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Reconfigurable Materials Based on Photocontrolled Metal–Ligand Coordination 基于光控金属配体配位的可重构材料
Pub Date : 2020-07-29 DOI: 10.1002/aisy.202000112
Jianxiong Han, Yun-shuai Huang, Ni Yang, Si Wu
Photoresponsive materials have attracted growing interest because of their potential applications in materials science, such as photoswitches, photopatterning, information storage, and so on. However, there are some challenges for photoresponsive materials for certain applications: 1) Only a few photoresponsive surfaces are transformed into multiple states after photoreactions to adapt to changing environmental conditions; 2) Photoresponsive materials may not function properly in cold environments, especially for gels. To address these problems, we have recently developed photoresponsive materials based on ruthenium (Ru) complexes. Such Ru complexes showed a photoinduced ligand substitution under visible light irradiation. Reconfigurable surfaces that can adapt to environmental changes and photoresponsive organohydrogels that function effectively at sub‐zero temperatures have been fabricated using photoresponsive Ru complexes. Herein, it is demonstrated that based on photocontrolled Ru–ligand coordination, reconfigurable surfaces can be modified for user‐defined functions via visible light irradiation and that photoresponsive gels can function even at –20 °C. As a perspective, Ru‐containing photoresponsive complexes could open up pathways for a variety of applications.
光响应材料因其在光开关、光图像化、信息存储等材料科学领域的潜在应用而受到越来越多的关注。然而,在某些应用中,光响应材料面临着一些挑战:1)只有少数光响应表面在光反应后转变为多种状态以适应不断变化的环境条件;2)光响应材料在寒冷环境下可能无法正常工作,尤其是凝胶。为了解决这些问题,我们最近开发了基于钌(Ru)配合物的光响应材料。这种钌配合物在可见光照射下表现出光诱导的配体取代。利用光响应性钌配合物制备了可适应环境变化的可重构表面和在零下温度下有效工作的光响应性有机水凝胶。本文证明,基于光控ru配体配位,可重构表面可以通过可见光照射修改为用户定义的功能,并且光响应凝胶即使在-20°C下也可以发挥作用。从一个角度来看,含钌的光响应复合物可以为各种应用开辟途径。
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引用次数: 3
Ink‐Based Additive Nanomanufacturing of Functional Materials for Human‐Integrated Smart Wearables 用于人体集成智能可穿戴设备的功能材料的油墨纳米增材制造
Pub Date : 2020-07-28 DOI: 10.1002/aisy.202000117
Shujia Xu, Wenzhuo Wu
The economical, agile, customizable manufacturing, and integration of multifunctional device modules into networked systems with mechanical compliance and robustness enable unprecedented human‐integrated smart wearables and usher in exciting opportunities in emerging technologies. The additive manufacturing (AM) processes have emerged as potential candidates for rapid prototyping printed devices with diversified functionalities, e.g., energy harvesting/storage, sensing, actuation, and computation. However, there are few review reports about the ink‐based additive nanomanufacturing of functional materials for human‐integrated smart wearables. To fill this gap, herein, the recent progress in ink‐based additive nanomanufacturing technologies, focusing on their capability and potential for producing wearable human‐integrated devices, is reviewed. The manufacturing process integration, functional materials, device implementation, and application performance issues in designing and implementing the ink‐based additively nanomanufactured wearable systems are thoroughly discussed. The recent printed devices focusing on the processing conditions and performance metrics are comprehensively reviewed. Finally, the vision and outlook for the challenges and opportunities associated with related topics are provided. The rapid progress achieved in related disciplines enables more capable smart human‐integrated wearable systems that can be fully printed with rapid, agile, reconfigurable, and smart AM platforms.
