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Machine learning for QoS and security enhancement of RPL in IoT-Enabled wireless sensors 利用机器学习提高物联网无线传感器 RPL 的服务质量和安全性
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2024.100289
Abubakar Wakili, Sara Bakkali, Ahmed El Hilali Alaoui

Internet of Things (IoT) networks rely on wireless sensors for data collection and transmission, making them vulnerable to security threats that undermine their Quality of Service (QoS). The Routing Protocol for Low-Power and Lossy Networks (RPL) is crucial for efficient data transmission in IoT networks, but its performance can be significantly degraded by attacks such as Rank, Sinkhole and Wormhole attacks. These threats disrupt network integrity by manipulating routing information, attracting traffic through malicious nodes and tunneling data to malicious endpoints. This paper presents a novel machine learning-based framework to enhance RPL's security and QoS. Our approach integrates a random forest model for precise traffic classification, a reinforcement learning module for dynamic and adaptive routing, and a modified RPL objective function that incorporates classification outcomes into routing decisions. Simulations demonstrate that our framework significantly improves network throughput, reduces latency, and enhances packet delivery ratios while maintaining low jitter. Furthermore, it achieves a high detection rate, minimal false positives, and swift response to security incidents, thereby robustly securing the RPL protocol and enhancing QoS in IoT-enabled wireless sensor networks. The findings of this research offer substantial contributions to the field, providing a comprehensive solution to strengthen RPL against prevalent security threats.

物联网(IoT)网络依赖无线传感器进行数据收集和传输,因此很容易受到安全威胁,从而破坏其服务质量(QoS)。低功耗和低损耗网络路由协议(RPL)对于物联网网络中的高效数据传输至关重要,但其性能会因 Rank、Sinkhole 和 Wormhole 攻击等攻击而大幅降低。这些威胁通过篡改路由信息、通过恶意节点吸引流量以及向恶意端点隧道传输数据来破坏网络的完整性。本文提出了一种新颖的基于机器学习的框架,以增强 RPL 的安全性和 QoS。我们的方法集成了用于精确流量分类的随机森林模型、用于动态和自适应路由选择的强化学习模块,以及将分类结果纳入路由选择决策的修正 RPL 目标函数。仿真结果表明,我们的框架在保持低抖动的同时,显著提高了网络吞吐量,减少了延迟,提高了数据包传送率。此外,它还实现了高检测率、最小误报率和对安全事件的快速响应,从而确保了 RPL 协议的稳健安全,并提高了物联网无线传感器网络的 QoS。这项研究成果为该领域做出了重大贡献,提供了一个全面的解决方案来加强 RPL 的安全性,抵御普遍存在的安全威胁。
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引用次数: 0
Integration of wireless power transfer and low power wide area networks in IoT applications—A review 物联网应用中的无线电力传输与低功耗广域网整合--综述
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2024.100284
Molefi J. Makhetha , Elisha D. Markus , Adnan M. Abu-Mahfouz

The significance of a more convenient and sustainable power transfer has been more crucial recently with the increasing need for low power electronic devices and their applications in internet of things (IoT). Wireless power transfer (WPT) technologies can conveniently transmit power to sensor and electronic devices deployed in hard-to-reach locations and therefore improving their convenience and mobility. On the other hand, low power wide area networks (LPWANs) provide low-power consumption, low bandwidth interaction between IoTs and the cloud, all which are traits of low-cost solutions for long range communication. Conversely, due to these devices’ locations (hard-to-reach/hazardous), it is a challenge to sustainably charge them and for the power sources or their mechanisms to last for longer term. This review analyses recent work on LPWANs and low power WPT with strong focus on the main challenges and key solutions that would allow for their integration in IoT applications. Challenges facing WPT systems such as end-device power intake, transmission power loss, power regulation, and coil/loop misalignment are highlighted in reference to recent research, recommending various challenge-mitigating techniques. Furthermore, for LPWAN end-devices, energy profiling of such devices is discussed through recent work aiming to optimise their power consumption. Specifically, we discuss factors affecting LPWAN end-devices’ power consumption which comprises the spreading factor, communication range and bit-rate. Also, comparison analysis is performed to highlight the superiority of wireless sensors/power transfer, in terms of cost, reliability, environmental impact and scalability Essentially, it is necessary to realise the potential of these two techniques (WPT and LPWAN), as their integration can advance various fields like structural health monitoring (SHM), precision agriculture, healthcare, and environmental monitoring.

