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Development of HECAM Passive Samplers for Discovering the Occurrence, Sources, and Transport of Tire Additives and Their Transformation Products in Surface Waters 用于探测地表水中轮胎添加剂及其转化产物的发生、来源和迁移的HECAM被动采样器的研制
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-07 DOI: 10.1016/j.envpol.2026.127789
Ran Zhu, Yuchen Li, Xiaofan Yang, Xiaozhong Gao, Xiang Cheng
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引用次数: 0
Increased risks of systemic and abdominal obesity associated with long-term exposure to PM2.5 constituents 长期暴露于PM2.5成分中会增加全身和腹部肥胖的风险
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-06 DOI: 10.1016/j.envpol.2026.127777
Yang Yuan, Kai Wang, Yongqiang Liu, Yaqi Wang, Yunquan Zhang
Nexus between PM<sub>2.5</sub> constituents and obesity remain unclear, particular in densely populated and highly polluted regions. This study aims to assess the obese risk related to long-term exposure to PM<sub>2.5</sub> components among the Chinese elderly. We designed two nationwide dynamic cohort followed up from 2011 to 2015, through combining respondents from 28 provinces and estimates of PM<sub>2.5</sub> constituents predicted by well-validated spatiotemporal models. Based on data of physical examination measured by well-trained interviewers using standard devices, we adopted body mass index and waist circumference to define systemic and abdominal obesity, respectively. Cox proportional hazard models with time-varying exposures and a qg-computation approach were employed to evaluate individual and joint associations of obesity with long-term exposure to PM<sub>2.5</sub> constituents. The prevalences of systemic and abdominal obesity were 5.7% and 26.0% during 43814.6 and 27052.9 person-years follow-up, respectively. In the single-constituent analysis, the highest risk of systemic obesity derived from multivariable-adjusted model was 1.62 (95%: 1.40–1.87) linked with a 10.2 μg/m<sup>3</sup> increase of <span><span style=""></span><span data-mathml='<math xmlns="http://www.w3.org/1998/Math/MathML" />' role="presentation" style="font-size: 90%; display: inline-block; position: relative;" tabindex="0"><svg aria-hidden="true" focusable="false" height="0.24ex" role="img" style="vertical-align: -0.12ex;" viewbox="0 -51.7 0 103.4" width="0" xmlns:xlink="http://www.w3.org/1999/xlink"><g fill="currentColor" stroke="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"></g></svg><span role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"></math></span></span><script type="math/mml"><math></math></script></span>, while the top-risk component of abdominal obesity was <span><span style=""></span><span data-mathml='<math xmlns="http://www.w3.org/1998/Math/MathML" />' role="presentation" style="font-size: 90%; display: inline-block; position: relative;" tabindex="0"><svg aria-hidden="true" focusable="false" height="0.24ex" role="img" style="vertical-align: -0.12ex;" viewbox="0 -51.7 0 103.4" width="0" xmlns:xlink="http://www.w3.org/1999/xlink"><g fill="currentColor" stroke="currentColor" stroke-width="0" transform="matrix(1 0 0 -1 0 0)"></g></svg><span role="presentation"><math xmlns="http://www.w3.org/1998/Math/MathML"></math></span></span><script type="math/mml"><math></math></script></span>, with a hazard ratio of 1.30 (95% CI: 1.20–1.41) for per 6.2 μg/m<sup>3</sup> rise. For joint exposure, a quartile increase in the five-component mixture was associated with a 29% (95% CI: 19–40%) and 17% (95% CI: 12–23%) higher risk of systemic and abdominal obesity, respectively. This study offered robust associations between long-term exposure to PM<sub>2.5</sub> constituents and increased risks of both obesity outcomes, sug
PM2.5成分与肥胖之间的关系尚不清楚,特别是在人口密集和污染严重的地区。本研究旨在评估中国老年人长期暴露于PM2.5成分的肥胖风险。我们设计了两个2011 - 2015年的全国动态队列,结合28个省份的受访者和经过验证的时空模型预测的PM2.5成分估计值。根据训练有素的采访者使用标准设备测量的体格检查数据,我们分别采用身体质量指数和腰围来定义全身性肥胖和腹部肥胖。采用时变暴露的Cox比例风险模型和qg计算方法来评估肥胖与长期暴露于PM2.5成分之间的个体和联合关联。在43814.6和27052.9人年的随访期间,全身性肥胖和腹部肥胖的患病率分别为5.7%和26.0%。在单成分分析中,多变量调整模型得出的系统性肥胖的最高风险为1.62(95%:1.40-1.87),与10.2 μg/m3的增加有关,而腹部肥胖的最高风险成分为1.30 (95% CI: 1.20-1.41),每增加6.2 μg/m3。对于关节暴露,五组分混合物的四分之一增加分别与29% (95% CI: 19-40%)和17% (95% CI: 12-23%)的系统性和腹部肥胖风险增加相关。这项研究提供了长期暴露于PM2.5成分与两种肥胖结果风险增加之间的强有力关联,表明减少空气污染可以降低肥胖负担。
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引用次数: 0
Widespread PFAS Contamination in Pet Food: Dietary Sources and Health Risks to Companion Animals 宠物食品中广泛存在的PFAS污染:食物来源和对伴侣动物的健康风险
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-06 DOI: 10.1016/j.envpol.2026.127779
Kei Nomiyama, Aika Sato, Rumi Tanoue, Kohei Saeki, Yoshinori Ikenaka, Hazuki Mizukawa
