Pub Date : 2024-06-27DOI: 10.1016/j.wear.2024.205469
Dingshan Liang , Chengxia Wei , Zongyuan Li , Qiming Zhuang, Lu Yang, Chen Wu, Fuzeng Ren
Face-centered-cubic (FCC) compositionally complex alloys (CCAs) are recognized for their exceptional mechanical properties, rendering them promising candidates for demanding engineering applications. However, a significant challenge faced by these alloys is their limited wear resistance. In this study, we addressed this issue by introducing 5 at.% Nb into an equiatomic FCC CrFeNi alloy, thereby creating a Laves phase-strengthened CrFeNiNb0.158 alloy, and investigated its sliding wear behavior at both room and elevated temperatures. Our findings reveal a substantial improvement in the wear performance of the Laves phase-strengthened CrFeNiNb0.158 alloy. Specifically, at room temperature (RT), the alloy exhibited a remarkable 62 % reduction in wear rate compared to the CrFeNi alloy. Furthermore, at an elevated temperature of 600 °C, the wear rate decreased by approximately 95 %, primarily attributed to the formation of a lubricating (Cr, Fe)2O3 oxide layer. Through detailed analysis, we identified the wear modes as abrasive wear at RT and oxidative wear at elevated temperatures. These results provide valuable insights for designing wear-resistant FCC CCAs by utilizing Laves phase strengthening and incorporating elements prone to oxidation to facilitate the formation of a protective oxide layer at elevated temperatures.
面心立方(FCC)成分复杂合金(CCA)因其优异的机械性能而广受认可,使其有望应用于要求苛刻的工程领域。然而,这些合金面临的一个重大挑战是其有限的耐磨性。在本研究中,我们通过在等原子 FCC CrFeNi 合金中引入 5 at.% Nb 来解决这一问题,从而创建了拉维斯相强化 CrFeNiNb 合金,并研究了其在室温和高温下的滑动磨损行为。我们的研究结果表明,拉维斯相强化铬铁镍铌合金的磨损性能得到了大幅改善。具体来说,与铬镍铁合金相比,该合金在室温(RT)下的磨损率显著降低了 62%。此外,在 600 °C 的高温下,磨损率降低了约 95%,这主要归功于润滑性(Cr, Fe)O 氧化层的形成。通过详细分析,我们确定了磨损模式,即在实时温度下的磨料磨损和在高温下的氧化磨损。这些结果为设计耐磨的催化裂化碳酸钙提供了宝贵的启示,即利用拉维斯相强化和加入易氧化的元素来促进高温下保护性氧化层的形成。
{"title":"Sliding wear behavior of a Laves phase-strengthened CrFeNiNb0.158 alloy at room and elevated temperatures","authors":"Dingshan Liang , Chengxia Wei , Zongyuan Li , Qiming Zhuang, Lu Yang, Chen Wu, Fuzeng Ren","doi":"10.1016/j.wear.2024.205469","DOIUrl":"10.1016/j.wear.2024.205469","url":null,"abstract":"<div><p>Face-centered-cubic (FCC) compositionally complex alloys (CCAs) are recognized for their exceptional mechanical properties, rendering them promising candidates for demanding engineering applications. However, a significant challenge faced by these alloys is their limited wear resistance. In this study, we addressed this issue by introducing 5 at.% Nb into an equiatomic FCC CrFeNi alloy, thereby creating a Laves phase-strengthened CrFeNiNb<sub>0.158</sub> alloy, and investigated its sliding wear behavior at both room and elevated temperatures. Our findings reveal a substantial improvement in the wear performance of the Laves phase-strengthened CrFeNiNb<sub>0.158</sub> alloy. Specifically, at room temperature (RT), the alloy exhibited a remarkable 62 % reduction in wear rate compared to the CrFeNi alloy. Furthermore, at an elevated temperature of 600 °C, the wear rate decreased by approximately 95 %, primarily attributed to the formation of a lubricating (Cr, Fe)<sub>2</sub>O<sub>3</sub> oxide layer. Through detailed analysis, we identified the wear modes as abrasive wear at RT and oxidative wear at elevated temperatures. These results provide valuable insights for designing wear-resistant FCC CCAs by utilizing Laves phase strengthening and incorporating elements prone to oxidation to facilitate the formation of a protective oxide layer at elevated temperatures.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-27DOI: 10.1016/j.wear.2024.205470
Taoshuo Bai , Jingmang Xu , Hui Zhu , Kai Wang , Jian Yang , Yao Qian , Ping Wang , Lu Li , Chunxiang Tian
Tempering treatment can improve the fatigue resistance while maintaining the wear resistance of laminar plasma discrete quenching (LPDQ) rails, but the fatigue crack initiation and propagation forms of LPDQ rails and tempered rails (TLPDQ) are not clear. In this study, twin-disc tests are performed on LPDQ and TLPDQ rails to obtain the wear and fatigue damage evolution of wheels and rails, and discuss the crack propagation mechanism. The results show that fatigue cracks in LPDQ rails initiate at the quenching zone edge and tend to propagate along the boundary after expanding to the quenching zone/substrate boundary in the depth direction. Whereas TLPDQ rail cracks tend to penetrate the boundary and propagate towards the substrate interior after expanding to the boundary.