近来,随着对低功耗电子设备及其在物联网(IoT)中应用的需求日益增长,更便捷、更可持续的电力传输变得更加重要。无线电力传输(WPT)技术可以方便地向部署在难以到达位置的传感器和电子设备传输电力,从而提高它们的便利性和移动性。另一方面,低功耗广域网(LPWAN)提供低功耗、低带宽的物联网与云之间的互动,这些都是低成本远距离通信解决方案的特点。与此相反,由于这些设备的位置(难以到达/危险),为其持续充电以及电源或其机制的长期使用都是一个挑战。本综述分析了 LPWAN 和低功耗 WPT 的最新研究成果,重点关注将其集成到物联网应用中的主要挑战和关键解决方案。参考最新研究,重点介绍了 WPT 系统面临的挑战,如终端设备功率摄入、传输功率损耗、功率调节和线圈/环路错位,并推荐了各种挑战缓解技术。此外,对于 LPWAN 终端设备,我们通过近期旨在优化其功耗的工作,讨论了此类设备的能量剖析。具体而言,我们讨论了影响 LPWAN 终端设备功耗的因素,包括传播因子、通信范围和比特率。此外,我们还进行了比较分析,以突出无线传感器/功率传输在成本、可靠性、环境影响和可扩展性方面的优势。 从根本上说,有必要实现这两种技术(WPT 和 LPWAN)的潜力,因为它们的集成可以推动结构健康监测 (SHM)、精准农业、医疗保健和环境监测等多个领域的发展。
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引用次数: 0
A colorimetric detection of creatinine based-on EDTA capped-gold nanoparticles (EDTA-AuNPs): Digital Image Colorimetry 基于乙二胺四乙酸封端金纳米粒子(EDTA-AuNPs)的肌酐比色检测法:数字图像比色法
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2024.100286
Eduwin Saputra
A colorimetric sensor based on EDTA-modified gold nanoparticles (EDTA-AuNPs) has been developed for the sensitive and selective detection of creatinine using UV–vis spectrophotometer and digital image method. The presence of creatinine in EDTA-AuNPs results in a decrease in the absorbance peak at 524 nm and the appearance of an absorbance peak at 700 nm in the UV–vis spectrum. Creatinine induces the aggregation of EDTA-AuNPs, resulting in a color change from wine red to blue, which is easily observable with the naked eye. Color changes in colloids of EDTA-AuNPs can be further developed using digital image methods based on red, green, and blue colors to detect creatinine. The UV–vis spectrophotometer method demonstrated a linear relationship between the absorbance ratio at A700/A524 nm in the range of 0.0–5.0 mM, with a regression coefficient of 0.9906 and a detection limit of 0.125 mM. Meanwhile, the digital image method demonstrates a linear relationship between red color intensity (R) and creatinine concentration, with a high regression coefficient of 0.996 and a low detection limit of 0.050 mM. Creatinine testing conducted on artificial urine samples demonstrated a recovery rate between 97.5 % and 101.7 %, with a relative standard deviation (RSD) ranging from 0.28 % to 0.74 %. These results indicate good measurement accuracy and precision for the creatinine testing method.
基于edta修饰金纳米粒子(EDTA-AuNPs)的比色传感器,采用紫外-可见分光光度计和数字图像法对肌酐进行了灵敏、选择性的检测。EDTA-AuNPs中肌酐的存在导致524 nm处的吸光度峰降低,700 nm处的吸光度峰出现。肌酐诱导EDTA-AuNPs聚集,导致颜色从酒红色变为蓝色,这很容易用肉眼观察到。EDTA-AuNPs胶体的颜色变化可以进一步利用基于红、绿、蓝的数字图像方法来检测肌酐。紫外可见分光光度法在A700/A524 nm处的吸光度比在0.0 ~ 5.0 mM范围内呈线性关系,回归系数为0.9906,检出限为0.125 mM。同时,数字图像法显示红色强度(R)与肌酐浓度呈线性关系。对人工尿液进行肌酐检测,回收率为97.5% ~ 101.7%,相对标准偏差(RSD)为0.28% ~ 0.74%。结果表明,该方法具有较好的测量准确度和精密度。
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引用次数: 0
Synthesis and application of optical silver nanoparticles capped carbon dots as dual-mode sensors for trivalent chromium ions in dietary supplements 作为膳食补充剂中三价铬离子双模传感器的光学银纳米粒子封端碳点的合成与应用
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2024.100281
Ratchadaporn Seedad , Pornpimol Prayongpan , Wutthikrai Busayaporn , Kriangsak Songsrirote

