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Scratching properties of 4H–SiC single crystal after oxidation under different conditions 不同条件下 4H-SiC 单晶氧化后的划痕特性
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-23 DOI: 10.1016/j.wear.2024.205503

Single-crystal silicon carbide (SiC) has poor machinability because of its low fracture toughness, and surface modification has become the first choice for SiC polishing to obtain a high removal rate and a smooth surface. However, the removal mechanism of SiC after modification remains unclear. In this study, diamond scratching experiments were performed on 4H–SiC after oxidation under two conditions. To reveal the material removal mechanism, the scratch morphology and subsurface defects were analysed using Raman spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy. The results showed that oxidation improved the scratch depth and critical depth for ductile removal, resulting in a smooth scratch surface with low damage. However, weak oxidation increased the median crack length and exacerbated the subsurface damage. The SiOxCy, C = O, C–O–C, and Si–O–Si functional groups produced during oxidation reduced the hardness and improved the machinability of the 4H–SiC substrate. On the other hand, strong oxidation reduced the generation of surface cracks, tearing, and spalling, and weakened the propagation of subsurface median cracks. These results prove that ultrasonic-assisted photocatalytic oxidation provides high removal efficiency and defect control, providing a new approach for the synergistic polishing of SiC substrates.

单晶碳化硅(SiC)因断裂韧性低而加工性能差,为获得高去除率和光滑表面,表面改性已成为碳化硅抛光的首选。然而,SiC 经改性后的去除机理仍不清楚。本研究在两种条件下对氧化后的 4H-SiC 进行了金刚石划痕实验。为了揭示材料的去除机制,使用拉曼光谱、X 射线光电子能谱、扫描电子显微镜和透射电子显微镜分析了划痕形态和次表面缺陷。结果表明,氧化提高了划痕深度和韧性去除的临界深度,使划痕表面光滑且损伤小。然而,弱氧化增加了裂纹的中位长度,加剧了表层下的损伤。氧化过程中产生的 SiOxCy、C = O、C-O-C 和 Si-O-Si 官能团降低了 4H-SiC 基底的硬度,改善了其可加工性。另一方面,强氧化减少了表面裂纹、撕裂和剥落的产生,减弱了表面下中间裂纹的扩展。这些结果证明,超声波辅助光催化氧化具有很高的去除效率和缺陷控制能力,为碳化硅基底的协同抛光提供了一种新方法。
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引用次数: 0
The effects of the angle between the indenter edge and the scratch direction on the scratch characteristics of Ti–6Al–4V alloy 压头边缘与划痕方向的夹角对 Ti-6Al-4V 合金划痕特性的影响
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-23 DOI: 10.1016/j.wear.2024.205507

Ti–6Al–4V alloy has become a crucial raw material in aerospace and other industries owing to its exceptional mechanical properties. However, it is also a typical difficult-to-machine material, and its removal process and mechanism have been widely investigated by scratch testing. Nevertheless, the inherent non-rotational symmetry of the Vickers indenter introduces a crucial parameter, i.e., the angle λ between the indenter edge and the scratch direction, which affects not only the mechanical response of materials but also its surface formation mechanism during scratch. This study systematically characterized the micro/nano scratch characteristics of Ti–6Al–4V alloy under three typical angles λ (0°, 22.5°, 45°) as well as various normal forces and scratch speeds. The coefficient of friction (COF), scratch depth, scratch width, residual scratch morphology, and specific scratch energy were comparatively analyzed. Finite element simulations confirmed that the direction of material flow changed with the change in angle λ. The corresponding deformation mechanisms during scratch were discussed accordingly. The results revealed a significant influence of the angle λ on the scratch behaviors and surface quality of Ti–6Al–4V alloy.

Ti-6Al-4V 合金因其优异的机械性能已成为航空航天和其他行业的重要原材料。然而,它也是一种典型的难加工材料,其去除过程和机理已通过划痕测试得到广泛研究。然而,维氏压头固有的非旋转对称性带来了一个关键参数,即压头边缘与划痕方向之间的夹角 λ,它不仅影响材料的机械响应,还影响材料在划痕过程中的表面形成机制。本研究系统地描述了 Ti-6Al-4V 合金在三种典型角度 λ(0°、22.5°、45°)以及各种法向力和划痕速度下的微/纳米划痕特性。对比分析了摩擦系数(COF)、划痕深度、划痕宽度、残余划痕形态和比划痕能。有限元模拟证实,材料流动方向随角度 λ 的变化而变化,并对划痕过程中相应的变形机制进行了讨论。结果表明,角度 λ 对 Ti-6Al-4V 合金的划痕行为和表面质量有显著影响。
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引用次数: 0
Wear behavior of white alumina and seeded gel abrasive wheels in ultrasonic vibration-assisted grinding of nickel-based single-crystal alloy 镍基单晶合金超声振动辅助磨削中白氧化铝和种子凝胶砂轮的磨损行为
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-23 DOI: 10.1016/j.wear.2024.205505