经济、灵活、可定制的制造,以及将多功能设备模块集成到具有机械遵从性和稳健性的网络系统中,使前所未有的人机集成智能可穿戴设备成为可能,并在新兴技术中迎来令人兴奋的机遇。增材制造(AM)工艺已成为具有多种功能的快速原型打印设备的潜在候选者,例如能量收集/存储、传感、驱动和计算。然而,关于墨水基添加剂纳米制造用于人体集成智能可穿戴设备的功能材料的综述报道很少。为了填补这一空白,本文综述了油墨基添加剂纳米制造技术的最新进展,重点介绍了它们在生产可穿戴人体集成设备方面的能力和潜力。深入讨论了基于油墨的纳米增材可穿戴系统的制造工艺集成、功能材料、器件实现和应用性能问题。全面回顾了近年来印刷器件的加工条件和性能指标。最后,对与相关主题相关的挑战和机遇进行了展望。相关学科的快速进展使更有能力的智能人机集成可穿戴系统能够通过快速、灵活、可重构和智能AM平台完全打印。
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引用次数: 12
Development of Artificial Neural Network System to Recommend Process Conditions of Injection Molding for Various Geometries 各种几何形状注射成型工艺条件推荐的人工神经网络系统的开发
Pub Date : 2020-07-23 DOI: 10.1002/aisy.202000037
Chihun Lee, Juwon Na, Kyongho Park, Hye-jeong Yu, Jongsun Kim, Kwon-Il Choi, D. Park, Seongjin Park, J. Rho, Seungchul Lee
This study combines an artificial neural network (ANN) and a random search to develop a system to recommend process conditions for injection molding. Both simulation and experimental results are collected using a mixed sampling method that combines Taguchi and random sampling. The dataset consists of 3600 simulations and 476 experiments from 36 different molds. Each datum has five process and 15 geometry features as input and one weight feature as output. Hyper‐parameter tuning is conducted to find the optimal ANN model. Then, transfer learning is introduced, which allows the use of simultaneous experimental and simulation data to reduce the error. The final prediction model has a root mean‐square error of 0.846. To develop a recommender system, random search is conducted using the trained ANN forward model. As a result, the weight‐prediction model based on simulated data has a relative error (RE) of 0.73%, and the weight prediction using the transfer model has an RE of 0.662%. A user interface system is also developed, which can be used directly with the injection‐molding machine. This method enables the setting of process conditions that yield parts having weights close to the target, by considering only the geometry and target weight.
本研究将人工神经网络(ANN)与随机搜索相结合,开发了一个注塑成型工艺条件推荐系统。采用田口抽样和随机抽样相结合的混合抽样方法收集仿真和实验结果。该数据集包括来自36个不同模具的3600次模拟和476次实验。每个基准有5个过程和15个几何特征作为输入,一个权重特征作为输出。进行超参数整定以找到最优的人工神经网络模型。然后,引入迁移学习,允许同时使用实验和仿真数据来减少误差。最终预测模型的均方根误差为0.846。为了开发推荐系统,使用训练好的人工神经网络前向模型进行随机搜索。结果表明,基于模拟数据的权重预测模型的相对误差(RE)为0.73%,而基于迁移模型的权重预测的相对误差(RE)为0.662%。还开发了一个用户界面系统,该系统可以直接与注塑机一起使用。这种方法能够通过只考虑几何形状和目标重量来设置产生零件重量接近目标的工艺条件。
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引用次数: 13
Lighter and Stronger: Cofabricated Electrodes and Variable Stiffness Elements in Dielectric Actuators 更轻、更强:电介质致动器中的共制电极和变刚度元件
Pub Date : 2020-07-23 DOI: 10.1002/aisy.202000069
Yegor Piskarev, J. Shintake, V. Ramachandran, Neil Baugh, M. Dickey, D. Floreano
The inherent compliance of soft robots often makes it difficult for them to exert forces on surrounding surfaces or withstand mechanical loading. Controlled stiffness is a solution to empower soft robots with the ability to apply large forces on their environments and sustain external loads without deformations. Herein, a compact, soft actuator composed of a shared electrode used for both electrostatic actuation and variable stiffness is described. The device operates as a dielectric elastomer actuator, while variable stiffness is provided by a shared electrode made of gallium. The fabricated actuator, namely variable stiffness dielectric elastomer actuator (VSDEA), has a compact and lightweight structure with a thickness of 930 μm and a mass of 0.7 g. It exhibits a stiffness change of 183×, a bending angle of 31°, and a blocked force of 0.65 mN. Thanks to the lightweight feature, the stiffness change per mass of the actuator (261× g−1) is 2.6 times higher than that of the other type of VSDEA that has no shared electrode.