A facile method for trivalent chromium (Cr3+) ion determination using optical silver nanoparticles capped carbon dots (Ag@CDs) was developed. The optical responses via absorption and fluorescence of Ag@CDs in the presence of Cr3+ ion were detected. The nanocomposite showed maximum absorption wavelength at 406.0 nm, while emission wavelength appeared at 526.0 nm when excited at 406.0 nm. Optimal conditions for the Ag@CDs activity on Cr3+ ion detection were at pH 6, volume ratio between Ag@CDs and Cr3+ ion of 1.0:4.0, and reaction time of 20 min. The linearity range of the detection was 0.1–10.0 mg/L. In the absorption mode, the limit of detection (LOD) and limit of quantification (LOQ) were 0.10 mg/L and 0.31 mg/L, respectively. The fluorescence mode of detection showed LOD and LOQ of 0.06 mg/L and 0.18 mg/L, respectively. The dual-mode sensor was applied for Cr3+ ion quantification in dietary supplement samples because it is an essential micronutrient and widely used as supplement products. The recovery study of the spiked sample extracts was in the range of 96.86–103.05 %. The results showed good agreement with those from a conventional method of atomic emission spectrometry. The optical changing mechanism of the nanocomposite could be explained by the electron transfer from Ag@CDs to Cr3+.

利用光学银纳米粒子封端碳点(Ag@CDs)开发了一种测定三价铬(Cr3+)离子的简便方法。检测了 Ag@CDs 在 Cr3+ 离子存在下的吸收和荧光响应。该纳米复合材料的最大吸收波长为 406.0 nm,而在 406.0 nm 处激发时的发射波长为 526.0 nm。Ag@CDs 对 Cr3+ 离子的最佳检测条件为 pH 值为 6,Ag@CDs 与 Cr3+ 离子的体积比为 1.0:4.0,反应时间为 20 分钟。检测线性范围为 0.1-10.0 mg/L。在吸收模式下,检出限(LOD)和定量限(LOQ)分别为 0.10 mg/L 和 0.31 mg/L。荧光检测模式的检测限和定量限分别为 0.06 mg/L 和 0.18 mg/L。由于 Cr3+ 是人体必需的微量营养元素,被广泛应用于补充剂产品中,因此该双模式传感器被用于膳食补充剂样品中 Cr3+ 离子的定量分析。加标样品提取物的回收率为 96.86-103.05%。该结果与传统原子发射光谱法的结果一致。纳米复合材料的光学变化机理可通过 Ag@CDs 向 Cr3+ 的电子转移来解释。
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引用次数: 0
Fabrication and characterization of rGO-SnO2 nanocomposite for electrochemical sensor of ciprofloxacin 用于环丙沙星电化学传感器的 rGO-SnO2 纳米复合材料的制备与表征
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2023.100276
Prastika Krisma Jiwanti , Dewi Kartika Azizah Sukardi , Anis Puspita Sari , Mai Tomisaki , Siti Wafiroh , Sri Hartati , Arramel , Yew Hoong Wong , Pei Meng Woi , Joon Ching Juan

