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3rd International Conference 'Novel Applications of Wide Bandgap Layers' Abstract Book (Cat. No.01EX500)最新文献

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CVD diamonds as active and passive detectors of ionising radiation. Assessment of their applicability for medical dosimetry CVD金刚石作为电离辐射的主动和被动探测器。评估其在医疗剂量学中的适用性
B. Marczewska, T. Nowak, P. Olko, M. Waligórski, M. Nesladek
Several batches of CVD diamonds obtained commercially from De Beers Company and produced at the Institute of Materials Research at Limburg University (Belgium) have been used in our study. CVD diamonds were investigated with respect to their TL properties Irradiated CVD diamonds feature glow curves in which a dominant peak with a maximum at about 240/spl deg/C can be used for dosimetry, with sensitivity (TL output per Gy) comparable to that of commercial LiF:Mg,Ti (TLD-100, MTS-N) CVD diamonds produced at Limburg University were investigated with respect to their electrical parameters. A special contact preparation technique was developed. Gold contacts were placed on opposite sides of the crystals. The crystals were encapsulated in a special holder. Current and charge were measured by a UNIDOS (PTW Freiburg) electrometer. The bias current of 0.8 mm thick crystals was less than 1 pA.
我们的研究使用了几批从戴比尔斯公司获得的CVD钻石,这些钻石是在比利时林堡大学材料研究所生产的。辐照CVD金刚石具有发光曲线,其中最大峰约为240/spl度/C,可用于剂量测定,灵敏度(每Gy的TL输出)与商业LiF相当:研究了林堡大学生产的Mg,Ti (TLD-100, MTS-N) CVD金刚石的电参数。开发了一种特殊的接触面制备技术。金触点被放置在晶体的两侧。晶体被封装在一个特殊的容器里。电流和电荷由UNIDOS (PTW Freiburg)静电计测量。0.8 mm厚晶体的偏置电流小于1pa。
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引用次数: 0
Cadmium sulfide thin films manufactured by chemical bath deposition method 化学浴沉积法制备硫化镉薄膜
T. Pisarkiewicz, E. Schabowska-Osiowska, E. Kusior
The objective of this work was the investigation of CdS grown by CBD on commercial glass and glass covered by transparent conductive oxide (TCO) substrates. Both TCO and CdS are window layers influencing the photovoltaic response of the cell. CBD technology offers the possibility of the deposition of a thin uniform film with a minimal thickness on a rough substrate surface. CBD growth of CdS using uncoated glass substrates enabled optimization of deposition parameters, e.g. concentrations of CdSO/sub 4/, NH/sub 3/ and thiourea SC(NH/sub 2/), bath temperature and deposition time. Successively glass plates coated with TCO (SnO/sub 2/, ZnO) layers were used as substrates. Both as-grown and air-annealed samples were studied. Investigation of optical transmission in the range 350 - 2200 nm, using Perkin - Elmer Lambda 19 spectrophotometer enabled the evaluation of heat treatment and selected technological parameters on CdS and CdS/ TCO bilayer optical properties. SEM and AFM surface morphology investigations indicate that CdS films reproduce morphology and roughness of the polycrystalline TCO sublayer. That conformal growth and thickness uniformity of cadmium sulfide thin films deposited by CBD technique are presumably the main reasons of their superior quality as buffer layers in CIS solar cells.