{"title":"Investigation into the wear evolution and fatigue crack propagation behaviour of rails subjected to laminar plasma discrete quenching and tempering treatment","authors":"Taoshuo Bai , Jingmang Xu , Hui Zhu , Kai Wang , Jian Yang , Yao Qian , Ping Wang , Lu Li , Chunxiang Tian","doi":"10.1016/j.wear.2024.205470","DOIUrl":"10.1016/j.wear.2024.205470","url":null,"abstract":"<div><p>Tempering treatment can improve the fatigue resistance while maintaining the wear resistance of laminar plasma discrete quenching (LPDQ) rails, but the fatigue crack initiation and propagation forms of LPDQ rails and tempered rails (TLPDQ) are not clear. In this study, twin-disc tests are performed on LPDQ and TLPDQ rails to obtain the wear and fatigue damage evolution of wheels and rails, and discuss the crack propagation mechanism. The results show that fatigue cracks in LPDQ rails initiate at the quenching zone edge and tend to propagate along the boundary after expanding to the quenching zone/substrate boundary in the depth direction. Whereas TLPDQ rail cracks tend to penetrate the boundary and propagate towards the substrate interior after expanding to the boundary.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141553284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-27DOI: 10.1016/j.wear.2024.205468
Sharjeel Ahmed Khan , Fabio Ferreira , João Oliveira , Nazanin Emami , Amilcar Ramalho
In this study, the tribological behaviour of different Diamond-like-Carbon (DLC) coatings sliding against titanium alloy (Ti6Al4V) was analysed in a pin-on-disc tribometer at different applied loads to study effectiveness of tool coatings in titanium alloys machining. Three different DLC coatings were deposited on cemented carbide substrate using HiPIMS (DLC-Ar, DLC-Ne) and arc (DLC-Bn) deposition techniques. A detailed analysis of the wear track and titanium countersurfaces were performed following the tribotest to develop understanding about the wear mechanism and associated variation in the friction response. The results indicated that DLC-Ar presents low friction and reduced wear of coating and respective titanium countersurface at lowest load, seemingly due to its inherent tendency to spontaneously form graphitic transfer-layer at the interface. With an increase in the applied load, the tendency to retain tribofilm decreases as shearing ensue quickly exposing the underneath substrate material. The wear performance of DLC-Ne coatings is better than DLC-Ar under highest load and friction behaviour relatively close to DLC-Ar coatings. In comparison, under increased applied loads, DLC-Bn coatings offered better wear resistance and low friction compared with DLC-Ne and DLC-Ar coatings, which would offer improved performance in machining of titanium alloys.
{"title":"A comparative study in the tribological behaviour of different DLC coatings sliding against titanium alloys","authors":"Sharjeel Ahmed Khan , Fabio Ferreira , João Oliveira , Nazanin Emami , Amilcar Ramalho","doi":"10.1016/j.wear.2024.205468","DOIUrl":"10.1016/j.wear.2024.205468","url":null,"abstract":"<div><p>In this study, the tribological behaviour of different Diamond-like-Carbon (DLC) coatings sliding against titanium alloy (Ti6Al4V) was analysed in a pin-on-disc tribometer at different applied loads to study effectiveness of tool coatings in titanium alloys machining. Three different DLC coatings were deposited on cemented carbide substrate using HiPIMS (DLC-Ar, DLC-Ne) and arc (DLC-Bn) deposition techniques. A detailed analysis of the wear track and titanium countersurfaces were performed following the tribotest to develop understanding about the wear mechanism and associated variation in the friction response. The results indicated that DLC-Ar presents low friction and reduced wear of coating and respective titanium countersurface at lowest load, seemingly due to its inherent tendency to spontaneously form graphitic transfer-layer at the interface. With an increase in the applied load, the tendency to retain tribofilm decreases as shearing ensue quickly exposing the underneath substrate material. The wear performance of DLC-Ne coatings is better than DLC-Ar under highest load and friction behaviour relatively close to DLC-Ar coatings. In comparison, under increased applied loads, DLC-Bn coatings offered better wear resistance and low friction compared with DLC-Ne and DLC-Ar coatings, which would offer improved performance in machining of titanium alloys.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0043164824002333/pdfft?md5=aa955bc77419cdc6bacd0b68b4845987&pid=1-s2.0-S0043164824002333-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-25DOI: 10.1016/j.wear.2024.205467
