Pub Date : 2025-12-02DOI: 10.1016/j.susmat.2025.e01798
Mingxin Ran , Chunyan Zhang , Jiaxing Luo , Zhengquan He , Yu Jiang , Wei Xiao , Xuemin Yan
A composite material derived from graphite modified with high-specific-capacity metal oxides demonstrates significant enhancement in electrochemical performance for lithium-ion battery anodes. In this study, calcium carbide and tin (II) chloride dihydrate can be directly converted into graphite and elemental tin by a one-step thermochemical reaction. Subsequently, through a low-temperature heat treatment in air environment, thin-layer graphite-confined nano-SnO2 (SnO2@G) was obtained. The nano-sized tin dioxide generated in situ enhanced the lithium storage capacity, while the thin layer of graphite provided a flexible and tough base, effectively alleviating the volume expansion of tin dioxide. As an anode material for lithium-ion batteries, SnO2@G900 demonstrates excellent lithium storage performance, achieving a capacity of 913.5 mA h g−1 at 0.1 A g−1, and a capacity of 515.4 mA h g−1 after 400 cycles at 2 A g−1. This work proposes a simple and successful approach for producing SnO2-thin layer graphite composites, which are anticipated to represent a novel generation of anode materials for lithium-ion batteries.
用高比容金属氧化物改性石墨制备的复合材料显著提高了锂离子电池阳极的电化学性能。在本研究中,电石和二水合氯化锡可以通过一步热化学反应直接转化为石墨和单质锡。随后,通过空气环境下的低温热处理,得到了薄层石墨约束的纳米sno2 (SnO2@G)。原位生成的纳米二氧化锡增强了锂的存储能力,而石墨薄层提供了灵活而坚韧的基底,有效缓解了二氧化锡的体积膨胀。作为锂离子电池的负极材料,SnO2@G900表现出优异的锂存储性能,在0.1 ag−1下,其容量为913.5 mA h g−1,在2 ag−1下,循环400次后,其容量为515.4 mA h g−1。这项工作提出了一种简单而成功的方法来生产sno2薄层石墨复合材料,这有望代表锂离子电池的新一代负极材料。
{"title":"Thin layer graphite confined nano-SnO2 formed in-situ for advanced lithium-ion batteries","authors":"Mingxin Ran , Chunyan Zhang , Jiaxing Luo , Zhengquan He , Yu Jiang , Wei Xiao , Xuemin Yan","doi":"10.1016/j.susmat.2025.e01798","DOIUrl":"10.1016/j.susmat.2025.e01798","url":null,"abstract":"<div><div>A composite material derived from graphite modified with high-specific-capacity metal oxides demonstrates significant enhancement in electrochemical performance for lithium-ion battery anodes. In this study, calcium carbide and tin (II) chloride dihydrate can be directly converted into graphite and elemental tin by a one-step thermochemical reaction. Subsequently, through a low-temperature heat treatment in air environment, thin-layer graphite-confined nano-SnO<sub>2</sub> (SnO<sub>2</sub>@G) was obtained. The nano-sized tin dioxide generated in situ enhanced the lithium storage capacity, while the thin layer of graphite provided a flexible and tough base, effectively alleviating the volume expansion of tin dioxide. As an anode material for lithium-ion batteries, SnO<sub>2</sub>@G<sub>900</sub> demonstrates excellent lithium storage performance, achieving a capacity of 913.5 mA h g<sup>−1</sup> at 0.1 A g<sup>−1</sup>, and a capacity of 515.4 mA h g<sup>−1</sup> after 400 cycles at 2 A g<sup>−1</sup>. This work proposes a simple and successful approach for producing SnO<sub>2</sub>-thin layer graphite composites, which are anticipated to represent a novel generation of anode materials for lithium-ion batteries.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"47 ","pages":"Article e01798"},"PeriodicalIF":9.2,"publicationDate":"2025-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145692091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
While acid modification is widely employed to enhance the performance of biochar-based catalysts, the environmental implications associated with the use of non-environmentally friendly reagents remain a significant concern. A wood vinegar-modified nitrogen-doped coffee grounds biochar-supported iron catalyst (V-Fe@N-BC) was successfully synthesized and exhibited high efficacy for activating potassium persulfate (PS) to degrade persistent organic pollutants(POPs). The bisphenol A(BPA) degradation rate constant of V-Fe@N-BC is 6 times on that of Fe@N-BC (non-wood vinegar modification). The wood vinegar generated exceptional microstructure and high density of reaction sites on biochar (BC). The surface characterization of the V-Fe@N-BC revealed an increase in carbonyl (C=O) content from 18.44 % to 35.79 % and a rise in specific surface area from 145.78 m2 g−1 to 396.77 m2 g−1. Furthermore, the V-Fe@N-BC exhibits not only outstanding catalytic activity but also strong environmental adaptability and excellent recyclability. This study proposes the application of wood vinegar and biochar derived from agroforestry wastes as a sustainable alternative modifiers for persulfate activing to clean wastewater.
