Materials Today最新文献_第2页

A facile construction of LiF interlayer and F-doping via PECVD for LATP-based hybrid electrolytes: Enhanced Li-ion transport kinetics and superior lithium metal compatibility 通过PECVD快速构建基于latp的混合电解质的liff中间层和f掺杂：增强的锂离子传输动力学和优越的锂金属相容性

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.10.003

Xian-Ao Li , Yiwei Xu , Kepin Zhu , Yang Wang , Ziqi Zhao , Shengwei Dong , Bin Wu , Hua Huo , Shuaifeng Lou , Xinhui Xia , Xin Liu , Minghua Chen , Stefano Passerini , Zhen Chen

Hybrid solid-liquid electrolytes show promise in resolving interfacial side reactions and poor electrode|electrolyte contact of solid-state batteries. However, the energy barrier between the liquid and the solid-state electrolytes impedes Li-ion migration, reducing Li⁺ transport efficiency and overall battery performance. Here, we propose a modification strategy using plasma-enhanced chemical vapor deposition (PECVD) technology with fluoroethylene carbonate as the fluorine source, enabling in situ construction of a LiF buffer layer and F-doping on the Li_1.3Al_0.3Ti_1.7P₃O₁₂ (LATP) skeleton. Computational analyses reveal that F-doping activates additional Li-ion migration pathways, enhances ionic conductivity, and suppresses Li dendrite growth. The LiF layer prevents electron penetration and direct contact between LATP and Li metal, while also reducing the desolvation energy barrier to improve Li-ion transport across the solid|liquid interface with aids of F-doping. Consequently, Li||Li cells demonstrate stable cycling for 9000 h at 0.1 mA cm^–² and a critical current density of 2.2 mA cm^–². Furthermore, full cells paired with LiFePO₄ and LiNi_0.8Co_0.1Mn_0.1O₂ cathodes retain 81.3 % and 67.2 % of their initial capacity after 300 cycles at 0.5 C. This study highlights the potential of PECVD technology for optimizing the interfaces of solid-state electrolytes, offering new insights into advancing next generation lithium metal battery performance.

固液混合电解质在解决固态电池的界面副反应和电极与电解质接触不良等问题上具有广阔的前景。然而，液态和固态电解质之间的能量屏障阻碍了锂离子的迁移，降低了锂离子的传输效率和电池的整体性能。本文提出了一种采用等离子体增强化学气相沉积（PECVD）技术的改性策略，以氟乙烯碳酸酯为氟源，在Li1.3Al0.3Ti1.7P3O12 （LATP）骨架上原位构建LiF缓冲层并掺杂f。计算分析表明，f掺杂激活了额外的锂离子迁移途径，增强了离子电导率，抑制了锂枝晶的生长。LiF层阻止了电子渗透和LATP与Li金属之间的直接接触，同时也降低了脱溶能垒，通过f掺杂提高了Li离子在固体|液体界面上的输运。因此，Li||锂电池在0.1 mA cm-2下稳定循环9000小时，临界电流密度为2.2 mA cm-2。此外，在0.5 c下循环300次后，与LiFePO4和LiNi0.8Co0.1Mn0.1O2阴极配对的完整电池保留了81.3%和67.2%的初始容量。这项研究强调了PECVD技术在优化固态电解质界面方面的潜力，为推进下一代锂金属电池的性能提供了新的见解。

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引用次数: 0

Electrochemical nitrate-to-ammonia conversion: Mechanisms, electrocatalyst design, and system-level strategies for sustainable nitrogen chemistry 电化学硝酸盐到氨的转化：机制，电催化剂设计，和可持续氮化学的系统级策略

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.11.012

Wenjing Huang , Jiandong Yao , Hao Wu , Yanguang Li , Shaoming Huang

Electrochemical ammonia (NH₃) synthesis via the nitrate reduction reaction (NO₃⁻RR) under ambient conditions has emerged as a compelling alternative to the energy-intensive Haber-Bosch (H-B) process. Despite its promise, the design of efficient electrocatalysts for NO₃⁻RR, particularly those powered by renewable energy, remains in its infancy. Achieving simultaneously high activity, selectivity, and operational stability continues to be a key bottleneck. This review provides a critical overview of the mechanistic underpinnings of NO₃⁻RR to NH₃ and identifies key physicochemical parameters governing catalytic performance. Recent developments in catalyst design are systematically examined, emphasizing structure–activity correlations that enable targeted performance enhancement. Progress in system-level innovations-ranging from paired electrolysis strategies to efficient energy storage platforms is also discussed. The review concludes by outlining emerging directions and knowledge gaps to accelerate the deployment of NO₃⁻RR-based NH₃ production technologies. Overall, this work offers a comprehensive perspective on the current status and future prospects of sustainable NH₃ synthesis via NO₃⁻RR, aligning with global efforts toward carbon neutrality.

