Pub Date : 2025-10-01DOI: 10.1016/j.ijggc.2025.104494
Baiyi Li , Kang Long , Wenbo Cheng , Xinghui Fu , Jiayuan Ma , Shuaijie Zhang
Carbon-negative backfilling was proposed to facilitate the co-disposal of the solid waste and CO2, based on the mineralization characteristics of calcium-containing solid waste from coal mining. However, uncertainties remain regarding the carbon sequestration capacity and potential environmental impacts following backfilling. In this study, carbon sequestration tests were conducted with a sealed mixing tank by injecting CO2 into gangue slurry, and the heavy metals leaching from the slurry were recorded. The results indicated that the coal gangue backfilling slurry (CGBS) demonstrated the capacity to absorb 11.17 g·kg⁻¹ of CO2 at an initial pressure of 1 MPa, alongside a decrease in the four kinds of heavy metal concentration. The maximum carbon sequestration and efficiency were observed at 100 °C, yielding 23.49 g·kg⁻¹ and 74.42%, respectively. The leaching content of heavy metals decreased after the CO2 mixing treatment, indicating that the carbonization process significantly mitigates the environmental risks associated with CGBS leakage during underground backfilling, reducing the water exudation of coal gangue slurry and inhibiting the leaching of most heavy metals. This study provides a theoretical foundation for advancing the carbon-negative backfilling techniques and enhancing solid waste resource utilization by mitigating the environmental impact.
{"title":"Experimental investigation into CO2 sequestration and associated ecological behaviours of carbon-negative backfilling with coal gangues","authors":"Baiyi Li , Kang Long , Wenbo Cheng , Xinghui Fu , Jiayuan Ma , Shuaijie Zhang","doi":"10.1016/j.ijggc.2025.104494","DOIUrl":"10.1016/j.ijggc.2025.104494","url":null,"abstract":"<div><div>Carbon-negative backfilling was proposed to facilitate the co-disposal of the solid waste and CO<sub>2</sub>, based on the mineralization characteristics of calcium-containing solid waste from coal mining. However, uncertainties remain regarding the carbon sequestration capacity and potential environmental impacts following backfilling. In this study, carbon sequestration tests were conducted with a sealed mixing tank by injecting CO<sub>2</sub> into gangue slurry, and the heavy metals leaching from the slurry were recorded. The results indicated that the coal gangue backfilling slurry (CGBS) demonstrated the capacity to absorb 11.17 <em>g</em>·kg⁻¹ of CO<sub>2</sub> at an initial pressure of 1 MPa, alongside a decrease in the four kinds of heavy metal concentration. The maximum carbon sequestration and efficiency were observed at 100 °C, yielding 23.49 <em>g</em>·kg⁻¹ and 74.42%, respectively. The leaching content of heavy metals decreased after the CO<sub>2</sub> mixing treatment, indicating that the carbonization process significantly mitigates the environmental risks associated with CGBS leakage during underground backfilling, reducing the water exudation of coal gangue slurry and inhibiting the leaching of most heavy metals. This study provides a theoretical foundation for advancing the carbon-negative backfilling techniques and enhancing solid waste resource utilization by mitigating the environmental impact.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104494"},"PeriodicalIF":5.2,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145325748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01DOI: 10.1016/j.ijggc.2025.104496
Rongbin Li , Abbas Firoozabadi
Low-cost, low concentration, and environmentally friendly thickeners are of great significance for enhancing carbon dioxide (CO2) geological storage efficiency and oil recovery. In this study, a new approach (the accumulator dilution method) is proposed to measure solubility and viscosification of a dozen olefin oligomers and copolymers in supercritical CO2 (scCO2). It is found that the solubility of oligomers and copolymers with different chain lengths and branching structures in scCO2 follows specific trends. The unique branching of these molecules differentiates them from those studied in the literature, enabling new insights into effective viscosification at low concentrations. Among the oligomers, the copolymer of 1-octene and 1-dodecene with an average repeat unit of 32 has high performance, enhancing scCO2 viscosity by approximately 2.5 times at 0.30 wt % at 35 °C and 3500 psi. An important characteristic of the new branched oligomer is high efficiency in both brine and oil displacement in porous media. In CO2 sequestration, the new copolymer can effectively increase the displacement of brine (at 3500 psi and 90 °C) by 32 % and 22 % in horizontal and vertical displacements, respectively. The crude oil (at 3500 psi and 120 °C) recovery is increased by 33 % and 28 % in the secondary and tertiary processes. The combination of effective viscosification and residual liquid saturation reduction makes the new molecule promising for both applications. Future investigations will focus on exploring alternative branching configurations, such as a copolymer of 1-hexene and 1-tetradecene, to achieve improved performance at even lower concentrations and higher viscosification.