软机器人固有的顺应性往往使它们难以对周围表面施加力或承受机械载荷。控制刚度是一种解决方案,使软机器人能够在其环境中施加较大的力,并在不变形的情况下承受外部负载。本文描述了一种紧凑的软致动器,该致动器由用于静电致动和可变刚度的共享电极组成。该装置作为介电弹性体致动器运行,而可变刚度由镓制成的共享电极提供。所制备的变刚度介质弹性体致动器(VSDEA)结构紧凑,重量轻,厚度为930 μm,质量为0.7 g。其刚度变化为183x,弯曲角度为31°,阻挡力为0.65 mN。由于其轻量化特性,该驱动器的每质量刚度变化(261x g−1)比其他类型的无共享电极的VSDEA高2.6倍。
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引用次数: 16
Engineering Intelligent Nanosystems for Enhanced Medical Imaging 工程智能纳米系统增强医学成像
Pub Date : 2020-07-21 DOI: 10.1002/aisy.202000087
Guido T. van Moolenbroek, Tania Patiño, J. Llop, S. Sánchez
Medical imaging serves to obtain anatomical and physiological data, supporting medical diagnostics as well as providing therapeutic evaluation and guidance. A variety of contrast agents have been developed to enhance the recorded signals and to provide molecular imaging. However, fast clearance from the body or nonspecific biodistribution often limit their efficiency, constituting challenges that need to be overcome. Nanoparticle‐based systems are currently emerging as versatile and highly integrated platforms providing improved circulating times, tissue specificity, high loading capacity for signaling moieties, and multimodal imaging features. Furthermore, nanoengineered devices can be tuned for specific applications and the development of responsive behaviors. Responses include in situ modulation of nanoparticle size, increased intratissue mobility through active propulsion of motorized particles, and active modulation of the particle surroundings such as the extracellular matrix for an improved penetration and retention at the desired locations. Once accumulated in the targeted tissue, smart nanoparticle‐based contrast agents can provide molecular sensing of biomarkers or characteristics of the tissue microenvironment. In this case, the signal or contrast provided by the nanosystem is responsive to the presence or concentration of an analyte. Herein, recent developments of intelligent nanosystems to improve medical imaging are presented.
医学影像用于获取解剖和生理数据,支持医学诊断以及提供治疗评估和指导。各种造影剂已经开发出来,以增强记录的信号和提供分子成像。然而,体内的快速清除或非特异性生物分布往往限制了它们的效率,构成了需要克服的挑战。基于纳米颗粒的系统目前正在成为多功能和高度集成的平台,可改善循环时间、组织特异性、高信号部分负载能力和多模态成像特征。此外,纳米工程设备可以针对特定的应用和响应行为的发展进行调整。响应包括纳米颗粒尺寸的原位调节,通过主动推进电动颗粒来增加组织内的流动性,以及主动调节颗粒周围环境,如细胞外基质,以改善在所需位置的渗透和保留。一旦在目标组织中积累,基于纳米颗粒的智能造影剂可以提供生物标志物或组织微环境特征的分子传感。在这种情况下,纳米系统提供的信号或对比对分析物的存在或浓度有响应。本文介绍了智能纳米系统在改善医学成像方面的最新进展。
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引用次数: 23
Stent Deployment Detection Using Radio Frequency‐Based Sensor and Convolutional Neural Networks 基于射频传感器和卷积神经网络的支架部署检测
Pub Date : 2020-07-20 DOI: 10.1002/aisy.202000092
Mengya Xu, Seenivasan Lalithkumar, L. Yeo, Hongliang Ren
A lack of sensory feedback often hinders minimally invasive operations. Although endoscopy has addressed this limitation to an extent, endovascular procedures such as angioplasty or stenting still face significant challenges. Sensors that rely on a clear line of sight cannot be used because it is unable to gather feedback in blood environments. During the stent deployment procedure, feedback on the deployed stent's state is critical because a partially open stent can affect the blood flow. Despite this, no robust and noninvasive clinical solutions that allow real‐time monitoring of the stent deployment exists. In recent years, radio frequency (RF)‐based sensors can detect the shape and material of an object that is hidden from the direct line of sight. Herein, the use of a 3D RF‐based imaging sensor and a novel Convolutional Neural Network (CNN) called StentNet is proposed for detecting the stent's state without a need for a clear line of sight. The StentNet achieves an overall accuracy of 90% in detecting the state of an occluded stent in the test dataset. Compared with an existing CNN model, the StentNet significantly outperforms the 3D LeNet in the evaluation metrics such as accuracy, precision, recall, and F1‐score.
