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Prediction model for fracture toughness of waterborne polyurethane modified concrete at different temperatures 水性聚氨酯改性混凝土在不同温度下的断裂韧性预测模型
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139146
Haoliang Dong , Huajian Li , Zhiqiang Yang , Henan Shi , Liangshun Li , Fali Huang , Zhen Wang , Zhonglai Yi
In certain extreme environments, the bearing capacity of concrete structures diminishes significantly as temperatures soar, simultaneously exposing them to a heightened risk of brittle cracking. The paper aims to elucidate the fracture toughness of waterborne polyurethane modified concrete (WPMC) at different temperatures. Furthermore, a predictive model for the fracture toughness of WPMC, which incorporates both temperature and the waterborne polyurethane (WP) content, is proposed. The flexural strength and fracture toughness of WPMC were tested separately at 20℃, 40℃, 60℃, and 80℃. Utilizing digital image correlation (DIC) technology, the bottom longitudinal strain of WPMC under flexural loading was analyzed. The impact of temperature and WP content on the energy absorption capacity and deformation behavior of WPMC exposed to extreme environment was also investigated. By introducing the microstructural parameters C and Cw to characterize the elastic and plastic deformations of WPMC before and after cracking, a prediction model between the microstructural parameters and temperature, WP content was established. This model enables the prediction of the fracture toughness KIC of WPMC at different temperatures by measuring Fmax.
在某些极端环境下,混凝土结构的承载能力会随着温度的升高而显著降低,同时脆性开裂的风险也会增加。本文旨在阐明水性聚氨酯改性混凝土(WPMC)在不同温度下的断裂韧性。此外,本文还提出了一个包含温度和水性聚氨酯(WP)含量的 WPMC 断裂韧性预测模型。分别在 20℃、40℃、60℃ 和 80℃下测试了 WPMC 的抗弯强度和断裂韧性。利用数字图像相关(DIC)技术,分析了弯曲加载下 WPMC 的底部纵向应变。此外,还研究了温度和可湿性粉末含量对暴露于极端环境下的 WPMC 能量吸收能力和变形行为的影响。通过引入微观结构参数 C 和 Cw 来表征 WPMC 在开裂前后的弹性和塑性变形,建立了微观结构参数与温度、可湿性粉剂含量之间的预测模型。该模型可通过测量 Fmax 预测不同温度下 WPMC 的断裂韧性 KIC。
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引用次数: 0
Study on the impact of grouting reinforcement on the mechanical behavior of non-penetrating fracture sandstone 灌浆加固对非穿透性断裂砂岩力学行为的影响研究
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139079
Zhongshao Yao , Mingli Li , Shibo Huang , Ming Chang , Zhibin Yang
The grouting reinforcement technology is an essential method to enhance the mechanical performance of fractured rock masses and the effectiveness of reinforcement varies with different grouting materials. To further understand the mechanical improvement capabilities of each grout and the reinforcement mechanisms at the grout-rock interface, this study prepared samples with different grouting materials (sulphoaluminate cement (SAC), ultra-fine cement (UFC), and epoxy resin (EPR)) and the uniaxial compression tests were conducted. Based on these tests, the macro and micro mechanical characteristics of different grouting samples were revealed using particle image velocimetry (PIV), acoustic emission (AE), scanning electron microscopy (SEM), and nuclear magnetic resonance (NMR). The results indicate that grouting helps improve the mechanical performance and deformation resistance of fractured rock masses. It effectively limited lateral displacement of the samples, reduced stress concentration at fracture tips, enhanced shear effects during sample fracture, and altered the crack propagation process and failure modes. Compared to the fractured samples, the peak strength of SAC, UFC, and EPR samples increased by 17.8 %, 23.4 %, and 28.3 %, and the elastic modulus increased by 14.3 %, 7.9 %, and 24.8 %, respectively. Among these, the EPR samples exhibited a similarity in parameter indicators to intact samples of over 85 %, making EPR the optimal grouting material. The degree of grout-rock fusion is the primary factor influencing grouting reinforcement effectiveness. SAC is covering-type cement, UFC is embedded cement, EPR is a fusion material, and the fusion-type materials are more beneficial for improving the mechanical performance of fractured rocks.
