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Preparation of Bronze (CuSn10) Parts by Material Extrusion Process Using Paraffin-Based Binder 使用石蜡基粘合剂通过材料挤压工艺制备青铜(CuSn10)零件
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1007/s11665-024-09455-x
Kai Jin, Gemin Li, Bangzheng Wei, Ruizhi Chen, Pengqi Chen, Jigui Cheng

In this study, bronze (CuSn10) feedstocks were prepared using paraffin-based binders, which were extrusion printed to obtain green parts, and bronze samples were obtained by debinding and sintering the green parts. The influence of powder loading capacity, printing temperature, and sintering temperature on the microstructure and properties of the obtained bronze samples were investigated. The results show that the obtained green bronze parts with 55% powder loading capacity printed at 160 °C have the highest density of 5.11 g/cm3. After debinding, the samples were sintered at 840 °C for 90 min in H2 atmosphere, showing the highest relative density (97.97 ± 1.05%) and hardness (65.6 ± 0.5 HB), which were comparable to bronze samples prepared by the pressing and sintering process using the same raw materials. And the maximum tensile strength and flexural strength of the printed bronze products are 286.5 ± 2.1 MPa and 313.6 ± 1.5 MPa. The present work has shown that bronze samples with complex shapes, high precision, and fewer defects can be successfully prepared by the material extrusion process under the optimum parameters.

本研究使用石蜡基粘合剂制备了青铜(CuSn10)原料,并对其进行挤压印刷以获得绿色部件,然后通过对绿色部件进行脱脂和烧结获得青铜样品。研究了粉末装载量、印刷温度和烧结温度对青铜样品微观结构和性能的影响。结果表明,在 160 ℃ 下印刷的绿色青铜零件的粉末装载量为 55%,其密度最高,为 5.11 g/cm3。去胶后,样品在 840 ℃ 的 H2 气氛中烧结 90 分钟,显示出最高的相对密度(97.97 ± 1.05%)和硬度(65.6 ± 0.5 HB),与使用相同原材料通过压制和烧结工艺制备的青铜样品相当。印刷青铜产品的最大拉伸强度和弯曲强度分别为 286.5 ± 2.1 兆帕和 313.6 ± 1.5 兆帕。本研究表明,在最佳参数条件下,材料挤压工艺可以成功制备出形状复杂、精度高、缺陷少的青铜样品。
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引用次数: 0
Experimental Investigation on Microstructure and Mechanical Properties of 15CDV6 High Strength Low Alloy Steel Welded Using Spin Arc Gas Metal Arc Welding Process 使用旋转电弧气体金属弧焊工艺焊接 15CDV6 高强度低合金钢的显微组织和力学性能实验研究
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1007/s11665-024-09432-4
G. Rajesh Kannan, P. Sathiya, T. Deepan Bharathi Kannan, M. Umar

15CDV6 is one of the widely used high strength low alloy steels in the applications of aerospace, automotive, and defense components. Welding plays a key role in all these joining applications. In this research, an attempt is made to join 15CDV6 high strength low alloy (HSLA) steel using a spin arc gas metal arc welding process (SA-GMAW) with 3.7 mm thick 15CDV6 plates and joined in butt joint configuration at three different spin rotation speed (SRS), viz., 1200, 1500, and 1800 rpm. The effect of SRS on the weld quality was studied by measuring the depth of penetration, bead width, tensile strength, and microhardness. The results indicate that increasing the SRS increases the side wall fusion. A spin rotation of 1200 rpm with 230 A, and 24 V makes a good quality weld with comparatively better strength weldment (WM) than base metal (BM). The slower spin rotational speed maintains a moderate temperature in the weld pool, causing the creation of vanadium carbide precipitates that have an impact on the mechanical properties.

