Coordination Chemistry Reviews最新文献_第8页

In vivo NIR-II fluorescence imaging based on microscopy set-ups: probes, set-ups, bioimaging and bioanalysis applications 基于显微镜装置的体内NIR-II荧光成像：探针，装置，生物成像和生物分析应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-19 DOI: 10.1016/j.ccr.2026.217598

Yanling Yang , Hongxin Zhang , Zhen Yang , Wei Huang

The emerging second near-infrared (NIR-II, 1000–2300 nm) fluorescence imaging based on microscopy set-ups (NIR-II FLI MS) has been proven to enable real-time tracking of dynamic physiological processes and facilitate the reconstruction of clear two- and three-dimensional morphological images of living tissues, which can offer high signal-to-background ratio and imaging contrast of live tissues at the cellular level. Focusing on the significant role of NIR-II FLI MS in intravital imaging and bioanalysis, in this contribution, we begin with the performance trade-off between NIE-II fluorescence probes and microscopy set-ups, focused on specific requirements for fluorescent probes across different NIR-II FLI MS modalities and feasible strategies to enhance their optical performances of the different NIR-II probes. Subsequently, we summarize recent advances in NIR-II microscopy set-ups, with an emphasis on the operational principles and specific requirements of wide-field, confocal, and light-sheet systems for high-performance in vivo detection. The cutting-edged applications of these probes and set-ups for in vivo NIR-II FLI MS is also discussed in detail. Finally, we provide a comprehensive and interdisciplinary analysis of the enduring challenges and prospective directions within this field, aiming to inspire further development of novel NIR-II high-performance probes and microscopy technologies for advanced intravital detection and facilitate the transition of in vivo NIR-II FLI MS from “technology-driven” to “science-driven”.

基于显微镜装置的第二种近红外（NIR-II, 1000-2300 nm）荧光成像技术（NIR-II FLI MS）已被证明能够实时跟踪动态生理过程，并有助于重建清晰的活体组织二维和三维形态学图像，可以在细胞水平上提供高信本比和成像对比度的活体组织。关注NIR-II FLI质谱在生命成像和生物分析中的重要作用，在本贡献中，我们从NIR-II荧光探针和显微镜设置之间的性能权衡开始，重点关注不同NIR-II FLI质谱模式下荧光探针的具体要求以及提高不同NIR-II探针光学性能的可行策略。随后，我们总结了NIR-II显微镜装置的最新进展，重点介绍了用于高性能体内检测的宽视场、共聚焦和光片系统的工作原理和具体要求。这些探针和设置在体内NIR-II FLI质谱的尖端应用也进行了详细的讨论。最后，我们对该领域的长期挑战和前景方向进行了全面的跨学科分析，旨在启发新型NIR-II高性能探针和显微技术的进一步发展，以实现先进的活体检测，并促进体内NIR-II FLI质谱从“技术驱动”向“科学驱动”的转变。

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引用次数: 0

Solid-state photoswitches based on excited-state intramolecular proton transfer 基于激发态分子内质子转移的固态光开关

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-18 DOI: 10.1016/j.ccr.2026.217589

Yahui Chen , Wenjing Wang , Xin He , Yaqian Huang , Huofeng Cen , Mingle Li , Hao Gu , Xiaoqiang Chen , Juyoung Yoon , Xiaojun Peng

Solid-state photoswitches based on excited-state intramolecular proton transfer (ESIPT) have attracted extensive research interest due to their unique photophysical properties and broad potential in functional smart materials. This review provides a comprehensive overview of recent advances in ESIPT-based photoswitches, with a primary focus on imine derivatives, hydrazone derivatives, and other emerging photoresponsive systems. Particular emphasis is placed on their molecular design strategies, mechanistic insights, and solid-state photochromic behaviors, as well as the associated structure-property relationships. The fundamental principles of ESIPT processes are discussed, followed by molecular engineering strategies aimed at enhancing photoisomerization efficiency, controlling excited-state dynamics, and tuning emission characteristics through conformational modulation. Representative applications, including information encryption and optical data storage, ultraviolet sensing, ferroelectric and optoelectronic materials, molecular machines, flexible photonic devices, and crystal actuators, are systematically summarized. Moreover, current challenges such as achieving high switching contrast, improving photofatigue resistance, and enriching optical outputs are critically examined, along with emerging strategies to overcome these limitations. This review aims to provide new insights and perspectives to inspire the rational design of next-generation solid-state ESIPT photoswitches for advanced functional materials.

