Melina Wertnik, Lukas Wacker, Stefano M. Bernasconi, Negar Haghipour, Timothy I Eglinton, Caroline Welte
While simultaneous radiocarbon and δ13C measurements have been available for organic materials (by accelerator mass spectrometry, AMS, and isotope ratio mass spectrometry, IRMS, respectively), this has not been possible for carbonates until now. Using an existing interface for gas ion source AMS measurements, we developed a prototype for a universal gas interface that allows simultaneous measurement of both carbon isotope ratios from potentially any source of CO2. First results obtained from reference materials (IAEA-C6, OxaII, PhA, IAEA-C1, IAEA-C2, ETH-4) show that for both organic as well as carbonate samples, the precision of radiocarbon measurements in the coupled mode is comparable to routine standalone AMS measurements. For IRMS δ13C measurements, the performance for different materials shows more variation with precisions ranging from 0.07‰ to 0.47‰. However, both organic materials and carbonates can achieve precisions as good as 0.13‰. Once fully automated, the method shows potential for filling the gap of simultaneous carbon isotope measurements for non-organic materials.
{"title":"A UNIVERSAL GAS INTERFACE FOR SIMULTANEOUS 14C AND δ13C MEASUREMENTS","authors":"Melina Wertnik, Lukas Wacker, Stefano M. Bernasconi, Negar Haghipour, Timothy I Eglinton, Caroline Welte","doi":"10.1017/rdc.2023.113","DOIUrl":"https://doi.org/10.1017/rdc.2023.113","url":null,"abstract":"<p>While simultaneous radiocarbon and δ<span>13</span>C measurements have been available for organic materials (by accelerator mass spectrometry, AMS, and isotope ratio mass spectrometry, IRMS, respectively), this has not been possible for carbonates until now. Using an existing interface for gas ion source AMS measurements, we developed a prototype for a universal gas interface that allows simultaneous measurement of both carbon isotope ratios from potentially any source of CO<span>2</span>. First results obtained from reference materials (IAEA-C6, OxaII, PhA, IAEA-C1, IAEA-C2, ETH-4) show that for both organic as well as carbonate samples, the precision of radiocarbon measurements in the coupled mode is comparable to routine standalone AMS measurements. For IRMS δ<span>13</span>C measurements, the performance for different materials shows more variation with precisions ranging from 0.07‰ to 0.47‰. However, both organic materials and carbonates can achieve precisions as good as 0.13‰. Once fully automated, the method shows potential for filling the gap of simultaneous carbon isotope measurements for non-organic materials.</p>","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2023-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138573085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gianluca Quarta, Theodora Eleftheriou, Istenc Engin, Lucio Maruccio, Marisa D’Elia, Lucio Calcagnile
The Committee on Missing Persons in Cyprus (CMP) is a bicommunal committee with the mandate to locate and identify the skeletal remains of 2002 persons who were reported missing during the inter-communal fighting of 1963–64, as well as the events of July and August 1974. During the periods of conflict, several archaeological sites and old cemeteries were used as primary burial sites, among several other types of burials, as they were easily accessed by the persons involved in the interment and little effort was needed to conceal the bodies. The relatively large post-mortem interval and the generally poor post-mortem preservation of the skeletal remains poses an additional challenge in the forensic examination process and the identification of the remains, particularly in the absence of a context or other associated artifacts/evidence. Between 2016 and 2020, the CMP has been collaborating with CEDAD to clarify the relevancy of several cases by using radiocarbon dating. The CMP submitted 139 cases to CEDAD out of which 112 were determined as not linked to the 1963–64 and 1974 events and then not relevant for the CMP project. For the remaining samples radiocarbon dating was used to determine death age.
