Coordination Chemistry Reviews最新文献_第8页

Nano-engineered paper-based electrochemical biosensors: Versatile diagnostic tools for biomarker detection 纳米工程纸基电化学生物传感器：用于生物标记检测的多功能诊断工具

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-08 DOI: 10.1016/j.ccr.2024.216261

Ramalingam Manikandan , Hyeon-Geun Jang , Chang-Seok Kim , Jang-Hee Yoon , Jaewon Lee , Hyun-jong Paik , Seung-Cheol Chang

After the COVID-19 pandemic, the demand for highly sensitive, miniaturized, non-destructive sensing of disease biomarkers has received significant attention. Nanomaterial-coated paper-based electrochemical biosensors were utilized to diagnose various disease biomarkers. Nanomaterials have contributed significantly to electrochemical biosensors advancements because they improve biosensing properties such as specificity, sensitivity, robustness, and reproducibility. Moreover, the viability of environmentally friendly paper-based electrochemical biosensors for the highly sensitive detection of target analytes in complicated samples has improved. Paper-based electrode (PE) substrates are desirable for lab-scale and large-scale manufacturing applications because they are inexpensive, do not require microfluidic pumps because electrolyte migration can be achieved through capillary action, can be stacked with reagents for reagent-less applications, and can achieve multiphase detection via origami-based approaches. Therefore, this review considers the properties of functional nanomaterials, such as the active surface area available for interactions, attachment of biorecognition species to the electrode via microporous capillary action, cellulose conductivity, and photochemical functional properties, and electrochemical properties of carbon-based conductive pastes that are widely used to print sensors onto paper substrates. The conclusions can be used to improve PE biosensors for biomedical research. Recent paper-based electrodes modified with different nanomaterials for detecting various biomarkers are discussed.

COVID-19 大流行之后，对高灵敏度、微型化、非破坏性疾病生物标志物传感的需求受到极大关注。基于纳米材料涂层纸的电化学生物传感器被用来诊断各种疾病生物标记物。纳米材料提高了生物传感特性，如特异性、灵敏度、稳健性和可重复性，因而极大地推动了电化学生物传感器的发展。此外，环保型纸基电化学生物传感器在高灵敏度检测复杂样品中目标分析物方面的可行性也有所提高。纸基电极（PE）基板是实验室规模和大规模生产应用的理想选择，因为它们价格低廉，不需要微流泵，因为电解质迁移可以通过毛细作用实现，可以与试剂堆叠在一起实现无试剂应用，还可以通过折纸方法实现多相检测。因此，本综述考虑了功能纳米材料的特性，如可用于相互作用的活性表面积、生物识别物种通过微孔毛细作用附着到电极上、纤维素的导电性和光化学功能特性，以及广泛用于在纸基底上打印传感器的碳基导电浆料的电化学特性。这些结论可用于改进用于生物医学研究的 PE 生物传感器。本文讨论了最近用不同纳米材料修饰的纸基电极，用于检测各种生物标记物。

{"title":"Nano-engineered paper-based electrochemical biosensors: Versatile diagnostic tools for biomarker detection","authors":"Ramalingam Manikandan , Hyeon-Geun Jang , Chang-Seok Kim , Jang-Hee Yoon , Jaewon Lee , Hyun-jong Paik , Seung-Cheol Chang","doi":"10.1016/j.ccr.2024.216261","DOIUrl":"10.1016/j.ccr.2024.216261","url":null,"abstract":"<div><div>After the COVID-19 pandemic, the demand for highly sensitive, miniaturized, non-destructive sensing of disease biomarkers has received significant attention. Nanomaterial-coated paper-based electrochemical biosensors were utilized to diagnose various disease biomarkers. Nanomaterials have contributed significantly to electrochemical biosensors advancements because they improve biosensing properties such as specificity, sensitivity, robustness, and reproducibility. Moreover, the viability of environmentally friendly paper-based electrochemical biosensors for the highly sensitive detection of target analytes in complicated samples has improved. Paper-based electrode (PE) substrates are desirable for lab-scale and large-scale manufacturing applications because they are inexpensive, do not require microfluidic pumps because electrolyte migration can be achieved through capillary action, can be stacked with reagents for reagent-less applications, and can achieve multiphase detection via origami-based approaches. Therefore, this review considers the properties of functional nanomaterials, such as the active surface area available for interactions, attachment of biorecognition species to the electrode via microporous capillary action, cellulose conductivity, and photochemical functional properties, and electrochemical properties of carbon-based conductive pastes that are widely used to print sensors onto paper substrates. The conclusions can be used to improve PE biosensors for biomedical research. Recent paper-based electrodes modified with different nanomaterials for detecting various biomarkers are discussed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216261"},"PeriodicalIF":20.3,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142384997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An updated overview on nitrogen-rich azole-based gold coordination complexes as potent anticancer agents 富氮唑基金配位复合物作为强效抗癌剂的最新概述

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-07 DOI: 10.1016/j.ccr.2024.216233

Monireh Ghorbanpour , Behzad Soltani

The ability of gold-based complexes in diagnosis and treatment of cancers as the main worldwide health problems, along with the successful clinical reports of bioactive azole-based drugs has attracted high attention from medicinal chemists and increased the significant interest in conducting research of azole-based gold complexes. The present review gives an updated overview of the anticancer potential of nitrogen-rich azole-based gold coordination complexes with the aim of providing an insight into the correlations between the biological activity and chemical structures of these complexes to the achievement of efficient anticancer agents. Comparison of the anticancer potential of these complexes clearly indicates the role of various influencing factors in this case. Selection and designing of suitable ligands and analysis of the structure-activity relationships (SAR) of compounds is the true cornerstone and a key constituent in medicinal chemistry. The geometry of complexes, the oxidation states of the gold centers along with the effect of the donor atoms, the types of ligands and the existence of different groups in the framework of the ligands are the important parameters that determine the final bioactivity of the complexes. The synergic mechanism of action along with combination therapies of them are another approach that can overcome the limitations of some of the approved drugs. These complexes can be efficient in cancer therapy as chemotherapy agents, as photodynamic therapy (PDT) agents and as biomolecule imaging agents. We believe that this review can prompt widespread studies and progress in order to design and synthesize efficient complexes in treatment and diagnosis of cancer. Finding and concluding the molecular mechanism of action and the synergic pathway of the complexes and comparison of the corresponding data can help to the development of efficient anticancer drugs with low toxicity and least side effects with respect to the combination therapy and considering the synergic mechanism of action of them. This review will be interesting for inorganic chemists and specialists in medicinal chemistry about the discovery and development of anticancer drugs.

