首页 > 最新文献

Composites Science and Technology最新文献

英文 中文
Water-based PES-NaPSS sizing agent without surfactant for interface enhancement of CF/PEEK composites 用于增强 CF/PEEK 复合材料界面的不含表面活性剂的水基 PES-NaPSS 施胶剂
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-10-01 DOI: 10.1016/j.compscitech.2024.110892
Kaixuan Lei , Wenzhen Qin , Shulin Bai , Jianfan Cao , Liang Chen
Improving the weak interfacial bonding of carbon fiber (CF)/polyetheretherketone (PEEK) composites is an extremely urgent need. Addressing this issue, sizing modification on CF surfaces is a conventional and effective method. In this work, polyethersulfone-polystyrene sulfonate sodium (PES-NaPSS) was successfully synthesized by UV illumination. A novel surfactant-free aqueous PES-NaPSS sizing agent was prepared by emulsion/solvent evaporation method to regulate the interface of CF/PEEK composites. From the XPS and SEM results, it can be seen that PES-NaPSS was uniformly coated on the CF surfaces, which introduced the reactive groups on the CF surfaces. The PES-NaPSS sizing agent exhibits good thermal performance and storage stability, meeting the needs for high temperature processing of CF/PEEK composites. Compared with the unsized CF/PEEK composites, the ILSS, flexural strength and modulus of the 0.9 wt% PES-NaPSS modified CF/PEEK composite are improved by 32.8 %, 40.3 % and 37.4 %, respectively. Accordingly, the mechanisms of the interface improvement are physical riveting, chain entanglement, chemical and physical interactions between the PES-NaPSS and PEEK matrix. This green and effective method of interface improvement will supply a prerequisite for the extensive application of CF/PEEK composites.
改善碳纤维(CF)/聚醚醚酮(PEEK)复合材料的弱界面结合是一项极为迫切的需求。为解决这一问题,对 CF 表面进行施胶改性是一种传统而有效的方法。在这项工作中,通过紫外线照射成功合成了聚醚砜-聚苯乙烯磺酸钠(PES-NaPSS)。利用乳液/溶剂蒸发法制备了一种新型的无表面活性剂水性 PES-NaPSS 施胶剂,用于调节 CF/PEEK 复合材料的界面。从 XPS 和 SEM 结果可以看出,PES-NaPSS 均匀地涂覆在 CF 表面,在 CF 表面引入了活性基团。PES-NaPSS 施胶剂具有良好的热性能和储存稳定性,可满足 CF/PEEK 复合材料高温加工的需要。与未施胶的 CF/PEEK 复合材料相比,0.9 wt% PES-NaPSS 改性 CF/PEEK 复合材料的 ILSS、弯曲强度和模量分别提高了 32.8%、40.3% 和 37.4%。因此,界面改善的机理是 PES-NaPSS 与 PEEK 基体之间的物理铆接、链缠结、化学和物理相互作用。这种绿色、有效的界面改善方法将为 CF/PEEK 复合材料的广泛应用提供先决条件。
{"title":"Water-based PES-NaPSS sizing agent without surfactant for interface enhancement of CF/PEEK composites","authors":"Kaixuan Lei ,&nbsp;Wenzhen Qin ,&nbsp;Shulin Bai ,&nbsp;Jianfan Cao ,&nbsp;Liang Chen","doi":"10.1016/j.compscitech.2024.110892","DOIUrl":"10.1016/j.compscitech.2024.110892","url":null,"abstract":"<div><div>Improving the weak interfacial bonding of carbon fiber (CF)/polyetheretherketone (PEEK) composites is an extremely urgent need. Addressing this issue, sizing modification on CF surfaces is a conventional and effective method. In this work, polyethersulfone-polystyrene sulfonate sodium (PES-NaPSS) was successfully synthesized by UV illumination. A novel surfactant-free aqueous PES-NaPSS sizing agent was prepared by emulsion/solvent evaporation method to regulate the interface of CF/PEEK composites. From the XPS and SEM results, it can be seen that PES-NaPSS was uniformly coated on the CF surfaces, which introduced the reactive groups on the CF surfaces. The PES-NaPSS sizing agent exhibits good thermal performance and storage stability, meeting the needs for high temperature processing of CF/PEEK composites. Compared with the unsized CF/PEEK composites, the ILSS, flexural strength and modulus of the 0.9 wt% PES-NaPSS modified CF/PEEK composite are improved by 32.8 %, 40.3 % and 37.4 %, respectively. Accordingly, the mechanisms of the interface improvement are physical riveting, chain entanglement, chemical and physical interactions between the PES-NaPSS and PEEK matrix. This green and effective method of interface improvement will supply a prerequisite for the extensive application of CF/PEEK composites.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110892"},"PeriodicalIF":8.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142418003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molecular dynamics simulations of thermomechanical properties of silicone-modified phenolic polymer 硅改性酚醛聚合物热力学特性的分子动力学模拟
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-30 DOI: 10.1016/j.compscitech.2024.110878
Jie Xiao, Guodong Fang, Bing Wang, Changqing Hong, Songhe Meng
The silicone-phenolic multicomponent polymers are typically employed as the matrix of fiber-reinforced nanocomposites developed for reentry vehicles due to their excellent thermal and mechanical properties. The thermomechanical properties of the silicone-phenolic multicomponent polymer system, which are greatly related to the processing and microstructures, were studied using molecular dynamics (MD) simulations combined with experiments. A multistep dynamic polymerization approach was utilized to form the crosslinked polymer model, which was also validated in terms of both microstructures and properties. The thermomechanical properties of the crosslinked polymer system were established as a function of crosslinking degree, component ratio, temperature, strain rate, and cooling rate, and the influence mechanisms of the processing parameters were revealed. The crosslinking degree can greatly influence the glass transition temperature and volumetric coefficient of thermal expansion, which is attributed to the constrained chain mobility. The crosslinking degree and the component ratio have a significant effect on the morphologies and vibrational density of states of the polymer system, respectively, which in turn affects the thermal conductivity. The failure mode during uniaxial tensile was investigated in terms of the atomic energy distribution through MD simulations. The elastic and plastic deformation stages are dominated by intermolecular non-bonding interactions, but less contributed by the bonding interactions. This work can guide the design of polymeric nanocomposites by establishing the relationship of processing-microstructure-thermomechanical properties.