{"title":"THE ROLE OF 14C DATING IN THE IDENTIFICATION OF MISSING PERSONS IN CYPRUS","authors":"Gianluca Quarta, Theodora Eleftheriou, Istenc Engin, Lucio Maruccio, Marisa D’Elia, Lucio Calcagnile","doi":"10.1017/rdc.2023.104","DOIUrl":"https://doi.org/10.1017/rdc.2023.104","url":null,"abstract":"<p>The Committee on Missing Persons in Cyprus (CMP) is a bicommunal committee with the mandate to locate and identify the skeletal remains of 2002 persons who were reported missing during the inter-communal fighting of 1963–64, as well as the events of July and August 1974. During the periods of conflict, several archaeological sites and old cemeteries were used as primary burial sites, among several other types of burials, as they were easily accessed by the persons involved in the interment and little effort was needed to conceal the bodies. The relatively large post-mortem interval and the generally poor post-mortem preservation of the skeletal remains poses an additional challenge in the forensic examination process and the identification of the remains, particularly in the absence of a context or other associated artifacts/evidence. Between 2016 and 2020, the CMP has been collaborating with CEDAD to clarify the relevancy of several cases by using radiocarbon dating. The CMP submitted 139 cases to CEDAD out of which 112 were determined as not linked to the 1963–64 and 1974 events and then not relevant for the CMP project. For the remaining samples radiocarbon dating was used to determine death age.</p>","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2023-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138567232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Felice Larocca, Francesco Breglia, Lucio Calcagnile, Marisa D’Elia, Gianluca Quarta
The Pertosa Caves, today also known as the Pertosa-Auletta Caves, constitute an important karst system in the Campania region (southern Italy). Crossed by the waters of a river that re-emerges on the surface, they have an overall development of about 3 km. Thanks to the width of the entrance, the excellent location along a natural communication route through the mountains and the natural availability of water directly on the site, the initial part of the cavity was frequented by humans, without interruption, from prehistoric times to the Middle Ages. During the protohistory, in particular, the moment of most marked human presence is recorded in the cave. In this phase an extensive pile dwelling system was built on the waters of the underground river. The system was probably created to make the location, subject to frequent flooding, suitable for human settlement. This structure today constitutes an archaeological unicum not only in Italy but throughout Europe. We briefly analyze its general characteristics providing the results of a radiocarbon dating campaign which allowed to assess the occupation phases of the different contexts and the life span of the wooden artifacts, which came to us in a very good state of preservation. Radiocarbon data allowed to assess the chronological range of the human frequentation of the caves and to date the exceptionally well preserved underground pile dwelling system.
{"title":"A RADIOCARBON CHRONOLOGY FOR “GROTTE DI PERTOSA” IN CAMPANIA, SOUTHERN ITALY","authors":"Felice Larocca, Francesco Breglia, Lucio Calcagnile, Marisa D’Elia, Gianluca Quarta","doi":"10.1017/rdc.2023.108","DOIUrl":"https://doi.org/10.1017/rdc.2023.108","url":null,"abstract":"<p>The Pertosa Caves, today also known as the Pertosa-Auletta Caves, constitute an important karst system in the Campania region (southern Italy). Crossed by the waters of a river that re-emerges on the surface, they have an overall development of about 3 km. Thanks to the width of the entrance, the excellent location along a natural communication route through the mountains and the natural availability of water directly on the site, the initial part of the cavity was frequented by humans, without interruption, from prehistoric times to the Middle Ages. During the protohistory, in particular, the moment of most marked human presence is recorded in the cave. In this phase an extensive pile dwelling system was built on the waters of the underground river. The system was probably created to make the location, subject to frequent flooding, suitable for human settlement. This structure today constitutes an archaeological unicum not only in Italy but throughout Europe. We briefly analyze its general characteristics providing the results of a radiocarbon dating campaign which allowed to assess the occupation phases of the different contexts and the life span of the wooden artifacts, which came to us in a very good state of preservation. Radiocarbon data allowed to assess the chronological range of the human frequentation of the caves and to date the exceptionally well preserved underground pile dwelling system.</p>","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2023-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138567557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soichiro Oda, Stephen P Obrochta, Osamu Fujiwara, Yusuke Yokoyama, Yosuke Miyairi, Yoshiya Hatakeyama
Analysis of the chronological data and observation of a lagoonal sediment core reveal sand washover events between around 2.4 to 2.5 cal. ky BP in the Isumi River lowland. We conducted radiocarbon dating with AMS and constructed an age-depth model using the latest calibration curve and appropriate model routine. In the middle to lower part of the core, dark-gray sand layers are repeatedly deposited. Sand layers may exhibit an erosional surface at the base with fining upward grading. The overwash layers are composed of well-rounded sand with occasional gravel, indicative of transportation. overwash sediment characteristics are consistent with proximal marine deposits, suggesting an ocean origin (though riverine sediment is also similar in character). The age-depth model indicates very high sediment accumulation rates associated with overwash deposits. Based on the amount of accumulated sediment, relatively large-scale redeposition events occurred during this period but more information is needed to constrain the mechanism(s) causing the events. We also present a local reservoir age correction compatible with the Marine20 calibration curve.