在环境条件下，通过硝酸盐还原反应（NO3−RR）合成氨（NH3）已成为能源密集型Haber-Bosch （H-B）工艺的一个令人信服的替代方案。尽管前景光明，但NO3−RR高效电催化剂的设计，特别是那些由可再生能源驱动的电催化剂，仍处于起步阶段。同时实现高活动性、选择性和操作稳定性仍然是一个关键的瓶颈。本文综述了NO3 - RR转化为NH3的机理基础，并确定了控制催化性能的关键物理化学参数。系统地检查了催化剂设计的最新发展，强调了结构-活性相关性，从而能够有针对性地提高性能。还讨论了系统级创新的进展，从配对电解策略到高效储能平台。报告最后概述了加快部署基于NO3−r的NH3生产技术的新兴方向和知识差距。总的来说，这项工作为通过NO3 - RR可持续合成NH3的现状和未来前景提供了一个全面的视角，与全球碳中和的努力保持一致。

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引用次数: 0

The evolution of MOF discovery for CO2 capture: From high-throughput screening to AI design and automated laboratories 二氧化碳捕获MOF发现的演变：从高通量筛选到人工智能设计和自动化实验室

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.10.017

Yong Qiu , Lei Wang , Chang Liu , Xu Zhang , Yun Tian , Zhen Zhou

As a predominant greenhouse gas, CO₂ has emerged as a critical environmental challenge on a global scale. Metal-organic frameworks (MOFs), with their large surface area, high pore volume, and tunable structure, exhibit extraordinary potential in CO₂ capture. Despite advances in CO₂ capture, lack of systematic understanding of inherent mechanisms governing framework flexibility and kinetic behavior in the guest–host system has largely impeded the practical applications. Although most existing work is still at the preliminary stage of brute-force material screening with limited integration of machine learning and theoretical calculations to solve these long-standing problems, AI-driven automated experimentation integrated with intelligent design framework has brought promising solutions, making it possible to bridge the gap between structural properties and separation performance. This review summarizes recent advances in machine learning, theoretical methods, and automated laboratories for CO₂ capture with MOFs, highlighting the paradigm shift from theoretical computation to AI-driven automated experimentation.

作为一种主要的温室气体，二氧化碳已成为全球范围内的重大环境挑战。金属有机骨架（mof）具有大表面积、高孔隙体积和可调结构，在二氧化碳捕获方面具有非凡的潜力。尽管CO2捕集技术取得了进展，但由于缺乏对主客系统中控制框架灵活性和动力学行为的内在机制的系统理解，在很大程度上阻碍了实际应用。虽然现有的大多数工作仍处于暴力筛选材料的初步阶段，机器学习和理论计算的结合有限，以解决这些长期存在的问题，但人工智能驱动的自动化实验与智能设计框架相结合，带来了有希望的解决方案，使弥合结构性能和分离性能之间的差距成为可能。本文总结了mof在机器学习、理论方法和二氧化碳捕获自动化实验室方面的最新进展，强调了从理论计算到人工智能驱动的自动化实验的范式转变。

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引用次数: 0

Ultra-thin high-resolution transfer-printed breathable electronics for conformal wearable devices 用于适形可穿戴设备的超薄高分辨率转移印刷透气电子产品

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.10.008

Hyeokjoo Choi , Dongju Lee , Sieun Hwang , Juhee Shin , Jihoon Bae , Gain Jang , Seokhun Kwon , Hyunil Kang , Jihyeon Myeong , Youngtae Jeong , Jong Wook Roh , Sungwon Lee

