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Recycled Surgical Mask Waste as a Resource Material in Sustainable Geopolymer Bricks 将回收的手术面罩废料作为可持续土工聚合物砖的资源材料
IF 4.3 Q2 Environmental Science Pub Date : 2023-11-19 DOI: 10.3390/recycling8060093
Domenico Asprone, Dariusz Mierzwi´nski, Kritish Thoudam, N. Hossiney, Srinidhi Lakshmish Kumar, Jacob Alex, Sanoop Prakasan, Sarath Chandra, Yogeshraj Urs, A. S. Arunkumar
With the advent of the COVID-19 pandemic, the global consumption of single-use surgical masks has risen immensely, and it is expected to grow in the coming years. Simultaneously, the disposal of surgical masks in the environment has caused plastic pollution, and therefore, it is exigent to find innovative ways to handle this problem. In this study, surgical masks were processed in a laboratory using the mechanical grinding method to obtain recycled surgical masks (RSM). The RSM was added in doses of 0%, 1%, 2%, 3%, and 4% by volume of geopolymer bricks, which were synthesized with ground granulated blast furnace slag (GGBS), rice husk ash (RHA), sand, and sodium silicate (Na2SiO3) at ambient conditions for a duration of 28 days. The developed bricks were tested for compressive strength, flexural strength, density, water absorption, efflorescence, and drying shrinkage. The results of the study reveal that compressive strength and flexural strength improved with the inclusion of RSM in the bricks. The highest values of compressive strength and flexural strength were 5.97 MPa and 1.62 MPa for bricks with 4% RSM, respectively. Further, a reduction in the self-weight of the bricks was noticed with an increase in RSM. There was no pronounced effect of RSM on the water absorption and efflorescence properties. However, the RSM played a role in reducing the drying shrinkage of the bricks. The sustainability analysis divulges the catalytic role of RSM in improving material performance, thereby proving to be a potential candidate for low-carbon material in the construction industry.
随着 COVID-19 大流行的到来,一次性外科口罩的全球消费量大幅上升,预计未来几年还将继续增长。与此同时,手术口罩在环境中的弃置也造成了塑料污染,因此迫切需要找到创新的方法来解决这一问题。在这项研究中,我们在实验室中使用机械研磨法处理外科口罩,以获得再生外科口罩(RSM)。在土工聚合物砖中按体积添加 0%、1%、2%、3% 和 4% 的 RSM,土工聚合物砖是用磨细高炉矿渣 (GGBS)、稻壳灰 (RHA)、沙子和硅酸钠 (Na2SiO3) 在环境条件下合成的,持续时间为 28 天。对开发的砖块进行了抗压强度、抗弯强度、密度、吸水率、风化和干燥收缩率测试。研究结果表明,在砖中加入 RSM 后,抗压强度和抗折强度都有所提高。含有 4% RSM 的砖的抗压强度和抗折强度的最高值分别为 5.97 兆帕和 1.62 兆帕。此外,随着 RSM 的增加,砖的自重也有所减轻。RSM 对吸水率和风化性能没有明显影响。不过,RSM 在减少砖的干燥收缩方面发挥了作用。可持续性分析揭示了 RSM 在改善材料性能方面的催化作用,从而证明它是建筑行业低碳材料的潜在候选材料。
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引用次数: 0
Recovery of Kish Graphite from Steelmaking Byproducts with a Multi-Stage Froth Flotation Process 采用多级浮选工艺从炼钢副产品中回收基什石墨
IF 4.3 Q2 Environmental Science Pub Date : 2023-11-18 DOI: 10.3390/recycling8060092
Yingtong Chen, Wei-Ping Chiang, Ping-Yu Hsieh
Steelmaking processes inevitably generate large amounts of byproducts, including slags, specks of dust, etc., and their treatment has been a critical issue for the steelmaking industry. Kish graphite is a valuable substance existing in steelmaking byproducts, and the recovery of Kish graphite has attracted more attention in recent years. The purpose of this study was to use a multi-stage froth flotation process for the beneficiation of Kish graphite and to investigate the influence of flotation conditions on the mass distribution of graphite and impurities. The results showed that the dust D2 contained ~34 wt.% of graphite and thus had the highest potential for the recovery of Kish graphite. The dosages of frother (methyl isobutyl carbinol, MIBC) at 0.005 kg/t and collector (kerosene) at 1 kg/t were optimal for the flotation of Kish graphite. After three-stage froth flotation, the graphite content of the concentrate was progressively increased to 84.09 wt.%, and the entire recovery rate was 93.05%. During the multi-stage froth flotation process, most of the impurities were separated in stage I, but the Fe-containing impurities were mainly separated in stage II. Some Ca2+, Na+, and K+ were leached out, and there were barely any heavy metals in the liquid phases.