This study investigated the tool wear behavior of white alumina (WA) and seeded gel (SG) abrasive wheels in the ultrasonic vibration-assisted creep feed grinding (UVACFG) of nickel-based single-crystal alloy. The abrasive wheel wear characteristics were examined, and their effects on the grinding force, temperature, and surface quality were evaluated. Finally, the wheel wear mechanism in the UVACFG was discussed by analyzing the intermittent cutting behavior and wear patterns of a single grain. Experimental results indicated that the workpiece material adhesion and pore-clogging were the main wear patterns of abrasive wheels without ultrasonic vibration. In contrast, these were adequately mitigated after introducing ultrasonic vibration, and the main wear pattern for both wheels became the grain fracture. The WA wheel in the UVACFG experienced reduced radial wear by around 60.7 % in the initial wear state, 40.2 % in the stable wear state, and 25.3 % in the rapid wear stage, respectively, compared to the conventional grinding (CG). The intermittent cutting behavior of SG grains caused by high-frequency vibration promoted the micro-fracture capacity and ensured the coolant entered the grinding zone sufficiently, which reduced the grinding force and temperature by up to 63.2 % and 46.7 %, respectively, and meanwhile introduced the defects of high bulges and slight plastic deformation on the workpiece surface.

本研究探讨了在镍基单晶合金的超声振动辅助蠕变进给磨削(UVACFG)中白矾砂轮(WA)和种子凝胶砂轮(SG)的刀具磨损行为。研究了砂轮磨损特性,并评估了其对磨削力、温度和表面质量的影响。最后,通过分析单个晶粒的间歇切削行为和磨损模式,讨论了 UVACFG 中的砂轮磨损机理。实验结果表明,工件材料粘附和孔隙堵塞是无超声波振动情况下砂轮的主要磨损模式。相比之下,引入超声波振动后,这些问题得到了充分缓解,两种砂轮的主要磨损模式都变成了晶粒断裂。与传统磨削(CG)相比,UVACFG 中的 WA 砂轮在初始磨损状态、稳定磨损状态和快速磨损阶段的径向磨损分别减少了约 60.7%、40.2% 和 25.3%。高频振动导致的 SG 磨粒间歇切削行为提高了微观断裂能力,确保了冷却液充分进入磨削区,从而使磨削力和温度分别降低了 63.2% 和 46.7%,同时在工件表面产生了高凸起和轻微塑性变形缺陷。
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引用次数: 0
Initial and grow-up stages of material transfer on Arc-DLC coating in aluminum forming processes at high temperatures 高温铝成型工艺中电弧-DLC 涂层材料转移的初始和成长阶段
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-22 DOI: 10.1016/j.wear.2024.205491

The mechanisms of material transfer in aluminum forming processes at high temperatures have remained a contentious tribological issue. This study aims to investigate the transfer mechanisms in the initial and grow-up stages of 6082-T6 aluminum alloy against commercial Arc-DLC coating under lubricant-free forming conditions. The warm and hot upsetting sliding test (WHUST) was used as the tribological test. It was conducted with two sliding configurations: the full sliding test to study the evolution of aluminum transfer and the short sliding test with a 2-mm sliding distance to observe the initiation of aluminum transfer. Furthermore, the effect of different sliding speeds, 0.5 and 5.0 mm/s, and initial temperatures of the specimen, 300 °C–500 °C, on the phenomenon of aluminum transfer was examined. Experimental results found that the aluminum transfer on the Arc-DLC coating in the initial stage of all cases was mainly caused by mechanical plowing. However, in the grow-up stage, the aluminum transfer could be dominated by mechanical plowing and/or adhesive bonding, depending on contact conditions. The different transfer mechanisms caused variations in the coefficient of friction and surface characteristics on the friction track. It led to the skewness Ssk could be an indicator to differentiate the transfer mechanisms.

