Electrochemical migration (ECM) has become a major reliability concern in miniaturized and high-density electronic components, particularly under damp-heat and condensation environments. This study comparatively investigates the ECM behavior of chip resistors exposed to these two moisture regimes. After applying a 6 V bias voltage for 30 min under damp-heat atmospheres with 60 %, 70 %, and 80 % relative humidity, no significant signs of corrosion were observed at the resistor terminals. In damp-heat conditions (up to 90 % RH), the anode underwent gradual Sn oxidation dominated by Sn4+ species, yet no dendritic structures were observed due to the absence of a continuous electrolyte film. In contrast, condensation environments (RH > 60 %) facilitated the formation of a continuous liquid layer, leading to rapid ECM initiation and the growth of Sn-based dendrites enriched in Sn2+ species. Furthermore, as the relative humidity increased, the degree of corrosion at both ends of the resistor became more severe correspondingly. At 90 % RH, simultaneous anodic darkening and aggravated corrosion were observed, confirming the accelerated redox processes within the condensed electrolyte. The results demonstrate that ECM failure occurs only when both a continuous electrolyte film and an external bias potential coexist, providing new insights into moisture-induced reliability degradation of surface-mount components.
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