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Middle School Fifth-Grade Students’ Level of Understanding the Concept of Condensation in Different Contexts 初中五年级学生在不同情境中对凝结概念的理解程度
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-09 DOI: 10.1021/acs.jchemed.4c0037310.1021/acs.jchemed.4c00373
Ekrem Cengiz,  and , Faruk Arıcı*, 

Evaporation, condensation, and boiling are fundamental concepts taught in science and chemistry classes, closely linked to daily life. These concepts are vital for students to grasp the transformation and conservation of matter, the particulate nature of matter, and related principles. This study evaluated fifth-grade students’ comprehension of condensation across various contexts. The research involved 80 male and 59 female students from a public school in a qualitative phenomenological study. Data analysis utilized the content analysis method. As a result of the study, it was revealed that the students who participated in the research did not understand the concept of condensation sufficiently and could not explain this concept at the desired level in different contexts. Based on the findings, incorporating real-life contexts when teaching the concept of condensation can enhance the understanding of the topic. Moreover, it highlights the significance of an investigative approach to learning new concepts.

蒸发、凝结和沸腾是科学和化学课上讲授的基本概念,与日常生活密切相关。这些概念对于学生掌握物质的转化和守恒、物质的微粒性质以及相关原理至关重要。本研究评估了五年级学生在不同情境下对凝华的理解。来自一所公立学校的 80 名男生和 59 名女生参与了这项定性现象学研究。数据分析采用了内容分析法。研究结果表明,参与研究的学生对凝结概念的理解不够充分,在不同情境中对这一概念的解释不能达到预期水平。根据研究结果,在讲授凝结概念时,结合实际生活情境可以加深学生对这一主题的理解。此外,研究还强调了探究式学习新概念的重要性。
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引用次数: 0
Exploring Climate Change through Experiential Learning Activities for Nonscience Majors 通过面向非科学专业学生的体验式学习活动探索气候变化
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-08 DOI: 10.1021/acs.jchemed.4c0018110.1021/acs.jchemed.4c00181
Ji Kim*, 

This climate change-related experiential learning initiative targeted nonscience majors enrolled in an introductory chemistry course at a two-year college to enhance their understanding of climate change. The activity aimed to connect abstract chemistry concepts to real-world significance over several sessions involving activities like library research, social media interviews, collaboration with environmental advocates, and practical lab activities and simulations. Implemented in a class size of 16–20 students, the initiative was seamlessly integrated without compromising the course curriculum. Students′ reflections highlighted the impactful outcomes of the activity. They exhibited heightened awareness regarding environmental issues, specifically ethical concerns in factory farming and the adverse effects of CO2 emissions on ocean acidity. This led to a newfound sense of responsibility among students, driving them to advocate for change and engage in proactive measures. Ultimately, this climate change-related experiential learning approach effectively linked chemistry education with practical, relatable contexts. It empowered students to comprehend, reflect upon, and advocate for environmental stewardship, fostering a deeper connection to climate change issues in their communities and beyond.

这项与气候变化有关的体验式学习活动针对的是一所两年制学院化学入门课程的非理科专业学生,目的是提高他们对气候变化的认识。该活动旨在通过图书馆研究、社交媒体采访、与环保倡导者合作、实际实验室活动和模拟等活动,将抽象的化学概念与现实世界的意义联系起来。该活动在一个 16-20 人的班级实施,在不影响课程设置的情况下实现了无缝整合。学生们的反思凸显了活动的影响。他们提高了对环境问题的认识,特别是对工厂化养殖中的道德问题和二氧化碳排放对海洋酸度的不利影响的认识。这使学生们产生了一种新的责任感,促使他们倡导变革,并采取积极措施。最终,这种与气候变化相关的体验式学习方法有效地将化学教育与实际、可亲近的背景联系起来。它增强了学生理解、反思和倡导环境管理的能力,促进了他们与社区内外气候变化问题的更深联系。
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引用次数: 0
Student Engagement During an Experiment on the Bioelectrochemistry of Cytochrome c 学生参与细胞色素 c 的生物电化学实验
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-08 DOI: 10.1021/acs.jchemed.3c0129610.1021/acs.jchemed.3c01296
Sarah K. Linden, Damien W. M. Arrigan* and Alexandra Yeung*, 