灌浆加固技术是提高断裂岩体力学性能的重要方法,不同灌浆材料的加固效果各不相同。为了进一步了解每种灌浆材料的力学改善能力以及灌浆材料与岩石界面的加固机制,本研究制备了不同灌浆材料(硫铝酸盐水泥(SAC)、超细水泥(UFC)和环氧树脂(EPR))的样品,并进行了单轴压缩试验。在这些试验的基础上,利用粒子图像测速仪(PIV)、声发射(AE)、扫描电子显微镜(SEM)和核磁共振(NMR)揭示了不同灌浆样品的宏观和微观力学特性。结果表明,灌浆有助于改善断裂岩体的机械性能和抗变形能力。它有效地限制了样品的横向位移,减少了断裂尖端的应力集中,增强了样品断裂过程中的剪切效应,并改变了裂纹的扩展过程和破坏模式。与断裂样品相比,SAC、UFC 和 EPR 样品的峰值强度分别提高了 17.8%、23.4% 和 28.3%,弹性模量分别提高了 14.3%、7.9% 和 24.8%。其中,EPR 样品与完整样品的参数指标相似度超过 85%,因此 EPR 是最佳的灌浆材料。灌浆料与岩石的融合度是影响灌浆加固效果的主要因素。SAC 是覆盖型水泥,UFC 是嵌入型水泥,EPR 是熔融型材料,熔融型材料更有利于改善断裂岩石的力学性能。
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引用次数: 0
Manufacturing accuracy improvement of concrete product by hybrid additive-subtractive method based on the time-dependent characteristics of cementitious materials 基于胶凝材料随时间变化的特性,用混合加减法提高混凝土产品的制造精度
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139135
Li Wang , Wenyu Lin , Qian Wan , Zhijian Li , Gang Bai
Cementitious materials used in 3D printing exhibit significant time-dependent characteristics in terms of early-age rheology and stiffness development that limit high-quality manufacturing. However, the centimeter-level accuracy of concrete 3D printing makes satisfying engineering requirements difficult. To address these challenges, a hybrid additive–subtractive method was developed in this study to improve the accuracy of manufacturing concrete products. The printed components were subjected to a cutting/grinding subtractive treatment until their actual dimensions matched the design dimensions within acceptable tolerances. The processing error of the method was quantitatively analyzed using 3D laser-scanning technology, and the method’s effectiveness was validated by conducting various case studies. The results indicated that the manufacturing mismatch can be controlled within a range of 2 mm, and the surface roughness of the components can be reduced from 8.5 mm to 0.5 mm, resulting in a 94.12 % increase. Thus, the proposed method can be used in the high-precision construction of various free-form structures.
三维打印中使用的水泥基材料在早期流变和刚度发展方面表现出明显的时间依赖性特征,这限制了高质量的制造。然而,混凝土三维打印的厘米级精度难以满足工程要求。为了应对这些挑战,本研究开发了一种增材-减材混合方法,以提高混凝土产品的制造精度。打印出的部件经过切割/打磨减法处理,直到其实际尺寸与设计尺寸相匹配,公差在可接受范围内。利用三维激光扫描技术对该方法的加工误差进行了定量分析,并通过各种案例研究验证了该方法的有效性。结果表明,加工误差可控制在 2 毫米范围内,部件表面粗糙度可从 8.5 毫米降低到 0.5 毫米,提高了 94.12%。因此,所提出的方法可用于各种自由形态结构的高精度制造。
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引用次数: 0
Chloride ion diffusion in recycled concrete containing slag under biaxial compression 含矿渣的再生混凝土在双轴压缩条件下的氯离子扩散
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139136
Jingwei Ying , Wei Chen , Shuangren Chen , Baixi Chen
The presence of cracks and pores in recycled aggregates exacerbates the susceptibility of recycled concrete to chloride ion penetration, thereby diminishing its durability. The incorporation of slag has shown promise in enhancing the chloride ion resistance of recycled concrete, although its mechanism under biaxial loading conditions remains unclear. In this study, a self-made apparatus was employed to investigate chloride ion diffusion in recycled concrete with slag content ranging from 0 % to 30 %, subjected to biaxial loading with stress ratios of 1:0, 1:1, and 2:1. To validate the reliability of the self-made device, both natural diffusion tests and standard rapid chloride ion migration (RCM) tests were conducted. All three approaches provided consistent evidence of a decrease in the chloride ion diffusion coefficient as the slag content increased. This phenomenon was attributed to the slag's capacity to fill large pores and interrupt interconnected cracks, as observed through SEM analysis, even though porosity increased. Under biaxial loading, the chloride ion diffusion coefficient of slag-recycled concrete exhibited an initial decrease followed by an increase as the stress level escalated. The lowest chloride ion diffusion coefficient for recycled concrete was achieved at a stress ratio of 1:1, a stress level of 0.5, and a slag content of 30 %. Furthermore, a predictive model for the chloride ion diffusion coefficient in slag concrete under biaxial loading conditions was developed.