Guoqing Zhang , Yaohui Wang , Zexuan Huo , Jiangfeng Zheng , Wenqi Zhang
Cubic boron nitride (CBN), with a hardness second only to diamond and an excellent chemical stability, is used to replace the role of diamond and machine precision/ultra-precision components in ferrous materials. However, the wear mechanisms of CBN tools and their wear-induced effects on machining system vibration seriously affect the machined surface quality. Therefore, this research focus on the wear characteristics of CBN tools in machining of NAK80. Based on the wear characteristics, the change in surface morphology and finish of the machined surface with tool wear was investigated. Meanwhile, the transformation of chip morphology at different wear stages was observed. Also, the effect of tool wear on the machining system vibration is analyzed by Butterworth filtering and Fourier transforming the cutting force signal. Research results show that the wear mechanisms of CBN cutting NAK80 are abrasive wear, oxidative wear and diffusive wear. Further, when the width of the flank wear of the CBN tool reaches 53 μm it causes multimodal vibration of the machining system, resulting in chattering patterns on the machined surface. As the width of the flank wear increased from 56.64 μm to 70.80 μm, the vibration frequency increased by 13.3 %. However, by reducing the feed rate from 5 μm/rev to 2 μm/rev, the vibration frequency can be reduced by 66.8 %. This study provides theoretical help in the research of wear of CBN cutting NAK80.
{"title":"Tool wear induced multimode vibration and multiscale patterns in precision turning NAK80","authors":"Guoqing Zhang , Yaohui Wang , Zexuan Huo , Jiangfeng Zheng , Wenqi Zhang","doi":"10.1016/j.wear.2024.205467","DOIUrl":"10.1016/j.wear.2024.205467","url":null,"abstract":"<div><p>Cubic boron nitride (CBN), with a hardness second only to diamond and an excellent chemical stability, is used to replace the role of diamond and machine precision/ultra-precision components in ferrous materials. However, the wear mechanisms of CBN tools and their wear-induced effects on machining system vibration seriously affect the machined surface quality. Therefore, this research focus on the wear characteristics of CBN tools in machining of NAK80. Based on the wear characteristics, the change in surface morphology and finish of the machined surface with tool wear was investigated. Meanwhile, the transformation of chip morphology at different wear stages was observed. Also, the effect of tool wear on the machining system vibration is analyzed by Butterworth filtering and Fourier transforming the cutting force signal. Research results show that the wear mechanisms of CBN cutting NAK80 are abrasive wear, oxidative wear and diffusive wear. Further, when the width of the flank wear of the CBN tool reaches 53 μm it causes multimodal vibration of the machining system, resulting in chattering patterns on the machined surface. As the width of the flank wear increased from 56.64 μm to 70.80 μm, the vibration frequency increased by 13.3 %. However, by reducing the feed rate from 5 μm/rev to 2 μm/rev, the vibration frequency can be reduced by 66.8 %. This study provides theoretical help in the research of wear of CBN cutting NAK80.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This work investigates the possibility of doping Si and Sn solid solution components (separate/simultaneous incorporation) into Ti3AlC2 to provide desired mechanical properties and tribological self-adaptability over a broad temperature range. The specimens are sintered at 1450 °C for 2 h in a vacuum environment with a pressure of 30 MPa. The phase composition, mechanical properties and tribological characteristics sliding against Al2O3 counter balls over a wide temperature range from room temperature to 800 °C are investigated. The results demonstrate considerable lattice distortion together with significant solid solution strengthening effects in quinary solid solutions. The friction coefficients of the four solid solutions are discovered to be temperature-sensitive from the distinguished variation tendencies in the wide temperature range. The wear rates exhibit a comparable tendency with test temperature that the values are two orders of magnitude lower at 600−800 °C than those at RT−400 °C. The noticeably lubricant tribofilm is responsible for the decreased wear rate at elevated temperatures. The distinct tribological behaviors of the quaternary and quinary solid solutions are ascribed to the characteristics of the self-generated oxides.