Learning about electrochemical protein science and technology is useful due to its importance in society, for example, in widely used glucose biosensors. The aim of the experiment presented here is to provide third-year undergraduate chemistry students with an introduction to the electrochemistry of cytochrome c as a first step in bioelectrochemistry. The experiment was designed with the learning outcomes of the Curtin University unit Bioanalytical and Biophysical Chemistry in mind. The effectiveness of this experiment was measured via a modified version of the Advancing Science by Enhancing Learning in the Laboratory (ASELL) Students Laboratory Experience (ASLE) survey. Comparisons of the students’ experimental data to model data were employed, as well as an analysis of the ability of students to use and learn with a portable potentiostat and its relevant software. In the survey results, 69% of students agreed/strongly agreed with the statement “I found this to be an interesting experiment”, and the remaining students (31%) responded “neutral”, indicating an overall positive student experience. The student responses to the main goals of this experiment (i.e., development of laboratory skills, increasing understanding of electrochemistry, and development of data interpretation skills) were very favorable (positive responses were garnered from 92%, 84%, and 85% of students for each respective goal). The results show that this experiment on the electrochemistry of cytochrome c provides a basis for introducing new experimental methods and skills to undergraduate chemistry students.

由于电化学蛋白质科学和技术在社会中的重要性,例如在广泛使用的葡萄糖生物传感器中,学习电化学蛋白质科学和技术是非常有用的。本文介绍的实验旨在向化学专业本科三年级学生介绍细胞色素 c 的电化学,作为生物电化学的第一步。实验的设计考虑到了科廷大学生物分析和生物物理化学单元的学习成果。该实验的效果通过改进版的 "通过加强实验室学习促进科学发展(ASELL)学生实验室体验(ASLE)调查 "来衡量。学生的实验数据与模型数据进行了比较,还分析了学生使用和学习便携式恒电位仪及其相关软件的能力。调查结果显示,69% 的学生同意/非常同意 "我觉得这是一个有趣的实验 "这一说法,其余学生(31%)的回答为 "中立",这表明学生的总体体验是积极的。学生对本实验的主要目标(即培养实验技能、加深对电化学的理解和培养数据解读技能)的反应非常好(92%、84% 和 85% 的学生对每个目标都做出了积极的反应)。结果表明,细胞色素 c 的电化学实验为向化学本科生介绍新的实验方法和技能奠定了基础。
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引用次数: 0
Electrospinning as a Fascinating Platform for Teaching Applied Polymer Science with Safe and Sustainable Experiments 电纺丝是利用安全和可持续实验进行应用聚合物科学教学的迷人平台
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-08 DOI: 10.1021/acs.jchemed.4c0050410.1021/acs.jchemed.4c00504
Jessica Noll, Felix Leven, Johannes Limberg, Christoph Weidmann and Rainer Ostermann*, 

Electrospinning has been widely used as a versatile technique to generate nanofibers of various materials. It is also helpful in teaching topics ranging from macromolecular chemistry to physics, safety, and sustainability at various levels of difficulty and student involvement. Simple and safe hands-on experiments/manual assays can be realized for less than 30 euros to demonstrate polymer viscosity and nanofiber alignment and solubility. Students can further study (super)hydrophobicity and even upcycle packaging waste into useful filter materials but also improve the electrospinning setup from a manual assay to an inexpensive Arduino-based 3D printed research platform. Alternatively, the latter can be used for teacher demonstrations of more challenging experiments that can also be easily done using a commercial syringe-pump.

电纺丝作为一种多功能技术,已被广泛用于生成各种材料的纳米纤维。电纺丝还有助于教授从高分子化学到物理、安全和可持续发展等不同难度和学生参与程度的课题。只需花费不到 30 欧元,就能实现简单安全的动手实验/手动测定,以演示聚合物粘度和纳米纤维的排列和溶解性。学生们可以进一步研究(超)疏水性,甚至将包装废弃物循环利用为有用的过滤材料,还可以改进电纺丝装置,从手动测定到基于 Arduino 的廉价 3D 打印研究平台。此外,后者还可用于教师演示更具挑战性的实验,而使用商用注射泵也能轻松完成这些实验。
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引用次数: 0
Using Content Area Reading to Support an Interdisciplinary Storyline Involving Climate Science 利用内容领域阅读支持涉及气候科学的跨学科故事情节
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-06 DOI: 10.1021/acs.jchemed.4c0039010.1021/acs.jchemed.4c00390
Ted M. Clark*, Caroline T. Clark, Sophia Jeong and Jason Cervenec, 

Addressing the complex and politicized issue of climate change requires innovative educational approaches that transcend traditional disciplinary boundaries. This article describes the development of a collaborative interdisciplinary General Education (GE) course, “Climate Science Chemistry, Education, and Citizenship,″ to merge STEM with non-STEM subjects and address learning objectives that involve personal growth, critical thinking, self-reflection, and informed action. Within a semester-long storyline, the strands of content learning, process, and action are combined and addressed by using content area reading and disciplinary literacy resources. In this Perspective, design considerations of the course are discussed along with educational strategies aiming to cultivate informed, critical, and active citizens ready to tackle the challenges posed by climate change.