再生骨料中裂缝和孔隙的存在加剧了再生混凝土对氯离子渗透的敏感性,从而降低了其耐久性。掺入矿渣有望增强再生混凝土的抗氯离子能力,但其在双轴加载条件下的作用机理仍不清楚。在本研究中,我们使用了自制仪器来研究在应力比为 1:0、1:1 和 2:1 的双轴加载条件下,矿渣含量从 0% 到 30% 不等的再生混凝土中的氯离子扩散情况。为了验证自制装置的可靠性,进行了自然扩散试验和标准氯离子快速迁移(RCM)试验。所有三种方法都一致证明,随着矿渣含量的增加,氯离子扩散系数会降低。通过扫描电镜分析观察到,即使孔隙率增加,炉渣仍能填充大孔隙并打断相互连接的裂缝,因此出现了这种现象。在双轴荷载作用下,矿渣回收混凝土的氯离子扩散系数在最初出现下降,然后随着应力水平的增加而上升。应力比为 1:1、应力水平为 0.5、矿渣含量为 30% 时,再生混凝土的氯离子扩散系数最低。此外,还建立了双轴加载条件下矿渣混凝土中氯离子扩散系数的预测模型。
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引用次数: 0
Study on the transverse compression damage behavior of CFRP tendons in the wedge-type anchorage system 楔形锚固系统中 CFRP 筋的横向压缩破坏行为研究
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139094
Jie Xu , Qiang Cao , Weixin Wang , Yihang Liu
The wedge-type anchorage system is widely used for CFRP tendon anchoring due to its convenient construction, compact size and high efficiency. However, stress concentration at the gap between wedges often causes transverse damage in CFRP tendons, which compromises the safety of CFRP cables. Presently, research on the transverse compression damage behavior of CFRP tendons caused by wedges remains limited to qualitative descriptions and lacks essential theoretical support. This study investigates the transverse mechanical properties and compression damage behavior of CFRP tendons. Prismatic specimen tests for transverse compression and shear were conducted to accurately determine the transverse mechanical properties of CFRP tendons. By conducting matching shaped compression tests on CFRP tendons, the influence of different wedge gaps on compression damage behavior was examined, and the compression damage mechanism caused by wedges was analyzed. Furthermore, the LaRC05 composite material failure criterion was utilized to predict the compression damage behavior of CFRP tendons. The results indicate that compression damage of CFRP tendons in wedge-type anchorage primarily occurs due to transverse shear cracks initiating at the edges of the gaps. These cracks propagate inward under compression load until the tendons collapse. The extent of compression damage is significantly influenced by the ratio of gap width to tendon diameter β. Under the same loading conditions, the compression damage exacerbates with the increase of β. Digital Image Correlation (DIC) analysis was used to determine the critical damage state under various β values, and a linear relationship between the critical equivalent contact pressure (pc) and β was established. The LaRC05 composite material failure criterion accurately predicts the morphology of compression cracks and critical damage states of CFRP tendons. The research results of this paper provide crucial theoretical support for damage control and offer valuable guidance for the future design of anchorage systems.