这项研究探讨了在 TiAlC 中掺入 Si 和 Sn 固溶体成分(单独/同时掺入)的可能性,以便在较宽的温度范围内提供所需的机械性能和摩擦学自适应性。试样在压力为 30 兆帕的真空环境中于 1450 °C 下烧结 2 小时。在从室温到 800 °C 的宽温度范围内,对相组成、机械性能和与 AlO 对球滑动的摩擦学特性进行了研究。结果表明,在二元固溶体中,晶格畸变相当大,固溶强化效应显著。从宽温度范围内的显著变化趋势来看,四种固溶体的摩擦系数都对温度敏感。磨损率随测试温度的变化呈现出相似的趋势,即 600-800 °C 时的值比 RT-400 °C 时的值低两个数量级。温度升高时磨损率降低的原因在于明显的润滑三膜。四元固溶体和二元固溶体的不同摩擦学行为归因于自生成氧化物的特性。
{"title":"Synthesis and tribological characterization over a wide temperature range for A-site elements doping in Ti3AlC2","authors":"Leping cai, Jinxin Li, Baoji Luo, Nairu He, Mingjie Shen, Junhong Jia","doi":"10.1016/j.wear.2024.205466","DOIUrl":"10.1016/j.wear.2024.205466","url":null,"abstract":"<div><p>This work investigates the possibility of doping Si and Sn solid solution components (separate/simultaneous incorporation) into Ti<sub>3</sub>AlC<sub>2</sub> to provide desired mechanical properties and tribological self-adaptability over a broad temperature range. The specimens are sintered at 1450 °C for 2 h in a vacuum environment with a pressure of 30 MPa. The phase composition, mechanical properties and tribological characteristics sliding against Al<sub>2</sub>O<sub>3</sub> counter balls over a wide temperature range from room temperature to 800 °C are investigated. The results demonstrate considerable lattice distortion together with significant solid solution strengthening effects in quinary solid solutions. The friction coefficients of the four solid solutions are discovered to be temperature-sensitive from the distinguished variation tendencies in the wide temperature range. The wear rates exhibit a comparable tendency with test temperature that the values are two orders of magnitude lower at 600−800 °C than those at RT−400 °C. The noticeably lubricant tribofilm is responsible for the decreased wear rate at elevated temperatures. The distinct tribological behaviors of the quaternary and quinary solid solutions are ascribed to the characteristics of the self-generated oxides.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141552025","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A combination of optical imaging (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and atom probe tomography (APT) was used to examine the white etching layer (WEL) and brown etching layer (BEL) formed in the flow lip region of a heavy haul curved rail. These flow lips eventually serve as crack initiating regions, leading to reverse detail fractures. OM distinctly identified the WEL/BEL region based on light contrast, while SEM micrographs identified a fine-grained structure within the WEL with intermittent patches of a deformed pearlitic structure. SEM images of the WEL/BEL indicate that the fraction of cementite patches was higher in the BEL region than in the WEL. TEM investigations revealed the presence of martensite/nano-crystalline ferrite along with newly formed austenite and cementite particles in the WEL and the BEL. The ferrite/martensite grain size was much finer in the WEL than in the BEL. The lath morphology of martensite was observed in the BEL, whereas a mixed morphology of lath and twinned martensite was observed in the WEL. APT studies show no Mn/Si partitioning in WEL/BEL along with C-concentrations ranging from 10 to 15 at.% and up to 20 at.% in the WEL and BEL respectively. The synergistic effect of elevated wheel-rail contact temperatures and severe plastic deformation dictated the overall microstructural evolution of the BELs and WELs on the outer rail surface in the flow lip.
采用光学成像 (OM)、扫描电子显微镜 (SEM)、透射电子显微镜 (TEM) 和原子探针层析成像 (APT) 技术,对重载曲线钢轨流唇区形成的白色蚀刻层 (WEL) 和棕色蚀刻层 (BEL) 进行了检测。这些流唇最终会成为裂纹起始区,导致反向细节断裂。根据光对比度,OM 可明显识别出 WEL/BEL 区域,而 SEM 显微照片则可识别出 WEL 内的细粒结构,以及间歇性的变形珠光体结构斑块。WEL/BEL 的扫描电镜图像显示,BEL 区域的雪明碳酸盐斑块比例高于 WEL。TEM 研究显示,在 WEL 和 BEL 中存在马氏体/纳米晶铁素体以及新形成的奥氏体和雪明碳铁颗粒。WEL 中的铁素体/马氏体晶粒比 BEL 中的要细得多。在 BEL 中观察到马氏体的板条形态,而在 WEL 中观察到板条和孪晶马氏体的混合形态。APT 研究表明,WEL/BEL 中没有锰/硅分区,而 WEL 和 BEL 中的 C 浓度分别为 10 至 15 % 和高达 20 %。轮轨接触温度升高和剧烈塑性变形的协同作用决定了流唇中外轨表面 BEL 和 WEL 的整体微观结构演变。