{"title":"Enhanced viscosification of supercritical CO2 by a new polyolefin copolymer: Insights from solubility and displacement of brine and oil in porous media flow","authors":"Rongbin Li , Abbas Firoozabadi","doi":"10.1016/j.ijggc.2025.104496","DOIUrl":"10.1016/j.ijggc.2025.104496","url":null,"abstract":"<div><div>Low-cost, low concentration, and environmentally friendly thickeners are of great significance for enhancing carbon dioxide (CO<sub>2</sub>) geological storage efficiency and oil recovery. In this study, a new approach (the accumulator dilution method) is proposed to measure solubility and viscosification of a dozen olefin oligomers and copolymers in supercritical CO<sub>2</sub> (scCO<sub>2</sub>). It is found that the solubility of oligomers and copolymers with different chain lengths and branching structures in scCO<sub>2</sub> follows specific trends. The unique branching of these molecules differentiates them from those studied in the literature, enabling new insights into effective viscosification at low concentrations. Among the oligomers, the copolymer of 1-octene and 1-dodecene with an average repeat unit of 32 has high performance, enhancing scCO<sub>2</sub> viscosity by approximately 2.5 times at 0.30 wt % at 35 °C and 3500 psi. An important characteristic of the new branched oligomer is high efficiency in both brine and oil displacement in porous media. In CO<sub>2</sub> sequestration, the new copolymer can effectively increase the displacement of brine (at 3500 psi and 90 °C) by 32 % and 22 % in horizontal and vertical displacements, respectively. The crude oil (at 3500 psi and 120 °C) recovery is increased by 33 % and 28 % in the secondary and tertiary processes. The combination of effective viscosification and residual liquid saturation reduction makes the new molecule promising for both applications. Future investigations will focus on exploring alternative branching configurations, such as a copolymer of 1-hexene and 1-tetradecene, to achieve improved performance at even lower concentrations and higher viscosification.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104496"},"PeriodicalIF":5.2,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145321372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01DOI: 10.1016/j.ijggc.2025.104497
John D.O. Williams , Somali Roy , Nabarun Pal , Paul Bridger , Vikram Vishal , Kaustav Nag
High-level studies have identified potential for subsurface CO2 storage in India, however lack of detailed technical appraisals aimed at understanding and de-risking the storage resource presents a major challenge to development of CO2 storage. The onshore Cambay Basin has been identified as a promising target for CO2 storage given its history of hydrocarbon production and proximity to emission sources. To expedite subsurface characterisation activities in the region, this study uses a 350 km2 3D seismic volume and well dataset to identify a stratigraphic succession suitable for consideration in a CO2 storage complex. The Middle to Upper Eocene Ankleshwar Formation comprises several potential reservoir and top seal units which may be considered for storage. A high-level assessment of the stratigraphic and structural characteristics of the Ankleshwar Formation is presented, along with a first-order assessment of the principal containment risks and associated uncertainties. Remaining uncertainties are identified along with suggested appraisal activities to reduce uncertainty and further de-risk the storage concept. Whilst there is considerable uncertainty related to the lateral migration of CO2 within the storage system, the high number of legacy wells in the study area presents the most significant risk to CO2 containment.