{"title":"Wood vinegar-enhanced iron-loaded coffee grounds biochar activated persulfate for removing persistent organic pollutants","authors":"Jiujiu Xiong , Junfeng Zhu , Qingzhu Zeng , Zhaohan Zhang , Jiahui Liu , Wen Zha , Guanghua Zhang","doi":"10.1016/j.susmat.2025.e01800","DOIUrl":"10.1016/j.susmat.2025.e01800","url":null,"abstract":"<div><div>While acid modification is widely employed to enhance the performance of biochar-based catalysts, the environmental implications associated with the use of non-environmentally friendly reagents remain a significant concern. A wood vinegar-modified nitrogen-doped coffee grounds biochar-supported iron catalyst (V-Fe@N-BC) was successfully synthesized and exhibited high efficacy for activating potassium persulfate (PS) to degrade persistent organic pollutants(POPs). The bisphenol A(BPA) degradation rate constant of V-Fe@N-BC is 6 times on that of Fe@N-BC (non-wood vinegar modification). The wood vinegar generated exceptional microstructure and high density of reaction sites on biochar (BC). The surface characterization of the V-Fe@N-BC revealed an increase in carbonyl (C=O) content from 18.44 % to 35.79 % and a rise in specific surface area from 145.78 m<sup>2</sup> g<sup>−1</sup> to 396.77 m<sup>2</sup> g<sup>−1</sup>. Furthermore, the V-Fe@N-BC exhibits not only outstanding catalytic activity but also strong environmental adaptability and excellent recyclability. This study proposes the application of wood vinegar and biochar derived from agroforestry wastes as a sustainable alternative modifiers for persulfate activing to clean wastewater.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"47 ","pages":"Article e01800"},"PeriodicalIF":9.2,"publicationDate":"2025-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145748071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The performance and stability of solid oxide fuel cell (SOFC) cathodes are severely limited by chromium poisoning. To address these concerns, we designed and investigated A-site two high-entropy perovskite oxides, which possess equivalent configuration entropy but distinct elemental compositions. Compared to the conventional double perovskite PrBaCo2O5+δ (PBC), the PBSLSC cathode demonstrated superior oxygen reduction reaction activity, while PBSNGC showed inferior performance. Crucially, both high-entropy cathodes exhibited significantly enhanced resistance to chromium poisoning, as evidenced by the suppressed formation of SrCrO4 and Co3O4 secondary phases. This improved Cr-tolerance is due to high-entropy sluggish diffusion effect, which mitigates the segregation of Ba/Sr and cobalt elements. Our findings demonstrate that while configurational entropy is critical, the specific elemental composition is a decisive factor in determining cathode activity. This work establishes high-entropy engineering as a powerful strategy for developing highly active and Cr-tolerant cathodes for intermediate-temperature SOFCs.