{"title":"Microstructural and elemental analysis of flow lips of heavy haul curved rails affected by deformation driven phase transformation","authors":"Sudharm Rathore , Soumyajit Mojumder , Cong Qiu , Peter Mutton , Aparna Singh","doi":"10.1016/j.wear.2024.205462","DOIUrl":"10.1016/j.wear.2024.205462","url":null,"abstract":"<div><p>A combination of optical imaging (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and atom probe tomography (APT) was used to examine the white etching layer (WEL) and brown etching layer (BEL) formed in the flow lip region of a heavy haul curved rail. These flow lips eventually serve as crack initiating regions, leading to reverse detail fractures. OM distinctly identified the WEL/BEL region based on light contrast, while SEM micrographs identified a fine-grained structure within the WEL with intermittent patches of a deformed pearlitic structure. SEM images of the WEL/BEL indicate that the fraction of cementite patches was higher in the BEL region than in the WEL. TEM investigations revealed the presence of martensite/nano-crystalline ferrite along with newly formed austenite and cementite particles in the WEL and the BEL. The ferrite/martensite grain size was much finer in the WEL than in the BEL. The lath morphology of martensite was observed in the BEL, whereas a mixed morphology of lath and twinned martensite was observed in the WEL. APT studies show no Mn/Si partitioning in WEL/BEL along with C-concentrations ranging from 10 to 15 at.% and up to 20 at.% in the WEL and BEL respectively. The synergistic effect of elevated wheel-rail contact temperatures and severe plastic deformation dictated the overall microstructural evolution of the BELs and WELs on the outer rail surface in the flow lip.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141553039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-21DOI: 10.1016/j.wear.2024.205463
Liyuan Zhao , Lei Tian , Qian Li , Yu Mao , Xiaolin Li , Ke Hua , Xiangtao Deng , Haifeng Wang
Fe–Co–Ni face-centered cubic (FCC) alloy has been one of the most extensively investigated alloys due to its potential ductility and toughness, while its low yield strength and wear resistance limit the engineering application. In this study, the different Mo content is added in the Fe–Co–Ni based alloy to solve this problem. The microstructure, wear resistance and tribological mechanism of Fe60-xCo20MoxNi20 (x = 10, 15, 20) high-entropy alloys after different annealing treatments are systematically investigated. The results reveal that the content of the μ phase increases with the addition of Mo element when annealed at 600 °C, and the highest amount of the μ phase is observed in the Mo20 alloy. The formation of the μ phase enhances the hardness of the Mo20 alloy, reduces the surface roughness during the wear process compared to Mo10 and Mo15 alloys, thereby improving the wear resistance. Furthermore, increasing annealing temperature also affects the content and distribution of the μ phase. The Mo20 alloy annealed at 600 °C exhibits the best wear resistance. However, as the annealing temperature increases to 1000 °C, the wear resistance deteriorates due to the spalling of the μ phase. In contrast, the wear resistance of the Mo15 alloy is optimized due to the uniform distribution of the μ phase. Additionally, when the sliding force increases from 2 N to 10 N, the wear resistance of the Mo20 alloy initially deteriorates before improves. This is mainly due to the increase in abrasive wear when the load is increased from 2 N to 5 N, while as the sliding force further increases to 10 N, a glaze layer is formed on the wear surface, which produces a lubricating effect. Furthermore, the better wear resistance of Mo20 and Mo15 alloys compared with others can also be attributed to the friction subsurface with nano-scale structure.
