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Enhancing the tribological behavior of high-speed train braking interfaces and suppressing stick-slip vibration via the stacking of disc springs 通过盘式弹簧叠加提高高速列车制动界面的摩擦学性能,抑制粘滑振动
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-13 DOI: 10.1016/j.wear.2025.206475
Jin Peng , Zaiyu Xiang , Jiakun Zhang , Shaohao Deng , Xiaoqin Liu
During low-speed braking of high-speed trains, the frictional interaction at the braking interface often triggers severe stick-slip instability, manifesting as friction-induced stick-slip vibration (FISSV). This generates sharp frictional noise and accelerates wear, causes block detachment, and compromises system stability, posing risks to operational safety. Thus, effective strategies are urgently needed to improve tribological behavior and suppress FISSV. Floating brake blocks based on disc spring structures have shown promise; however, the theoretical basis for optimizing spring number and stiffness remains insufficient. In this work, a floating friction block design with stacked disc springs is proposed to enhance tribological performance and vibration suppression. Comparative experiments were performed on a multifunctional friction test rig, evaluating a fixed connection and three disc spring configurations (2, 4, and 6 springs). Surface morphology characterization and finite element simulations were conducted to further reveal suppression mechanisms. Results show that floating structures consistently outperform fixed ones, yet suppression exhibits a nonlinear dependence on spring number. Among the tested configurations, the four-spring (SPR4) design delivered the most favorable performance: displacement, acceleration, and noise RMS values decreased by 35.68 %, 54.37 %, and 49.14 %, respectively, while friction force RMS increased by 41.5 %. SPR2 generated unstable adhesion-slip cycles, whereas SPR6 showed noise amplification at later stages. Mechanistic analysis demonstrated that suppression is achieved through a cooperative “moderate - compliance - hysteresis - uniform - redistribution” effect, with SPR4 forming stable contact plateaus and uniform stress distribution. These findings identify medium-stiffness floating structures as the optimal solution, offering theoretical and engineering guidance for the design of high-speed train brake pads.
在高速列车低速制动过程中,制动界面处的摩擦相互作用往往会引发严重的粘滑失稳,表现为摩擦诱发的粘滑振动(FISSV)。这会产生剧烈的摩擦噪声,加速磨损,导致滑块脱落,影响系统稳定性,给操作安全带来风险。因此,迫切需要有效的策略来改善摩擦学行为并抑制FISSV。基于盘式弹簧结构的浮动制动块已经显示出了前景;然而,优化弹簧数量和刚度的理论依据仍然不足。为了提高摩擦块的摩擦学性能和抑制振动,提出了一种带有叠放盘式弹簧的浮动摩擦块设计。在多功能摩擦试验台上进行了对比实验,评估了固定连接和三种碟形弹簧配置(2、4和6个弹簧)。表面形貌表征和有限元模拟进一步揭示了抑制机制。结果表明,浮动结构始终优于固定结构,但抑制表现出非线性依赖于弹簧数。在测试配置中,四弹簧(SPR4)设计的性能最优:位移、加速度和噪声的均方根值分别下降了35.68%、54.37%和49.14%,而摩擦力的均方根值增加了41.5%。SPR2产生了不稳定的黏附-滑移循环,而SPR6在后期表现出噪声放大。机理分析表明,抑制是通过“适度-顺性-滞后-均匀-再分布”的协同效应实现的,SPR4形成稳定的接触高原和均匀的应力分布。研究结果确定了中等刚度浮动结构为最佳方案,为高速列车刹车片的设计提供了理论和工程指导。
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引用次数: 0
Effects of Al-Si coating quantity on the wear behavior of 22MnB5 steel in hot stamping Al-Si涂层量对22MnB5钢热冲压磨损性能的影响
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-13 DOI: 10.1016/j.wear.2025.206471
Hee Geon Lee , Min-Ki Ji , Hyun-Hak Kang , Hyun-sung Son , Tea-Sung Jun
This study investigates the wear behavior of Al-Si-coated 22MnB5 steel, with respect to coating quantity, during a simulated hot-stamping process. A strip-drawing tribometer was used to replicate the process. Specimens were prepared with three distinct coating quantities (AS40, AS80, and AS140) and were subjected to an identical heat treatment at 900 °C for 5 min. Under the specific contact pressure and sliding velocity conditions tested in this study, tribological tests revealed that specimens with higher coating quantities exhibited lower friction coefficients and increased tool weight. In contrast, specimens with lower coating quantities exhibited the opposite trend. The level of oxidation varied inversely with coating quantity, with lower coating quantities promoting greater iron oxide formation. As the coating quantity increased, the amount of residual aluminum (Al) available for alloying also increased. This variation in residual Al was a critical factor that dictated the reaction pathways of the diffused iron (Fe), which either formed intermetallic compounds or oxides. Our findings demonstrate that variations in the Al-Si coating quantity, followed by heat treatment, significantly influence the friction behavior, tool wear, Fe reaction pathways, and oxidation characteristics during the hot-stamping process.
本文研究了al - si涂层22MnB5钢在模拟热冲压过程中的磨损行为,以及涂层量。用拉丝摩擦计复制了这一过程。用三种不同的涂层量(AS40、AS80和AS140)制备样品,并在900°C下进行相同的热处理5分钟。在本研究测试的比接触压力和滑动速度条件下,摩擦学测试表明,涂层量越大,试样的摩擦系数越低,刀具重量越大。相比之下,较低涂层量的试样表现出相反的趋势。氧化水平与涂敷量成反比,涂敷量越低,氧化铁生成越多。随着涂层量的增加,可合金化的残余铝(Al)量也增加。残余Al的这种变化是决定扩散铁(Fe)反应途径的关键因素,Fe要么形成金属间化合物,要么形成氧化物。我们的研究结果表明,Al-Si涂层量的变化以及热处理对热冲压过程中的摩擦行为、刀具磨损、铁反应路径和氧化特性有显著影响。
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引用次数: 0
Experimental study of impregnated diamond bit, Part 1: Bit wear 浸渍金刚石钻头的试验研究,第一部分:钻头磨损
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-13 DOI: 10.1016/j.wear.2025.206467
Rui Huang, Thomas Richard, Masood Mostofi
Impregnated diamond bits are designed with segments containing multiple layers of embedded diamonds. As the outermost layer of diamonds wears out, the next layer of sharp diamonds is exposed, sustaining performance in drilling hard and abrasive formations. Although allowing diamonds to wear fully before renewal may seem optimal for bit life, industry practices often prioritize maintaining sharp diamonds. This raises a key question: which approach delivers greater efficiency? Answering this question requires a clear understanding of bit wear mechanisms, the variables governing their occurrence, and associated wear rates. Previous studies have described different wear mechanisms, but most have been qualitative and lacked methods to quantify the bit wear state and wear rate. This research addresses these gaps by: (i) developing a systematic experimental methodology to track bit wear while drilling, and (ii) conducting a comprehensive study to identify dominant wear mechanisms and quantify wear rates under various drilling conditions.