基于激发态分子内质子转移（ESIPT）的固态光开关由于其独特的光物理性质和在功能智能材料中的广阔潜力而引起了广泛的研究兴趣。本文综述了基于esipt的光开关的最新进展，主要集中在亚胺衍生物，腙衍生物和其他新兴的光响应系统。特别强调的是他们的分子设计策略，机理见解，固态光致变色行为，以及相关的结构-性质关系。讨论了ESIPT过程的基本原理，然后介绍了旨在提高光异构化效率、控制激发态动力学和通过构象调制调节发射特性的分子工程策略。系统总结了信息加密和光数据存储、紫外传感、铁电和光电子材料、分子机器、柔性光子器件、晶体致动器等具有代表性的应用。此外，当前的挑战，如实现高开关对比度，提高光疲劳抗性，丰富的光输出严格审查，以及新兴的策略来克服这些限制。本文旨在为新一代先进功能材料固态ESIPT光开关的合理设计提供新的见解和视角。

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引用次数: 0

A green strategy for sustainable water treatment: performance and applications of MOF@wood composites 可持续水处理的绿色策略：MOF@wood复合材料的性能和应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-17 DOI: 10.1016/j.ccr.2026.217599

Xin Zhou , Yixuan Song , Xu Wang , Dan Zou , Shaohua Jiang , Qingfeng Sun , Xiaofan Ma

MOF@wood composites represent an emerging class of high-performance materials for water purification, combinating the unique adsorption properties of metal-organic frameworks (MOFs) and hierarchical pore structure of wood. MOFs contribute exceptionally high specific surface area and adsorption capacity, while wood provides a renewable substrate with a hierarchical porous structure, excellent mechanical strength, and surface functionalizability. The bonding strength of MOF@wood composite is significantly enhanced through chemical bonding between functional groups (e.g., hydroxyl and carboxyl groups) in the wood cell wall and those in the MOFs. MOF@wood composites exhibit significant synergistic advantages in water treatment. The multi-level pore structure of wood acts as an ideal carrier, enabling uniform dispersion and stable anchoring of MOF particles, thereby effectively preventing their agglomeration. Simultaneously, wood's interconnected channels facilitate low-resistance water transport, significantly enhancing the contact efficiency between pollutants and the active sites on the MOFs. This review comprehensively summarizes recent advances in MOF@wood composites, focusing on their applications in oil-water separation, removal of antibiotics, pharmaceuticals, dyes, and heavy metal ions, as well as their use in water evaporators for purification. Finally, the future development prospects were discussed, current challenges such as the need to achieve scalable manufacturing processes and improve long-term stability were identified, and directions for subsequent research were proposed.

MOF@wood复合材料代表了一种新兴的高性能水净化材料，结合了金属有机框架（MOFs）独特的吸附性能和木材的分层孔结构。mof具有极高的比表面积和吸附能力，而木材提供了具有分层多孔结构、优异机械强度和表面功能化的可再生基板。通过木材细胞壁中官能团（如羟基和羧基）与mof中的官能团之间的化学键合，MOF@wood复合材料的键合强度显著增强。MOF@wood复合材料在水处理中表现出显著的协同优势。木材的多层孔隙结构是理想的载体，可以使MOF颗粒均匀分散，稳定锚定，有效防止MOF颗粒团聚。同时，木材相互连接的通道促进了低阻力的水输送，显著提高了污染物与mof上活性位点之间的接触效率。综述了MOF@wood复合材料的研究进展，重点介绍了MOF@wood复合材料在油水分离、抗生素、药物、染料、重金属离子去除、蒸发器净化等方面的应用。最后，讨论了未来的发展前景，指出了当前面临的挑战，如需要实现可扩展的制造工艺和提高长期稳定性，并提出了后续的研究方向。