Nanomesh electronics offer remarkable potential for biomedical and human–machine interface applications due to their conformability to nonplanar surfaces, versatile functionality, and long-term reliability. However, existing materials face significant challenges related to surface structure and chemical resistance, resulting in high electrical resistance and complex fabrication requirements. To address these challenges, we present transfer-printed nanomesh electrodes (NEs) produced by integrating fine-patterned 2D electrodes with porous nanomesh. Electrospun thermoplastic-polyurethane nanofibers provide strong adhesion to the electrodes, which generate sufficient force (95.1 mN∙cm⁻¹) to maintain structural integrity and electrical performance. Unlike direct deposition, which requires a minimum thickness of 100 nm to achieve 14.12 ± 2 mS, transfer-printed NEs reach 16.91 ± 8.7 mS only with 20 nm. Furthermore, our electrodes demonstrate excellent durability under deformation, maintaining stable electrical performance with only a 0.53 % change at a bending radius of 1 mm. To validate their practical application, we demonstrate a NE-based tactile sensor, which exhibits a conductance change from 0 mS in the normal state to 130 mS upon touch. These results highlight the potential of transfer-printed NEs for next-generation e-skin with fine patterning, high conductivity, and long-term reliability. In addition, our novel method addresses the challenges of manufacturing breathable devices with functionalities extending beyond simple electrodes.

纳米电子产品由于其与非平面表面的一致性、多功能和长期可靠性，在生物医学和人机界面应用方面具有显着的潜力。然而，现有材料面临着与表面结构和耐化学性相关的重大挑战，导致高电阻和复杂的制造要求。为了解决这些挑战，我们提出了通过将精细图案的二维电极与多孔纳米网集成而产生的转移印刷纳米电极（NEs）。电纺丝热塑性聚氨酯纳米纤维对电极具有很强的附着力，产生足够的力（95.1 mN∙cm−1）以保持结构完整性和电性能。直接沉积需要最小厚度为100 nm才能达到14.12±2 mS，而转移打印的ne仅需20 nm即可达到16.91±8.7 mS。此外，我们的电极在变形下表现出优异的耐久性，在弯曲半径为1毫米时保持稳定的电气性能，仅变化0.53%。为了验证其实际应用，我们展示了一个基于ne的触觉传感器，其电导从正常状态的0 mS变化到触摸时的130 mS。这些结果突出了转移打印NEs在下一代电子皮肤中的潜力，具有精细的图案，高导电性和长期可靠性。此外，我们的新方法解决了制造功能超越简单电极的透气设备的挑战。

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引用次数: 0

Experimental and computational advancement of cathode materials for futuristic sodium ion batteries 未来钠离子电池正极材料的实验与计算进展

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2023.06.013

Jena Akash Kumar Satrughna , Archana Kanwade , Abhishek Srivastava , Manish Kumar Tiwari , Subhash Chand Yadav , Surya Teja Akula , Parasharam M. Shirage

Owing to the earth’s abundance and wide availability of natural sodium sources, sodium-ion batteries (SIBs) are potential alternatives to lithium-ion batteries (LIBs). SIBs showcase similar chemistry to LIBs making them likely competitors for smart grid-scale and large-scale energy storage systems. The performance and practical development of SIBs are dependent upon selecting suitable electrodes, electrolytes, additives, and binder materials. This review summarizes the advancement of various cathode materials for SIBs along with other crucial components. Approaches used to improve the electrochemical performance of cathode materials are discussed along with critical challenges and assessments to boost the development of SIBs. We discuss past and present research on advanced cathode materials and propose future strategies for the betterment of SIBs. A major focus is given to theoretical along with experimental work on cathode materials. This review article provides a detailed explanation of the theoretical calculation such as the energy band structure, total density of states, partial/projected density of states, Na⁺ storage mechanism, and stability through density functional theory (DFT) for various cathode materials. We hope and believe this article will light on some insights into the basic of SIBs and the development of advanced cathode materials.

