In this work, a comparative investigation was done on the physiochemical and biological properties of tetracycline-loaded polypropylene sutures prepared through nitrogen, oxygen, and/or argon plasma treatment/grafting method. Two types of multi- and monofilament polypropylene sutures were treated by various plasma gases followed by acrylonitrile and acrylic acid grafting. Nitrogen and oxygen plasmas compared to argon plasma showed higher efficiencies in functionalization and wettability of the filaments. Tetracycline hydrochloride loading on the plasma-treated/grafted filaments was done through immersion method. The prepared filaments were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and attenuated total reflection–Fourier transform infrared spectroscopy (ATR-FTIR) and their mechanical properties were determined, accordingly. The antibacterial effect of tetracycline hydrochloride was studied over two different Gram-positive and Gram-negative bacteria. No cytotoxicity was observed for these filaments on the L929 fibroblast cell line using MTT assay. The release profile of the tetracycline hydrochloride-loaded sutures reached the stationary phase in 25 h. Nitrogen plasma-treated sutures showed the highest drug release profile among the others. The current work showed the effects of different plasma treatments on the biological, mechanical, and chemical properties of the tetracycline-loaded polypropylene sutures. The nitrogen plasma was superior to oxygen plasma in the opinion of grafting rate, mechanical properties, and antibacterial activities.
{"title":"A comparative study of the physiochemical and biological properties of tetracycline-loaded polypropylene sutures prepared through different plasma treatments","authors":"Nader kasiri, Marziyeh Mousazadeh, Faezeh Mousazadeh, Maryam Nikkhah, Hamid Keshvari","doi":"10.1007/s13726-024-01353-2","DOIUrl":"https://doi.org/10.1007/s13726-024-01353-2","url":null,"abstract":"<p>In this work, a comparative investigation was done on the physiochemical and biological properties of tetracycline-loaded polypropylene sutures prepared through nitrogen, oxygen, and/or argon plasma treatment/grafting method. Two types of multi- and monofilament polypropylene sutures were treated by various plasma gases followed by acrylonitrile and acrylic acid grafting. Nitrogen and oxygen plasmas compared to argon plasma showed higher efficiencies in functionalization and wettability of the filaments. Tetracycline hydrochloride loading on the plasma-treated/grafted filaments was done through immersion method. The prepared filaments were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and attenuated total reflection–Fourier transform infrared spectroscopy (ATR-FTIR) and their mechanical properties were determined, accordingly. The antibacterial effect of tetracycline hydrochloride was studied over two different Gram-positive and Gram-negative bacteria. No cytotoxicity was observed for these filaments on the L929 fibroblast cell line using MTT assay. The release profile of the tetracycline hydrochloride-loaded sutures reached the stationary phase in 25 h. Nitrogen plasma-treated sutures showed the highest drug release profile among the others. The current work showed the effects of different plasma treatments on the biological, mechanical, and chemical properties of the tetracycline-loaded polypropylene sutures. The nitrogen plasma was superior to oxygen plasma in the opinion of grafting rate, mechanical properties, and antibacterial activities.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\u0000","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141524994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-02DOI: 10.1007/s13726-024-01344-3
Fahima M. Helaly, Adel A. Koriem, Samaa R. Salem, Sanaa M. El-Sawy, Fikry A. Abdel-Mohdy, Aman I. Khalaf
Enhancing the vulcanization rate of elastomers is a common objective for optimizing their performance. Styrene–butadiene rubber (SBR) was vulcanized employing several conventional systems designed with various amounts of sulfur and activators/accelerators. Herein, it was an attempt to synthesize a copolymer from glycidyl methacrylate (GMA) and diethylaminoethyl methacrylate (DEAEMA)-(GMA-co-DEAEMA) and study its effect as a secondary accelerator on the curing characteristics and vulcanizate properties of SBR. The copolymer GMA-co-DEAEMA (III) was grafted with three different functional groups (R) including thioglycolic acid, 2-aminothiophenol, and 2-amino-5-mercaptothiazole, to yield III/S/1, IIII/S/2, and III/S/3 copolymers, respectively. The three-modified copolymers with an added conventional accelerator N-cyclohexyl-2-benzothiazole sulfenamide (CBS) were used to accelerate the efficiency of the vulcanizing agent (sulfur). Additional characterization of the synthesized copolymer and the obtained cured elastomer were carried out through different techniques, including mass and Fourier-transform infrared spectroscopy and thermogravimetric analysis (TGA), in addition to the rheological and mechanical studies. The results revealed that all the subject copolymers, when applied as a secondary accelerator for the SBR vulcanization reaction, enhanced the rate and the state of the cross-linking process. The findings of this study eruditely recommended that large rubber articles, like tires, could be cured more efficiently and cost-effectively when employing the presented copolymer as a secondary accelerator.
