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Wear mechanisms of Ni–W and Ni–W/Al2O3 composite coatings sliding against Si3N4 and AISI 52100 steel counterbodies Ni-W和Ni-W/Al2O3复合涂层与Si3N4和AISI 52100钢对抗体滑动的磨损机理
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-09 DOI: 10.1016/j.wear.2024.205486
Ze Fan , Yumei Yang , Fahai Ba , Ze Chai , Le Zhao , Xinying Han , Zhongquan Zhang , Guoying Wei

In this work, wear mechanisms of electrodeposited Ni–W and Ni–W/Al2O3 coatings sliding against Si3N4 and AISI 52100 steel have been comparatively studied. For both Ni–W and its composite coatings sliding against Si3N4, worn morphology shows the tribochemical reaction (tribooxidation) followed by abrasive wear is the dominated mechanism. Comparing with Ni–W coatings, the protective oxide layer is slower peeled off at tribooxidation stage and wear debris are easier squeezed on the Ni–W/Al2O3 during abrasive wear stage. The incorporated Al2O3 provide load bearing effect during microploughing and improve the wear resistance. As sliding against AISI 52100 steel, wear rate of Ni–W/Al2O3 is several times higher than that of Ni–W coatings. Conformity between surfaces of the Ni–W coating and counterbody leads to mild smoothening wear, while the plastic deformation dominated delamination makes severe wear of Ni–W/Al2O3. Deformation resistance of the coatings and transition of counterbodies materials from ceramic to hard metal are responsible for the different wear mechanisms. For Si3N4 ceramic, low thermal conductivity leads to tribooxidation followed by abrasive wear of both Ni–W and Ni–W/Al2O3 coatings. Relatively high deformation resistance of Ni–W coatings is responsible for the conformity as the premise for mild wear sliding against AISI 52100. Low deformation resistance of composite coatings induced by weak interfaces between Al2O3 and Ni–W matrix makes delamination sustained.

这项研究比较了电沉积 Ni-W 和 Ni-W/Al2O3 涂层与 Si3N4 和 AISI 52100 钢滑动时的磨损机理。对于在 Si3N4 上滑动的 Ni-W 及其复合涂层,磨损形貌表明摩擦化学反应(摩擦氧化)和磨料磨损是主要的磨损机制。与 Ni-W 涂层相比,保护氧化层在摩擦氧化阶段的剥离速度较慢,在磨料磨损阶段,磨损碎屑更容易挤压到 Ni-W/Al2O3 上。加入的 Al2O3 可在微刨过程中起到承载作用,提高耐磨性。在与 AISI 52100 钢滑动时,Ni-W/Al2O3 的磨损率是 Ni-W 涂层的数倍。Ni-W 涂层和对体表面之间的一致性会导致轻微的平滑磨损,而塑性变形主导的分层会使 Ni-W/Al2O3 严重磨损。涂层的抗变形能力以及对撞体材料从陶瓷到硬金属的转变是造成不同磨损机制的原因。对于 Si3N4 陶瓷来说,低导热性导致 Ni-W 和 Ni-W/Al2O3 涂层先发生摩擦氧化,然后出现磨料磨损。Ni-W 涂层相对较高的抗变形能力是其与 AISI 52100 相比符合轻度磨损滑动的前提条件。由于 Al2O3 和 Ni-W 基体之间的界面较弱,复合涂层的抗变形能力较低,因此分层现象持续存在。
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引用次数: 0
Facile fabrication of Co-containing coating to enhance the wear resistance of 24CrNiMo steel at elevated temperature 简易制备含 Co 涂层以提高 24CrNiMo 钢在高温下的耐磨性
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-09 DOI: 10.1016/j.wear.2024.205484
Gongbin Tang , Haobing Hu , Zongbi Huang , Yiting Pan , Tao Zou , Zhongwei Liang , Jingwen Wang , Fenghua Su

High-speed train brake discs, relying on surface friction for braking, can reach up to 600 °C, significantly increasing wear and adversely affecting performance and lifespan. Here, we propose a facile approach employing ultrasonic shot peening with the addition of cobalt (Co) particles (termed UEG) to creates a dense Co-containing coating on the 24CrNiMo steel. Friction tests show that UEG samples exhibit more stable friction coefficients and lower wear rates at temperatures ranging from 25 to 600 °C. Experimental and analytical results reveal a higher dislocation density in the UEG-treated samples surface and the formation of a dense Co-enriched tribofilm, effectively enhancing wear resistance. The findings indicate that UEG has considerable promise for enhancing the wear resistance of brake discs in high-temperature environments.