The uncontrolled use of ciprofloxacin (CIP) has led to increased resistance in patients and potential health issues such as kidney disorders, digestive disorder, and liver complications. This study addresses these concerns by introducing an innovative electrochemical sensor utilizing a screen-printed electrode (SPE) enhanced with a novel rGO-SnO2 nanocomposite for the precise monitoring of CIP concentration. Through square wave voltammetry (SWV), this sensor demonstrates unparalleled sensitivity and accuracy in determining CIP levels. These analyses validated the superior performance of the SPE/rGO-SnO2 electrode, revealing CIP potential range of 0.85–1.50 V with irreversible oxidation reaction and an exceptional signal-to-background (S/B) ratio of 1.91, surpassing the 1.21 ratio achieved by the SPE/rGO electrode. The SPE/rGO-SnO2 electrode also exhibited the highest active surface area (0.0252 cm2), facilitating faster transfer electron. Crucially, the SPE/rGO-SnO2 electrode exhibited an impressively low limit of detection (LOD) at 2.03 μM within a concentration range of 30–100 μM for CIP, setting a new benchmark for sensitivity (9.348 μA/μM) in CIP detection. The %RSD value was less than 5 % indicating that this modified electrodes exhibit good precision and stability. The real-world applicability of this developed methods was exemplified through its successful implementation in the analysis of river water and milk, achieving remarkable recovery rates of 101.2 % and 97.7 %, respectively. Consequently, the SPE modified with rGO-SnO2 nanocomposite emerges as a highly promising and effective tool for precise and sensitive CIP measurement, offering unparalleled performance metrics and opening avenues for enhanced environmental and health monitoring.

环丙沙星(CIP)的无节制使用导致患者耐药性增加,并引发潜在的健康问题,如肾脏疾病、消化系统疾病和肝脏并发症。为了解决这些问题,本研究引入了一种创新的电化学传感器,利用新型 rGO-SnO2 纳米复合材料增强的丝网印刷电极 (SPE),精确监测 CIP 的浓度。通过方波伏安法(SWV),该传感器在确定 CIP 含量方面表现出了无与伦比的灵敏度和准确性。这些分析验证了 SPE/rGO-SnO2 电极的优越性能,显示 CIP 电位范围为 0.85-1.50 V,具有不可逆的氧化反应,并且具有 1.91 的优异信噪比 (S/B),超过了 SPE/rGO 电极的 1.21。此外,SPE/rGO-SnO2 电极还具有最高的活性表面积(0.0252 平方厘米),从而加快了电子转移速度。最重要的是,SPE/rGO-SnO2 电极在 30-100 μM 的 CIP 浓度范围内表现出令人印象深刻的低检测限 (LOD),仅为 2.03 μM,为 CIP 检测灵敏度(9.348 μA/μM)树立了新的基准。%RSD值小于5%,表明这种改良电极具有良好的精度和稳定性。在河水和牛奶的分析中,该方法的回收率分别达到了 101.2 % 和 97.7 %。因此,使用 rGO-SnO2 纳米复合材料修饰的 SPE 是一种极具前景的有效工具,可用于精确、灵敏的 CIP 测量,提供无与伦比的性能指标,为加强环境和健康监测开辟了途径。
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引用次数: 0
Recent achievement of graphene in biomedicine: Advancements by integrated microfluidics system and conventional techniques 石墨烯在生物医学领域的最新成果:集成微流控系统和传统技术的进展
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2024.100293
Mohammad Aminul Islam , Aslam Hossain , Nayem Hossain , Md Mir Shakib Ahmed , Safiul Islam , A.M.A. Henaish , A.V. Soldatov , Mohammad Asaduzzaman Chowdhury