对一个泻湖沉积物岩心的年代学分析和观测表明,Isumi河低地在2.4 ~ 2.5 cal. ky BP之间发生了冲砂事件。利用AMS进行了放射性碳测年,并利用最新的校正曲线和合适的模型程序构建了年龄深度模型。岩心中下部反复沉积深灰色砂层。砂层可能在底部呈现侵蚀面,向上分级细化。上冲层由圆润的沙子和偶尔的砾石组成,表明了运输。上冲沉积物的特征与近海相沉积物一致,表明其起源为海洋(尽管河流沉积物的特征也相似)。年龄-深度模型表明,与过冲沉积物相关的沉积物堆积率非常高。根据沉积物的累积量,这一时期发生了相对大规模的再沉积事件,但需要更多的信息来约束事件发生的机制。我们还提出了一个与Marine20校准曲线兼容的局部储层年龄校正。
{"title":"HOLOCENE OVERWASH OCCURRENCE AGE IN THE ISUMI RIVER LOWLAND, EASTERN BOSO PENINSULA, JAPAN","authors":"Soichiro Oda, Stephen P Obrochta, Osamu Fujiwara, Yusuke Yokoyama, Yosuke Miyairi, Yoshiya Hatakeyama","doi":"10.1017/rdc.2023.105","DOIUrl":"https://doi.org/10.1017/rdc.2023.105","url":null,"abstract":"Analysis of the chronological data and observation of a lagoonal sediment core reveal sand washover events between around 2.4 to 2.5 cal. ky BP in the Isumi River lowland. We conducted radiocarbon dating with AMS and constructed an age-depth model using the latest calibration curve and appropriate model routine. In the middle to lower part of the core, dark-gray sand layers are repeatedly deposited. Sand layers may exhibit an erosional surface at the base with fining upward grading. The overwash layers are composed of well-rounded sand with occasional gravel, indicative of transportation. overwash sediment characteristics are consistent with proximal marine deposits, suggesting an ocean origin (though riverine sediment is also similar in character). The age-depth model indicates very high sediment accumulation rates associated with overwash deposits. Based on the amount of accumulated sediment, relatively large-scale redeposition events occurred during this period but more information is needed to constrain the mechanism(s) causing the events. We also present a local reservoir age correction compatible with the Marine20 calibration curve.","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2023-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138524443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jason A Rech, Christina N Tenison, Alexander Baldasare, Brian S Currie
Late Quaternary fluvial channel deposits are notoriously difficult to date. In the midwestern United States, shells of aquatic mollusks can be found within many fluvial channel sediments and therefore can be radiocarbon (14C) dated to determine the age of the deposits. However, carbonate platform rocks are abundant in this region, potentially causing freshwater 14C reservoir effects (FRE) in mollusk shells. We 14C dated 11 aquatic gastropod and bivalve shell samples from specimens collected live from a stream in southwestern Ohio during three different years to assess the modern 14C reservoir effect. Modern samples yielded an average 14C FREmodern of 518 ± 65 14C yrs for 2020 (n=5), 640 ± 34 14C yrs for 2021 (n=2), and 707 ± 76 14C yrs for 2022 (n=4). We also 14C dated matched pairs of organic wood or charcoal and aquatic mollusk shells from late Pleistocene and Holocene deposits in the Four Mile Creek floodplain to determine the FREfossil. These samples, free of any potential influence from nuclear bomb testing, yielded an overall weighted mean FREfossil of 1029 ± 345 14C yrs. We then assess the advantages and limitations of both the FREmodern and FREfossil methods for determining freshwater reservoir effects. Finally, we apply the FREfossil correction to a series of shell ages from fluvial terrace deposits as a case study. The results indicate that although there is a 14C FRE in streams from the midwestern United States, aquatic shells can provide robust age control on fluvial channel deposits. More research is needed to understand the spatial and temporal variability of FREs, as well as any species effects, among various watersheds across the midwestern United States.