铁-铜-镍面心立方(FCC)合金因其潜在的延展性和韧性而成为研究最广泛的合金之一,但其较低的屈服强度和耐磨性限制了其工程应用。本研究在铁-铜-镍基合金中添加了不同的钼含量,以解决这一问题。系统研究了不同退火处理后 FeCoMoNi ( = 10、15、20) 高熵合金的显微组织、耐磨性和摩擦学机理。结果表明,在 600 ℃ 退火时,μ 相的含量随 Mo 元素的加入而增加,Mo20 合金中的μ 相含量最高。与 Mo10 和 Mo15 合金相比,μ 相的形成提高了 Mo20 合金的硬度,降低了磨损过程中的表面粗糙度,从而提高了耐磨性。此外,提高退火温度也会影响 μ 相的含量和分布。在 600 °C 下退火的 Mo20 合金表现出最佳的耐磨性。然而,当退火温度升高到 1000 ℃ 时,由于 μ 相的剥落,耐磨性变差。相反,由于 μ 相分布均匀,Mo15 合金的耐磨性得到了优化。此外,当滑动力从 2 N 增加到 10 N 时,Mo20 合金的耐磨性在改善之前开始恶化。这主要是由于当载荷从 2 N 增加到 5 N 时,磨料磨损增加,而当滑动力进一步增加到 10 N 时,磨损表面会形成釉层,从而产生润滑作用。此外,与其他合金相比,Mo20 和 Mo15 合金具有更好的耐磨性,这也可归因于具有纳米级结构的摩擦副表面。
{"title":"An investigation on the wear resistance and mechanism of Fe60-xCo20MoxNi20 (x=10, 15, 20) high-entropy alloy reinforced by μ-phase","authors":"Liyuan Zhao , Lei Tian , Qian Li , Yu Mao , Xiaolin Li , Ke Hua , Xiangtao Deng , Haifeng Wang","doi":"10.1016/j.wear.2024.205463","DOIUrl":"10.1016/j.wear.2024.205463","url":null,"abstract":"<div><p>Fe–Co–Ni face-centered cubic (FCC) alloy has been one of the most extensively investigated alloys due to its potential ductility and toughness, while its low yield strength and wear resistance limit the engineering application. In this study, the different Mo content is added in the Fe–Co–Ni based alloy to solve this problem. The microstructure, wear resistance and tribological mechanism of Fe<sub>60-<em>x</em></sub>Co<sub>20</sub>Mo<sub><em>x</em></sub>Ni<sub>20</sub> (<em>x</em> = 10, 15, 20) high-entropy alloys after different annealing treatments are systematically investigated. The results reveal that the content of the μ phase increases with the addition of Mo element when annealed at 600 °C, and the highest amount of the μ phase is observed in the Mo20 alloy. The formation of the μ phase enhances the hardness of the Mo20 alloy, reduces the surface roughness during the wear process compared to Mo10 and Mo15 alloys, thereby improving the wear resistance. Furthermore, increasing annealing temperature also affects the content and distribution of the μ phase. The Mo20 alloy annealed at 600 °C exhibits the best wear resistance. However, as the annealing temperature increases to 1000 °C, the wear resistance deteriorates due to the spalling of the μ phase. In contrast, the wear resistance of the Mo15 alloy is optimized due to the uniform distribution of the μ phase. Additionally, when the sliding force increases from 2 N to 10 N, the wear resistance of the Mo20 alloy initially deteriorates before improves. This is mainly due to the increase in abrasive wear when the load is increased from 2 N to 5 N, while as the sliding force further increases to 10 N, a glaze layer is formed on the wear surface, which produces a lubricating effect. Furthermore, the better wear resistance of Mo20 and Mo15 alloys compared with others can also be attributed to the friction subsurface with nano-scale structure.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141529703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-21DOI: 10.1016/j.wear.2024.205454
Guangjun Chen , Jiaqi Wang , Jinkai Xu , Zhiwu Han , Huadong Yu , Luquan Ren
C/SiC composites have excellent mechanical properties such as high specific strength and high temperature resistance, and are widely used in aerospace fields. However, due to its special structure and material properties, the tool wear is severe when machining with conventional methods, and the processing quality is poor. The purpose of this paper is to reveal the progressive wear behavior, wear mechanism of the tool, and its effect on machining performance in conventional milling (CM) and ultrasonic vibration-assisted milling (UVM) of C/SiC composites under forward fiber cutting (FC) and reverse fiber cutting (RC). The material removal and heat transfer models were established, and the stress distribution characteristics of cutting -edge were analyzed by finite element method (FEM). Combined with the wear morphology, cutting heat, and cutting force, the tool wear behavior and mechanism in UVM and CM under FC and RC were studied, and their effects on machining quality were analyzed. The results show that there are great differences in heat transfer and removal process between FC and RC. In UVM, the introduction of ultrasonic vibration reduces the adhesion of fine chips, weakens the strong friction and scratching between the hard chips and the cutting -edge, and alleviates the tool wear. The flank wear VB and cutting -edge wear area WA in RC are larger than those in FC, the abrasive wear is intensified, the material even peeling under mechanical shock, and the adhesive wear is more serious. When the tool wear intensifies to a certain extent, the difference of the cutting process caused by mechanical anisotropy of C/SiC composites is weakened, and the surface micro-defects and surface roughness Sa change little under FC and RC. This research contributes to the realization of high-quality and low-cost processing of C/SiC composites.
