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Wear and RCF damage behaviours of bainitic rail steels under low temperature environments 低温环境下贝氏体钢轨钢的磨损和RCF损伤行为
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-05 DOI: 10.1016/j.wear.2026.206523
Yang Qin , Yuan Wang , Honghao Wang , Shuyue Zhang , Xin Lu , Hudong Xue , Wenjian Wang , Enrico Meli , Roger Lewis , Zhongrong Zhou , Haohao Ding
This study investigated the wear and RCF behaviours of a lath-like (1380B) bainitic rail steel and a granular bainitic rail steel (1250B) in low-temperature environments through rolling contact tests, using a pearlitic rail steel (U75VH) for comparison. Results showed that as temperature decreased, overall wear increased markedly, while average crack length and depth in all three steels became smaller. Among the steels, pearlitic rail steel consistently demonstrated the highest wear resistance and strongest resistance to crack initiation. At ambient temperature, lath-like bainitic rail steel performed better in resisting wear than the granular one; however, at −40 °C the opposite occurred, since the granular bainitic rail steel exhibited higher plastic deformation capacity. The lath-like bainitic rail steel also developed a few long cracks at low temperature. The superior low-temperature wear resistance of granular bainitic rail steel was attributed to differences in transformation behaviour compared with lath-like bainitic rail steel. Furthermore, fragments generated from multi-layer cracks were observed in both bainitic steels under low temperature, caused by brittle fracture and subsequent extrusion and twisting of the material between cracks. In contrast, no such fragments formed in pearlitic rail steel, which retained relatively high plasticity even in cold environments and thus avoided brittle fracture. These findings highlight the distinct wear and RCF responses of rail steels of different microstructures, and reveal the temperature-dependent mechanisms governing their tribological performance.
本研究通过滚动接触试验,研究了板条状贝氏体钢轨钢(1380B)和粒状贝氏体钢轨钢(1250B)在低温环境下的磨损和RCF行为,并以珠光体钢轨钢(U75VH)为对照。结果表明:随着温度的降低,三种钢的总磨损量显著增加,平均裂纹长度和深度减小;其中,珠光体钢轨的耐磨性最高,抗裂性最强。常温下,条状贝氏体钢轨钢的耐磨性优于粒状贝氏体钢轨钢;然而,在- 40℃时,情况正好相反,因为颗粒状贝氏体钢轨表现出更高的塑性变形能力。板条状贝氏体轨钢在低温下也出现了一些长裂纹。粒状贝氏体钢轨与条状贝氏体钢轨的相变行为不同,使其具有优异的低温耐磨性。此外,两种贝氏体钢在低温下均存在多层裂纹产生的碎片,这是由脆性断裂和裂纹间材料随后的挤压和扭转引起的。而珠光体钢轨钢则没有形成这样的碎片,即使在寒冷的环境中也保持了较高的塑性,从而避免了脆性断裂。这些发现突出了不同微观结构钢轨钢的不同磨损和RCF响应,并揭示了控制其摩擦学性能的温度依赖机制。
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引用次数: 0
Balancing friction and wear properties in Nano-Al2O3 strengthened 7075 Al alloys fabricated by laser assisted cold spray 激光辅助冷喷涂制备纳米al2o3增强7075铝合金的摩擦磨损平衡性能
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-30 DOI: 10.1016/j.wear.2025.206473
Qiang Wang, Jin Wang, Nan Li, Wenjuan Niu, Nan Guo, Shukai Ge, Liangliang Huang
Laser assisted cold spray (LACS) is an emerging solid-state deposition technique integrating cold spray (CS) and laser heating advantages, for fabricating components with low oxidation and high densification. However, the inherently low laser absorptivity of aluminum (Al) alloy powders limits thermal-assisted plastic deformation and overall coating performance in LACS. This study developed a micro-nano composite powder by incorporating Nano-Al2O3 particles (0–3 wt %) into 7075 Al alloy powder to enhance laser absorption and optimize coating quality. Results showed increasing Al2O3 led to a rougher powder surface, enhancing laser absorptivity from 60.91 % to 77.84 %. Deposition efficiency first increased then decreased, peaking at 62.3 % before dropping to 31.7 %. Nano-Al2O3 promoted localized heat absorption and enhanced particle plastic deformation, reducing porosity from 2.73 % to 0.69 %. Microhardness increased significantly from 117.46 HV0.2 to 161.51 HV0.2 with increasing nanoparticle content. Tribological tests revealed the 3 wt % Al2O3 coating showed a 52.9 % lower wear rate than pure 7075 Al when sliding against GCr15 steel ball. Adding Nano-Al2O3 shifted the wear mechanism from severe adhesive wear to mild adhesive combined with abrasive wear, with oxidative wear throughout. This study demonstrated a feasible surface modification strategy to enhance laser energy utilization and coating performance in LACS, offering a new pathway for wear-resistant Al alloy coatings.
