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Thin layer graphite confined nano-SnO2 formed in-situ for advanced lithium-ion batteries 原位形成了一层石墨约束的纳米sno2,用于先进锂离子电池
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-02 DOI: 10.1016/j.susmat.2025.e01798
Mingxin Ran , Chunyan Zhang , Jiaxing Luo , Zhengquan He , Yu Jiang , Wei Xiao , Xuemin Yan
A composite material derived from graphite modified with high-specific-capacity metal oxides demonstrates significant enhancement in electrochemical performance for lithium-ion battery anodes. In this study, calcium carbide and tin (II) chloride dihydrate can be directly converted into graphite and elemental tin by a one-step thermochemical reaction. Subsequently, through a low-temperature heat treatment in air environment, thin-layer graphite-confined nano-SnO2 (SnO2@G) was obtained. The nano-sized tin dioxide generated in situ enhanced the lithium storage capacity, while the thin layer of graphite provided a flexible and tough base, effectively alleviating the volume expansion of tin dioxide. As an anode material for lithium-ion batteries, SnO2@G900 demonstrates excellent lithium storage performance, achieving a capacity of 913.5 mA h g−1 at 0.1 A g−1, and a capacity of 515.4 mA h g−1 after 400 cycles at 2 A g−1. This work proposes a simple and successful approach for producing SnO2-thin layer graphite composites, which are anticipated to represent a novel generation of anode materials for lithium-ion batteries.
用高比容金属氧化物改性石墨制备的复合材料显著提高了锂离子电池阳极的电化学性能。在本研究中,电石和二水合氯化锡可以通过一步热化学反应直接转化为石墨和单质锡。随后,通过空气环境下的低温热处理,得到了薄层石墨约束的纳米sno2 (SnO2@G)。原位生成的纳米二氧化锡增强了锂的存储能力,而石墨薄层提供了灵活而坚韧的基底,有效缓解了二氧化锡的体积膨胀。作为锂离子电池的负极材料,SnO2@G900表现出优异的锂存储性能,在0.1 ag−1下,其容量为913.5 mA h g−1,在2 ag−1下,循环400次后,其容量为515.4 mA h g−1。这项工作提出了一种简单而成功的方法来生产sno2薄层石墨复合材料,这有望代表锂离子电池的新一代负极材料。
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引用次数: 0
Wood vinegar-enhanced iron-loaded coffee grounds biochar activated persulfate for removing persistent organic pollutants 木醋增强铁负载咖啡渣生物炭活化过硫酸盐去除持久性有机污染物
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-02 DOI: 10.1016/j.susmat.2025.e01800
Jiujiu Xiong , Junfeng Zhu , Qingzhu Zeng , Zhaohan Zhang , Jiahui Liu , Wen Zha , Guanghua Zhang
While acid modification is widely employed to enhance the performance of biochar-based catalysts, the environmental implications associated with the use of non-environmentally friendly reagents remain a significant concern. A wood vinegar-modified nitrogen-doped coffee grounds biochar-supported iron catalyst (V-Fe@N-BC) was successfully synthesized and exhibited high efficacy for activating potassium persulfate (PS) to degrade persistent organic pollutants(POPs). The bisphenol A(BPA) degradation rate constant of V-Fe@N-BC is 6 times on that of Fe@N-BC (non-wood vinegar modification). The wood vinegar generated exceptional microstructure and high density of reaction sites on biochar (BC). The surface characterization of the V-Fe@N-BC revealed an increase in carbonyl (C=O) content from 18.44 % to 35.79 % and a rise in specific surface area from 145.78 m2 g−1 to 396.77 m2 g−1. Furthermore, the V-Fe@N-BC exhibits not only outstanding catalytic activity but also strong environmental adaptability and excellent recyclability. This study proposes the application of wood vinegar and biochar derived from agroforestry wastes as a sustainable alternative modifiers for persulfate activing to clean wastewater.