铝在高温成形过程中的材料转移机制一直是一个有争议的摩擦学问题。本研究旨在探讨在无润滑剂成型条件下,6082-T6 铝合金与商用 Arc-DLC 涂层在初始和成长阶段的材料转移机制。摩擦学试验采用了温热镦粗滑动试验(WHUST)。试验采用了两种滑动结构:全滑动试验用于研究铝转移的演变过程,而滑动距离为 2 毫米的短滑动试验则用于观察铝转移的起始过程。此外,还研究了不同滑动速度(0.5 和 5.0 mm/s)和试样初始温度(300 ℃-500 ℃)对铝转移现象的影响。实验结果发现,在所有情况下,Arc-DLC 涂层在初始阶段的铝转移主要是由机械犁造成的。然而,在成长阶段,铝的转移可能主要由机械耕作和/或粘合剂粘结引起,具体取决于接触条件。不同的转移机制导致了摩擦轨迹上摩擦系数和表面特征的变化。因此,偏斜度 Ssk 可以作为区分转移机制的指标。
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引用次数: 0
Research on erosion wear behavior of NiTi alloy coating fabricated via high-frequency induction heating technology 通过高频感应加热技术制造的镍钛合金涂层的侵蚀磨损行为研究
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-22 DOI: 10.1016/j.wear.2024.205506

NiTi alloy is widely used in extreme working conditions due to its pseudoelasticity, shape memory effect and wear resistance. In this study, the NiTi alloy coating (Ni49.8Ti50.2 (at%)) was fabricated by high-frequency induction heating. The coating was well-formed on the surface of cemented carbide YG8 and converted to crystalline after aging treatment. The results of 70h erosion wear experiments carried on the rotary erosion wear test device showing that the erosion wear amount of the coating was reduced by 93 % compared with that of YG8, resulting from the deformation recovery effect. Moreover, the main erosion wear mechanism of the coating was micro-cutting and ploughing. This study can provide technical support and theoretical basis for preparing of NiTi alloy coating and erosion wear resistance.

镍钛合金具有假弹性、形状记忆效应和耐磨性,因此被广泛应用于极端工作条件。本研究采用高频感应加热法制备了镍钛合金涂层(Ni49.8Ti50.2 (at%))。涂层在硬质合金 YG8 表面成型良好,并在时效处理后转化为晶体。在旋转侵蚀磨损试验装置上进行的 70h 侵蚀磨损实验结果表明,由于变形恢复效应,涂层的侵蚀磨损量比 YG8 减少了 93%。此外,涂层的主要侵蚀磨损机理是微切削和犁蚀。该研究可为镍钛合金涂层的制备和抗侵蚀磨损提供技术支持和理论依据。
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引用次数: 0
An investigation of the contact mechanisms between Inconel 718 blades and a NiCrAl-bentonite abradable system 铬镍铁合金 718 叶片与镍铬铝膨润土可磨系统之间的接触机制研究
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-18 DOI: 10.1016/j.wear.2024.205465

This work has focused on contact mechanisms between Inconel 718 blades and a NiCrAl-bentonite abradable – a combination commonly used in the hot end of aero-engine compressors, where a transition to high forces and blade wear has been observed in certain contact conditions. In the first set of tests the effects of blade length and rig arrangement were investigated through testing on two different rigs. The purpose was twofold: establishing a connection to the previous research performed on the slower of the two rigs, and developing a general understanding of the effects of these two parameters on results. It was demonstrated that both rig stiffness and blade length in the considered range did not have a strong effect on the likelihood of transition of a test to the aforementioned high wear regime. The higher speed rig was then used to investigate the progression to high contact forces and blade wear in more detail by performing tests at speeds of 200 m/s and 280 m/s, with three incursion rates considered at each speed. Test to test variability was similarly investigated by performing five repeats for each test condition. Two distinct contact modes were observed – one where forces remained low and no blade wear occurred, and another where forces progressively increased until blade wear initiated and forces stabilised at significantly higher values than in the case of low force tests. These contact modes were explained through interaction between the incursion rate and rate of abradable fracture. The results have shown that an increase in incursion rate has increased the likelihood of the high-force contact mode, and an increase in blade tip speed decreased it. The inherent randomness of the abradable spraying process was demonstrated to lead to variability in material properties for nominally similar samples, and in turn the transition in contact mode was in essence probabilistic in nature. This variability also highlighted the importance of performing repeats when contacts with sprayed abradable materials are considered.