有机硅-酚醛多组分聚合物因其优异的热性能和机械性能,通常被用作为重返大气层飞行器开发的纤维增强纳米复合材料的基体。分子动力学(MD)模拟与实验相结合,研究了有机硅-酚醛多组分聚合物体系的热机械性能,这些性能与加工过程和微观结构密切相关。利用多步动态聚合方法形成了交联聚合物模型,并从微观结构和性能两方面对该模型进行了验证。建立了交联聚合物体系的热力学性质与交联度、组分比例、温度、应变速率和冷却速率的函数关系,并揭示了加工参数的影响机制。交联度会对玻璃化温度和体积热膨胀系数产生很大影响,这归因于受约束的链流动性。交联度和组分比分别对聚合物体系的形态和振动态密度有显著影响,进而影响热导率。通过 MD 模拟,从原子能量分布的角度研究了单轴拉伸过程中的破坏模式。在弹性和塑性变形阶段,分子间的非键相互作用占主导地位,而键相互作用的贡献较小。这项研究通过建立加工-微结构-热机械性能之间的关系,为聚合物纳米复合材料的设计提供了指导。
{"title":"Molecular dynamics simulations of thermomechanical properties of silicone-modified phenolic polymer","authors":"Jie Xiao,&nbsp;Guodong Fang,&nbsp;Bing Wang,&nbsp;Changqing Hong,&nbsp;Songhe Meng","doi":"10.1016/j.compscitech.2024.110878","DOIUrl":"10.1016/j.compscitech.2024.110878","url":null,"abstract":"<div><div>The silicone-phenolic multicomponent polymers are typically employed as the matrix of fiber-reinforced nanocomposites developed for reentry vehicles due to their excellent thermal and mechanical properties. The thermomechanical properties of the silicone-phenolic multicomponent polymer system, which are greatly related to the processing and microstructures, were studied using molecular dynamics (MD) simulations combined with experiments. A multistep dynamic polymerization approach was utilized to form the crosslinked polymer model, which was also validated in terms of both microstructures and properties. The thermomechanical properties of the crosslinked polymer system were established as a function of crosslinking degree, component ratio, temperature, strain rate, and cooling rate, and the influence mechanisms of the processing parameters were revealed. The crosslinking degree can greatly influence the glass transition temperature and volumetric coefficient of thermal expansion, which is attributed to the constrained chain mobility. The crosslinking degree and the component ratio have a significant effect on the morphologies and vibrational density of states of the polymer system, respectively, which in turn affects the thermal conductivity. The failure mode during uniaxial tensile was investigated in terms of the atomic energy distribution through MD simulations. The elastic and plastic deformation stages are dominated by intermolecular non-bonding interactions, but less contributed by the bonding interactions. This work can guide the design of polymeric nanocomposites by establishing the relationship of processing-microstructure-thermomechanical properties.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110878"},"PeriodicalIF":8.3,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142417678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication and in-plane compressive collapse of CFRP honeycomb metamaterials CFRP 蜂窝超材料的制作和平面内压缩塌陷
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-30 DOI: 10.1016/j.compscitech.2024.110888
Zhipeng Wang , Jianfeng Li , Wei Zhang , Jinze Jiao , Yuan Yuan , Qinghua Qin
A pin-slot positioning method was proposed to fabricate carbon fiber reinforced polymer (CFRP) metamaterials of hexagonal and zero Poisson's ratio semi-re-entrant honeycombs with the same mass of monolayer continuous twill-woven carbon fiber/epoxy prepregs. The in-plane compressive collapse of CFRP honeycombs was explored through experiments and finite element (FE) simulations. Furthermore, analytical models were developed to predict the modulus and initial collapse stress of the hexagonal and semi-re-entrant honeycombs. Good agreement is achieved between analytical predictions, FE simulations and experimental results. It is shown that the initial collapse of CFRP honeycombs is by the bending of cell walls. Once initial collapse has been attained, both hexagonal and semi-re-entrant honeycombs have a stress softening. The collapse and failure modes of CFRP honeycombs strongly depend on cellular configurations and loading directions.