{"title":"RADIOCARBON DATING AND FRESHWATER RESERVOIR EFFECTS OF AQUATIC MOLLUSKS WITHIN FLUVIAL CHANNEL DEPOSITS IN THE MIDWESTERN UNITED STATES","authors":"Jason A Rech, Christina N Tenison, Alexander Baldasare, Brian S Currie","doi":"10.1017/rdc.2023.93","DOIUrl":"https://doi.org/10.1017/rdc.2023.93","url":null,"abstract":"<p>Late Quaternary fluvial channel deposits are notoriously difficult to date. In the midwestern United States, shells of aquatic mollusks can be found within many fluvial channel sediments and therefore can be radiocarbon (<span>14</span>C) dated to determine the age of the deposits. However, carbonate platform rocks are abundant in this region, potentially causing freshwater <span>14</span>C reservoir effects (FRE) in mollusk shells. We <span>14</span>C dated 11 aquatic gastropod and bivalve shell samples from specimens collected live from a stream in southwestern Ohio during three different years to assess the modern <span>14</span>C reservoir effect. Modern samples yielded an average <span>14</span>C FRE<span>modern</span> of 518 ± 65 <span>14</span>C yrs for 2020 (n=5), 640 ± 34 <span>14</span>C yrs for 2021 (n=2), and 707 ± 76 <span>14</span>C yrs for 2022 (n=4). We also <span>14</span>C dated matched pairs of organic wood or charcoal and aquatic mollusk shells from late Pleistocene and Holocene deposits in the Four Mile Creek floodplain to determine the FRE<span>fossil</span>. These samples, free of any potential influence from nuclear bomb testing, yielded an overall weighted mean FRE<span>fossil</span> of 1029 ± 345 <span>14</span>C yrs. We then assess the advantages and limitations of both the FRE<span>modern</span> and FRE<span>fossil</span> methods for determining freshwater reservoir effects. Finally, we apply the FRE<span>fossil</span> correction to a series of shell ages from fluvial terrace deposits as a case study. The results indicate that although there is a <span>14</span>C FRE in streams from the midwestern United States, aquatic shells can provide robust age control on fluvial channel deposits. More research is needed to understand the spatial and temporal variability of FREs, as well as any species effects, among various watersheds across the midwestern United States.</p>","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2023-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138524454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Margaret A Davis, Brendan J Culleton, Richard L Rosencrance, Christopher S Jazwa
ABSTRACT Skin-based samples (leather, skin, and parchment) in archaeological, historic and museum settings are among the most challenging materials to radiocarbon ( 14 C) date in terms of removing exogenous carbon sources—comparable to bone collagen in many respects but with much less empirical study to guide pretreatment approaches. In the case of leather, the 14 C content of materials used in manufacturing the leather can vary greatly. The presence of leather manufacturing chemicals before pretreatment and their absence afterward is difficult to demonstrate, and the accuracy of dates depends upon isolating the original animal proteins and removing exogenous carbon. Parchments differ in production technique from leather but include similar unknowns. It is not clear that lessons learned in the treatment of one are always salient for treating the other. We measured the 14 C content of variously pretreated leather, parchment, skin samples, and extracts, producing apparent ages that varied by hundreds or occasionally thousands of years depending upon sample pretreatment. Fourier Transform Infrared Spectroscopy (FTIR) and C:N ratios provided insight into the chemical composition of carbon reservoirs contributing to age differences. The results of these analyses demonstrated that XAD column chromatography resulted in the most accurate 14 C dates for leather and samples of unknown tannage, and FTIR allowed for the detection of contamination that might have otherwise been overlooked.