这项工作的重点是铬镍铁合金 718 叶片与镍铬铝-膨润土可磨材料之间的接触机制--这种组合通常用于航空发动机压缩机的热端,在某些接触条件下可观察到向高力和叶片磨损的过渡。在第一组测试中,通过在两个不同的钻机上进行测试,研究了叶片长度和钻机布置的影响。这样做有两个目的:一是与之前对两台钻机速度较慢的情况进行的研究建立联系,二是全面了解这两个参数对结果的影响。结果表明,在所考虑的范围内,钻机刚度和叶片长度对试验过渡到上述高磨损状态的可能性影响不大。然后,使用更高速度的钻机在 200 米/秒和 280 米/秒的速度下进行测试,更详细地研究了高接触力和叶片磨损的进展情况,并考虑了每种速度下的三种侵入率。同样,通过对每种试验条件进行五次重复试验,研究了试验之间的可变性。观察到两种截然不同的接触模式--一种是接触力保持在较低水平,叶片没有磨损;另一种是接触力逐渐增加,直到叶片开始磨损,接触力稳定在比低接触力测试高得多的数值上。这些接触模式是通过侵入率和可磨蚀断裂率之间的相互作用来解释的。结果表明,侵入率的增加增加了高力接触模式的可能性,而叶片尖端速度的增加则降低了这种可能性。可磨蚀喷射过程固有的随机性被证明会导致名义上相似的样品在材料属性上的变化,而接触模式的转变本质上是概率性的。这种变异性还突出了在考虑与喷涂可研磨材料接触时进行重复试验的重要性。
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引用次数: 0
Oxidative wear assisted enhanced wear performance of spark plasma sintered in situ Fe-based bulk metallic glass composites 火花等离子体原位烧结铁基块状金属玻璃复合材料的氧化磨损辅助增强磨损性能
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-18 DOI: 10.1016/j.wear.2024.205485

Current study reports the dry sliding wear behavior of Fe57Cr9Mo5B16P7C6 (at. %) fully amorphous bulk metallic glass (BMG) and in situ BMG composites, synthesized via spark plasma sintering. Fully amorphous alloy and in situ amorphous-crystalline composites containing various amount of crystallinity with a relative density > 98% were fabricated via optimized sintering conditions. Effect of in situ induced crystalline phase content on wear behavior and wear mechanism was investigated. In situ crystallization of intermetallic phases such as Fe5PB2, Fe2B and Cr2B led to significant increase in the hardness of the composite samples up to 15.1 GPa from 10.1 GPa in the case of fully amorphous sample. Increase in crystallinity in the studied Fe-based amorphous-crystalline composites was found to have a positive effect on wear performance. In the BMG sample with completely amorphous phase, sliding wear induced debonding of the sintered particles along with surface oxidation. However, in the case of amorphous-crystalline composite samples, sliding wear caused the formation of oxide rich tribolayer that resulted in lower coefficient of friction and significantly lower wear rates compared to the fully amorphous sample. Coefficient of friction values assumed more than 50% decrease in the case of 20% amorphous composite sample in comparison to the fully amorphous sample. Wear rates of the current Fe-based amorphous-crystalline composite samples were found to be in the order of 10−7 mm3/N.m, which are relatively lower compared to the recently reported Fe-based BMGs.

本研究报告了通过火花等离子烧结法合成的 Fe57Cr9Mo5B16P7C6 (at. %) 全非晶块状金属玻璃 (BMG) 和原位 BMG 复合材料的干滑动磨损行为。通过优化烧结条件,制造出了含有不同结晶度(相对密度为 98%)的全非晶合金和原位非晶-结晶复合材料。研究了原位诱导结晶相含量对磨损行为和磨损机理的影响。金属间相如 Fe5PB2、Fe2B 和 Cr2B 的原位结晶使复合材料样品的硬度显著提高,从完全无定形样品的 10.1 GPa 提高到 15.1 GPa。在所研究的铁基非晶-晶体复合材料中,结晶度的增加对磨损性能有积极影响。在完全非晶相的 BMG 样品中,滑动磨损会导致烧结颗粒脱落和表面氧化。然而,在非晶-晶体复合材料样品中,滑动磨损会形成富含氧化物的摩擦层,与完全非晶样品相比,摩擦系数更低,磨损率也明显降低。与完全非晶样品相比,20% 非晶复合样品的摩擦系数值降低了 50%以上。目前发现的铁基非晶-晶体复合材料样品的磨损率约为 10-7 mm3/N.m,与最近报道的铁基 BMG 相比相对较低。
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引用次数: 0
Internally cooled tools: An eco-friendly approach to wear reduction in AISI 304 stainless steel machining 内部冷却工具:在 AISI 304 不锈钢加工中减少磨损的环保方法
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-15 DOI: 10.1016/j.wear.2024.205490

