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Additive manufacturing by the selective paste intrusion: Effect of the distance of the print nozzle to the particle bed on the print quality 通过选择性浆料侵入进行增材制造:打印喷嘴与颗粒床的距离对打印质量的影响
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138274

Selective Paste Intrusion (SPI) is an additive manufacturing (AM) process in which thin layers of aggregates are selectively bonded by cement paste only where the structure is to be produced. In this way, concrete elements with complex geometries and structures can be created. Reinforcement is required to increase the flexural strength of the concrete elements and, thus, enable their applicability in practice. Integrating the reinforcement is a difficult task, particularly in the case of SPI, due to the layerwise printing method. Especially with respect to possible complex structures, the production of the reinforcement needs to be adapted to SPI, thereby offering a high degree of freedom. One concept for reinforcement integration is combining the two additive manufacturing processes, SPI and Wire and Arc Additive Manufacturing (WAAM). However, since the two processes serve different fields of application, their compatibility is not necessarily given. Ongoing investigations show that the temperatures caused by WAAM adversely affect both the cement paste rheology required for sufficient paste penetration into the particle bed and the overall concrete strength. This paper provides an overview of ongoing research focusing on different cooling strategies and their effects on the compressive strength of SPI-printed concrete parts.

选择性浆料侵入(SPI)是一种增材制造(AM)工艺,只在需要制造结构的地方用水泥浆选择性地粘合薄层骨料。通过这种方法,可以制造出具有复杂几何形状和结构的混凝土构件。为了提高混凝土构件的抗弯强度,从而使其能够应用于实践,需要进行加固。由于 SPI 采用分层打印的方法,整合钢筋是一项艰巨的任务,尤其是在 SPI 的情况下。特别是对于可能出现的复杂结构,钢筋的生产需要与 SPI 相适应,从而提供较高的自由度。钢筋集成的一个概念是将 SPI 和线弧增材制造(WAAM)这两种增材制造工艺结合起来。然而,由于这两种工艺的应用领域不同,它们之间并不一定具有兼容性。正在进行的研究表明,WAAM 产生的温度会对水泥浆流变性产生不利影响,而水泥浆流变性是水泥浆充分渗入颗粒床和混凝土整体强度所必需的。本文概述了正在进行的研究,重点是不同的冷却策略及其对 SPI 印刷混凝土部件抗压强度的影响。
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引用次数: 0
Production of low-carbon cement composites using red sandstone: CO2 storage and performance analysis 利用红砂岩生产低碳水泥复合材料:二氧化碳储存和性能分析
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138323

Carbonation curing is currently one of the most effective methods for reducing carbon and absorbing carbon dioxide in cement-based materials. This study evaluated the macroscopic, microscopic, and thermal properties of red sandstone and limestone with different dosages under different curing methods. The results show that the carbonation rate is higher when 20 % red sandstone is added, and the carbon fixation amount is the highest. The inclusion of red sandstone provides more nucleation sites for the formation of carbonation product silica gel. At 600°C, the strength reduction of the carbonation samples is lower than that of the sealed samples, and the carbonation products are more resistant to high temperatures. Furthermore, the relationship between the microscopic, macroscopic, and thermal properties of red sandstone and limestone under different curing methods is explored. This study provides a new approach to the utilization of red sandstone resources.

碳化固化是目前水泥基材料中最有效的减碳和吸收二氧化碳的方法之一。本研究评估了不同固化方法下不同掺量的红砂岩和石灰石的宏观、微观和热性能。结果表明,加入 20% 的红砂岩时,碳化率更高,固碳量也最高。红砂岩的加入为碳化产物硅胶的形成提供了更多的成核点。在 600°C 时,碳化样品的强度降低幅度低于密封样品,碳化产物的耐高温性更强。此外,还探讨了红砂岩和石灰石在不同固化方法下的微观、宏观和热性能之间的关系。这项研究为红砂岩资源的利用提供了一种新方法。
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引用次数: 0
Experimental study on the compressive behavior of UHPC filled stainless steel tubes subjected to monotonic and cyclic loading 单调和循环加载下 UHPC 填充不锈钢管抗压行为的实验研究
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138301