本工作的目的是研究CBD在商用玻璃和透明导电氧化物(TCO)衬底玻璃上生长CdS。TCO和CdS都是影响电池光伏响应的窗口层。CBD技术提供了在粗糙的基材表面沉积厚度最小的均匀薄膜的可能性。在非镀膜玻璃基底上生长CdS,优化了沉积参数,如CdSO/sub 4/、NH/sub 3/和硫脲SC(NH/sub 2/)浓度、镀液温度和沉积时间。先后用涂有TCO (SnO/sub 2/, ZnO)层的玻璃板作为衬底。研究了生长样品和空气退火样品。利用Perkin - Elmer Lambda 19分光光度计对CdS和CdS/ TCO双分子层在350 ~ 2200nm范围内的光透射率进行了研究,评价了热处理工艺参数对CdS和CdS/ TCO双分子层光学性能的影响。SEM和AFM表面形貌研究表明,CdS薄膜再现了多晶TCO亚层的形貌和粗糙度。CBD技术沉积的硫化镉薄膜的适形生长和厚度均匀性可能是其作为CIS太阳能电池缓冲层质量优越的主要原因。
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引用次数: 6
FTIR spectroscopy of annealing processes in neutron irradiated diamonds 中子辐照钻石退火过程的FTIR光谱
V. Mironov
Natural diamonds with nitrogen defects at a concentration of about 10/sup 20/ cm/sup -3/ were investigated after irradiation by neutrons at a temperature of 330-340 K at a dose of 10/sup 19/ cm/sup -2/. Detailed thermal perturbations in the 1200-1800 cm/sup -1/ region were investigated by isochronal annealing with 10 min and 50 K steps. The upper temperature limit was 850 K because of oxidation onset. The spectra were rexamined after each annealing step. Immediately after irradiation the crystals were absolutely black, making it impossible to register or determine the GR1 centers concentrations. The first lines to appear were at 1530 and 1370 cm/sup -1/.
用10/sup 19/ cm/sup -2/的中子辐照温度为330 ~ 340 K后,研究了氮缺陷浓度约为10/sup 20/ cm/sup -3/的天然金刚石。在1200 ~ 1800 cm/sup -1/区域用10 min、50 K步长等时退火方法研究了详细的热扰动。由于氧化发生,温度上限为850 K。在每个退火步骤后对光谱进行了重新检查。照射后晶体立即完全变黑,因此无法记录或确定GR1中心的浓度。第一批出现的线条是1530和1370 cm/sup -1/。
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引用次数: 0
SiC/DLC composite layers synthesised by the IPD method 用IPD法合成SiC/DLC复合层
M. Elert, K. Zdunek
Silicon carbide is a wide band gap semiconductor material. Although it has been known for several years, investigators continue to examine it in fundamental as well as application terms. SiC is used in devices operated under high-power, high temperature and high radiation conditions. A typical application of this material is its use as a substrate material in modern opto-electronic devices. The foundation of the SiC structure is a tetrehedral coordination of the atoms of both the elements that form it. The principal phases are: /spl alpha/-SiC (blende structure), and /spl beta/-SiC (wurtzite structure). In addition to these two phases, about 200 phases of SiC have been identified. The paper reports on the studies on the synthesis of SiC layers using the IPD method with the plasma reactants being delivered in various manners. It has been found that the product of the synthesis is a composite material built of a DLC matrix and SiC single crystals of the /spl alpha/-SiC 51R type, with grain sizes of about 100nm. Depending on the silicon dosing method (solid state source, TMS), the silicon content in the layer material ranged from 2 to 13%.
碳化硅是一种宽带隙半导体材料。尽管人们已经知道它好几年了,但研究人员仍在继续从基础和应用方面对它进行研究。SiC用于在高功率、高温和高辐射条件下工作的器件。这种材料的典型应用是在现代光电器件中用作衬底材料。碳化硅结构的基础是构成它的两种元素的原子的四面体配位。主要相为/spl α /-SiC(闪锌矿结构)和/spl β /-SiC(纤锌矿结构)。除了这两种相外,还鉴定出了大约200种碳化硅相。本文报道了等离子体反应物以不同方式输送的IPD法制备SiC层的研究。结果表明,该合成产物是由DLC基体和/spl α /-SiC 51R型SiC单晶构成的复合材料,晶粒尺寸约为100nm。根据硅的添加方法(固态源,TMS),层材料中的硅含量在2%至13%之间。
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引用次数: 0
Plasma processes for formation of electronic structures with wide bandgap material layers 具有宽带隙材料层的电子结构形成的等离子体过程
A. Jakubowski, R. B. Beck, J. Szmidt, A. Werbowy
The authors discuss the role of plasma processing in standard Si vs. wide bandgap materials technology. They consider the specific problems of plasma processing and their consequences in wide band gap semiconductor technology.
作者讨论了等离子体加工在标准硅与宽禁带材料技术中的作用。他们考虑了等离子体加工的具体问题及其对宽带隙半导体技术的影响。
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引用次数: 0
Net-shape diamond growth: applications in optics and electronics 净形金刚石生长:在光学和电子领域的应用
V. Ralchenko
A direct growth of CVD diamond components in order to avoid (or minimize) further surface treatment is considered. This transfer molding technique is based on diamond growth on a patterned substrate, the replica of those patterns being formed on the nucleation side of the diamond film. If the diamond nucleation density is high enough to provide the conformal coating of the microstructured substrate surface the exact replica of the original structure after removal of the substrate can be produced.
