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230-nm-wavelength range far-UVC LED with low Al-composition differentiation between well and barrier layers of MQWs 波长范围为 230 纳米的远紫外 LED,MQW 的阱层和势垒层之间的铝成分差异较小
Pub Date : 2024-04-12 DOI: 10.35848/1882-0786/ad3e48
K. Uesugi, R. Akaike, S. Ichikawa, Takao Nakamura, K. Kojima, Masahiko Tsuchiya, Hideto Miyake
Reducing the average Al composition of AlxGa1−xN/AlyGa1−yN multiple quantum wells (MQWs) is an effective approach to increase the current injection efficiencies of far-ultraviolet-C light-emitting diodes (far-UVC LEDs). A reduction can be realized by decreasing the Al-composition differentiation between the well and barrier layers. Compared to conventional MQWs, a 230-nm-wavelength far-UVC LED equipped with a single-Al-composition and a 50-nm-thick light-emitting layer exhibits a higher external quantum efficiency (EQE). The EQE of far-UVC LEDs with low Al-composition differentiation (~1%) is enhanced to approximately 0.6% and 1.4% under continuous wave operations at 230 nm and 236 nm wavelengths, respectively.
降低 AlxGa1-xN/AlyGa1-yN 多量子阱 (MQW) 的平均铝成分是提高远紫外-C 发光二极管 (far-UVC LED) 电流注入效率的有效方法。通过减少阱层和势垒层之间的铝成分差异,可以实现电流注入效率的降低。与传统的 MQW 相比,波长为 230 纳米的远紫外发光二极管配备了单一铝成分和 50 纳米厚的发光层,具有更高的外部量子效率(EQE)。在 230 纳米和 236 纳米波长的连续波操作下,铝成分差异较低(约 1%)的远紫外 LED 的 EQE 分别提高到约 0.6% 和 1.4%。
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引用次数: 0
P-i-n photodetector with active GePb layer grown by sputtering epitaxy 通过溅射外延技术生长的带有有源 GePb 层的 Pi-n 光电探测器
Pub Date : 2024-04-11 DOI: 10.35848/1882-0786/ad3dc1
Jiulong Yu, Guangyang Lin, Shilong Xia, Wei Huang, Tianwei Yang, J. Jiao, Xiangquan Liu, Songyan Chen, Cheng Li, Jun Zheng, Jun Li
In this paper, single-crystal GePb films were obtained by magnetron sputtering with high substrate temperature and rapid deposition rate. The GePb films have high crystalline qualities and smooth surfaces. The Pb content reached 1.29% and no segregation was observed. Based on this, a GePb-based p-i-n photodetector was successfully prepared. The device showed a room-temperature dark current density of 5.83 mA/cm2 at -1.0 V and a cutoff wavelength of 1990 nm, which covers all communication windows. At the wavelength of 1625 nm, responsivity of the photodetector reached 0.132 A/W at -1.0 V. The device demonstrates potential application in optical communications.
本文采用磁控溅射技术,以较高的基底温度和较快的沉积速率获得了单晶 GePb 薄膜。GePb 薄膜结晶度高,表面光滑。铅含量达到 1.29%,且未观察到偏析现象。在此基础上,成功制备了基于 GePb 的 pi-n 光电探测器。该器件在 -1.0 V 时的室温暗电流密度为 5.83 mA/cm2,截止波长为 1990 nm,覆盖了所有通信窗口。在波长为 1625 nm 时,光电探测器的响应率在 -1.0 V 时达到 0.132 A/W。该器件展示了在光通信领域的应用潜力。
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引用次数: 0
Carrier density control of Sb-doped rutile-type SnO2 thin films and fabrication of a vertical Schottky barrier diode 掺锑金红石型二氧化锡薄膜的载流子密度控制与垂直肖特基势垒二极管的制造
Pub Date : 2024-04-10 DOI: 10.35848/1882-0786/ad3d2b
Yui Takahashi, Hitoshi Takane, Hirokazu Izumi, Takeru Wakamatsu, Yuki Isobe, Kentaro Kaneko, Katsuhisa Tanaka
We report on the control of carrier density in r-SnO2 thin films grown on isostructural r-TiO2 substrates by doping with Sb aiming for power-electronics applications. The carrier density was tuned within a range of 3×1016 −2×1019 cm−3. Two types of donors with different activation energies, attributed to Sb at Sn sites and oxygen vacancies, are present in the thin films. Both activation energies decrease as the concentration of Sb increases. A vertical Schottky barrier diode employing a Sb:r-SnO2/Nb:r-TiO2 exhibits a clear rectifying property with a rectification ratio of 103 at ± 1V.
