首页 > 最新文献

Additive manufacturing letters最新文献

英文 中文
Cellular structure engineering of additive manufactured CoCrFeMnNi high-entropy composite: The role of hard ceramic reinforcements in elemental segregation of constitutive elements 增材制造CoCrFeMnNi高熵复合材料的胞状结构工程:硬质陶瓷增强剂在本构元素偏析中的作用
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-09-22 DOI: 10.1016/j.addlet.2023.100172
Soung Yeoul Ahn , Farahnaz Haftlang , Eun Seong Kim , Ji Sun Lee , Sang Guk Jeong , Jae Bok Seol , Hyunjoo Choi , Hyoung Seop Kim

This study explores cellular structures in TiC/B4CCoCrFeMnNi high-entropy composites (HECs) fabricated by direct energy deposition (DED) additive manufacturing process, investigating the role of TiC and B4C nano-paticles in enhancing mechanical properties. Despite larger dislocation cell structures and thinner boundaries in TiC/B4CCoCrFeMnNi HECs compared to CoCrFeMnNi high-entropy alloy (HEA), they exhibit significantly higher hardness and strength, challenging traditional strength-size relationships. Additionally, we examine the behavior of ceramic nano-particles (TiC and B4C) with high melting points relative to matrix CoCrFeMnNi HEA. Rapid scanning prevents full nano-particle melting, leading to distinct element distribution of cell structure. These findings provide insights for selecting suitable nanoceramic particles in HEC development via metal additive manufacturing.

本研究探索了通过直接能量沉积(DED)增材制造工艺制备的TiC/B4CCoCrFeMnNi高熵复合材料(HECs)中的细胞结构,研究了TiC和B4C纳米颗粒在提高力学性能中的作用。尽管与CoCrFeMnNi高熵合金(HEA)相比,TiC/B4CCoCrFeMnNi HECs中的位错胞结构更大,边界更薄,但它们表现出显著更高的硬度和强度,挑战了传统的强度-尺寸关系。此外,我们还研究了具有高熔点的陶瓷纳米粒子(TiC和B4C)相对于基体CoCrFeMnNi HEA的行为。快速扫描可防止纳米颗粒完全熔化,导致细胞结构的元素分布明显。这些发现为通过金属增材制造在HEC开发中选择合适的纳米陶瓷颗粒提供了见解。
{"title":"Cellular structure engineering of additive manufactured CoCrFeMnNi high-entropy composite: The role of hard ceramic reinforcements in elemental segregation of constitutive elements","authors":"Soung Yeoul Ahn ,&nbsp;Farahnaz Haftlang ,&nbsp;Eun Seong Kim ,&nbsp;Ji Sun Lee ,&nbsp;Sang Guk Jeong ,&nbsp;Jae Bok Seol ,&nbsp;Hyunjoo Choi ,&nbsp;Hyoung Seop Kim","doi":"10.1016/j.addlet.2023.100172","DOIUrl":"https://doi.org/10.1016/j.addlet.2023.100172","url":null,"abstract":"<div><p>This study explores cellular structures in TiC/B<sub>4</sub>C<img>CoCrFeMnNi high-entropy composites (HECs) fabricated by direct energy deposition (DED) additive manufacturing process, investigating the role of TiC and B<sub>4</sub>C nano-paticles in enhancing mechanical properties. Despite larger dislocation cell structures and thinner boundaries in TiC/B<sub>4</sub>C<img>CoCrFeMnNi HECs compared to CoCrFeMnNi high-entropy alloy (HEA), they exhibit significantly higher hardness and strength, challenging traditional strength-size relationships. Additionally, we examine the behavior of ceramic nano-particles (TiC and B<sub>4</sub>C) with high melting points relative to matrix CoCrFeMnNi HEA. Rapid scanning prevents full nano-particle melting, leading to distinct element distribution of cell structure. These findings provide insights for selecting suitable nanoceramic particles in HEC development via metal additive manufacturing.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100172"},"PeriodicalIF":0.0,"publicationDate":"2023-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49751392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Prediction and understanding of non-linear distortion on large curved wall manufactured by wire-arc direct energy deposition 线弧直接能量沉积大曲面壁非线性畸变的预测与认识
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-09-22 DOI: 10.1016/j.addlet.2023.100173
Yousub Lee , Andrzej Nycz , Srdjan Simunovic , Luke Meyer , Derek Vaughan , William Carter , Sudarsanam S. Babu , Joshua Vaughan , Lonnie Love