楔形锚固系统因其施工方便、体积小、效率高而被广泛用于 CFRP 筋的锚固。然而,楔块间隙处的应力集中往往会造成 CFRP 筋的横向损坏,从而影响 CFRP 缆线的安全性。目前,对楔块引起 CFRP 筋横向压缩破坏行为的研究仍局限于定性描述,缺乏基本的理论支持。本研究探讨了 CFRP 筋的横向机械性能和压缩破坏行为。为了准确测定 CFRP 筋的横向力学性能,对其进行了横向压缩和剪切的棱柱试样试验。通过对 CFRP 筋进行匹配形压缩试验,研究了不同楔形间隙对压缩破坏行为的影响,并分析了楔形造成的压缩破坏机理。此外,还利用 LaRC05 复合材料失效准则预测了 CFRP 筋的压缩破坏行为。结果表明,楔形锚固中 CFRP 筋的压缩破坏主要是由于在缝隙边缘产生的横向剪切裂缝造成的。在压缩荷载作用下,这些裂缝向内扩展,直至肌腱塌陷。压缩破坏的程度受间隙宽度与肌腱直径之比 β 的显著影响。 在相同的加载条件下,压缩破坏随着 β 的增大而加剧。 采用数字图像相关分析 (DIC) 确定了不同 β 值下的临界破坏状态,并建立了临界等效接触压力 (pc) 与 β 之间的线性关系。LaRC05 复合材料失效准则准确地预测了 CFRP 筋的压缩裂缝形态和临界破坏状态。本文的研究成果为损伤控制提供了重要的理论支持,并为未来的锚固系统设计提供了宝贵的指导。
{"title":"Study on the transverse compression damage behavior of CFRP tendons in the wedge-type anchorage system","authors":"Jie Xu ,&nbsp;Qiang Cao ,&nbsp;Weixin Wang ,&nbsp;Yihang Liu","doi":"10.1016/j.conbuildmat.2024.139094","DOIUrl":"10.1016/j.conbuildmat.2024.139094","url":null,"abstract":"<div><div>The wedge-type anchorage system is widely used for CFRP tendon anchoring due to its convenient construction, compact size and high efficiency. However, stress concentration at the gap between wedges often causes transverse damage in CFRP tendons, which compromises the safety of CFRP cables. Presently, research on the transverse compression damage behavior of CFRP tendons caused by wedges remains limited to qualitative descriptions and lacks essential theoretical support. This study investigates the transverse mechanical properties and compression damage behavior of CFRP tendons. Prismatic specimen tests for transverse compression and shear were conducted to accurately determine the transverse mechanical properties of CFRP tendons. By conducting matching shaped compression tests on CFRP tendons, the influence of different wedge gaps on compression damage behavior was examined, and the compression damage mechanism caused by wedges was analyzed. Furthermore, the LaRC05 composite material failure criterion was utilized to predict the compression damage behavior of CFRP tendons. The results indicate that compression damage of CFRP tendons in wedge-type anchorage primarily occurs due to transverse shear cracks initiating at the edges of the gaps. These cracks propagate inward under compression load until the tendons collapse. The extent of compression damage is significantly influenced by the ratio of gap width to tendon diameter <span><math><mi>β</mi></math></span>. Under the same loading conditions, the compression damage exacerbates with the increase of <span><math><mi>β</mi></math></span>. Digital Image Correlation (DIC) analysis was used to determine the critical damage state under various <span><math><mi>β</mi></math></span> values, and a linear relationship between the critical equivalent contact pressure (<span><math><msub><mrow><mi>p</mi></mrow><mrow><mi>c</mi></mrow></msub></math></span>) and <span><math><mi>β</mi></math></span> was established. The LaRC05 composite material failure criterion accurately predicts the morphology of compression cracks and critical damage states of CFRP tendons. The research results of this paper provide crucial theoretical support for damage control and offer valuable guidance for the future design of anchorage systems.</div></div>","PeriodicalId":288,"journal":{"name":"Construction and Building Materials","volume":"454 ","pages":"Article 139094"},"PeriodicalIF":7.4,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142651082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development and characterization of saturated fatty acids and biopolymer based novel multilayer encapsulated phase change materials system for buildings 基于饱和脂肪酸和生物聚合物的新型建筑用多层封装相变材料系统的开发与表征
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139115
Amit Jain, Ghanshyam Pal