{"title":"EXPERIMENTAL OBSERVATIONS ON PROCESSING LEATHER, SKIN, AND PARCHMENT FOR RADIOCARBON DATING","authors":"Margaret A Davis, Brendan J Culleton, Richard L Rosencrance, Christopher S Jazwa","doi":"10.1017/rdc.2023.88","DOIUrl":"https://doi.org/10.1017/rdc.2023.88","url":null,"abstract":"ABSTRACT Skin-based samples (leather, skin, and parchment) in archaeological, historic and museum settings are among the most challenging materials to radiocarbon ( 14 C) date in terms of removing exogenous carbon sources—comparable to bone collagen in many respects but with much less empirical study to guide pretreatment approaches. In the case of leather, the 14 C content of materials used in manufacturing the leather can vary greatly. The presence of leather manufacturing chemicals before pretreatment and their absence afterward is difficult to demonstrate, and the accuracy of dates depends upon isolating the original animal proteins and removing exogenous carbon. Parchments differ in production technique from leather but include similar unknowns. It is not clear that lessons learned in the treatment of one are always salient for treating the other. We measured the 14 C content of variously pretreated leather, parchment, skin samples, and extracts, producing apparent ages that varied by hundreds or occasionally thousands of years depending upon sample pretreatment. Fourier Transform Infrared Spectroscopy (FTIR) and C:N ratios provided insight into the chemical composition of carbon reservoirs contributing to age differences. The results of these analyses demonstrated that XAD column chromatography resulted in the most accurate 14 C dates for leather and samples of unknown tannage, and FTIR allowed for the detection of contamination that might have otherwise been overlooked.","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136346852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L G van der Sluis, A Zazzo, O Tombret, F Thil, J-M Pétillon
ABSTRACT Museum collections are extremely valuable sources of material for ongoing research, although the conservation history of some objects is not always recorded, which can be problematic for chemical analyses. While most contamination is removed using the acid-base-acid treatment, this may not be the case for cross-linked contamination. The XAD resin protocol was implemented at the radiocarbon ( 14 C) laboratory in the Muséum national d’Histoire naturelle, and the setup was tested using known age bone samples and a consolidated Palaeolithic bone. Known age samples were consolidated with shellac or Paraloid, aged for a month, treated with or without the XAD resin and 14 C dated. Bone blank results showed that XAD resin was able to remove shellac, which was not the case for the ABA-only method. Results from VIRI I were more variable and VIRI F was possibly too young to show the effects of the consolidants. Two 14 C dates on the Palaeolithic bone after XAD treatment are statistically the same, while a sample without XAD treatment was significantly older, suggesting that the contaminant was not fully removed by the ABA-only treatment. This study demonstrates the potential of the XAD treatment to clean heritage bone samples stored in museums prior to geochemical analyses.
博物馆的藏品对于正在进行的研究来说是极有价值的材料来源,尽管一些物品的保存历史并不总是被记录下来,这可能会给化学分析带来问题。虽然使用酸碱-酸处理可以去除大多数污染,但交联污染可能不是这种情况。XAD树脂方案在mus national d’histoire naturelle的放射性碳(14c)实验室实施,并使用已知年龄的骨骼样本和旧石器时代的固结骨骼进行了测试。已知年龄的样品用紫胶或副胶体固结,陈化一个月,用或不用XAD树脂处理,并测定14c年代。骨空白结果表明,XAD树脂能够去除紫胶,而仅使用aba的方法则不能。VIRI I的结果变化更大,VIRI F可能太年轻,无法显示固结剂的效果。经过XAD处理的旧石器时代骨骼上的两个14c日期在统计上是相同的,而未经XAD处理的样本明显更老,这表明仅使用aba处理并没有完全去除污染物。这项研究证明了XAD处理在地球化学分析之前清洁博物馆中保存的遗产骨样本的潜力。
{"title":"TESTING THE USE OF XAD RESIN TO REMOVE SYNTHETIC CONTAMINATION FROM ARCHAEOLOGICAL BONE PRIOR TO RADIOCARBON DATING","authors":"L G van der Sluis, A Zazzo, O Tombret, F Thil, J-M Pétillon","doi":"10.1017/rdc.2023.100","DOIUrl":"https://doi.org/10.1017/rdc.2023.100","url":null,"abstract":"ABSTRACT Museum collections are extremely valuable sources of material for ongoing research, although the conservation history of some objects is not always recorded, which can be problematic for chemical analyses. While most contamination is removed using the acid-base-acid treatment, this may not be the case for cross-linked contamination. The XAD resin protocol was implemented at the radiocarbon ( 14 C) laboratory in the Muséum national d’Histoire naturelle, and the setup was tested using known age bone samples and a consolidated Palaeolithic bone. Known age samples were consolidated with shellac or Paraloid, aged for a month, treated with or without the XAD resin and 14 C dated. Bone blank results showed that XAD resin was able to remove shellac, which was not the case for the ABA-only method. Results from VIRI I were more variable and VIRI F was possibly too young to show the effects of the consolidants. Two 14 C dates on the Palaeolithic bone after XAD treatment are statistically the same, while a sample without XAD treatment was significantly older, suggesting that the contaminant was not fully removed by the ABA-only treatment. This study demonstrates the potential of the XAD treatment to clean heritage bone samples stored in museums prior to geochemical analyses.","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136347161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M Wojcieszak, J Veenhoven, T Van den Brande, S Saverwyns, F Lynen, M Boudin