{"title":"Compositional and configuration entropy tuning enabling Cr-resistance cathodes for solid oxide fuel cells","authors":"Zhe Wang , Hongru Hao , Yushi Feng , Dmitry Sergeevich Tsvetkov , Zhe Lv , Lingling Xu , Bo Wei","doi":"10.1016/j.susmat.2025.e01769","DOIUrl":"10.1016/j.susmat.2025.e01769","url":null,"abstract":"<div><div>The performance and stability of solid oxide fuel cell (SOFC) cathodes are severely limited by chromium poisoning. To address these concerns, we designed and investigated A-site two high-entropy perovskite oxides, which possess equivalent configuration entropy but distinct elemental compositions. Compared to the conventional double perovskite PrBaCo<sub>2</sub>O<sub>5+δ</sub> (PBC), the PBSLSC cathode demonstrated superior oxygen reduction reaction activity, while PBSNGC showed inferior performance. Crucially, both high-entropy cathodes exhibited significantly enhanced resistance to chromium poisoning, as evidenced by the suppressed formation of SrCrO<sub>4</sub> and Co<sub>3</sub>O<sub>4</sub> secondary phases. This improved Cr-tolerance is due to high-entropy sluggish diffusion effect, which mitigates the segregation of Ba/Sr and cobalt elements. Our findings demonstrate that while configurational entropy is critical, the specific elemental composition is a decisive factor in determining cathode activity. This work establishes high-entropy engineering as a powerful strategy for developing highly active and Cr-tolerant cathodes for intermediate-temperature SOFCs.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"46 ","pages":"Article e01769"},"PeriodicalIF":9.2,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145614421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.susmat.2025.e01775
Gaowen Zhao , Fengzu Peng , Yaning Ding , Zhibao Nie , Feng Wei , Cheng Wang , Shijun Ding
The accumulation of iron ore tailings (IOT) poses significant environmental risks. Efficient utilization of IOT in cast-in-place concrete structures can mitigate these impacts and advance sustainability. To address the degradation mechanisms of cast-in-situ concrete with IOT in complex sulfate-chloride corrosion environments, IOT concrete (IOTC) were studied under four conditions, including no attack (NA), external attack (EA), internal attack (IA), and combined attack (CA). Specimens with 0 %, 25 % and 50 % IOT replacement ratios of fine aggregates were prepared and put in different corrosion conditions for 180 days. Dimension, mass, surface changes and compressive and flexural strength were continuously measured. Mineral, microstructural and pore structure evolution were analyzed. The effect of pore structure parameters on compressive strength was evaluated by the GM(1,3) model and Pearson correlation. Life cycle assessment is used to assess the environmental impact of IOTC. Results indicate that IA bypasses the diffusion barrier and occurs directly from the inside, which can cause more severe damage. Among them, chemical corrosion is the main cause of concrete deterioration, and the increasement of macropores is the direct cause of concrete deterioration. IOTC with 25 % IOT can enhance the durability of concrete by reducing sulfate penetration and corrosion through the utilization of physical, chemical, and transport mechanisms. However, excessive IOT content will reduce durability. Life cycle assessment confirms IOTC reduces the environmental impact of IOT. This study provides a theoretical basis for the reutilization of iron ore tailings and offers practical insights for designing durable ecological concrete in harsh environments.
{"title":"Application of iron tailings as fine aggregates in cast-in-situ concrete: The durability evaluation under sulfate and chloride combined corrosion","authors":"Gaowen Zhao , Fengzu Peng , Yaning Ding , Zhibao Nie , Feng Wei , Cheng Wang , Shijun Ding","doi":"10.1016/j.susmat.2025.e01775","DOIUrl":"10.1016/j.susmat.2025.e01775","url":null,"abstract":"<div><div>The accumulation of iron ore tailings (IOT) poses significant environmental risks. Efficient utilization of IOT in cast-in-place concrete structures can mitigate these impacts and advance sustainability. To address the degradation mechanisms of cast-in-situ concrete with IOT in complex sulfate-chloride corrosion environments, IOT concrete (IOTC) were studied under four conditions, including no attack (NA), external attack (EA), internal attack (IA), and combined attack (CA). Specimens with 0 %, 25 % and 50 % IOT replacement ratios of fine aggregates were prepared and put in different corrosion conditions for 180 days. Dimension, mass, surface changes and compressive and flexural strength were continuously measured. Mineral, microstructural and pore structure evolution were analyzed. The effect of pore structure parameters on compressive strength was evaluated by the GM(1,3) model and Pearson correlation. Life cycle assessment is used to assess the environmental impact of IOTC. Results indicate that IA bypasses the diffusion barrier and occurs directly from the inside, which can cause more severe damage. Among them, chemical corrosion is the main cause of concrete deterioration, and the increasement of macropores is the direct cause of concrete deterioration. IOTC with 25 % IOT can enhance the durability of concrete by reducing sulfate penetration and corrosion through the utilization of physical, chemical, and transport mechanisms. However, excessive IOT content will reduce durability. Life cycle assessment confirms IOTC reduces the environmental impact of IOT. This study provides a theoretical basis for the reutilization of iron ore tailings and offers practical insights for designing durable ecological concrete in harsh environments.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"46 ","pages":"Article e01775"},"PeriodicalIF":9.2,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145614420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.susmat.2025.e01783
Zeinab Qazanfarzadeh, Amparo Jiménez-Quero
The growing demand for safe and fresh food, coupled with the challenge of significant food loss and waste, has stimulated research on active packaging. In this study, artichoke leaf extract (ALE), obtained from food loss streams, was mixed with carboxymethyl cellulose (CMC) to develop an active coating on polylactic acid (PLA)-based packaging using a spray-coating approach. Prior surface modification of PLA using 1 % w/v PLA containing 20 wt% polyethylene glycol improved hydrophilicity and enhanced coating adhesion. Substituting ALE for CMC reduced coating solution viscosity, allowing a uniform coating. The inclusion of ALE conferred antioxidant (40–67 % DPPH scavenging) and antibacterial properties (2.11 and 1.08 log reduction against E. coli and S. aureus) to the coating, with controlled release governed by diffusion and swelling in lipophilic media (50 % ethanol) and predominantly swelling-controlled release in hydrophilic media (10 % ethanol and 3 % acetic acid). Analysis of the performance of active packaging in preservation of cut apples and strawberries demonstrated that ALE-coated PLA packaging effectively slowed oxidation, acid degradation, and microbial proliferation in cut apples and strawberries over 8 and 10 days storage, respectively, thereby improving overall freshness. While limited improvements were observed for firmness and browning in apples, coated packaging significantly enhanced phenolic content, antioxidant activity, and microbial stability, with strawberries showing the strongest protective effects. These findings highlight the potential of ALE-based coatings as a sustainable strategy to extend fruit shelf life and reduce food waste through active packaging solutions.