激光辅助冷喷涂技术(LACS)是一种结合冷喷涂技术和激光加热技术优点的新型固体沉积技术,用于制造低氧化、高密度的零件。然而,铝(Al)合金粉末固有的低激光吸收率限制了LACS中热辅助塑性变形和整体涂层性能。本研究通过在7075铝合金粉末中掺入纳米al2o3颗粒(0-3 wt %)制备微纳复合粉末,增强激光吸收,优化涂层质量。结果表明:Al2O3的增加使粉末表面更加粗糙,激光吸收率从60.91%提高到77.84%;沉积效率先升高后降低,峰值为62.3%,后降至31.7%。纳米al2o3促进了局部吸热,增强了颗粒塑性变形,孔隙率从2.73%降低到0.69%。随着纳米颗粒含量的增加,显微硬度从117.46 HV0.2显著增加到161.51 HV0.2。摩擦学测试表明,当与GCr15钢球滑动时,3wt % Al2O3涂层的磨损率比纯7075 Al降低52.9%。纳米al2o3的加入使磨损机制从严重的粘接磨损转变为轻度粘接结合磨粒磨损,并伴有氧化磨损。本研究为提高激光能量利用率和涂层性能提供了一种可行的表面改性策略,为铝合金耐磨涂层提供了一条新的途径。
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引用次数: 0
Advances in erosion and wear of barrels: Inhibition strategies, predictive models, and future challenges 油桶冲蚀磨损研究进展:抑制策略、预测模型和未来挑战
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-26 DOI: 10.1016/j.wear.2025.206502
Xiaobing Zhang , Yongtao Wang , Xiaohe Zhang
Special mechanical equipment, such as rocket engines, high-speed vehicles, and gun barrels, suffers serious erosion and damage to their material surfaces under extreme working conditions of high temperature, high pressure, and high velocity. Investigating erosion and wear is of great significance in improving the service life of mechanical equipment. Taking the barrel of a gun as an example, the mechanism of erosion is clarified by summarizing the thermal-chemical-mechanical factors that affect the service life of mechanical equipment. The literature of the last fifteen years is analyzed to obtain the key directions of erosion research. Recent advances in coatings, protective materials, and erosion-resistant groove structure are summarized. Then, advances in prediction methods for barrel erosion are outlined in terms of heat transfer and erosion simulation. Prediction models that consider multi-physical field coupling, such as the flow-solid-thermal three-phase coupling model, have higher precision. Finally, future challenges and recommendations for research on resistance to erosion of gun barrels and aeroengines are presented. The study of erosion mechanisms, anti-erosion techniques, and erosion prediction techniques is crucial for enhancing the performance of guns, which not only improves the service life of guns but also provides important references for other engineering applications in extreme environments.