要解决复杂而政治化的气候变化问题,就必须采用超越传统学科界限的创新教育方法。本文介绍了跨学科通识教育(GE)课程 "气候科学化学、教育和公民意识 "的合作开发情况,该课程将科学、技术、工程和数学学科与非科学、技术、工程和数学学科融合在一起,实现了涉及个人成长、批判性思维、自我反思和知情行动的学习目标。在一个学期的故事情节中,内容学习、过程和行动三者结合起来,并通过使用内容领域的阅读和学科素养资源加以解决。在本视角中,将讨论课程的设计考虑因素以及旨在培养知情、批判和积极的公民的教育策略,以应对气候变化带来的挑战。
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引用次数: 0
Students’ Perspectives on the Application of a Generative Pre-Trained Transformer (GPT) in Chemistry Learning: A Case Study in Indonesia 学生对化学学习中应用生成式预训练变压器(GPT)的看法:印度尼西亚案例研究
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-06 DOI: 10.1021/acs.jchemed.4c0022010.1021/acs.jchemed.4c00220
Ananta Ardyansyah, Agung Budhi Yuwono, Sri Rahayu*, Naif Mastoor Alsulami and Oktavia Sulistina, 

The rapid development of artificial intelligence (AI) has transformed chatbots into generative pre-trained transformers (GPTs) capable of performing various tasks. The use of GPTs is expanding to learning, including natural sciences like chemistry. GPTs can assist students in understanding and solving chemistry problems. However, there are potential negative impacts of using GPTs. This study aims to explore Indonesian university students’ perspectives on using GPTs for chemistry learning. The research used a case study method and collected data through questionnaires, interviews, and GPT usage logs, which were then analyzed thematically. The study revealed that students use GPTs in learning due to perceived usefulness, ease of use, emotional aspects, benefits, and social influence. Students appreciate GPT answers for being easy to understand, detailed, reliable, fairly accurate, fast, and helpful. However, students also recognize that GPT answers can be unreliable, difficult to understand, not always accurate, and potentially unethical. Students evaluate GPT responses by stimulating thoughts, confirming answers, integrating with other sources, directly copying responses, and paraphrasing before use. They are also aware of ethical considerations, drawbacks, and limitations associated with using GPTs. Findings pertaining to motives, constraints, and the evaluation of answer quality and its utilization can serve as indicators for the proper application of GPT in educational contexts. In many countries, including Indonesia, where there is a lack of usage regulations, concrete policies are necessary to ensure the proper integration of GPT into education.