Graphene and its derivatives have become essential materials in modern biomedical research due to their positive impact on various applications. Moreover, the integration of graphene-based materials with microfluidics technology has opened up new possibilities. The novelty of the current review is considering comprehensive analysis of the transformative impact of graphene and its derivatives in biomedical applications, particularly highlighting the integration with microfluidics technology. While many studies have focused on individual applications of graphene, this review uniquely present a holistic view of its potential across various biomedical fields, including drug delivery, gene delivery, tissue engineering, and photothermal treatment, detection, sensor with respect to conventional and microfluidics techniques. In this review, we analysed published research to unveil the increasing interest in graphene's potential applications in healthcare and medicine, as well as its prospects for further exploration. We explore the fundamental concepts of graphene, its properties, and its latest applications in medical implants and biological fields within the context of microfluidics and conventional prospects. The review also addresses the challenges and limitations of these materials and their promising future, recognizing that graphene research is still in its early stages compared to commercial applications.

石墨烯及其衍生物对各种应用产生了积极影响,已成为现代生物医学研究的重要材料。此外,石墨烯基材料与微流控技术的结合也开辟了新的可能性。本综述的新颖之处在于全面分析了石墨烯及其衍生物在生物医学应用中的变革性影响,特别强调了与微流控技术的整合。虽然许多研究都集中在石墨烯的个别应用上,但本综述以独特的视角全面介绍了石墨烯在各个生物医学领域的潜力,包括药物输送、基因输送、组织工程、光热治疗、检测、传感器以及传统和微流控技术。在这篇综述中,我们分析了已发表的研究成果,揭示了人们对石墨烯在医疗保健和医药领域的潜在应用日益增长的兴趣,以及进一步探索的前景。我们探讨了石墨烯的基本概念、特性及其在微流体技术和传统前景背景下在医疗植入物和生物领域的最新应用。本综述还探讨了这些材料所面临的挑战和局限性,以及它们充满希望的未来,同时认识到与商业应用相比,石墨烯研究仍处于早期阶段。
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引用次数: 0
Integration of carbon dioxide sensor with GNSS receiver for dynamic air quality monitoring applications 将二氧化碳传感器与全球导航卫星系统接收器集成,用于动态空气质量监测应用
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2024.100279
Lin Yola , Garrin Alif Nanditho , Kaito Kobayashi , Dinesh Manandhar

Air pollution is a significant problem in big cities due to the rapid increase of anthropogenic activities and severe traffic congestion. Therefore, real-time and micro tools for air monitoring are urgently necessary for fast and better policy decision-making. The current city air monitoring tool is typically static and serves a macro area. This study introduces technology development to integrate the air quality sensor with the satellite-based navigation receiver. This study used a carbon dioxide (CO2) MH-Z19C sensor and real-time kinematic global navigation satellite system (RTK GNSS) U-Blox F9P with GNSS Trimble NetR9 receiver. The field air quality monitoring (CO2 observed in ppm) and the movement velocity (vehicle speed observed in km/h) were recorded on two main roads of Jakarta by using a survey vehicle. The study compares the observation results of the non-integrated system (NIS) and integrated technology system (IS). The two systems generated the CSV database (CO2 and vehicle speed); however, IS generated the automatic synchronized and error-free data output. The statistical regression analysis of CSV data (CO2 and vehicle speed) between the NIS and IS reported significant results, which means both are reliable. Still, the NIS did not require manual synchronization, with some possibility of error. The R square values show a significant gap (speed 0.99 over CO2 0.144), indicating that IS needs further development as the CO2 data varies due to technicality. The finding presents that integrating the CO2 sensor and GNSS receiver generates a more effective time synchronization process and a reliable error removal technique in developing the CSV data. This finding is a significant reference in developing the integrated satellite-based receiver system with external environmental sensors.