Wire-arc direct energy deposition (wire-arc DED) has been developed to manufacture large-scale metal products with high deposition rates, low material cost, and high material efficiency. However, dynamically varying printing conditions and complex geometries frequently lead to unfavorable part distortions during and after printing which are magnified as part sizes increase. In this study, an effective computational simulation method was developed for large-scale 316 L stainless steel parts using finite element method. The model was validated with the measured distortion using a 3D laser scanner. The distribution of deviation is within 16 % (=1.6 mm) against a measured value for a 483.6 mm tall part with 248 layers, with excellent agreement with the spatial pattern of distortion. The dynamic part deformation during printing and cooling was tracked using vision camera to investigate the thermo-mechanical deformation mechanism. The result showed that long pauses during machine maintenance pauses have strong influence on part distortion.

线弧直接能量沉积(Wire-arc DED)已被开发用于制造具有高沉积速率、低材料成本和高材料效率的大规模金属产品。然而,动态变化的打印条件和复杂的几何形状经常导致在打印期间和打印之后的不利零件变形,这些变形随着零件尺寸的增加而放大。本研究采用有限元方法对大型316 L不锈钢零件进行了有效的计算模拟。使用3D激光扫描仪通过测量的畸变对模型进行了验证。对于具有248层的483.6mm高的零件,偏差分布相对于测量值在16%(=1.6mm)以内,与畸变的空间模式非常一致。利用视觉相机跟踪零件在印刷和冷却过程中的动态变形,研究其热机械变形机制。结果表明,在机器维修暂停过程中,长时间的暂停对零件变形有很大影响。
{"title":"Prediction and understanding of non-linear distortion on large curved wall manufactured by wire-arc direct energy deposition","authors":"Yousub Lee ,&nbsp;Andrzej Nycz ,&nbsp;Srdjan Simunovic ,&nbsp;Luke Meyer ,&nbsp;Derek Vaughan ,&nbsp;William Carter ,&nbsp;Sudarsanam S. Babu ,&nbsp;Joshua Vaughan ,&nbsp;Lonnie Love","doi":"10.1016/j.addlet.2023.100173","DOIUrl":"https://doi.org/10.1016/j.addlet.2023.100173","url":null,"abstract":"<div><p>Wire-arc direct energy deposition (wire-arc DED) has been developed to manufacture large-scale metal products with high deposition rates, low material cost, and high material efficiency. However, dynamically varying printing conditions and complex geometries frequently lead to unfavorable part distortions during and after printing which are magnified as part sizes increase. In this study, an effective computational simulation method was developed for large-scale 316 L stainless steel parts using finite element method. The model was validated with the measured distortion using a 3D laser scanner. The distribution of deviation is within 16 % (=1.6 mm) against a measured value for a 483.6 mm tall part with 248 layers, with excellent agreement with the spatial pattern of distortion. The dynamic part deformation during printing and cooling was tracked using vision camera to investigate the thermo-mechanical deformation mechanism. The result showed that long pauses during machine maintenance pauses have strong influence on part distortion.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100173"},"PeriodicalIF":0.0,"publicationDate":"2023-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49758992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Large Format Composite Additive Manufacturing for Low-Head Hydropower 用于低水头水电的大幅面复合增材制造
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-09-21 DOI: 10.1016/j.addlet.2023.100170
Alex Roschli , Brian Post , Randal Mueller , Vito Gervasi , Phillip Chesser , Jesse Heineman , Rebecca Brink