特种机械设备,如火箭发动机、高速车辆、炮管等,在高温、高压、高速的极端工况下,其材料表面受到严重的侵蚀和损坏。研究冲蚀磨损对提高机械设备的使用寿命具有重要意义。以某炮管为例,通过总结影响机械设备使用寿命的热-化学-力学因素,阐明了冲蚀机理。通过对近15年的文献分析,得出侵蚀研究的重点方向。综述了涂料、防护材料和耐蚀槽结构的最新进展。然后从传热和冲蚀模拟两方面概述了桶身冲蚀预测方法的研究进展。考虑多物理场耦合的预测模型,如流-固-热三相耦合模型,精度更高。最后,提出了今后在炮管和航空发动机抗冲蚀研究中面临的挑战和建议。研究冲蚀机理、防冲蚀技术和冲蚀预测技术对提高火炮的性能至关重要,不仅可以提高火炮的使用寿命,还可以为其他极端环境下的工程应用提供重要参考。
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引用次数: 0
Effect of hydrogen charging on the tribocorrosion performance of C45CE steel 充氢对C45CE钢摩擦腐蚀性能的影响
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-26 DOI: 10.1016/j.wear.2025.206482
Marcin Kowalski , Ayush Khurana , Michael Weil , Anna Neus Igual Muñoz , Stefano Mischler
Tribocorrosion of hydrogen-embrittled steel is a critical concern for materials, particularly used in applications involving high mechanical stress and corrosive conditions. Hydrogen uptake by steel structures, induced by an electrochemical process, can cause degradation of mechanical properties and induce cracks. It is widely known as hydrogen embrittlement. This study investigates the combined effects of mechanical wear and electrochemical corrosion on hydrogen-charged C45CE carbon steel, in the presence and absence of surface film. The tribocorrosion behavior of hydrogen-charged steel is evaluated through tests in corrosive solutions, accompanied by microstructural analysis. The method of hydrogen charging in carbon steel was carried out electrochemically under galvanostatic conditions in a 0.5M Na2S solution for 24 h. The tribocorrosion tests were done in a reciprocating tribometer in a borate solution under well-controlled mechanical and electrochemical conditions, allowing for imposing a specific surface chemistry. Dry wear tests were also carried out in the same tribological configuration.
Results show that hydrogen reduces the fracture energy of the hydrogen-charged steel by 50 % despite no differences in hardness were observed. Hydrogen charging neither modifies the grain structure of the steel. The tribocorrosion results show that the hydrogen uptake has an impact on the steel degradation (hydrogen blocks deformation, increases the strain accumulation, and higher subsurface recrystallization was observed) when no passive film is formed on the steel (cathodic conditions). The main effect of hydrogen is grain refinement. In the presence of surface films (passive conditions), no difference was observed between the tribocorrosion behaviour of the charged and non-charged samples. When imposing passive conditions, hydrogen intake into the material can be oxidized, thus its effect on the tribocorrosion response is minimized. The surface of the material was embrittled by the presence of the passive film, regardless of the hydrogen charging.