Despite the growing concern over per- and polyfluoroalkyl substances (PFAS) exposure in companion animals, dietary intake through commercial pet food remains poorly characterized. In this study, we conducted a comprehensive analysis of 100 commercially available pet food products for dogs and cats in Japan, encompassing both dry and wet types, to quantify 34 target PFAS compounds. PFAS were frequently detected, with concentrations varying by food type, ingredients, and country of origin. Fish-based products contained elevated levels of perfluorooctanesulfonic acid (PFOS), perfluoroundecanoic acid (PFUnDA), and perfluorotridecanoic acid (PFTrDA), and regional patterns suggested the influence of Asian-specific PFAS sources such as F-53B. Hazard quotient (HQ) assessments based on EFSA tolerable weekly intakes indicated that average HQs exceeded 1 for both dogs and cats in several products, signaling potential health risks. However, due to the lack of species-specific toxicokinetic information for dogs and cats, the EFSA-based risk characterization presented here should be interpreted as a preliminary assessment. Although dry food had higher PFAS concentrations when converted to feeding amounts, estimated exposure was higher for wet food due to higher consumption. These findings provide the first evidence of ingredient-driven and country-of-origin-dependent PFAS contamination in pet food. Fish used as ingredients are a significant source of exposure to PFAS. They also highlight the urgent need for regulatory oversight and toxicological evaluations specific to companion animals. These animals serve as vulnerable populations and as sentinels of human co-exposure in domestic environments.
尽管人们越来越关注伴侣动物的全氟和多氟烷基物质(PFAS)暴露,但通过商业宠物食品摄入的饮食特征仍然很差。在这项研究中,我们对日本100种市售的猫狗宠物食品进行了全面分析,包括干型和湿型,以量化34种目标PFAS化合物。PFAS经常被检测到,其浓度因食品类型、成分和原产国而异。鱼类产品中全氟辛烷磺酸(PFOS)、全氟癸酸(PFUnDA)和全氟三烷酸(PFTrDA)的含量较高,区域模式表明亚洲特有的全氟辛烷磺酸来源(如F-53B)的影响。基于欧洲食品安全局每周可容忍摄入量的危害商数(HQ)评估表明,在一些产品中,狗和猫的平均HQ均超过1,表明存在潜在的健康风险。然而,由于缺乏狗和猫的物种特异性毒性动力学信息,本文提出的基于欧洲食品安全局的风险表征应被解释为初步评估。虽然干粮在转化为饲料量时含有较高的PFAS浓度,但由于消费量较高,湿粮的估计暴露量较高。这些发现提供了宠物食品中全氟辛烷磺酸污染由成分驱动和原产国决定的第一个证据。用作原料的鱼是接触PFAS的重要来源。他们还强调了对伴侣动物进行监管和毒理学评估的迫切需要。这些动物是脆弱的种群,也是人类在家庭环境中共同暴露的哨兵。
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引用次数: 0
Insights from Over a Million Births on Maternal Exposure to Multiple Pollutants and the Risk of Isolated Ventricular Septal Defects 100多万新生儿对母亲暴露于多种污染物和孤立性室间隔缺陷风险的见解
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-05 DOI: 10.1016/j.envpol.2026.127736
Xuelian Yuan, Li Dai, Ke Wang, Qi Li, Zhen Liu, Wenyan Li, Wenli Xu, Zhiyu Chen, Yuyang Gao, Jun Zhu, Hanmin Liu, Xiaohong Li
Numerous research works have established connections between maternal exposure to specific air pollutants and ventricular septal defects (VSD), there are still gaps in understanding the complexities of combined exposures in real-world settings. This study seeks to investigate the correlation between simultaneous exposure to five air pollutants throughout pregnancy and the likelihood of isolated VSD occurrence. It aims to address the gap between research focusing on individual pollutants and the complexities of real-world exposure scenarios. Utilizing data from China's National Population-Based Birth Defects Surveillance Network, we analyzed 850 isolated VSD cases against 1,097,056 unaffected births. Using a random forest land use regression model, we estimated daily pollutant concentrations (SO2, NO2, CO, O3, PM2.5) at geocoded maternal residences from 2014 to 2017. Based on these daily estimates, trimester-specific exposure concentrations were derived using dates of pregnancy onset and gestational weeks. Additionally, we devised an "air pollution score" to evaluate their cumulative exposure. The risk of isolated VSDs rose significantly with every 10-μg/m3 increase in air pollution score during pregnancy, especially the first trimester (OR 1.023, 95% CI 1.011-1.035), and the third trimester (OR 1.015, 95% CI 1.003-1.026). A linear relationship was observed between levels of air pollution scores during the entire pregnancy and the risk of isolated VSDs. The heightened risk linked to air pollution score during the first trimester surpassed that of the second and third trimesters. Besides, the results highlighted a pronounced risk among mothers in rural, low-income areas and being pregnant in cold season. By providing a more comprehensive assessment of the potential risks that pollutants pose to maternal and infant health, this study may offer important insights for public health policy and inform the development of new clinical tools for risk assessment and early screening.
