Safety and Environmental Protection","volume":"209 ","pages":"Article 108628"},"PeriodicalIF":7.8,"publicationDate":"2026-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146209403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the use of machine learning for the development of an acoustic-based detection system for early-stage thermal runaway 利用机器学习开发基于声学的早期热失控检测系统
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-18 DOI: 10.1016/j.psep.2026.108617
Wai Cheong Tam , MD. Ismail Siddiqi Emon , Jian Chen , Hongqiang Fang , Jun Deng , Anthony Putorti Jr
The paper presents the development of a multi-class classification model for detecting early-stage thermal runaway events in button-top single-cell lithium-ion batteries. A signal gate mechanism is introduced to extract relevant acoustic data. A data alignment technique is applied to enhance the model training. A multi-layer, two-dimensional convolutional neural network is employed to learn the key features that distinguish non-thermal runaway events from thermal runaway events. Results show that the proposed model can detect thermal runaway events with an overall accuracy, precision, and recall of 99.8 %, 98.1 %, and 98.3 %, respectively. Sensitivity studies are conducted and the results indicate that the data alignment and data augmentation techniques help to enhance the model performance significantly. The findings presented in this paper aim to contribute to the development of a practical and accurate early-stage thermal runaway detection model, which can enhance process safety and risk engineering strategies by providing earlier warnings before thermal runaway occurs.
提出了一种用于纽扣式单芯锂离子电池早期热失控事件检测的多类分类模型。引入信号门机制提取相关声学数据。采用数据对齐技术加强模型训练。采用多层二维卷积神经网络学习区分非热失控事件和热失控事件的关键特征。结果表明,该模型能够有效地检测出热失控事件,其总体准确度、精密度和召回率分别为99.8% %、98.1% %和98.3% %。进行了敏感性研究,结果表明数据对齐和数据增强技术有助于显著提高模型性能。本文的研究结果旨在为建立一个实用和准确的早期热失控检测模型做出贡献,该模型可以通过在热失控发生之前提供早期预警来增强过程安全和风险工程策略。
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引用次数: 0
Evaluation of passive fire protection installation methods: Full-scale LNG fire testing of 3-sided and 4-sided coated structure beams 被动防火装置方法的评价:三面和四面涂覆结构梁的全尺寸LNG防火试验
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-10 DOI: 10.1016/j.psep.2026.108589
Mitchell Huffman , Chi-Yang Li , Jazmine Aiya D. Marquez , Zihao Wang , Bryant Hendrickson , Thomas Butts , Filippo Gavelli , Qingsheng Wang
Passive Fire Protection (PFP) plays a critical role in minimizing the risks of liquefied natural gas (LNG) spills and fire hazards in processing and storage facilities. One common PFP strategy for LNG structures is the use of fire-resistant coatings. In this study, two one-hour LNG pool fire tests were conducted in a 10-ft by 10-ft pit to evaluate the thermal response of PFP-coated structural beams. The beams were coated with three different PFP systems, including cementitious, foam, and epoxy. The objective was to generate data for evaluating thermal response models and to compare the thermal performance of beams coated on all surfaces (as typically done in standardized testing) versus beams coated only on three sides, leaving the top flange uncoated (as commonly seen in installed equipment). During the tests, the PFP-coated beams were exposed to direct flame impingement from an LNG pool fire for one hour. Results showed that the 3-sided coating configuration led to higher maximum steel temperatures compared to the 4-sided coating due to the absence of thermal resistance on the exposed top flange. When compared to industry-standard thresholds for permissible heating, local temperature readings from the 3-sided coating were found to exceed the limits; however, cross-sectional average temperatures remained within those limits in two out of three cases. These findings have important implications for the insulation of structural beams in the LNG industry, emphasizing the need for comprehensive coating strategies to ensure structural integrity in pool fire scenarios.