{"title":"Artichoke leaf extract coating on polylactic acid packaging to prolong fruit shelf life","authors":"Zeinab Qazanfarzadeh, Amparo Jiménez-Quero","doi":"10.1016/j.susmat.2025.e01783","DOIUrl":"10.1016/j.susmat.2025.e01783","url":null,"abstract":"<div><div>The growing demand for safe and fresh food, coupled with the challenge of significant food loss and waste, has stimulated research on active packaging. In this study, artichoke leaf extract (ALE), obtained from food loss streams, was mixed with carboxymethyl cellulose (CMC) to develop an active coating on polylactic acid (PLA)-based packaging using a spray-coating approach. Prior surface modification of PLA using 1 % w/v PLA containing 20 wt% polyethylene glycol improved hydrophilicity and enhanced coating adhesion. Substituting ALE for CMC reduced coating solution viscosity, allowing a uniform coating. The inclusion of ALE conferred antioxidant (40–67 % DPPH scavenging) and antibacterial properties (2.11 and 1.08 log reduction against <em>E. coli</em> and <em>S. aureus</em>) to the coating, with controlled release governed by diffusion and swelling in lipophilic media (50 % ethanol) and predominantly swelling-controlled release in hydrophilic media (10 % ethanol and 3 % acetic acid). Analysis of the performance of active packaging in preservation of cut apples and strawberries demonstrated that ALE-coated PLA packaging effectively slowed oxidation, acid degradation, and microbial proliferation in cut apples and strawberries over 8 and 10 days storage, respectively, thereby improving overall freshness. While limited improvements were observed for firmness and browning in apples, coated packaging significantly enhanced phenolic content, antioxidant activity, and microbial stability, with strawberries showing the strongest protective effects. These findings highlight the potential of ALE-based coatings as a sustainable strategy to extend fruit shelf life and reduce food waste through active packaging solutions.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"46 ","pages":"Article e01783"},"PeriodicalIF":9.2,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145614566","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.susmat.2025.e01778
Lun Chen , Fu-Lu Chang , Zi-Yang Hua , Fu-Rui Chen , Han Yang , Sheng Wang , Xian-Wu Cao , Xiao-Chun Yin , Guang-Jian He
Conversion of plastic waste into functional chemicals stands as a promising and sustainable strategy for augmenting the availability of high-value chemical feedstocks. In this study, we present a laser-induced pyrolysis (LIP) approach for upcycling end-of-life polyethylene (PE) into long-chain terminal alkenes (LT-alkenes), which is well-suited for subsequent downstream conversion into high-value amphiphilic copolymers. The ultrafast heating (>8 × 104 °C/s) and quenching (>4000 °C/s) process achieved by 4.53 kW/cm2 infrared laser irradiation plays a critical role in the kinetic-controlled degradation of polyethylene into long-chain terminal alkenes. This unique thermal profile—difficult to replicate with conventional pyrolysis methods—effectively suppresses by-product formation while eliminating the need for catalysts. Using recycled yogurt bottles as a waste model, we demonstrate a high yield of approximately 65 wt% toward LT-alkenes. These long-chain terminal alkenes are then functionalized into an amphiphilic polyethylene-block-poly(ethylene glycol) (PE-b-PEG) copolymer by end-group grafting reactions. This PE-b-PEG is employed to fabricate hydrophilic and anti-fouling micrporous membranes with a polyethylene matrix in a liquid-liquid thermally induced phase separation (L-LTIPS) process. Compared to pure polyethylene L-LTIPS membranes, the incorporation of 15 wt% PE-b-PEG results in a marked improvement in antifouling performance, as evidence by a reduced water contact angle (117.6° to 77.6°), a 90 % decrease in protein adsorption (1.12 to 0.11 mg/cm2), and a 33 % increase in water permeability, collectively demonstrating strongly potential for water treatment applications.
