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A Review on Manufacturing Pure Refractory Metals by Selective Laser Melting 选择性激光熔融法制造纯耐火金属综述
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-10 DOI: 10.1007/s11665-024-09693-z
Biyao Liu, Peilei Zhang, Hua Yan, Qinghua Lu, Haichuan Shi, Zhenyu Liu, Di Wu, Tianzhu Sun, Ruifeng Li, Qingzhao Wang

Refractory metals have increasingly attracted the attention of researchers due to their excellent high-temperature strength, thermal conductivity, radiation resistance, and biocompatibility for applications in extreme environments such as aerospace and nuclear industries. However, beyond traditional manufacturing processes, the complex post-treatment process, high cost, and difficulty in manufacturing complex geometry components limit its further application in modern industry. Compared to conventional manufacturing processes, selective laser melting (SLM) technology, an emerging technology, can significantly simplify the production process and has the advantage of manufacturing parts with complex geometry. Therefore, there is increasing research on manufacturing refractory metals using SLM technology. This article describes the current research progress of pure refractory metals manufactured by SLM regarding the preparation process, microstructure, metallurgical defects, and mechanical properties of refractory metals (tungsten, molybdenum, niobium, tantalum, etc.). Generally speaking, there are some technical difficulties in the fabrication of refractory alloys by SLM, summarized in this paper. Finally, the article presented the prospect of developing SLM refractory metals.

难熔金属具有优异的高温强度、导热性、抗辐射性和生物相容性,可应用于航空航天和核工业等极端环境,因此越来越受到研究人员的关注。然而,除传统制造工艺外,复杂的后处理工艺、高昂的成本以及复杂几何形状部件的制造难度限制了其在现代工业中的进一步应用。与传统制造工艺相比,选择性激光熔融(SLM)技术作为一种新兴技术,可以大大简化生产流程,并具有制造复杂几何形状部件的优势。因此,利用 SLM 技术制造难熔金属的研究越来越多。本文就难熔金属(钨、钼、铌、钽等)的制备工艺、微观结构、冶金缺陷和机械性能等方面介绍了目前利用 SLM 制造纯难熔金属的研究进展。一般来说,用 SLM 制造难熔合金存在一些技术难题,本文对此进行了总结。最后,文章介绍了开发 SLM 难熔金属的前景。
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引用次数: 0
Synthesis of Medium Entropy Coatings and Study of the Influence of Bias Voltage and Nitrogen Flow on Their Microstructural and Tribological Properties 合成中熵涂层并研究偏压和氮气流对其微观结构和摩擦学特性的影响
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-07 DOI: 10.1007/s11665-024-09518-z
M. Alejandro Grisales, M. Daniela Chimá, G. Bejarano Gaitán

TiTaZrNb medium entropy coatings and their nitride forms (TiTaZrNb)Nx were synthesized by direct current magnetron sputtering. The study evaluated the bias voltage affects microstructure, chemical and phase composition of the metallic coatings. Also, the effect of nitrogen flow on the microstructural and tribological properties of the corresponding nitrides was studied. A change in the crystalline structure from BCC for TiTaZrNb coatings to FCC for (TiTaZrNb)Nx was observed. It was associated with the incorporation of nitrogen into the matrix and the consequent formation of a solid solution of (TiTaZrNb)Nx. An increase in the hardness and residual stresses of the metallic coating was observed with increasing bias voltage to − 130 V and of the nitride coating with increasing nitrogen flow to 12 sccm, reaching hardness values of 12.8 GPa and 25 GPa, respectively. A slight reduction in the hardness of the deposited nitride coating was observed at the higher nitrogen flow of 15 sccm, probably due to the formation of the TiN and ZrN phases. The higher hardness and lower wear rate of the (TiTaZrNb)Nx nitride coatings compared to the uncoated M2 steel samples demonstrate the protective effect against wear of these coatings.