Application of encapsulated phase change materials (PCM) is becoming an attractive passive measure to develop energy efficient buildings. In the present work, the eutectic mixture of two saturated fatty acids (lauric acid and palmitic acid in 80:20 ratio, HTPCM) was selected and encapsulated in a novel multilayer architecture to develop PCM beads. The bead architecture includes a PCM core enveloped by thermally conductive calcium alginate (Ca-Alg) biopolymer + multiwall carbon nanotubes intermediate shell to promote heat transfer from the core and the outer rugged coating of flyash + water-based polyurethane (PU) to improve mechanical integrity and interlocking with wet cement mortar matrix during mix preparation. The thermal characteristics of four pure PCM (capric acid, lauric acid, myristic acid, and stearic acid) and one eutectic mixture (HTPCM) were measured using differential scanning calorimetry (DSC) to select the suitable PCM as per prevailing local ambient temperature. As per scanning electron microscopy (SEM) results, the average core size is in the range of 1.5 – 2.0 mm and PCM is stored in the bead core as tiny globules separated by Ca-Alg membrane. Single bead compression test performed on multilayer PCM (m-PCM) bead show that the shell of the bead possesses sufficient mechanical strength. The Fourier transformed infrared spectroscopy (FTIR) analysis and thermogravimetric analysis (TGA) studies confirm that the HTPCM and coating materials are chemically / thermally stable through different steps of fabrication and heating / cooling thermal cycles. Finally, the filter paper leakage test showed that the multilayer bead shell can prevent the PCM leakage from the core during bead heating. The various test results reported herein corroborate that the proposed architecture provides good physical properties and mechanical strength to the encapsulated PCM beads.
封装相变材料(PCM)的应用正成为开发节能建筑的一种有吸引力的被动措施。在本研究中,我们选择了两种饱和脂肪酸(月桂酸和棕榈酸,比例为 80:20,HTPCM)的共晶混合物,并将其封装在一种新型多层结构中,以开发 PCM 珠。该珠子结构包括由导热海藻酸钙(Ca-Alg)生物聚合物+多壁碳纳米管中间层外壳包裹的 PCM 内核,以促进内核的热量传递,以及粉煤灰+水性聚氨酯(PU)的凹凸不平的外层,以提高机械完整性和在混合料制备过程中与湿水泥砂浆基质的互锁性。使用差示扫描量热仪(DSC)测量了四种纯 PCM(癸酸、月桂酸、肉豆蔻酸和硬脂酸)和一种共晶混合物(HTPCM)的热特性,以根据当地环境温度选择合适的 PCM。扫描电子显微镜(SEM)结果表明,珠心的平均尺寸在 1.5 - 2.0 毫米之间,PCM 以被 CaAlg 膜分离的小球形式储存在珠心中。对多层 PCM(m-PCM)珠子进行的单珠压缩测试表明,珠子的外壳具有足够的机械强度。傅立叶变换红外光谱(FTIR)分析和热重分析(TGA)研究证实,HTPCM 和涂层材料在不同的制造步骤和加热/冷却热循环中具有化学/热稳定性。最后,滤纸泄漏测试表明,多层微珠外壳可以防止微珠加热过程中 PCM 从芯部泄漏。本文所报告的各种测试结果证实,所提出的结构为封装的 PCM 微珠提供了良好的物理性能和机械强度。
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引用次数: 0
Effect of sisal fibers on the disintegration characteristics of sisal fiber-amended loess 剑麻纤维对剑麻纤维改良黄土崩解特性的影响
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139032
Rong Jiang, Jiading Wang, Tao Xiao, Dengfei Zhang
Loess, an aeolian and unsaturated deposit, is highly sensitive to water. It can swiftly cause a series of detrimental effects including soil erosion, water and soil losses, and slope instability under the action of water and loading. Consequently, enhancing the water stability of loess is paramount for mitigating these issues. This study systematically investigates the effect of sisal fibers on the disintegration characteristics and microstructure of Q3 Malan loess using a self-designed disintegration apparatus and scanning electron microscope (SEM). In addition, the disintegration ratio, rate, and microstructure between untreated loess and loess amended with sisal fibers are compared and analyzed. A quantitative analysis was conducted to assess how the sisal fiber dosage and curing period influence the disintegration characteristics of sisal fiber-amended loess. The results show that sisal fibers effectively enhance the resistance of soil to disintegration, with this resistance intensifying with increasing sisal fiber dosage and extended curing periods. Notably, when the curing period reached 3 days and the fiber dosage reached 0.45 %, the sisal fiber-amended loess did not disintegrate. The incorporation of sisal fibers results in a decrease in soil pore area, with a greater fiber dosage leading to a lower pore area. In addition, sisal fiber can promote the formation and accumulation of organic matter in the soil, which can not only improve the bonding energy between soil particles but also facilitate carbon sequestration. This study underscores the potential of sisal fiber as a green and environmentally friendly modifier for loess, offering a promising solution for mitigating soil erosion and slope instability by enhancing the resistance of the soil to water-induced disintegration.