我们报告了通过掺杂锑来控制生长在等结构 r-TiO2 基底上的 r-SnO2 薄膜中的载流子密度,旨在实现功率电子应用。载流子密度的调节范围为 3×1016 -2×1019 cm-3。薄膜中存在两种活化能不同的供体,分别是锡位点上的锑和氧空位。这两种活化能都随着锑浓度的增加而降低。采用 Sb:r-SnO2/Nb:r-TiO2 的垂直肖特基势垒二极管具有明显的整流特性,在 ± 1V 时的整流比为 103。
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引用次数: 0
Imaginary impedance due to hopping phenomena and evaluation of dopant ionization time in cryogenic metal-oxide-semiconductor devices on highly doped substrate 高掺杂基底上的低温金属氧化物半导体器件中跳变现象引起的虚阻抗和掺杂离子化时间评估
Pub Date : 2024-04-10 DOI: 10.35848/1882-0786/ad3d2a
Tomohisa Miyao, Keito Yoshinaga, Takahisa Tanaka, Hiroki Ishikuro, Munehiro Tada, Ken Uchida
MOS capacitors fabricated on substrates with doping concentrations as high as 1018 cm-3 were characterized at 4.2 K. The highly doped substrate exhibited an intrinsic imaginary component of impedance at 4.2 K. The imaginary component is attributed to the time delay induced by hopping phenomena, leading to a decrease in the gate capacitance. Furthermore, we investigated the time constant associated with dopant ionization under depletion conditions and determined it to be 0.35 μs. An equivalent circuit model of the highly doped substrate at 4.2 K is also shown.
在掺杂浓度高达 1018 cm-3 的衬底上制造的 MOS 电容器在 4.2 K 下进行了表征。高掺杂衬底在 4.2 K 下表现出固有的阻抗虚分量。此外,我们还研究了耗尽条件下与掺杂电离相关的时间常数,并确定其为 0.35 μs。图中还显示了高掺杂基底在 4.2 K 时的等效电路模型。
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引用次数: 0
Sub-two-cycle intense pulse generation based on two-stage hollow-core fiber compression using an ytterbium amplifier 基于使用镱放大器的两级中空芯光纤压缩技术的亚两周期强脉冲生成技术
Pub Date : 2024-04-09 DOI: 10.35848/1882-0786/ad3cb5
Nobuhisa Ishii, Ryuji Itakura
We demonstrate the generation of sub-two-cycle intense laser pulses based on two-stage hollow-core fiber compression in a compact setup (footprint of 0.65 m x 2.85 m) using a commercial Yb:KGW regenerative amplifier. Spectrally broadened laser pulses with an output power of 7.2 W from the second hollow-core fiber stage are compressed down to 6.6 fs (1.9 cycles at 1030 nm) using a pair of chirp mirrors and a pair of wedges with an efficiency of 86%, leading to a compressed output of 6.2 W. A pulse-to-pulse energy stability of 0.26% is measured for 10 minutes.