{"title":"Laser-induced pyrolysis of waste polyethylene to long-chain terminal alkenes and amphiphilic functionalization for anti-fouling film application","authors":"Lun Chen , Fu-Lu Chang , Zi-Yang Hua , Fu-Rui Chen , Han Yang , Sheng Wang , Xian-Wu Cao , Xiao-Chun Yin , Guang-Jian He","doi":"10.1016/j.susmat.2025.e01778","DOIUrl":"10.1016/j.susmat.2025.e01778","url":null,"abstract":"<div><div>Conversion of plastic waste into functional chemicals stands as a promising and sustainable strategy for augmenting the availability of high-value chemical feedstocks. In this study, we present a laser-induced pyrolysis (LIP) approach for upcycling end-of-life polyethylene (PE) into long-chain terminal alkenes (LT-alkenes), which is well-suited for subsequent downstream conversion into high-value amphiphilic copolymers. The ultrafast heating (>8 × 10<sup>4</sup> °C/s) and quenching (>4000 °C/s) process achieved by 4.53 kW/cm<sup>2</sup> infrared laser irradiation plays a critical role in the kinetic-controlled degradation of polyethylene into long-chain terminal alkenes. This unique thermal profile—difficult to replicate with conventional pyrolysis methods—effectively suppresses by-product formation while eliminating the need for catalysts. Using recycled yogurt bottles as a waste model, we demonstrate a high yield of approximately 65 wt% toward LT-alkenes. These long-chain terminal alkenes are then functionalized into an amphiphilic polyethylene-<em>block</em>-poly(ethylene glycol) (PE-<em>b</em>-PEG) copolymer by end-group grafting reactions. This PE-<em>b</em>-PEG is employed to fabricate hydrophilic and anti-fouling micrporous membranes with a polyethylene matrix in a liquid-liquid thermally induced phase separation (L-LTIPS) process. Compared to pure polyethylene L-LTIPS membranes, the incorporation of 15 wt% PE-b-PEG results in a marked improvement in antifouling performance, as evidence by a reduced water contact angle (117.6° to 77.6°), a 90 % decrease in protein adsorption (1.12 to 0.11 mg/cm<sup>2</sup>), and a 33 % increase in water permeability, collectively demonstrating strongly potential for water treatment applications.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"46 ","pages":"Article e01778"},"PeriodicalIF":9.2,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145614565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-01DOI: 10.1016/j.susmat.2025.e01780
Xinrui Zhang , Jun Wang , Man Zhou , Yuanyuan Yu , Ping Wang , Qiang Wang
In recent years, with the advancement in the consumer market and industrial trends, wool has shown new vitality in the fields of outdoor sports apparel and smart wearable textiles due to its unique properties. However, the inherent felting characteristic of wool leads to undesirable dimensional shrinkage after machine washing, which necessitates that wool products be dry-cleaned. Conventional dry cleaning solvents like perchloroethylene are considered to be carcinogenic and detrimental to the environment. Factories usually adopt the chlorination process to manufacture machine-washable wool textiles, which may release harmful adsorbable organic halides (AOX) to the environment. Herein, we developed a “valley-filling and peak-shaving” dual-effect enzymatic anti-felting strategy as an ideal sustainable alternative. The pre-filling not only inhibits the protease from penetrating the fiber interior but also enhances its adsorption on the fiber surface. Hence, the compound proteases, possessing efficacy in degrading keratin-rich scales, primarily hydrolyze the fiber surface. This selective hydrolysis endows these textiles with machine-washability while preserving their original mechanical properties and color attributes, achieving a felting shrinkage of 5.06 % and an increase in tensile strength of 0.27 % for wool fabric. In summary, we present a green and feasible enzymatic approach to eliminate shrinkage, thereby facilitating the diversified application of wool products.