缺乏感觉反馈常常阻碍微创手术。虽然内窥镜在一定程度上解决了这一局限性,但血管内手术如血管成形术或支架置入术仍然面临着重大挑战。依赖于清晰视线的传感器无法使用,因为它无法在血液环境中收集反馈。在支架部署过程中,对部署支架状态的反馈是至关重要的,因为部分开放的支架会影响血流。尽管如此,目前还没有可靠的、无创的临床解决方案来实时监测支架的部署。近年来,基于射频(RF)的传感器可以探测到隐藏在视线之外的物体的形状和材料。在此,提出了使用3D射频成像传感器和称为StentNet的新型卷积神经网络(CNN)来检测支架的状态,而无需清晰的视线。在测试数据集中,StentNet在检测闭塞支架状态方面达到了90%的总体准确率。与现有的CNN模型相比,StentNet在准确性、精密度、召回率和F1分数等评价指标上明显优于3D LeNet。
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引用次数: 2
Programmable Photoelectric Memristor Gates for In Situ Image Compression 用于原位图像压缩的可编程光电忆阻门
Pub Date : 2020-07-14 DOI: 10.1002/aisy.202000079
D. Berco, D. Ang, P. S. Kalaga
Integrated circuits designed to perform mathematical operations, such as Fourier transforms and matrix multiplications, in artificial visual perception and intelligent image processing are mainly constructed of conventional logic gates. However, Boolean logic is probably not the most optimal approach for brain‐inspired computing due to the fuzzy nature of biologic neural networks. This work demonstrates an application based on programmable fuzzy‐logic gates capable of combined photoelectric computations. Such an apparatus may be used to perform image compression immediately upon acquisition without having the need to rely on interaction between separate processor and sensor modules. It is based on resistive memory devices capable of state transitions in response to both electronic and light stimulations. Material nonimplication and logical true operations are first presented. A more complex functionality for material nonimplication of a logic conjunction is then demonstrated. These gates are then used as building blocks in the design and simulation of a configurable matrix multiplication unit that effectively implements in situ image compression. A membership function (FUZZIFY) that may be used to map strict logic levels to incremental fuzzy analog ones is also shown. Finally, an approach for integrating conventional logic with a fuzzy computation is discussed.
在人工视觉感知和智能图像处理中,用于执行傅里叶变换和矩阵乘法等数学运算的集成电路主要由传统逻辑门构成。然而,由于生物神经网络的模糊性,布尔逻辑可能不是大脑启发计算的最佳方法。本工作演示了基于可编程模糊逻辑门的光电组合计算应用。这样的设备可用于在采集后立即执行图像压缩,而不需要依赖于单独的处理器和传感器模块之间的交互。它是基于电阻式存储器件,能够响应电子和光刺激进行状态转换。首先提出了物质非蕴涵运算和逻辑真运算。然后演示了逻辑连接的物质非蕴涵的更复杂的功能。然后将这些门用作设计和模拟有效实现原位图像压缩的可配置矩阵乘法单元的构建块。一个隶属函数(FUZZIFY),可用于映射严格的逻辑级别到增量模糊模拟的也显示。最后,讨论了一种将传统逻辑与模糊计算相结合的方法。
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引用次数: 7
3D Manipulation of Magnetic Liquid Metals 磁性液态金属的三维操作
Pub Date : 2020-07-12 DOI: 10.1002/aisy.201900170
Wenqing Zhou, Qingxuan Liang, Tianning Chen
Herein, a new method for steering liquid metals (LMs) using only a magnetic field in open 3D space is proposed. The magnetic LM is composed of the alloy Galinstan and iron particles. The 3D horizontal and vertical manipulation of a magnetic LM can be realized via an external magnetic field. The magnetically actuated LM is not only manipulated on various complex pathways in the horizontal plane, but also vertically in 3D space without the use of electrolytes and electrodes. As a proof‐of‐principle, an intelligent delivery vehicle that can avoid obstacles and traps horizontally and overcome gravity vertically to offload a cargo is designed and implemented successfully. Furthermore, a biomimetic soft robotics that can realize both in‐plane and out‐of‐plane locomotion is demonstrated using only magnetic field. The novel 3D motion of the demonstrated system facilitates the development of practical LM‐based smart structures and devices.