许多研究工作已经建立了母亲暴露于特定空气污染物和室间隔缺陷(VSD)之间的联系,但在了解现实环境中联合暴露的复杂性方面仍然存在差距。本研究旨在探讨在怀孕期间同时暴露于五种空气污染物与孤立性室间隔发育的可能性之间的关系。它旨在解决关注单个污染物的研究与现实世界暴露情景的复杂性之间的差距。利用中国全国人口出生缺陷监测网的数据,我们分析了850例孤立的室性室间隔缺损病例和1,097,056例未受影响的新生儿。利用随机林地利用回归模型,我们估算了2014年至2017年地理编码的孕产妇居住地的日污染物浓度(SO2、NO2、CO、O3和PM2.5)。基于这些每日估计,根据妊娠开始日期和妊娠周得出妊娠期特异性暴露浓度。此外,我们设计了一个“空气污染评分”来评估他们的累积暴露。妊娠期空气污染评分每增加10 μg/m3,尤其是妊娠前期(OR 1.023, 95% CI 1.011 ~ 1.035)和妊娠晚期(OR 1.015, 95% CI 1.003 ~ 1.026),分离性VSDs的发生风险显著增加。在整个怀孕期间的空气污染评分水平与孤立性室性心脏疾病的风险之间观察到线性关系。怀孕前三个月与空气污染得分相关的风险增加程度超过了妊娠中期和晚期。此外,研究结果还强调了农村、低收入地区的母亲在寒冷季节怀孕的明显风险。通过对污染物对母婴健康构成的潜在风险进行更全面的评估,本研究可能为公共卫生政策提供重要见解,并为风险评估和早期筛查的新临床工具的开发提供信息。
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引用次数: 0
Artificial Light at Night Disrupts Immune Rhythms in Wild Rodents under Semi-Natural Conditions 夜间人造光在半自然条件下扰乱野生啮齿动物的免疫节律
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-05 DOI: 10.1016/j.envpol.2026.127774
Hagar Vardi-Naim, Gul Janovsky, Noga Kronfeld-Schor, Yariv Wine
Artificial light at night (ALAN) is a rapidly expanding form of environmental pollution that disrupts natural light–dark cycles and alters behavioral and physiological rhythms across species. Because immune function is tightly linked to environmental cues, studying ALAN within an ecoimmunological framework is essential for understanding its real-world impacts on wildlife fitness. In natural settings, immune rhythms are shaped by multiple, interacting environmental pressures, and evaluating ALAN against this broader ecological backdrop is critical for interpreting its physiological consequences.We investigated how low-intensity ALAN affects immune and endocrine rhythmicity, antibody responses, and survival in two wild rodent species with opposing activity patterns, the nocturnal <em>Acomys dimidiatus</em> and the diurnal <em>Acomys russatus</em>, maintained in semi-natural outdoor enclosures. Under natural light-dark conditions, both species exhibited daily oscillations in circulating lymphocyte frequencies, and in <em>A. dimidiatus</em>, fecal cortisol also showed a clear daily rhythm. These rhythms were disrupted or dampened under ALAN. Moreover, antibody titers were significantly higher when immunization occurred during the species-specific rest phase, but ALAN exposure disrupted these rhythms, eliminating time-of-day variation in antibody responses. Overall, ALAN increased the mortality risk by 2.35-fold.Although controlled laboratory experiments have been essential for advancing immunology, they offer limited insight into how environmental disturbances like light pollution affect wildlife under realistic conditions. By studying wild rodents in semi-natural habitats, we reveal that ALAN exposure alters immune rhythms, endocrine patterns, and survival in ways that emerge only when animals experience natural ecological variation. These results highlight that immune baselines in the wild are products of complex environmental interactions and that ALAN can disrupt these integrated physiological systems. Together, these findings underscore the need for ecoimmunological approaches to assess how expanding light pollution threatens wildlife health and resilience.Significance StatementArtificial light at night (ALAN) is a growing anthropogenic disturbance with wide-ranging ecological and physiological impacts. While its disruptive effect on circadian rhythms is well documented, its effects on immune function remain underexplored. Our findings show that ALAN alters immune rhythmicity and weakens time-dependent antibody responses in wild rodents under semi-natural conditions, potentially increasing susceptibility to infection. Studying the effects of light pollution on wild species under natural conditions is essential not only for understanding its impact on ecosystem health, but also for assessing how altered immune function may influence the emergence and spread of zoonotic diseases. These insights underscore the need to investigate immunity in ecolog