高速列车制动盘依靠表面摩擦力进行制动,温度可高达 600 °C,这大大增加了磨损,并对性能和使用寿命产生不利影响。在此,我们提出了一种简单易行的方法,即在 24CrNiMo 钢中添加钴(Co)颗粒(称为 UEG),利用超声波喷丸强化技术形成致密的含 Co 涂层。摩擦测试表明,UEG 样品在 25 至 600 °C 的温度范围内表现出更稳定的摩擦系数和更低的磨损率。实验和分析结果表明,经过 UEG 处理的试样表面位错密度更高,并形成了致密的富钴三膜,从而有效提高了耐磨性。研究结果表明,UEG 在提高高温环境下制动盘的耐磨性方面大有可为。
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引用次数: 0
Solid particle erosion of CVD diamond coatings: A review CVD 金刚石涂层的固体颗粒侵蚀:综述
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-09 DOI: 10.1016/j.wear.2024.205488

This paper reviews the behaviour of CVD diamond coatings when subjected to solid particle erosion. The high hardness, elastic modulus and strength of diamond coatings make them attractive options for use in components employed in erosive environments. Nevertheless, despite the disparity in properties between diamond and many common erodents such as silica, which can result in extensive damage to the impacting particles, repeated particle impacts can generate damage to the coating resulting in sudden and catastrophic failure. The factors affecting the erosion behaviour of diamond coatings are described, as well as the common features of erosion damage in diamond coatings, together with the mechanisms by which they were formed. Such understanding can assist in the design of coated components for use in erosive environments.

本文回顾了 CVD 金刚石涂层在受到固体颗粒侵蚀时的表现。金刚石涂层的高硬度、弹性模量和强度使其成为在侵蚀环境中使用的部件的理想选择。然而,尽管金刚石和许多常见侵蚀物(如二氧化硅)之间的特性存在差异,会对撞击颗粒造成大面积破坏,但反复的颗粒撞击会对涂层造成破坏,导致突然的灾难性故障。本文介绍了影响金刚石涂层侵蚀行为的因素,以及金刚石涂层侵蚀损伤的常见特征及其形成机理。这种认识有助于设计在侵蚀环境中使用的涂层部件。
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引用次数: 0
Regulating the severe running-in wear of polymer composites by a dual-pin-on-disk (DPOD) multicomponent approach 通过盘上双针(DPOD)多组分方法调节聚合物复合材料的严重磨合磨损
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-08 DOI: 10.1016/j.wear.2024.205483
Zhibin Lin , Peng Tao , Ke Zhang , Xiaogang Zhao , Bingzhao Gao , Zenghai Shan , Zhikai Chen , Zhihui Zhang

Polymer composites are increasingly used as frictional components due to their self-lubricating properties. However, they tend to exhibit severe wear during the running-in stage, thus significantly impairing their service life. In the present work, a dual-pin-on-disk (DPOD) method is developed in order to reduce the running-in wear of a polytetrafluoroethylene/alumina (PTFE/Al2O3) composite when sliding against GCr15 bearing steel by introducing an assistant polymer component during the running-in stage. The results show that the running-in wear rate of the main polymer pin is reduced by up to 77.26 %. This is because the assistant pin causes excess wear debris to be released into the wear track and provides a higher shear force, thereby promoting the tribological chemical reactions and facilitating the generation of tribofilms on the worn surfaces. In addition, the processed polymer achieves a wear rate similar to that of the conventional single pin condition (∼3 × 10−7mm3/Nm) in the subsequent steady-state stage. The results of the present work are expected to increase significantly the wear life span and application prospects of the polymer composites.