为了避免(或最小化)进一步的表面处理,考虑了CVD金刚石组件的直接生长。这种转移成型技术是基于在有图案的衬底上的金刚石生长,这些图案的复制品在金刚石膜的成核侧形成。如果金刚石成核密度足够高,可以在微结构基体表面提供保形涂层,则可以产生去除基体后原始结构的精确复制品。
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引用次数: 0
Amorphous superlattice structures with carbon as a wide bandgap component 以碳为宽禁带组分的非晶超晶格结构
R. Mazurczyk, M. Gazicki
Since the pioneering work of Esaki and Tsu, superlattice (SL) systems have been intensively studied. There are two main difficulties in the technology of crystalline superlattices. One consists in a necessity of using expensive and hazardous deposition processes such as MBE. The second difficulty deals with problem of lattice mismatch between different materials used for the superlattice preparation. Both these difficulties gave rise to an alternative approach to the preparation of superlattice systems from amorphous semiconductors. In this case the problem of lattice mismatch disappears due to the very nature of amorphous state of matter. In this work we present technology used for the deposition of the superlattices based on amorphous hydrogenated carbon-germanium semiconductors (a-Ge/sub x/C/sub y/:H) using plasma decomposition of an organogermanium compound. It has been shown in our previous papers that the optical gap E/sub opt/ (defined by the Tauc law) of a-Ge/sub x/C/sub y/:H materials strongly depend on RF power input into glow discharge. It is obvious then that by application of an alternating power profile one should obtain a structure with periodically varied E/sub opt/. The time-power profile suitable to fulfill this condition was proposed and superlattice structures were deposited in a typical parallel-plate 13.56 MHz glow discharge deposition system. Variable angle-of-incidence spectroscopic ellipsometry (VASE) was used to study both topology and optical properties of the samples. The results of VASE measurements not only confirmed a layered structure of the SL systems but revealed a blue shift effect as well - a phenomenon which can be attributed to quantum confinement of charge carriers in superlattices.
自Esaki和Tsu的开创性工作以来,超晶格(SL)系统得到了广泛的研究。在晶体超晶格技术中有两个主要的难点。一是必须使用昂贵而危险的沉积工艺,如MBE。第二个难点是用于制备超晶格的不同材料之间的晶格不匹配问题。这两个困难产生了一种从非晶半导体制备超晶格系统的替代方法。在这种情况下,由于物质无定形的本质,晶格不匹配的问题消失了。在这项工作中,我们提出了利用等离子体分解有机锗化合物沉积非晶氢化碳锗半导体(a-Ge/sub x/C/sub y/:H)超晶格的技术。在我们之前的论文中已经表明,a-Ge/sub x/C/sub y/:H材料的光隙E/sub opt/(由tac定律定义)强烈依赖于射频功率输入到辉光放电中。很明显,通过应用交流功率分布图,可以得到具有周期性变化的E/sub /的结构。提出了满足这一条件的时间-功率分布,并在典型的平行板13.56 MHz辉光放电沉积系统中沉积了超晶格结构。利用变入射角椭圆偏振光谱(花瓶)研究了样品的拓扑结构和光学性质。花瓶测量的结果不仅证实了SL系统的层状结构,而且还揭示了蓝移效应——这种现象可归因于超晶格中载流子的量子限制。
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引用次数: 0
The study of thermal oxidation of SiC surface SiC表面热氧化的研究
M.T.H. Aung, J. Szmidt, M. Bakowski
The authors report systematic investigation of SiO/sub 2/-SiC interface states for n-type 4H-SiC. MOS capacitors were fabricated on homoepilayers grown on n-type 4H-SiC with wet oxidation followed by wet re-oxidation and postmetallization anneals (PMA).