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引用次数: 0

Micro- and nanorobots for intelligent bone tissue engineering 用于智能骨组织工程的微纳米机器人

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-17 DOI: 10.1016/j.ccr.2026.217593

Zelin Ai , Yan Wei , Jiatao Zhang , Jinhua Li

The repair of bone defects presents a significant challenge in balancing material properties with biocompatibility. While traditional materials such as alloys are widely used, they still exhibit limitations in mechanical adaptability, osseointegration capacity, and imaging interference. In recent years, the integration of biodegradable materials and 3D printing technology has provided novel approaches for personalized bone repair, however, the implantation of these scaffolds often requires open surgery, which causes pain for patients, increases the risk of infection, and prolongs healing time. In this context, the micro- and nanorobots (MNRs) can offer groundbreaking opportunities for precision bone tissue engineering in a minimally invasive or even non-invasive manner owing to their unique advantages such as tiny size, precise delivery, and dynamic modulation capabilities. This article focuses on the application potential of MNRs in bone repair, systematically examining their design prerequisites: achieving targeted movement within the tubular structures (such as blood vessels and lymph vessels), cavity structures (such as marrow cavity and articular cavity), and defect space (such as fractures and osteoporosis) in the bone tissue, and analyzing their material selection, propulsion mechanisms, and real-time monitoring strategies. Furthermore, we review recent advances in MNRs-assisted bone defect regeneration, bone infection control, and bone tumor therapy, highlighting their advantages in modulating the local bone microenvironment through the delivery of growth factors, stem cells, or therapeutic agents. Finally, we summarize current technological bottlenecks and propose interdisciplinary solutions to address these challenges. The prospects of MNRs in dynamic repair and regenerative medicine are also discussed. Our goal is to provide a comprehensive reference and offer guidance for rationally designing versatile MNRs for advanced bone tissue engineering, thereby bridging the gap between tiny active MNRs and traditional bone tissue engineering by making full use of the anatomical structures of healthy bones and the abnormal structures of diseased or injured bones.

骨缺损的修复在平衡材料性能和生物相容性方面提出了重大挑战。虽然合金等传统材料被广泛使用，但它们在机械适应性、骨整合能力和成像干扰方面仍然存在局限性。近年来，生物可降解材料与3D打印技术的结合为个性化骨修复提供了新的途径，但这些支架的植入往往需要开放性手术，给患者带来疼痛，增加感染风险，延长愈合时间。在这种情况下，微型和纳米机器人（MNRs）由于其独特的优势，如微小的尺寸、精确的输送和动态调制能力，可以为微创甚至非侵入性的精密骨组织工程提供开创性的机会。本文重点探讨了微磁共振在骨修复中的应用潜力，系统考察了其设计前提条件：在骨组织的管状结构（如血管和淋巴管）、腔状结构（如骨髓腔和关节腔）和缺陷空间（如骨折和骨质疏松症）内实现定向运动，并分析了其材料选择、推进机制和实时监测策略。此外，我们回顾了mnmr辅助骨缺损再生、骨感染控制和骨肿瘤治疗的最新进展，强调了它们在通过递送生长因子、干细胞或治疗剂来调节局部骨微环境方面的优势。最后，我们总结了当前的技术瓶颈，并提出了跨学科的解决方案来应对这些挑战。并对纳米核磁共振在动态修复和再生医学中的应用前景进行了展望。我们的目标是充分利用健康骨骼的解剖结构和患病或损伤骨骼的异常结构，为高级骨组织工程合理设计多功能磁阻器提供全面的参考和指导，从而弥合微型活性磁阻器与传统骨组织工程之间的差距。

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引用次数: 0

Corrigendum to “Physical stimulus-triggered dynamic therapy based on two-dimensional sensitizers” [Coord. Chem. Rev. 549 (2026) 217315] “基于二维致敏剂的物理刺激触发的动态疗法”的勘误表[Coord. Chem.]。Rev. 549 (2026) 217315]

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-17 DOI: 10.1016/j.ccr.2026.217591