炼钢过程中不可避免地会产生大量副产品,包括炉渣、粉尘等,其处理一直是炼钢行业的关键问题。基什石墨是存在于炼钢副产品中的一种有价值的物质,近年来基什石墨的回收引起了越来越多的关注。本研究的目的是采用多级泡沫浮选工艺选矿基什石墨,并研究浮选条件对石墨和杂质质量分布的影响。结果表明,粉尘 D2 含有约 34 重量%的石墨,因此回收基什石墨的潜力最大。浮选剂(甲基异丁基甲醇,MIBC)的用量为 0.005 kg/t,捕收剂(煤油)的用量为 1 kg/t,这两种用量是浮选基什石墨的最佳用量。经过三级泡沫浮选,精矿中的石墨含量逐渐增加到 84.09 wt.%,总回收率为 93.05%。在多级泡沫浮选过程中,大部分杂质在第一阶段分离,但含铁杂质主要在第二阶段分离。部分 Ca2+、Na+ 和 K+ 被浸出,液相中几乎没有重金属。
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引用次数: 0
Exploring the 5Rs Holistic Model for Zero Food Waste in Saudi Arabian Food Service Outlets 探索沙特阿拉伯餐饮服务网点的5Rs零食物浪费整体模式
Q2 Environmental Science Pub Date : 2023-11-11 DOI: 10.3390/recycling8060091
Abu Elnasr E. Sobaih, Ahmed E. Abu Elnasr
Background: The proportion of food waste in the Kingdom of Saudi Arabia, particularly in food service outlets, sends an important and urgent call for a holistic model to either prevent or at least properly manage this high level of food waste. This study draws on the European Union Waste Hierarchy Framework and the United States Environmental Protection Agency Food Recovery Framework to develop a holistic model to manage the high rate of food waste in Saudi food service outlets. Methods: This study adopted the Standards for Reporting Qualitative Research using one-to-one interviews with food service experts to explore the current and appropriate practices for food waste prevention. The in-depth interviews discussed the implementation of the 5Rs hierarchy, which includes reducing food surplus and waste at the source, redistributing food surplus to needy people, reusing food surplus/waste, recycling food waste, and recovering food waste benefits, i.e., bioenergy production. Results: The successful implementation of the 5Rs hierarchy depends on effective collaboration between the key stakeholders, i.e., policy makers, food industry administrators, non-governmental organizations, and customers. The effective management of the food supply chain is also vital to avoid food surplus and prevent waste in food service outlets. Additionally, sustainable production by staff and responsible consumption by consumers contribute effectively to the implementation of the 5Rs model, which contributes to the achievement of zero food waste and, ultimately, to sustainable development. Conclusions: This study provided a novel hierarchy model, which has five tiers, aiming to avoid food waste. The successful implementation of this model will lead to several significant positive impacts on the economy, community, and environment.