{"title":"Characterisation of a potential CO2 storage complex and first-order containment risk assessment in the Cambay Basin, India","authors":"John D.O. Williams , Somali Roy , Nabarun Pal , Paul Bridger , Vikram Vishal , Kaustav Nag","doi":"10.1016/j.ijggc.2025.104497","DOIUrl":"10.1016/j.ijggc.2025.104497","url":null,"abstract":"<div><div>High-level studies have identified potential for subsurface CO<sub>2</sub> storage in India, however lack of detailed technical appraisals aimed at understanding and de-risking the storage resource presents a major challenge to development of CO<sub>2</sub> storage. The onshore Cambay Basin has been identified as a promising target for CO<sub>2</sub> storage given its history of hydrocarbon production and proximity to emission sources. To expedite subsurface characterisation activities in the region, this study uses a 350 km<sup>2</sup> 3D seismic volume and well dataset to identify a stratigraphic succession suitable for consideration in a CO<sub>2</sub> storage complex. The Middle to Upper Eocene Ankleshwar Formation comprises several potential reservoir and top seal units which may be considered for storage. A high-level assessment of the stratigraphic and structural characteristics of the Ankleshwar Formation is presented, along with a first-order assessment of the principal containment risks and associated uncertainties. Remaining uncertainties are identified along with suggested appraisal activities to reduce uncertainty and further de-risk the storage concept. Whilst there is considerable uncertainty related to the lateral migration of CO<sub>2</sub> within the storage system, the high number of legacy wells in the study area presents the most significant risk to CO<sub>2</sub> containment.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104497"},"PeriodicalIF":5.2,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145321356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-01DOI: 10.1016/j.ijggc.2025.104477
Zhicheng Wang, Seyyed A. Hosseini, Alexander P. Bump
The injection of CO2 into geological formations can result in pressure interference among different projects. With the increasing number of Geological Carbon Storage (GCS) well applications, new projects will inevitably affect both local and regional pressure distribution. Therefore, it is crucial to model pressure buildup and the associated Area of Review (AoR) before initiating new projects, considering interactions with nearby injection operations. This study employs EASiTool, an analytical tool designed to predict pressure distribution and the associated AoR. We assess basin-scale, multi-site CO2 injection in the Gulf Coast, focusing on potential pressure interference among GCS projects targeting Eocene, Oligocene, Miocene, and Pliocene-age intervals. A key outcome of this work is a map-view representation of AoRs, particularly their shapes. Rather than developing a definitive model, this study explores the use of EASiTool for rapid assessment, providing quick evaluations of pressure interference risks, identifying key variables controlling bottomhole pressure, and assessing the impact of existing Saltwater Disposal (SWD) wells on GCS projects. Our findings indicate that announced projects could collectively alter pressure distribution across large areas, extending far beyond individual AoRs. Visual analyses reveal that overlapping projects may merge AoRs, significantly expanding the pressure footprint. We evaluate pressure interference both among GCS projects (Class VI) and between SWD (Class II) wells and CO2 injection wells. Additionally, a sensitivity analysis examines how varying critical pressure build-up thresholds influence AoR size.