夜间人造光(ALAN)是一种迅速扩大的环境污染形式,它破坏了自然的光暗循环,改变了物种的行为和生理节律。由于免疫功能与环境因素密切相关,因此在生态免疫学框架内研究ALAN对于理解其对野生动物适应性的现实影响至关重要。在自然环境中,免疫节律是由多种相互作用的环境压力形成的,在这种更广泛的生态背景下评估ALAN对于解释其生理后果至关重要。我们研究了低强度ALAN如何影响两种活动模式相反的野生啮齿动物的免疫和内分泌节律、抗体反应和存活率,这两种啮齿动物分别是夜间活动的侏儒和白天活动的侏儒,饲养在半自然的室外围栏中。在自然光照-黑暗条件下,这两种物种的循环淋巴细胞频率均表现出日振荡,而在a . dimidiatus中,粪便皮质醇也表现出明显的日节律。在ALAN的作用下,这些节律被打乱或减弱了。此外,当免疫发生在物种特异性休息阶段时,抗体滴度显着较高,但ALAN暴露破坏了这些节律,消除了抗体反应的时间变化。总的来说,ALAN使死亡风险增加了2.35倍。尽管受控的实验室实验对于推进免疫学至关重要,但它们对光污染等环境干扰如何在现实条件下影响野生动物提供的见解有限。通过研究半自然栖息地的野生啮齿动物,我们发现ALAN暴露会以只有在动物经历自然生态变化时才会出现的方式改变免疫节律、内分泌模式和生存。这些结果表明,野外的免疫基线是复杂环境相互作用的产物,ALAN可以破坏这些综合生理系统。总之,这些发现强调了生态免疫学方法的必要性,以评估不断扩大的光污染如何威胁野生动物的健康和恢复能力。意义声明:夜间人造光(ALAN)是一种日益增长的具有广泛生态和生理影响的人为干扰。虽然其对昼夜节律的破坏性影响已被充分记录,但其对免疫功能的影响仍未得到充分探讨。我们的研究结果表明,在半自然条件下,ALAN改变了野生啮齿动物的免疫节律,削弱了时间依赖性抗体反应,可能增加了对感染的易感性。研究自然条件下光污染对野生物种的影响不仅对了解其对生态系统健康的影响至关重要,而且对于评估免疫功能的改变如何影响人畜共患疾病的出现和传播至关重要。这些见解强调了在传统实验室模型和条件之外,在生态相关背景下调查免疫的必要性。
{"title":"Artificial Light at Night Disrupts Immune Rhythms in Wild Rodents under Semi-Natural Conditions","authors":"Hagar Vardi-Naim, Gul Janovsky, Noga Kronfeld-Schor, Yariv Wine","doi":"10.1016/j.envpol.2026.127774","DOIUrl":"https://doi.org/10.1016/j.envpol.2026.127774","url":null,"abstract":"Artificial light at night (ALAN) is a rapidly expanding form of environmental pollution that disrupts natural light–dark cycles and alters behavioral and physiological rhythms across species. Because immune function is tightly linked to environmental cues, studying ALAN within an ecoimmunological framework is essential for understanding its real-world impacts on wildlife fitness. In natural settings, immune rhythms are shaped by multiple, interacting environmental pressures, and evaluating ALAN against this broader ecological backdrop is critical for interpreting its physiological consequences.We investigated how low-intensity ALAN affects immune and endocrine rhythmicity, antibody responses, and survival in two wild rodent species with opposing activity patterns, the nocturnal &lt;em&gt;Acomys dimidiatus&lt;/em&gt; and the diurnal &lt;em&gt;Acomys russatus&lt;/em&gt;, maintained in semi-natural outdoor enclosures. Under natural light-dark conditions, both species exhibited daily oscillations in circulating lymphocyte frequencies, and in &lt;em&gt;A. dimidiatus&lt;/em&gt;, fecal cortisol also showed a clear daily rhythm. These rhythms were disrupted or dampened under ALAN. Moreover, antibody titers were significantly higher when immunization occurred during the species-specific rest phase, but ALAN exposure disrupted these rhythms, eliminating time-of-day variation in antibody responses. Overall, ALAN increased the mortality risk by 2.35-fold.Although controlled laboratory experiments have been essential for advancing immunology, they offer limited insight into how environmental disturbances like light pollution affect wildlife under realistic conditions. By studying wild rodents in semi-natural habitats, we reveal that ALAN exposure alters immune rhythms, endocrine patterns, and survival in ways that emerge only when animals experience natural ecological variation. These results highlight that immune baselines in the wild are products of complex environmental interactions and that ALAN can disrupt these integrated physiological systems. Together, these findings underscore the need for ecoimmunological approaches to assess how expanding light pollution threatens wildlife health and resilience.Significance StatementArtificial light at night (ALAN) is a growing anthropogenic disturbance with wide-ranging ecological and physiological impacts. While its disruptive effect on circadian rhythms is well documented, its effects on immune function remain underexplored. Our findings show that ALAN alters immune rhythmicity and weakens time-dependent antibody responses in wild rodents under semi-natural conditions, potentially increasing susceptibility to infection. Studying the effects of light pollution on wild species under natural conditions is essential not only for understanding its impact on ecosystem health, but also for assessing how altered immune function may influence the emergence and spread of zoonotic diseases. These insights underscore the need to investigate immunity in ecolog","PeriodicalId":311,"journal":{"name":"Environmental Pollution","volume":"134 1","pages":""},"PeriodicalIF":8.9,"publicationDate":"2026-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146122226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Contamination of Organophosphate Esters in Soil Surrounding Paint Factories: Machine Learning-based Distribution Prediction and Risk Prioritization Assessment 涂料工厂周围土壤中有机磷酯污染:基于机器学习的分布预测和风险优先级评估
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-05 DOI: 10.1016/j.envpol.2026.127775