With the proposed methodology, bit wear was investigated across seven rock types, five depths of cut (thickness of rock removed per bit revolution), and three angular velocities. The results led to the development of a conceptual wear model governed by depth of cut, identifying three distinct wear regimes and two critical depths of cut. Wear rates for each regime were quantified for rock types studied. The model provides a practical framework to select the optimum depth of cut based on rock properties. A sequel to this paper will explore the relationship between bit wear state and drilling response, which is defined as the relation between depth of cut and forces (axial thrust and torque) acting on the bit.
浸渍金刚石钻头设计成含有多层嵌钻的分段。随着最外层钻石的磨损,下一层锋利的钻石暴露出来,在坚硬和磨蚀性地层中保持性能。虽然在更新之前让钻石完全磨损似乎是钻头寿命的最佳选择,但行业惯例通常优先考虑保持锋利的钻石。这就提出了一个关键问题:哪种方法效率更高?回答这个问题需要清楚地了解钻头磨损机制、控制其发生的变量以及相关的磨损率。之前的研究描述了不同的磨损机制,但大多数都是定性的,缺乏量化钻头磨损状态和磨损率的方法。本研究通过以下方法解决了这些问题:(i)开发了一种系统的实验方法来跟踪钻井过程中的钻头磨损,(ii)进行了全面的研究,以确定主要磨损机制并量化各种钻井条件下的磨损率。采用所提出的方法,研究了7种岩石类型、5种切削深度(每钻头旋转所去除的岩石厚度)和3种角速度下的钻头磨损情况。结果导致了由切削深度控制的概念磨损模型的发展,确定了三种不同的磨损状态和两个临界切削深度。根据所研究的岩石类型,对每种状态下的磨损率进行了量化。该模型为根据岩石性质选择最佳切割深度提供了一个实用的框架。本文的后续将探讨钻头磨损状态与钻井响应之间的关系,钻井响应被定义为切削深度与作用在钻头上的力(轴向推力和扭矩)之间的关系。
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引用次数: 0
Amorphous CaSO4 nanocrystal deposits for friction and wear reduction at silicon interfaces 非晶CaSO4纳米晶沉积在硅界面的摩擦和磨损减少
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-12 DOI: 10.1016/j.wear.2025.206457
Tijn Vernooij , H. Tunç Çiftçi , Noushine Shahidzadeh , Bart Weber
When an object is placed on a surface, friction and wear cause uncertainty in its exact position, and thus challenge precision manufacturing. Here, we explore the development of a sacrificial nanocrystal deposit that can suppress friction and wear. Amorphous CaSO4 nanocrystals are deposited through salt solution droplet deposition followed by evaporation. During droplet drying, a precursor film of the aqueous CaSO4 solution spreads onto a hydrophilic silicon wafer, thus nucleating evenly spread unfaceted amorphous nanocrystals of CaSO4 on the wafer surface. We used atomic force microscopy to study the extent, topography, and friction and wear behavior of the deposited nanocrystals. We find that the sacrificial layer of nanocrystals is easy to apply and remove, spreads over large (few cm) areas with a constant thickness of about 8 nm, and has favorable friction and wear behavior.
当一个物体被放置在表面上时,摩擦和磨损会导致其精确位置的不确定性,从而给精密制造带来挑战。在这里,我们探索了一种可以抑制摩擦和磨损的牺牲纳米晶体沉积的发展。采用盐溶液液滴沉积-蒸发法制备无定形CaSO4纳米晶。在液滴干燥过程中,含水CaSO4溶液的前驱体膜扩散到亲水硅片上,从而在硅片表面形成均匀分布的无面无定形CaSO4纳米晶体。我们使用原子力显微镜研究了沉积纳米晶体的范围、形貌和摩擦磨损行为。我们发现纳米晶体牺牲层易于涂抹和去除,分布在大(几厘米)的区域,厚度约为8 nm,并且具有良好的摩擦和磨损性能。
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引用次数: 0
Microstructure and third-body behavior of Cu-MoS2-TiC composite coatings deposited by cold spray 冷喷涂Cu-MoS2-TiC复合镀层的显微组织和第三体行为
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-10 DOI: 10.1016/j.wear.2025.206464
Aosong Li , Wendong Fang , Tongyue Liang , Sima A. Alidokht , Phuong Vo , Bertrand Jodoin , Richard R. Chromik
To investigate the effect of ceramic particle addition on the properties of cold sprayed MoS2-based metal matrix composite coatings, Cu-MoS2 and Cu-MoS2-TiC coatings were deposited using feedstocks containing 0 (CM), 15 (CM-15T), 30 (CM-30T) and 50 (CM-50T) wt% TiC, respectively, while maintaining a constant MoS2 ratio of 5.5 wt% relative to the combined Cu and MoS2 powders. The influence of TiC content on the coatings microstructure and mechanical properties was systematically evaluated. TiC addition led to a tamping effect that densified the coatings and enhanced plastic deformation of the Cu matrix, thereby improving cohesion strength as well as nano- and micro-hardness. However, MoS2 retention decreased in CM-30T and CM-50T. Polished coating surfaces were tested for reciprocating sliding wear using a ball-on-plate tribometer in dry air and nitrogen, with Al2O3 spheres as counterbodies. CM showed low coefficients of friction but the highest wear rate in both environments because of its inferior mechanical properties. In dry air, CM-15T demonstrated the lowest friction and superior wear resistance, attributed to its high MoS2 retention and improved mechanical properties. Mild abrasive wear in CM-15T suggested a significant reduction in adhesive wear which was dominant for the other coatings. In nitrogen, adhesive wear was minimal for all coatings. The high MoS2 content in CM-15T contributed to low coefficients of friction. CM-50T exhibited the lowest wear rate, benefiting from its high hardness, enhanced cohesion strength, and more retained TiC particles that facilitated the fast formation of hard tribo-layers. These findings highlight the interplay between tribological behavior, mechanical properties, tribo-oxidation, and third-body effects in metal matrix composite coatings incorporating solid lubricants and hard phases.