{"title":"Synergistic effect of a new binary accelerator system on curing characteristics and properties of styrene–butadiene rubber vulcanizates","authors":"Fahima M. Helaly, Adel A. Koriem, Samaa R. Salem, Sanaa M. El-Sawy, Fikry A. Abdel-Mohdy, Aman I. Khalaf","doi":"10.1007/s13726-024-01344-3","DOIUrl":"https://doi.org/10.1007/s13726-024-01344-3","url":null,"abstract":"<p>Enhancing the vulcanization rate of elastomers is a common objective for optimizing their performance. Styrene–butadiene rubber (SBR) was vulcanized employing several conventional systems designed with various amounts of sulfur and activators/accelerators. Herein, it was an attempt to synthesize a copolymer from glycidyl methacrylate (GMA) and diethylaminoethyl methacrylate (DEAEMA)-(GMA-<i>co</i>-DEAEMA) and study its effect as a secondary accelerator on the curing characteristics and vulcanizate properties of SBR. The copolymer GMA-<i>co</i>-DEAEMA (III) was grafted with three different functional groups (R) including thioglycolic acid, 2-aminothiophenol, and 2-amino-5-mercaptothiazole, to yield III/S/1, IIII/S/2, and III/S/3 copolymers, respectively. The three-modified copolymers with an added conventional accelerator <i>N</i>-cyclohexyl-2-benzothiazole sulfenamide (CBS) were used to accelerate the efficiency of the vulcanizing agent (sulfur). Additional characterization of the synthesized copolymer and the obtained cured elastomer were carried out through different techniques, including mass and Fourier-transform infrared spectroscopy and thermogravimetric analysis (TGA), in addition to the rheological and mechanical studies. The results revealed that all the subject copolymers, when applied as a secondary accelerator for the SBR vulcanization reaction, enhanced the rate and the state of the cross-linking process. The findings of this study eruditely recommended that large rubber articles, like tires, could be cured more efficiently and cost-effectively when employing the presented copolymer as a secondary accelerator.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\u0000","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-24DOI: 10.1007/s13726-024-01350-5
Wenxi Cheng, Yuanhang Cao, Wei Miao, Yongjian Zhang, Li Tian, Haowei Lin, Weiqiang Song, Yike Zhang, Tao Wang
Polylactide (PLA)/polyvinyl acetate (PVAc)/poly(ethylene glycol) (PEG) blends with different molecular weights of PEG (4000, 10000, and 20000 g/mol) were prepared, and the weight ratio was fixed at 72/18/10 (g/g/g) after the tensile analysis of PLA/PVAc and PLA/PEG blends, and finally the samples were characterized by various methods. The tensile and impact results showed that all the ternary blends were well toughened by PEG, and with the increase of PEG molecular weight, the tensile strength and impact strength increased. Scanning electron microscopy and energy-dispersive X-ray spectroscopy results indicated that 20% (by weight) of PVAc exceeded its solubility limit with PLA, and therefore the excess PVAc was dispersed as nanoparticles in the matrix. When PEG was added, the insoluble amount of PVAc decreased, indicating that the miscibility between PLA and PVAc could be increased by PEG. Differential Scanning Calorimetry results showed that Tm optical microscopy results showed that the number and size of PLA spherulites was peak areas of PLA in PLA/PVAc/PEG blends were smaller than that in PLA/PVAc blend, showing that the crystallinity of PLA was decreased with the addition of PEG in the presence of PVAc, which was confirmed by X-ray diffraction results. Polarization was the smallest in PLA/PVAc/PEG blends. All the ternary blends were transparent and had better visible light transmissions than PLA/PVAc blend. Thermal gravimetric analysis results showed that PLA and its blends had similar thermal stability. Overall, a low-cost PLA-modified material that combined high toughness, strength, and transparency without the need for customization was provided.