聚合物复合材料具有自润滑特性,因此越来越多地被用作摩擦部件。然而,它们在磨合阶段往往会出现严重磨损,从而大大影响其使用寿命。在本研究中,为了减少聚四氟乙烯/氧化铝(PTFE/Al2O3)复合材料在与 GCr15 轴承钢滑动时的磨合磨损,开发了一种盘上双针(DPOD)方法,即在磨合阶段引入辅助聚合物成分。结果表明,主聚合物销的磨合磨损率降低了 77.26%。这是因为辅助销会将多余的磨损碎片释放到磨损轨道中,并提供更高的剪切力,从而促进摩擦化学反应,有利于在磨损表面生成摩擦薄膜。此外,在随后的稳态阶段,加工聚合物的磨损率与传统单销状态下的磨损率(∼3 × 10-7mm3/Nm)相近。本研究成果有望显著延长聚合物复合材料的磨损寿命,并拓展其应用前景。
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引用次数: 0
Mechanochemical exfoliation of sugar-assisted boron nitride nanosheets for achieving superlubricity and wear distinction 机械化学法剥离糖辅助氮化硼纳米片,实现超润滑性和耐磨损性
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-03 DOI: 10.1016/j.wear.2024.205482
Shuang Yi , Jinjin Li , Zhengguang Zuo , Jiawei Fu , Hongbin Chen , Liu Yang , Yadong Xu , Linfang Qian , Longmiao Chen , Songlin Ding

Boron nitride nanosheets (BNNS) possess extensive potential applications across various fields. However, their limited dispersibility in liquids constrains their effectiveness as lubricating additives. In this study, a streamlined sugar-assisted mechanochemical exfoliation technique was employed to concurrently exfoliate and functionalize BNNS. This approach enabled the covalent grafting of sucrose molecules onto BNNS, enhancing their dispersion in water. The application of water containing sucrose-modified BNNS (S-BNNS) facilitated an ultralow coefficient of friction (COF = 0.001) at the Si₃N₄-Si₃N₄ interface. Additionally, using S-BNNS nanosheets as lubricating additives in water achieved superlubricity with a significant surface roughness (Ra ≤120 nm). We explored the correlation between surface roughness and superlubricity, revealing that tribological performance was enhanced by the formation of a tribofilm composed of S-BNNS and a silica layer at the interface through tribochemical reactions. The exceptional anti-wear properties and significantly reduced shear strength of S-BNNS within the tribofilm substantially contributed to achieving the ultralow COF, thus enhancing lubrication performance.

氮化硼纳米片(BNNS)在各个领域都具有广泛的应用潜力。然而,氮化硼在液体中的分散性有限,限制了其作为润滑添加剂的有效性。在本研究中,我们采用了一种简化的糖辅助机械化学剥离技术来同时剥离和功能化 BNNS。这种方法可将蔗糖分子共价接枝到 BNNS 上,从而增强其在水中的分散性。使用含有蔗糖改性 BNNS(S-BNNS)的水,有助于在硅₃N₄-硅₃N₄界面上实现超低摩擦系数(COF = 0.001)。此外,在水中使用 S-BNNS 纳米片作为润滑添加剂可获得超润滑性,同时具有显著的表面粗糙度(Ra ≤120 nm)。我们探索了表面粗糙度与超润滑性之间的相关性,发现通过摩擦化学反应,在界面上形成了由 S-BNNS 和二氧化硅层组成的三膜,从而提高了摩擦学性能。三膜中的 S-BNNS 具有优异的抗磨损性能,并显著降低了剪切强度,这在很大程度上有助于实现超低 COF,从而提高润滑性能。
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引用次数: 0
Enhanced reducing effect induced by biocarbon-modified magnesium silicate hydroxide for better tribologicalproperties 生物碳改性硅酸镁氢氧化物可增强还原效应,从而获得更好的摩擦学性能
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-03 DOI: 10.1016/j.wear.2024.205479
Rongqin Gao , Wenbo Liu , Qiuying Chang

In this study, the reducibility from silicate minerals is determined and its effect on their tribological properties as lubricant additive is introduced firstly with magnesium silicate hydroxide (MSH) and biocarbon-modified magnesium silicate hydroxide (MSH@C) as operating medium. The differentiated reduction effects induced by MSH and MSH@C are clarified through worn surface analysis, and related tribological tests are conducted on a four-ball machine under different conditions. Results show that biocarbon surface-coating on MSH will enhance the reducibility of MSH and results in better lubrication performance (wear reduced by 10.487 % and friction reduced by 11.321 % under boundary lubrication while wear reduced by 16.566 % and friction reduced by 33.871 % under mixed lubrication compared with MSH) by reducing Fe2O3 to Fe3O4 more effectively on worn surfaces. Besides, the reduction mechanisms of MSH and MSH@C on iron oxides are explained.