通过直流磁控溅射合成了钛锆铌中熵涂层及其氮化物形式 (TiTaZrNb)Nx。研究评估了偏压对金属涂层微观结构、化学成分和相组成的影响。此外,还研究了氮气流对相应氮化物微观结构和摩擦学特性的影响。观察到晶体结构从 TiTaZrNb 涂层的 BCC 转变为 (TiTaZrNb)Nx 的 FCC。这与基体中加入氮以及由此形成的 (TiTaZrNb)Nx 固溶体有关。随着偏置电压升高到 - 130 V,金属涂层的硬度和残余应力都有所增加;随着氮气流量升高到 12 sccm,氮化物涂层的硬度和残余应力都有所增加,硬度值分别达到 12.8 GPa 和 25 GPa。氮气流量增加到 15 sccm 时,沉积氮化物涂层的硬度略有下降,这可能是由于形成了 TiN 和 ZrN 相。与未涂层的 M2 钢样品相比,(TiTaZrNb)Nx 氮化物涂层的硬度更高,磨损率更低,这表明这些涂层对磨损具有保护作用。
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引用次数: 0
Correction: Increasing Energy Efficiency by Optimizing Heat Treatment Parameters for High-Alloyed Tool Steels 更正:通过优化高合金工具钢的热处理参数提高能效
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-05 DOI: 10.1007/s11665-024-09673-3
Jannik Schuppener, Santiago Benito, Sebastian Weber
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引用次数: 0
Effect of Salt Spray Corrosion Performance on Variable Polarity Plasma Arc Welding of Aerospace Aluminum Alloy 盐雾腐蚀性能对航空铝合金变极性等离子弧焊的影响
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-04 DOI: 10.1007/s11665-023-08725-4
Chong Gao, Lihong Dong, Bin Liu, Haidou Wang, Bin Li, Xiaoren Lv

Variable polarity plasma arc welding (VPPAW) can be used for the excellent welding of 5A06 aluminum alloy, which is promising for aerospace applications due to its excellent welding performance and small welding deformation. In this paper, the corrosion behavior of the welding specimens was studied by a metallographic microscope, scanning electron microscope, energy dispersive spectrometer, x-ray diffractometer, and electrochemical workstation. The VPPA welded joint metallographic specimens were subjected to salt spray corrosion tests for 24, 54, 84, 114 and 144 h. The results showed that the heat-affected zone (HAZ) is more sensitive to corrosion than the weld metal (WM) and the base metal (BM), which resulted from the existence and distribution of β(Al3Mg2) and Al6(FeMn) phases in welded joints. The corrosion resistance of VPPA welded joints is WM > BM > HAZ. However, salt spray corrosion increased the corrosion sensitivity of the WM. With the increase of salt spray corrosion time, the WM corrosion tendency raised, and the corrosion resistance of WM became lower than the BM. The corrosion rate curve showed an increasing trend at first and then decreased with the increase of corrosion time, and the corrosion rate reached the highest at 84 h.

可变极性等离子弧焊(VPPAW)可用于 5A06 铝合金的优良焊接,由于其焊接性能优异、焊接变形小,因此在航空航天领域具有广阔的应用前景。本文利用金相显微镜、扫描电子显微镜、能量色散光谱仪、X 射线衍射仪和电化学工作站对焊接试样的腐蚀行为进行了研究。结果表明,热影响区(HAZ)比焊缝金属(WM)和母材金属(BM)对腐蚀更敏感,这是由于β(Al3Mg2)和 Al6(FeMn)相在焊接接头中的存在和分布造成的。VPPA 焊点的耐腐蚀性为 WM > BM > HAZ。然而,盐雾腐蚀增加了 WM 的腐蚀敏感性。随着盐雾腐蚀时间的增加,WM 的腐蚀趋势增强,WM 的耐腐蚀性能变得低于 BM。随着腐蚀时间的延长,腐蚀速率曲线呈现先上升后下降的趋势,在 84 h 时腐蚀速率达到最高。
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引用次数: 0
Comparison of Mechanical Properties of Bulk NiAl-Re-Al2O3 Intermetallic Material Manufactured by Laser Powder Bed Fusion and Hot Pressing 激光粉末床熔融和热压制造的块状 NiAl-Re-Al2O3 金属间化合物材料的力学性能比较
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-04 DOI: 10.1007/s11665-024-09657-3
Kamil Bochenek, Siegfried Arneitz, Christof Sommitsch, Michał Basista