氢脆钢的摩擦腐蚀是材料的一个关键问题,特别是在涉及高机械应力和腐蚀性条件的应用中。由电化学过程引起的钢结构吸氢会导致钢结构的力学性能退化并诱发裂纹。这就是众所周知的氢脆。本文研究了表面膜存在和不存在情况下,充氢C45CE碳钢的机械磨损和电化学腐蚀的综合影响。通过腐蚀溶液试验和显微组织分析,评价了含氢钢的摩擦腐蚀行为。在0.5M Na2S溶液中,在恒流条件下进行碳钢充氢的电化学方法,持续24小时。摩擦腐蚀试验在往复摩擦计中进行,在良好控制的机械和电化学条件下,在硼酸盐溶液中进行,允许施加特定的表面化学。干磨损试验也进行了相同的摩擦学配置。结果表明,氢使含氢钢的断裂能降低50%,但硬度没有变化。充氢既不能改变钢的晶粒结构。摩擦腐蚀结果表明,当钢表面未形成钝化膜时(阴极条件下),氢吸收对钢的降解有影响(氢阻碍变形,增加应变积累,并观察到更高的表面下再结晶)。氢的主要作用是细化晶粒。在表面膜(钝化条件)存在的情况下,在带电和不带电样品的摩擦腐蚀行为之间没有观察到差异。当施加被动条件时,进入材料的氢可以被氧化,因此它对摩擦腐蚀响应的影响最小。材料的表面被钝化膜的存在而变脆,不管氢气充入与否。
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引用次数: 0
Prediction of cast steel three-body abrasive wear by multivariate analysis 用多变量分析预测铸钢三体磨料磨损
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-25 DOI: 10.1016/j.wear.2025.206501
Beata Białobrzeska
This study presents an evaluation of the abrasive wear of various grades of cast steel in relation to their mechanical properties and microstructure. Experimental values of volumetric wear were compared with values calculated using the classical Archard model, with a particular focus on the validity of employing a constant wear coefficient. It was found that, for high-hardness cast steels with a martensitic microstructure, the model showed good agreement with experimental data (differences up to ±14 %). For materials with greater ductility and a ferritic–pearlitic microstructure, the discrepancies reached as much as 66 %, indicating the need to modify the model by incorporating microstructural characteristics. To correlate mechanical properties with wear resistance, regression analysis and discriminant analysis were applied. Regression analysis demonstrated a correlation between wear resistance and both hardness and yield strength, whereas no clear relationships were found for parameters describing ductility. Discriminant analysis, however, indicated that hardness and percentage elongation after fracture had the greatest influence on the wear behaviour. To relate the type of microstructure to wear resistance, correspondence analysis was employed. The results enabled the ranking of microstructures according to increasing wear resistance. It was thus confirmed that the microstructures providing the highest wear resistance are lower bainite with martensite and precipitates of finely dispersed primary carbides.
本研究评估了不同牌号铸钢的磨料磨损与力学性能和显微组织的关系。将体积磨损的实验值与使用经典Archard模型计算的值进行了比较,特别关注采用恒定磨损系数的有效性。结果表明,对于马氏体组织的高硬度铸钢,该模型与实验数据吻合较好(误差可达±14%)。对于延展性更强、铁素体-珠光体微观结构的材料,差异高达66%,这表明需要通过纳入微观结构特征来修改模型。为了将机械性能与耐磨性联系起来,应用了回归分析和判别分析。回归分析表明耐磨性与硬度和屈服强度之间存在相关性,而描述延展性的参数没有发现明确的关系。判别分析表明,硬度和断后伸长率对磨损行为影响最大。为了将组织类型与耐磨性联系起来,采用了对应分析方法。结果可以根据耐磨性的增加对微观组织进行排序。结果表明,具有最高耐磨性的组织是下贝氏体、马氏体和细小分散的初生碳化物析出相。
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引用次数: 0
Mechanism of increased resistance to fretting wear of bearing steel achieved through multiscale microstructural control 通过多尺度显微组织控制获得轴承钢抗微动磨损增强机理
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-24 DOI: 10.1016/j.wear.2025.206486
Jian Zhang , Dianxiu Xia , Han Zhang , R.D.K. Misra , Shouren Wang , Lin Cui , Xiucheng Li
An innovative multiscale microstructural approach based on a secondary quenching heat treatment was adopted to increase resistance to fretting wear in a bearing steel. In this regard, the mechanisms associated with fretting wear are discussed. The wear-resistance was enabled by synergistic grain refinement and precipitation strengthening. By designing a dual-stage quenching process and employing multiscale characterization techniques including scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and transmission electron microscopy (TEM), the study comprehensively elucidates the effects of secondary quenching on austenite grain evolution, martensitic transformation, and nanoscale precipitation. The results demonstrated that secondary quenching significantly refined the austenite grain size from 18.61 ± 0.31 μm after single quenching (880 °C) to 5.23 ± 0.09 μm, with a refinement rate of ∼72 %—and simultaneously promoted the refinement and homogenization of martensitic laths. Electron microscopy studies revealed uniform dispersion of nanoscale carbides in the secondary-quenched samples, which effectively inhibited dislocation motion and interface migration, thereby enhancing matrix strengthening. In fretting wear tests conducted using a Si3N4 (silicon nitride) ball as the counterpart, the secondary-quenched samples exhibited an 18.2 % reduction in wear volume (down to (2.34 ± 0.03) × 106 μm3) compared to the single-quenched (880 °C) samples, together with noticeable reduction in both friction coefficient and wear rate. Surface morphology observations revealed smoother wear scars with significantly reduced spalling and cracking. Further analysis showed that secondary quenching facilitated the formation of a stable dynamic oxide film, reducing interfacial shear strength and shifting the dominant wear mechanism from brittle spalling to an oxidative–abrasive composite mode. This study provides both theoretical foundation and guidelines for microstructural design and performance optimization of high-reliability bearing materials.