{"title":"Polylactide/polyvinyl acetate blends containing different molecular weights of poly(ethylene glycol)","authors":"Wenxi Cheng, Yuanhang Cao, Wei Miao, Yongjian Zhang, Li Tian, Haowei Lin, Weiqiang Song, Yike Zhang, Tao Wang","doi":"10.1007/s13726-024-01350-5","DOIUrl":"https://doi.org/10.1007/s13726-024-01350-5","url":null,"abstract":"<p>Polylactide (PLA)/polyvinyl acetate (PVAc)/poly(ethylene glycol) (PEG) blends with different molecular weights of PEG (4000, 10000, and 20000 g/mol) were prepared, and the weight ratio was fixed at 72/18/10 (g/g/g) after the tensile analysis of PLA/PVAc and PLA/PEG blends, and finally the samples were characterized by various methods. The tensile and impact results showed that all the ternary blends were well toughened by PEG, and with the increase of PEG molecular weight, the tensile strength and impact strength increased. Scanning electron microscopy and energy-dispersive X-ray spectroscopy results indicated that 20% (by weight) of PVAc exceeded its solubility limit with PLA, and therefore the excess PVAc was dispersed as nanoparticles in the matrix. When PEG was added, the insoluble amount of PVAc decreased, indicating that the miscibility between PLA and PVAc could be increased by PEG. Differential Scanning Calorimetry results showed that T<sub>m</sub> optical microscopy results showed that the number and size of PLA spherulites was peak areas of PLA in PLA/PVAc/PEG blends were smaller than that in PLA/PVAc blend, showing that the crystallinity of PLA was decreased with the addition of PEG in the presence of PVAc, which was confirmed by X-ray diffraction results. Polarization was the smallest in PLA/PVAc/PEG blends. All the ternary blends were transparent and had better visible light transmissions than PLA/PVAc blend. Thermal gravimetric analysis results showed that PLA and its blends had similar thermal stability. Overall, a low-cost PLA-modified material that combined high toughness, strength, and transparency without the need for customization was provided.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\u0000","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141529810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-23DOI: 10.1007/s13726-024-01354-1
Ning Gu, Qingxiao Liu, Qichao Liu, Ying Ren, Xiaodong Liu, Youyi Sun, Yang Cao
Polymer bone binder has attracted lots of attention due to its facile preparation, biodegradability, and so on. However, achieving strong adhesion, easy preparation, and fast setting rate for polymer bone binding is still a great challenge. So, here, a new polymer bone binder is developed and prepared to simultaneously improve setting rate and strength. The bone binder is composed of polyethyleneglycol, ethylhydroacrylate, chitosan, and SiO2 nanoparticles. It exhibits good biocompatibility and large bonding strength (ca. 2.0 MPa). Furthermore, the bone binder shows an ultra-fast setting rate (ca. 100 s), which is far faster than that reported in previous works. The bone binder is further evaluated to bond chicken bone, which exhibits a high binding force of 2.0 kgf in a short setting time of only 5.0 min. The good biocompatibility and the large bonding strength of the present bone binder are attributed to the green and environmentally friendly composition (e.g., cyanoacrylate, chitosan, polyethyleneglycol and SiO2 nanoparticles) and cross-linking network between chitosan and SiO2 nanoparticles. The ultra-fast setting process is attributed to the rapid polymerization of cyanoacrylate and the physical interaction of SiO2 nanoparticles with chitosan and polyethyleneglycol. The work provides a new method to design and prepare high-performance bone binders for use in bone fracture repair.
{"title":"Ultra-fast setting rate of a new bioactive binder for bone repair","authors":"Ning Gu, Qingxiao Liu, Qichao Liu, Ying Ren, Xiaodong Liu, Youyi Sun, Yang Cao","doi":"10.1007/s13726-024-01354-1","DOIUrl":"https://doi.org/10.1007/s13726-024-01354-1","url":null,"abstract":"<p>Polymer bone binder has attracted lots of attention due to its facile preparation, biodegradability, and so on. However, achieving strong adhesion, easy preparation, and fast setting rate for polymer bone binding is still a great challenge. So, here, a new polymer bone binder is developed and prepared to simultaneously improve setting rate and strength. The bone binder is composed of polyethyleneglycol, ethylhydroacrylate, chitosan, and SiO<sub>2</sub> nanoparticles. It exhibits good biocompatibility and large bonding strength (ca. 2.0 MPa). Furthermore, the bone binder shows an ultra-fast setting rate (ca. 100 s), which is far faster than that reported in previous works. The bone binder is further evaluated to bond chicken bone, which exhibits a high binding force of 2.0 kgf in a short setting time of only 5.0 min. The good biocompatibility and the large bonding strength of the present bone binder are attributed to the green and environmentally friendly composition (e.g., cyanoacrylate, chitosan, polyethyleneglycol and SiO<sub>2</sub> nanoparticles) and cross-linking network between chitosan and SiO<sub>2</sub> nanoparticles. The ultra-fast setting process is attributed to the rapid polymerization of cyanoacrylate and the physical interaction of SiO<sub>2</sub> nanoparticles with chitosan and polyethyleneglycol. The work provides a new method to design and prepare high-performance bone binders for use in bone fracture repair.