{"title":"Valley-filling and peak-shaving: A dual-effect and controllable enzymatic approach for achieving machine-washability of dyed wool textiles as a sustainable alternative to dry cleaning","authors":"Xinrui Zhang , Jun Wang , Man Zhou , Yuanyuan Yu , Ping Wang , Qiang Wang","doi":"10.1016/j.susmat.2025.e01780","DOIUrl":"10.1016/j.susmat.2025.e01780","url":null,"abstract":"<div><div>In recent years, with the advancement in the consumer market and industrial trends, wool has shown new vitality in the fields of outdoor sports apparel and smart wearable textiles due to its unique properties. However, the inherent felting characteristic of wool leads to undesirable dimensional shrinkage after machine washing, which necessitates that wool products be dry-cleaned. Conventional dry cleaning solvents like perchloroethylene are considered to be carcinogenic and detrimental to the environment. Factories usually adopt the chlorination process to manufacture machine-washable wool textiles, which may release harmful adsorbable organic halides (AOX) to the environment. Herein, we developed a “valley-filling and peak-shaving” dual-effect enzymatic anti-felting strategy as an ideal sustainable alternative. The pre-filling not only inhibits the protease from penetrating the fiber interior but also enhances its adsorption on the fiber surface. Hence, the compound proteases, possessing efficacy in degrading keratin-rich scales, primarily hydrolyze the fiber surface. This selective hydrolysis endows these textiles with machine-washability while preserving their original mechanical properties and color attributes, achieving a felting shrinkage of 5.06 % and an increase in tensile strength of 0.27 % for wool fabric. In summary, we present a green and feasible enzymatic approach to eliminate shrinkage, thereby facilitating the diversified application of wool products.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"46 ","pages":"Article e01780"},"PeriodicalIF":9.2,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145614563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-29DOI: 10.1016/j.susmat.2025.e01796
Guoqiang Sun , Ruiqing Sun , Chen Yang , Yiming Li , Tong Lu , Guangchen Wang
The development of novel eco-friendly polyurethane bitumen modifiers utilizing sustainable bio-based resources was currently a research hotspot. Castor oil (CO), with its unique chemical structure (containing hydroxyl groups) and bio-renewable advantages, represented an ideal choice for preparing bio-based PU. This study aimed to develop a high-performance, environmentally friendly renewable castor oil-based polyurethane modified bitumen (CO-PUMB), using petroleum-based polyurethane modified bitumen (P-PUMB) as a comparison, to provide insights for advancing the greening of road construction materials. First, the PU composition (isocyanate index R = 1, hard segment content Ch = 20 %) was designed and optimized, and determine the optimal hydroxyl substitution ratio for CO-substituted petroleum-derived polytetrahydrofuran (PTMG). Subsequently, the preparation process (90 °C, 400 rpm, 2 min) and the curing process (100 °C, 2 h) were established. Then, five types of CO-PUMB and P-PUMB with varying PU contents were prepared and subjected to microscopic morphology observation, physical performance testing, and rheological testing. Fluorescence microscopy observation indicated that, benefiting from the trihydroxy structure and low molecular weight of castor oil (CO), CO-PU formed an earlier, more extensive, and more efficient chemically cross-linked network than P-PU at a lower PU content (≥40 %). In contrast, P-PU relied primarily on physical entanglement and required a higher PU content (60 %) to achieve cross-linking. Physical performance and rheological tests demonstrated that CO-PUMB, leveraging its dense chemical cross-linked network, exhibited significantly superior high-temperature stability, fatigue life, elastic recovery, and resistance to permanent deformation compared to P-PUMB. Additionally, increasing the CO/P-PU content enhanced the overall performance of CO/P-PUMB across the entire frequency (temperature) range. Notably, the performance improvement in CO-PUMB within the high-frequency (low-temperature) region was dependent on an effective crosslinking network, while that in P-PUMB relied on the high motional freedom generated by PTMG molecules. The experiments demonstrated that CO-PUMB incorporating optimized CO substitution (≥40 % CO-PU) represented an environmentally friendly, high-performance bitumen material with excellent high and low temperature performance and anti-fatigue capability.