15CDV6 是广泛应用于航空航天、汽车和国防部件的高强度低合金钢之一。焊接在所有这些连接应用中都起着关键作用。在这项研究中,尝试使用旋转电弧气体金属弧焊工艺(SA-GMAW)焊接 15CDV6 高强度低合金(HSLA)钢,15CDV6 钢板厚度为 3.7 毫米,在三种不同的旋转速度(SRS)(即 1200、1500 和 1800 转/分)下以对接配置进行焊接。通过测量熔透深度、焊缝宽度、拉伸强度和显微硬度,研究了 SRS 对焊接质量的影响。结果表明,增加 SRS 会增加侧壁熔合。转速为 1200 转/分、电流为 230 A、电压为 24 V 时,焊接质量良好,焊接件(WM)的强度相对优于母材(BM)。较慢的旋转速度可保持焊池温度适中,从而产生碳化钒析出物,对机械性能产生影响。
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引用次数: 0
The Role of Microstructure in the Gradient of Tensile Properties through Thickness in 7449 Aluminium Alloy Thick Plate 微观结构在 7449 铝合金厚板拉伸性能厚度梯度中的作用
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1007/s11665-024-09445-z
J. A. Heredero, J. Medina, J. M. Antoranz, P. Adeva

In this article, the yield strength, tensile strength, and the microstructure of the wrought aluminium alloy 7449 rolled thick plate have been studied through thickness under different temper conditions. For all heat treatments, it has been proven that the yield strength and tensile strength values increase from the surface to the centre. The largest difference between the centre and the surface, in both properties, occurs in the case of a sample aged at room temperature for 120 h (TTA temper). The sample artificially aged at 120 °C for 24 h (TTB temper) shows the best strength-gradient relationship of the tensile properties through the thickness. Metallographic characterisation carried out by optical and scanning electron microscopy shows much finer elongated grains in the region near the surface of the plate than in the centre, with incipient recrystallisation in the area near the surface. In addition, electron backscattered diffraction technique, used for micro-texture analysis, has proven the presence of a gradient of crystallography texture in the plate. This explains the yield strength gradient, since the rate of change of the Taylor factor through thickness correlates with the rate of the change of yield strength in the longitudinal direction for the samples studied.

本文研究了锻造铝合金 7449 轧制厚板在不同回火条件下的屈服强度、抗拉强度和微观结构。事实证明,在所有热处理中,屈服强度和抗拉强度值都是从表面向中心递增的。在室温下老化 120 小时(TTA 回火)的试样,中心和表面在这两项性能上的差异最大。在 120 °C 下人工老化 24 小时的样品(TTB 回火)显示出拉伸性能在厚度上的最佳强度梯度关系。通过光学显微镜和扫描电子显微镜进行的金相表征显示,板材表面附近区域的细长晶粒比中心区域的细长晶粒要细得多,表面附近区域出现了初生再结晶现象。此外,用于微观纹理分析的电子反向散射衍射技术证明,板材中存在结晶纹理梯度。这就解释了屈服强度梯度,因为泰勒系数在厚度上的变化率与所研究样品在纵向上的屈服强度变化率相关。
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引用次数: 0
Analysis of Microstructural Transformations Induced by Thermal Aging of Co-Cr-Ni-W-C Alloy Deposits and Their Impact on Corrosion Behavior in a 3.5% NaCl Medium 分析 Co-Cr-Ni-W-C 合金沉积物热老化引起的微结构转变及其对 3.5% 氯化钠介质中腐蚀行为的影响
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-15 DOI: 10.1007/s11665-024-09348-z
Abdelaziz Sellidj, Rym Mekideche, Bachir Zaid

This paper presents a study on the microstructural evolution of deposits based on the stellite F alloy during temperature aging and consequently its effect on corrosion resistance in 3.5% NaCl medium. The deposits were made by transferred arc plasma (PTA) spraying on an austenitic steel substrate. Heat aging treatments were carried out at 950 °C for durations ranging from 50 to 500 h. The microstructural study was performed using scanning electron microscopy coupled with energy dispersive spectrometry and the x-ray diffraction technique allowed the identification of the phases. Quantitative chemical analyses of each phase were performed using the CAMECA X50 microprobe and the electron energy loss spectrometer on a transmission electron microscope. The electrochemical behavior was achieved by monitoring the open-circuit potential and plotting the potentiodynamic and cyclic polarization curves. The electrochemical parameters of the aged bare and coated samples, in aqueous solution of NaCl 3.5% at 298 K, are derived from the polarization curves. The results of the microstructural study show a significant evolution of the microstructure of the deposits during heat treatments, marked by the decomposition of M7C3 carbides and the precipitation of M23C6 and M6C secondary carbides in the matrix. The presence of these carbides and the enrichment of the matrix in Cr improve the protective properties of the passive film formed, and consequently, the corrosion resistance of stellite alloy deposits.