研究人员提出了一种针槽定位方法,利用相同质量的单层连续斜纹编织碳纤维/环氧树脂预浸料,制造出六边形和零泊松比半重向蜂窝的碳纤维增强聚合物(CFRP)超材料。通过实验和有限元(FE)模拟探讨了 CFRP 蜂窝的面内压缩塌陷。此外,还建立了分析模型来预测六角形和半重向蜂窝的模量和初始塌陷应力。分析预测、有限元模拟和实验结果之间取得了良好的一致性。研究表明,CFRP 蜂窝的初始坍塌是由蜂窝壁的弯曲造成的。一旦达到初始坍塌,六角形和半内凹蜂窝都会出现应力软化。CFRP 蜂窝的坍塌和破坏模式在很大程度上取决于蜂窝结构和加载方向。
{"title":"Fabrication and in-plane compressive collapse of CFRP honeycomb metamaterials","authors":"Zhipeng Wang ,&nbsp;Jianfeng Li ,&nbsp;Wei Zhang ,&nbsp;Jinze Jiao ,&nbsp;Yuan Yuan ,&nbsp;Qinghua Qin","doi":"10.1016/j.compscitech.2024.110888","DOIUrl":"10.1016/j.compscitech.2024.110888","url":null,"abstract":"<div><div>A pin-slot positioning method was proposed to fabricate carbon fiber reinforced polymer (CFRP) metamaterials of hexagonal and zero Poisson's ratio semi-re-entrant honeycombs with the same mass of monolayer continuous twill-woven carbon fiber/epoxy prepregs. The in-plane compressive collapse of CFRP honeycombs was explored through experiments and finite element (FE) simulations. Furthermore, analytical models were developed to predict the modulus and initial collapse stress of the hexagonal and semi-re-entrant honeycombs. Good agreement is achieved between analytical predictions, FE simulations and experimental results. It is shown that the initial collapse of CFRP honeycombs is by the bending of cell walls. Once initial collapse has been attained, both hexagonal and semi-re-entrant honeycombs have a stress softening. The collapse and failure modes of CFRP honeycombs strongly depend on cellular configurations and loading directions.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110888"},"PeriodicalIF":8.3,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142529886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hygroscopic and hydrothermal aging behaviors and performance deterioration mechanisms of jute yarn wound composites 黄麻纱缠绕复合材料的吸湿和水热老化行为及性能劣化机理
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-30 DOI: 10.1016/j.compscitech.2024.110891
Jiangjing Shi , Tianhao Shen , Wenfu Zhang , Hong Chen , Changlei Xia
The gyratory jute yarn wound composites (JYWCs) manufactured by the filament winding process show significant potential as eco-friendly alternatives to plastic pipes commonly used in outdoor settings. Ensuring the long-term service performance and durability of the JYWCs in hot and humid environments becomes critical. This study investigated the hygroscopic and hydrothermal aging behaviors of the JYWCs to elucidate their performance deterioration mechanisms. Compared with hygroscopic aging, long-term hydrothermal aging posed a more serious threat to the overall performance of the JYWCs. The jute yarns in the JYWCs experienced swelling, shrinkage, and degradation due to hygroscopic and hydrothermal aging, leading to a 47.4 % and 161.5 % increase in the void volume fraction of the JYWCs, respectively. The deterioration in the mechanical properties of the JYWCs was attributed to the attenuation of jute yarn properties, debonding of the fiber-resin matrix interface, and an increase in voids within the composites. Improving the manufacturing process to minimize voids in the JYWCs and control the pathways for moisture absorption is a highly effective strategy to enhance their long-term performance and durability.