Ultra-High Performance Concrete Filled Stainless Steel Tubular (UHPCFSST) column is a novel type of composite columns appealing to be adopted in corrosive and marine environment. To explore the axial performance of UHPCFSST columns, this paper initiates an experimental program containing 14 UHPCFSST columns subjected to either monotonic or cyclical axial compressive loading. The test variables in this program mainly include the column dimension, tube thickness and the loading schemes. Based on the test results, the damage evolution process, ultimate failure mode, load-deformation response and the typical mechanical performance indexes inclusive of loading-carrying capacity, stiffness degradation, as well as ductility coefficient are thoroughly examined. After that, theoretical analysis is carried out to explore the interaction behavior between UHPC and stainless-steel tube and hence judge the degree of confinement effect. To assess the applicability of the code equations stipulated in current international design guidelines and the empirical formulas proposed by other researchers, a small-scale dataset containing 41 UHPCFSST columns was compiled to make comparison of axial capacity between test results and analytical predictions. In view of the limited accuracy or the burdensome calculation process, a new formula considering actual loading carrying mechanism was proposed to calculate the axial capacity of UHPCFSST columns, which exhibits enhanced accuracy and efficiency than the current formulas.

超高性能混凝土填充不锈钢管(UHPCFSST)柱是一种新型复合材料柱,可用于腐蚀性和海洋环境。为了探索 UHPCFSST 柱的轴向性能,本文启动了一项实验计划,其中包含 14 个 UHPCFSST 柱,对其施加单调或循环轴向压缩荷载。试验变量主要包括柱子尺寸、管子厚度和加载方案。在试验结果的基础上,深入研究了破坏演变过程、最终破坏模式、载荷-变形响应和典型力学性能指标(包括承载能力、刚度退化和延性系数)。然后,进行理论分析,探讨 UHPC 与不锈钢管之间的相互作用行为,从而判断约束效应的程度。为了评估现行国际设计准则中规定的规范方程和其他研究人员提出的经验公式的适用性,我们编制了一个包含 41 个 UHPCFSST 柱的小规模数据集,以比较试验结果和分析预测之间的轴向承载力。鉴于计算精度有限或计算过程繁琐,提出了一种考虑实际承载机理的新公式来计算 UHPCFSST 柱的轴向承载力,与现有公式相比,其精度和效率均有所提高。
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引用次数: 0
Effects of antioxidants on chemical and rheological properties of asphalt binders from different crude oil sources 抗氧化剂对不同原油来源的沥青粘合剂的化学和流变特性的影响
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138260

Antioxidants can effectively mitigate or delay the oxidative aging degradation of asphalt binder, thereby improving pavement durability. While research has largely concentrated on the application of antioxidants to asphalt binders from a single source, limited studies have explored their effects on binders derived from different crude oil sources. Moreover, the relationship between the chemical and rheological properties of antioxidant-modified asphalt binders remains insufficiently understood. In this study, three antioxidants - zinc diethyldithiocarbamate (ZDC), Irganox 1010 and kraft lignin - were utilized and blended with base binders sourced from three distinct regions globally. Fourier transform infrared spectroscopy (FTIR) was utilized to analyze the impact of these antioxidants on the chemical composition of aged binders. Additionally, dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests were conducted to assess the high- and low-temperature performance of the antioxidant-modified binders, identifying the most effective antioxidant. The linear amplitude sweep (LAS) test further evaluated the performance of ZDC across binders from different crude oil sources. The results revealed three key findings: first, chemical functional group changes due to antioxidants are not always reflected in rheological performance; second, ZDC demonstrated superior performance across different base binders, as evidenced by improved aging indices, high-temperature rutting resistance, and enhanced fatigue and low-temperature cracking resistance; and third, asphalt binders from different crude oil sources exhibit varying sensitivities to antioxidant type and dosage. This study underscores the necessity of determining optimal antioxidant dosages for different asphalt binders, as the relationship between antioxidant dosage and effectiveness is not straightforward.