黄土是一种风化和非饱和沉积物,对水非常敏感。在水和荷载的作用下,它会迅速造成一系列有害影响,包括土壤侵蚀、水土流失和斜坡失稳。因此,提高黄土的水稳定性对于缓解这些问题至关重要。本研究利用自行设计的崩解仪和扫描电子显微镜(SEM),系统地研究了剑麻纤维对 Q3 马兰黄土崩解特性和微观结构的影响。此外,还比较和分析了未经处理的黄土与添加了剑麻纤维的黄土之间的崩解率、崩解速率和微观结构。还进行了定量分析,以评估剑麻纤维用量和固化期如何影响剑麻纤维改良黄土的崩解特性。结果表明,剑麻纤维能有效增强土壤的抗崩解性,随着剑麻纤维用量的增加和固化时间的延长,抗崩解性也会增强。值得注意的是,当固化期达到 3 天,纤维用量达到 0.45 % 时,剑麻纤维掺合的黄土不会崩解。掺入剑麻纤维后,土壤孔隙减少,纤维用量越大,孔隙越小。此外,剑麻纤维还能促进土壤中有机物的形成和积累,这不仅能提高土壤颗粒之间的结合能,还能促进固碳。这项研究强调了剑麻纤维作为一种绿色环保的黄土改良剂的潜力,通过增强土壤对水引起的崩解的抵抗力,为减轻土壤侵蚀和斜坡不稳定性提供了一种前景广阔的解决方案。
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引用次数: 0
Multi-scale thermo-poro-mechanical simulation of the frost resistance of low-heat and moderate-heat hydraulic concrete considering the aging microstructure 考虑老化微观结构的低热和中热水工混凝土抗冻性的多尺度热孔力学模拟
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139062
Zhe Huang , Jiazhang Cao , Fuyuan Gong , Ding Nie , Wenwei Li , Peng Lin , He Zhang
Hydraulic concrete structures in cold regions are vulnerable to freeze-thaw damage. This paper proposes a multi-scale simulation analysis approach to investigate the mechanical properties and frost resistance of Low-heat Portland (LHP) cement, Moderate-heat Portland (MHP) cement, and Ordinary Portland cement (OPC) concrete. The hydration heat, hydration degree, pore size distribution, and compressive strength of LHP, MHP, and OPC concrete at different curing ages, as well as the ice amount, expansion strain, and mechanical properties under different freeze-thaw cycles are calculated and compared. Due to the lower early-hydrated C3S content of LHP and the higher later-hydrated C2S content, the porosity of LHP after 90d curing is lower than that of MHP and OPC, resulting in better mechanical properties and frost resistance. On this basis, the evolution model proposed in this paper can quantitative analysis the frost resistance of cement paste based on different content of C3S and C2S, which provided a feasible method for predicting the frost resistance of hydraulic concrete structures in cold regions.