{"title":"Development and performance assessment of polyurethane modified bitumen utilizing castor oil as a sustainable feedstock","authors":"Guoqiang Sun , Ruiqing Sun , Chen Yang , Yiming Li , Tong Lu , Guangchen Wang","doi":"10.1016/j.susmat.2025.e01796","DOIUrl":"10.1016/j.susmat.2025.e01796","url":null,"abstract":"<div><div>The development of novel eco-friendly polyurethane bitumen modifiers utilizing sustainable bio-based resources was currently a research hotspot. Castor oil (CO), with its unique chemical structure (containing hydroxyl groups) and bio-renewable advantages, represented an ideal choice for preparing bio-based PU. This study aimed to develop a high-performance, environmentally friendly renewable castor oil-based polyurethane modified bitumen (CO-PUMB), using petroleum-based polyurethane modified bitumen (P-PUMB) as a comparison, to provide insights for advancing the greening of road construction materials. First, the PU composition (isocyanate index <em>R</em> = 1, hard segment content <em>C</em><sub><em>h</em></sub> = 20 %) was designed and optimized, and determine the optimal hydroxyl substitution ratio for <em>CO</em>-substituted petroleum-derived polytetrahydrofuran (PTMG). Subsequently, the preparation process (90 °C, 400 rpm, 2 min) and the curing process (100 °C, 2 h) were established. Then, five types of CO-PUMB and P-PUMB with varying PU contents were prepared and subjected to microscopic morphology observation, physical performance testing, and rheological testing. Fluorescence microscopy observation indicated that, benefiting from the trihydroxy structure and low molecular weight of castor oil (CO), CO-PU formed an earlier, more extensive, and more efficient chemically cross-linked network than P-PU at a lower PU content (≥40 %). In contrast, P-PU relied primarily on physical entanglement and required a higher PU content (60 %) to achieve cross-linking. Physical performance and rheological tests demonstrated that CO-PUMB, leveraging its dense chemical cross-linked network, exhibited significantly superior high-temperature stability, fatigue life, elastic recovery, and resistance to permanent deformation compared to P-PUMB. Additionally, increasing the CO/P-PU content enhanced the overall performance of CO/P-PUMB across the entire frequency (temperature) range. Notably, the performance improvement in CO-PUMB within the high-frequency (low-temperature) region was dependent on an effective crosslinking network, while that in P-PUMB relied on the high motional freedom generated by PTMG molecules. The experiments demonstrated that CO-PUMB incorporating optimized CO substitution (≥40 % CO-PU) represented an environmentally friendly, high-performance bitumen material with excellent high and low temperature performance and anti-fatigue capability.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"47 ","pages":"Article e01796"},"PeriodicalIF":9.2,"publicationDate":"2025-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145748131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Porous nature and water desorption capacity of recycled fine brick aggregate (RFCB) is crucial to the long-term evolution of shrinkage behavior of recycled concrete (RC) exposed to the dry environment. Thus, this study assessed both the pore feature and water desorption of RFCB with different particle sizes (including 0–5 mm, 0.075–5 mm and 0.15–5 mm), followed by the effect of particle size, replacement level and initial saturation degree of RFCB on the microstructure, strength development, water migration and drying shrinkage of RC. Results shown that the pore feature of RFCB yielded coarse pore size and high porosity with an increase in particle size, which in turn endowed a superior water desorption potential. Microstructure revealed that incorporating porous RFCB into RC increased the pore volume, porosity and total capillary pores, whereas performed better in improving the average pore diameter and interface bonding. The presence of RFCB imposed a deteriorate effect on the compressive strength, relative humidity, electrical resistivity and drying shrinkage, and this degraded effect exacerbated as particle size and replacement ratio raised. However, introducing full saturation degree of fine RFCB was beneficial for mitigating the relative humidity reduction, electrical resistivity increment and drying shrinkage development. Finally, the drying shrinkage-prediction model considering RFCB coefficients was developed based on the CEB-FIP model, which was helpful for the design of low-carbon and durable RC.