人工智能(AI)的快速发展已将聊天机器人转变为能够执行各种任务的生成式预训练变换器(GPT)。GPT 的使用正扩展到学习领域,包括化学等自然科学。GPT 可以帮助学生理解和解决化学问题。然而,使用 GPT 可能会产生负面影响。本研究旨在探讨印度尼西亚大学生对使用 GPT 学习化学的看法。研究采用案例研究法,通过问卷调查、访谈和 GPT 使用日志收集数据,然后进行专题分析。研究结果显示,学生在学习中使用 GPT 的原因主要包括实用性、易用性、情感因素、益处和社会影响。学生赞赏 GPT 答案易懂、详细、可靠、相当准确、快速和有帮助。不过,学生也认识到 GPT 答案可能不可靠、难以理解、不一定准确,而且可能不道德。学生通过启发思考、确认答案、与其他来源整合、直接复制答案以及在使用前进行转述来评估 GPT 答案。他们还了解与使用 GPT 相关的道德考虑、缺点和限制。有关动机、限制因素、答案质量评估及其使用的研究结果,可以作为在教育环境中正确应用 GPT 的指标。在包括印度尼西亚在内的许多国家,由于缺乏使用规定,因此有必要制定具体的政策,以确保将 GPT 适当纳入教育。
{"title":"Students’ Perspectives on the Application of a Generative Pre-Trained Transformer (GPT) in Chemistry Learning: A Case Study in Indonesia","authors":"Ananta Ardyansyah,&nbsp;Agung Budhi Yuwono,&nbsp;Sri Rahayu*,&nbsp;Naif Mastoor Alsulami and Oktavia Sulistina,&nbsp;","doi":"10.1021/acs.jchemed.4c0022010.1021/acs.jchemed.4c00220","DOIUrl":"https://doi.org/10.1021/acs.jchemed.4c00220https://doi.org/10.1021/acs.jchemed.4c00220","url":null,"abstract":"<p >The rapid development of artificial intelligence (AI) has transformed chatbots into generative pre-trained transformers (GPTs) capable of performing various tasks. The use of GPTs is expanding to learning, including natural sciences like chemistry. GPTs can assist students in understanding and solving chemistry problems. However, there are potential negative impacts of using GPTs. This study aims to explore Indonesian university students’ perspectives on using GPTs for chemistry learning. The research used a case study method and collected data through questionnaires, interviews, and GPT usage logs, which were then analyzed thematically. The study revealed that students use GPTs in learning due to perceived usefulness, ease of use, emotional aspects, benefits, and social influence. Students appreciate GPT answers for being easy to understand, detailed, reliable, fairly accurate, fast, and helpful. However, students also recognize that GPT answers can be unreliable, difficult to understand, not always accurate, and potentially unethical. Students evaluate GPT responses by stimulating thoughts, confirming answers, integrating with other sources, directly copying responses, and paraphrasing before use. They are also aware of ethical considerations, drawbacks, and limitations associated with using GPTs. Findings pertaining to motives, constraints, and the evaluation of answer quality and its utilization can serve as indicators for the proper application of GPT in educational contexts. In many countries, including Indonesia, where there is a lack of usage regulations, concrete policies are necessary to ensure the proper integration of GPT into education.</p>","PeriodicalId":43,"journal":{"name":"Journal of Chemical Education","volume":"101 9","pages":"3666–3675 3666–3675"},"PeriodicalIF":2.5,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142159795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"教育学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Making a Constant Temperature Phase-Change Medium Coffee Mug: A Real-World Application of Enthalpy of Crystallization 制作恒温相变介质咖啡杯:结晶焓的实际应用
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-06 DOI: 10.1021/acs.jchemed.4c0033710.1021/acs.jchemed.4c00337
Vera Alenicheva, Caitlin McEntee and Michael K. Bellamy*, 

The experiment presented relates the concept of enthalpy of crystallization to the real-world application of temperature-regulated coffee mugs. Students first measure the enthalpy of crystallization of a phase change material (PCM). Observing a temperature increase for a “freezing” process emphasizes that the formation of bonds is an exothermic process. In the case of a phase change, these bonds are intermolecular. In addition, knowing the value of the enthalpy of crystallization allows students to calculate the amount of heat that can be absorbed or released per gram of PCM during the phase change. Then, students insert PCM into vacuum mugs to make constant-temperature coffee mugs that mimic those that are commercially available. Students place hot water (coffee) into their user made PCM mugs and measure the temperature versus time. The PCM absorbs heat quickly and lowers the temperature of coffee to the melting point of the PCM, which is near the desired drinking temperature of the coffee. As the PCM resolidifies, heat is released and the temperature of their coffee is held near the melting point of the PCM. Students compare the performance of their PCM coffee mugs with commercially available mugs. If desired, the procedure can be modified to be a guided inquiry-based experiment. The experiment is designed to be used in either a first-semester freshman chemistry course at a university or a high school chemistry course. The experiment is inexpensive to implement since PCM can be reused. No chemical waste is generated, and student engagement has been positive. The content of the lab corresponds to the thermochemistry content of most textbooks.