在此基础上,提出了一种在开放三维空间中仅利用磁场操纵液态金属的新方法。磁性LM由Galinstan合金和铁颗粒组成。通过外加磁场可以实现磁性LM的三维水平和垂直操纵。磁致LM不仅可以在水平面上的各种复杂路径上操作,而且可以在三维空间中垂直操作,而无需使用电解质和电极。作为原理验证,设计并成功实现了一种水平避开障碍物和陷阱,垂直克服重力的智能送货车。此外,还展示了一种仅使用磁场即可实现平面内和平面外运动的仿生软机器人。演示系统的新颖3D运动促进了实用的基于LM的智能结构和设备的开发。
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引用次数: 13
Robot Audition and Computational Auditory Scene Analysis 机器人试听和计算听觉场景分析
Pub Date : 2020-07-08 DOI: 10.1002/aisy.202000050
K. Nakadai, Hiroshi G. Okuno
Robot audition aims at developing robot's ears that work in the real world, that is, machine listening of multiple sound sources. Its critical problem is noise. Speech interfaces have become more familiar and more indispensable as smartphones and artificial intelligence (AI) speakers spread. Their critical problems are noise and multiple simultaneous speakers. Recently two technological advances have contributed to significantly improve the performance of speech interfaces and robot audition. Emerging deep learning technology has improved noise robustness of automatic speech recognition, whereas microphone array processing has improved the performance of preprocessing such as noise reduction. Herein, an overview and history of robot audition are provided together with introduction of an open‐source software for robot audition and its wide applications in the real world. Also, it is discussed how robot audition contributes to the development of computational auditory scene analysis, that is, understanding of real‐world auditory environments.
机器人试听旨在开发能够在现实世界中工作的机器人耳朵,即机器聆听多个声源。它的关键问题是噪音。随着智能手机和人工智能(AI)扬声器的普及,语音界面变得越来越熟悉,越来越不可或缺。他们的主要问题是噪音和多名同时说话者。最近,两项技术进步显著提高了语音接口和机器人试听的性能。新兴的深度学习技术提高了自动语音识别的噪声鲁棒性,而麦克风阵列处理则提高了降噪等预处理性能。本文概述了机器人试听的历史,并介绍了机器人试听的开源软件及其在现实世界中的广泛应用。此外,还讨论了机器人听觉如何促进计算听觉场景分析的发展,即对现实世界听觉环境的理解。
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引用次数: 7
Pyroelectric Tweezers for Handling Liquid Unit Volumes 热释电镊子处理液体单位体积
Pub Date : 2020-07-01 DOI: 10.1002/aisy.202000044
G. Nasti, S. Coppola, V. Vespini, S. Grilli, A. Vettoliere, C. Granata, P. Ferraro
Liquids are the primary environments in which chemical, physical, and biological processes occur. Considering a liquid bridge as liquid unit volume (LUV) element, it is highly desirable to develop reliable tools for handling such volumes. Herein, a sort of intelligent microfluidic platform based on the pyroelectric‐electrohydrodynamics (EHD) is shown for manipulating liquid bridges and thus performing multiple functions in a flexible and simple way. Several basic operations with liquid bridges using an EHD‐pin matrix based on the pyroelectric effect engineered in ferroelectric crystals are demonstrated. By activating pyro‐EHD effect in predetermined positions (pins of the array), the locomotion and handling of single or multiple LUVs simultaneously are controlled. In particular, multiple operations such as lift, displacement, mixing, stretching, and carrying vector for microparticles, are shown. These tweezers based on a pyro‐EHD matrix can open the route for a multipurpose platform driven by physical intelligence and can be used for driving locomotion and operate manifolds functionalities in many areas of science and technology at microscale as well as nanoscale with advantages to be activated by the sole thermal stimulus, controlled remotely, and in noncontact mode.
液体是发生化学、物理和生物过程的主要环境。考虑到液体桥是液体单位体积(LUV)元件,开发可靠的工具来处理这种体积是非常必要的。本文提出了一种基于热释电-电流体动力学(EHD)的智能微流控平台,用于操纵液体桥,从而以灵活和简单的方式实现多种功能。本文演示了基于铁电晶体热释电效应的EHD引脚矩阵在液体桥中的几种基本操作。通过在预定位置(阵列的引脚)激活pyro - EHD效应,可以同时控制单个或多个luv的运动和处理。特别是,多个操作,如提升,位移,混合,拉伸和载体载体的微粒,显示。这些基于pyro - EHD矩阵的镊子可以为物理智能驱动的多用途平台开辟道路,可用于驱动微尺度和纳米尺度的许多科学和技术领域的运动和操作流形功能,其优点是通过唯一的热刺激激活,远程控制,非接触模式。
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引用次数: 10
期刊
Advanced Intelligent Systems
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