金配合物在诊断和治疗癌症这一主要的世界性健康问题方面的能力，以及生物活性唑类药物的成功临床报道，引起了药物化学家的高度关注，并增加了人们对唑基金配合物研究的浓厚兴趣。本综述概述了富氮唑基金配位配合物的抗癌潜力，旨在深入探讨这些配合物的生物活性与化学结构之间的相关性，以实现高效抗癌。这些配合物的抗癌潜力比较清楚地表明了各种影响因素在其中的作用。选择和设计合适的配体以及分析化合物的结构-活性关系（SAR）是药物化学的真正基石和关键组成部分。配合物的几何形状、金中心的氧化态以及供体原子的影响、配体的类型和配体框架中不同基团的存在是决定配合物最终生物活性的重要参数。它们的协同作用机制和联合疗法是另一种可以克服某些已批准药物局限性的方法。这些复合物可以作为化疗药物、光动力疗法（PDT）药物和生物分子成像药物有效地用于癌症治疗。我们相信，这篇综述能促进广泛的研究和进步，从而设计和合成高效的复合物，用于癌症的治疗和诊断。发现和总结复合物的分子作用机理和协同途径，并对相应数据进行比较，有助于开发低毒、副作用小的高效抗癌药物，同时考虑到它们之间的协同作用机理。这篇综述对无机化学家和药物化学专家发现和开发抗癌药物很有意义。

{"title":"An updated overview on nitrogen-rich azole-based gold coordination complexes as potent anticancer agents","authors":"Monireh Ghorbanpour , Behzad Soltani","doi":"10.1016/j.ccr.2024.216233","DOIUrl":"10.1016/j.ccr.2024.216233","url":null,"abstract":"<div><div>The ability of gold-based complexes in diagnosis and treatment of cancers as the main worldwide health problems, along with the successful clinical reports of bioactive azole-based drugs has attracted high attention from medicinal chemists and increased the significant interest in conducting research of azole-based gold complexes. The present review gives an updated overview of the anticancer potential of nitrogen-rich azole-based gold coordination complexes with the aim of providing an insight into the correlations between the biological activity and chemical structures of these complexes to the achievement of efficient anticancer agents. Comparison of the anticancer potential of these complexes clearly indicates the role of various influencing factors in this case. Selection and designing of suitable ligands and analysis of the structure-activity relationships (SAR) of compounds is the true cornerstone and a key constituent in medicinal chemistry. The geometry of complexes, the oxidation states of the gold centers along with the effect of the donor atoms, the types of ligands and the existence of different groups in the framework of the ligands are the important parameters that determine the final bioactivity of the complexes. The synergic mechanism of action along with combination therapies of them are another approach that can overcome the limitations of some of the approved drugs. These complexes can be efficient in cancer therapy as chemotherapy agents, as photodynamic therapy (PDT) agents and as biomolecule imaging agents. We believe that this review can prompt widespread studies and progress in order to design and synthesize efficient complexes in treatment and diagnosis of cancer. Finding and concluding the molecular mechanism of action and the synergic pathway of the complexes and comparison of the corresponding data can help to the development of efficient anticancer drugs with low toxicity and least side effects with respect to the combination therapy and considering the synergic mechanism of action of them. This review will be interesting for inorganic chemists and specialists in medicinal chemistry about the discovery and development of anticancer drugs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216233"},"PeriodicalIF":20.3,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142384013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advancements in MXene-based frameworks towards photocatalytic hydrogen production, carbon dioxide reduction and pollutant degradation: Current challenges and future prospects 基于 MXene 的框架在光催化制氢、二氧化碳减排和污染物降解方面的进展：当前挑战与未来展望

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-07 DOI: 10.1016/j.ccr.2024.216226

Zeeshan Ajmal , Asif Hayat , Abdul Qadeer , Yu Zhao , Essam H. Ibrahim , Mahmood ul Haq , Kanwal Iqbal , Mohd Imran , Mohammed Kuku , Iftikhar Hussain , Hamid Ali , Yasin Orooji , John L. Zhou , Teng Ben

The 2D-MXene frameworks (2D-MXene) comprising transition metal carbide, nitride, is regarded next generation advanced material, that have procured significant courtesy owing to their incredible characteristic of highly ordered framework, controllable structure, large surface area, along with ample surface functional groups. As, practical application of MXene in most research fields is still at up grading phase owing to their relatively rare surface-active site, low stability and structural configuration for photocatalytic reaction.The substantial research has been devoted to maximize their advantages and mitigate the shortcomings of 2D-MXene for photocatalysis. Thus, thanks to the progress of various kinds of MXene preparation strategies, now researcher could easily understand the weakness behind every step of MXene synthesis with accurate morphology and tunable characteristics for numerous applications. Besides, MXene with improved structure and up-to-date information regarding potential application in photocatalytic hydrogen evolution (PHE), photocatalytic carbon reduction (PCR) and photocatalytic pollutant degradation (PPD) along with key drawbacks and potential solutions is not sufficiently summarized in literature yet. By keeping in view these facts, this review article investigated the background, structural information, brief timeline of its progress, and notabl milestone in its synthesis with tunable properties to get better understanding about their PHE, PCR and PPD properties. In which, the role of MXene as a photocatalyst, along with different types of MXene (0D, 1D, 2D, 3D) is discussed in detail. Finally, the current challenges and their future recommendation on developing high performance MXene to improve photocatalytic activity, is discussed in this review. Hence, our review will open a new understanding in a sustaianble way to facilitate the discovery and application of MXene based photocatalyst to improve photocatalyticapplication.