为了研究陶瓷颗粒添加量对冷喷涂MoS2基金属基复合涂层性能的影响,分别使用含有0 (CM)、15 (CM- 15t)、30 (CM- 30t)和50 (CM- 50t) wt% TiC的原料沉积Cu-MoS2和Cu-MoS2-TiC涂层,同时保持相对于Cu和MoS2复合粉末的MoS2比例恒定在5.5 wt%。系统评价了TiC含量对涂层组织和力学性能的影响。TiC的加入使镀层致密化,增强了Cu基体的塑性变形,从而提高了镀层的内聚强度以及纳米和显微硬度。然而,CM-30T和CM-50T的MoS2保留率下降。在干燥空气和氮气中,使用球-板摩擦计测试抛光涂层表面的往复滑动磨损,并以Al2O3球体作为counterbodies。由于其较差的力学性能,CM在两种环境下均表现出较低的摩擦系数和较高的磨损率。在干燥空气中,CM-15T表现出最低的摩擦和优异的耐磨性,这归功于其高MoS2保留率和改进的机械性能。CM-15T的轻度磨粒磨损表明,粘着剂磨损显著减少,这在其他涂层中占主导地位。在氮气中,所有涂层的粘附磨损最小。CM-15T中MoS2含量高,摩擦系数低。CM-50T的磨损率最低,这得益于其高硬度、增强的内聚强度和更多的残留TiC颗粒,有利于快速形成硬摩擦层。这些发现强调了在含有固体润滑剂和硬相的金属基复合涂层中摩擦学行为、机械性能、摩擦氧化和第三体效应之间的相互作用。
{"title":"Microstructure and third-body behavior of Cu-MoS2-TiC composite coatings deposited by cold spray","authors":"Aosong Li ,&nbsp;Wendong Fang ,&nbsp;Tongyue Liang ,&nbsp;Sima A. Alidokht ,&nbsp;Phuong Vo ,&nbsp;Bertrand Jodoin ,&nbsp;Richard R. Chromik","doi":"10.1016/j.wear.2025.206464","DOIUrl":"10.1016/j.wear.2025.206464","url":null,"abstract":"<div><div>To investigate the effect of ceramic particle addition on the properties of cold sprayed MoS<sub>2</sub>-based metal matrix composite coatings, Cu-MoS<sub>2</sub> and Cu-MoS<sub>2</sub>-TiC coatings were deposited using feedstocks containing 0 (CM), 15 (CM-15T), 30 (CM-30T) and 50 (CM-50T) wt% TiC, respectively, while maintaining a constant MoS<sub>2</sub> ratio of 5.5 wt% relative to the combined Cu and MoS<sub>2</sub> powders. The influence of TiC content on the coatings microstructure and mechanical properties was systematically evaluated. TiC addition led to a tamping effect that densified the coatings and enhanced plastic deformation of the Cu matrix, thereby improving cohesion strength as well as nano- and micro-hardness. However, MoS<sub>2</sub> retention decreased in CM-30T and CM-50T. Polished coating surfaces were tested for reciprocating sliding wear using a ball-on-plate tribometer in dry air and nitrogen, with Al<sub>2</sub>O<sub>3</sub> spheres as counterbodies. CM showed low coefficients of friction but the highest wear rate in both environments because of its inferior mechanical properties. In dry air, CM-15T demonstrated the lowest friction and superior wear resistance, attributed to its high MoS<sub>2</sub> retention and improved mechanical properties. Mild abrasive wear in CM-15T suggested a significant reduction in adhesive wear which was dominant for the other coatings. In nitrogen, adhesive wear was minimal for all coatings. The high MoS<sub>2</sub> content in CM-15T contributed to low coefficients of friction. CM-50T exhibited the lowest wear rate, benefiting from its high hardness, enhanced cohesion strength, and more retained TiC particles that facilitated the fast formation of hard tribo-layers. These findings highlight the interplay between tribological behavior, mechanical properties, tribo-oxidation, and third-body effects in metal matrix composite coatings incorporating solid lubricants and hard phases.</div></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":"586 ","pages":"Article 206464"},"PeriodicalIF":6.1,"publicationDate":"2025-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145748878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wear mechanism and wear particles characterization of Zr-2.5Nb, ZTA, and CoCrMo articulating with UHMWPE in multidirectional motion Zr-2.5Nb、ZTA和CoCrMo与UHMWPE多向接合的磨损机理及磨损颗粒表征
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-09 DOI: 10.1016/j.wear.2025.206459
Ruijuan Liu , Yali Zhang , Xinle Li , Xiaogang Zhang , Jian Pu , Qin Xiong , Wen Shi , Zhongmin Jin
In traditional metal-on-polyethylene (MoP) implants, especially cobalt chrome molybdenum-ultra high molecular polyethylene (CoCrMo-UHMWPE) pairing, wear primarily occurs in the PE component. The wear particles from PE are considered a major cause of implant loosening and artificial joint failure. The development of oxidized zirconium-2.5 % niobium (Zr-2.5Nb) and zirconia-toughened alumina (ZTA) has shown promise in reducing wear and osteolysis risks. However, comparative studies on the wear mechanisms and wear particle characteristics of Zr-2.5Nb-UHMWPE, ZTA-UHMWPE, and CoCrMo-UHMWPE remain limited. In this study, Zr-2.5Nb, ZTA, and CoCrMo were selected and paired with UHMWPE as pairing materials. The wear mechanism was