{"title":"Hub scale subsurface fluid injection of GCS and SWD wells: Implications on inter-project interferences and regional pressure buildup","authors":"Zhicheng Wang, Seyyed A. Hosseini, Alexander P. Bump","doi":"10.1016/j.ijggc.2025.104477","DOIUrl":"10.1016/j.ijggc.2025.104477","url":null,"abstract":"<div><div>The injection of CO<sub>2</sub> into geological formations can result in pressure interference among different projects. With the increasing number of Geological Carbon Storage (GCS) well applications, new projects will inevitably affect both local and regional pressure distribution. Therefore, it is crucial to model pressure buildup and the associated Area of Review (AoR) before initiating new projects, considering interactions with nearby injection operations. This study employs EASiTool, an analytical tool designed to predict pressure distribution and the associated AoR. We assess basin-scale, multi-site CO<sub>2</sub> injection in the Gulf Coast, focusing on potential pressure interference among GCS projects targeting Eocene, Oligocene, Miocene, and Pliocene-age intervals. A key outcome of this work is a map-view representation of AoRs, particularly their shapes. Rather than developing a definitive model, this study explores the use of EASiTool for rapid assessment, providing quick evaluations of pressure interference risks, identifying key variables controlling bottomhole pressure, and assessing the impact of existing Saltwater Disposal (SWD) wells on GCS projects. Our findings indicate that announced projects could collectively alter pressure distribution across large areas, extending far beyond individual AoRs. Visual analyses reveal that overlapping projects may merge AoRs, significantly expanding the pressure footprint. We evaluate pressure interference both among GCS projects (Class VI) and between SWD (Class II) wells and CO<sub>2</sub> injection wells. Additionally, a sensitivity analysis examines how varying critical pressure build-up thresholds influence AoR size.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104477"},"PeriodicalIF":5.2,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145217707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-26DOI: 10.1016/j.ijggc.2025.104481
Ana Flávia Monteiro , David Gribble , Ambal Jayaraman , Gokhan Alptekin , Ryan Hughes , Goutham Kotamreddy , Benjamin Omell , Michael Matuszewski , Debangsu Bhattacharyya
In this work, a multi-scale model of a radial flow fixed bed contactor packed with a carbon sorbent is developed and validated with laboratory-scale and pilot plant scale dynamic data. For the lab scale system, the model results were compared with low, medium and high gas and sweep flowrates, yielding root mean square error (RMSE) of 0.80, 0.63, 0.96 CO2 mol%, respectively, for the outlet CO2 concentration profile considering the entire A-D cycle. For the bed outer temperature profile, maximum RMSE was found to be 5.5 °C considering all flowrates and entire A-D cycles. An experimental campaign was developed and applied to a pilot plant at Technology Center Mongstad (TCM), Norway. Approaches were developed for pre-processing of data including consideration of the effect of gas mixing, measurement delay, and determination of cyclic steady-state conditions. Considering profiles during A-D cycles for all test runs, it was found that the maximum RMSE for pressure drop, temperature for the outer section of the bed, temperature for the middle section of the bed, and outlet CO2 concentration profile remained less than 1.5 mbar, 3.5 °C, 2.8 °C, and 1.3 CO2 mol%, respectively. The validated model was used to perform sensitivity studies on several key design operating variables for the adsorption-desorption cycle. It was found that the flow rate and concentration of flue gas have dominant nonlinear effects on the breakthrough time while the desorption time was strongly affected by the sweep gas flowrate for the specific sorbent being evaluated in this study.
本文建立了含碳吸附剂的径向流固定床接触器的多尺度模型,并用实验室规模和中试工厂规模的动态数据进行了验证。对于实验室规模的系统,将模型结果与低、中、高气体和扫描流量进行比较,考虑整个A-D循环的出口CO2浓度曲线的均方根误差(RMSE)分别为0.80、0.63、0.96 CO2 mol%。对于床层外部温度分布,考虑到所有流量和整个A-D循环,最大RMSE为5.5°C。在挪威蒙斯塔德技术中心(TCM)的一个试验工厂开展了一项实验活动并加以应用。开发了数据预处理的方法,包括考虑气体混合的影响、测量延迟和循环稳态条件的确定。考虑所有测试运行的A-D循环的分布情况,发现压力降、床外侧温度、床中部温度和出口CO2浓度分布的最大RMSE分别小于1.5 mbar、3.5°C、2.8°C和1.3 CO2 mol%。该验证模型用于对吸附-解吸循环的几个关键设计操作变量进行敏感性研究。研究发现,烟气流量和浓度对突破时间的非线性影响占主导地位,而对特定吸附剂的脱附时间则受扫气流量的强烈影响。