虽然酸改性被广泛用于提高生物炭基催化剂的性能,但与使用非环境友好型试剂相关的环境影响仍然是一个重大问题。成功合成了木醋修饰的氮掺杂咖啡渣生物炭负载铁催化剂(V-Fe@N-BC),该催化剂具有活化过硫酸钾(PS)降解持久性有机污染物(POPs)的高效能。V-Fe@N-BC的双酚A(BPA)降解速率常数是Fe@N-BC(非木醋改性)的6倍。木醋在生物炭(BC)上产生了特殊的微观结构和高密度的反应位点。V-Fe@N-BC的表面表征表明,羰基(C=O)含量从18.44%增加到35.79%,比表面积从145.78 m2 g−1增加到396.77 m2 g−1。此外,V-Fe@N-BC不仅具有出色的催化活性,而且具有较强的环境适应性和优良的可回收性。本研究提出了将木醋和来自农林废弃物的生物炭作为过硫酸盐净化废水的可持续替代改性剂的应用。
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引用次数: 0
Compositional and configuration entropy tuning enabling Cr-resistance cathodes for solid oxide fuel cells 固体氧化物燃料电池中铬电阻阴极的成分和配置熵调整
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 DOI: 10.1016/j.susmat.2025.e01769
Zhe Wang , Hongru Hao , Yushi Feng , Dmitry Sergeevich Tsvetkov , Zhe Lv , Lingling Xu , Bo Wei
The performance and stability of solid oxide fuel cell (SOFC) cathodes are severely limited by chromium poisoning. To address these concerns, we designed and investigated A-site two high-entropy perovskite oxides, which possess equivalent configuration entropy but distinct elemental compositions. Compared to the conventional double perovskite PrBaCo2O5+δ (PBC), the PBSLSC cathode demonstrated superior oxygen reduction reaction activity, while PBSNGC showed inferior performance. Crucially, both high-entropy cathodes exhibited significantly enhanced resistance to chromium poisoning, as evidenced by the suppressed formation of SrCrO4 and Co3O4 secondary phases. This improved Cr-tolerance is due to high-entropy sluggish diffusion effect, which mitigates the segregation of Ba/Sr and cobalt elements. Our findings demonstrate that while configurational entropy is critical, the specific elemental composition is a decisive factor in determining cathode activity. This work establishes high-entropy engineering as a powerful strategy for developing highly active and Cr-tolerant cathodes for intermediate-temperature SOFCs.
铬中毒严重限制了固体氧化物燃料电池(SOFC)阴极的性能和稳定性。为了解决这些问题,我们设计并研究了a位两种高熵钙钛矿氧化物,它们具有相同的构型熵,但元素组成不同。与传统的双钙钛矿PrBaCo2O5+δ (PBC)相比,PBSLSC阴极表现出更高的氧还原反应活性,而PBSNGC表现出更低的氧还原反应活性。重要的是,这两种高熵阴极对铬中毒的抗性都有显著增强,这可以通过抑制SrCrO4和Co3O4二次相的形成来证明。这种耐铬性的提高是由于高熵的缓慢扩散效应,减缓了Ba/Sr和钴元素的偏析。我们的研究结果表明,虽然构型熵是至关重要的,但具体的元素组成是决定阴极活性的决定性因素。这项工作建立了高熵工程作为开发高活性和耐铬中温sofc阴极的有力策略。
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引用次数: 0
Application of iron tailings as fine aggregates in cast-in-situ concrete: The durability evaluation under sulfate and chloride combined corrosion 铁尾矿细集料在现浇混凝土中的应用:硫酸盐和氯化物复合腐蚀下的耐久性评价
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 DOI: 10.1016/j.susmat.2025.e01775
Gaowen Zhao , Fengzu Peng , Yaning Ding , Zhibao Nie , Feng Wei , Cheng Wang , Shijun Ding
The accumulation of iron ore tailings (IOT) poses significant environmental risks. Efficient utilization of IOT in cast-in-place concrete structures can mitigate these impacts and advance sustainability. To address the degradation mechanisms of cast-in-situ concrete with IOT in complex sulfate-chloride corrosion environments, IOT concrete (IOTC) were studied under four conditions, including no attack (NA), external attack (EA), internal attack (IA), and combined attack (CA). Specimens with 0 %, 25 % and 50 % IOT replacement ratios of fine aggregates were prepared and put in different corrosion conditions for 180 days. Dimension, mass, surface changes and compressive and flexural strength were continuously measured. Mineral, microstructural and pore structure evolution were analyzed. The effect of pore structure parameters