studied from the aspects of wear behavior and wear particle characterization at different contact pressures from 2 MPa to 4 MPa under multidirectional motion. The UHMWPE wear loss from Zr-2.5Nb-UHMWPE was 48 %, 27 %, and 18 % lower than that of CoCrMo-UHMWPE bearings at 2, 3, and 4 MPa. The results showed that there was no significant difference in the wear loss of UHMWPE from Zr-2.5Nb-UHMWPE and ZTA-UHMWPE at 2 MPa, but 34.5 % higher than that of ZTA-UHMWPE at 4 MPa. Zr-2.5Nb-UHMWPE exhibited a similar wear performance to ZTA-UHMWPE with no visible scratches on the surface of Zr-2.5Nb and ZTA, while multidirectional scratches appeared on the surface of CoCrMo. Moreover, the UHMWPE wear particles were consistent in size range and morphology, but different in quantity and size distribution at all loading conditions. The number of UHMWPE wear particles produced by the Zr-2.5Nb-UHMWPE pairing was 44 %–60 % lower than that of the CoCrMo-UHMWPE at 2, 3, and 4 MPa. However, the UHMWPE wear particles produced by Zr-2.5Nb-UHMWPE and ZTA-UHMWPE were very similar, which were 153 and 157 at 4 MPa, respectively. With increasing load, size distribution results revealed that the proportion of large-sized wear particles gradually increased for the three pairings. Notably, the UHMWPE wear particle from the Zr-2.5Nb-UHMWPE pairing exhibited the largest average particle size. Shape distribution analysis further indicated that the UHMWPE wear particle generated by the Zr-2.5Nb-UHMWPE pairing was predominantly fibrous in morphology, whereas that from the CoCrMo-UHMWPE pairing displayed the highest proportion of round and oval shapes. Based on the analysis of wear morphology and wear particle characteristics, the results showed that the wear mainly occurred in UHMWPE. Plastic deformation was the main cause of wear particle formation, and the wear mechanisms were adhesive wear and abrasive wear. This study compared the tribological behaviors of three typical pairings, providing a valuable understanding of artificial hip joint materials, which will contribute to optimizing orthopedic implant materials.
在传统的金属对聚乙烯(MoP)植入物中,特别是钴铬钼-超高分子聚乙烯(CoCrMo-UHMWPE)配对中,磨损主要发生在PE部件上。PE的磨损颗粒被认为是假体松动和人工关节失效的主要原因。氧化锆- 2.5%铌(Zr-2.5Nb)和氧化锆-增韧氧化铝(ZTA)的发展在减少磨损和骨溶解风险方面显示出希望。然而,对Zr-2.5Nb-UHMWPE、ZTA-UHMWPE和CoCrMo-UHMWPE的磨损机理和磨损颗粒特性的对比研究仍然有限。本研究选择Zr-2.5Nb、ZTA和CoCrMo作为配对材料,与UHMWPE进行配对。从多向运动下2 ~ 4 MPa不同接触压力下的磨损行为和磨损颗粒表征两方面研究了其磨损机理。Zr-2.5Nb-UHMWPE轴承在2、3和4 MPa时的UHMWPE磨损损失分别比CoCrMo-UHMWPE轴承低48%、27%和18%。结果表明:Zr-2.5Nb-UHMWPE和ZTA-UHMWPE在2 MPa时的磨损量与Zr-2.5Nb-UHMWPE和ZTA-UHMWPE无显著差异,但在4 MPa时的磨损量比ZTA-UHMWPE高34.5%;Zr-2.5Nb- uhmwpe的磨损性能与ZTA- uhmwpe相似,Zr-2.5Nb和ZTA表面无明显划痕,而CoCrMo表面出现多向划痕。在不同加载条件下,UHMWPE磨损颗粒的尺寸范围和形貌一致,但数量和尺寸分布不同。Zr-2.5Nb-UHMWPE在2、3、4 MPa下产生的UHMWPE磨损颗粒数比CoCrMo-UHMWPE少44% ~ 60%。而Zr-2.5Nb-UHMWPE和ZTA-UHMWPE产生的UHMWPE磨损颗粒非常相似,在4 MPa时分别为153和157。粒度分布结果表明,随着载荷的增加,三对磨损颗粒中大粒径磨损颗粒的比例逐渐增加。值得注意的是,Zr-2.5Nb-UHMWPE组合的UHMWPE磨损颗粒的平均粒径最大。形状分布分析进一步表明,Zr-2.5Nb-UHMWPE配对产生的UHMWPE磨粒形貌以纤维状为主,而CoCrMo-UHMWPE配对产生的UHMWPE磨粒形貌以圆形和椭圆形比例最高。基于磨损形貌和磨损颗粒特征分析,结果表明,磨损主要发生在超高分子量聚乙烯中。塑性变形是磨损颗粒形成的主要原因,磨损机制主要为粘着磨损和磨粒磨损。本研究比较了三种典型配对的摩擦学行为,为人工髋关节材料提供了有价值的认识,有助于骨科植入材料的优化。
{"title":"Wear mechanism and wear particles characterization of Zr-2.5Nb, ZTA, and CoCrMo articulating with UHMWPE in multidirectional motion","authors":"Ruijuan Liu ,&nbsp;Yali Zhang ,&nbsp;Xinle Li ,&nbsp;Xiaogang Zhang ,&nbsp;Jian Pu ,&nbsp;Qin Xiong ,&nbsp;Wen Shi ,&nbsp;Zhongmin Jin","doi":"10.1016/j.wear.2025.206459","DOIUrl":"10.1016/j.wear.2025.206459","url":null,"abstract":"<div><div>In traditional metal-on-polyethylene (MoP) implants, especially cobalt chrome molybdenum-ultra high molecular polyethylene (CoCrMo-UHMWPE) pairing, wear primarily occurs in the PE component. The wear particles from PE are considered a major cause of implant loosening and artificial joint failure. The development of oxidized zirconium-2.5 % niobium (Zr-2.5Nb) and zirconia-toughened alumina (ZTA) has shown promise in reducing wear and osteolysis risks. However, comparative studies on the wear mechanisms and wear particle characteristics of Zr-2.5Nb-UHMWPE, ZTA-UHMWPE, and CoCrMo-UHMWPE remain limited. In this study, Zr-2.5Nb, ZTA, and CoCrMo were selected and paired with UHMWPE as pairing materials. The wear mechanism was studied from