采用基于二次淬火热处理的多尺度显微组织方法提高轴承钢的抗微动磨损性能。在这方面,与微动磨损有关的机制进行了讨论。其耐磨性是通过晶粒细化和析出强化的协同作用实现的。通过设计双段淬火工艺,采用扫描电镜(SEM)、电子背散射衍射(EBSD)和透射电镜(TEM)等多尺度表征技术,全面阐明了二次淬火对奥氏体晶粒演化、马氏体相变和纳米级析出的影响。结果表明,二次淬火使奥氏体晶粒由一次淬火(880℃)后的18.61±0.31 μm细化到5.23±0.09 μm,细化率达到72%,同时促进了马氏体板条的细化和均匀化。电镜研究表明,二次淬火试样中纳米碳化物分布均匀,有效地抑制了位错运动和界面迁移,从而增强了基体的强度。以氮化硅(Si3N4)球为试样进行微动磨损试验,与单次淬火(880°C)相比,二次淬火试样的磨损体积减小18.2%(降至(2.34±0.03)× 106 μm3),摩擦系数和磨损率均显著降低。表面形貌观察显示磨痕光滑,剥落和开裂明显减少。进一步分析表明,二次淬火有助于形成稳定的动态氧化膜,降低界面抗剪强度,并将主要磨损机制从脆性剥落转变为氧化-磨粒复合模式。该研究为高可靠性轴承材料的微观结构设计和性能优化提供了理论基础和指导。
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引用次数: 0
High-temperature wear behavior and mechanical properties of laser-clad AlCoCrFeNi HEA coatings on H13 steel co-strengthened by B4C/Y2O3 B4C/Y2O3共强化H13钢激光熔覆AlCoCrFeNi HEA涂层的高温磨损行为及力学性能
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-24 DOI: 10.1016/j.wear.2025.206481
Yiwen Zhou , Jiang Bi , Dehua Liu , Zhuoyun Yang , Guojiang Dong , Yuhang Li , Xiangdong Jia
H13 hot-work die steel is susceptible to oxidative spalling during high-temperature service, while conventional treatments struggle to balance strength and toughness. In this study, an AlCoCrFeNi high-entropy alloy coating was fabricated via laser cladding, with an innovative dual-phase strengthening system incorporating. The composite coating exhibits superior performance: average microhardness reaches 596.9 (±8.4) HV0.2 (2.8 × higher than the substrate); at 600 °C, the wear rate ((3.86 ± 0.15) × 10−5 mm3 N−1 m−1) decreases by 70.2 % compared to H13 steel; corrosion current density (3.34 × 10−7 A/cm2) is 45 % lower than the base coating. The strengthening mechanisms originate from B4C-derived dispersion hardening and Y2O3-enhanced oxidation resistance. This work proposes a multi-scale synergistic strategy for prolonging mold service life and establishes a theoretical foundation for coatings under extreme conditions.