由于人为活动的迅速增加和严重的交通拥堵,空气污染已成为大城市的一个重大问题。因此,迫切需要实时、微观的空气监测工具,以便快速、更好地做出政策决策。目前的城市空气监测工具通常是静态的,服务于宏观区域。本研究介绍了将空气质量传感器与卫星导航接收器集成的技术开发。本研究使用了二氧化碳(CO2)MH-Z19C 传感器和实时运动全球导航卫星系统(RTK GNSS)U-Blox F9P 以及 GNSS Trimble NetR9 接收机。在雅加达的两条主干道上使用调查车记录了现场空气质量监测(观测到的二氧化碳浓度,单位为 ppm)和移动速度(观测到的车辆速度,单位为 km/h)。研究比较了非集成系统(NIS)和集成技术系统(IS)的观测结果。两个系统都生成了 CSV 数据库(二氧化碳和车速),但 IS 生成了自动同步和无差错的数据输出。对 NIS 和 IS 的 CSV 数据(二氧化碳和车辆速度)进行的统计回归分析结果显示,两者的结果都很显著,这说明两者都是可靠的。尽管如此,NIS 无需手动同步,但仍有可能出现误差。R 平方值显示出明显的差距(车速 0.99 大于二氧化碳 0.144),表明 IS 需要进一步开发,因为二氧化碳数据因技术原因而存在差异。研究结果表明,在开发 CSV 数据时,将二氧化碳传感器和全球导航卫星系统(GNSS)接收器整合在一起能产生更有效的时间同步过程和可靠的除错技术。这一发现对于开发带有外部环境传感器的集成卫星接收器系统具有重要的参考价值。
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引用次数: 0
Different electrode system based electrochemical aptasensor for the detection of dengue virus antigen in human serum: A comparative study 基于不同电极系统的电化学适体传感器用于检测人血清中的登革热病毒抗原:比较研究
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2024.100285
Mohd Rahil Hasan , Pradakshina Sharma , Saumitra Singh , Sushil Kumar , Shivani , Kirti Rani , Jagriti Narang

The current study demonstrates the manufacturing of highly sensitive aptasensr for the robust and effective detection of dengue virus antigen. The proposed electrochemical aptasensor employs both types of electrodes, namely commercialized screen-printed electrodes (C-SPEs) and self-fabricated screen-printed electrodes (SF-SPEs), were efficiently diagnose dengue virus antigen (DENV-Ag) and shows a lower limit of detection (LOD) i.e., 0.1 μg/ml. Both the electrode types were coated with chemically synthesized ZnO-Nanomaterial, which aids in electron transport, and to make it more selective highly specific DNA-aptamer was used against the DENV antigen. SEM and Uv–Vis spectra approaches were used to characterize the synthesized nanomaterial. To confirm the DENV-antigen detection results, electrochemical analysis was performed and the sensor cross-reactivity was also checked by a close member of the dengue virus i.e., chikungunya virus (CHIKV). The developed platform based on SF-SPEs & C-SPEs performed well in human serum. This investigation found that the SF-SPEs system had advanced sensitivity and responded very well to the C-SPEs. Consequently, the SF-SPEs system has emerged as a feasible choice for low-cost and highly sensitive DENV-detection and is also applicable for other analytes diagnostics.