由过渡金属碳化物和氮化物组成的二维-MXene 框架（2D-MXene）被认为是下一代先进材料，由于其高度有序的框架、可控的结构、较大的比表面积以及丰富的表面官能团等令人难以置信的特性而备受青睐。但由于二维氧化铝的表面活性位点相对稀少、稳定性较低以及光催化反应的结构构造等原因，其在大多数研究领域的实际应用仍处于提升阶段。因此，得益于各种 MXene 制备策略的进步，现在研究人员很容易理解 MXene 合成的每一步背后的弱点，其精确的形态和可调的特性可用于多种应用。此外，文献中还没有充分总结改良结构的 MXene 在光催化氢进化（PHE）、光催化碳还原（PCR）和光催化污染物降解（PPD）中的潜在应用、主要缺点和潜在解决方案的最新信息。有鉴于此，这篇综述文章对其背景、结构信息、发展简史以及可调特性合成过程中的重要里程碑进行了研究，以便更好地了解其 PHE、PCR 和 PPD 特性。其中，详细讨论了 MXene 作为光催化剂的作用以及不同类型的 MXene（0D、1D、2D、3D）。最后，本综述还讨论了开发高性能 MXene 以提高光催化活性的当前挑战和未来建议。因此，我们的综述将以一种可持续的方式开启一种新的认识，以促进基于 MXene 的光催化剂的发现和应用，从而改善光催化应用。

{"title":"Advancements in MXene-based frameworks towards photocatalytic hydrogen production, carbon dioxide reduction and pollutant degradation: Current challenges and future prospects","authors":"Zeeshan Ajmal , Asif Hayat , Abdul Qadeer , Yu Zhao , Essam H. Ibrahim , Mahmood ul Haq , Kanwal Iqbal , Mohd Imran , Mohammed Kuku , Iftikhar Hussain , Hamid Ali , Yasin Orooji , John L. Zhou , Teng Ben","doi":"10.1016/j.ccr.2024.216226","DOIUrl":"10.1016/j.ccr.2024.216226","url":null,"abstract":"<div><div>The 2D-MXene frameworks (2D-MXene) comprising transition metal carbide, nitride, is regarded next generation advanced material, that have procured significant courtesy owing to their incredible characteristic of highly ordered framework, controllable structure, large surface area, along with ample surface functional groups. As, practical application of MXene in most research fields is still at up grading phase owing to their relatively rare surface-active site, low stability and structural configuration for photocatalytic reaction.The substantial research has been devoted to maximize their advantages and mitigate the shortcomings of 2D-MXene for photocatalysis. Thus, thanks to the progress of various kinds of MXene preparation strategies, now researcher could easily understand the weakness behind every step of MXene synthesis with accurate morphology and tunable characteristics for numerous applications. Besides, MXene with improved structure and up-to-date information regarding potential application in photocatalytic hydrogen evolution (PHE), photocatalytic carbon reduction (PCR) and photocatalytic pollutant degradation (PPD) along with key drawbacks and potential solutions is not sufficiently summarized in literature yet. By keeping in view these facts, this review article investigated the background, structural information, brief timeline of its progress, and notabl milestone in its synthesis with tunable properties to get better understanding about their PHE, PCR and PPD properties. In which, the role of MXene as a photocatalyst, along with different types of MXene (0D, 1D, 2D, 3D) is discussed in detail. Finally, the current challenges and their future recommendation on developing high performance MXene to improve photocatalytic activity, is discussed in this review. Hence, our review will open a new understanding in a sustaianble way to facilitate the discovery and application of MXene based photocatalyst to improve photocatalyticapplication.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216226"},"PeriodicalIF":20.3,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142383780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Graphene quantum dots as nanotherapeutic agents for triple-negative breast cancer: Insights from 3D tumor models 石墨烯量子点作为三阴性乳腺癌的纳米治疗剂：三维肿瘤模型的启示

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-07 DOI: 10.1016/j.ccr.2024.216247

Mohammad Suhaan Dar , Pitcheri Rosaiah , Jarsangi Bhagyalakshmi , Satyaprakash Ahirwar , Ahmaduddin Khan , Ramasamy Tamizhselvi , Vasudeva Reddy Minnam Reddy , Arunkumar Palaniappan , Niroj Kumar Sahu

Chemotherapy is a fundamental modality in the treatment of breast cancer (BC), employed across both early and advanced stages. Triple-negative breast cancer (TNBC), known for its aggressive behavior and propensity for metastasis, presents significant treatment challenges due to its resistance to standard chemotherapeutic approaches. Identifying molecular targets for TNBC is imperative, especially in the absence of specifically targeted drugs and given the generally poor prognosis of the disease. Although nanomedicine has substantially grown, incorporating a variety of clinical applications, challenges such as dose-limiting toxicities and limited patient response rates continue to hinder its broader application. Over the past decade, graphene quantum dots (GQDs) have emerged as a promising category of luminescent materials, characterized by their outstanding optoelectronic properties, and their highly tunable structures and surface functionalities. These attributes make GQDs ideal candidates as drug carriers, facilitating straightforward functionalization, heightened chemotherapy sensitivity, and substantial drug loading capacities. This review provides a thorough exploration of recent advancements in GQDs applied to BC, with a specific focus on TNBC. It delves into the dynamics of breast cancer, emphasizing the diagnostic and therapeutic challenges of TNBC and the innovative potential of GQDs in this context. Furthermore, it discusses various GQD-based therapeutic strategies that hold promise for enhancing outcomes in breast cancer treatment, potentially leading to transformative advancements in the management of TNBC. Additionally, this review incorporates insights from three-dimensional (3D) tumor models, offering a comprehensive perspective on GQD-mediated interventions in breast cancer therapy.