Hydropower with a small elevation change from inlet to outlet, known as “low-head” hydropower, is a relatively untapped resource for reliable green power generation. One major barrier to entry is the cost of the components needed to generate the power. Each installation site is unique, with various head levels, flow rates, and other unique site characteristics that drive up the cost of development and installation. As a result, custom-made components are necessary because the sites are intrinsically inefficient. However, customized parts are generally more expensive to manufacture than ready-made parts. Often times, the cost of custom-made components is so high that the low-head hydropower installation becomes non-viable. Additive manufacturing offers the ability to make custom components, ideal for one-off applications, at low costs that are well suited for the needs of low-head hydropower. Indirect additive manufacturing, such as making tools or dies rather than end use components, can also be used to make low-cost composite tooling as needed for these custom applications. This paper explores the use of additive manufacturing, both directly and indirectly, to produce the components of a turbine system for a low-head hydropower site. The parts were designed to form a unique modular system, which saves time for future designs and iterations. The system has operated for more than three years without failure at a test site in Wisconsin, USA. This work serves as a basis for future application of AM to low-head systems, in which the modular components can be customized for each unique hydropower installation.

从进水口到出水口高程变化较小的水电,被称为“低水头”水电,是一种相对未开发的可靠绿色发电资源。进入的一个主要障碍是发电所需组件的成本。每个安装场地都是独特的,具有不同的水头水平、流速和其他独特的场地特性,这些特性会推高开发和安装成本。因此,定制组件是必要的,因为这些站点本质上效率低下。然而,定制零件的制造成本通常高于现成零件。通常情况下,定制组件的成本非常高,以至于低水头水电安装变得不可行。增材制造提供了以低成本制造定制组件的能力,非常适合一次性应用,非常适合低水头水电的需求。间接增材制造,例如制造工具或模具,而不是最终用途的部件,也可以用于制造这些定制应用所需的低成本复合材料工具。本文探讨了直接和间接使用增材制造来生产低水头水电站涡轮机系统的部件。这些部件被设计成一个独特的模块化系统,为未来的设计和迭代节省了时间。该系统已在美国威斯康星州的一个试验场运行了三年多,没有出现故障。这项工作为AM未来应用于低水头系统奠定了基础,在低水头系统中,模块化组件可以针对每个独特的水电安装进行定制。
{"title":"Large Format Composite Additive Manufacturing for Low-Head Hydropower","authors":"Alex Roschli ,&nbsp;Brian Post ,&nbsp;Randal Mueller ,&nbsp;Vito Gervasi ,&nbsp;Phillip Chesser ,&nbsp;Jesse Heineman ,&nbsp;Rebecca Brink","doi":"10.1016/j.addlet.2023.100170","DOIUrl":"https://doi.org/10.1016/j.addlet.2023.100170","url":null,"abstract":"<div><p>Hydropower with a small elevation change from inlet to outlet, known as “low-head” hydropower, is a relatively untapped resource for reliable green power generation. One major barrier to entry is the cost of the components needed to generate the power. Each installation site is unique, with various head levels, flow rates, and other unique site characteristics that drive up the cost of development and installation. As a result, custom-made components are necessary because the sites are intrinsically inefficient. However, customized parts are generally more expensive to manufacture than ready-made parts. Often times, the cost of custom-made components is so high that the low-head hydropower installation becomes non-viable. Additive manufacturing offers the ability to make custom components, ideal for one-off applications, at low costs that are well suited for the needs of low-head hydropower. Indirect additive manufacturing, such as making tools or dies rather than end use components, can also be used to make low-cost composite tooling as needed for these custom applications. This paper explores the use of additive manufacturing, both directly and indirectly, to produce the components of a turbine system for a low-head hydropower site. The parts were designed to form a unique modular system, which saves time for future designs and iterations. The system has operated for more than three years without failure at a test site in Wisconsin, USA. This work serves as a basis for future application of AM to low-head systems, in which the modular components can be customized for each unique hydropower installation.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100170"},"PeriodicalIF":0.0,"publicationDate":"2023-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49727329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-situ tension investigation of additively manufactured silver lines on flexible substrates 柔性基板上增材制造银线的现场张力研究
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-09-20 DOI: 10.1016/j.addlet.2023.100171
Seungjong Lee , Zabihollah Ahmadi , Mikyle Paul , Masoud Mahjouri-Samani , Shuai Shao , Nima Shamsaei