Yu Wang, Siyuan Li, Ergang Yuan, Zelin Fang, Zixiao Zhao, Yimeng Si, Meng Gao, Hongzhi Zhao, Hongwen Sun
Organophosphate esters (OPEs) are widely used in paint industry. However, their contamination and risk in paint industry-related areas remain insufficiently characterized. In this study, 33 OPEs, including traditional and novel OPEs, and their diester and hydroxylated transformation products were quantified in 48 surface soil samples collected around paint-related factories in eastern China. The total OPE concentrations ranged from 12.7 to 419 ng/g, and were dominated by chlorinated and novel OPEs. Spatial analysis using Kriging interpolation revealed a distinct point-source distribution pattern, with elevated concentrations in soils adjacent to paint factories reaching 334 to 419 ng/g. Additionally, four machine learning (ML) models were developed to predict OPE distribution in study region, using spatial coordinates, soil properties, and molecular descriptors as predictors. Among them, the tree-based model of gradient boosting regression tree achieved the highest predictive accuracy (testing set, R2=0.61, MAE=0.43, MSE=0.33), and outperformed Kriging interpolation based on external validation. This demonstrates the feasibility of ML-based approaches for predicting OPE distribution patterns. Furthermore, risk assessment results indicated that novel OPEs tris(2,4-di-tert-butylphenyl) phosphate (AO168=O) and tris(4-nonylphenyl) phosphate (TNPP) posed notably high risks, with risk quotient values of 3.60-1200 and ToxPi prioritization scores of 0.71-0.80. Overall, this study provides new insights and methodological references for understanding the contamination and risks of emerging pollutants associated with the paint industry.
有机磷酸酯(OPEs)在涂料工业中应用广泛。然而,它们在油漆工业相关领域的污染和风险仍然没有得到充分的描述。本研究对中国东部地区48份表层土壤样品中的33种有机磷化合物(包括传统有机磷化合物和新型有机磷化合物)及其二酯和羟基化转化产物进行了定量分析。总OPE浓度范围为12.7 ~ 419 ng/g,以氯化和新型OPE为主。利用Kriging插值法进行空间分析,发现了明显的点源分布模式,油漆厂附近土壤中重金属浓度升高,达到334 ~ 419 ng/g。此外,开发了四个机器学习(ML)模型来预测研究区域的OPE分布,使用空间坐标、土壤性质和分子描述符作为预测因子。其中,基于树的梯度增强回归树模型预测精度最高(测试集,R2=0.61, MAE=0.43, MSE=0.33),优于基于外部验证的Kriging插值。这证明了基于ml的方法预测OPE分布模式的可行性。此外,风险评估结果表明,新型OPEs(2,4-二叔丁基苯基)磷酸三酯(AO168= 0)和(4-壬基苯基)磷酸三酯(TNPP)具有显著的高风险,风险商值为3.60 ~ 1200,ToxPi优先级评分为0.71 ~ 0.80。总体而言,本研究为理解与涂料工业相关的污染和新兴污染物的风险提供了新的见解和方法参考。
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引用次数: 0
Ionic PFAS in PM2.5 and Dust: Insights on Indoor-Outdoor Profiles and Distribution PM2.5和粉尘中的离子PFAS:室内室外分布和分布的见解
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-05 DOI: 10.1016/j.envpol.2026.127767
Junqi Li, Yulong Ma, Yanli Li, Cuiping Jia, Ying Xiong, Bo Zhang, Stuart Harrad, Ke Du
Although extensive studies have been performed to characterize Per- and polyfluoroalkyl substances (PFAS) in the environment, PFAS in PM2.5 remains underexplored. This study presents a comprehensive investigation of PFAS in indoor and outdoor PM2.5 and dust samples to evaluate their quantities and distribution. Twenty-nine ionic PFAS species were quantified in samples collected from ten different environments such as daycare center, vehicle, airport, and fire training facility. PFAS were found to be ubiquitous, and present in both PM2.5 (3.34–22.2 pg/m3) and dust (1.27–9840 ng/g). Perfluoroalkyl carboxylic acids (PFCAs) dominated the PFAS profile in both indoor and outdoor PM2.5, accounting for 94.1 ± 11.1% of total PFAS, which was significantly higher than that in dust (61.5 ± 32.7%) (p < 0.01). In contrast, the proportion of perfluoroalkane sulfonic acids (PFSAs) in dust (21.7 ± 18.1%) was significantly higher than that in PM2.5 (4.54 ± 10.5%) (p < 0.01). This suggests that PFCAs are more likely than PFSAs to attach to PM2.5, and are capable of long-range atmospheric transport (LRT). Among the 11 PFCAs species, perfluorobutanoic acid (PFBA) and perfluorohexanoic acid (PFHxA), two short chain PFAS, were of the highest concentrations, particularly in samples collected during the wildfire events. This highlights the significance of short chain PFAS in LRT. For indoor PFAS, a strong relationship (r = 0.611–0.853, p < 0.01) was observed between long-chain PFCAs concentrations in PM2.5 and in dust. These findings provide new insights into the potential processes of indoor PFCAs emissions and distribution and suggest possible exposure pathways of airborne PFAS in urban environments.