H13热加工模具钢在高温使用过程中容易氧化剥落,而传统的处理方法难以平衡强度和韧性。在本研究中,采用激光熔覆的方法制备了AlCoCrFeNi高熵合金涂层,该涂层采用了创新的双相强化系统。复合镀层表现出优异的性能:平均显微硬度达到596.9(±8.4)HV0.2(比基体高2.8倍);在600℃时,磨损率((3.86±0.15)× 10−5 mm3 N−1 m−1)比H13钢降低了70.2%;腐蚀电流密度(3.34 × 10−7 A/cm2)比基层低45%。强化机制源于b4c的分散硬化和y2o3增强的抗氧化性。本文提出了延长模具使用寿命的多尺度协同策略,并为极端条件下涂层的研究奠定了理论基础。
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引用次数: 0
Effect of heat treatments on the cavitation erosion evolution of AISI 420 stainless steels 热处理对AISI 420不锈钢空化腐蚀演变的影响
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-23 DOI: 10.1016/j.wear.2025.206493
Lassi Raami , Kati Valtonen , Marco Wendler , Pasi Peura
Cavitation erosion of AISI 420 grade stainless steels was investigated after different heat treatments. The steels were subjected to 20 h of cavitation erosion using an ultrasonic vibratory apparatus. The mass losses were measured, and the results were compared with material properties. The eroded surfaces were examined with X-ray diffraction, scanning electron microscopy and optical profilometry. The results suggest that the cavitation erosion resistance is heavily dependent on the carbon content and the performed heat treatment. While for 0.2 C grade the best results were achieved in as-quenched condition, quenching and partitioning should be used when the carbon content is higher. During cavitation present retained austenite transforms into martensite, which hardens the surface and reduces the cavitation erosion rate. Thus, elimination of retained austenite with cryogenic treatment is not beneficial. If the steel is quenched without partitioning or tempering, the resulting microstructure may become brittle, eventually leading to high erosion rate. The results indicate that even short partitioning heat treatment can effectively reduce the martensite brittleness without sacrificing hardness or cavitation erosion resistance.
研究了AISI 420级不锈钢经不同热处理后的空化腐蚀。用超声振动装置对钢进行了20小时的空化腐蚀。测量了质量损失,并将结果与材料性能进行了比较。用x射线衍射、扫描电镜和光学轮廓术对侵蚀表面进行了检测。结果表明,合金的抗空化腐蚀性能与碳含量和热处理程度密切相关。而对于0.2 C级,在淬火状态下效果最好,当含碳量较高时应进行淬火和分块。空化过程中残余奥氏体转变为马氏体,使表面硬化,降低了空化侵蚀速率。因此,用低温处理消除残留的奥氏体是无益的。如果钢在淬火时不进行分块或回火,则产生的组织可能变脆,最终导致高侵蚀率。结果表明,在不牺牲硬度和抗空化侵蚀性能的情况下,即使是短分配热处理也能有效降低马氏体脆性。
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引用次数: 0
Significant improvement in elevated temperature galling resistance of austenitic iron-based hard-facings through heat treatment 热处理显著改善了奥氏体铁基硬表面的耐高温磨损性
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-23 DOI: 10.1016/j.wear.2025.206487
Jaimie L. Daure , Matthew J. Carrington , Daniel Kóti , Philip H. Shipway , D. Graham McCartney , David A. Stewart
This paper describes the development of a novel heat treatment to significantly improve the high temperature galling behaviour of austenitic iron-based hardfacings. The alloy examined in this work is hot isostatically pressed (HIPed) Tristelle 5183 (T-5183) which is comprised of an austenitic matrix with (Cr, Fe)7C3 and NbC hard phases. In the HIPed condition, the galling pressure, σg was bounded as 211 MPa < σg < 317 MPa at room temperature, but this fell to σg < 53 MPa at 100 °C. In the as-HIPed state, the (Cr, Fe)7C3 fraction was significantly smaller than its equilibrium value due to its sluggish nucleation and growth kinetics during HIPing, with this resulting in a commensurate supersaturation of carbon in solution in the austenitic matrix. This carbon supersaturation results in an increase in the austenite stacking fault energy (SFE) and it is suggested that this in turn results in reduced resistance to galling at elevated temperatures. An extended high temperature heat treatment of the alloy has resulted in the following: (i) an increase in the carbide particle