抗氧化剂可以有效减轻或延缓沥青胶结料的氧化老化降解,从而提高路面的耐久性。虽然研究主要集中在将抗氧化剂应用于单一来源的沥青粘结剂上,但对其对不同原油来源的粘结剂的影响的探讨却很有限。此外,人们对抗氧化剂改性沥青胶结料的化学性质和流变学性质之间的关系仍然了解不足。在这项研究中,使用了三种抗氧化剂--二乙基二硫代氨基甲酸锌(ZDC)、Irganox 1010 和牛皮纸木质素--并将其与来自全球三个不同地区的基础粘结剂混合。傅立叶变换红外光谱(FTIR)用于分析这些抗氧化剂对老化粘合剂化学成分的影响。此外,还进行了动态剪切流变仪(DSR)和弯曲梁流变仪(BBR)测试,以评估抗氧化剂改性粘合剂的高温和低温性能,从而确定最有效的抗氧化剂。线性振幅扫描(LAS)测试进一步评估了 ZDC 在不同原油来源的粘合剂中的性能。结果显示了三个重要发现:第一,抗氧化剂导致的化学官能团变化并不总能反映在流变性能上;第二,ZDC 在不同的基质粘结剂中表现出卓越的性能,具体表现为老化指数提高、抗高温车辙能力增强、抗疲劳和抗低温开裂能力增强;第三,不同原油来源的沥青粘结剂对抗氧化剂的类型和剂量表现出不同的敏感性。这项研究强调了针对不同沥青胶结料确定最佳抗氧化剂用量的必要性,因为抗氧化剂用量与效果之间的关系并不简单。
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引用次数: 0
Evaluating the impact of specimen and punch sizes on the tensile strength of UHPC through double punch testing 通过双冲试验评估试样和冲头尺寸对超高强度混凝土抗拉强度的影响
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138060

Many studies have shown that direct tensile tests are fraught with numerous challenges. The Double Punch Test (DPT) is considered a more reliable alternative for evaluating tensile properties among the indirect tensile methods. While DPT is efficient and reliable, its size effect should not be overlooked. Previous studies on DPT size effects have primarily focused on specimen size, with little discussion on the impact of punch size variations. Additionally, with the evolution of construction materials, the applicability of the generalized DPT formula to new materials, such as Ultra-High-Performance Concrete (UHPC), with its exceptional strength, toughness, durability, and crack resistance, needs to be evaluated. This study conducts experimental research on UHPC, focusing on the relationship between specimen and punch sizes and their impact on tensile strength measurements. By designing experiments with 12 different specimen sizes and punch ratios, we explore the differences between actual experimental results and simplified formula calculations. Bažant's theoretical methods are also applied to analyze the size effects of specimen and punch dimensions on DPT. The results indicate that, with appropriate specimen size and punch ratio, DPT can provide tensile strength measurements closer to those of Direct Tensile Tests (DTT). It was also found that tensile strength, strain, and toughness decrease with increasing specimen size. When the ratio of UHPC specimen to punch size (d/D) is 1/3, the results align well with the predictions of the simplified formula. This indicates that the optimal punch ratio is not fixed for different specimen sizes. These findings offer valuable references for designing related experiments and improving quality control and structural performance in various engineering fields.