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\u0000","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This work experimentally introduces a novel approach to vibration damping materials in industrial applications, investigating the synergistic effect of graphene nanoplates (GNP) and carbon black (CB) within styrene-butadiene rubber (SBR) to enhance both mechanical properties and vibration damping characteristics. The SBR hybrid nanocomposite containing a fixed amount of CB (20 phr) and a variable amount of GNP (2, 5, 7.5, and 10 phr) was prepared to compare with a neat SBR and 20 phr CB/SBR composite. The hybrid nanocomposites underwent assessment for morphology, tensile strength, tear strength, hardness, and vibration damping characteristics utilizing constrained layer damping (CLD). The results indicated that, in comparison to non-hybrid composites, the addition of GNP to the SBR matrix substantially improved the tensile strength by 64%, modulus by 28%, stiffness by 28%, and tear strength by 31.3%. Experimental modal analysis was used to determine the vibration characteristics. The system loss factor of the CLD exhibited a notable increase of 105% and 44% in the first and second modes, respectively, with the incorporation of 10 phr graphene in the hybridized composite, as compared to the composite containing only carbon black. The experimental damping loss factor was compared with theoretical model values proposed in one available mathematical model revealing a better agreement overall, though an exception was noted in the first mode. This paper can serve as a foundation for fabricating constrained layer damping (CLD) structures using hybrid fillers, resulting in high materials loss factors suitable for low-frequency applications.
{"title":"Synergistic effect of graphene and carbon black on the mechanical and vibration damping characteristics of styrene-butadiene rubber","authors":"Sivakumar Chandramohan, Muralidharan Vaithiyanathan, Bikash Chandra Chakraborty, Murali Manohar Dharmaraj","doi":"10.1007/s13726-024-01349-y","DOIUrl":"https://doi.org/10.1007/s13726-024-01349-y","url":null,"abstract":"<p>This work experimentally introduces a novel approach to vibration damping materials in industrial applications, investigating the synergistic effect of graphene nanoplates (GNP) and carbon black (CB) within styrene-butadiene rubber (SBR) to enhance both mechanical properties and vibration damping characteristics. The SBR hybrid nanocomposite containing a fixed amount of CB (20 phr) and a variable amount of GNP (2, 5, 7.5, and 10 phr) was prepared to compare with a neat SBR and 20 phr CB/SBR composite. The hybrid nanocomposites underwent assessment for morphology, tensile strength, tear strength, hardness, and vibration damping characteristics utilizing constrained layer damping (CLD). The results indicated that, in comparison to non-hybrid composites, the addition of GNP to the SBR matrix substantially improved the tensile strength by 64%, modulus by 28%, stiffness by 28%, and tear strength by 31.3%. Experimental modal analysis was used to determine the vibration characteristics. The system loss factor of the CLD exhibited a notable increase of 105% and 44% in the first and second modes, respectively, with the incorporation of 10 phr graphene in the hybridized composite, as compared to the composite containing only carbon black. The experimental damping loss factor was compared with theoretical model values proposed in one available mathematical model revealing a better agreement overall, though an exception was noted in the first mode. This paper can serve as a foundation for fabricating constrained layer damping (CLD) structures using hybrid fillers, resulting in high materials loss factors suitable for low-frequency applications.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\u0000","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-20DOI: 10.1007/s13726-024-01348-z
Sona Zenzingerova, Michal Kudlacek, Lubomir Benicek, David Jaska, Jana Navratilova, Lenka Gajzlerova, Roman Cermak
In this work, we examined the degradation behavior of isotactic poly(1-butene) (PB-1) under artificial aging and natural weathering conditions. PB-1 samples underwent accelerated aging through UV irradiation and natural weathering. Chemical and structural changes in the degraded samples were characterized using Fourier-transform infrared–attenuated total reflectance (FTIR–ATR) spectroscopy, surface analysis, and wide-angle X-ray scattering (WAXS). The mechanical properties were evaluated via tensile testing. FTIR–ATR analysis revealed the presence of carbonyl groups in the degraded samples, indicating oxidative degradation. Surface observations employing scanning electron microscopy (SEM) revealed the formation of surface cracks in both samples, with differing crack initiation mechanisms. The two aging methods affected the mechanical properties of the samples: artificial aging induced a gradual reduction in both tensile modulus and strength, whereas natural weathering engendered a marginal increment in modulus alongside diminished strength. Additionally, elongation-at-break value witnessed a marked decrease in both sample sets during the preliminary stages of degradation. This work employed accelerated time equivalent, obtained by juxtaposition of the values of carbonyl index during both artificial aging and natural weathering and their interpolation to determine the degradation rate and adequately to correlate the final properties of the aged PB-1. It was observed that surface morphology and mechanical attributes of degraded samples were subject to additional influences such as temperature, humidity, and precipitation during natural weathering. This research work provided significant insights into PB-1 degradation mechanisms and effect of different aging conditions on its performance.