size; (ii) an increase in the volume fraction of carbide; (iii) a commensurate reduction in the carbon content of the austenite and thus a reduction in its SFE. Following heat treatment, the room temperature galling pressure remained bounded as 211 MPa < σg < 317 MPa (i.e. no significant improvement in galling resistance was observed); however, the heat treatment resulted in a significant increase in the elevated temperature capability of the alloy with the galling pressure being again bounded as 211 MPa < σg < 317 MPa at temperatures as high as 300 °C. Given the temperature-sensitivity of the observed improvements in galling behaviour and the temperature-sensitivity of the SFE of the austenitic matrix, it is argued that it is the change in austenite SFE associated with the heat treatment that is the dominant influence in the observed improvement in the galling resistance of this alloy.
In light of a review of relevant adjacent literature related to the destabilisation of high chromium cast irons, it is argued that the heat treatment method proposed here for improving high temperature galling capability has general applicability to any ferrous system composed of austenite and complex carbides (including hardfacings) and is generalisable to a variety of methods of manufacture (e.g. HIPing, weld and laser cladding, casting etc).
本文介绍了一种新的热处理方法的发展,以显着改善奥氏体铁基堆焊的高温磨损行为。本文研究的合金是热等静压(HIPed) Tristelle 5183 (T-5183)合金,由奥氏体基体组成,具有(Cr, Fe)7C3和NbC硬相。在HIPed条件下,摩擦压力σg在室温下为211 MPa; σg在室温下为317 MPa,在100℃时下降到53 MPa。在HIPing状态下,(Cr, Fe)7C3分数明显小于其平衡值,这是由于HIPing过程中(Cr, Fe)7C3分数的成核和生长动力学缓慢,导致奥氏体基体中碳溶液相应过饱和。这种碳过饱和导致奥氏体层错能(SFE)的增加,这反过来又导致高温下抗磨损性的降低。延长合金的高温热处理导致以下结果:(1)碳化物粒度增加;(ii)碳化物体积分数增加;(iii)奥氏体碳含量相应降低,从而降低其SFE。热处理后,室温蠕变压力保持在211 MPa <, σg <, 317 MPa(即耐蠕变性能没有明显提高);然而,热处理导致合金的高温性能显著提高,在高达300℃的温度下,磨损压力再次限制在211 MPa <; σg < 317 MPa。考虑到观察到的磨损行为改善的温度敏感性和奥氏体基体SFE的温度敏感性,有人认为,与热处理相关的奥氏体SFE的变化是该合金抗磨损性能改善的主要影响因素。根据对有关高铬铸铁失稳的相关文献的回顾,本文提出的用于提高高温磨损能力的热处理方法普遍适用于任何由奥氏体和复杂碳化物(包括堆焊)组成的含铁体系,并适用于各种制造方法(例如HIPing,焊接和激光熔覆,铸造等)。
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引用次数: 0
Enhanced ultrasonic cavitation resistance of photopolymerizable acrylate resins through increased proportion of polyurethane acrylate in the blend 通过增加聚氨酯丙烯酸酯在共混物中的比例,增强光聚合丙烯酸酯树脂的抗超声空化能力
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-23 DOI: 10.1016/j.wear.2025.206492
Mohammed Bendimerad , Sylvain Giljean , Marie-José Pac , Cyril Marsiquet , Gautier Schrodj , Loïc Vidal , Dominique Zwingelstein , Jacques Lalevée , Laurent Vonna
This study investigates the influence of polyurethane acrylate (PUA) content on the cavitation resistance of UV-cured epoxy acrylate (EPA)-PUA polymer networks. Four blends containing 0, 15, 30, and 45 wt% PUA were prepared and characterized to understand the relationship between mechanical properties and cavitation resistance. Thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), and nanoindentation were used to confirm that increasing PUA content in the epoxy matrix enhanced material deformability. Cavitation tests performed according to ASTM G32 revealed that increasing PUA content improved cavitation resistance, as evidenced by longer incubation periods before surface damage and fewer pits and cracks. Notably, nanoindentation conducted on cavitated surfaces showed a hardening effect during the incubation phase, particularly in the 45 % PUA blend, which was attributed to plastic deformation induced by cavitation. These findings highlight the role of material deformability in absorbing energy from collapsing bubble, making UV-cured EPA-PUA blends promising candidates for applications requiring polymeric coatings resistant to cavitation erosion.