在本研究中,首先以硅酸镁氢氧化物(MSH)和生物碳改性硅酸镁氢氧化物(MSH@C)为工作介质,测定了硅酸盐矿物的还原性,并介绍了其作为润滑油添加剂对摩擦学特性的影响。通过磨损表面分析,阐明了 MSH 和 MSH@C 所引起的不同减摩效果,并在四球机上进行了不同条件下的相关摩擦学试验。结果表明,MSH 上的生物碳表面涂层能更有效地将磨损表面上的 Fe2O3 还原成 Fe3O4,从而提高 MSH 的还原性并改善润滑性能(与 MSH 相比,在边界润滑条件下磨损减少了 10.487 %,摩擦减少了 11.321 %;在混合润滑条件下磨损减少了 16.566 %,摩擦减少了 33.871 %)。此外,还解释了 MSH 和 MSH@C 对铁氧化物的还原机制。
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引用次数: 0
Superdispersed spherical fullerenol and lamellar graphene oxide synergize to enhance the antiwear properties of water-based lubricants: Mathematical model and mechanism investigation 超分散球形富勒烯醇与片状氧化石墨烯协同增强水基润滑剂的抗磨损性能:数学模型与机理研究
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-03 DOI: 10.1016/j.wear.2024.205481
Bo Wu , Liangbin Wu , Chuan Li , Ziji Yuan , Qian Wu , Changge Wang , Ling Xu , Ye Qin , Xianguo Hu , Chuanrun Li

The development of high-performance water-based lubricating additives with excellent properties has been the focus of research recently. Herein, carbon-based nanomaterials made of spherical fullerenol and lamellar graphene oxide (GO) were explored as water-based lubricating additives to enhance tribological properties via the response surface method systematically. The antiwear mechanisms of the carbon-based nanomaterials were revealed through simultaneous wear surface characterizations and molecular dynamics simulations. Results showed that the spherical fullerenol and lamellar GO had superdispersion stability in the water-based lubricants. Fullerenol and GO could play a superior synergistic role to considerably enhance the antiwear properties of the water-based lubricants. Particularly, the wear rate decreased by almost 93 % when the water-based lubricant was supplemented with fullerenol and GO (0.1 wt% each) at the load of 1.5 N and sliding speed of 30 mm/s. The antiwear mechanisms indicated that an excellent antiwear effect was produced by the stable tribofilms containing GO and fullerenol, which combined with hydration layers synergistically exerting a bearing capacity.

开发性能优异的高性能水基润滑添加剂是近年来的研究重点。本文通过响应面法系统地探讨了球状富勒烯醇和片状氧化石墨烯(GO)组成的碳基纳米材料作为水基润滑添加剂增强摩擦学性能的问题。通过同时进行磨损表面表征和分子动力学模拟,揭示了碳基纳米材料的抗磨损机理。结果表明,球形富勒烯醇和片状 GO 在水基润滑剂中具有超分散稳定性。富勒烯醇和 GO 可发挥卓越的协同作用,大大提高水基润滑剂的抗磨损性能。特别是在负荷为 1.5 N、滑动速度为 30 mm/s 的条件下,在水基润滑剂中添加富勒烯醇和 GO(各 0.1 wt%)后,磨损率降低了近 93%。抗磨损机理表明,含有 GO 和富勒烯醇的稳定三膜产生了极佳的抗磨损效果,它们与水化层相结合,协同发挥了承载能力。
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引用次数: 0
Determination of “tribological performance working fields” for pure PEEK and PEEK composites under dry sliding conditions 确定纯 PEEK 和 PEEK 复合材料在干燥滑动条件下的 "摩擦学性能工作区域
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-02 DOI: 10.1016/j.wear.2024.205464
Ahmet Maslavi , Huseyin Unal , M. Nadir Olabi