由于地球上天然钠资源丰富且广泛可用，钠离子电池（SIBs）是锂离子电池（lib）的潜在替代品。sib显示出与lib类似的化学反应，使它们可能成为智能电网规模和大规模能源存储系统的竞争对手。sib的性能和实际发展取决于选择合适的电极、电解质、添加剂和粘结材料。本文综述了sib阴极材料及其关键部件的研究进展。讨论了提高阴极材料电化学性能的方法，以及促进阴极材料发展的关键挑战和评估。我们讨论了先进阴极材料的过去和现在的研究，并提出了未来的策略，以改善sib。主要集中在阴极材料的理论和实验工作上。本文综述了利用密度泛函理论（DFT）对各种正极材料的能带结构、总态密度、部分/投射态密度、Na+的储存机制和稳定性等理论计算方法。我们希望并相信本文将对sib的基本原理和先进阴极材料的发展有所启发。

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引用次数: 0

Correlating metal migration with phase change behaviors in sodium layered oxide cathodes 钠层状氧化物阴极中金属迁移与相变行为的关系

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.09.026

Zibin Liang , Chuying Ouyang , Xiaonan Luo , Longze Li , Min Lin , Sulan Cheng , Liangjie Xu , He Zhao , Qiang Li , Shaofei Wang , Bo Xu , Xinxin Zhang , Bingkun Guo , Kai Wu

The phase changes of sodium layered oxide (SLO) cathodes occurring at high voltage could raise structural instability and oxidative activity with electrolyte. Understanding the evolving processes and key influence factors of these phase changes is critical to find targeted strategies for improvements. Herein, we demonstrate that metal migration, a frequently overlooked influence factor, can induce gliding of transition metal layers and thus a P to O phase transition. Also, the thermodynamic voltage, Na⁺ distribution, and lattice change induced by the P to O phase transition can be finely tuned by adjusting the metal migration properties. As a proof-of-concept, an O3-type SLO cathode with an O3 solid-solution phase transition induced by Zn migration is designed, which exhibits a high reversible capacity of 139 mAh/g at 4.1 V in pouch-type sodium-ion full cells along with excellent cycling stability, enhanced rate capability, and greatly suppressed gas evolution.

层状氧化钠（SLO）阴极在高压下发生的相变会增加结构的不稳定性和与电解质的氧化活性。了解这些阶段变化的演变过程和关键影响因素对于找到有针对性的改进策略至关重要。在此，我们证明了金属迁移，一个经常被忽视的影响因素，可以诱导过渡金属层的滑动，从而导致P到O的相变。此外，可以通过调整金属迁移特性来精细调节由P到O相变引起的热力学电压、Na+分布和晶格变化。作为概念验证，设计了一种具有Zn迁移诱导的O3固溶相变的O3型SLO阴极，该阴极在4.1 V时具有139 mAh/g的高可逆容量，并且具有良好的循环稳定性，提高了倍率能力，并大大抑制了气体的析出。

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引用次数: 0

Scalable low-emissivity and RF-transparent dielectric coatings for year-round energy-saving buildings under all weather conditions 可伸缩的低发射率和rf透明介电涂料，适用于全天候节能建筑

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.10.014

Yi Zhang , Senji Li , Yucan Peng , Chenglong She , Minghao Dong , Keqiao Li , Fan Yang , Weiying Hou , Han Gao , Chenshu Wu , Baoling Huang , Jiawei Zhou , Philip C.Y. Chow , Xiaobo Yin

Low-emissivity (low-E) materials are crucial for building energy efficiency, but all conventional solutions rely on electrically conductive materials that severely block wireless communication, posing a critical obstacle for smart city infrastructure. Here, we present a simple and scalable polymer-ceramic composite (LE-PCC) that breaks this long-standing trade-off. Composed of zinc sulfide (ZnS) microparticles and polyethylene (PE) binders with tailored microporosity, our LE-PCC achieves a high mid-infrared reflectance (0.68). Unlike existing low-E materials, which rely on free electrons to reflect thermal radiation, LE-PCC operates through enhanced back-scattering of mid-infrared light by multiple scatterings in a disordered dielectric medium. LE-PCC significantly outperforms conventional low-E materials in telecommunication signal transmission, reducing attenuation to 2.5 dB (vs. 15 to 70 dB for conventional low-E materials). Furthermore, incorporating infrared-transparent pigments allows for customizable coloring without compromising mid-infrared reflectance, broadening its architectural versatility. Building energy simulations reveal that white and colored LE-PCCs are effective in different climates, such as Hong Kong (46.33 GJ savings) and Los Angeles (43.59 GJ savings), for a midrise apartment annually. Combining thermal insulation, wireless transparency, architectural adaptability, and low-cost, scalable fabrication, LE-PCC emerges as a new class of photonic coatings and a transformative solution for energy-efficient and IoT-enabled smart cities.