许多研究表明,直接拉伸试验存在诸多挑战。在间接拉伸方法中,双冲试验(DPT)被认为是评估拉伸特性的更可靠的替代方法。虽然 DPT 高效可靠,但其尺寸效应也不容忽视。以往关于 DPT 尺寸效应的研究主要集中在试样尺寸上,很少讨论冲头尺寸变化的影响。此外,随着建筑材料的发展,需要评估通用 DPT 公式对新材料的适用性,如具有超高强度、韧性、耐久性和抗裂性的超高性能混凝土 (UHPC)。本研究对 UHPC 进行了实验研究,重点是试样和冲头尺寸之间的关系及其对拉伸强度测量的影响。通过设计 12 种不同试样尺寸和冲孔比例的实验,我们探索了实际实验结果与简化公式计算之间的差异。我们还应用 Bažant 的理论方法分析了试样和冲头尺寸对 DPT 的影响。结果表明,在试样尺寸和冲孔比例适当的情况下,DPT 可以提供更接近直接拉伸试验 (DTT) 的拉伸强度测量结果。研究还发现,拉伸强度、应变和韧性随着试样尺寸的增大而降低。当 UHPC 试样与冲头尺寸之比 (d/D) 为 1/3 时,结果与简化公式的预测结果非常吻合。这表明,对于不同尺寸的试样,最佳冲孔比例并不是固定不变的。这些发现为设计相关实验、改进各工程领域的质量控制和结构性能提供了有价值的参考。
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引用次数: 0
Effects of marine environment and fatigue pre-damage on the residual tensile properties of SFCBs 海洋环境和疲劳预损伤对 SFCB 残余拉伸性能的影响
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138273

Steel-fiber reinforced polymer (FRP) composite bars (SFCBs) present a promising solution to corrosion issues associated with conventional reinforcement in marine environments, offering a viable alternative. While the performance of SFCBs under marine environments or fatigue loading is well understood, their behavior under combined conditions remains unreported. This study conducted tension-tension fatigue tests on seawater-immersed SFCBs to assess the effects of fatigue loading (at a stress level of 0.36), various aging temperatures (23°C, 40°C, and 60°C), and durations (30, 180, and 360 days) on their residual properties. Microscopic analysis was used to investigate the degradation mechanisms due to environmental aging. The results indicate that environmental aging deteriorates the GFRP matrix in the outer layer of SFCBs, with fatigue loading further causing matrix cracking and reducing the quasi-static tensile strength. The residual tensile strength of SFCBs decreases with increasing aging times or temperatures, while aging shows no significant effect on their fatigue life. Additionally, a model predicting the residual tensile strength of SFCBs based on damage accumulation was proposed. According to the model, tensile strength initially rapidly decreases with aging time and eventually stabilizes. These findings offer practical insights for the application of SFCBs in concrete structures.

钢纤维增强聚合物(FRP)复合材料棒材(SFCBs)为解决海洋环境中与传统加固材料相关的腐蚀问题提供了一种可行的替代方案。虽然 SFCBs 在海洋环境或疲劳载荷下的性能已广为人知,但其在组合条件下的行为仍未见报道。本研究对浸入海水中的 SFCB 进行了拉伸疲劳试验,以评估疲劳加载(应力水平为 0.36)、各种老化温度(23°C、40°C 和 60°C)和持续时间(30、180 和 360 天)对其残余特性的影响。显微分析用于研究环境老化引起的降解机制。结果表明,环境老化会使 SFCB 外层的 GFRP 基体退化,疲劳载荷会进一步导致基体开裂,降低准静态抗拉强度。SFCB 的残余抗拉强度会随着老化时间或温度的增加而降低,而老化对其疲劳寿命没有明显影响。此外,还提出了一个基于损伤累积的 SFCBs 残余抗拉强度预测模型。根据该模型,抗拉强度最初会随着老化时间的延长而迅速降低,最终趋于稳定。这些发现为 SFCB 在混凝土结构中的应用提供了实用见解。
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引用次数: 0
Quantifying the blending efficiency of warm mix asphalt-synchronous rejuvenated SBS-modified asphalt through a dynamic shear rheometer (DSR) testing approach 通过动态剪切流变仪(DSR)测试方法量化温拌沥青-同步再生 SBS 改性沥青的混合效率
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138183