化疗是治疗乳腺癌（BC）的基本方法，可用于早期和晚期乳腺癌的治疗。三阴性乳腺癌（TNBC）以其侵袭性和转移倾向而闻名，由于其对标准化疗方法的耐药性，给治疗带来了巨大挑战。鉴别 TNBC 的分子靶点势在必行，尤其是在缺乏特异性靶向药物以及该疾病预后普遍较差的情况下。虽然纳米医学已取得了长足的发展，纳入了多种临床应用，但剂量限制毒性和有限的患者反应率等挑战仍阻碍着纳米医学的广泛应用。在过去十年中，石墨烯量子点（GQDs）已成为一类前景广阔的发光材料，其特点是具有出色的光电特性、高度可调的结构和表面功能。这些特性使 GQDs 成为药物载体的理想候选材料，有利于直接功能化、提高化疗敏感性和药物负载能力。本综述深入探讨了将 GQDs 应用于乳腺癌的最新进展，并特别关注 TNBC。它深入探讨了乳腺癌的动态变化，强调了 TNBC 在诊断和治疗方面的挑战以及 GQDs 在这方面的创新潜力。此外，它还讨论了各种基于 GQD 的治疗策略，这些策略有望提高乳腺癌的治疗效果，从而有可能在 TNBC 的管理方面取得变革性进展。此外，这篇综述还纳入了三维（3D）肿瘤模型的见解，为 GQD 介导的乳腺癌治疗干预提供了一个全面的视角。

{"title":"Graphene quantum dots as nanotherapeutic agents for triple-negative breast cancer: Insights from 3D tumor models","authors":"Mohammad Suhaan Dar , Pitcheri Rosaiah , Jarsangi Bhagyalakshmi , Satyaprakash Ahirwar , Ahmaduddin Khan , Ramasamy Tamizhselvi , Vasudeva Reddy Minnam Reddy , Arunkumar Palaniappan , Niroj Kumar Sahu","doi":"10.1016/j.ccr.2024.216247","DOIUrl":"10.1016/j.ccr.2024.216247","url":null,"abstract":"<div><div>Chemotherapy is a fundamental modality in the treatment of breast cancer (BC), employed across both early and advanced stages. Triple-negative breast cancer (TNBC), known for its aggressive behavior and propensity for metastasis, presents significant treatment challenges due to its resistance to standard chemotherapeutic approaches. Identifying molecular targets for TNBC is imperative, especially in the absence of specifically targeted drugs and given the generally poor prognosis of the disease. Although nanomedicine has substantially grown, incorporating a variety of clinical applications, challenges such as dose-limiting toxicities and limited patient response rates continue to hinder its broader application. Over the past decade, graphene quantum dots (GQDs) have emerged as a promising category of luminescent materials, characterized by their outstanding optoelectronic properties, and their highly tunable structures and surface functionalities. These attributes make GQDs ideal candidates as drug carriers, facilitating straightforward functionalization, heightened chemotherapy sensitivity, and substantial drug loading capacities. This review provides a thorough exploration of recent advancements in GQDs applied to BC, with a specific focus on TNBC. It delves into the dynamics of breast cancer, emphasizing the diagnostic and therapeutic challenges of TNBC and the innovative potential of GQDs in this context. Furthermore, it discusses various GQD-based therapeutic strategies that hold promise for enhancing outcomes in breast cancer treatment, potentially leading to transformative advancements in the management of TNBC. Additionally, this review incorporates insights from three-dimensional (3D) tumor models, offering a comprehensive perspective on GQD-mediated interventions in breast cancer therapy.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216247"},"PeriodicalIF":20.3,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142384015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Correlating structure-activity-stability relationship of high-valent 3d-metal-based MOFs and MOF-derived materials for electrochemical energy conversion and storage 用于电化学能量转换和储存的高价 3d 金属基 MOF 和 MOF 衍生材料的结构-活性-稳定性相关关系

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-05 DOI: 10.1016/j.ccr.2024.216239

Baghendra Singh, Rakesh Kumar, Apparao Draksharapu

The energy crises and environmental pollution are the current main challenges for society. In this regard, efficient electrochemical energy conversion and storage technologies could be a promising solution to overcome these challenges. In the past few years, metal-organic frameworks (MOFs) and their derived materials have emerged as potential candidates for energy conversion and storage owing to their finely tuned structural and electronic properties, 3D morphology, large surface area, abundant active sites, good stability, and improved mass transport and diffusion. Among the thousands of MOFs reported in the literature, most are prepared using divalent 3d-metals (i.e., Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) with a combination of various organic linkers. In contrast, MOFs based on high-valent 3d metals, such as Ti, V, Cr, and Mn are less studied but have shown promise in energy conversion and storage. The high-valent 3d-metal-based MOFs offer easier synthesis, facile charge, and mass transport, tunable electronic properties, and high synergistic effects. Although many reviews have been published in recent years, none have focused on high-valent 3d-metal-based MOFs and their usage in energy conversion and storage. The current review summarizes the applications of MOFs made from high-valent 3d metals (Ti, V, Cr, and Mn) and their derived materials. This review focuses on the structure, porosity, and stability of high-valent 3d-metal-based MOFs and MOF-derived materials with their application in energy conversion and storage. Taking into account pioneering reports, this review offers a deeper comprehension and insight into the characteristics and uses of high-valent 3d-metal-based MOFs and MOF-derived materials. The recent progress, challenges related to the field, and the structure-activity-stability correlation have been established with plausible prospects.