我们利用商用 Yb:KGW 再生放大器,在紧凑型装置(占地面积为 0.65 m x 2.85 m)中演示了基于两级中空芯光纤压缩技术的亚两周期强激光脉冲的产生。使用一对啁啾镜和一对楔形镜,将第二级中空芯光纤输出功率为 7.2 W 的光谱展宽激光脉冲压缩到 6.6 fs(1030 nm 波长下的 1.9 个周期),效率高达 86%,从而获得 6.2 W 的压缩输出功率。
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引用次数: 0
Unusual photoinduced crystal structure dynamics in TaTe2 with double zigzag chain superstructure 具有双人字链上层结构的 TaTe2 中非同寻常的光诱导晶体结构动力学
Pub Date : 2024-04-05 DOI: 10.35848/1882-0786/ad3b61
Jumpei Koga, Yusuke Chiashi, A. Nakamura, Tomoki Akiba, Hidefumi Takahashi, Takahiro Shimojima, Shintaro Ishiwata, Kyoko Ishizaka
Transition metal dichalcogenides with superperiodic lattice distortions have been widely investigated as the platform of ultrafast structural phase manipulations. Here we performed ultrafast electron diffraction on room-temperature TaTe2, which exhibits peculiar double zigzag chain pattern of Ta atoms. From the time-dependent electron diffraction pattern, we revealed a photoinduced change in the crystal structure occurring within <0.5 ps, though there is no corresponding high-temperature equilibrium phase. We further clarified the slower response (~1.5 ps) reflecting the lattice thermalization. Our result suggests the unusual ultrafast crystal structure dynamics specific to the non-equilibrium transient process in TaTe2.
作为超快结构相操作的平台,具有超周期晶格畸变的过渡金属二碲化物已被广泛研究。在这里,我们对室温下的 TaTe2 进行了超快电子衍射。从随时间变化的电子衍射图谱中,我们发现晶体结构在小于 0.5 ps 的时间内发生了光诱导变化,但并不存在相应的高温平衡相。我们进一步澄清了反映晶格热化的较慢响应(约 1.5 ps)。我们的研究结果表明,TaTe2 的非平衡瞬变过程具有不寻常的超快晶体结构动力学特性。
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引用次数: 0
Fabrication of free-standing GaN substrates using electrochemically formed porous separation layers 利用电化学形成的多孔分离层制造独立的氮化镓衬底
Pub Date : 2024-04-03 DOI: 10.35848/1882-0786/ad3a2f
Masafumi Yokoyama, F. Horikiri, Hisashi Mori, Taichiro Konno, H. Fujikura
We have developed a pore-assisted separation (PAS) method for the fabrication of free-standing GaN substrates, where bulk GaN crystals were separated from seed GaN templates at electrochemically formed porous layers. The pore size was controlled by the electrochemical process conditions and must be greater than 100 nm to realize separation within whole wafers. A 2-inch free-standing GaN substrate having a low dislocation density of 2.7×106 cm−2 was realized by growth of an 800-μm-thick GaN layer on the porous GaN template. A 3-inch free-standing GaN substrate was also fabricated by the PAS method, indicating its good scalability.
我们开发了一种用于制造独立氮化镓衬底的孔隙辅助分离(PAS)方法,在这种方法中,块状氮化镓晶体与种子氮化镓模板在电化学形成的多孔层上分离。孔隙大小由电化学工艺条件控制,必须大于 100 纳米才能在整个晶片内实现分离。通过在多孔氮化镓模板上生长 800 微米厚的氮化镓层,实现了位错密度低至 2.7×106 厘米-2 的 2 英寸独立氮化镓衬底。利用 PAS 方法还制造出了 3 英寸的独立 GaN 衬底,这表明该方法具有良好的可扩展性。
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引用次数: 0
Triarylborane-based thermally activated delayed fluorescence materials with an efficient reverse intersystem crossing 具有高效反向系统间交叉的三芳基硼烷基热激活延迟荧光材料
Pub Date : 2024-03-29 DOI: 10.35848/1882-0786/ad392a
Ryosuke Okumura, Y. Kusakabe, Florian Rauch, Lukas Lubczyk, Katsuaki Suzuki, Todd Marder, Hironori Kaji
Efficient reverse intersystem crossing (RISC) is an important process for thermally activated delayed fluorescence (TADF) to suppress efficiency roll-off in organic light-emitting diodes (OLEDs). Enhancing spin-orbit coupling is effective for fast RISC, which is achieved by mediating a locally excited triplet state when RISC occurs between charge transfer states. Here, we experimentally confirmed that efficient RISC occurred in triarylborane-based TADF emitters named Phox-Meπ, Phox-MeOπ, and MeO3Ph-FMeπ. The three emitters showed large rate constants of RISC exceeding 106 s−1. Phox-Meπ-based OLEDs exhibited higher maximum external quantum efficiency (EQEmax = 10.0%) compared to Phox-MeOπ-based OLED (EQEmax = 6.7%).