通过长丝缠绕工艺制造的回旋黄麻纱缠绕复合材料(JYWC)作为户外常用塑料管道的环保替代品,显示出巨大的潜力。确保 JYWCs 在高温潮湿环境中的长期使用性能和耐用性变得至关重要。本研究调查了 JYWC 的吸湿老化和水热老化行为,以阐明其性能劣化机制。与吸湿老化相比,长期水热老化对 JYWC 的整体性能构成了更严重的威胁。由于吸湿老化和水热老化,JYWC 中的黄麻纱经历了膨胀、收缩和降解,导致 JYWC 的空隙体积分数分别增加了 47.4% 和 161.5%。JYWCs 机械性能的下降归因于黄麻纱性能的衰减、纤维-树脂基体界面的脱粘以及复合材料内部空隙的增加。改进生产工艺以尽量减少 JYWCs 中的空隙并控制吸湿途径,是提高其长期性能和耐用性的一项非常有效的策略。
{"title":"Hygroscopic and hydrothermal aging behaviors and performance deterioration mechanisms of jute yarn wound composites","authors":"Jiangjing Shi ,&nbsp;Tianhao Shen ,&nbsp;Wenfu Zhang ,&nbsp;Hong Chen ,&nbsp;Changlei Xia","doi":"10.1016/j.compscitech.2024.110891","DOIUrl":"10.1016/j.compscitech.2024.110891","url":null,"abstract":"<div><div>The gyratory jute yarn wound composites (JYWCs) manufactured by the filament winding process show significant potential as eco-friendly alternatives to plastic pipes commonly used in outdoor settings. Ensuring the long-term service performance and durability of the JYWCs in hot and humid environments becomes critical. This study investigated the hygroscopic and hydrothermal aging behaviors of the JYWCs to elucidate their performance deterioration mechanisms. Compared with hygroscopic aging, long-term hydrothermal aging posed a more serious threat to the overall performance of the JYWCs. The jute yarns in the JYWCs experienced swelling, shrinkage, and degradation due to hygroscopic and hydrothermal aging, leading to a 47.4 % and 161.5 % increase in the void volume fraction of the JYWCs, respectively. The deterioration in the mechanical properties of the JYWCs was attributed to the attenuation of jute yarn properties, debonding of the fiber-resin matrix interface, and an increase in voids within the composites. Improving the manufacturing process to minimize voids in the JYWCs and control the pathways for moisture absorption is a highly effective strategy to enhance their long-term performance and durability.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110891"},"PeriodicalIF":8.3,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142417679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Atomic force microscopy-based nanoindentation technique for characterizing the transverse and shear moduli of flax fibers 基于原子力显微镜的纳米压痕技术表征亚麻纤维的横向和剪切模量
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-30 DOI: 10.1016/j.compscitech.2024.110890
P.V. Divakarraju , V. Pandurangan , M. Nithyadharan
Experimentally evaluating the elastic properties of flax fibers is challenging due to their complex hierarchical structure, and a standard test procedure for measuring their transverse and shear moduli is currently not reported in the literature. Hence, this study presents an atomic force microscopy (AFM) based nanoindentation technique to evaluate the transverse and shear moduli of flax fiber. A high-precision focused ion beam (FIB)-milling process was used to fabricate a flat surface for indentation along the longitudinal fiber cross-section of the fiber and transverse fiber cross-section by polishing the unidirectional (UD) lamina in order to evaluate the indentation modulus. Further, Swanson's numerical contour approach was adopted to evaluate the elastic properties of the fiber from the measured indentation modulus. The accuracy of the experimentally obtained fiber properties is verified by using it in a micromechanics model for predicting the elastic properties of the UD lamina and comparing it with experimental results reported in the literature.
由于亚麻纤维具有复杂的层次结构,因此对其弹性特性进行实验评估具有挑战性,目前文献中还没有关于测量其横向和剪切模量的标准测试程序的报道。因此,本研究提出了一种基于原子力显微镜(AFM)的纳米压痕技术来评估亚麻纤维的横向和剪切模量。采用高精度聚焦离子束(FIB)铣削工艺,沿着纤维的纵向纤维横截面和横向纤维横截面,通过抛光单向(UD)薄片,制造出用于压痕的平面,以评估压痕模量。此外,还采用了斯旺森数值轮廓方法,根据测得的压痕模量评估纤维的弹性特性。通过在微观力学模型中使用实验获得的纤维特性来预测 UD 薄片的弹性特性,并将其与文献中报道的实验结果进行比较,从而验证了实验获得的纤维特性的准确性。
{"title":"Atomic force microscopy-based nanoindentation technique for characterizing the transverse and shear moduli of flax fibers","authors":"P.V. Divakarraju ,&nbsp;V. Pandurangan ,&nbsp;M. Nithyadharan","doi":"10.1016/j.compscitech.2024.110890","DOIUrl":"10.1016/j.compscitech.2024.110890","url":null,"abstract":"<div><div>Experimentally evaluating the elastic properties of flax fibers is challenging due to their complex hierarchical structure, and a standard test procedure for measuring their transverse and shear moduli is currently not reported in the literature. Hence, this study presents an atomic force microscopy (AFM) based nanoindentation technique to evaluate the transverse and shear moduli of flax fiber. A high-precision focused ion beam (FIB)-milling process was used to fabricate a flat surface for indentation along the longitudinal fiber cross-section of the fiber and transverse fiber cross-section by polishing the unidirectional (UD) lamina in order to evaluate the indentation modulus. Further, Swanson's numerical contour approach was adopted to evaluate the elastic properties of the fiber from the measured indentation modulus. The accuracy of the experimentally obtained fiber properties is verified by using it in a micromechanics model for predicting the elastic properties of the UD lamina and comparing it with experimental results reported in the literature.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110890"},"PeriodicalIF":8.3,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142417754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aspect ratio-dependent volume resistivity in unidirectional composites: Insights from electrical conduction behavior 单向复合材料中与长宽比相关的体积电阻率:从电传导行为中获得的启示
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-28 DOI: 10.1016/j.compscitech.2024.110887
Gen Li, Tianwei Wu, Junjie Zhang, Frew Asamnewu Fikru, Baozhong Sun, Bohong Gu
The electrical properties of carbon fibers serve as the foundation for the multifunctional applications of carbon fiber-reinforced composite structures. In scenarios that exploit the electrical characteristics of materials, accurate estimation of electrical resistivity stands as a critical factor. This study endeavors to elucidate the electrical conduction behaviors in unidirectional composites with different fiber orientation angles (0°, 15°, 30°, 45°, 60°, 75°, and 90°) and aspect ratios, thereby deriving the volume resistivity within an arbitrary Cartesian coordinate system. Employing thermal infrared imaging technology and finite element analysis, we identified distinctive electrical conduction behaviors associated with aspect ratios in carbon fiber composite plates. Notably, a critical aspect ratio exists wherein the diagonal yarn is the only conductive path between two electrodes. Below this critical threshold, no direct conductive path exists, and current flows through the shortest distance between parallel yarns. Conversely, beyond the critical aspect ratio value, multiple yarns form conductive paths between the two electrodes. Based on the electrical conduction behavior of unidirectional composites under different angles and aspect ratios, the volume resistivity with finite boundaries was derived and examined under an arbitrary Cartesian coordinate basis.