Yao Zhu , Albert Yu , Zihan Lv , Yue Wang , Zhongjian Xie

引用次数: 0

Cooperative, anti-cooperative, and synergistic supramolecular interactions mediate self-organization of self-assembling dendrons, dendrimers, and dendronized macromolecules 合作、反合作和协同的超分子相互作用介导自组装树突、树突大分子和树突化大分子的自组织

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-17 DOI: 10.1016/j.ccr.2026.217588

Virgil Percec , Dipankar Sahoo , Devendra S. Maurya , Jasper Adamson

After a brief discussion of the discovery of covalent and self-organizable dendrons, dendrimers, and dendronized macromolecules, examples of cooperative, anti-cooperative and synergistic supramolecular-interactions mediating self-assembly and self-organization of supramolecular dendrimers will be presented. Dendronized crown-ethers will be used to demonstrate these interactions generated by cation-dipole, π–π stacking, H-bonding, fluorination, the specialty of Professor Giuseppe Resnati celebrated with this occasion, and covalent macromolecular interactions. It will be demonstrated that fluorination of self-assembling dendrons generates a simple approach to dendronized donors and acceptors and of their donor-acceptor complexes. The evolution of helical chirality from its discovery in tobacco mosaic virus-like supramolecular dendrimers to helical-globular-dendrimers producing chiral Frank-Kasper and quasicrystal periodic and quasiperiodic arrays will be highlighted. Helical Aquaporin-like transmembrane proteins and spherical containers will be assembled from dendritic dipeptides by a combination of H-bonding and aromatic π–π interactions. The work of Giulio Natta will be honored by a discussion of the dendronized helical stereoisomers of poly(phenylacetylene) and their intramolecular electrocyclization. Polymer chemistry will be employed as a tool to support the quasi-equivalence of self-assembling dendrons and elaborate their shape inversion from helical spheres to helical columns. Helical supramolecular dendrimers induce a helical conformation into atactic-polymer backbones, a dream which even Giulio Natta could not think of. Hydrophobic, H-bonding and ion-ion interactions generated self-assembling amphiphilic Janus dendrimers and glycodendrimers which mimic cell membranes, their glycans, and provide one-component multifunctional sequence-defined ionizable amphiphilic Janus dendrimers which target the delivery of mRNA to specific organs for stable vaccines and therapeutics.

在简要讨论了共价和自组织树突、树突大分子和树突大分子的发现之后，将介绍协同、反协同和协同超分子相互作用介导超分子树突自组装和自组织的例子。树突冠醚将用于演示阳离子偶极子、π -π堆叠、氢键、氟化（Giuseppe Resnati教授的专业）和共价大分子相互作用产生的相互作用。将证明，自组装树突的氟化产生了一种简单的方法来研究树突化的供体和受体及其供体-受体复合物。从烟草花叶病毒样超分子树状大分子中发现螺旋手性到产生手性Frank-Kasper和准晶体周期和准周期阵列的螺旋-球形树状大分子的演变将被重点介绍。螺旋水通道蛋白样跨膜蛋白和球形容器将由树突状二肽通过氢键和芳香π -π相互作用组合而成。Giulio Natta的工作将通过对聚（苯乙炔）的枝状螺旋立体异构体及其分子内电环化的讨论而得到表彰。高分子化学将作为一种工具来支持自组装树突的准等效性，并阐述它们从螺旋球体到螺旋柱的形状转换。螺旋状的超分子树状大分子诱导成无链聚合物骨架的螺旋构象，这是连朱利奥·纳塔都无法想象的梦想。疏水、氢键和离子相互作用产生自组装的两亲性Janus树状大分子和糖状树状大分子，它们模拟细胞膜及其聚糖，并提供单组分多功能序列定义的可电离的两亲性Janus树状大分子，其目标是将mRNA递送到特定器官，用于稳定的疫苗和治疗。

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引用次数: 0

Small-molecule fluorescent probes for sulfur redox biology in oxidative stress 氧化应激中硫氧化还原生物学的小分子荧光探针

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-17 DOI: 10.1016/j.ccr.2026.217597