ABSTRACT Lacquerwork technologies comprise multiple techniques depending on countries, time, and traditions. Carved Asian lacquers applied on wooden objects consist of multiple thin uncolored or pigmented layers spread over the surface. To radiocarbon ( 14 C) date these types of objects, often only the wooden structure is used. Here we report on a set of carved lacquered objects that were dated based on stylistic form, 14 C dating of the wooden structure and of the Asian lacquers. THM-Py-GC-MS and micro-Raman spectroscopy were used to confirm the molecular composition of the lacquers and helped assessing the pretreatment protocol. The lacquers analyzed contained between 20 and 50% wt carbon, thus 2–5 mg of sample were necessary for 14 C dating. The dates obtained on wood and lacquers showed a reliable correlation. The results suggest that, in most cases, it is sufficient to sample a part of the lacquer layers to date an object. We advise to perform an acid pretreatment followed by a successive solvent immersion with an increasing polarity. Dating different components of a lacquered object can also help to understand previous restoration interventions that frequently occur for ancient lacquered objects. Ceramic, metallic, and other objects covered with Asian lacquers can also be dated using this approach.
{"title":"RADIOCARBON DATING OF ASIAN LACQUERS: MOLECULAR CHARACTERIZATION AND ASSESSMENT OF A PRETREATMENT METHOD PRIOR TO ACCELERATOR MASS SPECTROMETRY","authors":"M Wojcieszak, J Veenhoven, T Van den Brande, S Saverwyns, F Lynen, M Boudin","doi":"10.1017/rdc.2023.90","DOIUrl":"https://doi.org/10.1017/rdc.2023.90","url":null,"abstract":"ABSTRACT Lacquerwork technologies comprise multiple techniques depending on countries, time, and traditions. Carved Asian lacquers applied on wooden objects consist of multiple thin uncolored or pigmented layers spread over the surface. To radiocarbon ( 14 C) date these types of objects, often only the wooden structure is used. Here we report on a set of carved lacquered objects that were dated based on stylistic form, 14 C dating of the wooden structure and of the Asian lacquers. THM-Py-GC-MS and micro-Raman spectroscopy were used to confirm the molecular composition of the lacquers and helped assessing the pretreatment protocol. The lacquers analyzed contained between 20 and 50% wt carbon, thus 2–5 mg of sample were necessary for 14 C dating. The dates obtained on wood and lacquers showed a reliable correlation. The results suggest that, in most cases, it is sufficient to sample a part of the lacquer layers to date an object. We advise to perform an acid pretreatment followed by a successive solvent immersion with an increasing polarity. Dating different components of a lacquered object can also help to understand previous restoration interventions that frequently occur for ancient lacquered objects. Ceramic, metallic, and other objects covered with Asian lacquers can also be dated using this approach.","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135244379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rachel Wood, Fleur King, Rebecca Esmay, Qianyang Chen, Larissa Schneider, Emilie Dotte-Sarout, Stewart Fallon, Kirstie Fryirs, Richard Gillespie, Russell Blong
ABSTRACT Radiocarbon dates on charred plant remains are often used to define the chronology of archives such as lake cores and fluvial sequences. However, charcoal is often older than its depositional context because old-wood can be burnt and a range of transport and storage stages exist between the woodland and stream or lake bed (“inherited age”). In 1978, Blong and Gillespie dated four size fractions of charcoal found floating or saltating in the Macdonald River, Australia. They found larger fragments gave younger age estimates, raising the possibility that taphonomic modifications could help identify the youngest fragments. In 1978 each date required 1000s charcoal fragments. This study returns to a sample from the Macdonald River to date individual charcoal fragments and finds the inherited age may be more than 1700 years (mode 250 years) older than the collection date. Taphonomic factors, e.g., size, shape or fungal infestation cannot identify the youngest fragments. Only two fragments on short-lived materials correctly estimated the date of collection. In SE Australia, this study suggests that wood charcoal will overestimate the age of deposition, taphonomic modifications cannot be used to identify which are youngest, and multiple short-lived materials are required to accurately estimate the deposition age.