背景:沙特阿拉伯王国的食物浪费比例,特别是食品服务网点的食物浪费比例,发出了一个重要而紧迫的呼吁,要求建立一个整体模式,以防止或至少妥善管理这种高水平的食物浪费。本研究借鉴了欧盟废物等级框架和美国环境保护署食物回收框架,开发了一个整体模型来管理沙特食品服务网点的高食物浪费率。方法:本研究采用定性研究报告标准,对餐饮服务专家进行一对一访谈,探讨当前预防食物浪费的适当做法。深入访谈讨论了5Rs层次结构的实施,其中包括从源头减少食物剩余和浪费,将剩余食物重新分配给有需要的人,再利用剩余食物/废物,回收食物废物,以及回收食物废物的效益,即生物能源生产。结果:5Rs层级的成功实施取决于关键利益相关者(即政策制定者、食品行业管理者、非政府组织和客户)之间的有效协作。食品供应链的有效管理对于避免食品过剩和防止食品服务网点的浪费也至关重要。此外,员工的可持续生产和消费者的负责任消费有效地促进了5r模式的实施,从而有助于实现零食物浪费,并最终实现可持续发展。结论:本研究提供了一种新颖的分层模型,该模型分为五层,旨在避免食物浪费。这一模式的成功实施将对经济、社区和环境产生重大的积极影响。
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引用次数: 0
An Overview of Management Status and Recycling Strategies for Plastic Packaging Waste in China 中国塑料包装废弃物管理现状及回收策略综述
Q2 Environmental Science Pub Date : 2023-11-11 DOI: 10.3390/recycling8060090
Chaojie Yu, Diyi Jin, Xichao Hu, Wenzhi He, Guangming Li
Given their exceptional performance, plastic packaging products are widely used in daily life, and the dramatic expansion in plastic packaging waste (PPW) has exacerbated environmental problems. Many countries have enacted laws and developed recycling technologies to manage plastic packaging waste in consideration of the nature of PPW as both garbage and a resource. As the world’s largest producer and consumer of plastics, China has also taken measures to address this issue. This paper presents the latest management regulations and recycling strategies for PPW in China. Based on an analysis of the current management status of PPW and recycling technologies and their carbon emission impacts, some management suggestions and a comprehensive full-chain recycling process were put forward. We supposed that management challenges that need to be overcome in the future can be solved through the improvement of green designs for plastic packaging, manufacturing technology updates, consumption concept changes, and the high-value utilization of PPW. This paper aims to provide valuable references for government decisions on PPW management and, furthermore, to set up an economically sensible and industrially feasible PPW solution and boost the development of PPW recycling.
由于塑料包装产品具有优异的性能,在日常生活中得到了广泛的应用,塑料包装废弃物的急剧增加加剧了环境问题。考虑到塑料包装废弃物既是垃圾又是资源,许多国家都制定了法律和开发了回收技术来管理塑料包装废弃物。作为世界上最大的塑料生产国和消费国,中国也在采取措施解决这一问题。本文介绍了中国最新的PPW管理法规和回收策略。在分析PPW和回收技术的管理现状及其对碳排放影响的基础上,提出了管理建议和全面的全链回收流程。我们认为,未来需要克服的管理挑战可以通过塑料包装绿色设计的改进、制造技术的更新、消费观念的转变以及PPW的高价值利用来解决。本文旨在为政府制定PPW管理决策提供有价值的参考,进而建立经济上合理、工业上可行的PPW解决方案,促进PPW回收利用的发展。
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引用次数: 0
Automated Battery Disassembly—Examination of the Product- and Process-Related Challenges for Automotive Traction Batteries 电池自动拆卸——汽车牵引电池产品和工艺相关挑战的研究
Q2 Environmental Science Pub Date : 2023-11-08 DOI: 10.3390/recycling8060089
Domenic Klohs, Christian Offermanns, Heiner Heimes, Achim Kampker
As the market share of electric vehicles continues to rise, the number of battery systems that are retired after their service life in the vehicle will also increase. This large growth in battery returns will also have a noticeable impact on processes such as battery disassembly. The purpose of this paper is, therefore, to examine the challenges of the battery disassembly process in relation to the required increase in the degree of automation. For this purpose, a survey of various experts along the battery value chain was conducted, and product-side hurdles, such as the wide range of variants, and process-side challenges, such as the opening of the housing cover or the removal of cables and connectors, were identified. Together with an assessment of the potential degree of automation in the context of downstream processes (reuse, repair, remanufacturing, and recycling), this results in a variety of streams for future research in the field of automated battery disassembly. The core aspect in this context is data availability consisting of product and component data as well as process-relevant parameters.