The degree of blending (DOB), which is controlled by the diffusion between virgin and aged/rejuvenated asphalt binder, has a major impact on the performance of the asphalt mixture incorporated with reclaimed asphalt pavement (RAP). Despite numerous studies investigating the DOB through experimental methods, the blending efficiency of warm mix asphalt (WMA) and synchronous rejuvenated SBS-modified asphalt (SBSMA) is still unexplored. In this study, a dynamic shear rheometer (DSR) testing approach was developed to quantify the blending efficiency of WMA modified SBSMA and synchronous rejuvenated SBSMA. The novelty of this approach lies in the innovative use of a DSR asphalt double-layer structure to determine the DOB in combination with a developed theoretical calculation framework. The individual and synergistic effects of WMA additive and rejuvenator type on the DOB of WMA modified SBSMA-Synchronous rejuvenated SBSMA were investigated, while the influence of blending temperature, blending time, and dosage of aged/rejuvenated SBSMA on the blending efficiency were systemically evaluated. Results indicated that the SBS repairing agent in the synchronous rejuvenator can dramatically increase the DOB, while the presence of WMA additive can further increase the DOB by improving the fluidity of the virgin SBSMA. Furthermore, increasing the blending temperature/blending time and decreasing the dosage of aged/rejuvenated SBSMA were also conducive to enhancing the DOB. In addition, a blending chart of the WMA modified SBSMA-Synchronous rejuvenated SBSMA was developed to facilitate the accurate prediction of the DOB at any given blending temperature and blending time.

掺和度(DOB)由原生沥青胶结料和老化/再生沥青胶结料之间的扩散控制,对掺入再生沥青路面(RAP)的沥青混合料的性能有重大影响。尽管有许多研究通过实验方法对 DOB 进行了调查,但对温拌沥青(WMA)和同步再生 SBS 改性沥青(SBSMA)的混合效率仍未进行探索。本研究开发了一种动态剪切流变仪(DSR)测试方法,用于量化 WMA 改性 SBSMA 和同步再生 SBSMA 的掺混效率。这种方法的新颖之处在于创新性地使用了动态剪切流变仪沥青双层结构,结合已开发的理论计算框架来确定 DOB。研究了 WMA 添加剂和修复剂类型对 WMA 改性 SBSMA-Synchronous rejuvenated SBSMA DOB 的单独效应和协同效应,同时系统评估了混合温度、混合时间和老化/修复 SBSMA 用量对混合效率的影响。结果表明,同步再生剂中的 SBS 修复剂可显著提高 DOB,而 WMA 添加剂的存在可通过改善原始 SBSMA 的流动性进一步提高 DOB。此外,提高混合温度/混合时间和减少老化/再生 SBSMA 的用量也有利于提高 DOB。此外,还开发了 WMA 改性 SBSMA-Synchronous rejuvenated SBSMA 的混合图,以便准确预测任何给定混合温度和混合时间下的 DOB。
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引用次数: 0
Evaluation of chemo-physio-mechanical characteristics of GGBS-MBS-based ready-mix geopolymer under ambient curing condition 环境固化条件下基于 GGBS-MBS 的预拌土工聚合物的化学物理力学特性评估
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138202