碳纤维的电特性是碳纤维增强复合材料结构多功能应用的基础。在利用材料电气特性的应用场景中,准确估算电阻率是一个关键因素。本研究致力于阐明不同纤维取向角(0°、15°、30°、45°、60°、75°和 90°)和长宽比的单向复合材料的导电行为,从而推导出任意直角坐标系中的体积电阻率。利用热红外成像技术和有限元分析,我们确定了碳纤维复合板中与纵横比相关的独特电导行为。值得注意的是,在对角线纱线是两个电极之间唯一导电路径的情况下,存在一个临界纵横比。在此临界值以下,不存在直接导电路径,电流流经平行纱线之间的最短距离。相反,超过临界纵横比值时,多根纱线会在两个电极之间形成导电路径。根据单向复合材料在不同角度和纵横比下的导电行为,推导出了有限边界的体积电阻率,并在任意笛卡尔坐标基础上对其进行了研究。
{"title":"Aspect ratio-dependent volume resistivity in unidirectional composites: Insights from electrical conduction behavior","authors":"Gen Li,&nbsp;Tianwei Wu,&nbsp;Junjie Zhang,&nbsp;Frew Asamnewu Fikru,&nbsp;Baozhong Sun,&nbsp;Bohong Gu","doi":"10.1016/j.compscitech.2024.110887","DOIUrl":"10.1016/j.compscitech.2024.110887","url":null,"abstract":"<div><div>The electrical properties of carbon fibers serve as the foundation for the multifunctional applications of carbon fiber-reinforced composite structures. In scenarios that exploit the electrical characteristics of materials, accurate estimation of electrical resistivity stands as a critical factor. This study endeavors to elucidate the electrical conduction behaviors in unidirectional composites with different fiber orientation angles (0°, 15°, 30°, 45°, 60°, 75°, and 90°) and aspect ratios, thereby deriving the volume resistivity within an arbitrary Cartesian coordinate system. Employing thermal infrared imaging technology and finite element analysis, we identified distinctive electrical conduction behaviors associated with aspect ratios in carbon fiber composite plates. Notably, a critical aspect ratio exists wherein the diagonal yarn is the only conductive path between two electrodes. Below this critical threshold, no direct conductive path exists, and current flows through the shortest distance between parallel yarns. Conversely, beyond the critical aspect ratio value, multiple yarns form conductive paths between the two electrodes. Based on the electrical conduction behavior of unidirectional composites under different angles and aspect ratios, the volume resistivity with finite boundaries was derived and examined under an arbitrary Cartesian coordinate basis.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110887"},"PeriodicalIF":8.3,"publicationDate":"2024-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142417755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D printing enhanced piezoelectricity of MXene/P(VDF-TrFE) composites for energy harvesting and force sensing 三维打印增强 MXene/P(VDF-TrFE)复合材料的压电性,用于能量采集和力传感
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-27 DOI: 10.1016/j.compscitech.2024.110881
Ceng Li , Ziyue Huang , Liang Zhang , Zifei Song , Ying Chen , Xiangwu Chang , Penghao Hu
In pursuit of advanced self-powered wearable devices, piezoelectric materials have aroused great attention due to their stable energy harvesting ability from surroundings. However, traditional piezoelectric polymer-based nanogenerators necessitate a high-energy process to align the dipoles of the polymer, which is cumbersome, expensive, and could even lead to material deterioration. To address this challenge, we present a composite strategy with self-poling capability enabled by the extrusion-based 3D printing. MXene nanosheets were introduced into the fluoropolymer poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE) to provide strong hydrogen bonding as anchors. Under the shear stress generated by the extrusion process, the alignment of the dipoles was realized without additional treatment. The resulting piezoelectric nanogenerator exhibits an open-circuit voltage of 5.5 V, a short-circuit current of 1.1 μA, and the output power density of 68 μWcm−3 under the force of 22 N and a frequency of 2 Hz. A self-powered sensor was assembled and demonstrated high sensitivity for human motions and facial expressions. Moreover, the 3D-printed piezoelectric composites present good flexibility, which is a crucial property for wearable devices. With the free design capabilities of the 3D printing technology, this strategy may pave the way for customized and feasible processing of high-performance piezoelectric nanogenerators and force sensors.