本文研究了基于stellite F合金的沉积物在温度老化过程中的微观结构演变及其对3.5%氯化钠介质中耐腐蚀性的影响。这些沉积物是通过在奥氏体钢基体上进行转弧等离子(PTA)喷涂制成的。使用扫描电子显微镜和能量色散光谱仪进行了微观结构研究,并利用 X 射线衍射技术对各相进行了鉴定。使用 CAMECA X50 微型探针和透射电子显微镜上的电子能量损失光谱仪对每种相进行了定量化学分析。电化学行为是通过监测开路电势和绘制电位和循环极化曲线来实现的。在 298 K 的 3.5% 氯化钠水溶液中,根据极化曲线得出了老化裸样品和涂层样品的电化学参数。微观结构研究结果表明,在热处理过程中,沉积物的微观结构发生了显著变化,主要表现为 M7C3 碳化物的分解以及 M23C6 和 M6C 二次碳化物在基体中的沉淀。这些碳化物的存在和基体中 Cr 的富集改善了所形成的被动膜的保护性能,从而提高了卫星合金沉积物的耐腐蚀性。
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引用次数: 0
Austempering and Bainitic Transformation Kinetics of AISI 52100 AISI 52100 的奥氏体化和贝氏体转变动力学
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-12 DOI: 10.1007/s11665-024-09436-0
Haoxing You, Mei Yang, Yishu Zhang, Richard D. Sisson Jr.

AISI 52100 is a high carbon alloy steel typically used in bearings. One hardening heat treatment method for AISI 52100 is austempering, in which the steel is heated to above austenitizing temperature, cooled to just above martensite starting (Ms) temperature in quench media (typically molten salt), held at that temperature until the transformation to bainite is completed and then cooled further to room temperature. Different austempering temperatures and holding times will develop different bainite percentages in the steel and result in a variation in mechanical properties. In the present work, the bainitic transformation kinetics of AISI 52100 were investigated through experiments and simulation. Molten salt austempering trials of AISI 52100 were conducted at selected austempering temperatures and holding times. The microstructure of austempered samples were characterized with optical microscope and x-ray diffraction. The bainitic transformation kinetics were analyzed by Avrami equations using measured hardness data. The CHTE quench probe was used to measure the cooling curves in the molten salt from austenitizing temperature to the selected austempering temperatures. The heat transfer coefficient (HTC) was calculated with the measured cooling rates and used to calculate the bainitic transformation kinetics via DANTE software. The experimental results were compared with the calculated results and displayed good agreement.

AISI 52100 是一种高碳合金钢,通常用于轴承。奥氏体回火是 AISI 52100 的一种淬火热处理方法,将钢加热至奥氏体化温度以上,在淬火介质(通常为熔盐)中冷却至略高于马氏体起始(Ms)温度,在该温度下保温至贝氏体转变完成,然后进一步冷却至室温。不同的奥氏体回火温度和保温时间会在钢中形成不同比例的贝氏体,并导致机械性能的变化。本研究通过实验和模拟研究了 AISI 52100 的贝氏体转变动力学。在选定的奥氏体回火温度和保温时间下,对 AISI 52100 进行了熔盐奥氏体回火试验。用光学显微镜和 X 射线衍射法对奥氏体回火样品的微观结构进行了表征。利用测得的硬度数据,通过阿夫拉米方程分析了贝氏体转变动力学。使用 CHTE 淬火探头测量了熔盐从奥氏体化温度到选定奥氏体回火温度的冷却曲线。根据测量的冷却速率计算出传热系数 (HTC),并通过 DANTE 软件计算贝氏体转变动力学。实验结果与计算结果进行了比较,显示出良好的一致性。
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引用次数: 0
Correction: Microstructures and Mechanical Behaviors of Ni-Based Single-Crystal Superalloy DD90 Joints Brazed with a Co-Based Interlayer 更正:采用共基夹层钎焊的镍基单晶超合金 DD90 接头的微观结构和力学性能
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-11 DOI: 10.1007/s11665-024-09439-x
F. Gao, J. D. Liu, C. W. Zhu, H. Mei, Z. P. Zhang, J. L. Liu, X. M. Du, J. G. Li
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引用次数: 0
Regularization of Hole-Drilling Residual Stress Measurements with Eccentric Holes: An Approach with Influence Functions 偏心孔钻孔残余应力测量的正则化:利用影响函数的方法
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-10 DOI: 10.1007/s11665-024-09447-x
M. Beghini, L. Bertini, M. Cococcioni, T. Grossi, C. Santus, A. Benincasa