研究了聚氨酯丙烯酸酯(PUA)含量对环氧丙烯酸酯(EPA)-PUA聚合物网络抗空化性能的影响。制备了四种含有0、15、30和45 wt% PUA的共混物,并对其进行了表征,以了解其力学性能与抗空化性能之间的关系。热重分析(TGA)、动态力学分析(DMA)和纳米压痕分析证实,环氧基中PUA含量的增加提高了材料的变形能力。根据ASTM G32进行的空化测试表明,增加PUA含量可以提高抗空化能力,这可以通过延长表面损伤前的潜伏期和减少凹坑和裂缝来证明。值得注意的是,在空化表面上进行的纳米压痕在培养阶段显示出硬化效应,特别是在45% PUA共混物中,这归因于空化引起的塑性变形。这些发现强调了材料的可变形性在吸收气泡破裂能量中的作用,使uv固化的EPA-PUA共混物成为需要抗空化侵蚀的聚合物涂层的有希望的候选材料。
{"title":"Enhanced ultrasonic cavitation resistance of photopolymerizable acrylate resins through increased proportion of polyurethane acrylate in the blend","authors":"Mohammed Bendimerad ,&nbsp;Sylvain Giljean ,&nbsp;Marie-José Pac ,&nbsp;Cyril Marsiquet ,&nbsp;Gautier Schrodj ,&nbsp;Loïc Vidal ,&nbsp;Dominique Zwingelstein ,&nbsp;Jacques Lalevée ,&nbsp;Laurent Vonna","doi":"10.1016/j.wear.2025.206492","DOIUrl":"10.1016/j.wear.2025.206492","url":null,"abstract":"<div><div>This study investigates the influence of polyurethane acrylate (PUA) content on the cavitation resistance of UV-cured epoxy acrylate (EPA)-PUA polymer networks. Four blends containing 0, 15, 30, and 45 wt% PUA were prepared and characterized to understand the relationship between mechanical properties and cavitation resistance. Thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), and nanoindentation were used to confirm that increasing PUA content in the epoxy matrix enhanced material deformability. Cavitation tests performed according to ASTM <span><span>G32</span><svg><path></path></svg></span> revealed that increasing PUA content improved cavitation resistance, as evidenced by longer incubation periods before surface damage and fewer pits and cracks. Notably, nanoindentation conducted on cavitated surfaces showed a hardening effect during the incubation phase, particularly in the 45 % PUA blend, which was attributed to plastic deformation induced by cavitation. These findings highlight the role of material deformability in absorbing energy from collapsing bubble, making UV-cured EPA-PUA blends promising candidates for applications requiring polymeric coatings resistant to cavitation erosion.</div></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":"587 ","pages":"Article 206492"},"PeriodicalIF":6.1,"publicationDate":"2025-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145842284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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