尽管对环境中的全氟烷基和多氟烷基物质(PFAS)进行了广泛的研究,但对PM2.5中的PFAS的研究仍然不足。本研究对室内和室外PM2.5和粉尘样品中的PFAS进行了全面调查,以评估其数量和分布。在日托中心、车辆、机场和消防训练设施等10种不同环境中采集了29种离子PFAS。PFAS普遍存在于PM2.5 (3.34-22.2 pg/m3)和粉尘(1.27-9840 ng/g)中。全氟烷基羧酸(PFCAs)在室内外PM2.5中均占主导地位,占总PFAS的94.1±11.1%,显著高于粉尘(61.5±32.7%)(p < 0.01)。全氟烷烃磺酸(PFSAs)在粉尘中的比例(21.7±18.1%)显著高于PM2.5(4.54±10.5%)(p < 0.01)。这表明PFCAs比pfsa更有可能附着在PM2.5上,并且能够进行远距离大气输送(LRT)。在11种PFCAs中,全氟丁酸(PFBA)和全氟己酸(PFHxA)这两种短链PFAS的浓度最高,特别是在野火事件期间收集的样品中。这凸显了短链PFAS在LRT中的重要性。对于室内PFAS, PM2.5中长链PFCAs浓度与粉尘中存在较强的相关性(r = 0.611-0.853, p < 0.01)。这些发现为了解室内PFAS排放和分布的潜在过程提供了新的见解,并提出了城市环境中空气中PFAS的可能暴露途径。
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引用次数: 0
Wet deposition modeling and behavior analysis of 137Cs aerosols using ten observation-based continuous size distributions following the Fukushima accident 福岛事故后137Cs气溶胶的湿沉积模型和行为分析,基于10次观测的连续大小分布
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-05 DOI: 10.1016/j.envpol.2026.127773
Shuhan Zhuang, Sheng Fang, Yuhan Xu, Xinwen Dong, Daisuke Goto, Yu Morino
Cesium-137 is one of the most concerned radionuclides produced by fission energy, which has a long half-life, considerable biological toxicity and complex transport behaviors. Wet deposition is a key process in determining the atmospheric transport of 137Cs aerosols following the Fukushima Daiichi nuclear power plant (FDNPP) accident. However, our understanding of this process remains insufficient because of the complex size distributions of the 137Cs aerosols and related atmospheric transport processes. This study investigates the wet deposition behavior of observed 137Cs aerosols by developing a wet deposition model that considers multiple continuous size distributions in the online-coupled WRF-Chem. The wet deposition efficiency is calculated based on Köhler’s theory. Ten log-normal size distributions are constructed, with geometric mean diameters (dm) derived from observation. These distributions are applied to simulate the 137Cs transport following the FDNPP accident. The results reveal that the established model successfully reproduces the 137Cs transport and wet deposition. Below-cloud deposition is dominant over in-cloud deposition for 137Cs aerosols with dm≤2.0 μm. In-cloud deposition is also important when dm>2.0 μm, whereas dry deposition is predominant for dm>6.4 μm. As for the atmospheric concentration, the influence of aerosol size is substantial during weak rain near the source. 137Cs aerosols with dm≈2.8 μm best reproduce both the cumulative deposition and atmospheric concentration at the same time. The results indicate the importance of considering multiple log-normal size distributions and fog deposition.
铯-137是核裂变能产生的最受关注的放射性核素之一,其半衰期长,生物毒性大,转运行为复杂。湿沉降是确定福岛第一核电站事故后137Cs气溶胶在大气中运移的关键过程。然而,由于137Cs气溶胶的复杂大小分布和相关的大气输送过程,我们对这一过程的理解仍然不足。本研究通过开发考虑在线耦合WRF-Chem中多个连续尺寸分布的湿沉积模型,研究了观测到的137Cs气溶胶的湿沉积行为。根据Köhler的理论计算了湿沉积效率。构造了10个对数正态尺寸分布,几何平均直径(dm)由观测得到。这些分布被应用于模拟福岛核电站事故后的137Cs传输。结果表明,所建立的模型成功地再现了137Cs的输运和湿沉积过程。dm≤2.0 μm的137Cs气溶胶以云下沉积为主,云内沉积为主。当dm>;2.0 μm时,云内沉积也很重要,而当dm>;6.4 μm时,干沉积占主导地位。对于大气浓度,在近源弱雨期间气溶胶大小的影响较大。dm≈2.8 μm的137Cs气溶胶最能同时再现累积沉降和大气浓度。结果表明,考虑多重对数正态分布和雾沉积的重要性。
{"title":"Wet deposition modeling and behavior analysis of 137Cs aerosols using ten observation-based continuous size distributions following the Fukushima accident","authors":"Shuhan Zhuang, Sheng Fang, Yuhan Xu, Xinwen Dong, Daisuke Goto, Yu Morino","doi":"10.1016/j.envpol.2026.127773","DOIUrl":"https://doi.org/10.1016/j.envpol.2026.127773","url":null,"abstract":"Cesium-137 is one of the most concerned radionuclides produced by fission energy, which has a long half-life, considerable biological toxicity and complex transport behaviors. Wet deposition is a key process in determining the atmospheric transport of <sup>137</sup>Cs aerosols following the Fukushima Daiichi nuclear power plant (FDNPP) accident. However, our understanding of this process remains insufficient