随着电动汽车市场份额的不断上升,超过车辆使用寿命的电池系统也将越来越多。电池回报的大幅增长也将对电池拆卸等工艺产生显著影响。因此,本文的目的是研究与所需的自动化程度增加有关的电池拆卸过程的挑战。为此,对电池价值链上的各种专家进行了调查,并确定了产品方面的障碍,例如各种型号,以及工艺方面的挑战,例如打开外壳盖或拆除电缆和连接器。再加上对下游过程(再利用、维修、再制造和回收)中潜在自动化程度的评估,这就为自动化电池拆卸领域的未来研究提供了多种思路。这种情况下的核心方面是由产品和组件数据以及与流程相关的参数组成的数据可用性。
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引用次数: 0
Recent Recycling Innovations to Facilitate Sustainable Packaging Materials: A Review 最近的回收创新促进可持续包装材料:综述
Q2 Environmental Science Pub Date : 2023-11-07 DOI: 10.3390/recycling8060088
Idowu D. Ibrahim, Emmanuel R. Sadiku, Yskandar Hamam, Williams K. Kupolati, Julius M. Ndambuki, Tamba Jamiru, Azunna A. Eze, Jacques Snyman
Packaging materials play a significant role in the meat, fish, and seafood, pharmaceutical, beverages, and electronics industries. These materials protect the contents during handling and transportation from damage, contamination, and loss of quality, thus enhancing the shelf life of the products being packaged. Several materials, like paper and cardboard, plastics, metals, and glass, have been widely used. However, the vast consumption of these materials leads to high waste generation due to increasing demands globally. This article considers some aspects of recycling waste packaging materials, the need for recycling in terms of environmental impacts, and the energy-saving and economic benefits. It also provides some highlights on the sustainability of the processes of recycling and how the government and public can influence recycling operations. The impact of the COVID-19 pandemic on packaging systems and solid waste management is also highlighted. This study also provides a short note on the possible future methods to be adopted in the recycling process of waste packaging materials.
包装材料在肉类、鱼类和海鲜、制药、饮料和电子工业中发挥着重要作用。这些材料在搬运和运输过程中保护内容物免受损坏、污染和质量损失,从而延长了被包装产品的保质期。一些材料,如纸和纸板、塑料、金属和玻璃,已经被广泛使用。然而,由于全球需求的增加,这些材料的大量消耗导致了高废物的产生。本文考虑了废旧包装材料回收利用的几个方面,回收利用对环境的影响,以及节能和经济效益。报告亦重点介绍回收过程的可持续性,以及政府和公众如何影响回收工作。报告还强调了2019冠状病毒病大流行对包装系统和固体废物管理的影响。本研究也提供了一个简短的说明,在废弃包装材料的回收过程中,未来可能采用的方法。
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引用次数: 0
Safety Assessment of Recycled Plastics from Post-Consumer Waste with a Combination of a Miniaturized Ames Test and Chromatographic Analysis 小型Ames试验与色谱分析相结合对消费后废弃物中再生塑料的安全性评价
Q2 Environmental Science Pub Date : 2023-11-04 DOI: 10.3390/recycling8060087
Elisa Mayrhofer, Lukas Prielinger, Victor Sharp, Bernhard Rainer, Christian Kirchnawy, Christian Rung, Anita Gruner, Mladen Juric, Arielle Springer
European circular economy goals require the use of recycled polymers in sensitive applications such as food packaging. As plastic recyclates can contain unknown post-consumer substances, the European Food Safety Authority evaluates recycling processes using a worst-case assumption: all contaminants are DNA-reactive mutagens/carcinogens with extremely low safety thresholds. The current data are insufficient to estimate whether this assumption is justified. To provide scientific evidence on the presence of DNA-reactive mutagens in recycled plastics, 119 input and output samples from plastic recycling were tested with a miniaturized Ames test. DNA-reactive mutagens were not detected in recycled polyethylene terephthalate, which is already approved for food contact. However, other types of recycled plastics (polyethylene, polypropylene and polystyrene), which are currently unauthorized for food contact, showed DNA-reactive, mutagenic effects in a total of 51 samples. The DNA-reactive substances that are responsible for the detected mutagenic activity could not be identified by comparison of the bioassay data with analytical results from a chromatographical screening. The data from the Ames test analysis of different independent batches and a comparison of input and output material indicate that the DNA-reactive contaminants are not randomly introduced through the misuse of recycled packaging by consumers, but are systematically formed during the recycling process from precursors in the input. This publication highlights the need to identify the source for this critical contaminant to enable the future use of polyethylene, polypropylene and polystyrene in sensitive applications.