{"title":"THE SIZE INHERITED AGE EFFECT ON RADIOCARBON DATES OF ALLUVIAL DEPOSITS: REDATING CHARCOAL FRAGMENTS IN A SAND-BED STREAM, MACDONALD RIVER, NSW, AUSTRALIA","authors":"Rachel Wood, Fleur King, Rebecca Esmay, Qianyang Chen, Larissa Schneider, Emilie Dotte-Sarout, Stewart Fallon, Kirstie Fryirs, Richard Gillespie, Russell Blong","doi":"10.1017/rdc.2023.75","DOIUrl":"https://doi.org/10.1017/rdc.2023.75","url":null,"abstract":"ABSTRACT Radiocarbon dates on charred plant remains are often used to define the chronology of archives such as lake cores and fluvial sequences. However, charcoal is often older than its depositional context because old-wood can be burnt and a range of transport and storage stages exist between the woodland and stream or lake bed (“inherited age”). In 1978, Blong and Gillespie dated four size fractions of charcoal found floating or saltating in the Macdonald River, Australia. They found larger fragments gave younger age estimates, raising the possibility that taphonomic modifications could help identify the youngest fragments. In 1978 each date required 1000s charcoal fragments. This study returns to a sample from the Macdonald River to date individual charcoal fragments and finds the inherited age may be more than 1700 years (mode 250 years) older than the collection date. Taphonomic factors, e.g., size, shape or fungal infestation cannot identify the youngest fragments. Only two fragments on short-lived materials correctly estimated the date of collection. In SE Australia, this study suggests that wood charcoal will overestimate the age of deposition, taphonomic modifications cannot be used to identify which are youngest, and multiple short-lived materials are required to accurately estimate the deposition age.","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135340647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yannis Maniatis, Marisa Marthari, Georgios S Polymeris
ABSTRACT We have radiocarbon-dated the main settlement of Skarkos (Skarkos II) on the Cycladic island of Ios, using a set of animal bone samples. The site of Skarkos stands on a hill in a coastal plain, mid-way down the western side of Ios island and about 1 km from the island’s harbour. It is the first time this important settlement with a wealth of finds and an extraordinary building system with two-storey houses is dated in absolute terms complementing the chronology of the Cycladic EBA II period. The radiocarbon determinations show that the major phase of the settlement came to an end between circa 2550 and circa 2500 BC. The dates also confirm the archaeological evidence that the main occupation period is dated archaeologically to the EC II period (Keros-Syros culture). Furthermore, in order to embed the new Skarkos dates within the overall Cycladic chronology and define better the end of the EC II phase, we treated the Skarkos dates together with published dates from other Cycladic sites using Bayesian analysis considering two different models.
{"title":"RADIOCARBON DATING OF THE MAJOR SETTLEMENT AT SKARKOS (IOS ISLAND, CYCLADES) AND INFERENCES FOR THE EARLY CYCLADIC CHRONOLOGY","authors":"Yannis Maniatis, Marisa Marthari, Georgios S Polymeris","doi":"10.1017/rdc.2023.101","DOIUrl":"https://doi.org/10.1017/rdc.2023.101","url":null,"abstract":"ABSTRACT We have radiocarbon-dated the main settlement of Skarkos (Skarkos II) on the Cycladic island of Ios, using a set of animal bone samples. The site of Skarkos stands on a hill in a coastal plain, mid-way down the western side of Ios island and about 1 km from the island’s harbour. It is the first time this important settlement with a wealth of finds and an extraordinary building system with two-storey houses is dated in absolute terms complementing the chronology of the Cycladic EBA II period. The radiocarbon determinations show that the major phase of the settlement came to an end between circa 2550 and circa 2500 BC. The dates also confirm the archaeological evidence that the main occupation period is dated archaeologically to the EC II period (Keros-Syros culture). Furthermore, in order to embed the new Skarkos dates within the overall Cycladic chronology and define better the end of the EC II phase, we treated the Skarkos dates together with published dates from other Cycladic sites using Bayesian analysis considering two different models.","PeriodicalId":21020,"journal":{"name":"Radiocarbon","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135480538","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}