{"title":"Multi-scale dynamic modeling and validation of radial flow fixed bed contactors for post-combustion CO2 capture using bench scale and pilot plant data","authors":"Ana Flávia Monteiro , David Gribble , Ambal Jayaraman , Gokhan Alptekin , Ryan Hughes , Goutham Kotamreddy , Benjamin Omell , Michael Matuszewski , Debangsu Bhattacharyya","doi":"10.1016/j.ijggc.2025.104481","DOIUrl":"10.1016/j.ijggc.2025.104481","url":null,"abstract":"<div><div>In this work, a multi-scale model of a radial flow fixed bed contactor packed with a carbon sorbent is developed and validated with laboratory-scale and pilot plant scale dynamic data. For the lab scale system, the model results were compared with low, medium and high gas and sweep flowrates, yielding root mean square error (RMSE) of 0.80, 0.63, 0.96 CO<sub>2</sub> mol%, respectively, for the outlet CO<sub>2</sub> concentration profile considering the entire A-D cycle. For the bed outer temperature profile, maximum RMSE was found to be 5.5 °C considering all flowrates and entire A-D cycles. An experimental campaign was developed and applied to a pilot plant at Technology Center Mongstad (TCM), Norway. Approaches were developed for pre-processing of data including consideration of the effect of gas mixing, measurement delay, and determination of cyclic steady-state conditions. Considering profiles during A-D cycles for all test runs, it was found that the maximum RMSE for pressure drop, temperature for the outer section of the bed, temperature for the middle section of the bed, and outlet CO<sub>2</sub> concentration profile remained less than 1.5 mbar, 3.5 °C, 2.8 °C, and 1.3 CO<sub>2</sub> mol%, respectively. The validated model was used to perform sensitivity studies on several key design operating variables for the adsorption-desorption cycle. It was found that the flow rate and concentration of flue gas have dominant nonlinear effects on the breakthrough time while the desorption time was strongly affected by the sweep gas flowrate for the specific sorbent being evaluated in this study.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104481"},"PeriodicalIF":5.2,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-25DOI: 10.1016/j.ijggc.2025.104480
J.A. Ademilola, Jack C. Pashin
Assessing the geomechanical integrity of seals and storage reservoirs is important prior to carbon dioxide (CO2) storage because it can determine the safety of storage, containment and stability of a proposed storage, and helps minimize the possibility of CO2 leakage. This study has integrated simultaneous seismic inversion, multi-attribute transform, and a probabilistic neural network, and uses geophysical well logs to evaluate geomechanical parameters for reservoir and seal integrity assessment of Cenozoic strata. Results indicate that candidate reservoir and seal units identified from wells in the study area possesses greater failure strength than the in-situ stresses and are geomechanically stable. However, there is possibility of tensile failure occurring when the injection get to the mature stage and the effective minimum stress crosses the zero effective normal stress line. Each candidate reservoir storage unit has higher rock strength than its overlying shale layer. The thickness of the caprock units is adequately high to provide effective seal and the thickness of the reservoirs are sufficient to support optimal CO2 storage resources in the study area. The friction angle of Pliocene–Pleistocene strata is adequately high especially in the eastern part of the study area to minimize the risk of fault reactivation and associated deformation. Additional work can be performed to simulate the response of seals, reservoirs, and geomechanical deformation at variable rates and durations of injection.
{"title":"Integrated multi-attribute transform and seismic driven machine learning technique for geomechanical assessment of Cenozoic reservoirs and seal integrity for carbon storage in the Central Gulf of Mexico","authors":"J.A. Ademilola, Jack C. Pashin","doi":"10.1016/j.ijggc.2025.104480","DOIUrl":"10.1016/j.ijggc.2025.104480","url":null,"abstract":"<div><div>Assessing the geomechanical integrity of seals and storage reservoirs is important prior to carbon dioxide (CO<sub>2</sub>) storage because it can determine the safety of storage, containment and stability of a proposed storage, and helps minimize the possibility of CO<sub>2</sub> leakage. This study has integrated simultaneous seismic inversion, multi-attribute transform, and a probabilistic neural network, and uses geophysical well logs to evaluate geomechanical parameters for reservoir and seal integrity assessment of Cenozoic strata. Results indicate that candidate reservoir and seal units identified from wells in the study area possesses greater failure strength than the in-situ stresses and are geomechanically stable. However, there is possibility of tensile failure occurring when the injection get to the mature stage and the effective minimum stress crosses the zero effective normal stress line. Each candidate reservoir storage unit has higher rock strength than its overlying shale layer. The thickness of the caprock units is adequately high to provide effective seal and the thickness of the reservoirs are sufficient to support optimal CO<sub>2</sub> storage resources in the study area. The friction angle of Pliocene–Pleistocene strata is adequately high especially in the eastern part of the study area to minimize the risk of fault reactivation and associated deformation. Additional work can be performed to simulate the response of seals, reservoirs, and geomechanical deformation at variable rates and durations of injection.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104480"},"PeriodicalIF":5.2,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-25DOI: 10.1016/j.ijggc.2025.104472