被动防火(PFP)在最大限度地降低液化天然气(LNG)泄漏和处理和储存设施火灾风险方面发挥着关键作用。LNG结构常见的PFP策略是使用防火涂层。在这项研究中,在一个10英尺× 10英尺的坑中进行了两次一小时的LNG池火灾测试,以评估pfp涂层结构梁的热响应。梁涂有三种不同的PFP系统,包括水泥、泡沫和环氧树脂。目的是生成用于评估热响应模型的数据,并比较在所有表面涂覆的梁(通常在标准化测试中进行)与仅在三面涂覆的梁(顶部法兰未涂覆)的热性能(在已安装的设备中常见)。在测试过程中,pfp涂层梁暴露在LNG池火的直接火焰冲击下一小时。结果表明,由于在暴露的顶部法兰上没有热阻,与4面涂层相比,3面涂层配置导致钢的最高温度更高。当与允许加热的行业标准阈值进行比较时,发现三面涂层的局部温度读数超过了限制;然而,在三分之二的情况下,截面平均温度保持在这些限制范围内。这些发现对LNG行业结构梁的绝缘具有重要意义,强调需要综合涂层策略来确保池火场景下的结构完整性。
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引用次数: 0
Metabolic basis and ecological stability of bioaugmented AO-MBR treating low-temperature toilet wastewater: Linking functional genes, pathway efficiency, and microbial dynamics 生物增强AO-MBR处理低温厕所废水的代谢基础和生态稳定性:连接功能基因、途径效率和微生物动力学
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-13 DOI: 10.1016/j.psep.2026.108595
LIU Fuyao , QIU Fuguo , TIAN Hongyu , LIU Jianwei
This study addressed the issue of performance degradation in toilet wastewater treatment systems under low-temperature conditions by constructing a bio-enhanced anaerobic-aerobic membrane bioreactor (AO-MBR) system.Through inoculation of low-temperature-adapted microbial communities, the system's treatment performance, sludge characteristics, and microbial community response mechanisms were systematically evaluated under gradient temperature reduction (16℃→8℃). The bioaugmented reactor (S1) achieved COD, NH4+ -N, and TN removal efficiencies of 85.5 %, 87.6 %, and 67.8 %, respectively, which were higher than those of the control reactor (S2: 76.6 %, 75.1 %, and 54.8 %). Low-temperature microbial enhancement effectively improved sludge settleability, reduced the sludge volume index (SVI), and enhanced system resilience to low-temperature loads by promoting the secretion of proteins and polysaccharides in extracellular polymeric substances (EPS). Microbial community analysis revealed enrichment of cold-tolerant functional genera such as Acinetobacter and Flavobacterium in S1. Metabolic function prediction indicated significantly increased abundances of genes related to carbohydrate metabolism, nitrogen metabolism, and stress response. These findings elucidate the synergistic metabolic mechanisms and ecological stability of the bioaugmented AO-MBR system. The results provide theoretical and practical support for the engineering application of microbial enhancement technology in low-temperature toilet wastewater treatment.
本研究通过构建生物增强型厌氧-好氧膜生物反应器(AO-MBR)系统,解决了低温条件下厕所污水处理系统性能下降的问题。通过接种低温适应微生物群落,系统评价了梯度降温(16℃→8℃)条件下该系统的处理性能、污泥特性及微生物群落响应机制。生物增强反应器(S1)对COD、NH4+ -N和TN的去除率分别为85.5 %、87.6% %和67.8% %,高于对照反应器(S2: 76.6% %、75.1% %和54.8% %)。低温微生物强化通过促进细胞外聚合物质(EPS)中蛋白质和多糖的分泌,有效改善污泥沉降性,降低污泥体积指数(SVI),增强系统对低温负荷的恢复能力。微生物群落分析显示S1中富集了耐冷功能属如不动杆菌和黄杆菌。代谢功能预测显示,与碳水化合物代谢、氮代谢和应激反应相关的基因丰度显著增加。这些发现阐明了生物增强型AO-MBR系统的协同代谢机制和生态稳定性。研究结果为微生物强化技术在低温厕所污水处理中的工程应用提供了理论和实践支持。
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引用次数: 0
Dissolution-complexation of steel slag containing alcoholic amine compounds and its hydration properties in composite cement 含醇胺钢渣在复合水泥中的溶解络合及其水化性能
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-12 DOI: 10.1016/j.psep.2026.108576
Jihui Zhao , Jie Liu , Hongjin Zhong , Lu Luo , Huali He , Haijiao Xie
Steel slag (SS), a major solid waste from the iron and steel industry, possesses a chemical composition similar to Portland cement and exhibits latent hydraulic activity. This study investigated the effects of triethanolamine (TEA) and triisopropanolamine (TIPA), used as complexing agents, on SS dissolution and the performance of SS-cement based materials in a simulated cement pore solution (Ca(OH)2 and 0.2 mol/L NaOH). Results demonstrated that a) TEA exhibited stronger complexation capabilities towards Ca2 + and Fe3+, b) TIPA accelerated the precipitation of hydration products, notably promoting the formation of ettringite. The fundamental difference in Ca2+ complexation ability between TEA and TIPA stems from the influence of their spatial configurations. In the SS-cement system, both complexing agents significantly enhanced the early-age mechanical properties. However, TIPA had a more pronounced effect on later-age strength development. This was attributed to the unique effects by TIPA in improving and optimizing SS-PC pastes pore structure. Furthermore, both agents not only promoted the hydration of mineral phases within both the SS and cement but also facilitated the pozzolanic reaction between the amorphous phase of SS and CH.