The low fracture toughness of NiAl at room temperature is one of the critical issues limiting its application in aircraft engines. It has been previously shown that a small addition of rhenium and alumina significantly improves the fracture toughness of hot-pressed NiAl. In this work, NiAl with an admixture of rhenium and alumina was produced by laser powder bed fusion additive technology (LPBF). The purpose was to compare the fracture toughness, bending strength, and microhardness of the NiAl-Re-Al2O3 material produced by LPBF and hot pressing (HP). Our results show that the LPBF material has lower fracture toughness and bending strength compared to its hot-pressed equivalent. Microcracks generated by thermal stresses during the LPBF process were the primary cause of this behavior. To improve the LPBF material, a post-processing by HP was applied. However, the fracture toughness of the (LPBF + HP) material remained at 50% of the KIC of the HP material. This study supports hot pressing as a suitable processing method for NiAl with rhenium and alumina additions. However, a hybrid approach combining LPBF and HP proved to be highly effective on the raw NiAl powder, resulting in superior fracture toughness of the final material compared to that consolidated by singular HP.

室温下镍铝的断裂韧性较低,这是限制其在飞机发动机中应用的关键问题之一。以前的研究表明,添加少量铼和氧化铝可显著提高热压镍铝的断裂韧性。在这项工作中,采用激光粉末床熔融添加剂技术(LPBF)生产了掺有铼和氧化铝的镍铝。目的是比较 LPBF 和热压(HP)生产的 NiAl-Re-Al2O3 材料的断裂韧性、弯曲强度和显微硬度。结果表明,LPBF 材料的断裂韧性和抗弯强度低于热压材料。LPBF 工艺中的热应力产生的微裂缝是造成这种行为的主要原因。为了改善 LPBF 材料,采用了 HP 后处理。然而,(LPBF + HP)材料的断裂韧性仍然只有 HP 材料 KIC 的 50%。这项研究支持将热压作为添加铼和氧化铝的镍铝的合适加工方法。然而,结合 LPBF 和 HP 的混合方法被证明对未加工的镍铝粉非常有效,使最终材料的断裂韧性优于单一 HP 巩固的材料。
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引用次数: 0
Thank You to Our Volunteer Reviewers 感谢我们的志愿评审员
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-03 DOI: 10.1007/s11665-024-09481-9
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引用次数: 0
Measurement and Control of Residual Stress of High-Grade and Large-Diameter Welded Pipe for Oil and Gas Transportation 油气运输用高级别大口径焊管残余应力的测量与控制
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-03 DOI: 10.1007/s11665-024-09283-z
Qingren Xiong, Yanhua Li, Wenqin Shen, Weiwei Li, Xiao Li, Yonghong Zhang, Xiaofeng Xu, Junjun Jia

It was discussed that the research progress and technical achievements had been obtained in the field of residual stress measurement and control of high-grade and large-diameter welded pipe for oil and gas transportation in China. (1) The layout scheme of measuring points and the requirements of spaces between measuring points, hole depth, etc., for residual stress measurement of welded pipe using hole drilling strain-gage method were proposed. On which, the residual stress measurement technology for welded pipe was proposed. (2) The measurement results indicate that the characteristics and distribution of residual stress of SAWH pipes with different grades and sizes were quite different. In general, the residual stress of SAWH pipe was highest, followed by JCOE pipe and UOE pipe. After the ring splitting test, SAWH pipe section usually had relative displacement in circumferential, axial and radial directions, and the degree of deformation varies greatly; But SAWL pipe section usually only occurs circumferential opening, without axial and radial stagger, and the circumferential opening of JCOE pipe was usually larger than that of UOE pipe. (3) Based on the mechanical analysis of the complex deformation of SAWH pipe after the ring splitting test and the superposition principle of elastic mechanics, a prediction model of the residual stress of the high-grade and large-diameter welded pipe suitable for SAWH pipe was established, which overcame the deficiency of the existing prediction models of the residual stress of the welded pipe only considering the circumferential deformation. (4) The key forming parameters affecting the residual stress of SAWH pipe were analyzed and determined as the reduction and forming angle. Combined with the finite element simulation analysis, field adjustment and residual stress analysis, the forming technology and residual stress control technology of low residual stress SAWH pipe were developed.