本实验将结晶焓的概念与温度调节咖啡杯的实际应用联系起来。学生首先测量相变材料 (PCM) 的结晶焓。观察 "冻结 "过程的温度升高,可以强调键的形成是一个放热过程。在相变情况下,这些键是分子间的。此外,通过了解结晶焓值,学生可以计算出每克 PCM 在相变过程中可吸收或释放的热量。然后,学生将 PCM 放入真空杯中,模仿市面上的咖啡杯制作恒温咖啡杯。学生将热水(咖啡)放入自己制作的 PCM 杯中,测量温度与时间的关系。PCM 快速吸热,将咖啡温度降低到 PCM 的熔点,即接近咖啡的理想饮用温度。随着 PCM 的分解,热量释放出来,咖啡的温度保持在 PCM 熔点附近。学生将 PCM 咖啡杯的性能与市售咖啡杯进行比较。如果需要,还可以将该程序修改为引导式探究实验。该实验可用于大学一年级化学课程的第一学期或高中化学课程。由于 PCM 可以重复使用,因此该实验的实施成本很低。不会产生化学废物,学生的参与度也很高。实验内容与大多数教科书中的热化学内容一致。
{"title":"Making a Constant Temperature Phase-Change Medium Coffee Mug: A Real-World Application of Enthalpy of Crystallization","authors":"Vera Alenicheva,&nbsp;Caitlin McEntee and Michael K. Bellamy*,&nbsp;","doi":"10.1021/acs.jchemed.4c0033710.1021/acs.jchemed.4c00337","DOIUrl":"https://doi.org/10.1021/acs.jchemed.4c00337https://doi.org/10.1021/acs.jchemed.4c00337","url":null,"abstract":"<p >The experiment presented relates the concept of enthalpy of crystallization to the real-world application of temperature-regulated coffee mugs. Students first measure the enthalpy of crystallization of a phase change material (PCM). Observing a temperature increase for a “freezing” process emphasizes that the formation of bonds is an exothermic process. In the case of a phase change, these bonds are intermolecular. In addition, knowing the value of the enthalpy of crystallization allows students to calculate the amount of heat that can be absorbed or released per gram of PCM during the phase change. Then, students insert PCM into vacuum mugs to make constant-temperature coffee mugs that mimic those that are commercially available. Students place hot water (coffee) into their user made PCM mugs and measure the temperature versus time. The PCM absorbs heat quickly and lowers the temperature of coffee to the melting point of the PCM, which is near the desired drinking temperature of the coffee. As the PCM resolidifies, heat is released and the temperature of their coffee is held near the melting point of the PCM. Students compare the performance of their PCM coffee mugs with commercially available mugs. If desired, the procedure can be modified to be a guided inquiry-based experiment. The experiment is designed to be used in either a first-semester freshman chemistry course at a university or a high school chemistry course. The experiment is inexpensive to implement since PCM can be reused. No chemical waste is generated, and student engagement has been positive. The content of the lab corresponds to the thermochemistry content of most textbooks.</p>","PeriodicalId":43,"journal":{"name":"Journal of Chemical Education","volume":"101 9","pages":"3912–3916 3912–3916"},"PeriodicalIF":2.5,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acs.jchemed.4c00337","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142159808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"教育学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Presenting Biochemistry Topics through a Systems Thinking Approach 通过系统思考法介绍生物化学专题
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-05 DOI: 10.1021/acs.jchemed.4c0028510.1021/acs.jchemed.4c00285
Corina E. Brown*,  and , Richard M. Hyslop, 

The 21st century presents global challenges that require interdisciplinary approaches. The emerging area of Systems Thinking in Chemistry Education (STICE) encourages reform in chemistry education and practice using different cognitive frameworks, tools, and strategies to visualize the interconnectivity of how chemistry knowledge relates not only among branches within the discipline but also connections to the domains within and beyond the natural sciences. Changes in the pedagogical approach of a biochemistry course are suggested herein to address some of these challenges. Based on some of these changes, the reductionist approach is replaced by a systems thinking approach that stimulates the students to think beyond the basic concepts introduced in order to see the connections and applications to areas other than the specific discipline. In this manuscript, examples of metabolism and metabolites are used to exemplify the application of systems thinking in presenting different areas of knowledge related to topics in a biochemistry course. The specific topic of “ketone bodies” is used as the core subsystem. The connections among different subsystems including biochemistry/metabolism, physiology/medicine, nutrition/diet, and environment/society are discussed in detail.