on compressive strength was evaluated by the GM(1,3) model and Pearson correlation. Life cycle assessment is used to assess the environmental impact of IOTC. Results indicate that IA bypasses the diffusion barrier and occurs directly from the inside, which can cause more severe damage. Among them, chemical corrosion is the main cause of concrete deterioration, and the increasement of macropores is the direct cause of concrete deterioration. IOTC with 25 % IOT can enhance the durability of concrete by reducing sulfate penetration and corrosion through the utilization of physical, chemical, and transport mechanisms. However, excessive IOT content will reduce durability. Life cycle assessment confirms IOTC reduces the environmental impact of IOT. This study provides a theoretical basis for the reutilization of iron ore tailings and offers practical insights for designing durable ecological concrete in harsh environments.
铁矿尾矿的堆积会带来重大的环境风险。在现浇混凝土结构中有效利用物联网可以减轻这些影响并促进可持续性。为了研究物联网现浇混凝土在复杂硫酸盐-氯化物腐蚀环境中的降解机理,对物联网混凝土(IOTC)在无攻击(NA)、外部攻击(EA)、内部攻击(IA)和联合攻击(CA)四种条件下进行了研究。制备细集料物联网替代率为0%、25%和50%的试样,在不同的腐蚀条件下放置180天。连续测量尺寸、质量、表面变化以及抗压和抗弯强度。分析了矿物、微观结构和孔隙结构的演化。采用GM(1,3)模型和Pearson相关性评价孔隙结构参数对抗压强度的影响。采用生命周期评价方法,对物联网的环境影响进行评价。结果表明,IA绕过扩散屏障,直接从内部发生,可造成更严重的损伤。其中,化学腐蚀是混凝土劣化的主要原因,大孔隙的增加是混凝土劣化的直接原因。25% IOT的IOTC可以通过利用物理、化学和运输机制减少硫酸盐的渗透和腐蚀,从而提高混凝土的耐久性。然而,过多的物联网内容会降低耐用性。生命周期评估证实物联网减少了物联网对环境的影响。本研究为铁矿尾矿资源化利用提供了理论依据,为设计恶劣环境下耐久的生态混凝土提供了实践见解。
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引用次数: 0
Artichoke leaf extract coating on polylactic acid packaging to prolong fruit shelf life 洋蓟叶提取物涂在聚乳酸包装上,延长水果保质期
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 DOI: 10.1016/j.susmat.2025.e01783
Zeinab Qazanfarzadeh, Amparo Jiménez-Quero
The growing demand for safe and fresh food, coupled with the challenge of significant food loss and waste, has stimulated research on active packaging. In this study, artichoke leaf extract (ALE), obtained from food loss streams, was mixed with carboxymethyl cellulose (CMC) to develop an active coating on polylactic acid (PLA)-based packaging using a spray-coating approach. Prior surface modification of PLA using 1 % w/v PLA containing 20 wt% polyethylene glycol improved hydrophilicity and enhanced coating adhesion. Substituting ALE for CMC reduced coating solution viscosity, allowing a uniform coating. The inclusion of ALE conferred antioxidant (40–67 % DPPH scavenging) and antibacterial properties (2.11 and 1.08 log reduction against E. coli and S. aureus) to the coating, with controlled release governed by diffusion and swelling in lipophilic media (50 % ethanol) and predominantly swelling-controlled release in hydrophilic media (10 % ethanol and 3 % acetic acid). Analysis of the performance of active packaging in preservation of cut apples and strawberries demonstrated that ALE-coated PLA packaging effectively slowed oxidation, acid degradation, and microbial proliferation in cut apples and strawberries over 8 and 10 days storage, respectively, thereby improving overall freshness. While limited improvements were observed for firmness and browning in apples, coated packaging significantly enhanced phenolic content, antioxidant activity, and microbial stability, with strawberries showing the strongest protective effects. These findings highlight the potential of ALE-based coatings as a sustainable strategy to extend fruit shelf life and reduce food waste through active packaging solutions.