论述了我国在油气输送用高等级大口径焊管残余应力测量与控制领域取得的研究进展和技术成果。(1)提出了采用钻孔应变片法测量焊管残余应力的测点布置方案及测点间距、孔深等要求。在此基础上,提出了焊管残余应力测量技术。(2) 测量结果表明,不同等级和尺寸的 SAWH 焊管的残余应力特征和分布存在很大差异。一般来说,SAWH 焊管的残余应力最大,其次是 JCOE 焊管和 UOE 焊管。劈环试验后,SAWH 管断面通常在圆周、轴向和径向都有相对位移,且变形程度差异较大;而 SAWL 管断面通常只出现圆周开口,没有轴向和径向错开,且 JCOE 管的圆周开口通常大于 UOE 管。(3)基于劈环试验后 SAWH 管复杂变形的力学分析和弹性力学叠加原理,建立了适合 SAWH 管的高级别大口径焊管残余应力预测模型,克服了现有焊管残余应力预测模型仅考虑圆周变形的不足。(4) 分析并确定了影响 SAWH 焊管残余应力的关键成形参数为减径和成形角。结合有限元模拟分析、现场调整和残余应力分析,开发了低残余应力 SAWH 焊管的成形技术和残余应力控制技术。
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引用次数: 0
316L Reinforced with Tungsten Carbide Particles by Laser-Directed Energy Deposition: Interface Microstructure and Friction-Wear Performance 通过激光能量沉积强化碳化钨颗粒的 316L:界面微观结构与摩擦磨损性能
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-03 DOI: 10.1007/s11665-024-09669-z
Yufeng Zhao, Byungwon Min, Yinfang Jiang

In order to enhance the hardness and wear resistance of 316L alloy, a strengthening phase was incorporated and laser-directed energy deposition was utilized to create a composite deposition layer consisting of coarse WC/316L, fine WC/316L, and coarse/fine WC/316L. Microstructural observations, phase composition analysis, Vickers hardness testing, interfacial coupling analysis, x-ray diffraction (XRD), and evaluation of friction-wear performance were systematically performed on the deposited samples. These investigations were undertaken to elucidate the impact of incorporating WC particles on both microstructural features and wear characteristics. Results showed that the average grain size of the composite deposition sample with coarse WC/316L decreased by 24% compared to 316L, with a 15.9% increase in hardness and a 97.6% decrease in wear rate. Similarly, the fine WC/316L composite deposition sample saw a 23% reduction in grain size, a 6.4% hardness increase, and a 62.4% decrease in wear rate compared to 316L. The hardness increased by 6.4%. The wear rate decreased by 62.4%. The coarse/fine WC/316L composite deposition samples exhibited a 34% decrease in average grain size, a 35.9% hardness increase, and a 99.1% decrease in wear rate compared to 316L. The addition of WC significantly enhanced the properties of 316L alloy, with coarse/fine WC showing the most significant improvements in microhardness and wear resistance.

为了提高 316L 合金的硬度和耐磨性,我们加入了一种强化相,并利用激光定向能量沉积来创建由粗 WC/316L、细 WC/316L 和粗/细 WC/316L 组成的复合沉积层。对沉积样品系统地进行了微观结构观察、相组成分析、维氏硬度测试、界面耦合分析、X 射线衍射 (XRD) 和摩擦磨损性能评估。这些研究旨在阐明加入 WC 颗粒对微观结构特征和磨损特性的影响。结果表明,与 316L 相比,粗 WC/316L 复合沉积样品的平均晶粒尺寸减少了 24%,硬度提高了 15.9%,磨损率降低了 97.6%。同样,与 316L 相比,细 WC/316L 复合沉积样品的晶粒尺寸减少了 23%,硬度提高了 6.4%,磨损率降低了 62.4%。硬度增加了 6.4%。磨损率降低了 62.4%。与 316L 相比,粗/细 WC/316L 复合沉积样品的平均晶粒尺寸减少了 34%,硬度提高了 35.9%,磨损率降低了 99.1%。添加碳化钨可明显提高 316L 合金的性能,其中粗/细碳化钨在显微硬度和耐磨性方面的改善最为显著。
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引用次数: 0
Residual Stress Estimation Using Hole Drilling and Contour Methods in Rail Welds Treated with and without Ultrasonic Impact Treatment 使用钻孔法和等值线法估算经过和未经过超声波冲击处理的钢轨焊缝中的残余应力
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-06-03 DOI: 10.1007/s11665-024-09665-3
Ananyo Bandyopadhyay, Gary T. Fry, Brett Watanabe