The hole-drilling method is one of the most widespread techniques to measure residual stresses. Since the introduction of the Integral Method to evaluate non-uniform stress distributions, there has been a considerable improvement in the instrumentation technology, as step increments of about 10 microns are now achievable. However, that spatial resolution makes the ill-posedness of the problem stand out among other sources of uncertainty. As the solution becomes totally dominated by noise, an additional regularization of the problem is needed to obtain meaningful results. Tikhonov regularization is the most common option, as it is also prescribed by the hole-drilling ASTM E837 standard, but it has only been studied in the reference case of a hole with no eccentricity with respect to the strain rosette. A recent work by Schajer addresses the eccentricity problem by defining a correction strategy that transforms strain measurements, allowing one to obtain the solution with the usual decoupled equations. In this work, Tikhonov regularization is applied to the eccentric hole case through the influence functions approach, in order to avoid the introduction of new error-compensating functions and bias-prone interpolations. Some useful general considerations for a practical implementation of the procedure and an experimental test case on an aluminum specimen are presented.

钻孔法是测量残余应力最广泛的技术之一。自从引入积分法来评估非均匀应力分布以来,仪器技术有了长足的进步,现在可以实现约 10 微米的步进增量。然而,这种空间分辨率使得问题的不确定性在其他不确定性来源中显得尤为突出。由于解法完全由噪声主导,因此需要对问题进行额外的正则化处理,以获得有意义的结果。Tikhonov 正则化是最常见的选择,因为它也是钻孔 ASTM E837 标准的规定,但它只在孔相对于应变罗盘没有偏心的参考情况下进行过研究。Schajer 最近的一项研究通过定义一种转换应变测量值的修正策略来解决偏心问题,从而使人们能够通过通常的解耦方程获得解决方案。在这项工作中,通过影响函数方法将 Tikhonov 正则化应用于偏心孔情况,以避免引入新的误差补偿函数和易产生偏差的插值。文中介绍了一些有用的一般考虑因素,以便实际应用该程序,并介绍了一个铝试样的实验测试案例。
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引用次数: 0
Residual Stress in Cold Spray SS304L Measured Via Neutron Diffraction and Comparison of Analytical Models to Predict the Residual Stress 通过中子衍射测量冷喷 SS304L 的残余应力并比较预测残余应力的分析模型
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-10 DOI: 10.1007/s11665-024-09422-6
Christopher M. Roper, Chris M. Fancher, Jeffrey R. Bunn, Luke N. Brewer

This study employs neutron diffraction to investigate the relationship between residual stress and coating thickness in cold sprayed 304L austenitic stainless steel. Results show that shot peening predominantly impacts the residual stress profile, leading to substantial in-plane compressive force. The impact of laser heating, a widely used method to alter cold spray's microstructural properties, on the coating's residual stress is also analyzed. The findings indicate that the maximum compressive residual stress in the in-plane component is mainly independent of coating thickness, which suggests that the material properties determine the maximum residual stress. The cold sprayed deposits possessed compressive, nearly biaxial strain and stresses. After laser heating, these stresses were replaced by tensile residual stresses. Two analytical models, the Tsui and Clyne and the Boruah models, for predicting residual stresses are also evaluated, and both models provide reasonable fits to the experimental data. At this point, the deviations between the experimental results and the models are principally caused by the inability of the current models to address plastic deformation and relaxation, and the residual stresses generated by thermal gradients.