高效的反向系统间交叉(RISC)是热激活延迟荧光(TADF)抑制有机发光二极管(OLED)效率衰减的一个重要过程。当电荷转移态之间发生 RISC 时,通过介导局部激发的三重态,增强自旋轨道耦合对快速 RISC 非常有效。在此,我们通过实验证实,在名为 Phox-Meπ、Phox-MeOπ 和 MeO3Ph-FMeπ 的三芳基硼烷基 TADF 发射器中发生了高效的 RISC。这三种发射器的 RISC 速率常数均超过 106 s-1。与基于 Phox-MeOπ 的 OLED(EQEmax = 6.7%)相比,基于 Phox-MeOπ 的 OLED 表现出更高的最大外部量子效率(EQEmax = 10.0%)。
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引用次数: 0
Selective phase transition of cholesteric blue phase I induced by pattern-controlled Grandjean-Cano disclinations 由模式控制的 Grandjean-Cano 披露诱导的胆甾蓝 I 相的选择性相变
Pub Date : 2024-03-28 DOI: 10.35848/1882-0786/ad38fc
Kazuma Nakajima, Shogo Mitsuhashi, Masanori Ozaki
This study investigates the influence of Grandjean-Cano disclinations on the cholesteric-blue phase I (Ch-BPI) phase transition, revealing the pivotal role of defects in phase transition of liquid crystals (LCs). We prepared the disclinations by wedge cells or parallel cells with an alignment pattern and demonstrated that the disclinations induce a phase transition in Ch-BPI. Furthermore, we demonstrated the control of the BPI appearance areas by utilizing this property. This defect-induced transition technique not only provides a novel method for controlling BPI orientation but also offers insights into soft material crystal growth, suggesting potential applications in new BPLC-based device development.
本研究探讨了 Grandjean-Cano 披露对胆固醇蓝相 I(Ch-BPI)相变的影响,揭示了缺陷在液晶相变中的关键作用。我们通过楔形晶胞或平行晶胞制备了具有排列模式的披露点,并证明披露点诱导了 Ch-BPI 的相变。此外,我们还利用这一特性证明了对 BPI 外观区域的控制。这种缺陷诱导转变技术不仅提供了一种控制 BPI 取向的新方法,而且还提供了对软材料晶体生长的见解,为基于 BPLC 的新器件开发提供了潜在应用。
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引用次数: 0
First principles study on the time-related properties of 4H-32SiC as energy converting material of betavoltaic battery 关于 4H-32SiC 作为光伏电池能量转换材料的时间相关特性的第一性原理研究
Pub Date : 2024-03-27 DOI: 10.35848/1882-0786/ad388d
Xiaoyi Li, Jingbin Lu, Xinrui Liu, Yu Zhang, Yuxin Liu, Yuehui Zhang, Fubo Tian
The radioactive 4H-32SiC is applied as energy converting material to fabricate high performance betavoltaic batteries. The time-related component change is considered, and the structural, stability and electrical property changes are calculated by Density Functional Theory (DFT). As time goes by, the number of 32Si atoms decrease exponentially while the concentration of 32S increases gradually. The Si63PC64 configurations have smaller lattice constants, while the lattices of Si62PSC64 configurations are larger. All Si63PC64 and Si62PSC64 configurations have very small bandgaps indicating the metallic behavior. This suggests that the betavoltaic battery with 4H-32SiC is likely to transform into a Schottky diode over time.
放射性 4H-32SiC 被用作制造高性能光伏电池的能量转换材料。研究考虑了与时间相关的组分变化,并通过密度泛函理论(DFT)计算了结构、稳定性和电性能的变化。随着时间的推移,32Si 原子的数量呈指数级减少,而 32S 的浓度则逐渐增加。Si63PC64 构型的晶格常数较小,而 Si62PSC64 构型的晶格常数较大。所有 Si63PC64 和 Si62PSC64 配置的带隙都非常小,这表明它们具有金属特性。这表明,使用 4H-32SiC 的光伏电池很可能随着时间的推移转变为肖特基二极管。
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引用次数: 0
期刊
Applied Physics Express
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