对安全和新鲜食品的需求日益增长,加上严重的食品损失和浪费的挑战,刺激了对活性包装的研究。在本研究中,从食物损失流中获得的朝鲜蓟叶提取物(ALE)与羧甲基纤维素(CMC)混合,采用喷涂方法在聚乳酸(PLA)基包装上制备活性涂层。先前使用含有20 wt%聚乙二醇的1% w/v聚乳酸对PLA进行表面改性,改善了亲水性并增强了涂层的附着力。用ALE代替CMC降低了涂层溶液粘度,使涂层均匀。ALE的加入使涂层具有抗氧化(清除40 - 67% DPPH)和抗菌性能(对大肠杆菌和金黄色葡萄球菌减少2.11和1.08对数),在亲脂介质(50%乙醇)中由扩散和溶胀控制释放,在亲水介质(10%乙醇和3%乙酸)中主要由溶胀控制释放。对活性包装在苹果切块和草莓切块保鲜中的性能分析表明,ale涂层PLA包装分别在8天和10天的贮藏期内有效减缓了苹果切块和草莓切块的氧化、酸降解和微生物增殖,从而提高了整体新鲜度。虽然对苹果的硬度和褐变的改善有限,但涂层包装显著提高了酚含量、抗氧化活性和微生物稳定性,草莓表现出最强的保护作用。这些发现突出了基于ale的涂料作为一种可持续战略的潜力,通过积极的包装解决方案来延长水果的保质期和减少食物浪费。
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引用次数: 0
Laser-induced pyrolysis of waste polyethylene to long-chain terminal alkenes and amphiphilic functionalization for anti-fouling film application 激光诱导废聚乙烯热解制长链末端烯烃及其两亲功能化防污膜应用
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 DOI: 10.1016/j.susmat.2025.e01778
Lun Chen , Fu-Lu Chang , Zi-Yang Hua , Fu-Rui Chen , Han Yang , Sheng Wang , Xian-Wu Cao , Xiao-Chun Yin , Guang-Jian He
Conversion of plastic waste into functional chemicals stands as a promising and sustainable strategy for augmenting the availability of high-value chemical feedstocks. In this study, we present a laser-induced pyrolysis (LIP) approach for upcycling end-of-life polyethylene (PE) into long-chain terminal alkenes (LT-alkenes), which is well-suited for subsequent downstream conversion into high-value amphiphilic copolymers. The ultrafast heating (>8 × 104 °C/s) and quenching (>4000 °C/s) process achieved by 4.53 kW/cm2 infrared laser irradiation plays a critical role in the kinetic-controlled degradation of polyethylene into long-chain terminal alkenes. This unique thermal profile—difficult to replicate with conventional pyrolysis methods—effectively suppresses by-product formation while eliminating the need for catalysts. Using recycled yogurt bottles as a waste model, we demonstrate a high yield of approximately 65 wt% toward LT-alkenes. These long-chain terminal alkenes are then functionalized into an amphiphilic polyethylene-block-poly(ethylene glycol) (PE-b-PEG) copolymer by end-group grafting reactions. This PE-b-PEG is employed to fabricate hydrophilic and anti-fouling micrporous membranes with a polyethylene matrix in a liquid-liquid thermally induced phase separation (L-LTIPS) process. Compared to pure polyethylene L-LTIPS membranes, the incorporation of 15 wt% PE-b-PEG results in a marked improvement in antifouling performance, as evidence by a reduced water contact angle (117.6° to 77.6°), a 90 % decrease in protein adsorption (1.12 to 0.11 mg/cm2), and a 33 % increase in water permeability, collectively demonstrating strongly potential for water treatment applications.