Jie Zhang , Xing Wei , Yong Deng , Xiaofeng Wu , Wei Chen

Oxidative stress, driven by redox imbalance, is a pivotal pathological process underpinning major diseases such as cancer, neurodegenerative disorders, and cardiovascular conditions. Reactive sulfur species (RSS) and sulfur-related proteins serve as central regulators within this network, yet their real-time monitoring remains challenging due to low abundance and high reactivity. Small-molecule fluorescent probes, with their high spatiotemporal resolution and biocompatibility, have emerged as indispensable tools for elucidating sulfur redox biology in living systems. This review systematically summarizes recent advances in the rational design and biological applications of fluorescent probes for RSS and sulfur-related proteins, with a dedicated focus on oxidative stress models-including cellular damage, inflammation, and in vivo disease models. We critically analyze probe mechanisms, performance metrics, and translational potential, while highlighting pioneering studies that link RSS and sulfur-related proteins fluctuations to disease pathogenesis. Furthermore, we identify key challenges such as limited tissue penetration, irreversible detection schemes, and the need for reversible/real-time monitoring. By integrating chemical, biological, and medical perspectives, this work not only provides a comprehensive resource for researchers but also outlines future directions for probe development and therapeutic innovation in redox-related diseases

氧化应激由氧化还原失衡驱动，是癌症、神经退行性疾病和心血管疾病等重大疾病的关键病理过程。活性硫物质（RSS）和硫相关蛋白在该网络中起着中心调节作用，但由于其丰度低且反应性高，因此对其进行实时监测仍然具有挑战性。小分子荧光探针具有高时空分辨率和生物相容性，已成为阐明生命系统中硫氧化还原生物学不可缺少的工具。本文系统总结了RSS和硫相关蛋白荧光探针的合理设计和生物学应用的最新进展，重点关注氧化应激模型，包括细胞损伤、炎症和体内疾病模型。我们批判性地分析探针机制、性能指标和转化潜力，同时强调将RSS和硫相关蛋白波动与疾病发病机制联系起来的开创性研究。此外，我们确定了关键挑战，如有限的组织穿透，不可逆检测方案，以及对可逆/实时监测的需求。通过整合化学、生物学和医学的观点，这项工作不仅为研究人员提供了全面的资源，而且还概述了氧化还原相关疾病的探针开发和治疗创新的未来方向

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引用次数: 0

Stable and isolable carbanions: synthesis, chemical bonding, and unique applications 稳定和可分离的碳离子：合成，化学键和独特的应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-16 DOI: 10.1016/j.ccr.2025.217522

Hikaru Yanai

Carbanions were widely regarded as unstable and highly reactive species. However, in fact, the first example of stable and isolable carbanion-containing salts was reported more than 120 years ago. Recent research of stable carbanions endowed a renewed context such as carbanionic “substituents” for tuning the physicochemical properties of organic materials. In addition, unique electronic and geometric structures of the anionic carbon atom enable to be used as ionic liquids, polymer materials, and electrolytes. This review summarises notable recent advances in stable carbanions, covering their synthetic methodologies, chemical bonding behaviour, coordination chemistry, and emerging applications. In particular, carbanions stabilised by cyano, fluorinated sulfonyl, and phosphonio groups are discussed.

碳离子被广泛认为是一种不稳定的高活性物质。然而，事实上，第一个稳定和可分离的含碳盐的例子是在120多年前报道的。近年来对稳定碳离子的研究为调整有机材料的物理化学性质提供了新的背景，例如碳离子“取代基”。此外，阴离子碳原子独特的电子和几何结构使其可以用作离子液体、聚合物材料和电解质。本文综述了近年来稳定碳的研究进展，包括稳定碳的合成方法、化学键行为、配位化学和新兴应用。特别讨论了氰基、氟化磺酰基和膦基稳定的碳离子。

引用次数: 0

Molecular devices based on the mechanical bond: recent advances 基于机械键的分子装置：最新进展

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-14 DOI: 10.1016/j.ccr.2026.217583