低辐射（low-E）材料对建筑节能至关重要，但所有传统解决方案都依赖于导电材料，这严重阻碍了无线通信，对智慧城市基础设施构成了严重障碍。在这里，我们提出了一种简单且可扩展的聚合物-陶瓷复合材料（LE-PCC），打破了这种长期存在的权衡。我们的LE-PCC由硫化锌（ZnS）微粒和聚乙烯（PE）粘合剂组成，具有定制的微孔率，具有较高的中红外反射率（0.68）。与现有的依靠自由电子反射热辐射的低e材料不同，LE-PCC通过在无序介电介质中通过多次散射增强中红外光的反向散射来工作。在电信信号传输方面，LE-PCC显著优于传统的低e材料，将衰减降低至2.5 dB（传统低e材料为15至70 dB）。此外，结合红外透明颜料可以在不影响中红外反射率的情况下进行可定制的着色，扩大了其建筑的多功能性。建筑能源模拟显示，白色和彩色的le - pcs在不同的气候条件下是有效的，例如香港（每年节省46.33 GJ）和洛杉矶（每年节省43.59 GJ）的中层公寓。LE-PCC结合了隔热、无线透明度、建筑适应性以及低成本、可扩展的制造，成为一种新型的光子涂层，是节能和物联网智能城市的变革性解决方案。

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引用次数: 0

Covalent organic framework/hexagonal boron nitride heterostructure photocatalysts for efficient degradation of emerging contaminants 共价有机骨架/六方氮化硼异质结构光催化剂高效降解新出现的污染物

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.11.004

Yifan Zhu , Yuren Feng , Yunrui Yan , Zhiyu Wang , Xiang Zhang , Somayeh Faraji , Qing Ai , Tianyou Xie , Xintong Weng , Lixin Zhou , Tianshu Zhai , Yifeng Liu , Xiaochuan Huang , Chen-yang Lin , Sarah Glass , Bongki Shin , Yimo Han , Angel A Martí , Pulickel M Ajayan , Mingjie Liu , Jun Lou

Nature-inspired photocatalysis provides a sustainable solution for energy conversion and pollutant degradation. Covalent organic frameworks (COFs), with tunable properties and high porosity, have shown promise as photocatalysts, though their synthesis often requires extensive efforts. In this study, we report the in-situ growth of COFs on defective hexagonal boron nitride (hBN) surfaces to form hBN@1,3,5-triformylphloroglucinol (Tp)-4,4′-diamino-[1,1′-biphenyl]-3,3′-dicarbonitrile (DBCN) heterostructures. Bandgap analysis and ultraviolet photoelectron spectroscopy revealed the formation of type-II heterojunctions, enhancing charge separation and minimizing recombination. Density functional theory simulations confirmed efficient charge transfer at the COF-hBN interface. The hBN@Tp-DBCN heterostructures demonstrated remarkable versatility, achieving nearly complete degradation of dyes, pharmaceutical waste, and persistent compounds such as perfluorooctanoic acid. Practical implementation in vertical and horizontal configurations further validated their application potential. This research underscores the efficacy of hBN@COFs heterostructures in photocatalysis and offers a promising direction for metal-free heterostructures in artificial photosynthesis and water treatment.

受自然启发的光催化为能量转换和污染物降解提供了可持续的解决方案。共价有机框架（COFs）具有可调的性能和高孔隙率，作为光催化剂具有广阔的前景，尽管它们的合成通常需要大量的努力。在这项研究中，我们报道了COFs在缺陷六方氮化硼（hBN）表面原位生长，形成hBN@1,3,5-三甲酰间苯三酚(Tp)-4,4 ' -二氨基-[1,1 ' -联苯]-3,3 ' -二腈（DBCN）异质结构。带隙分析和紫外光电子能谱揭示了ii型异质结的形成，增强了电荷分离，减少了复合。密度泛函理论模拟证实了COF-hBN界面上有效的电荷转移。hBN@Tp-DBCN异质结构表现出显著的多功能性，几乎可以完全降解染料、制药废物和持久性化合物，如全氟辛酸。在垂直和水平配置中的实际应用进一步验证了它们的应用潜力。该研究强调了hBN@COFs异质结构在光催化中的作用，为无金属异质结构在人工光合作用和水处理中的应用提供了一个有前途的方向。

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引用次数: 0

Engineering bone tissue with mRNA: from molecular design and delivery to clinical applications mRNA工程骨组织：从分子设计和递送到临床应用