能源危机和环境污染是当前社会面临的主要挑战。在这方面，高效的电化学能量转换和储存技术可能是克服这些挑战的一个有前途的解决方案。在过去几年中，金属有机框架（MOFs）及其衍生材料因其精细的结构和电子特性、三维形态、大比表面积、丰富的活性位点、良好的稳定性以及更佳的质量传输和扩散性，已成为能量转换和存储的潜在候选材料。在文献报道的数以千计的 MOFs 中，大多数都是利用二价 3d 金属（即 Fe2+、Co2+、Ni2+、Cu2+ 和 Zn2+）与各种有机连接剂结合制备的。相比之下，基于高价 3d 金属（如 Ti、V、Cr 和 Mn）的 MOF 研究较少，但在能量转换和储存方面已显示出前景。基于高价 3d 金属的 MOFs 具有合成容易、电荷和质量传输方便、电子特性可调以及协同效应高等特点。虽然近年来发表了许多综述，但没有一篇综述关注高价 3d 金属基 MOFs 及其在能量转换和存储中的应用。本综述总结了由高价 3d 金属（钛、钒、铬和锰）及其衍生材料制成的 MOFs 的应用。本综述侧重于高价 3d 金属基 MOF 及其衍生材料的结构、孔隙率和稳定性，以及它们在能量转换和储存中的应用。本综述结合先驱性报告，对高价三维金属基 MOFs 和 MOF 衍生材料的特性和用途进行了深入的理解和洞察。该领域的最新进展、面临的挑战以及结构-活性-稳定性的相关性均已确定，并具有合理的前景。

{"title":"Correlating structure-activity-stability relationship of high-valent 3d-metal-based MOFs and MOF-derived materials for electrochemical energy conversion and storage","authors":"Baghendra Singh, Rakesh Kumar, Apparao Draksharapu","doi":"10.1016/j.ccr.2024.216239","DOIUrl":"10.1016/j.ccr.2024.216239","url":null,"abstract":"<div><div>The energy crises and environmental pollution are the current main challenges for society. In this regard, efficient electrochemical energy conversion and storage technologies could be a promising solution to overcome these challenges. In the past few years, metal-organic frameworks (MOFs) and their derived materials have emerged as potential candidates for energy conversion and storage owing to their finely tuned structural and electronic properties, 3D morphology, large surface area, abundant active sites, good stability, and improved mass transport and diffusion. Among the thousands of MOFs reported in the literature, most are prepared using divalent 3d-metals (i.e., Fe<sup>2+</sup>, Co<sup>2+</sup>, Ni<sup>2+</sup>, Cu<sup>2+</sup>, and Zn<sup>2+</sup>) with a combination of various organic linkers. In contrast, MOFs based on high-valent 3d metals, such as Ti, V, Cr, and Mn are less studied but have shown promise in energy conversion and storage. The high-valent 3d-metal-based MOFs offer easier synthesis, facile charge, and mass transport, tunable electronic properties, and high synergistic effects. Although many reviews have been published in recent years, none have focused on high-valent 3d-metal-based MOFs and their usage in energy conversion and storage. The current review summarizes the applications of MOFs made from high-valent 3d metals (Ti, V, Cr, and Mn) and their derived materials. This review focuses on the structure, porosity, and stability of high-valent 3d-metal-based MOFs and MOF-derived materials with their application in energy conversion and storage. Taking into account pioneering reports, this review offers a deeper comprehension and insight into the characteristics and uses of high-valent 3d-metal-based MOFs and MOF-derived materials. The recent progress, challenges related to the field, and the structure-activity-stability correlation have been established with plausible prospects.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216239"},"PeriodicalIF":20.3,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142377463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Transition metal sulfides: From design strategies to environmental and energy-related applications 过渡金属硫化物：从设计策略到环境和能源相关应用

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-04 DOI: 10.1016/j.ccr.2024.216237

Sharafat Ali , Syed Ul Hasnain Bakhtiar , Ahmed Ismail , Pir Muhammad Ismail , Salman Hayat , Amir Zada , Xiaoqiang Wu , Abdullah N. Alodhayb , Muhammad Zahid , Fazal Raziq , Jiabao Yi , Liang Qiao

Over the preceding years, there has been a notable rise in scientific inquiry focused on nanocrystals composed of transition metal sulfides (TMSs) materials. This heightened interest stems from their potential applications in environmental conservancy and the advancement of renewable energy solutions. This is largely attributed to the plentiful availability of materials with readily adjustable electronic-optical, physical, and chemical characteristics. TMSs represent semiconducting compounds wherein sulfur functions as the anion coordinated with a metal cation. These compounds can exhibit mono-, bi-, or multiple forms of metal ions. The extensive range of TMSs materials offers a distinctive framework for generating a myriad of potential materials showcasing diverse chemical, physical, and electronic phenomena, along with innovative serviceable characteristics and applications. Unlocking the complete potential of these captivating materials necessitates the development of scalable techniques for fabricating cost-effective TMSs, heterostructures, and high-quality hybrids. This inclusive review delineates methodologies for the precise fabrication of TMSs, followed by an examination of the recent morphologies of TMSs nanocrystals achieved through various material fabrication techniques. This study highlights the notable contribution of various metal-sulfide-based nano-photocatalysts in efficiently degrading toxic organic pollutants, antibiotics, and dyes. Additionally, a detailed exploration of their role in water splitting for hydrogen fuel has been presented by specifying different charge transfer mechanisms in nanocomposites containing TMSs nanocrystals. Furthermore, TMSs-based electrodes for electrocatalytic and photoelectrocatalytic water splitting, carbon dioxide reduction, energy storage, and supercapacitance have been chartered in detail to cope with energy crises. Finally, some shortcomings of TMSs-based semiconductors are discussed from a future perspective in this review article. We hope this review article presents new directions for pollutant degradation, energy generation, and storage to reduce the impacts of global warming.