将塑料废物转化为功能性化学品是增加高价值化学原料供应的一项有前途和可持续的战略。在这项研究中,我们提出了一种激光诱导热解(LIP)方法,将寿命终止的聚乙烯(PE)升级为长链末端烯烃(lt -烯烃),这非常适合随后的下游转化为高价值的两亲共聚物。在4.53 kW/cm2红外激光照射下实现的超快加热(>8 × 104℃/s)和淬火(>4000℃/s)过程对聚乙烯动力学控制降解为长链末端烯烃起着关键作用。这种独特的热剖面——难以用传统的热解方法复制——有效地抑制了副产品的形成,同时消除了对催化剂的需求。使用回收的酸奶瓶作为废物模型,我们证明了lt -烯烃的高收率约为65%。这些长链末端烯烃通过端基接枝反应被功能化成两亲性聚乙烯-嵌段聚乙二醇(PE-b-PEG)共聚物。采用液-液热诱导相分离(L-LTIPS)工艺制备了以聚乙烯为基体的亲水防污微孔膜。与纯聚乙烯L-LTIPS膜相比,掺入15wt % PE-b-PEG的膜的防污性能显著提高,水接触角降低(117.6°至77.6°),蛋白质吸附减少90%(1.12至0.11 mg/cm2),水渗透性增加33%,这些都表明了水处理应用的巨大潜力。
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引用次数: 0
Valley-filling and peak-shaving: A dual-effect and controllable enzymatic approach for achieving machine-washability of dyed wool textiles as a sustainable alternative to dry cleaning 谷填充和峰剃:一种双效和可控的酶促方法,用于实现染色羊毛纺织品的机洗性,作为干洗的可持续替代品
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-12-01 DOI: 10.1016/j.susmat.2025.e01780
Xinrui Zhang , Jun Wang , Man Zhou , Yuanyuan Yu , Ping Wang , Qiang Wang
In recent years, with the advancement in the consumer market and industrial trends, wool has shown new vitality in the fields of outdoor sports apparel and smart wearable textiles due to its unique properties. However, the inherent felting characteristic of wool leads to undesirable dimensional shrinkage after machine washing, which necessitates that wool products be dry-cleaned. Conventional dry cleaning solvents like perchloroethylene are considered to be carcinogenic and detrimental to the environment. Factories usually adopt the chlorination process to manufacture machine-washable wool textiles, which may release harmful adsorbable organic halides (AOX) to the environment. Herein, we developed a “valley-filling and peak-shaving” dual-effect enzymatic anti-felting strategy as an ideal sustainable alternative. The pre-filling not only inhibits the protease from penetrating the fiber interior but also enhances its adsorption on the fiber surface. Hence, the compound proteases, possessing efficacy in degrading keratin-rich scales, primarily hydrolyze the fiber surface. This selective hydrolysis endows these textiles with machine-washability while preserving their original mechanical properties and color attributes, achieving a felting shrinkage of 5.06 % and an increase in tensile strength of 0.27 % for wool fabric. In summary, we present a green and feasible enzymatic approach to eliminate shrinkage, thereby facilitating the diversified application of wool products.