Alex Marcil , Marc-Antoine Lacroix , Thierry Hotte-Bélanger , Gabriel Vézina , Martin Brouillette
Solid sorbent Direct Air Capture (DAC) technologies face significant challenges due to the high energy demands associated with adsorption and regeneration phases. Overcoming these limitations is essential to improve the scalability and sustainability of carbon removal solutions. This study investigates the performance of a novel sequential moving-bed (SMB) DAC architecture that utilizes solid sorbent cells circulating through three distinct zones: adsorption, regeneration, and heat exchange, in order to increase system duty cycle and allow for heat recovery between sorption and desorption. The primary objective is to evaluate the energy and capture performance of this configuration in comparison to a conventional fixed-bed system, using the same sorbent under the same operating conditions. Compared to a conventional fixed-bed system, the SMB configuration increased CO2 uptake by nearly 30% while reducing total energy intensity by more than 35%, to just over 1000 Wh/kgCO2. These gains are attributed to reduced sorbent working mass, lower pressure drops, and efficient heat recovery. The findings highlight the potential of the SMB approach to enhance the performance and energy efficiency of DAC systems, offering a pathway toward more sustainable and scalable carbon removal solutions.
{"title":"Experimentation of a novel sequential moving-bed DAC System","authors":"Alex Marcil , Marc-Antoine Lacroix , Thierry Hotte-Bélanger , Gabriel Vézina , Martin Brouillette","doi":"10.1016/j.ijggc.2025.104472","DOIUrl":"10.1016/j.ijggc.2025.104472","url":null,"abstract":"<div><div>Solid sorbent Direct Air Capture (DAC) technologies face significant challenges due to the high energy demands associated with adsorption and regeneration phases. Overcoming these limitations is essential to improve the scalability and sustainability of carbon removal solutions. This study investigates the performance of a novel sequential moving-bed (SMB) DAC architecture that utilizes solid sorbent cells circulating through three distinct zones: adsorption, regeneration, and heat exchange, in order to increase system duty cycle and allow for heat recovery between sorption and desorption. The primary objective is to evaluate the energy and capture performance of this configuration in comparison to a conventional fixed-bed system, using the same sorbent under the same operating conditions. Compared to a conventional fixed-bed system, the SMB configuration increased CO<sub>2</sub> uptake by nearly 30% while reducing total energy intensity by more than 35%, to just over 1000 Wh/kgCO<sub>2</sub>. These gains are attributed to reduced sorbent working mass, lower pressure drops, and efficient heat recovery. The findings highlight the potential of the SMB approach to enhance the performance and energy efficiency of DAC systems, offering a pathway toward more sustainable and scalable carbon removal solutions.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104472"},"PeriodicalIF":5.2,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-24DOI: 10.1016/j.ijggc.2025.104460
Arnab Dhara, Sohini Dasgupta, Mrinal K. Sen
Time-lapse seismic data has shown great promise in accurate monitoring of CO2 injection sites. There are many sources of uncertainty in derived rock porosity and CO2 saturation from time lapse seismic data. Variability in noise during data acquisition and noise inherent in seismic data can degrade signal quality and contribute to uncertainty in derived saturation estimates. The process of deriving saturation estimates involves solving an ill-posed, non-unique and highly non-linear seismic petrophysical inversion. Deep learning, particularly utilizing convolutional neural networks (CNNs), has demonstrated potential in addressing such complex and nonlinear seismic inversion challenges. Neural networks frequently find it challenging to offer reliable uncertainty estimates similar to those achieved with Markov Chain Monte Carlo (MCMC) techniques which are widely recognized for their statistical rigor in solving inverse problems. However, MCMC techniques are computationally expensive due to the need for repeated forward model evaluations to adequately sample the posterior distribution. To address this issue, we investigate the use of Invertible Neural Networks (INNs) to predict the full posterior distribution of porosity and CO2 saturation directly from time lapse data and capture the related uncertainty. INNs provide bijective mapping between data (input) and models (output) and uses a latent vector sampled from a Gaussian distribution to model the uncertainty. Our proposed approach is validated using two seismic vintages and well-logs from the Cranfield reservoir.