21 世纪提出的全球性挑战需要跨学科的方法。化学教育中的系统思考(STICE)这一新兴领域鼓励使用不同的认知框架、工具和策略对化学教育和实践进行改革,以直观地了解化学知识不仅与学科内各分支之间的相互联系,而且与自然科学内外各领域之间的联系。本文建议改变生物化学课程的教学方法,以应对其中的一些挑战。基于其中的一些变化,还原论方法被系统思维方法所取代,系统思维方法激发学生思考所介绍的基本概念之外的问题,以便看到与特定学科以外领域的联系和应用。本手稿以新陈代谢和代谢物为例,说明在介绍与生物化学课程主题相关的不同知识领域时如何应用系统思维。酮体 "这一特定主题被用作核心子系统。文中详细讨论了生物化学/代谢、生理学/医学、营养学/饮食和环境/社会等不同子系统之间的联系。
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引用次数: 0
Determination of End Point in Benzoic Acid Crystallization via Laser Irradiation 通过激光照射确定苯甲酸结晶的终点
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-05 DOI: 10.1021/acs.jchemed.4c0043710.1021/acs.jchemed.4c00437
Liying Dong, Yun He and Zunting Zhang*, 

The recrystallization experiment is a significant component of chemistry laboratory instruction in both middle schools and universities. The method for identifying the crystallization end point is absent from the textbooks. In this paper, the characteristic of light propagation in nonuniform media was employed to identify the crystallization end point. Filter the crude benzoic acid solution while it is hot, allowing the laser beam to pass through the center of the filtrate. Observe the alteration in the light spot projected onto the white screen through the beam. As the concentration gradient of the solution changes, the gradual recovery of the light spot from the reticulated stripes of light and dark indicates completion of the crystallization process, signaling readiness for the subsequent filtration experiment. This method offers a simple means to determine the end point of crystallization, and the phenomenon is intuitive, making it suitable for chemistry teaching experiments.

再结晶实验是中学和大学化学实验教学的重要组成部分。教科书中没有确定结晶终点的方法。本文利用光在非均匀介质中传播的特性来确定结晶终点。趁热过滤粗苯甲酸溶液,让激光束穿过滤液中心。观察通过光束投射到白色屏幕上的光斑的变化。随着溶液浓度梯度的变化,光点从明暗网状条纹中逐渐恢复,表明结晶过程已经完成,为随后的过滤实验做好了准备。这种方法提供了确定结晶终点的简单手段,而且现象直观,适合化学教学实验。
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引用次数: 0
Molecular Insights into Marcuss Theory: An Ab Initio Quantum Chemistry Computational Lab Practice for Charge Transfer Kinetics Pedagogy 马库斯理论的分子洞察力:电荷转移动力学教学的初始量子化学计算实验室实践
IF 2.5 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-08-02 DOI: 10.1021/acs.jchemed.4c0028610.1021/acs.jchemed.4c00286
Yacong Fan, Jing Du, Wentao Zhao*, Xiaofei Ma and Xi Yu*, 

Charge transfer (CT) is a fundamental process in various chemical systems, and its kinetics, depicted by Marcus theory, is one of the central parts of chemistry education. While the practical demonstration of charge transfer mechanisms and kinetics in laboratories can be challenging, the microscopic origins of such processes are even more complex to observe. We introduce an ab initio quantum chemistry computation practice to unravel the intricacies of CT at the molecular scale. Using the “Koopmans’ theorem–energy splitting in dimer” (KT-ESD) method and the 4-point method, the electronic coupling and reorganization energy (ROE) have been obtained in series of model molecules. Through the analysis of the electronic coupling and ROE, we discern the pivotal factors of molecular structure impacting charge transfer rates. Particularly, the results from this practice align with cutting edge experimental measurements from single-molecule conducting and photoelectron spectroscopy. This computational lab module provides a valuable instrument for comprehending charge transfer rates, thereby fostering enhanced learning experiences across major chemistry courses such as kinetics, physical chemistry, quantum chemistry, and organic chemistry.

电荷转移(CT)是各种化学体系中的一个基本过程,马库斯理论所描述的电荷转移动力学是化学教育的核心内容之一。在实验室中实际演示电荷转移机理和动力学具有挑战性,而观察此类过程的微观起源则更为复杂。我们引入了一种自证量子化学计算实践,以揭示分子尺度上错综复杂的电荷转移。我们利用 "库普曼斯定理-二聚体中的能量分裂"(KT-ESD)方法和四点法,得到了一系列模型分子的电子耦合和重组能(ROE)。通过对电子耦合和重组能的分析,我们发现了分子结构影响电荷转移速率的关键因素。特别是,这一实践的结果与单分子传导和光电子能谱的前沿实验测量结果相吻合。这一计算实验模块为理解电荷转移率提供了宝贵的工具,从而促进了动力学、物理化学、量子化学和有机化学等主要化学课程的学习体验。
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引用次数: 0
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Journal of Chemical Education
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