在追求先进的自供电可穿戴设备的过程中,压电材料因其能够稳定地从周围环境中收集能量而备受关注。然而,传统的基于压电聚合物的纳米发电机必须采用高能量工艺来调整聚合物的偶极子,这种工艺既麻烦又昂贵,甚至会导致材料老化。为了应对这一挑战,我们提出了一种复合策略,通过基于挤压的三维打印技术实现自校正能力。我们在氟聚合物聚偏二氟乙烯-共三氟乙烯(PVDF-TrFE)中引入了 MXene 纳米片,以提供强大的氢键作为锚。在挤压过程产生的剪切应力作用下,无需额外处理即可实现偶极子的排列。由此产生的压电纳米发电机在 22 N 的力和 2 Hz 的频率下,开路电压为 5.5 V,短路电流为 1.1 μA,输出功率密度为 68 μWcm-3。自供电传感器已组装完成,对人体运动和面部表情具有高灵敏度。此外,三维打印压电复合材料具有良好的柔韧性,这对于可穿戴设备来说是至关重要的特性。借助三维打印技术的自由设计能力,这一策略可为定制和加工高性能压电纳米发电机和力传感器铺平道路。
{"title":"3D printing enhanced piezoelectricity of MXene/P(VDF-TrFE) composites for energy harvesting and force sensing","authors":"Ceng Li ,&nbsp;Ziyue Huang ,&nbsp;Liang Zhang ,&nbsp;Zifei Song ,&nbsp;Ying Chen ,&nbsp;Xiangwu Chang ,&nbsp;Penghao Hu","doi":"10.1016/j.compscitech.2024.110881","DOIUrl":"10.1016/j.compscitech.2024.110881","url":null,"abstract":"<div><div>In pursuit of advanced self-powered wearable devices, piezoelectric materials have aroused great attention due to their stable energy harvesting ability from surroundings. However, traditional piezoelectric polymer-based nanogenerators necessitate a high-energy process to align the dipoles of the polymer, which is cumbersome, expensive, and could even lead to material deterioration. To address this challenge, we present a composite strategy with self-poling capability enabled by the extrusion-based 3D printing. MXene nanosheets were introduced into the fluoropolymer poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE) to provide strong hydrogen bonding as anchors. Under the shear stress generated by the extrusion process, the alignment of the dipoles was realized without additional treatment. The resulting piezoelectric nanogenerator exhibits an open-circuit voltage of 5.5 V, a short-circuit current of 1.1 μA, and the output power density of 68 μWcm<sup>−3</sup> under the force of 22 N and a frequency of 2 Hz. A self-powered sensor was assembled and demonstrated high sensitivity for human motions and facial expressions. Moreover, the 3D-printed piezoelectric composites present good flexibility, which is a crucial property for wearable devices. With the free design capabilities of the 3D printing technology, this strategy may pave the way for customized and feasible processing of high-performance piezoelectric nanogenerators and force sensors.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110881"},"PeriodicalIF":8.3,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142356989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
“Reinforced concrete” design of robust mineralized cellulose composite with multilayered structure for efficient CO2 capture and passive radiative cooling ability 具有多层结构的坚固矿化纤维素复合材料的 "钢筋混凝土 "设计,可有效捕获二氧化碳并具有被动辐射冷却能力
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-27 DOI: 10.1016/j.compscitech.2024.110886
Chengling Huang, Hou-Yong Yu, Guozhuo Chen, Yiqi Liao
The construction industry promotes the economic development of the country by addressing society's housing needs. However, the industry's energy consumption and carbon dioxide (CO2) emissions are the primary contributors to global warming. Traditional building materials are no longer capable of meeting the requirements of sustainable development, while natural cellulose can be used as a new type of carbon capture construction material. Inspired by the “reinforced concrete” methodology, a mineralized cellulose composite (ML-CCM) was fabricated through a strategy of vacuum filling and in-situ mineralization, resulting in a composite with a multi-level structure (a natural microporous 3D scaffold loofah as “rebar” and cellulose filler as “cement” are staggered in the composite). The resultant ML-CCM1 exhibited a significantly high flexural strain (approximately 215.9 % of that of cellulose composite without loofah) because of the 3D scaffold loofah acting as a “rebar”. Furthermore, the composite possesses flame retardancy, superior thermal insulation at 90 °C, and passive radiative cooling performance due to the micro-nano ZnO particle in the “cement”. Moreover, the multi-level structure, consisting of pores and micro-nano particles, enables it to effectively adsorb CO2 and environment tobacco smoke. As a result, lifecycle assessments underscore the composite's low Global Warming Potential. Therefore, this work reports a promising 3D bio-based composite with CO2 capture for energy conservation and carbon reduction in the construction industry.