This research demonstrates the synthesis of GGBS-based ready-mix (one-part) geopolymer (RMG) utilizing MBS as partial replacement to GGBS (10, 20 and 30 % by-mass) in addition to solid-alkaline reagents (NaOH-flakes and Na2SiO3 powder) using thermal and mechanical treatments, resulting in the formation of “ready-to-use” geopolymer product, “just-add-water” alike cement. The RMG was characterized by analyzing mineral phases, functional-groups identification followed by surface-morphology and elemental analysis at multiple stages, and engineering properties such as setting-time, flowability, compressive strength and ultrasonic-pulse-velocity were evaluated under ambient curing condition. The results show that GGBS-MBS-based RMG has dense morphology, affirming the development of C-S-H and C(N)-A-S-H gels due to its amorphous nature with some crystalline-phases (SiO2) which are in-linked to Si-O-Si and Al-O-Si bonds. The dry-mix of GGBS with powdered-Na2SiO3 and 4 m molality NaOH (Na2SiO3/NaOH=1), pre-heated at 105±5°C for 6 h, followed by 6 h ball-milling with 20 % MBS replacement, achieved the highest 28-day compressive strength of 72.8 MPa, 10 % higher than the referenced mix and had satisfactory UPV results. The RMG not only solves handling problems caused due to concentrated aqueous-alkaline reagents used in two-part geopolymer synthesis but also provides sustainability by utilizing industrial and agricultural waste/by-products, hence reducing Portland cement demand, carbon footprint and waste-disposal issues.

本研究展示了基于 GGBS 的预拌(单组分)土工聚合物(RMG)的合成方法,利用 MBS 作为 GGBS 的部分替代物(10%、20% 和 30%(质量百分比)),再加上固碱试剂(NaOH 片和 Na2SiO3 粉),通过热处理和机械处理,形成 "即用型 "土工聚合物产品,即 "加水型 "类似水泥。通过分析矿物相、官能团鉴定以及表面形态和元素分析等多个阶段对 RMG 进行了表征,并在常温固化条件下对凝结时间、流动性、抗压强度和超声波脉冲速度等工程特性进行了评估。结果表明,基于 GGBS-MBS 的 RMG 具有致密的形态,肯定了 C-S-H 和 C(N)-A-S-H 凝胶的发展,这是因为其无定形性质中含有一些晶相(SiO2),这些晶相与 Si-O-Si 和 Al-O-Si 键相连。GGBS 与粉末状 Na2SiO3 和 4 m 摩尔 NaOH(Na2SiO3/NaOH=1)的干混料在 105±5°C 下预热 6 小时,然后进行 6 小时球磨,MBS 替代率为 20%,28 天抗压强度最高,达到 72.8 MPa,比参考混合物高 10%,UPV 结果也令人满意。RMG 不仅解决了双组分土工聚合物合成中使用的高浓度水碱试剂造成的处理问题,还通过利用工业和农业废物/副产品实现了可持续发展,从而减少了对波特兰水泥的需求、碳足迹和废物处置问题。
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引用次数: 0
Direct tensile failures of concrete with various moisture contents and sizes at low temperatures via mesoscale simulations with ice explicit modelling 通过冰显性建模的中尺度模拟,分析不同含水率和尺寸的混凝土在低温条件下的直接拉伸破坏情况
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138300

The enhancement of mechanical properties of concrete meso-components and the interaction caused by non-uniform deformation as well as phase change can cause significant changes in the macro-mechanical performances of concrete at low temperatures. Based on the action mechanism of the above low-temperature effect, this paper established a thermal-mechanical sequential coupled simulation method with explicit modelling of pore ice at the mesoscale level to quantitatively investigate the direct tensile failures and the corresponding size effect of concrete with four structural sizes (D75, D150, D225 and D300) and three moisture contents (2.0 %, 4.0 % and 6.0 %) at different temperatures (20, −30, −60 and −90°C), in term of failure mode, deformation curve, peak strength and residual strength. The numerical results show that the direct tensile peak strength performs an obvious low-temperature enhancement effect due to the more damaged aggregates and more areas being in a state of multi-axial stress caused by low-temperature non-uniform stress field. However, with the decreasing temperature, the residual strength shows a decrease trend and the trend slows down with the increasing moisture content. Besides, as the temperature drops from 20°C to −90°C, both the size effects on direct tensile peak strength and residual strength are strengthened (with the increase approaches nearly 200 % for peak strength while 33 % for residual strength). Finally, a modified size effect theoretical model was developed considering the quantitative coupling effects of low temperature and moisture content. The present research results can provide a reference for the performance evaluation and safe design of large-sized concrete exposed to low-temperature environments.