{"title":"Evolution of drying shrinkage and water migration of concrete: Effects of pore feature and water desorption of recycled fine brick aggregate","authors":"Juntao Dang , Huiqiang Jing , Jun Zhao , Wei Zhang , Jianzhuang Xiao , Hexin Zhang","doi":"10.1016/j.susmat.2025.e01789","DOIUrl":"10.1016/j.susmat.2025.e01789","url":null,"abstract":"<div><div>Porous nature and water desorption capacity of recycled fine brick aggregate (RFCB) is crucial to the long-term evolution of shrinkage behavior of recycled concrete (RC) exposed to the dry environment. Thus, this study assessed both the pore feature and water desorption of RFCB with different particle sizes (including 0–5 mm, 0.075–5 mm and 0.15–5 mm), followed by the effect of particle size, replacement level and initial saturation degree of RFCB on the microstructure, strength development, water migration and drying shrinkage of RC. Results shown that the pore feature of RFCB yielded coarse pore size and high porosity with an increase in particle size, which in turn endowed a superior water desorption potential. Microstructure revealed that incorporating porous RFCB into RC increased the pore volume, porosity and total capillary pores, whereas performed better in improving the average pore diameter and interface bonding. The presence of RFCB imposed a deteriorate effect on the compressive strength, relative humidity, electrical resistivity and drying shrinkage, and this degraded effect exacerbated as particle size and replacement ratio raised. However, introducing full saturation degree of fine RFCB was beneficial for mitigating the relative humidity reduction, electrical resistivity increment and drying shrinkage development. Finally, the drying shrinkage-prediction model considering RFCB coefficients was developed based on the CEB-FIP model, which was helpful for the design of low-carbon and durable RC.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"47 ","pages":"Article e01789"},"PeriodicalIF":9.2,"publicationDate":"2025-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145692013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-27DOI: 10.1016/j.susmat.2025.e01791
Shoukat Ali Mugheri , Ali Azam , Touqeer Aslam , Ammar Ahmed , Zutao Zhang , Chengliang Fan , Juhuang Song
Urbanization and transport development boost energy consumption; however, roadway harvesters prioritize traffic infrastructure needs with limited attention to powering nearby facilities. This research proposed a road stud-based mechanical energy extractor (MEE) system that uses vehicle kinetic energy to power sensors for health monitoring at a smart health unit adjacent to the road. The proposed setup comprises four modules: an energy intake module that captures vehicular kinetic energy, a mechanical drive module using a rack-and-pinion mechanism for energy conversion, a power output module that generates electrical energy, and a power backup module that ensures stable energy storage and supply. Mathematical modeling, finite element analysis using ANSYS to evaluate structural stability under varying loads, simulation with MATLAB Simscape, laboratory experiments using a Mechanical Testing and Sensing (MTS) machine, and field testing were conducted to assess the performance of the proposed setup model. The proposed system achieved a maximum RMS voltage of 2.42 V at a resistance of 6 Ω and an optimum RMS power of 7.05 W at a resistance of 2 Ω with an excitation frequency of 4 Hz. In the field test, the system attained an RMS power of 26.6 W at a speed of 20 km/h with the same load resistance. Furthermore, a deep learning-based performance monitoring system using the Gated Recurrent Unit (GRU) framework to categorize the motion states (low, medium, and high) and forecast maintenance requirements, attaining a training precision rate of 99.9 %. This novel approach generates higher energy at low traffic speeds, ensures a continuous power supply to IoT-based health sensors, and offers enhanced durability and adaptability.
{"title":"A road stud-based mechanical energy extractor with AI-supported monitoring for intelligent healthcare infrastructure","authors":"Shoukat Ali Mugheri , Ali Azam , Touqeer Aslam , Ammar Ahmed , Zutao Zhang , Chengliang Fan , Juhuang Song","doi":"10.1016/j.susmat.2025.e01791","DOIUrl":"10.1016/j.susmat.2025.e01791","url":null,"abstract":"<div><div>Urbanization and transport development boost energy consumption; however, roadway harvesters prioritize traffic infrastructure needs with limited attention to powering nearby facilities. This research proposed a road stud-based mechanical energy extractor (MEE) system that uses vehicle kinetic energy to power sensors for health monitoring at a smart health unit adjacent to the road. The proposed setup comprises four modules: an energy intake module that captures vehicular kinetic energy, a mechanical drive module using a rack-and-pinion mechanism for energy conversion, a power output module that generates electrical energy, and a power backup module that ensures stable energy storage and supply. Mathematical modeling, finite element analysis using ANSYS to evaluate structural stability under varying loads, simulation with MATLAB Simscape, laboratory experiments using a Mechanical Testing and Sensing (MTS) machine, and field testing were conducted to assess the performance of the proposed setup model. The proposed system achieved a maximum RMS voltage of 2.42 V at a resistance of 6 Ω and an optimum RMS power of 7.05 W at a resistance of 2 Ω with an excitation frequency of 4 Hz. In the field test, the system attained an RMS power of 26.6 W at a speed of 20 km/h with the same load resistance. Furthermore, a deep learning-based performance monitoring system using the Gated Recurrent Unit (GRU) framework to categorize the motion states (low, medium, and high) and forecast maintenance requirements, attaining a training precision rate of 99.9 %. This novel approach generates higher energy at low traffic speeds, ensures a continuous power supply to IoT-based health sensors, and offers enhanced durability and adaptability.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"47 ","pages":"Article e01791"},"PeriodicalIF":9.2,"publicationDate":"2025-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145692032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}