系统地研究了n型4H-SiC的SiO/sub - 2/-SiC界面态。采用湿氧化、湿再氧化和后金属化退火(PMA)法制备了n型4H-SiC薄膜上的MOS电容器。
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引用次数: 6
Nanocrystalline CsPbCl/sub 3/: grain boundary transport properties 纳米晶CsPbCl/ sub3 /:晶界输运性能
G. Conte, F. Somma, M. Nikl
Recently the ternary compound CsPbCl/sub 3/ produced by co-evaporating CsCl and PbCl/sub 2/ has attracted much interest for its interesting optical characteristics. Indeed, aggregates with dimensions of about 10 nm are produced in the material as evidenced by luminescence spectroscopy and X-ray diffraction. Identification of the aggregates is based on a similarity of the observed emission properties with those of the bulk material. CsPbCl/sub 3/ is a wide-gap semiconductor with direct band-to-band transitions. The phase diagram of the CsCl-PbCl/sub 2/ system reveals the existence of complex ternary CsPbCl/sub 3/ (phase III semiconductor) and Cs/sub 4/PbCl/sub 6/ (phase VI, insulator) compounds. Varying the deposition rate the phase III is deposited together with the insulating phase VI. The crucible temperatures have also been optimized to control the deposition rate in order to achieve the ternary phase III only. The aim of this paper is to report on the preparation, optical and electrical characteristics of bulk and vacuum evaporated ternary compounds. To our knowledge this is the first time that the electrical behaviour in dark and in light is reported for these compounds. The correlation of the aggregate dimensions with the exciton absorption will be also introduced and discussed. X-ray diffraction spectroscopy is used as an independent evidence for aggregated phase creation. Samples used for this study have been grown by vacuum evaporation starting from Bridgman crystal chips of CsPbCl/sub 3/ or by co-evaporation of CsCl and PbCl/sub 2/ purified powders onto 7059 Coming glass substrates.
近年来,由CsCl和PbCl/sub - 2/共蒸发制备的三元化合物CsPbCl/sub - 3/因其有趣的光学特性引起了人们的广泛关注。事实上,发光光谱和x射线衍射证明,材料中产生了尺寸约为10纳米的聚集体。聚集体的识别是基于观测到的发射特性与那些块状材料的相似性。CsPbCl/sub 3/是一种具有直接带到带跃迁的宽间隙半导体。CsPbCl -PbCl/sub - 2/体系的相图揭示了CsPbCl/sub - 3/(相III半导体)和Cs/sub - 4/PbCl/sub - 6/(相VI绝缘体)复合三元化合物的存在。通过改变沉积速率,III相与绝缘相VI一起沉积。为了只得到三元III相,还对坩埚温度进行了优化,以控制沉积速率。本文的目的是报道体蒸发和真空蒸发三元化合物的制备及其光学和电学特性。据我们所知,这是第一次报道这些化合物在黑暗和光线下的电行为。还将介绍和讨论聚集体尺寸与激子吸收的关系。x射线衍射光谱被用作聚集相产生的独立证据。用于本研究的样品是通过真空蒸发从CsPbCl/sub - 3/ Bridgman晶片开始,或通过CsCl和PbCl/sub - 2/纯化粉末在7059 Coming玻璃衬底上共同蒸发来生长的。
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引用次数: 0
AlN for mirror passivation of high power AlGaAs single quantum well separate confinement heterostructure lasers AlN用于高功率AlGaAs单量子阱分离约束异质结构激光器的镜像钝化
A. Jagoda, L. Dobrzański, M. Możdżonek, S. Wróbel
The authors propose AlN dielectric layer as a mirror coating for AlGaAs SQW-SCH laser diodes. As a semitransparent (low reflective - LR) coating they use a single AlN layer, and as a high reflective coating (HR) they use six pairs of AlN-Si layers. The measured reflection coefficients for LR and HR coatings and optical output power characteristics for coated and uncoated mirrors are presented. The optical output power of diodes with coated mirrors is two times higher than the optical power of uncoated diodes.
作者提出AlN介电层作为AlGaAs SQW-SCH激光二极管的镜面涂层。作为半透明(低反射- LR)涂层,他们使用单个AlN层,作为高反射涂层(HR),他们使用六对AlN- si层。给出了涂层和非涂层反射镜的反射系数和光输出功率特性。有涂层反射镜的二极管的光输出功率比无涂层二极管的光输出功率高2倍。
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引用次数: 3
期刊
3rd International Conference 'Novel Applications of Wide Bandgap Layers' Abstract Book (Cat. No.01EX500)
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