because of the complex size distributions of the <sup>137</sup>Cs aerosols and related atmospheric transport processes. This study investigates the wet deposition behavior of observed <sup>137</sup>Cs aerosols by developing a wet deposition model that considers multiple continuous size distributions in the online-coupled WRF-Chem. The wet deposition efficiency is calculated based on Köhler’s theory. Ten log-normal size distributions are constructed, with geometric mean diameters (d<sub>m</sub>) derived from observation. These distributions are applied to simulate the <sup>137</sup>Cs transport following the FDNPP accident. The results reveal that the established model successfully reproduces the <sup>137</sup>Cs transport and wet deposition. Below-cloud deposition is dominant over in-cloud deposition for <sup>137</sup>Cs aerosols with d<sub>m</sub>≤2.0 μm. In-cloud deposition is also important when d<sub>m</sub>&gt;2.0 μm, whereas dry deposition is predominant for d<sub>m</sub>&gt;6.4 μm. As for the atmospheric concentration, the influence of aerosol size is substantial during weak rain near the source. <sup>137</sup>Cs aerosols with d<sub>m</sub>≈2.8 μm best reproduce both the cumulative deposition and atmospheric concentration at the same time. The results indicate the importance of considering multiple log-normal size distributions and fog deposition.","PeriodicalId":311,"journal":{"name":"Environmental Pollution","volume":"384 1","pages":""},"PeriodicalIF":8.9,"publicationDate":"2026-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146129661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A study on the association between early-pregnancy hair metal levels and gestational diabetes mellitus 妊娠早期发金属水平与妊娠期糖尿病相关性的研究
IF 8.9 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-05 DOI: 10.1016/j.envpol.2026.127765
Feng Tang, Jun Guo, Li-An-Sheng Wu, Xiao-Yuan Fan, Han-Wen Zhang, Noora Kartiosuo, Boris Novakovic, Ting-Li Han, Hua Zhang, Yin-Yin Xia, Philip Baker, Richard Saffery
Gestational diabetes mellitus (GDM) is a common complication of pregnancy with a complex etiology, and environmental exposure to metals is considered a potential and important risk factor. However, there is still insufficient research on the comprehensive effects of long-term mixed exposure to multiple metals during early pregnancy on GDM and the potential mediating factors. This study aimed to systematically explore the independent and combined effects of exposure to 15 metals during early pregnancy on GDM risk and to clarify the potential mediating role of saturated fatty acids (SFAs) through a prospective cohort of 665 pregnant women recruited between September 2015 and June 2017. Hair samples were collected during early pregnancy, and metal concentrations were measured using inductively coupled plasma mass spectrometry (ICP-MS). SFAs levels in mid-pregnancy were measured by gas chromatography-mass spectrometry (GC-MS). Statistically, logistic regression and restricted cubic splines (RCS) were used to assess the effects of individual metals, and Weighted Quantile Sum (WQS) and Bayesian kernel machine regression(BKMR) model were applied to analyze the combined effects of metal mixtures. Additionally, mediation analysis was conducted to investigate the mediating roles of three SFAs. The results showed that potassium (K), rubidium (Rb), niobium (Nb), silver (Ag), and thallium (Tl) were positively associated with GDM risk, while Nb, Ag, and mercury (Hg) exhibited non-linear exposure-response relationships. Metals mixture had an overall possitive effect on GDM risk. Mediation analysis revealed that myristic acid (C14:0) mediated the associations of K, Rb, Nb, and Ag with GDM risk; pentadecanoic acid (C15:0) mediated the associations of K, Rb, and Nb with GDM risk; and heptadecanoic acid (C17:0) mediated the associations of Rb and Ag with GDM risk.