the aspects of wear behavior and wear particle characterization at different contact pressures from 2 MPa to 4 MPa under multidirectional motion. The UHMWPE wear loss from Zr-2.5Nb-UHMWPE was 48 %, 27 %, and 18 % lower than that of CoCrMo-UHMWPE bearings at 2, 3, and 4 MPa. The results showed that there was no significant difference in the wear loss of UHMWPE from Zr-2.5Nb-UHMWPE and ZTA-UHMWPE at 2 MPa, but 34.5 % higher than that of ZTA-UHMWPE at 4 MPa. Zr-2.5Nb-UHMWPE exhibited a similar wear performance to ZTA-UHMWPE with no visible scratches on the surface of Zr-2.5Nb and ZTA, while multidirectional scratches appeared on the surface of CoCrMo. Moreover, the UHMWPE wear particles were consistent in size range and morphology, but different in quantity and size distribution at all loading conditions. The number of UHMWPE wear particles produced by the Zr-2.5Nb-UHMWPE pairing was 44 %–60 % lower than that of the CoCrMo-UHMWPE at 2, 3, and 4 MPa. However, the UHMWPE wear particles produced by Zr-2.5Nb-UHMWPE and ZTA-UHMWPE were very similar, which were 153 and 157 at 4 MPa, respectively. With increasing load, size distribution results revealed that the proportion of large-sized wear particles gradually increased for the three pairings. Notably, the UHMWPE wear particle from the Zr-2.5Nb-UHMWPE pairing exhibited the largest average particle size. Shape distribution analysis further indicated that the UHMWPE wear particle generated by the Zr-2.5Nb-UHMWPE pairing was predominantly fibrous in morphology, whereas that from the CoCrMo-UHMWPE pairing displayed the highest proportion of round and oval shapes. Based on the analysis of wear morphology and wear particle characteristics, the results showed that the wear mainly occurred in UHMWPE. Plastic deformation was the main cause of wear particle formation, and the wear mechanisms were adhesive wear and abrasive wear. This study compared the tribological behaviors of three typical pairings, providing a valuable understanding of artificial hip joint materials, which will contribute to optimizing orthopedic implant materials.</div></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":"586 ","pages":"Article 206459"},"PeriodicalIF":6.1,"publicationDate":"2025-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145798143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tribo-mechanisms of Cr2AlC nanocoating in lead-bismuth eutectic under multi-stage fretting cycles: Oxide-driven self-adaptive fretting wear protection 多级微动循环下铅铋共晶Cr2AlC纳米涂层的摩擦机制:氧化物驱动的自适应微动磨损保护
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-08 DOI: 10.1016/j.wear.2025.206460
Guangzhao Wang , Hui Chen , Xiaoyu Sun , Wenqi Song , Zhenyu Wang , Guorui Zhu
In Generation IV lead-cooled fast reactors, austenitic 316L stainless steel steam generator tubes are susceptible to both dissolution corrosion and fretting fatigue wear in liquid lead–bismuth eutectic (LBE) environment. To address this challenge, a Cr2AlC nanocoating was deposited on 316L tubes and evaluated through multi-stage fretting wear tests in LBE at 450 °C, using a self-developed high temperature tribo-tester with a tube–plate contact configuration. The results demonstrate that the coating maintains a stable friction coefficient (0.6 ± 0.05) throughout 5 × 103 to 2 × 106 cycles, representing an approximately 40 % reduction compared to bare 316L stainless steel. The maximum wear depth stabilizes at 14.2 ± 0.1 μm, approximately 70 % lower than that of uncoated 316L. Multiscale characterization by SEM/EDS, XRD, and nanoindentation revealed a three-stage friction response on the coating: an initial stage where the coating surface remains intact, and wear occurs mainly on the plate; a transitional stage characterized by the formation of a discontinuous third-body layer (TBL) comprising oxides and wear debris, exhibiting relatively low mechanical properties; and a stable stage dominated by a compact TBL primarily consisting of Cr3+-doped α-Al2O3, the wear surface H2/E3 ratio increases, which enhances resistance to both wear and Pb-Bi corrosion. The proposed Cr2AlC self-adaptive protection mechanism offers a scientific basis for designing wear-resistant coatings for steam generator tubing in Generation IV nuclear reactors.