在过去几年中，对过渡金属硫化物（TMSs）材料组成的纳米晶体的科学研究明显增加。这种浓厚的兴趣源于它们在环境保护和推进可再生能源解决方案方面的潜在应用。这在很大程度上归功于大量可随时调节电子光学、物理和化学特性的材料。TMS 代表半导体化合物，其中硫作为阴离子与金属阳离子配位。这些化合物可以呈现单、双或多种形式的金属离子。范围广泛的 TMSs 材料提供了一个独特的框架，可生成无数潜在的材料，展示出各种化学、物理和电子现象，以及创新的可用特性和应用。要释放这些迷人材料的全部潜能，就必须开发可扩展的技术，以制造具有成本效益的 TMS、异质结构和高质量的混合材料。本综述阐述了精确制造 TMSs 的方法，随后研究了通过各种材料制造技术实现的 TMSs 纳米晶体的最新形态。本研究强调了各种基于金属硫化物的纳米光催化剂在高效降解有毒有机污染物、抗生素和染料方面的显著贡献。此外，研究还详细探讨了它们在水分离制取氢燃料方面的作用，具体说明了含有 TMSs 纳米晶体的纳米复合材料中的不同电荷转移机制。此外，还详细介绍了基于 TMSs 的电极在电催化和光电催化水分离、二氧化碳还原、能量存储和超级电容方面的作用，以应对能源危机。最后，本综述文章从未来的角度讨论了基于 TMSs 的半导体的一些不足之处。我们希望这篇综述文章能为污染物降解、能源生成和存储提供新的方向，以减少全球变暖的影响。

{"title":"Transition metal sulfides: From design strategies to environmental and energy-related applications","authors":"Sharafat Ali , Syed Ul Hasnain Bakhtiar , Ahmed Ismail , Pir Muhammad Ismail , Salman Hayat , Amir Zada , Xiaoqiang Wu , Abdullah N. Alodhayb , Muhammad Zahid , Fazal Raziq , Jiabao Yi , Liang Qiao","doi":"10.1016/j.ccr.2024.216237","DOIUrl":"10.1016/j.ccr.2024.216237","url":null,"abstract":"<div><div>Over the preceding years, there has been a notable rise in scientific inquiry focused on nanocrystals composed of transition metal sulfides (TMSs) materials. This heightened interest stems from their potential applications in environmental conservancy and the advancement of renewable energy solutions. This is largely attributed to the plentiful availability of materials with readily adjustable electronic-optical, physical, and chemical characteristics. TMSs represent semiconducting compounds wherein sulfur functions as the anion coordinated with a metal cation. These compounds can exhibit mono-, bi-, or multiple forms of metal ions. The extensive range of TMSs materials offers a distinctive framework for generating a myriad of potential materials showcasing diverse chemical, physical, and electronic phenomena, along with innovative serviceable characteristics and applications. Unlocking the complete potential of these captivating materials necessitates the development of scalable techniques for fabricating cost-effective TMSs, heterostructures, and high-quality hybrids. This inclusive review delineates methodologies for the precise fabrication of TMSs, followed by an examination of the recent morphologies of TMSs nanocrystals achieved through various material fabrication techniques. This study highlights the notable contribution of various metal-sulfide-based nano-photocatalysts in efficiently degrading toxic organic pollutants, antibiotics, and dyes. Additionally, a detailed exploration of their role in water splitting for hydrogen fuel has been presented by specifying different charge transfer mechanisms in nanocomposites containing TMSs nanocrystals. Furthermore, TMSs-based electrodes for electrocatalytic and photoelectrocatalytic water splitting, carbon dioxide reduction, energy storage, and supercapacitance have been chartered in detail to cope with energy crises. Finally, some shortcomings of TMSs-based semiconductors are discussed from a future perspective in this review article. We hope this review article presents new directions for pollutant degradation, energy generation, and storage to reduce the impacts of global warming.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216237"},"PeriodicalIF":20.3,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142374616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rare earth luminescent nanothermometers for biological thermal sensing 用于生物热感应的稀土发光纳米温度计

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-04 DOI: 10.1016/j.ccr.2024.216222

Yishuo Sun, Mengya Kong, Jiaming Ke, Yuyang Gu, Fuyou Li, Wei Feng

Temperature is a fundamental parameter closely related to physiological status in various biological cycles. Due to the significant role that temperature plays in life science, thermal sensing has gained extensive attention in the field of biological detection. Thermal sensing based on luminescence signals shows certain advantages, such as being non-invasive and fast. By further reducing the size of luminescent thermometers to the nanoscale, it is expected to accurately detect temperature in small biological settings. Among several nanothermometers, rare earth luminescent nanothermometers exhibit distinctive thermal sensing properties, making them excellent for measuring biological temperatures. This review primarily discusses thermal sensing methods for optimal detection performance. The optical systems used as thermal sensing equipment and the thermal sensing evaluation indexes as the evaluation standards are subsequently summarized. For specific biological scenarios, the selection of thermal sensing methods based on the requirements of relevant biological parameters are specifically analyzed. In particular, state-of-the-art biological applications based on the unique rare earth luminescent properties are highlighted for accurate thermal measurement from the cellular level to the organism. With a multidisciplinary approach that involves material, optical, and biological analysis, the review aims to provide guidance and propose the prospects of rare earth nanothermometers for biological thermal sensing.

