Toxic emissions from asphalt production pose significant environmental and health risks, highlighting the critical need for high-efficiency fume suppressants to develop eco-friendly asphalt. In this study, an eco-friendly asphalt was developed using a novel high-efficiency reactive fume suppressant, synthesized by combining attapulgite (ATP) with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), referred to as attapulgite@DOPO (ATP@DOPO). Characterization through Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) confirmed that DOPO was successfully grafted onto ATP and contributed to an increase in interlayer spacing of ATP. Asphalt modified with 1 wt% ATP@DOPO at 160 °C achieved up to 79.0 % and 76.1 % reductions in H2S and VOCs emissions, respectively, with significant decreases in ozone formation potential (76.0 %) and secondary organic aerosol generation (60.3 %). Rheological tests revealed improved high-temperature performance with minimal impact on ductility. These findings suggest ATP@DOPO as a cost-effective solution for mitigating environmental harm while enhancing asphalt properties.
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