妊娠期糖尿病(GDM)是一种常见的妊娠并发症,病因复杂,环境暴露于金属被认为是一个潜在的重要危险因素。然而,妊娠早期长期混合暴露多种金属对GDM的综合影响及可能的介导因素研究尚不足。本研究旨在通过2015年9月至2017年6月招募的665名孕妇的前瞻性队列,系统探讨妊娠早期暴露于15种金属对GDM风险的独立和联合影响,并阐明饱和脂肪酸(sfa)的潜在介导作用。在怀孕早期收集头发样本,使用电感耦合等离子体质谱(ICP-MS)测定金属浓度。采用气相色谱-质谱联用(GC-MS)法测定妊娠中期SFAs水平。统计上,采用logistic回归和限制三次样条(RCS)评估单个金属的影响,采用加权分位数和(WQS)和贝叶斯核机回归(BKMR)模型分析金属混合物的综合影响。此外,我们还进行了中介分析,探讨了三种sfa的中介作用。结果表明,钾(K)、铷(Rb)、铌(Nb)、银(Ag)和铊(Tl)与GDM风险呈正相关,而铌(Nb)、银(Ag)和汞(Hg)呈非线性暴露-响应关系。金属混合物总体上对GDM风险有积极影响。中介分析显示,肉豆蔻酸(C14:0)介导K、Rb、Nb和Ag与GDM风险的关联;五酸(C15:0)介导K、Rb和Nb与GDM风险的关联;和十七烷酸(C17:0)介导Rb和Ag与GDM风险的关联。
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引用次数: 0
Occurrence of insecticides, fungicides, and herbicides in household drinking and irrigation water in an intensive floriculture region of Ecuador. 厄瓜多尔集约型花卉种植区家庭饮用水和灌溉水中杀虫剂、杀菌剂和除草剂的发生情况。
IF 7.3 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-05 DOI: 10.1016/j.envpol.2026.127757
M Pfaff, A Zambrano-Romero, G H LeFevre, V Ochoa-Herrera, S Gupta, Chronister B N C, A L Mianecki, N Carpintero-Salvador, H Checkoway, J R Suarez-Lopez, G L Kayser

Pesticides are widely used in agriculture, floriculture specifically, posing significant ecological and health risks. Limited research has been conducted on the presence of neonicotinoid insecticides (NNI) and atrazine, in drinking and irrigation water in agricultural regions of Latin America. This study describes targeted and non-targeted analysis of concentrations of pesticides in drinking and irrigation water sampled in 2022 and 2023 in an industrial floricultural region in Pedro Moncayo, Ecuador. In targeted analysis, we found NNI in treated drinking water in 20.5% of household tap water samples (8 out of 39), in a community well, and in 57.7% of irrigation water samples (n=15 out of 26). Imidacloprid and thiamethoxam emerged as the most frequently detected NNI in drinking water. Atrazine was detected in two household taps and one well. In exploratory non-targeted analysis, we found 63 compounds, including insecticides, herbicides, and fungicides, including azoles, in drinking and irrigation water samples. Fungicides accounted for 59% of all compounds (37 out of 63) detected. Intense pesticide use in floriculture in proximity to residential areas and aging piped water systems may allow pesticides to leach into treated drinking water pipes and irrigation water. The presence of a wide range of pesticides, especially NNI and fungicides (azoles, specifically), in drinking and irrigation water poses health risks to community members.

农药广泛应用于农业,特别是花卉种植,对生态和健康构成重大风险。对拉丁美洲农业区饮用水和灌溉水中新烟碱类杀虫剂和阿特拉津的存在进行了有限的研究。本研究描述了2022年和2023年在厄瓜多尔佩德罗蒙卡约一个工业花卉种植区取样的饮用水和灌溉水中农药浓度的目标和非目标分析。在针对性分析中,我们发现20.5%的家庭自来水样本(39个样本中的8个)和57.7%的灌溉水样本(26个样本中的15个)在处理后的饮用水中存在NNI。吡虫啉和噻虫嗪是饮用水中最常见的NNI。在两个住户水龙头及一个水井检出阿特拉津。在探索性非靶向分析中,我们在饮用水和灌溉水样品中发现了63种化合物,包括杀虫剂、除草剂和杀菌剂,包括唑类。在所有检测到的化合物中,杀菌剂占59%(63种化合物中的37种)。在居民区附近的花卉种植中大量使用农药和老化的管道供水系统可能使农药渗入处理过的饮用水管道和灌溉水中。饮用水和灌溉水中存在各种各样的杀虫剂,特别是NNI和杀菌剂(特别是唑类),对社区成员的健康构成威胁。
{"title":"Occurrence of insecticides, fungicides, and herbicides in household drinking and irrigation water in an intensive floriculture region of Ecuador.","authors":"M Pfaff, A Zambrano-Romero, G H LeFevre, V Ochoa-Herrera, S Gupta, Chronister B N C, A L Mianecki, N Carpintero-Salvador, H Checkoway, J R Suarez-Lopez, G L Kayser","doi":"10.1016/j.envpol.2026.127757","DOIUrl":"https://doi.org/10.1016/j.envpol.2026.127757","url":null,"abstract":"<p><p>Pesticides are widely used in agriculture, floriculture specifically, posing significant ecological and health risks. Limited research has been conducted on the presence of neonicotinoid insecticides (NNI) and atrazine, in drinking and irrigation water in agricultural regions of Latin America. This study describes targeted and non-targeted analysis of concentrations of pesticides in drinking and irrigation water sampled in 2022 and 2023 in an industrial floricultural region in Pedro Moncayo, Ecuador. In targeted analysis, we found NNI in treated drinking water in 20.5% of household tap water samples (8 out of 39), in a community well, and in 57.7% of irrigation water samples (n=15 out of 26). Imidacloprid and thiamethoxam emerged as the most frequently detected NNI in drinking water. Atrazine was detected in two household taps and one well. In exploratory non-targeted analysis, we found 63 compounds, including insecticides, herbicides, and fungicides, including azoles, in drinking and irrigation water samples. Fungicides accounted for 59% of all compounds (37 out of 63) detected. Intense pesticide use in floriculture in proximity to residential areas and aging piped water systems may allow pesticides to leach into treated drinking water pipes and irrigation water. The presence of a wide range of pesticides, especially NNI and fungicides (azoles, specifically), in drinking and irrigation water poses health risks to community members.</p>","PeriodicalId":311,"journal":{"name":"Environmental Pollution","volume":" ","pages":"127757"},"PeriodicalIF":7.3,"publicationDate":"2026-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146136934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Environmental Pollution
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