{"title":"The degradation of poly(1-butene) extrudates subjected to artificial and natural aging","authors":"Sona Zenzingerova, Michal Kudlacek, Lubomir Benicek, David Jaska, Jana Navratilova, Lenka Gajzlerova, Roman Cermak","doi":"10.1007/s13726-024-01348-z","DOIUrl":"https://doi.org/10.1007/s13726-024-01348-z","url":null,"abstract":"<p>In this work, we examined the degradation behavior of isotactic poly(1-butene) (PB-1) under artificial aging and natural weathering conditions. PB-1 samples underwent accelerated aging through UV irradiation and natural weathering. Chemical and structural changes in the degraded samples were characterized using Fourier-transform infrared–attenuated total reflectance (FTIR–ATR) spectroscopy, surface analysis, and wide-angle X-ray scattering (WAXS). The mechanical properties were evaluated via tensile testing. FTIR–ATR analysis revealed the presence of carbonyl groups in the degraded samples, indicating oxidative degradation. Surface observations employing scanning electron microscopy (SEM) revealed the formation of surface cracks in both samples, with differing crack initiation mechanisms. The two aging methods affected the mechanical properties of the samples: artificial aging induced a gradual reduction in both tensile modulus and strength, whereas natural weathering engendered a marginal increment in modulus alongside diminished strength. Additionally, elongation-at-break value witnessed a marked decrease in both sample sets during the preliminary stages of degradation. This work employed accelerated time equivalent, obtained by juxtaposition of the values of carbonyl index during both artificial aging and natural weathering and their interpolation to determine the degradation rate and adequately to correlate the final properties of the aged PB-1. It was observed that surface morphology and mechanical attributes of degraded samples were subject to additional influences such as temperature, humidity, and precipitation during natural weathering. This research work provided significant insights into PB-1 degradation mechanisms and effect of different aging conditions on its performance.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\u0000","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-14DOI: 10.1007/s13726-024-01345-2
J. D. Zuluaga‐Parra, Luis Francisco Ramos-de Valle, Saúl Sánchez-Valdéz, Rachel Faverzani-Magnago, Adriano da Silva, Luciano da Silva
{"title":"Synergistic effect between ammonium polyphosphate-functionalized poly(lactic acid) and phosphated avocado seed on the flame-retardant properties of poly(lactic acid)/ethylene–vinyl acetate copolymer composites","authors":"J. D. Zuluaga‐Parra, Luis Francisco Ramos-de Valle, Saúl Sánchez-Valdéz, Rachel Faverzani-Magnago, Adriano da Silva, Luciano da Silva","doi":"10.1007/s13726-024-01345-2","DOIUrl":"https://doi.org/10.1007/s13726-024-01345-2","url":null,"abstract":"","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141340464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-13DOI: 10.1007/s13726-024-01325-6
Nourhen Ben Kraiem, Asma Rhimi, Khira Zlaoui, K. Horchani-Naifer, A. Hafiane, Dorra Jellouli Ennigrou
{"title":"Development of polysulfone membranes and their application for removing rare earth ions from aqueous solutions by polyvinyl alcohol-enhanced ultrafiltration","authors":"Nourhen Ben Kraiem, Asma Rhimi, Khira Zlaoui, K. Horchani-Naifer, A. Hafiane, Dorra Jellouli Ennigrou","doi":"10.1007/s13726-024-01325-6","DOIUrl":"https://doi.org/10.1007/s13726-024-01325-6","url":null,"abstract":"","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141348478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-08DOI: 10.1007/s13726-024-01341-6
Dmitry S. Konovalov, Natalia N. Saprykina, V. Zuev
{"title":"Green based composite polyurethane coatings for steel","authors":"Dmitry S. Konovalov, Natalia N. Saprykina, V. Zuev","doi":"10.1007/s13726-024-01341-6","DOIUrl":"https://doi.org/10.1007/s13726-024-01341-6","url":null,"abstract":"","PeriodicalId":601,"journal":{"name":"Iranian Polymer Journal","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141368756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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