{"title":"Invertible Neural Networks based petrophysical inversion for carbon sequestration projects","authors":"Arnab Dhara, Sohini Dasgupta, Mrinal K. Sen","doi":"10.1016/j.ijggc.2025.104460","DOIUrl":"10.1016/j.ijggc.2025.104460","url":null,"abstract":"<div><div>Time-lapse seismic data has shown great promise in accurate monitoring of CO<sub>2</sub> injection sites. There are many sources of uncertainty in derived rock porosity and CO<sub>2</sub> saturation from time lapse seismic data. Variability in noise during data acquisition and noise inherent in seismic data can degrade signal quality and contribute to uncertainty in derived saturation estimates. The process of deriving saturation estimates involves solving an ill-posed, non-unique and highly non-linear seismic petrophysical inversion. Deep learning, particularly utilizing convolutional neural networks (CNNs), has demonstrated potential in addressing such complex and nonlinear seismic inversion challenges. Neural networks frequently find it challenging to offer reliable uncertainty estimates similar to those achieved with Markov Chain Monte Carlo (MCMC) techniques which are widely recognized for their statistical rigor in solving inverse problems. However, MCMC techniques are computationally expensive due to the need for repeated forward model evaluations to adequately sample the posterior distribution. To address this issue, we investigate the use of Invertible Neural Networks (INNs) to predict the full posterior distribution of porosity and CO<sub>2</sub> saturation directly from time lapse data and capture the related uncertainty. INNs provide bijective mapping between data (input) and models (output) and uses a latent vector sampled from a Gaussian distribution to model the uncertainty. Our proposed approach is validated using two seismic vintages and well-logs from the Cranfield reservoir.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104460"},"PeriodicalIF":5.2,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-20DOI: 10.1016/j.ijggc.2025.104463
Christopher Deranian , Sahar Bakhshian , Susan D. Hovorka
Maintaining injectivity over the planned duration is a major driver of risk in CO storage projects. Current insurance considerations are largely focused on leakage and well remediation, while operational issues from past carbon storage projects have shown injectivity issues due to unanticipated formation compartmentalization is a real risk. The financial penalty due to the disruption of injection operations is large for a site operator. This study explores the effect of storage compartment size and geologic boundary condition on injectivity, and the subsequent financial implications. Risk profiles of injectivity are generated through reservoir simulations constrained by statistics from a CO storage prospect on the Gulf Coast. A financial tool is built to understand the impact on project value when an injectivity issue occurs and an offset well needs to be drilled. We observe that even in relatively closed boundary conditions, pressure arising from the CO injection can dissipate in the formation to allow injection over the project life. The economic feasibility of a storage project that does face an injectivity issue depends on the year of the injection issue occurrence. This study helps understand the injectivity risk, project contingency, and the financial feasibility of mitigation options required to establish robust assurance against this risk.