在第四代铅冷快堆中,奥氏体316L不锈钢蒸汽发生器管在液态铅铋共晶(LBE)环境中容易发生溶解腐蚀和微动疲劳磨损。为了解决这一问题,研究人员在316L管上沉积了一层Cr2AlC纳米涂层,并使用自行开发的管板接触结构高温摩擦测试仪,在450°C的LBE中进行了多阶段微动磨损测试。结果表明,涂层在5 × 103到2 × 106循环中保持稳定的摩擦系数(0.6±0.05),与裸316L不锈钢相比,减少了约40%。最大磨损深度稳定在14.2±0.1 μm,比未涂层的316L低约70%。SEM/EDS、XRD和纳米压痕等多尺度表征表明,涂层表面存在三个阶段的摩擦响应:初始阶段涂层表面保持完整,磨损主要发生在板材上;过渡阶段,形成由氧化物和磨损碎屑组成的不连续第三体层(TBL),力学性能相对较低;进入以Cr3+掺杂α-Al2O3为主的致密TBL的稳定阶段,磨损表面H2/E3比值增大,耐磨性能和耐Pb-Bi腐蚀性能均增强。所提出的Cr2AlC自适应保护机制为第四代核反应堆蒸汽发生器管材耐磨涂层的设计提供了科学依据。
{"title":"Tribo-mechanisms of Cr2AlC nanocoating in lead-bismuth eutectic under multi-stage fretting cycles: Oxide-driven self-adaptive fretting wear protection","authors":"Guangzhao Wang ,&nbsp;Hui Chen ,&nbsp;Xiaoyu Sun ,&nbsp;Wenqi Song ,&nbsp;Zhenyu Wang ,&nbsp;Guorui Zhu","doi":"10.1016/j.wear.2025.206460","DOIUrl":"10.1016/j.wear.2025.206460","url":null,"abstract":"<div><div>In Generation IV lead-cooled fast reactors, austenitic 316L stainless steel steam generator tubes are susceptible to both dissolution corrosion and fretting fatigue wear in liquid lead–bismuth eutectic (LBE) environment. To address this challenge, a Cr<sub>2</sub>AlC nanocoating was deposited on 316L tubes and evaluated through multi-stage fretting wear tests in LBE at 450 °C, using a self-developed high temperature tribo-tester with a tube–plate contact configuration. The results demonstrate that the coating maintains a stable friction coefficient (0.6 ± 0.05) throughout 5 × 10<sup>3</sup> to 2 × 10<sup>6</sup> cycles, representing an approximately 40 % reduction compared to bare 316L stainless steel. The maximum wear depth stabilizes at 14.2 ± 0.1 μm, approximately 70 % lower than that of uncoated 316L. Multiscale characterization by SEM/EDS, XRD, and nanoindentation revealed a three-stage friction response on the coating: an initial stage where the coating surface remains intact, and wear occurs mainly on the plate; a transitional stage characterized by the formation of a discontinuous third-body layer (TBL) comprising oxides and wear debris, exhibiting relatively low mechanical properties; and a stable stage dominated by a compact TBL primarily consisting of Cr<sup>3+</sup>-doped α-Al<sub>2</sub>O<sub>3</sub>, the wear surface H<sup>2</sup>/E<sup>3</sup> ratio increases, which enhances resistance to both wear and Pb-Bi corrosion. The proposed Cr<sub>2</sub>AlC self-adaptive protection mechanism offers a scientific basis for designing wear-resistant coatings for steam generator tubing in Generation IV nuclear reactors.</div></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":"586 ","pages":"Article 206460"},"PeriodicalIF":6.1,"publicationDate":"2025-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145748881","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Differential effects of Ti addition on microstructure and corresponding mechanical and tribological properties of AlCr3Fe3NiTix high-entropy alloys Ti添加量对AlCr3Fe3NiTix高熵合金显微组织及相应力学摩擦学性能的差异影响
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-08 DOI: 10.1016/j.wear.2025.206463
Guijiang Diao , Zhen Xu , Anqiang He , Doug Fraser , Reinaldo Chung , Jing Li , D.Y. Li
High-entropy alloys (HEAs), particularly those with an A2+B2 dual-phase structure, offer balanced strength and toughness, leading to superior and well-adjustable wear resistance. The effect of titanium, known to promote the formation of hard intermetallic phases and enhance mechanical properties, on A2+B2 dual-phase HEAs remains less understood. In this work, selecting a representative AlCr3Fe3Ni alloy with A2+B2 phases as the base alloy, we systematically investigated the phase evolution induced by various amounts of Ti addition and their differential effects on the sliding wear and solid-particle erosion of AlCr3Fe3NiTix HEAs (x = 0–1.5, molar ratio). Microstructural analysis reveals that Ti addition promotes the formation of AlNi2Ti-type L21 and (Fe,Cr)2Ti-type C14 Laves phases, both of which strengthen the alloys at the expense of plasticity. However, a low Ti content (i.e., x = 0.2) helps improve both yield strength and plasticity, due to the solid-solution strengthening effect and refinement of grain size. Micro-indentation and scratching tests demonstrate that the C14 Laves phase exhibits the highest hardness but the lowest toughness, whereas the A2+B2 dual-phase structure possesses the highest toughness but the lowest hardness. The L21 phase displays intermediate properties between the two. Sliding wear and dry-sand erosion tests reveal that moderate Ti additions enhance wear resistance through solid-solution strengthening, hard-phase reinforcement, and oxidation-induced surface protection. However, erosion resistance deteriorates with increasing Ti content, primarily due to lowered toughness under impact conditions. This study elucidates the dual roles of Ti-induced hard yet brittle phases, i.e., beneficial for sliding wear resistance but detrimental to erosion performance in impact-involving environments requiring higher toughness. The findings provide valuable insights into structure-property relationships for the design of advanced structural and tribo-materials.
高熵合金(HEAs),特别是那些具有A2+B2双相结构的合金,具有平衡的强度和韧性,从而具有优越且可调节的耐磨性。钛在A2+B2双相HEAs中促进硬金属间相形成和提高力学性能的作用尚不清楚。本文以具有代表性的A2+B2相AlCr3Fe3Ni合金为基体,系统研究了不同Ti添加量对AlCr3Fe3NiTix HEAs (x = 0-1.5,摩尔比)滑动磨损和固相颗粒侵蚀的影响。显微组织分析表明,Ti的加入促进了AlNi2Ti-type L21和(Fe,Cr)2Ti-type C14 Laves相的形成,两者都以牺牲塑性为代价增强了合金。然而,由于固溶强化效应和晶粒细化,低Ti含量(即x = 0.2)有助于提高屈服强度和塑性。显微压痕和划痕试验表明,C14 Laves相的硬度最高,韧性最低;A2+B2双相组织的韧性最高,硬度最低。L21相表现出介于两者之间的中间性质。滑动磨损和干砂侵蚀试验表明,适量添加Ti通过固溶强化、硬相强化和氧化诱导的表面保护来提高耐磨性。然而,随着Ti含量的增加,耐蚀性恶化,这主要是由于在冲击条件下的韧性降低。该研究阐明了ti诱导的硬脆相的双重作用,即有利于滑动耐磨性,但不利于需要更高韧性的冲击环境中的侵蚀性能。这些发现为高级结构和摩擦材料的设计提供了有价值的结构-性能关系的见解。