欧洲循环经济目标要求在食品包装等敏感应用中使用回收聚合物。由于塑料回收物可能含有未知的消费后物质,欧洲食品安全局使用最坏的假设来评估回收过程:所有污染物都是dna反应性诱变剂/致癌物,安全阈值极低。目前的数据不足以估计这一假设是否合理。为了提供关于回收塑料中存在dna反应性诱变剂的科学证据,使用小型Ames试验对回收塑料的119个输入和输出样品进行了测试。在已被批准用于食品接触的回收聚对苯二甲酸乙二醇酯中未检测到dna反应性诱变剂。然而,其他类型的回收塑料(聚乙烯、聚丙烯和聚苯乙烯)目前未经批准用于食品接触,在总共51个样本中显示出dna反应性和诱变效应。通过将生物测定数据与色谱筛选的分析结果进行比较,无法确定导致检测到的致突变活性的dna反应性物质。不同独立批次的Ames测试分析数据以及输入和输出材料的对比表明,dna反应性污染物不是通过消费者滥用回收包装而随机引入的,而是在回收过程中由输入中的前体系统形成的。本出版物强调需要确定这种关键污染物的来源,以便将来在敏感应用中使用聚乙烯,聚丙烯和聚苯乙烯。
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引用次数: 0
A Systematic Literature Review of Waste Identification in Automatic Separation Systems 自动分类系统中废物识别的系统文献综述
Q2 Environmental Science Pub Date : 2023-11-02 DOI: 10.3390/recycling8060086
Juan Carlos Arbeláez-Estrada, Paola Vallejo, Jose Aguilar, Marta Silvia Tabares-Betancur, David Ríos-Zapata, Santiago Ruiz-Arenas, Elizabeth Rendón-Vélez
Proper waste separation is essential for recycling. However, it can be challenging to identify waste materials accurately, especially in real-world settings. In this study, a systematic literature review (SLR) was carried out to identify the physical enablers (sensors and computing devices), datasets, and machine learning (ML) algorithms used for waste identification in indirect separation systems. This review analyzed 55 studies, following the Kitchenham guidelines. The SLR identified three levels of autonomy in waste segregation systems: full, moderate, and low. Edge computing devices are the most widely used for data processing (9 of 17 studies). Five types of sensors are used for waste identification: inductive, capacitive, image-based, sound-based, and weight-based sensors. Visible-image-based sensors are the most common in the literature. Single classification is the most popular dataset type (65%), followed by bounding box detection (22.5%). Convolutional neural networks (CNNs) are the most commonly used ML technique for waste identification (24 out of 26 articles). One of the main conclusions is that waste identification faces challenges with real-world complexity, limited data in datasets, and a lack of detailed waste categorization. Future work in waste identification should focus on deployment and testing in non-controlled environments, expanding system functionalities, and exploring sensor fusion.