目前的研究表明,高灵敏度的适体传感器可用于登革热病毒抗原的稳健而有效的检测。所提出的电化学适配传感器采用了两种类型的电极,即商业化丝网印刷电极(C-SPEs)和自制丝网印刷电极(SF-SPEs),可有效诊断登革病毒抗原(DENV-Ag),并显示出较低的检测限(LOD),即 0.1 μg/ml。这两种类型的电极都涂有化学合成的 ZnO 纳米材料,有助于电子传输,为了使其更具选择性,还使用了针对 DENV 抗原的高特异性 DNA-aptamer。扫描电镜和紫外可见光谱法用于表征合成的纳米材料。为了证实 DENV 抗原的检测结果,还进行了电化学分析,并用登革热病毒的近亲基孔肯雅病毒(CHIKV)检测了传感器的交叉反应性。基于 SF-SPEs 和 C-SPEs 开发的平台在人类血清中表现良好。这项研究发现,SF-SPEs 系统的灵敏度较高,对 C-SPEs 的反应也非常好。因此,SF-SPEs 系统已成为低成本、高灵敏度 DENV 检测的可行选择,也适用于其他分析物的诊断。
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引用次数: 0
Commercial chip-based tunneling magnetoresistance sensor for green-synthesized magnetic nanoparticles assay 用于绿色合成磁性纳米粒子检测的商用芯片式隧道磁阻传感器
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2024.100288
Pinaka Elda Swastika , Harlina Ardiyanti , Zurnansyah , Deska Lismawenning Puspitarum , Nurul Imani Istiqomah , Nur Aji Wibowo , Edi Suharyadi

Owing to their significant roles in multiple sectors, the demand for high-performance, rapid, user-friendly, and low-cost sensors is crucial for biosensing. This paper reports the performance of a commercial chip-based tunneling magnetoresistance (TMR) sensor for detecting green-synthesized magnetic nanoparticles (MNP) as potential magnetic labels. A Simple and low-cost design consisting of a TMR chip ALT-025 integrated with an Arduino microcontroller and a basic differential amplifier was developed to provide real-time and measurable digital readouts. Three kinds of ferrite MNPs (Fe3O4, CoFe2O4 and MnFe2O4) was synthesized by the coprecipitation method on the green synthesis approach utilizing Moringa Oleifera extracts. All sample have a face-centered cubic inverse spinel structure with average grain size of 10.3 nm, 9.2 nm and 6.1 nm for Fe3O4, CoFe2O4 and MnFe2O4, respectively. Furthermore, soft ferromagnetic behavior is identified for all sample with magnetization saturation of 55.3 emu/g, 37.6 emu/g, 19.3 emu/g for Fe3O4, CoFe2O4 and MnFe2O4, respectively. The sensor showed a promising performance in the detection of MNPs. For the three particles, the sensitivity exhibited a linear function of the MNPs concentration. The sensitivity is related not only to the particle size but also to the magnetization of the nanoparticles in the bias field. The change in the output voltage was proportional to the bias magnetization (MBias), indicating that particles with a higher bias magnetization can produce a stronger magnetic stray field on the TMR sensor surface. The sensor system successfully detected MNPs at different stray field intensities. Furthermore, a low limit of detection was achieved using these methods. Moreover, the remarkable stability and repeatability of the sensor is further validated by the steady signal acquired for 30s with an RSD of 0.5–28.5 %. Therefore, the integration of commercial chip-based TMR sensors and green-synthesized MNPs has great potential for advancing the detection of various biomolecules.