寒冷地区的水工混凝土结构很容易受到冻融破坏。本文提出了一种多尺度模拟分析方法来研究低热硅酸盐(LHP)水泥、中热硅酸盐(MHP)水泥和普通硅酸盐水泥(OPC)混凝土的力学性能和抗冻性。计算并比较了 LHP、MHP 和 OPC 混凝土在不同养护龄期的水化热、水化程度、孔径分布和抗压强度,以及在不同冻融循环条件下的冰量、膨胀应变和力学性能。由于 LHP 早期水化的 C3S 含量较低,而后期水化的 C2S 含量较高,因此 90d 养护后 LHP 的孔隙率低于 MHP 和 OPC,从而具有更好的力学性能和抗冻性。在此基础上,本文提出的演化模型可以定量分析不同C3S和C2S含量水泥浆的抗冻性,为预测寒冷地区水工混凝土结构的抗冻性提供了可行的方法。
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引用次数: 0
CaCO3 coating of off-specification fly ash for upcycling in cementitious materials 将不合规格的粉煤灰制成 CaCO3 涂层,以便在水泥基材料中进行再循环利用
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139066
Zhuo Liu , Weina Meng
To address this challenge of shortage of specification-grade fly ash(SGFA) and recycling of off-specification fly ash(OSFA), this research proposes a novel approach of coating OSFA with nano-CaCO3. This improves the surface characteristics of the particles and creates nucleation sites that enhance cement hydration, thus potentially improving the fundamental properties of cementitious materials incorporating OSFA. The first step in this process involves optimizing the quantity of nano-CaCO3 coating on OSFA to achieve the best mechanical properties for concrete applications. Subsequently, experimental investigations were conducted to compare the mechanical properties of cementitious pastes prepared with original OSFA, OSFA and nano-CaCO3 powders, and coated OSFA. Isothermal calorimetry and pore structure analyses indicated that the coating treatment transformed OSFA from a detrimental additive to a beneficial one for concrete. This coating significantly strengthened the OSFA particles and promoted cement hydration, consequently enhancing the mechanical properties of cementitious composites containing OSFA. This innovative method offers a promising solution for addressing the fly ash shortage in the concrete industry while minimizing the need for land disposal of OSFA.
为了解决规格级粉煤灰(SGFA)短缺和规格外粉煤灰(OSFA)回收利用的难题,本研究提出了一种在 OSFA 上涂覆纳米 CaCO3 的新方法。这将改善颗粒的表面特性,并形成可增强水泥水化的成核点,从而有可能改善含有 OSFA 的胶凝材料的基本特性。这一过程的第一步是优化 OSFA 上纳米 CaCO3 涂层的数量,以实现混凝土应用的最佳机械性能。随后,进行了实验研究,以比较使用原始 OSFA、OSFA 和纳米 CaCO3 粉末以及涂覆 OSFA 制备的水泥基浆料的机械性能。等温量热法和孔隙结构分析表明,涂层处理将 OSFA 从对混凝土有害的添加剂转变为有益的添加剂。这种涂层大大增强了 OSFA 颗粒的强度,促进了水泥水化,从而提高了含有 OSFA 的水泥基复合材料的机械性能。这种创新方法为解决混凝土行业粉煤灰短缺问题提供了一种前景广阔的解决方案,同时最大限度地减少了在土地上处置 OSFA 的需要。
{"title":"CaCO3 coating of off-specification fly ash for upcycling in cementitious materials","authors":"Zhuo Liu ,&nbsp;Weina Meng","doi":"10.1016/j.conbuildmat.2024.139066","DOIUrl":"10.1016/j.conbuildmat.2024.139066","url":null,"abstract":"<div><div>To address this challenge of shortage of specification-grade fly ash(SGFA) and recycling of off-specification fly ash(OSFA), this research proposes a novel approach of coating OSFA with nano-CaCO<sub>3</sub>. This improves the surface characteristics of the particles and creates nucleation sites that enhance cement hydration, thus potentially improving the fundamental properties of cementitious materials incorporating OSFA. The first step in this process involves optimizing the quantity of nano-CaCO<sub>3</sub> coating on OSFA to achieve the best mechanical properties for concrete applications. Subsequently, experimental investigations were conducted to compare the mechanical properties of cementitious pastes prepared with original OSFA, OSFA and nano-CaCO<sub>3</sub> powders, and coated OSFA. Isothermal calorimetry and pore structure analyses indicated that the coating treatment transformed OSFA from a detrimental additive to a beneficial one for concrete. This coating significantly strengthened the OSFA particles and promoted cement hydration, consequently enhancing the mechanical properties of cementitious composites containing OSFA. This innovative method offers a promising solution for addressing the fly ash shortage in the concrete industry while minimizing the need for land disposal of OSFA.</div></div>","PeriodicalId":288,"journal":{"name":"Construction and Building Materials","volume":"454 ","pages":"Article 139066"},"PeriodicalIF":7.4,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142651087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ZIF-67-derived CuCo-layered double hydroxide/ammonium polyphosphate hybrid for highly efficient flame retardant epoxy resin via synergistic catalytic carbonization 通过协同催化碳化将 ZIF-67 衍生的铜钴层双氢氧化物/聚磷酸铵混合物用于高效阻燃环氧树脂