Poly-ether-ether-ketone (PEEK) and PEEK composites are widely used polymers in many engineering applications where dry sliding is required. In this study, the influence of sliding velocity and applied load values on the friction and wear behavior of pure PEEK, 30 wt% glass fiber reinforced PEEK (PEEK-30GF), 30 wt% carbon fiber reinforced PEEK (PEEK-30CF) and 10 wt% carbon fiber+10 wt%graphite +10 wt%poly-tetra-fluoro-ethylene (PTFE) filled PEEK (ie. High (H) pressure (P) and velocity (V) resistant PEEK (PEEK-HPV)) composites rubbing against AISI 304 stainless steel disc was investigated. The experiments were carried out at room temperature under dry sliding conditions in a pin-on-disc wear rig. The applied loads ranged from 30 to 250 N, while the sliding velocities ranged from 1.0 to 4.0 m/s. At these load and velocity ranges, the friction coefficient-wear rate relationship of pure PEEK and composites was established and evaluated. In addition, the operating load-velocity limits of each material were determined and stated. The lowest coefficient of friction and wear rate were obtained in PEEK-HPV, PEEK-30CF, PEEK-30GF composites and pure PEEK polymer, respectively. In addition, it was observed that the coefficient of friction (CoF) decreased and the specific wear rate (SWR) increased with the increase in sliding velocity and applied load in all PEEK materials. The wear rate values of PEEK-HPV and PEEK-30%CF composites are in the range of 10−7 - 10−6 (mm3/Nm), while the wear rate values of pure PEEK and PEEK-30%GF are in the range of 10−6 - 10−5 (mm3/Nm). It was determined that carbon fiber, graphite and PTFE additives added to PEEK polymer as hybrid were very effective in reducing the wear rate of PEEK composite (PEEK-HPV). An adhesive wear mechanism was observed in PEEK-HPV and PEEK-30CF composites both at low load and velocity values and at high load and velocity values.

聚醚醚酮(PEEK)和 PEEK 复合材料是许多需要干滑动的工程应用中广泛使用的聚合物。在这项研究中,滑动速度和外加载荷值对纯 PEEK、30 wt% 玻璃纤维增强 PEEK(PEEK-30GF)、30 wt% 碳纤维增强 PEEK(PEEK-30CF)和 10 wt% 碳纤维+10 wt% 石墨+10 wt% 聚四氟乙烯(PTFE)填充 PEEK(即 PEEK-30GF)的摩擦和磨损行为的影响。研究了与 AISI 304 不锈钢圆盘摩擦的耐高压(H)和耐高速(V)PEEK(PEEK-HPV)复合材料。实验是在室温下的干滑动条件下,在针盘磨损装置中进行的。施加的载荷从 30 牛顿到 250 牛顿不等,滑动速度从 1.0 米/秒到 4.0 米/秒不等。在这些载荷和速度范围内,建立并评估了纯 PEEK 和复合材料的摩擦系数-磨损率关系。此外,还确定并说明了每种材料的工作载荷-速度极限。PEEK-HPV、PEEK-30CF、PEEK-30GF 复合材料和纯 PEEK 聚合物的摩擦系数和磨损率分别最低。此外,还观察到所有 PEEK 材料的摩擦系数(CoF)随着滑动速度和施加载荷的增加而降低,比磨损率(SWR)随着滑动速度和施加载荷的增加而增加。PEEK-HPV 和 PEEK-30%CF 复合材料的磨损率值在 10-7 - 10-6 (mm3/Nm) 之间,而纯 PEEK 和 PEEK-30%GF 的磨损率值在 10-6 - 10-5 (mm3/Nm) 之间。结果表明,在 PEEK 聚合物中添加碳纤维、石墨和 PTFE 添加剂作为混合物能非常有效地降低 PEEK 复合材料(PEEK-HPV)的磨损率。在 PEEK-HPV 和 PEEK-30CF 复合材料中,无论是在低载荷和速度值下,还是在高载荷和速度值下,都观察到了粘着磨损机制。
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引用次数: 0
Analysis of transient lubrication and wear coupling behaviors considering thermal effect and journal misalignment for main bearings under dynamic load 考虑热效应和轴颈不对中的动载荷下主轴承瞬态润滑和磨损耦合行为分析
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-02 DOI: 10.1016/j.wear.2024.205478
Rui Chen , Bin Zhao , Qi Xin , Xiaoxiao Niu , Zhongliang Xie , Xiqun Lu , Dequan Zou

This study developed a numerical model that coupled transient lubrication and wear in misaligned main bearings under dynamic loading conditions. This model accounts for variations in oil film thickness attributable to journal misalignment, elastic deformation, wear, and temperature fluctuations during the operational cycle of the bearing. Validation of the model's accuracy is achieved through comparisons of bearing temperature, and wear depth. An extensive analysis is conducted on the temporal evolution of temperature, contact pressure, oil film pressure and thickness, wear depth, and wear loss. Comparative assessments between misaligned and aligned bearings are performed. The findings reveal that in cases of journal misalignment, wear depth and contact pressure predominantly accumulate on the edge side, with the maximum wear depth, peak oil film pressure, peak asperity contact pressure, and temperature significantly exceeding those in aligned conditions. Furthermore, to underscore the importance of incorporating temperature in the coupling model, a comparative analysis of lubrication and wear characteristics between isothermal and thermal models across varying radius gaps is conducted. It indicates the necessity of factoring in temperature effects when assessing lubrication and wear properties. It is observed that bearing temperature tends to decrease correspondingly with wear progression.