Leonardo Andreoni , Chiara Taticchi , Brian Sachini , Alberto Credi

The bottom-up construction and operation of nanoscale devices – namely, multicomponent (supra)molecular architectures capable of performing functions beyond the reach of their individual components – constitute a central focus in nanoscience and a compelling challenge in nanotechnology. Over the past three decades, the development of artificial molecular devices, including molecular machines and motors, has continuously stimulated the creativity of chemists, and the field continues to evolve at a remarkable pace. Among the strategies employed, the mechanical bond has emerged as a particularly powerful means of connecting molecular components to build functional systems. Mechanically interlocked molecules uniquely combine the robustness of covalent frameworks with the dynamic properties of non-covalent assemblies. Moreover, the precise modulation of steric and electronic interactions between mechanically bonded components offers rich opportunities for the emergence of novel functions. Recent advances in the design and synthesis of rotaxanes, catenanes and related interlocked structures have enabled the construction and operation of increasingly complex molecular devices and materials, many of which are capable of executing well-defined tasks. In this review, we present selected examples – classified according to their functional outputs – that exemplify the progress and potential of this rapidly developing area over the past decade.

纳米器件自下而上的构建和操作——即多组分（supra）分子结构，能够执行超出其单个组分所能达到的功能——构成了纳米科学的中心焦点，也是纳米技术的一个引人注目的挑战。在过去的三十年里，包括分子机器和马达在内的人工分子装置的发展不断激发着化学家的创造力，这一领域继续以惊人的速度发展。在所采用的策略中，机械键已成为连接分子组分以构建功能系统的一种特别强大的手段。机械互锁分子独特地结合了共价框架的鲁棒性和非共价组件的动态特性。此外，机械键合组件之间的空间和电子相互作用的精确调制为新功能的出现提供了丰富的机会。轮烷、链烷和相关联锁结构的设计和合成的最新进展使越来越复杂的分子器件和材料的构建和操作成为可能，其中许多能够执行明确定义的任务。在本次审查中，我们提出了一些根据其功能产出分类的例子，这些例子说明了过去十年来这一迅速发展领域的进展和潜力。

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引用次数: 0

Developments of one-dimensional (1D) covalent organic frameworks: A comprehensive review 一维共价有机骨架的研究进展：综述

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2026-01-14 DOI: 10.1016/j.ccr.2025.217558

Jingying Tan , Pengzhong Shi , Ziao Chen , Yanfeng Yue , Zhiyong Guo

CONSPECTUS: As a new type of crystalline porous material, covalent organic frameworks (COFs) have demonstrated remarkable application potential in various fields. However, most current research on COFs concentrated on two-dimensional (2D) and three-dimensional (3D) structures. In contrast, the development of 1D COF which structure extends in only one direction is relatively late and immature. The dual-chain-like edge architecture in 1D COF contributes to the stabilization of aromatic backbones, the enhancement of electronic conjugation, and the reduction of energy loss. This allows the 1D COF to exhibit superior performance compared to 2D COFs in applications such as catalysis and photoelectric/optoelectronic applications. It systematically summarized the synthetic principle of 1D COFs, principle including the topological structure, compositional modular structures, linkage and other derived structures. And then, it briefly discussed the general structure/composition characterization techniques for 1D COFs. Lastly, it outlined the main applications of 1D COFs in heterogenous catalysis, optoelectronic application, energy storage and conversion, sensing application, and selective adsorption. This review also proposed crucial guidance for the future development of 1D COFs.

摘要：共价有机骨架（COFs）作为一种新型的晶体多孔材料，在各个领域都显示出了显著的应用潜力。然而，目前对COFs的研究大多集中在二维（2D）和三维（3D）结构上。相比之下，结构只向一个方向延伸的一维碳纳米管的发展相对较晚和不成熟。一维碳纳米管的双链边缘结构有助于芳香骨架的稳定、电子共轭的增强和能量损失的降低。这使得1D COF在催化和光电/光电应用等应用中表现出优于2D COF的性能。系统总结了一维COFs的合成原理，原理包括拓扑结构、组合模块化结构、连杆结构和其他衍生结构。然后，简要讨论了一维COFs的一般结构/组成表征技术。最后概述了1D COFs在多相催化、光电、储能与转换、传感和选择性吸附等方面的主要应用。本综述还为1D COFs的未来发展提出了重要的指导意见。

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引用次数: 0