Austenitic stainless steel 304 is widely used in various applications due to its mechanical strength, toughness, and, most importantly, its corrosion resistance. However, machining this material presents significant challenges, primarily due to its high tendency for work hardening and generation of elevated temperatures. In the cutting process, this temperature rise can result in premature tool wear, leading to a reduction in their lifespan. To address these issues, cutting fluids are typically applied. Although this component offers advantages, it also contributes to environmental pollution, health risks, and significant costs, including disposal.Therefore, this study introduces an Internally Cooled Tool (ICT) method aimed at reducing the heat generated during machining. In this study, an analysis of tool life and wear was conducted to evaluate the effectiveness of ICTs compared to conventional machining methods during the turning of austenitic stainless steel 304 using double-coated tools (AlCrN on TiAlN, PVD (Physical Vapor Deposition)). Additionally, the use of ICTs in combination with lubrication (hybrid machining Minimum Quantity Lubrication (MQL) + ICT) was also investigated. The study covered five machining atmospheres (ICT, ICT + MQL, dry, wet, MQL). Cutting conditions were kept constant, including cutting speed (vc = 400 m/min), feed rate (f = 0.1 mm/rev), and depth of cut (ap = 0.5 mm). Scanning electron microscopy (SEM) analyses were conducted to examine the wear mechanisms and types present in each condition, along with statistical tests such as analysis of variance and Tukey tests to validate the experiments. The results indicated that ICTs (ICT and ICT + MQL) showed a longer tool life compared to dry machining and MQL techniques, while the wet machining method did not demonstrate significance compared to this technique. The observed wear mechanisms included abrasion, adhesion, and diffusion, with abrasion being the predominant mechanism. In summary, it was found that the durability of the inserts was directly related to coating adhesion, as coating detachment quickly led to the end of the insert's lifespan.

奥氏体不锈钢 304 因其机械强度、韧性以及最重要的耐腐蚀性而被广泛应用于各种领域。然而,加工这种材料却面临着巨大的挑战,这主要是由于它极易加工硬化并产生高温。在切削过程中,温度升高会导致刀具过早磨损,从而缩短刀具的使用寿命。为解决这些问题,通常会使用切削液。因此,本研究介绍了一种旨在减少加工过程中产生的热量的内冷工具 (ICT) 方法。本研究对刀具寿命和磨损进行了分析,以评估在使用双涂层刀具(AlCrN 和 TiAlN,PVD(物理气相沉积))车削奥氏体不锈钢 304 时,与传统加工方法相比,ICT 的有效性。此外,还研究了信息和通信技术与润滑(混合加工最小量润滑 (MQL) + 信息和通信技术)的结合使用。研究涵盖了五种加工环境(ICT、ICT + MQL、干式、湿式、MQL)。切削条件保持不变,包括切削速度(vc = 400 m/min)、进给量(f = 0.1 mm/rev)和切削深度(ap = 0.5 mm)。扫描电子显微镜(SEM)分析检查了每种条件下的磨损机理和类型,并进行了方差分析和 Tukey 检验等统计检验,以验证实验结果。结果表明,与干式加工和 MQL 技术相比,ICT(ICT 和 ICT + MQL)显示出更长的刀具寿命,而湿式加工方法与该技术相比并不明显。观察到的磨损机制包括磨损、粘附和扩散,其中磨损是最主要的机制。总之,研究发现刀片的耐用性与涂层附着力直接相关,因为涂层脱落很快就会导致刀片寿命的结束。
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引用次数: 0
Tribological behavior of MoS2–Sb2O3-annealed nanodiamond coating on PEO-LST treated Ti6Al4V 经 PEO-LST 处理的 Ti6Al4V 上的 MoS2-Sb2O3 退火纳米金刚石涂层的摩擦学特性
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-14 DOI: 10.1016/j.wear.2024.205489