{"title":"The financial implications of injectivity risk in compartmentalized storage formations for geologic carbon sequestration","authors":"Christopher Deranian , Sahar Bakhshian , Susan D. Hovorka","doi":"10.1016/j.ijggc.2025.104463","DOIUrl":"10.1016/j.ijggc.2025.104463","url":null,"abstract":"<div><div>Maintaining injectivity over the planned duration is a major driver of risk in CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> storage projects. Current insurance considerations are largely focused on leakage and well remediation, while operational issues from past carbon storage projects have shown injectivity issues due to unanticipated formation compartmentalization is a real risk. The financial penalty due to the disruption of injection operations is large for a site operator. This study explores the effect of storage compartment size and geologic boundary condition on injectivity, and the subsequent financial implications. Risk profiles of injectivity are generated through reservoir simulations constrained by statistics from a CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> storage prospect on the Gulf Coast. A financial tool is built to understand the impact on project value when an injectivity issue occurs and an offset well needs to be drilled. We observe that even in relatively closed boundary conditions, pressure arising from the CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> injection can dissipate in the formation to allow injection over the project life. The economic feasibility of a storage project that does face an injectivity issue depends on the year of the injection issue occurrence. This study helps understand the injectivity risk, project contingency, and the financial feasibility of mitigation options required to establish robust assurance against this risk.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104463"},"PeriodicalIF":5.2,"publicationDate":"2025-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145098136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-09-18DOI: 10.1016/j.ijggc.2025.104471
Julián L. Gómez , Ane Elisabet Lothe
Fault and fracture geometries, densities, and distributions play a critical role in assessing and mitigating risks associated with potential CO₂ storage sites in sedimentary basins, particularly saline aquifers. To enhance fault detection in 3D seismic data, we have developed, trained, and deployed a lightweight machine learning segmentation algorithm. This deep learning model, trained on synthetic seismic data, generates fault scores—pixel-scale classifications ranging from 0 to 1—where higher values indicate a greater likelihood of structural discontinuities. These fault scores are used to derive a fault density attribute, which summarizes the expected fault network distribution along seismic sections. Our workflow is computationally efficient and provides interpreters with valuable insight into the lateral and vertical distribution of faults. We apply this methodology to a 3D seismic survey of the Smeaheia area, Norway, covering the N-S trending Vette Fault and sections of the Øygarden Fault Complex (ØFC). Fault mapping was conducted at the reservoir level, as well as in the caprock and overburden. The detected fault patterns at the top of the Draupne Formation, the presumed caprock unit in the region, and fault pattern at the Top Cromer Knoll Group, align well with manual interpretations. Additionally, in the footwall of the deep-crustal ØFC, we identify faults extending to the seafloor, suggesting that a non-negligible fault density may be present within the caprock. Our results are compared with 3D variance and 3D semblance seismic attributes, further validating the efficacy of our approach.
{"title":"De-risking overburden and caprocks for CO2 storage using machine-learning seismic fault attributes","authors":"Julián L. Gómez , Ane Elisabet Lothe","doi":"10.1016/j.ijggc.2025.104471","DOIUrl":"10.1016/j.ijggc.2025.104471","url":null,"abstract":"<div><div>Fault and fracture geometries, densities, and distributions play a critical role in assessing and mitigating risks associated with potential CO₂ storage sites in sedimentary basins, particularly saline aquifers. To enhance fault detection in 3D seismic data, we have developed, trained, and deployed a lightweight machine learning segmentation algorithm. This deep learning model, trained on synthetic seismic data, generates fault scores—pixel-scale classifications ranging from 0 to 1—where higher values indicate a greater likelihood of structural discontinuities. These fault scores are used to derive a fault density attribute, which summarizes the expected fault network distribution along seismic sections. Our workflow is computationally efficient and provides interpreters with valuable insight into the lateral and vertical distribution of faults. We apply this methodology to a 3D seismic survey of the Smeaheia area, Norway, covering the N-S trending Vette Fault and sections of the Øygarden Fault Complex (ØFC). Fault mapping was conducted at the reservoir level, as well as in the caprock and overburden. The detected fault patterns at the top of the Draupne Formation, the presumed caprock unit in the region, and fault pattern at the Top Cromer Knoll Group, align well with manual interpretations. Additionally, in the footwall of the deep-crustal ØFC, we identify faults extending to the seafloor, suggesting that a non-negligible fault density may be present within the caprock. Our results are compared with 3D variance and 3D semblance seismic attributes, further validating the efficacy of our approach.</div></div>","PeriodicalId":334,"journal":{"name":"International Journal of Greenhouse Gas Control","volume":"147 ","pages":"Article 104471"},"PeriodicalIF":5.2,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145098135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}