钢渣(SS)是钢铁工业的主要固体废物,具有与硅酸盐水泥相似的化学成分,并表现出潜在的水力活性。研究了在模拟水泥孔溶液(Ca(OH)2和0.2mol/L NaOH)中,三乙醇胺(TEA)和三异丙醇胺(TIPA)作为络合剂对SS溶解和SS-水泥基材料性能的影响。结果表明:a) TEA对Ca2+和Fe3+具有较强的络合能力;b) TIPA加速了水化产物的沉淀,显著促进了钙矾石的形成。TEA和TIPA在Ca2+络合能力上的根本差异源于它们的空间构型的影响。在ss -水泥体系中,两种络合剂均显著提高了早期力学性能。然而,TIPA对后期力量发展的影响更为明显。这是由于TIPA在改善和优化SS-PC膏体孔隙结构方面具有独特的效果。此外,这两种药剂不仅促进了SS和水泥内部矿物相的水化,而且促进了SS与CH的非晶相之间的火山灰反应。
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引用次数: 0
Tensor network-driven pathway optimization for brewery waste recycling: A multi-scale decision framework towards carbon neutrality 张量网络驱动的啤酒废物回收途径优化:迈向碳中和的多尺度决策框架
IF 7.8 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-03-15 Epub Date: 2026-02-12 DOI: 10.1016/j.psep.2026.108599
Zhengbo Li , Dingtao Peng
The brewing industry annually generates 38.6 million tons of solid waste, with 85 % comprising brewery residues, creating significant sustainability challenges. Under pressure to achieve carbon neutrality, wastewater treatment facilities must enhance efficiency while operating with low carbon emissions. Traditional optimization methods cannot effectively handle the high-dimensional nonlinear problems involving 32 coupled variables across multiple scales in brewery wastewater systems. This study proposes a tensor network-driven framework that decomposes the 32-dimensional decision space into six factor matrices with 5–6 dimensions each, enabling parallel computation and multiscale optimization at molecular, process, and system levels. Six-month industrial validation at a 200,000-ton/year brewery demonstrated substantial improvements: energy consumption decreased from 0.90 to 0.56 kWh/m3 (37.8 % reduction), COD removal increased from 85.2 % to 94.6 %, and carbon emissions dropped from 0.65 to 0.13 kg CO2-eq/m3 (80 % reduction). Economic analysis revealed a 14-month payback period and $2.62 million five-year NPV. The quantum-inspired approach provides a replicable solution for intelligent transformation and carbon-neutral transition in wastewater treatment, advancing circular economy implementation in the brewing sector.
酿酒业每年产生3860万吨固体废物,其中85% 为啤酒残留物,这对可持续发展构成了重大挑战。在实现碳中和的压力下,污水处理设施必须在低碳排放的同时提高效率。传统的优化方法不能有效地处理啤酒废水系统中涉及32个耦合变量的多尺度高维非线性问题。本研究提出了一个张量网络驱动的框架,该框架将32维决策空间分解为6个因子矩阵,每个因子矩阵有5-6个维度,可以在分子、过程和系统层面进行并行计算和多尺度优化。在一家年产20万吨的啤酒厂进行的为期6个月的工业验证显示出了实质性的改善:能耗从0.90千瓦时/立方米下降到0.56千瓦时/立方米(减少37.8% %),COD去除率从85.2% %增加到94.6 %,碳排放量从0.65 kg co2当量/立方米下降到0.13 kg co2当量/立方米(减少80% %)。经济分析显示,投资回收期为14个月,5年净现值为262万美元。量子启发的方法为废水处理的智能转换和碳中和过渡提供了可复制的解决方案,推动了酿造行业循环经济的实施。
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Process Safety and Environmental Protection
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