本研究建立了一个数值模型,将动态载荷条件下错位主轴承的瞬态润滑和磨损耦合在一起。该模型考虑了轴承运行周期内轴颈错位、弹性变形、磨损和温度波动引起的油膜厚度变化。通过比较轴承温度和磨损深度,验证了模型的准确性。对温度、接触压力、油膜压力和厚度、磨损深度和磨损失效的时间演变进行了广泛分析。对不对中轴承和对中轴承进行了比较评估。研究结果表明,在轴颈错位的情况下,磨损深度和接触压力主要积聚在边缘侧,最大磨损深度、峰值油膜压力、峰值表面接触压力和温度明显超过对齐情况下的值。此外,为了强调将温度纳入耦合模型的重要性,我们对不同半径间隙的等温模型和热模型的润滑和磨损特性进行了比较分析。结果表明,在评估润滑和磨损特性时,有必要考虑温度效应。据观察,轴承温度往往会随着磨损的加剧而相应降低。
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引用次数: 0
Surface and core dual-designed carbon dots toward high-efficiency nano-lubricant additives for polyethylene glycol 面向聚乙二醇高效纳米润滑添加剂的表面和核心双重设计碳点
IF 5.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-07-02 DOI: 10.1016/j.wear.2024.205480
Weiwei Tang , Yi Wang , Yuhui Tan , Yunzhi Tang , Yufeng Li , Wei Zhu

Recently, energy and environmental crises have aggravated sharply, which results in the eco-friendly and high-efficiency polyethylene glycol (PEG) lubricating oils getting increasingly attention in lubrication. Advancing in PEG-based lubricating oils, especially their high-performance nano-additives is vitally important for energy conservation and reducing pollution. Therefore, a kind of surface and core dual-designed carbon dots (Zn,Cu,Fe-CDs-N) modified by ionic liquid groups ([AMIm][N(CF3SO2)2]) and doped by polymetallic atoms (Zn, Cu, and Fe) were first synthesized and creatively used as the nano-additives for the PEG200 base oil. Adding 1.0 wt% of Zn,Cu,Fe-CDs-N can endow the PEG200 base oil with optimal friction-reduction, anti-wear, and load-supporting performances, the maximal increase amplitudes of approximately 46.6 %, 66.3 %, and 125.0 %, respectively. Additionally, the tribological properties of Zn,Cu,Fe-CDs-N are without any weakening even under high load and long-time operating conditions, exhibiting good practicability and application prospects. Theoretical and experimental studies have illustrated the excellent tribological behaviors of Zn,Cu,Fe-CDs-N assigned to the synergy of film-forming and nano-lubrication effects.

近来,能源和环境危机急剧加剧,因此环保高效的聚乙二醇(PEG)润滑油在润滑领域日益受到重视。推进 PEG 润滑油的发展,尤其是其高性能纳米添加剂的发展,对于节约能源和减少污染至关重要。因此,我们首先合成了一种由离子液体基团([AMIm][N(CFSO)])修饰并由多金属原子(Zn、Cu 和 Fe)掺杂的表面和内核双设计碳点(Zn、Cu、Fe-CDs),并创造性地将其用作 PEG200 基础油的纳米添加剂。添加 1.0 wt% 的 Zn、Cu、Fe-CD 可使 PEG200 基础油具有最佳的减摩、抗磨和承载性能,最大增大幅度分别约为 46.6 %、66.3 % 和 125.0 %。此外,Zn、Cu、Fe-CDs 的摩擦学性能即使在高负荷和长时间工作条件下也不会减弱,具有良好的实用性和应用前景。理论和实验研究表明,Zn,Cu,Fe-CDs 的优异摩擦学性能归因于成膜效应和纳米润滑效应的协同作用。
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引用次数: 0
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