{"title":"Differential effects of Ti addition on microstructure and corresponding mechanical and tribological properties of AlCr3Fe3NiTix high-entropy alloys","authors":"Guijiang Diao ,&nbsp;Zhen Xu ,&nbsp;Anqiang He ,&nbsp;Doug Fraser ,&nbsp;Reinaldo Chung ,&nbsp;Jing Li ,&nbsp;D.Y. Li","doi":"10.1016/j.wear.2025.206463","DOIUrl":"10.1016/j.wear.2025.206463","url":null,"abstract":"<div><div>High-entropy alloys (HEAs), particularly those with an A2+B2 dual-phase structure, offer balanced strength and toughness, leading to superior and well-adjustable wear resistance. The effect of titanium, known to promote the formation of hard intermetallic phases and enhance mechanical properties, on A2+B2 dual-phase HEAs remains less understood. In this work, selecting a representative AlCr<sub>3</sub>Fe<sub>3</sub>Ni alloy with A2+B2 phases as the base alloy, we systematically investigated the phase evolution induced by various amounts of Ti addition and their differential effects on the sliding wear and solid-particle erosion of AlCr<sub>3</sub>Fe<sub>3</sub>NiTi<sub>x</sub> HEAs (x = 0–1.5, molar ratio). Microstructural analysis reveals that Ti addition promotes the formation of AlNi<sub>2</sub>Ti-type L2<sub>1</sub> and (Fe,Cr)<sub>2</sub>Ti-type C14 Laves phases, both of which strengthen the alloys at the expense of plasticity. However, a low Ti content (i.e., x = 0.2) helps improve both yield strength and plasticity, due to the solid-solution strengthening effect and refinement of grain size. Micro-indentation and scratching tests demonstrate that the C14 Laves phase exhibits the highest hardness but the lowest toughness, whereas the A2+B2 dual-phase structure possesses the highest toughness but the lowest hardness. The L2<sub>1</sub> phase displays intermediate properties between the two. Sliding wear and dry-sand erosion tests reveal that moderate Ti additions enhance wear resistance through solid-solution strengthening, hard-phase reinforcement, and oxidation-induced surface protection. However, erosion resistance deteriorates with increasing Ti content, primarily due to lowered toughness under impact conditions. This study elucidates the dual roles of Ti-induced hard yet brittle phases, i.e., beneficial for sliding wear resistance but detrimental to erosion performance in impact-involving environments requiring higher toughness. The findings provide valuable insights into structure-property relationships for the design of advanced structural and tribo-materials.</div></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":"586 ","pages":"Article 206463"},"PeriodicalIF":6.1,"publicationDate":"2025-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145749898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a white-box model for predicting in-process thermo-mechanical loading on PVD-coated carbide tools 开发用于预测pvd涂层硬质合金刀具在加工过程中热机械负荷的白盒模型
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-05 DOI: 10.1016/j.wear.2025.206458
T. Bergs , M. Meurer , M. Abouridouane , K. Bobzin , C. Kalscheuer , M. Tayyab
PVD coatings are widely used to improve tool life and machining efficiency, yet accurate tool-life prediction remains challenging because thin layers require very fine meshes, coating wear mechanisms are complex, and the coating-substrate interface introduces difficult thermal and mechanical boundary conditions. Traditional white-box models frequently neglect coating effects due to simplified assumptions, whereas black-box models capture complexity but lack physical interpretability. Grey-box approaches offer a promising compromise but require detailed coating- and load-dependent datasets. This study develops a finite-element (FE) model to predict in-process thermo-mechanical loading on PVD-coated carbide tools. The white-box model supports the extensive experimental testing typically required to generate thermo-mechanical load tables for grey-box tool-life prediction. Monolayer TiAlCrSiN and bilayer TiAlCrSiN/TiAlCrSiON coatings-commercially established and representative of industrial thermal-barrier behaviour were tested in orthogonal cutting of C45 + N steel. Cutting forces and tool temperatures were measured using a dynamometer and an embedded two-colour pyrometer for model validation. The model reproduces forces and temperatures with deviations below 10 % and shows that tool wear strongly affects local thermo-mechanical load distributions, while global loads remain similar between the coatings. Friction characterization reveals a tribological advantage of the bilayer coating, with reduced interface friction and smoother surfaces. High-resolution stress and temperature fields are correlated with coating properties to improve wear modelling and provide structured inputs for future grey-box model development.
PVD涂层广泛用于提高刀具寿命和加工效率,但准确的刀具寿命预测仍然具有挑战性,因为薄层需要非常精细的网格,涂层磨损机制复杂,涂层-基体界面引入了困难的热学和机械边界条件。传统的白盒模型往往由于假设简化而忽略了涂层效应,而黑盒模型捕获了复杂性,但缺乏物理可解释性。灰盒方法提供了一个有希望的折衷方案,但需要详细的涂层和负载相关数据集。本研究开发了一个有限元(FE)模型来预测pvd涂层硬质合金刀具在加工过程中的热机械载荷。白盒模型支持广泛的实验测试,通常需要生成用于灰盒工具寿命预测的热机械载荷表。在C45 + N钢的正交切削试验中,测试了单层TiAlCrSiN和双层TiAlCrSiN/TiAlCrSiON涂层的工业热障性能。切削力和刀具温度使用测功机和嵌入式双色高温计进行模型验证。该模型再现的力和温度偏差小于10%,表明刀具磨损强烈影响局部热机械载荷分布,而涂层之间的整体载荷保持相似。摩擦特性揭示了双层涂层的摩擦学优势,减少了界面摩擦,表面更光滑。高分辨率应力场和温度场与涂层性能相关联,以改进磨损建模,并为未来灰盒模型的开发提供结构化输入。