在各种生物循环中，温度是与生理状态密切相关的基本参数。由于温度在生命科学中的重要作用，热感应在生物检测领域得到了广泛关注。基于发光信号的热感应具有一定的优势，如非侵入性和快速性。通过将发光温度计的尺寸进一步缩小到纳米级，有望在小型生物环境中准确检测温度。在几种纳米温度计中，稀土发光纳米温度计具有独特的热传感特性，因此非常适合测量生物温度。本综述主要讨论了实现最佳检测性能的热感应方法。随后总结了用作热感应设备的光学系统和作为评估标准的热感应评估指标。针对特定的生物场景，具体分析了基于相关生物参数要求的热感应方法选择。特别强调了基于稀土独特发光特性的最新生物应用，以实现从细胞到生物体的精确热测量。本综述采用涉及材料、光学和生物分析的多学科方法，旨在为稀土纳米温度计在生物热传感方面的应用提供指导，并提出其发展前景。

{"title":"Rare earth luminescent nanothermometers for biological thermal sensing","authors":"Yishuo Sun, Mengya Kong, Jiaming Ke, Yuyang Gu, Fuyou Li, Wei Feng","doi":"10.1016/j.ccr.2024.216222","DOIUrl":"10.1016/j.ccr.2024.216222","url":null,"abstract":"<div><div>Temperature is a fundamental parameter closely related to physiological status in various biological cycles. Due to the significant role that temperature plays in life science, thermal sensing has gained extensive attention in the field of biological detection. Thermal sensing based on luminescence signals shows certain advantages, such as being non-invasive and fast. By further reducing the size of luminescent thermometers to the nanoscale, it is expected to accurately detect temperature in small biological settings. Among several nanothermometers, rare earth luminescent nanothermometers exhibit distinctive thermal sensing properties, making them excellent for measuring biological temperatures. This review primarily discusses thermal sensing methods for optimal detection performance. The optical systems used as thermal sensing equipment and the thermal sensing evaluation indexes as the evaluation standards are subsequently summarized. For specific biological scenarios, the selection of thermal sensing methods based on the requirements of relevant biological parameters are specifically analyzed. In particular, state-of-the-art biological applications based on the unique rare earth luminescent properties are highlighted for accurate thermal measurement from the cellular level to the organism. With a multidisciplinary approach that involves material, optical, and biological analysis, the review aims to provide guidance and propose the prospects of rare earth nanothermometers for biological thermal sensing.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216222"},"PeriodicalIF":20.3,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142374425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unlocking the potential of borophene: Recent progress in synthesis, properties, and applications 挖掘硼吩的潜力：合成、特性和应用方面的最新进展

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-04 DOI: 10.1016/j.ccr.2024.216246

Anuj Kumar , Alagarsamy S.K. Kumar , Ganeshraja A. Sundaram , Felipe Martins de Souza , Ram K. Gupta , Phuong V. Pham

Boron (B), located in close proximity to carbon and positioned between metals and non-metals in the periodic table, is an element that exhibits exceptional chemical and physical versatility. It can be effectively managed to create flat structures with small dimensions, known as borophene, which possess fascinating features. In the ever-expanding landscape of two-dimensional materials, borophene has recently emerged as a compelling focus of research, captivating the interest of scientists globally. Endowed with an extraordinary atomic structure and remarkable properties, borophene stands poised to unlock a multitude of breakthroughs across diverse domains, including supercapacitors, batteries, hydrogen storage, fuel cells, water splitting, biomedical, and beyond. This review provides a comprehensive overview of theoretical and practical advances in borophene synthesis, as well as its unique properties and applications in a variety of fields. This overview describes the decade-long effort to understand the structures of B-clusters, which vary in size, as well as the borophene synthesis strategies, which include bottom-up and up-down approaches. Furthermore, it aims to shed light on recent advancements while delineating future avenues for research and innovation in this burgeoning field.

硼（B）与碳相邻，在元素周期表中位于金属和非金属之间。它可以有效地制造出具有迷人特性的小尺寸扁平结构，即硼烯烃。在不断扩大的二维材料领域，硼吩是最近出现的一个引人注目的研究焦点，吸引了全球科学家的兴趣。硼铼具有非凡的原子结构和卓越的性能，有望在超级电容器、电池、储氢、燃料电池、水分离、生物医学等多个领域实现突破。本综述全面概述了硼吩合成的理论和实践进展，以及硼吩在各个领域的独特性质和应用。本综述介绍了长达十年之久的研究工作，旨在了解大小不一的硼簇结构，以及硼吩的合成策略，包括自下而上和自上而下的方法。此外，它还旨在阐明最新进展，同时勾勒出这一新兴领域未来的研究和创新途径。

{"title":"Unlocking the potential of borophene: Recent progress in synthesis, properties, and applications","authors":"Anuj Kumar , Alagarsamy S.K. Kumar , Ganeshraja A. Sundaram , Felipe Martins de Souza , Ram K. Gupta , Phuong V. Pham","doi":"10.1016/j.ccr.2024.216246","DOIUrl":"10.1016/j.ccr.2024.216246","url":null,"abstract":"<div><div>Boron (B), located in close proximity to carbon and positioned between metals and non-metals in the periodic table, is an element that exhibits exceptional chemical and physical versatility. It can be effectively managed to create flat structures with small dimensions, known as borophene, which possess fascinating features. In the ever-expanding landscape of two-dimensional materials, borophene has recently emerged as a compelling focus of research, captivating the interest of scientists globally. Endowed with an extraordinary atomic structure and remarkable properties, borophene stands poised to unlock a multitude of breakthroughs across diverse domains, including supercapacitors, batteries, hydrogen storage, fuel cells, water splitting, biomedical, and beyond. This review provides a comprehensive overview of theoretical and practical advances in borophene synthesis, as well as its unique properties and applications in a variety of fields. This overview describes the decade-long effort to understand the structures of B-clusters, which vary in size, as well as the borophene synthesis strategies, which include bottom-up and up-down approaches. Furthermore, it aims to shed light on recent advancements while delineating future avenues for research and innovation in this burgeoning field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216246"},"PeriodicalIF":20.3,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142374426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Molecular endoperoxides for optical imaging and photodynamic therapy 用于光学成像和光动力疗法的分子内过氧化物