本研究利用中子衍射法研究了冷喷 304L 奥氏体不锈钢中残余应力与涂层厚度之间的关系。结果表明,喷丸强化主要影响残余应力曲线,从而产生巨大的平面压缩力。此外,还分析了激光加热对涂层残余应力的影响,激光加热是改变冷喷微观结构特性的一种广泛使用的方法。研究结果表明,面内部分的最大压缩残余应力主要与涂层厚度无关,这表明材料特性决定了最大残余应力。冷喷沉积物具有近似双轴的压应变和应力。激光加热后,这些应力被拉伸残余应力所取代。我们还评估了预测残余应力的两个分析模型,即 Tsui 和 Clyne 模型以及 Boruah 模型,这两个模型都与实验数据进行了合理的拟合。目前,实验结果与模型之间的偏差主要是由于现有模型无法处理塑性变形和松弛以及热梯度产生的残余应力。
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引用次数: 0
Special Issue: Residual Stress Analysis—Measurement, Effects, and Control 特刊:残余应力分析--测量、影响和控制
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-10 DOI: 10.1007/s11665-024-09366-x
Rajan Bhambroo, Lesley Frame, Andrew Payzant, James Pineault
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引用次数: 0
Effect of Friction Time on Temperature Distribution, Plastic Flow, Microstructure, and Properties in Friction Welding of 1045 Carbon Steel and AISI 430 Ferritic Stainless Steel 摩擦时间对 1045 碳钢和 AISI 430 铁素体不锈钢摩擦焊接的温度分布、塑性流动、显微组织和性能的影响
IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-04-09 DOI: 10.1007/s11665-024-09410-w
Yongfang Deng, Kun Cao, Yutao Zhou, Liang Hu, Yangxin Ou, Jincheng Zeng, Zihang Li

In this paper, the effects of friction time on joint temperature distribution and plastic flow are studied by continuous drive friction welding (CDFW) and numerical simulation of 1045 carbon steel and AISI 430 ferritic stainless steel. The effects on the evolution of joint microstructure and mechanical properties are discussed. The results show that with the increase of friction time, the welding joint temperature increases gradually from 0 to 12 s and reaches the highest temperature when the welding time reaches 12 s, and then the temperature maintains a dynamic equilibrium state. The metal flow moves in both the axial and radial directions. The metal flow velocity is small in the central region and relatively large in the 0.5R region and the edge region. A thin layer of pre-eutectoid ferrite appeared at the weld zone (WZ), and the width of the pre-eutectoid layer increased with increasing friction time. C and Cr aggregated at WZ, and XRD showed that the main phase was the ferrite phase and carbides were present near the WZ. The highest microhardness was obtained at WZ, and the microhardness increased as the friction time increased. All the tested specimens experienced a brittle fracture at WZ and reached a maximum tensile strength of 467 MPa.

本文通过对 1045 碳钢和 AISI 430 铁素体不锈钢进行连续驱动摩擦焊接 (CDFW) 和数值模拟,研究了摩擦时间对接头温度分布和塑性流动的影响。讨论了对接头微观结构和机械性能演变的影响。结果表明,随着摩擦时间的增加,焊点温度从 0 秒到 12 秒逐渐升高,当焊接时间达到 12 秒时达到最高温度,随后温度保持动态平衡状态。金属流在轴向和径向都有移动。金属流动速度在中心区域较小,而在 0.5R 区域和边缘区域相对较大。在焊接区(WZ)出现了一层薄薄的前共晶铁素体,随着摩擦时间的增加,前共晶层的宽度也在增加。C 和 Cr 在 WZ 处聚集,XRD 显示主要相为铁素体相,WZ 附近存在碳化物。WZ 处的显微硬度最高,随着摩擦时间的延长,显微硬度也在增加。所有测试试样在 WZ 处均发生脆性断裂,最大抗拉强度为 467 兆帕。
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引用次数: 0
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