由于其在多个领域发挥着重要作用,对高性能、快速、用户友好和低成本传感器的需求对生物传感至关重要。本文报告了一种基于商用芯片的隧穿磁阻(TMR)传感器的性能,用于检测作为潜在磁性标签的绿色合成磁性纳米粒子(MNP)。为了提供实时、可测量的数字读数,我们开发了一种简单、低成本的设计,包括一个与 Arduino 微控制器和基本差分放大器集成的隧道磁阻芯片 ALT-025。在绿色合成方法中,利用油橄榄提取物通过共沉淀法合成了三种铁氧体 MNPs(Fe3O4、CoFe2O4 和 MnFe2O4)。所有样品都具有面心立方反尖晶石结构,Fe3O4、CoFe2O4 和 MnFe2O4 的平均晶粒大小分别为 10.3 nm、9.2 nm 和 6.1 nm。此外,所有样品都具有软铁磁性,Fe3O4、CoFe2O4 和 MnFe2O4 的磁化饱和度分别为 55.3 emu/g、37.6 emu/g、19.3 emu/g。该传感器在检测 MNPs 方面表现出良好的性能。对于这三种颗粒,灵敏度与 MNPs 浓度呈线性函数关系。灵敏度不仅与颗粒大小有关,还与纳米颗粒在偏置场中的磁化有关。输出电压的变化与偏置磁化(MBias)成正比,表明偏置磁化较高的颗粒能在 TMR 传感器表面产生较强的磁杂散场。传感器系统成功地检测到了不同杂散磁场强度下的 MNPs。此外,使用这些方法还实现了较低的检测限。此外,30 秒内获得的稳定信号进一步验证了传感器的出色稳定性和可重复性,RSD 为 0.5-28.5%。因此,将基于商用芯片的 TMR 传感器与绿色合成的 MNPs 相结合,在推进各种生物分子的检测方面具有巨大的潜力。
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引用次数: 0
Synthesis and characterization of indium-doped ZnO nanoparticles by coprecipitation method for highly photo-responsive UV light sensors 共沉淀法合成和表征掺铟氧化锌纳米粒子,用于高光响应紫外光传感器
Pub Date : 2024-01-01 DOI: 10.1016/j.sintl.2023.100271
Yogesh B. Waghadkar , Govind Umarji , Shankar S. Kekade , Sunit Rane , Ratna chauhan , Muthupandian Ashokkumar , Suresh W. Gosavi

In this investigation, we employed a cost-efficient co-precipitation technique to synthesize nanostructures of Indium-doped ZnO, incorporating varying percentages of Indium (0.25 %, 0.5 %, 1 %, 2 %, and 4 %) into the ZnO lattice. These Indium atoms were introduced either by replacing oxygen (O2) or occupying tetrahedral interstitial spaces within the structure. The resultant materials exhibited an average crystal size ranging from approximately 5 to 10 nm and displayed a highly crystalline nature. The UV–visible spectroscopy of these synthesized materials, revealing an excitation spectrum spanning 380 nm–395 nm. Photoluminescence measurements showed two distinct emission peaks at 390 nm and 471 nm, originates from the recombination of the free excitons through an exciton-exciton collision process and the presence of defects or impurities in the In–ZnO nanostructures. Defects in the crystal lattice, such as oxygen vacancies or interstitial defects, can create energy levels within the bandgap. Subsequently, we evaluated the suitability of these Indium-doped ZnO nanostructures for light sensor applications. Response and recovery times to infrared (IR), visible, and ultraviolet (UV) light was recorded. Remarkably, the nanostructures exhibited exceptional response and recovery times, in UV light compared to their performance with IR and visible light. This significant performance of synthesized materials in UV light shows the cost-effective co-precipitation method in fabricating Indium-doped ZnO nanostructures for UV light sensing applications.

在这项研究中,我们采用了一种具有成本效益的共沉淀技术来合成掺铟氧化锌的纳米结构,在氧化锌晶格中加入了不同比例的铟(0.25%、0.5%、1%、2% 和 4%)。这些铟原子是通过取代氧(O2)或占据结构中的四面体间隙空间而引入的。这些材料的平均晶体尺寸约为 5 至 10 纳米,具有高度结晶性。这些合成材料的紫外可见光谱显示,其激发光谱范围为 380 纳米至 395 纳米。光致发光测量结果表明,在 390 纳米和 471 纳米处有两个不同的发射峰,这源于自由激子通过激子-激子碰撞过程进行的重组,以及 In-ZnO 纳米结构中存在的缺陷或杂质。晶格中的缺陷,如氧空位或间隙缺陷,会在带隙内产生能级。随后,我们评估了这些掺铟氧化锌纳米结构在光传感器应用中的适用性。我们记录了对红外线(IR)、可见光和紫外线(UV)的响应和恢复时间。值得注意的是,与红外光和可见光相比,纳米结构在紫外光下的响应和恢复时间更长。合成材料在紫外光下的显著性能表明,用共沉淀法制造掺铟氧化锌纳米结构用于紫外光传感应用具有成本效益。
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引用次数: 0
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Sensors International
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