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-04 DOI: 10.1016/j.ccr.2024.216258

Dapeng Chen , Tian Zhang , Aihong Jiao , Xiaozhou Mou , Xiaochen Dong , Yu Cai

Molecular endoperoxide (MEPO) structuring with heterocycle peroxide (-O-O-) has shown tremendous promise for diseases diagnosis and treatment. Upon excitation by visible light, X-ray, or ultrasound, the afterglow or chemiluminescence emitted by MEPOs contribute to the development of autofluorescence-free optical imaging modes with ultrahigh signal-to-background ratio. Meanwhile, the reversible process of trapping and releasing of singlet oxygen from heterocycle substrates enables MEPOs to accomplish unconventional photodynamic effect featuring with dark and hypoxia tolerance. This review highlights the recent trends in the development of MEPOs as a powerful tool for optical imaging and photodynamic therapy (PDT). A summary was delivered to clarify the formation, decomposition, classification, and working mechanisms of MEPOs. Design strategies were also introduced with MEPOs towards a broad range of biomedical applications in optical imaging and PDT of different diseases. Lastly, perspectives and challenges for clinical translations were discussed for the direction of next-generation MEPOs.

以杂环过氧化物（-O-O-）为结构的分子过氧化物（MEPO）在疾病诊断和治疗方面显示出巨大的前景。在可见光、X 射线或超声波的激发下，MEPO 发出的余辉或化学发光有助于开发具有超高信噪比的无自发荧光光学成像模式。同时，由于单线态氧从杂环基质中捕获和释放的过程是可逆的，因此 MEPOs 能够实现非常规的光动力效应，具有耐暗和耐缺氧的特点。本综述重点介绍了 MEPOs 作为光学成像和光动力疗法 (PDT) 的有力工具的最新发展趋势。综述阐明了 MEPOs 的形成、分解、分类和工作机制。还介绍了 MEPOs 在不同疾病的光学成像和光动力疗法中广泛生物医学应用的设计策略。最后，针对下一代 MEPOs 的发展方向，讨论了临床转化的前景和挑战。

{"title":"Molecular endoperoxides for optical imaging and photodynamic therapy","authors":"Dapeng Chen , Tian Zhang , Aihong Jiao , Xiaozhou Mou , Xiaochen Dong , Yu Cai","doi":"10.1016/j.ccr.2024.216258","DOIUrl":"10.1016/j.ccr.2024.216258","url":null,"abstract":"<div><div>Molecular endoperoxide (MEPO) structuring with heterocycle peroxide (-O-O-) has shown tremendous promise for diseases diagnosis and treatment. Upon excitation by visible light, X-ray, or ultrasound, the afterglow or chemiluminescence emitted by MEPOs contribute to the development of autofluorescence-free optical imaging modes with ultrahigh signal-to-background ratio. Meanwhile, the reversible process of trapping and releasing of singlet oxygen from heterocycle substrates enables MEPOs to accomplish unconventional photodynamic effect featuring with dark and hypoxia tolerance. This review highlights the recent trends in the development of MEPOs as a powerful tool for optical imaging and photodynamic therapy (PDT). A summary was delivered to clarify the formation, decomposition, classification, and working mechanisms of MEPOs. Design strategies were also introduced with MEPOs towards a broad range of biomedical applications in optical imaging and PDT of different diseases. Lastly, perspectives and challenges for clinical translations were discussed for the direction of next-generation MEPOs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216258"},"PeriodicalIF":20.3,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142374453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent progress on modification strategies of both metal zinc anode and manganese dioxide cathode materials for high-performance aqueous zinc-ion batteries 高性能锌离子水电池金属锌阳极和二氧化锰阴极材料改性策略的最新进展

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-04 DOI: 10.1016/j.ccr.2024.216255

Xiaozhong Zhou, Xiangyuan Li, Junjun Pang, Ziqiang Lei

Aqueous zinc-ion batteries (AZIBs) are of the most potential energy storage systems for large-scale applications due to their low redox potential (−0.76 V vs standard hydrogen electrode, SHE), high theoretical specific capacity (820 mA h g⁻¹ and 5855 mA h cm⁻³), safety, low toxicity and price, eco-friendliness and abundant reserves. In spite of many hurdles before their practical application, great progress has been achieved on high-performance AZIBs. In this review, the main issues and their root causes faced by metal zinc anode and manganese dioxide cathode of AZIBs are analyzed, and the recent research progress on the modification strategies and their working mechanisms of both metal zinc anode and manganese dioxide cathode are focused on, and their challenges and future development prospects are also proposed, which provide a perspective for high-performance AZIBs, and further promote their practical process.

锌离子水电池（AZIBs）具有氧化还原电位低（-0.76 V，相对于标准氢电极，SHE）、理论比容量高（820 mA h g-1 和 5855 mA h cm-3）、安全、低毒、低价、生态友好和储量丰富等特点，是最有潜力大规模应用的储能系统。尽管在实际应用之前还存在许多障碍，但高性能 AZIBs 的研究已取得了重大进展。本综述分析了金属锌阳极和二氧化锰阴极 AZIBs 所面临的主要问题及其根本原因，重点介绍了金属锌阳极和二氧化锰阴极的改性策略及其工作机理的最新研究进展，并提出了其面临的挑战和未来的发展前景，为高性能 AZIBs 的发展提供了一个视角，进一步推动了其实用化进程。

引用次数: 0