建筑业通过满足社会的住房需求促进了国家的经济发展。然而,该行业的能源消耗和二氧化碳(CO2)排放是导致全球变暖的主要因素。传统的建筑材料已无法满足可持续发展的要求,而天然纤维素可以作为一种新型的碳捕获建筑材料。受 "钢筋混凝土 "方法的启发,通过真空填充和原位矿化的策略,制造出了矿化纤维素复合材料(ML-CCM),形成了多层次结构的复合材料(天然微孔三维支架丝瓜络作为 "钢筋",纤维素填料作为 "水泥",在复合材料中交错排列)。由于三维支架丝瓜络起到了 "螺纹钢 "的作用,因此制成的 ML-CCM1 显示出明显较高的挠曲应变(约为不含丝瓜络的纤维素复合材料的 215.9%)。此外,由于 "水泥 "中含有微纳米 ZnO 颗粒,该复合材料还具有阻燃性能,在 90 ℃ 下具有优异的隔热性能和被动辐射冷却性能。此外,由孔隙和微纳米颗粒组成的多层次结构使其能够有效吸附二氧化碳和烟草烟雾。因此,生命周期评估结果表明,这种复合材料的全球变暖潜能值较低。因此,这项工作报告了一种具有二氧化碳捕获功能的三维生物基复合材料,在建筑行业节能减碳方面大有可为。
{"title":"“Reinforced concrete” design of robust mineralized cellulose composite with multilayered structure for efficient CO2 capture and passive radiative cooling ability","authors":"Chengling Huang,&nbsp;Hou-Yong Yu,&nbsp;Guozhuo Chen,&nbsp;Yiqi Liao","doi":"10.1016/j.compscitech.2024.110886","DOIUrl":"10.1016/j.compscitech.2024.110886","url":null,"abstract":"<div><div>The construction industry promotes the economic development of the country by addressing society's housing needs. However, the industry's energy consumption and carbon dioxide (CO<sub>2</sub>) emissions are the primary contributors to global warming. Traditional building materials are no longer capable of meeting the requirements of sustainable development, while natural cellulose can be used as a new type of carbon capture construction material. Inspired by the “reinforced concrete” methodology, a mineralized cellulose composite (ML-CCM) was fabricated through a strategy of vacuum filling and in-situ mineralization, resulting in a composite with a multi-level structure (a natural microporous 3D scaffold loofah as “rebar” and cellulose filler as “cement” are staggered in the composite). The resultant ML-CCM1 exhibited a significantly high flexural strain (approximately 215.9 % of that of cellulose composite without loofah) because of the 3D scaffold loofah acting as a “rebar”. Furthermore, the composite possesses flame retardancy, superior thermal insulation at 90 °C, and passive radiative cooling performance due to the micro-nano ZnO particle in the “cement”. Moreover, the multi-level structure, consisting of pores and micro-nano particles, enables it to effectively adsorb CO<sub>2</sub> and environment tobacco smoke. As a result, lifecycle assessments underscore the composite's low Global Warming Potential. Therefore, this work reports a promising 3D bio-based composite with CO<sub>2</sub> capture for energy conservation and carbon reduction in the construction industry.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110886"},"PeriodicalIF":8.3,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142328110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improving the ablation performance of largely deformed silicone rubber-based composites under coupled mechanical-thermal-oxidative conditions by implementing deformable carbon fiber fabrics 在机械-热氧化耦合条件下,通过采用可变形碳纤维织物提高大变形硅橡胶基复合材料的烧蚀性能
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-25 DOI: 10.1016/j.compscitech.2024.110876
Zhaohui Lu, Shengtai Zhou, Liwei Yan, Yue Tian, Huawei Zou, Xiancheng Ren
Silicone rubber-based composites are used as thermal protection materials due to their large deformability and excellent thermal insulation properties. In this study, two types of commercially available silicone rubbers were selected as the matrices for preparing flexible thermal protection materials. The influence of applied strain rates on the microstructure, ablation and ceramifiable behavior of silicone rubbers was studied. The research showed that the ablation performance of silicone rubbers deteriorated greatly at large strain rates. The reinforcement using deformable carbon fiber fabrics was proposed to effectively counter the deterioration of the ablative properties incurred by applying external strain. The back-face temperature reached as low as 186 °C when the samples were ablated at above 1000 °C for 50s at a strain rate of 20 %. The proposed strategy was proved helpful in developing high performance flexible thermal protection systems that exhibit promising application in the fields of aerospace and fire protection among others.