近年来,随着消费市场和产业趋势的进步,羊毛因其独特的性能,在户外运动服装、智能可穿戴纺织品等领域焕发出新的活力。然而,羊毛固有的感觉特性导致机洗后尺寸收缩,这就需要羊毛产品干洗。像过氯乙烯这样的传统干洗溶剂被认为是致癌的,对环境有害。工厂通常采用氯化工艺生产可机洗羊毛纺织品,这可能会向环境释放有害的可吸附有机卤化物(AOX)。在此,我们开发了一种“填谷和削峰”双效酶抗毡策略,作为一种理想的可持续替代方案。预填充不仅抑制了蛋白酶渗透纤维内部,而且增强了蛋白酶在纤维表面的吸附。因此,具有降解富含角蛋白鳞片功效的复合蛋白酶主要水解纤维表面。这种选择性水解使这些纺织品具有机洗性,同时保持其原有的机械性能和颜色属性,使羊毛织物的毡缩率达到5.06%,拉伸强度增加0.27%。综上所述,我们提出了一种绿色可行的酶法来消除收缩,从而促进羊毛产品的多样化应用。
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引用次数: 0
Development and performance assessment of polyurethane modified bitumen utilizing castor oil as a sustainable feedstock 以蓖麻油为可持续原料的聚氨酯改性沥青的研制及性能评价
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-11-29 DOI: 10.1016/j.susmat.2025.e01796
Guoqiang Sun , Ruiqing Sun , Chen Yang , Yiming Li , Tong Lu , Guangchen Wang
The development of novel eco-friendly polyurethane bitumen modifiers utilizing sustainable bio-based resources was currently a research hotspot. Castor oil (CO), with its unique chemical structure (containing hydroxyl groups) and bio-renewable advantages, represented an ideal choice for preparing bio-based PU. This study aimed to develop a high-performance, environmentally friendly renewable castor oil-based polyurethane modified bitumen (CO-PUMB), using petroleum-based polyurethane modified bitumen (P-PUMB) as a comparison, to provide insights for advancing the greening of road construction materials. First, the PU composition (isocyanate index R = 1, hard segment content Ch = 20 %) was designed and optimized, and determine the optimal hydroxyl substitution ratio for CO-substituted petroleum-derived polytetrahydrofuran (PTMG). Subsequently, the preparation process (90 °C, 400 rpm, 2 min) and the curing process (100 °C, 2 h) were established. Then, five types of CO-PUMB and P-PUMB with varying PU contents were prepared and subjected to microscopic morphology observation, physical performance testing, and rheological testing. Fluorescence microscopy observation indicated that, benefiting from the trihydroxy structure and low molecular weight of castor oil (CO), CO-PU formed an earlier, more extensive, and more efficient chemically cross-linked network than P-PU at a lower PU content (≥40 %). In contrast, P-PU relied primarily on physical entanglement and required a higher PU content (60 %) to achieve cross-linking. Physical performance and rheological tests demonstrated that CO-PUMB, leveraging its dense chemical cross-linked network, exhibited significantly superior high-temperature stability, fatigue life, elastic recovery, and resistance to permanent deformation compared to P-PUMB. Additionally, increasing the CO/P-PU content enhanced the overall performance of CO/P-PUMB across the entire frequency (temperature) range. Notably, the performance improvement in CO-PUMB within the high-frequency (low-temperature) region was dependent on an effective crosslinking network, while that in P-PUMB relied on the high motional freedom generated by PTMG molecules. The experiments demonstrated that CO-PUMB incorporating optimized CO substitution (≥40 % CO-PU) represented an environmentally friendly, high-performance bitumen material with excellent high and low temperature performance and anti-fatigue capability.