适当的废物分类对回收是必不可少的。然而,准确识别废物可能是一项挑战,尤其是在现实环境中。在本研究中,进行了系统的文献综述(SLR),以确定间接分离系统中用于废物识别的物理使能器(传感器和计算设备)、数据集和机器学习(ML)算法。这篇综述分析了55项研究,遵循了Kitchenham指南。SLR确定了废物分类系统的三个自治水平:完全、中等和低。边缘计算设备在数据处理方面的应用最为广泛(17项研究中有9项)。五种类型的传感器用于废物识别:电感式、电容式、基于图像的、基于声音的和基于重量的传感器。基于可见图像的传感器在文献中是最常见的。单一分类是最流行的数据集类型(65%),其次是边界框检测(22.5%)。卷积神经网络(cnn)是垃圾识别中最常用的ML技术(26篇文章中有24篇)。其中一个主要结论是,废物识别面临着现实世界复杂性、数据集中数据有限以及缺乏详细废物分类的挑战。未来的废物识别工作应侧重于在非受控环境中的部署和测试,扩展系统功能,探索传感器融合。
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引用次数: 0
X-ray Fluorescence Analysis of Waste Sm-Co Magnets: A Rational Approach 废钐钴磁体的x射线荧光分析:一种合理的方法
Q2 Environmental Science Pub Date : 2023-11-01 DOI: 10.3390/recycling8060084
Alexandra Alexandrovna Arkhipenko, Galina Evgenievna Marina, Marina Sergeevna Doronina, Natalya Alexandrovna Korotkova, Vasilisa Borisovna Baranovskaya
Determination of the chemical composition of waste Sm-Co magnets is required for their efficient recycling. The non-stereotypical composition of said magnets makes an analysis extremely challenging. X-ray fluorescence spectrometry is a promising analytical tool for this task. It offers high accuracy and simplicity of sample preparation as it does not require sample dissolution. However, a serious limitation of X-ray fluorescence analysis is the spectral interference of matrix elements and impurities. In this work, a two-stage technique has been developed for the determination of the main components (Sm, Co) and impurities (Fe, Cu, Zr, Hf, Ti, Ni, Mn, Cr) in samples of spent samarium–cobalt magnets using wavelength dispersive X-ray fluorescence spectrometry. In order to overcome the main limitation of the chosen method and to maximize its capabilities of qualitative and quantitative analysis, we propose an approach to the selection of analytical lines and experimental conditions, as well as a preparation method for the calibration standards. The obtained results have been shown to have a good correlation with ICP-OES. The limits of detection are in the range of 0.001–0.02 wt%, and the limits of quantification are 0.003–0.08 wt%.
废钐钴磁体的化学成分测定是有效回收废钐钴磁体的必要条件。所述磁铁的非定型成分使分析极具挑战性。x射线荧光光谱法是一种很有前途的分析工具。它提供了高精度和简单的样品制备,因为它不需要样品溶解。然而,x射线荧光分析的一个严重限制是基体元素和杂质的光谱干扰。在这项工作中,开发了一种两阶段技术,用于使用波长色散x射线荧光光谱法测定废钐钴磁体样品中的主要成分(Sm, Co)和杂质(Fe, Cu, Zr, Hf, Ti, Ni, Mn, Cr)。为了克服所选方法的主要局限性,最大限度地提高其定性和定量分析的能力,我们提出了一种分析线和实验条件的选择方法,以及校准标准品的制备方法。所得结果与ICP-OES具有良好的相关性。检出限为0.001 ~ 0.02 wt%,定量限为0.003 ~ 0.08 wt%。
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引用次数: 0
Gravity Concentration in Urban Mining Applications—A Review 重力集中在城市采矿中的应用综述
Q2 Environmental Science Pub Date : 2023-11-01 DOI: 10.3390/recycling8060085
Weslei M. Ambrós
Urban mining has emerged as a concept that goes beyond conventional recycling, as it aims to tackle both the challenges of solid waste generation and management, as well as the scarcity of primary resources. Gravity concentration has gained increasing attention as a promising method for addressing crucial challenges in urban mining applications. In this sense, this review provides a comprehensive and up-to-date overview of gravity concentration in urban mining processes, covering principles, techniques, current applications, recent advancements, challenges, and opportunities. Emphasis was placed on shifting from the commonly found literature focus on ore processing to solid waste processing. Three types of solid waste, namely plastics, construction and demolition waste (CDW), and waste from electrical and electronic equipment (WEEE), were chosen for a more in-depth examination due to their massive production and widespread generation. Discussions also considered the potential of gravity concentration to address the unique challenges in their processing and explored possibilities for future developments.
城市采矿已经成为一个超越传统回收的概念,因为它旨在解决固体废物产生和管理的挑战,以及初级资源的稀缺。重力集中作为解决城市采矿应用中关键挑战的一种有前途的方法,越来越受到重视。从这个意义上说,本综述提供了城市采矿过程中重力集中的全面和最新概述,包括原理,技术,当前应用,最近的进展,挑战和机遇。重点放在从通常发现的文献集中于矿石处理转移到固体废物处理。三种固体废物,即塑料,建筑和拆除废物(CDW)和电气和电子设备废物(WEEE),被选中进行更深入的研究,因为它们的大量生产和广泛产生。讨论还考虑了重力浓缩的潜力,以解决其加工过程中的独特挑战,并探讨了未来发展的可能性。
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引用次数: 0
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Recycling
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