C/SiC 复合材料具有高比强度和耐高温等优异的机械性能,被广泛应用于航空航天领域。然而,由于其特殊的结构和材料性能,用传统方法加工时,刀具磨损严重,加工质量差。本文旨在揭示在正向纤维切削(FC)和反向纤维切削(RC)条件下,C/SiC 复合材料在常规铣削(CM)和超声振动辅助铣削(UVM)中的渐进磨损行为、刀具磨损机理及其对加工性能的影响。建立了材料去除和热传递模型,并采用有限元法(FEM)分析了切削边缘的应力分布特征。结合磨损形貌、切削热和切削力,研究了 FC 和 RC 下 UVM 和 CM 的刀具磨损行为和机理,并分析了其对加工质量的影响。结果表明,FC 和 RC 的传热和去除过程存在很大差异。在 UVM 中,超声波振动的引入减少了细小切屑的附着,减弱了硬切屑与切削刃之间的强烈摩擦和划伤,减轻了刀具磨损。RC 的侧面磨损 VB 和切削刃磨损面积 WA 比 FC 大,磨料磨损加剧,材料在机械冲击下甚至会剥落,粘着磨损更加严重。当刀具磨损加剧到一定程度时,C/SiC 复合材料机械各向异性引起的切削过程差异减弱,FC 和 RC 下的表面微缺陷和表面粗糙度 Sa 变化不大。该研究有助于实现 C/SiC 复合材料的高质量、低成本加工。
{"title":"Effect of forward and reverse cutting on tool wear behavior in ultrasonic vibration-assisted milling of 3D needle-punched C/SiC composites","authors":"Guangjun Chen , Jiaqi Wang , Jinkai Xu , Zhiwu Han , Huadong Yu , Luquan Ren","doi":"10.1016/j.wear.2024.205454","DOIUrl":"https://doi.org/10.1016/j.wear.2024.205454","url":null,"abstract":"<div><p>C/SiC composites have excellent mechanical properties such as high specific strength and high temperature resistance, and are widely used in aerospace fields. However, due to its special structure and material properties, the tool wear is severe when machining with conventional methods, and the processing quality is poor. The purpose of this paper is to reveal the progressive wear behavior, wear mechanism of the tool, and its effect on machining performance in conventional milling (CM) and ultrasonic vibration-assisted milling (UVM) of C/SiC composites under forward fiber cutting (FC) and reverse fiber cutting (RC). The material removal and heat transfer models were established, and the stress distribution characteristics of cutting -edge were analyzed by finite element method (FEM). Combined with the wear morphology, cutting heat, and cutting force, the tool wear behavior and mechanism in UVM and CM under FC and RC were studied, and their effects on machining quality were analyzed. The results show that there are great differences in heat transfer and removal process between FC and RC. In UVM, the introduction of ultrasonic vibration reduces the adhesion of fine chips, weakens the strong friction and scratching between the hard chips and the cutting -edge, and alleviates the tool wear. The flank wear <em>VB</em> and cutting -edge wear area <em>WA</em> in RC are larger than those in FC, the abrasive wear is intensified, the material even peeling under mechanical shock, and the adhesive wear is more serious. When the tool wear intensifies to a certain extent, the difference of the cutting process caused by mechanical anisotropy of C/SiC composites is weakened, and the surface micro-defects and surface roughness Sa change little under FC and RC. This research contributes to the realization of high-quality and low-cost processing of C/SiC composites.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141479376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-19DOI: 10.1016/j.wear.2024.205452
Rahul Kumar , Irina Hussainova , Maksim Antonov , Himanshu S. Maurya , Manel Rodríguez Ripoll
Additive manufacturing of self-lubricating alloys plays a crucial role in the production of complex wear-resistant components and in expanding repair capabilities, especially for intricate wear parts with low tolerances (e.g. with cooling channels). Herein, we report a novel approach providing nickel-based alloy with an excellent tribological performance in dry sliding contacts. Laser-deposited self-lubricating nickel alloys, infused with anti-wear additives of molybdenum disulfide, nickel sulfide, copper sulfide, or bismuth sulfide, were subjected to dry sliding wear tests against an alumina ball counterbody at a temperature range of up to 800 °C. The self-lubricating alloys exhibited a significant decline in friction (43 %) and wear (45 %) at room temperature, 400 °C (friction 40 %, wear rate 55 %), and 600 °C (MoS2-based, friction 58 %, wear rate 75 %). The MoS2-based alloy coating demonstrated excellent performance characteristics up to 800 °C (friction coefficient ⁓0.25, wear rate 11 × 10−6 mm3 N−1 m−1) due to the formation of a ‘glazed’ tribolayer. Wear mapping allowed to identification of a critical condition for self-lubricating alloys where positive transitions in wear mechanisms led to a synergistic lubrication mode involving the formation of tribologically induced new lubricious phases such as silver molybdate or nickel-bismuth intermetallic. This work provides a comparative evaluation of the micromechanisms, surface transitions, and tribochemistry of solid lubricants at a wide temperature range and a variety of applications.