混凝土中观构件力学性能的提高以及非均匀变形和相变引起的相互作用,会使混凝土在低温下的宏观力学性能发生显著变化。基于上述低温效应的作用机理,本文建立了一种热力-力学顺序耦合模拟方法,并在中尺度水平上对孔隙冰进行了显式建模,定量研究了四种结构尺寸(D75、D150、D225 和 D300)和三种含水率(2.0 %、4.0 % 和 6.0 %),在不同温度(20、-30、-60 和 -90°C)下的破坏模式、变形曲线、峰值强度和残余强度。数值结果表明,由于低温非均匀应力场导致更多聚集体受损,更多区域处于多轴应力状态,直接拉伸峰值强度具有明显的低温增强效应。然而,随着温度的降低,残余强度呈下降趋势,且随着含水量的增加,下降趋势放缓。此外,当温度从 20°C 降到 -90°C 时,尺寸效应对直接拉伸峰值强度和残余强度的影响都会加强(峰值强度增加近 200%,残余强度增加 33%)。最后,考虑到低温和含水量的定量耦合效应,建立了一个修正的尺寸效应理论模型。本研究成果可为暴露在低温环境中的大体积混凝土的性能评估和安全设计提供参考。
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引用次数: 0
Influence of CO2 curing on mechanical properties and microstructure of hydrated magnesium silicate 二氧化碳固化对水合硅酸镁机械性能和微观结构的影响
IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-09-12 DOI: 10.1016/j.conbuildmat.2024.138313

Hydrated magnesium silicate (M-S-H) samples with good fluidity of 270 mm were prepared. The mechanical properties of the M-S-H samples cured in CO2 conditions were examined. Moreover, the M-S-H samples under 70 % RH wet curing and standard curing conditions were prepared as comparison samples. As a result, the mechanical properties of the M-S-H samples under CO2 curing conditions significantly improved. Compared to the M-S-H samples under 70 % RH wet curing and standard curing conditions, the 28-day compressive strength of the samples under CO2 curing conditions was increased by 116.83 % and 74.25 %, respectively. Additionally, the microstructure of the M-S-H samples under the three curing conditions was investigated using XRD, SEM-EDS, TG/DSC, FTIR, and pore structure analysis. The results revealed that brucite reacted with CO2 to form nesquehornite under CO2 curing conditions. Furthermore, the volume stability of M-S-H was greatly affected by humidity, exhibiting expansion under standard curing and strong shrinkage under 70 % RH wet curing, while CO2 curing can attenuate the shrinkage of the M-S-H samples.

制备了流动性良好的 270 毫米水合硅酸镁(M-S-H)样品。研究了在二氧化碳条件下固化的 M-S-H 样品的机械性能。此外,还制备了 70 % RH 湿固化和标准固化条件下的 M-S-H 样品作为对比样品。结果表明,在二氧化碳固化条件下 M-S-H 样品的机械性能明显提高。与 70 % RH 湿固化和标准固化条件下的 M-S-H 样品相比,二氧化碳固化条件下样品的 28 天抗压强度分别提高了 116.83 % 和 74.25 %。此外,还使用 XRD、SEM-EDS、TG/DSC、傅立叶变换红外光谱和孔隙结构分析法研究了三种固化条件下 M-S-H 样品的微观结构。结果表明,在二氧化碳固化条件下,青金石与二氧化碳反应生成了黑云母。此外,M-S-H 的体积稳定性受湿度影响很大,在标准固化条件下会出现膨胀,而在 70 % RH 湿固化条件下会出现强烈收缩,而 CO2 固化则可减轻 M-S-H 样品的收缩。
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引用次数: 0
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Construction and Building Materials
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