硅橡胶基复合材料具有较大的变形能力和优异的隔热性能,因此被用作热保护材料。本研究选择了两种市售硅橡胶作为制备柔性热防护材料的基体。研究了施加应变速率对硅橡胶微观结构、烧蚀和可陶瓷化行为的影响。研究表明,硅橡胶的烧蚀性能在大应变速率下会大大降低。研究人员提出了使用可变形碳纤维织物进行加固的方法,以有效解决施加外部应变导致的烧蚀性能恶化问题。当样品在应变率为 20% 的条件下于 1000°C 以上的温度下烧蚀 50 秒时,其背面温度低至 186°C。事实证明,所提出的策略有助于开发高性能柔性热保护系统,该系统在航空航天和防火等领域的应用前景广阔。
{"title":"Improving the ablation performance of largely deformed silicone rubber-based composites under coupled mechanical-thermal-oxidative conditions by implementing deformable carbon fiber fabrics","authors":"Zhaohui Lu,&nbsp;Shengtai Zhou,&nbsp;Liwei Yan,&nbsp;Yue Tian,&nbsp;Huawei Zou,&nbsp;Xiancheng Ren","doi":"10.1016/j.compscitech.2024.110876","DOIUrl":"10.1016/j.compscitech.2024.110876","url":null,"abstract":"<div><div>Silicone rubber-based composites are used as thermal protection materials due to their large deformability and excellent thermal insulation properties. In this study, two types of commercially available silicone rubbers were selected as the matrices for preparing flexible thermal protection materials. The influence of applied strain rates on the microstructure, ablation and ceramifiable behavior of silicone rubbers was studied. The research showed that the ablation performance of silicone rubbers deteriorated greatly at large strain rates. The reinforcement using deformable carbon fiber fabrics was proposed to effectively counter the deterioration of the ablative properties incurred by applying external strain. The back-face temperature reached as low as 186 °C when the samples were ablated at above 1000 °C for 50s at a strain rate of 20 %. The proposed strategy was proved helpful in developing high performance flexible thermal protection systems that exhibit promising application in the fields of aerospace and fire protection among others.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110876"},"PeriodicalIF":8.3,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142417680","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A hyperelastic model considering the coupling of shear-compression for the forming simulation of 3D orthogonal composite preforms 考虑到剪切-压缩耦合的超弹性模型,用于三维正交复合预成型件的成型模拟
IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-09-24 DOI: 10.1016/j.compscitech.2024.110884
Xu Zhang , Sheng Zhang , Huajun Zhang , Chenyang Liu , Yue Zhou , Chengqian Dong , Xiguang Gao , Fang Wang , Yingdong Song
The shear-compression coupling phenomenon is vital in the forming process of complex 3D woven composite components, but has not been effectively considered in existing macroscopic material models. A hyperelastic material model considering shear-compression coupling is developed here. Firstly, in-plane shear tests on pre-compressed specimens and compression tests on pre-sheared specimens were carried out, respectively. The results show that pre-compression can hinder and promote the in-plane shear deformation before and after shear locking occurs in the fabric, respectively. In-plane shear can contribute to compression. Then, a nonlinear hyperelastic constitutive model is presented and implemented in an Abaqus/Explicit user subroutine. Finally, a simulation study of the hemispherical forming of 3D orthogonal woven fabric was conducted using this model. The simulation results considering shear-compression coupling show more accurate in-plane shear angles and edge shapes compared to those without considering coupling. Moreover, since the shear-compression coupling is considered, the friction between the fabric and the tool needs to be reasonably discussed in the moulding simulation.
剪切-压缩耦合现象在复杂的三维编织复合材料部件的成型过程中至关重要,但现有的宏观材料模型并未有效考虑这一现象。本文建立了一个考虑剪切-压缩耦合的超弹性材料模型。首先,分别对预压缩试样进行了平面内剪切试验,对预剪切试样进行了压缩试验。结果表明,在织物发生剪切锁定之前和之后,预压缩分别会阻碍和促进面内剪切变形。面内剪切可促进压缩。然后,介绍了一种非线性超弹性结构模型,并在 Abaqus/Explicit 用户子程序中实现了该模型。最后,使用该模型对三维正交编织物的半球成型进行了仿真研究。与未考虑耦合的仿真结果相比,考虑了剪切-压缩耦合的仿真结果显示了更精确的平面内剪切角和边缘形状。此外,由于考虑了剪切-压缩耦合,因此在成型模拟中需要合理讨论织物与工具之间的摩擦。
{"title":"A hyperelastic model considering the coupling of shear-compression for the forming simulation of 3D orthogonal composite preforms","authors":"Xu Zhang ,&nbsp;Sheng Zhang ,&nbsp;Huajun Zhang ,&nbsp;Chenyang Liu ,&nbsp;Yue Zhou ,&nbsp;Chengqian Dong ,&nbsp;Xiguang Gao ,&nbsp;Fang Wang ,&nbsp;Yingdong Song","doi":"10.1016/j.compscitech.2024.110884","DOIUrl":"10.1016/j.compscitech.2024.110884","url":null,"abstract":"<div><div>The shear-compression coupling phenomenon is vital in the forming process of complex 3D woven composite components, but has not been effectively considered in existing macroscopic material models. A hyperelastic material model considering shear-compression coupling is developed here. Firstly, in-plane shear tests on pre-compressed specimens and compression tests on pre-sheared specimens were carried out, respectively. The results show that pre-compression can hinder and promote the in-plane shear deformation before and after shear locking occurs in the fabric, respectively. In-plane shear can contribute to compression. Then, a nonlinear hyperelastic constitutive model is presented and implemented in an Abaqus/Explicit user subroutine. Finally, a simulation study of the hemispherical forming of 3D orthogonal woven fabric was conducted using this model. The simulation results considering shear-compression coupling show more accurate in-plane shear angles and edge shapes compared to those without considering coupling. Moreover, since the shear-compression coupling is considered, the friction between the fabric and the tool needs to be reasonably discussed in the moulding simulation.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110884"},"PeriodicalIF":8.3,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142356987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Composites Science and Technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1