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.conbuildmat.2024.139102
Yiwei Geng , Junxiu Piao , Xinliang Liu , Xilei Chen , Chuanmei Jiao
Ammonium polyphosphate (APP) has been commonly used as a commercial flame retardant. However, its application to flame-retardant epoxy resins (EP) has been faced with the problems of high smoke generation and degradation of mechanical properties. This has greatly limited its wide application in the field of building materials. In this work, a highly efficient flame retardant APP@M-LDH was prepared by using ZIF-67 as a bridge, and its microstructure, chemical composition, and thermal stability were comprehensively characterized. Due to the synergistic flame retardant effect of APP and LDH and the catalytic oxidation of copper and cobalt ions in the LDH structure in the gas phase, the peak heat release rate (PHRR), total heat release rate (THR) and total smoke release rate (TSP) of EP/4APP@M-LDH were reduced by 34 %, 35.3 % and 40.3 %, respectively, which achieved the high efficiency of flame retardancy for EP. In addition, due to the three-dimensional structure of the synthesized CuCo-LDH, which can expose more hydrogen bonds, the flexural strength and flexural modulus of EP/4APP@M-LDH were significantly increased by 54.1 % and 63.6 %, respectively. This study provides new ideas for the design of efficient flame retardants for EP.
聚磷酸铵(APP)是一种常用的商用阻燃剂。然而,将其应用于阻燃环氧树脂(EP)却面临着发烟量大和机械性能下降的问题。这大大限制了它在建筑材料领域的广泛应用。本研究以 ZIF-67 为桥,制备了高效阻燃 APP@M-LDH,并对其微观结构、化学成分和热稳定性进行了综合表征。由于APP和LDH的协同阻燃效应以及LDH结构中铜离子和钴离子在气相中的催化氧化作用,EP/4APP@M-LDH的峰值热释放率(PHRR)、总热释放率(THR)和总烟雾释放率(TSP)分别降低了34%、35.3%和40.3%,实现了EP的高效阻燃。此外,由于合成的 CuCo-LDH 具有三维结构,可以暴露出更多的氢键,因此 EP/4APP@M-LDH 的抗折强度和抗折模量分别显著提高了 54.1% 和 63.6%。这项研究为设计 EP 的高效阻燃剂提供了新思路。
{"title":"ZIF-67-derived CuCo-layered double hydroxide/ammonium polyphosphate hybrid for highly efficient flame retardant epoxy resin via synergistic catalytic carbonization","authors":"Yiwei Geng ,&nbsp;Junxiu Piao ,&nbsp;Xinliang Liu ,&nbsp;Xilei Chen ,&nbsp;Chuanmei Jiao","doi":"10.1016/j.conbuildmat.2024.139102","DOIUrl":"10.1016/j.conbuildmat.2024.139102","url":null,"abstract":"<div><div>Ammonium polyphosphate (APP) has been commonly used as a commercial flame retardant. However, its application to flame-retardant epoxy resins (EP) has been faced with the problems of high smoke generation and degradation of mechanical properties. This has greatly limited its wide application in the field of building materials. In this work, a highly efficient flame retardant APP@M-LDH was prepared by using ZIF-67 as a bridge, and its microstructure, chemical composition, and thermal stability were comprehensively characterized. Due to the synergistic flame retardant effect of APP and LDH and the catalytic oxidation of copper and cobalt ions in the LDH structure in the gas phase, the peak heat release rate (PHRR), total heat release rate (THR) and total smoke release rate (TSP) of EP/4APP@M-LDH were reduced by 34 %, 35.3 % and 40.3 %, respectively, which achieved the high efficiency of flame retardancy for EP. In addition, due to the three-dimensional structure of the synthesized CuCo-LDH, which can expose more hydrogen bonds, the flexural strength and flexural modulus of EP/4APP@M-LDH were significantly increased by 54.1 % and 63.6 %, respectively. This study provides new ideas for the design of efficient flame retardants for EP.</div></div>","PeriodicalId":288,"journal":{"name":"Construction and Building Materials","volume":"453 ","pages":"Article 139102"},"PeriodicalIF":7.4,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142659293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Construction and Building Materials
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