{"title":"Development of a white-box model for predicting in-process thermo-mechanical loading on PVD-coated carbide tools","authors":"T. Bergs ,&nbsp;M. Meurer ,&nbsp;M. Abouridouane ,&nbsp;K. Bobzin ,&nbsp;C. Kalscheuer ,&nbsp;M. Tayyab","doi":"10.1016/j.wear.2025.206458","DOIUrl":"10.1016/j.wear.2025.206458","url":null,"abstract":"<div><div>PVD coatings are widely used to improve tool life and machining efficiency, yet accurate tool-life prediction remains challenging because thin layers require very fine meshes, coating wear mechanisms are complex, and the coating-substrate interface introduces difficult thermal and mechanical boundary conditions. Traditional white-box models frequently neglect coating effects due to simplified assumptions, whereas black-box models capture complexity but lack physical interpretability. Grey-box approaches offer a promising compromise but require detailed coating- and load-dependent datasets. This study develops a finite-element (FE) model to predict in-process thermo-mechanical loading on PVD-coated carbide tools. The white-box model supports the extensive experimental testing typically required to generate thermo-mechanical load tables for grey-box tool-life prediction. Monolayer TiAlCrSiN and bilayer TiAlCrSiN/TiAlCrSiON coatings-commercially established and representative of industrial thermal-barrier behaviour were tested in orthogonal cutting of C45 + N steel. Cutting forces and tool temperatures were measured using a dynamometer and an embedded two-colour pyrometer for model validation. The model reproduces forces and temperatures with deviations below 10 % and shows that tool wear strongly affects local thermo-mechanical load distributions, while global loads remain similar between the coatings. Friction characterization reveals a tribological advantage of the bilayer coating, with reduced interface friction and smoother surfaces. High-resolution stress and temperature fields are correlated with coating properties to improve wear modelling and provide structured inputs for future grey-box model development.</div></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":"586 ","pages":"Article 206458"},"PeriodicalIF":6.1,"publicationDate":"2025-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145748879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation on the tribological performance of (NiCrFe)83(TiAl)17 high-entropy alloy-matrix self-lubricating coatings in helium environment (NiCrFe)83(TiAl)17高熵合金基自润滑涂层在氦环境下的摩擦学性能研究
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-04 DOI: 10.1016/j.wear.2025.206449
Dongsheng Yang , Zhilong Zhao , Yushan Geng , Qichun Sun , Wenyuan Chen , Juanjuan Chen , Shengyu Zhu , Jun Cheng , Peiqing La
This study successfully developed a (NiCrFe)83(TiAl)17-Al2O3-Ag/(BaF2/CaF2) composite self-lubricating coating and systematically investigated its tribological performance in helium environments from room temperature to 600 °C. The results revealed that the coating possessed a stable high-entropy phase structure consisting of a (Ni, Ti)-enriched BCC matrix and (Cr, Fe)-enriched FCC precipitates. The Al2O3 reinforcement phase increased the surface hardness to 692.17 HV through particle strengthening, representing a 21.3 % improvement over the (NiCrFe)83(TiAl)17 base material. The synergistic effect between the lubricating phases and Al2O3 reduced the friction coefficient to 0.25–0.31 and significantly decreased the wear rate to (0.8–3.5) × 10−5 mm3/N·m within the RT-400 °C range. As temperature increased, the friction interface underwent systematic evolution: a partial lubricating film formed at RT with dominant abrasive wear; the composite lubricating film expanded between 200–400 °C, effectively suppressing three-body wear; at 600 °C, BCC phase depletion caused the wear mechanism to transition to a mixed abrasive-adhesive mode. The synergistic strengthening between Al2O3 and the lubricating phases was identified as the key factor enabling the coating's excellent performance across the wide temperature range.
本研究成功制备了一种(NiCrFe)83(TiAl)17-Al2O3-Ag/(BaF2/CaF2)复合自润滑涂层,并系统地研究了其在室温至600℃氦气环境下的摩擦学性能。结果表明,该涂层具有稳定的高熵相结构,由富集(Ni, Ti)的BCC基体和富集(Cr, Fe)的FCC相组成。Al2O3增强相通过颗粒强化将表面硬度提高到692.17 HV,比(NiCrFe)83(TiAl)17基体提高了21.3%。在RT-400℃范围内,润滑相与Al2O3的协同作用使摩擦系数降至0.25 ~ 0.31,磨损率降至(0.8 ~ 3.5)× 10−5 mm3/N·m。随着温度的升高,摩擦界面发生了系统的演变:在高温下形成部分润滑膜,以磨粒磨损为主;复合润滑膜在200 ~ 400℃之间膨胀,有效抑制三体磨损;在600°C时,BCC相耗尽导致磨损机制转变为混合磨料-粘合剂模式。Al2O3与润滑相之间的协同强化是涂层在宽温度范围内具有优异性能的关键因素。
{"title":"Investigation on the tribological performance of (NiCrFe)83(TiAl)17 high-entropy alloy-matrix self-lubricating coatings in helium environment","authors":"Dongsheng Yang ,&nbsp;Zhilong Zhao ,&nbsp;Yushan Geng ,&nbsp;Qichun Sun ,&nbsp;Wenyuan Chen ,&nbsp;Juanjuan Chen ,&nbsp;Shengyu Zhu ,&nbsp;Jun Cheng ,&nbsp;Peiqing La","doi":"10.1016/j.wear.2025.206449","DOIUrl":"10.1016/j.wear.2025.206449","url":null,"abstract":"<div><div>This study successfully developed a (NiCrFe)<sub>83</sub>(TiAl)<sub>17</sub>-Al<sub>2</sub>O<sub>3</sub>-Ag/(BaF<sub>2</sub>/CaF<sub>2</sub>) composite self-lubricating coating and systematically investigated its tribological performance in helium environments from room temperature to 600 °C. The results revealed that the coating possessed a stable high-entropy phase structure consisting of a (Ni, Ti)-enriched BCC matrix and (Cr, Fe)-enriched FCC precipitates. The Al<sub>2</sub>O<sub>3</sub> reinforcement phase increased the surface hardness to 692.17 HV through particle strengthening, representing a 21.3 % improvement over the (NiCrFe)<sub>83</sub>(TiAl)<sub>17</sub> base material. The synergistic effect between the lubricating phases and Al<sub>2</sub>O<sub>3</sub> reduced the friction coefficient to 0.25–0.31 and significantly decreased the wear rate to (0.8–3.5) × 10<sup>−5</sup> mm<sup>3</sup>/N·m within the RT-400 °C range. As temperature increased, the friction interface underwent systematic evolution: a partial lubricating film formed at RT with dominant abrasive wear; the composite lubricating film expanded between 200–400 °C, effectively suppressing three-body wear; at 600 °C, BCC phase depletion caused the wear mechanism to transition to a mixed abrasive-adhesive mode. The synergistic strengthening between Al<sub>2</sub>O<sub>3</sub> and the lubricating phases was identified as the key factor enabling the coating's excellent performance across the wide temperature range.</div></div>","PeriodicalId":23970,"journal":{"name":"Wear","volume":"586 ","pages":"Article 206449"},"PeriodicalIF":6.1,"publicationDate":"2025-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145749899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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