MxV Rail has explored new methods of improving the longevity of both rail and thermite welds. As a part of this research, MxV Rail explored ultrasonic impact treatment (UIT) as a method for increasing thermite weld performance and performed a residual stress investigation to estimate the distribution of the compressive and tensile stresses along the weld cross sections. UIT uses a needle to impart very small and rapid localized impacts to plastically deform the material it is applied to. Weld material reshaping and compressive residual stresses all result from UIT, which produce fatigue life improvements that benefit the life of the weld. A residual stress investigation using latest methods was also executed on both new rails and rails with different amounts of wear to analyze the distribution of estimated stresses. Fatigue defects grow quickly under tensile stresses and slowly under compressive stresses. Since UIT introduces compressive stresses on the surfaces of the weld material, an increase in the life of thermite welds can be expected due to retarded crack growth in localized areas of compressive stresses. In order to estimate the change in stress conditions caused by UIT, MxV Rail analyzed residual stresses in three thermite welds: (1) a UIT-treated new weld, (2) a UIT-treated weld removed from track after 150 million gross tons, and (3) an untreated new thermite weld. The residual stress estimations were accomplished by using hole drilling (HD) and contour methods. While the HD method provides estimated strains along two axes (longitudinal and transverse) at very shallow depths in particular locations, the contour method involves wire electric discharge machining and advanced finite element analysis to estimate the overall longitudinal strains (εzz) across the entire cross section of the weld or rail. The contour method was also applied to the rails to better understand the influence of residual stresses due to wheel–rail interaction on the head along with rail wear and how the modified residual stress distribution in worn rail compares to the initial residual stress distribution in a new rail that has been rolled but not laid in track.

MxV Rail 探索了提高钢轨和热熔焊缝寿命的新方法。作为这项研究的一部分,MxV Rail 探索了超声波冲击处理 (UIT) 作为提高热熔焊接性能的方法,并进行了残余应力调查,以估计焊接横截面上的压应力和拉应力分布。UIT 使用针头进行非常小而快速的局部冲击,使材料发生塑性变形。UIT 可使焊接材料重塑并产生压缩残余应力,从而提高疲劳寿命,延长焊接寿命。此外,还采用最新方法对新钢轨和磨损程度不同的钢轨进行了残余应力调查,以分析估计应力的分布情况。疲劳缺陷在拉应力作用下增长迅速,而在压应力作用下增长缓慢。由于 UIT 会在焊接材料表面产生压应力,因此在局部压应力区域裂纹生长速度会减慢,从而延长热熔焊缝的使用寿命。为了估算 UIT 所引起的应力条件变化,MxV Rail 分析了三个热熔焊缝的残余应力:(1) 经过 UIT 处理的新焊缝,(2) 经过 UIT 处理并在 1.5 亿总吨后从轨道上拆除的焊缝,以及 (3) 未经处理的新热熔焊缝。残余应力的估算采用钻孔法(HD)和等高线法。钻孔(HD)法可估算特定位置极浅深度上沿两个轴(纵向和横向)的应变,而等值线法则涉及金属丝放电加工和先进的有限元分析,以估算焊缝或钢轨整个横截面上的整体纵向应变 (εzz)。轮廓法还应用于钢轨,以更好地了解轮轨相互作用产生的残余应力对轨头的影响以及钢轨磨损情况,并了解磨损钢轨的修正残余应力分布与经过轧制但未铺设在轨道上的新钢轨的初始残余应力分布的比较情况。
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引用次数: 0
Selected Papers from the International Conference on Processing and Characterization of Materials (ICPCM-2022) 材料加工与表征国际会议 (ICPCM-2022) 论文选编
IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-05-29 DOI: 10.1007/s11665-024-09491-7
Joao Pedro Oliveira, B. V. Manoj Kumar, D. Arvindha Babu, Kumud Kant Mehta, Anshuman Patra, Manab Mallik
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引用次数: 0
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