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.11.002

Claudia Del Toro Runzer , Martijn van Griensven , Elizabeth Rosado Balmayor

Bone possesses an intrinsic ability to regenerate after injury, but this capacity is often compromised in pathological conditions. Non-healing fractures are typically treated with autografts, which involve additional surgeries, patient discomfort, and risk of complications. Alternative strategies, such as the administration of growth factor proteins or plasmid DNA, have shown promise but are limited by high costs, immunogenicity, and safety concerns. Recently, messenger RNA (mRNA) therapies have emerged as a compelling alternative for inducing bone regeneration. Unlike DNA, mRNA functions in the cytoplasm, eliminating the need for nuclear entry and minimizing the risk of insertional mutagenesis. It is also transiently expressed and fully degradable, offering a favorable safety profile. Chemical modifications to mRNA can improve its stability, translational efficiency, and reduce innate immune activation, making it a versatile and potent tool for therapeutic applications. In this review, we explore the types of chemical modifications used to enhance mRNA performance, the delivery strategies employed for efficient cellular uptake (including in vivo and ex vivo routes), and the design of biomaterial scaffolds that support bone repair while enabling spatial and temporal control of gene expression. We also discuss the translational potential of mRNA-based approaches, including safety considerations, manufacturing scalability, and cost-effectiveness. Collectively, these advances position chemically modified mRNA as a next-generation therapeutic for bone regeneration, with the potential to overcome the limitations of current treatments and improve outcomes for patients with challenging fractures.

骨在损伤后具有内在的再生能力，但这种能力往往在病理条件下受到损害。无法愈合的骨折通常采用自体移植物治疗，这涉及到额外的手术，患者不适和并发症的风险。替代策略，如使用生长因子蛋白或质粒DNA，已经显示出希望，但受到高成本、免疫原性和安全性问题的限制。最近，信使RNA （mRNA）疗法已成为诱导骨再生的一个引人注目的替代方案。与DNA不同，mRNA在细胞质中起作用，消除了细胞核进入的需要，并将插入突变的风险降至最低。它也是瞬时表达和完全可降解的，提供了良好的安全性。对mRNA进行化学修饰可以提高其稳定性、翻译效率，并减少先天免疫激活，使其成为一种多功能和有效的治疗工具。在这篇综述中，我们探讨了用于提高mRNA性能的化学修饰类型，用于有效细胞摄取的递送策略（包括体内和体外途径），以及支持骨修复的生物材料支架的设计，同时实现基因表达的空间和时间控制。我们还讨论了基于mrna的方法的转化潜力，包括安全性考虑、制造可扩展性和成本效益。总的来说，这些进展将化学修饰mRNA定位为下一代骨再生治疗方法，有可能克服当前治疗方法的局限性，改善挑战性骨折患者的预后。

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引用次数: 0

Carbon-spin-catalyzed selective oxidation of styrene 碳自旋催化苯乙烯的选择性氧化

IF 22 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today

Pub Date : 2025-12-01 DOI: 10.1016/j.mattod.2025.11.007

Yulan Tian , Qi Zhang , Huaqiang Cao , Haiding Zhu , Haijun Yang , Wenqing Yao , Anthony K. Cheetham

The comprehensive investigation of the electronic-level intrinsic electron spin catalysis in carbon materials has been lacking for an extended period. This article presents the application of pulsed electron paramagnetic resonance (pulsed-EPR) spectroscopy to investigate the selective catalytic oxidation of styrene to benzaldehyde employing a category of graphene-like nanomesh catalysts synthesized via a bottom-up approach. The intuitive observation of the interaction between oxygen introduction and the electron spin of carbon materials is detailed, and the prevalent spin catalytic process inherent in carbon materials is elucidated at the electronic level through the integration of isotope labeling and density functional theory.

长期以来，对碳材料的电子级本征电子自旋催化一直缺乏全面的研究。本文介绍了脉冲电子顺磁共振（脉冲epr）光谱的应用，以研究选择性催化氧化苯乙烯为苯甲醛使用一类石墨烯类纳米催化剂通过自下而上的方法合成。对碳材料的氧引入与电子自旋相互作用进行了详细的直观观察，并通过同位素标记和密度泛函理论的结合，在电子水平上阐明了碳材料固有的普遍自旋催化过程。

引用次数: 0