利用可持续生物基资源开发新型环保型聚氨酯沥青改性剂是当前的研究热点。蓖麻油(CO)具有独特的化学结构(含羟基)和生物可再生的优点,是制备生物基PU的理想选择。本研究旨在开发一种高性能、环保的可再生蓖麻油基聚氨酯改性沥青(CO-PUMB),并与石油基聚氨酯改性沥青(P-PUMB)进行比较,为推进道路建筑材料的绿色化提供参考。首先,对PU组成(异氰酸酯指数R = 1,硬段含量Ch = 20%)进行了设计和优化,确定了co取代石油衍生聚四氢呋喃(PTMG)的最佳羟基取代比。随后,建立了制备工艺(90℃,400 rpm, 2 min)和固化工艺(100℃,2 h)。然后,制备了5种不同PU含量的CO-PUMB和P-PUMB,并进行了微观形貌观察、物理性能测试和流变学测试。荧光显微镜观察表明,得益于蓖麻油(CO)的三羟基结构和低分子量,在较低的PU含量(≥40%)下,CO-PU形成的化学交联网络比P-PU更早、更广泛、更高效。相比之下,P-PU主要依靠物理纠缠,需要更高的PU含量(60%)来实现交联。物理性能和流变学测试表明,CO-PUMB利用其致密的化学交联网络,与P-PUMB相比,具有明显优于P-PUMB的高温稳定性、疲劳寿命、弹性恢复和抗永久变形能力。此外,CO/P-PU含量的增加提高了CO/P-PUMB在整个频率(温度)范围内的整体性能。值得注意的是,CO-PUMB在高频(低温)区域的性能提升依赖于有效的交联网络,而P-PUMB的性能提升依赖于PTMG分子产生的高运动自由度。实验证明,含有优化CO取代(CO- pu≥40%)的CO- pumb是一种具有优异高低温性能和抗疲劳性能的环保型高性能沥青材料。
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引用次数: 0
Evolution of drying shrinkage and water migration of concrete: Effects of pore feature and water desorption of recycled fine brick aggregate 混凝土干燥收缩和水分迁移的演变:再生细砖骨料孔隙特征和解吸水性的影响
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-11-28 DOI: 10.1016/j.susmat.2025.e01789
Juntao Dang , Huiqiang Jing , Jun Zhao , Wei Zhang , Jianzhuang Xiao , Hexin Zhang
Porous nature and water desorption capacity of recycled fine brick aggregate (RFCB) is crucial to the long-term evolution of shrinkage behavior of recycled concrete (RC) exposed to the dry environment. Thus, this study assessed both the pore feature and water desorption of RFCB with different particle sizes (including 0–5 mm, 0.075–5 mm and 0.15–5 mm), followed by the effect of particle size, replacement level and initial saturation degree of RFCB on the microstructure, strength development, water migration and drying shrinkage of RC. Results shown that the pore feature of RFCB yielded coarse pore size and high porosity with an increase in particle size, which in turn endowed a superior water desorption potential. Microstructure revealed that incorporating porous RFCB into RC increased the pore volume, porosity and total capillary pores, whereas performed better in improving the average pore diameter and interface bonding. The presence of RFCB imposed a deteriorate effect on the compressive strength, relative humidity, electrical resistivity and drying shrinkage, and this degraded effect exacerbated as particle size and replacement ratio raised. However, introducing full saturation degree of fine RFCB was beneficial for mitigating the relative humidity reduction, electrical resistivity increment and drying shrinkage development. Finally, the drying shrinkage-prediction model considering RFCB coefficients was developed based on the CEB-FIP model, which was helpful for the design of low-carbon and durable RC.