{"title":"Temperature-induced wear micro-mechanism transition in additively deposited nickel alloys with different solid lubricants","authors":"Rahul Kumar , Irina Hussainova , Maksim Antonov , Himanshu S. Maurya , Manel Rodríguez Ripoll","doi":"10.1016/j.wear.2024.205452","DOIUrl":"https://doi.org/10.1016/j.wear.2024.205452","url":null,"abstract":"<div><p>Additive manufacturing of self-lubricating alloys plays a crucial role in the production of complex wear-resistant components and in expanding repair capabilities, especially for intricate wear parts with low tolerances (e.g. with cooling channels). Herein, we report a novel approach providing nickel-based alloy with an excellent tribological performance in dry sliding contacts. Laser-deposited self-lubricating nickel alloys, infused with anti-wear additives of molybdenum disulfide, nickel sulfide, copper sulfide, or bismuth sulfide, were subjected to dry sliding wear tests against an alumina ball counterbody at a temperature range of up to 800 °C. The self-lubricating alloys exhibited a significant decline in friction (43 %) and wear (45 %) at room temperature, 400 °C (friction 40 %, wear rate 55 %), and 600 °C (MoS<sub>2</sub>-based, friction 58 %, wear rate 75 %). The MoS<sub>2</sub>-based alloy coating demonstrated excellent performance characteristics up to 800 °C (friction coefficient ⁓0.25, wear rate 11 × 10<sup>−6</sup> mm<sup>3</sup> N<sup>−1</sup> m<sup>−1</sup>) due to the formation of a ‘glazed’ tribolayer. Wear mapping allowed to identification of a critical condition for self-lubricating alloys where positive transitions in wear mechanisms led to a synergistic lubrication mode involving the formation of tribologically induced new lubricious phases such as silver molybdate or nickel-bismuth intermetallic. This work provides a comparative evaluation of the micromechanisms, surface transitions, and tribochemistry of solid lubricants at a wide temperature range and a variety of applications.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141438483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-19DOI: 10.1016/j.wear.2024.205457
Zhi Li , Xiaoguang Han , Yingchun Shan , Yan Shen , Jiujun Xu
A Ni–Cr–MoS2 coating with trivalent Cr was prepared on the surface of the cylinder liner by the composite co-deposition method to modify its tribology performance. The effects of MoS2 concentration on the properties of the coatings and tribological properties of cylinder liners were studied by surface detection methods and reciprocating wear tests. The results show that Ni–Cr–MoS2 coating has a smaller grain size, higher micro-hardness, and greater coating thickness, compared with Ni–Cr coating. Doping by MoS2 effectively reduces the friction coefficient of Ni–Cr coating from 0.142 to 0.107, the wear amount of coating decreases from 7.9 mg to 7.1 mg, and the scuffing time increases from 19 min to 56 min. It is found that the doping of MoS2 provided more nucleation sites and promoted the deposition of ions, which resulted in the refined grain and thicker coating. The formation of solid lubrication film by MoS2 during the wear process and more coating thickness are mainly responsible for the modification of the tribology performance of cylinder liners. This research provides a practical approach to prolong the service life of friction pairs.
{"title":"The effect of MoS2 concentration on the thickness and tribology performance of electro-codeposited Ni–Cr–MoS2 coatings","authors":"Zhi Li , Xiaoguang Han , Yingchun Shan , Yan Shen , Jiujun Xu","doi":"10.1016/j.wear.2024.205457","DOIUrl":"https://doi.org/10.1016/j.wear.2024.205457","url":null,"abstract":"<div><p>A Ni–Cr–MoS<sub>2</sub> coating with trivalent Cr was prepared on the surface of the cylinder liner by the composite co-deposition method to modify its tribology performance. The effects of MoS<sub>2</sub> concentration on the properties of the coatings and tribological properties of cylinder liners were studied by surface detection methods and reciprocating wear tests. The results show that Ni–Cr–MoS<sub>2</sub> coating has a smaller grain size, higher micro-hardness, and greater coating thickness, compared with Ni–Cr coating. Doping by MoS<sub>2</sub> effectively reduces the friction coefficient of Ni–Cr coating from 0.142 to 0.107, the wear amount of coating decreases from 7.9 mg to 7.1 mg, and the scuffing time increases from 19 min to 56 min. It is found that the doping of MoS<sub>2</sub> provided more nucleation sites and promoted the deposition of ions, which resulted in the refined grain and thicker coating. The formation of solid lubrication film by MoS<sub>2</sub> during the wear process and more coating thickness are mainly responsible for the modification of the tribology performance of cylinder liners. This research provides a practical approach to prolong the service life of friction pairs.</p></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":null,"pages":null},"PeriodicalIF":5.3,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141434580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}