MoS2–Sb2O3 coating is commonly used as solid lubricant for titanium alloys, but the wear-resistance performance is still limited. Core-shell annealed nanodiamond (AND) particle is used as reinforcement for MoS2–Sb2O3 coating on Ti6Al4V substrate treated by plasma electrolytic oxidation (PEO) and laser surface texturing (LST). The incorporation of AND particles into the MoS2–Sb2O3 coating results in a 39 % decrease in friction and significantly reduces wear on the composite coating. Structural transformation of AND particles to amorphous carbon and graphitic structure promotes the densification of top-layer coating, enhancing lubrication and wear-resistance. Change of contact stress by PEO-LST promotes the formation of dense tribofilm and re-orientation of MoS2. This study has implications for the development of solid lubrication coatings for aerospace applications through functional nanomaterials and targeted designed surfaces.

MoS2-Sb2O3 涂层通常用作钛合金的固体润滑剂,但其耐磨性能仍然有限。在经过等离子电解氧化(PEO)和激光表面制绒(LST)处理的 Ti6Al4V 基材上,使用核壳退火纳米金刚石(AND)颗粒作为 MoS2-Sb2O3 涂层的增强剂。在 MoS2-Sb2O3 涂层中加入 AND 粒子后,摩擦力降低了 39%,并显著减少了复合涂层的磨损。AND 颗粒向无定形碳和石墨结构的结构转变促进了表层涂层的致密化,增强了润滑性和耐磨性。PEO-LST 对接触应力的改变促进了致密三膜的形成和 MoS2 的重新定向。这项研究通过功能纳米材料和有针对性的表面设计,对航空航天应用领域固体润滑涂层的开发具有重要意义。
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引用次数: 0
Microstructure and high-temperature tribological behaviours of nano-HfC reinforced Inconel 625 composite coating by plasma-transferred arc welding 等离子转移弧焊纳米 HfC 增强 Inconel 625 复合涂层的微观结构和高温摩擦学行为
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-09 DOI: 10.1016/j.wear.2024.205487
Jiangling Luo , Xiaofan Ma , Xianhang Huang , Yi Cao , Linlin Pan , Xiaodong Zou , Jianglong Yi , Lianyi Shao

The study involved plasma arc transfer welding (PTAW) for preparing coatings of Inconel 625 alloys that contained different amounts of nano-sized hafnium carbide (nano-HfC) particles. The impact of nano-HfC on the microstructure evolution and mechanical properties of PTAWed Inconel 625 were investigated. The research reveals that nano-HfC decomposes during the high-temperature plasma arc process and then react with O element to generate nano-HfO2. These HfO2 can serve as nucleation sites for MC carbides, which restricts the growth of secondary dendrite arms, leading to a more disordered grain growth direction. Simultaneously, the decomposition of HfC can increase the C/Nb ratio of the matrix, effectively suppressing Laves phase formation while encouraging the development of MC carbides. Compared with IN625, the wear rate of composites at room temperature and 600 °C were decreased. Notably, at 600 °C, the wear rate of the coating with 0.5 wt% HfC is the lowest among all the samples, as reflected by a noteworthy reduction in wear rate of 50 %. This is mainly attributed to the refinement of γ matrix, reduction of Laves phase as well as precipitation of the fine-sized MC carbides. This work illustrates that adding nano-HfC is an effective way to improve the wear resistance of the PTAWed Inconel 625.

该研究采用等离子弧转移焊接(PTAW)制备含有不同数量纳米碳化铪(纳米 HfC)颗粒的 Inconel 625 合金涂层。研究了纳米碳化铪对 PTAW 焊 Inconel 625 的微观结构演变和机械性能的影响。研究发现,纳米 HfC 在高温等离子弧过程中分解,然后与 O 元素反应生成纳米 HfO2。这些 HfO2 可作为 MC 碳化物的成核点,从而限制了次生枝晶臂的生长,导致晶粒生长方向更加无序。同时,HfC 的分解可提高基体的 C/Nb 比,有效抑制 Laves 相的形成,同时促进 MC 碳化物的发展。与 IN625 相比,复合材料在室温和 600 °C 下的磨损率都有所下降。值得注意的是,在 600 °C 时,含 0.5 wt% HfC 涂层的磨损率是所有样品中最低的,磨损率显著降低了 50%。这主要归因于γ基体的细化、拉维斯相的减少以及细小 MC 碳化物的析出。这项研究表明,添加纳米 HfC 是提高 PTAWed Inconel 625 耐磨性的有效方法。
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