再生细砖骨料的多孔性和解吸水能力对干燥环境下再生混凝土收缩性能的长期演变至关重要。因此,本研究首先考察了不同粒径(0 ~ 5mm、0.075 ~ 5mm和0.15 ~ 5mm)的RFCB的孔隙特征和解吸水性,然后考察了RFCB的粒径、替代水平和初始饱和度对RC的微观结构、强度发展、水分迁移和干燥收缩的影响。结果表明,随着颗粒尺寸的增大,RFCB的孔隙特征呈现出粗孔和高孔的特征,从而赋予了其优越的解吸水潜力。微观结构研究表明,在RC中掺入多孔RFCB可提高RC的孔隙体积、孔隙率和毛细孔总数,同时对RC的平均孔径和界面结合有较好的改善作用。RFCB的存在会对材料的抗压强度、相对湿度、电阻率和干燥收缩率产生劣化效应,且随着粒径和替代比的增大,劣化效应加剧。而引入细粒RFCB的全饱和度有利于减缓相对湿度降低、电阻率升高和干燥收缩的发展。最后,在CEB-FIP模型的基础上,建立了考虑RFCB系数的干燥收缩预测模型,为低碳耐久RC的设计提供了理论依据。
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引用次数: 0
A road stud-based mechanical energy extractor with AI-supported monitoring for intelligent healthcare infrastructure 基于路钉的机械式能量提取器,支持人工智能监控,用于智能医疗基础设施
IF 9.2 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2025-11-27 DOI: 10.1016/j.susmat.2025.e01791
Shoukat Ali Mugheri , Ali Azam , Touqeer Aslam , Ammar Ahmed , Zutao Zhang , Chengliang Fan , Juhuang Song
Urbanization and transport development boost energy consumption; however, roadway harvesters prioritize traffic infrastructure needs with limited attention to powering nearby facilities. This research proposed a road stud-based mechanical energy extractor (MEE) system that uses vehicle kinetic energy to power sensors for health monitoring at a smart health unit adjacent to the road. The proposed setup comprises four modules: an energy intake module that captures vehicular kinetic energy, a mechanical drive module using a rack-and-pinion mechanism for energy conversion, a power output module that generates electrical energy, and a power backup module that ensures stable energy storage and supply. Mathematical modeling, finite element analysis using ANSYS to evaluate structural stability under varying loads, simulation with MATLAB Simscape, laboratory experiments using a Mechanical Testing and Sensing (MTS) machine, and field testing were conducted to assess the performance of the proposed setup model. The proposed system achieved a maximum RMS voltage of 2.42 V at a resistance of 6 Ω and an optimum RMS power of 7.05 W at a resistance of 2 Ω with an excitation frequency of 4 Hz. In the field test, the system attained an RMS power of 26.6 W at a speed of 20 km/h with the same load resistance. Furthermore, a deep learning-based performance monitoring system using the Gated Recurrent Unit (GRU) framework to categorize the motion states (low, medium, and high) and forecast maintenance requirements, attaining a training precision rate of 99.9 %. This novel approach generates higher energy at low traffic speeds, ensures a continuous power supply to IoT-based health sensors, and offers enhanced durability and adaptability.
城镇化和交通发展拉动能源消费;然而,道路收割机优先考虑交通基础设施的需求,而对附近设施的供电关注有限。本研究提出了一种基于道路支柱的机械能提取器(MEE)系统,该系统利用车辆动能为道路附近智能健康单元的健康监测传感器供电。提出的装置包括四个模块:捕获车辆动能的能量摄取模块,使用齿条齿轮机构进行能量转换的机械驱动模块,产生电能的功率输出模块,以及确保稳定能量存储和供应的电源备份模块。通过数学建模、ANSYS有限元分析评估结构在不同载荷下的稳定性、MATLAB Simscape仿真、机械测试与传感(MTS)机的室内实验以及现场测试来评估所建立模型的性能。该系统在电阻为6 Ω时的最大RMS电压为2.42 V,在激励频率为4 Hz时,电阻为2 Ω时的最佳RMS功率为7.05 W。在现场测试中,在负载阻力相同的情况下,系统在20 km/h的速度下获得了26.6 W的均方根功率。此外,基于深度学习的性能监测系统使用门控循环单元(GRU)框架对运动状态(低、中、高)进行分类并预测维护需求,训练准确率达到99.9%。这种新颖的方法在低交通速度下产生更高的能量,确保为基于物联网的健康传感器持续供电,并提供增强的耐用性和适应性。
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