The reliability of additively manufactured flexible electronics or so-called printed electronics is defined as mean time to failure under service conditions, which often involve mechanical loads. It is thus important to understand the mechanical behavior of the printed materials under such conditions to ensure their applicational reliability in, for example, sensors, biomedical devices, battery and storage, and flexible hybrid electronics. In this article, a testing protocol to examine the print quality of additively nanomanufactured electronics is presented. The print quality is assessed by both tensile and electrical resistivity responses during in-situ tension tests. A laser based additive nanomanufacturing method is used to print conductive silver lines on polyimide substrates, which is then tested in-situ under tension inside a scanning electron microscope (SEM). The surface morphology of the printed lines is continuously monitored via the SEM until failure. In addition, the real-time electrical resistance variations of the printed silver lines are measured in-situ with a multimeter during tensile tests conducted outside of the SEM. The protocol is shown to be effective in assessing print quality and aiding process tuning. Finally, it is revealed that samples appearing identical under the SEM can have significant different tendencies to delaminate.

额外制造的柔性电子器件或所谓的印刷电子器件的可靠性被定义为在使用条件下的平均故障时间,这通常涉及机械负载。因此,重要的是了解印刷材料在这种条件下的机械行为,以确保其在例如传感器、生物医学设备、电池和存储器以及柔性混合电子器件中的应用可靠性。在这篇文章中,提出了一个测试协议,以检查添加纳米制造的电子产品的打印质量。在现场张力测试期间,通过拉伸和电阻率响应来评估打印质量。使用基于激光的增材纳米制造方法在聚酰亚胺基底上印刷导电银线,然后在扫描电子显微镜(SEM)内的张力下进行原位测试。通过SEM连续监测印刷线路的表面形态,直到失效。此外,在扫描电镜外进行的拉伸测试中,使用万用表原位测量印刷银线的实时电阻变化。该协议被证明在评估印刷质量和帮助工艺调整方面是有效的。最后,研究表明,在SEM下看起来完全相同的样品可能具有显著不同的分层趋势。
{"title":"In-situ tension investigation of additively manufactured silver lines on flexible substrates","authors":"Seungjong Lee ,&nbsp;Zabihollah Ahmadi ,&nbsp;Mikyle Paul ,&nbsp;Masoud Mahjouri-Samani ,&nbsp;Shuai Shao ,&nbsp;Nima Shamsaei","doi":"10.1016/j.addlet.2023.100171","DOIUrl":"https://doi.org/10.1016/j.addlet.2023.100171","url":null,"abstract":"<div><p>The reliability of additively manufactured flexible electronics or so-called printed electronics is defined as mean time to failure under service conditions, which often involve mechanical loads. It is thus important to understand the mechanical behavior of the printed materials under such conditions to ensure their applicational reliability in, for example, sensors, biomedical devices, battery and storage, and flexible hybrid electronics. In this article, a testing protocol to examine the print quality of additively nanomanufactured electronics is presented. The print quality is assessed by both tensile and electrical resistivity responses during in-situ tension tests. A laser based additive nanomanufacturing method is used to print conductive silver lines on polyimide substrates, which is then tested in-situ under tension inside a scanning electron microscope (SEM). The surface morphology of the printed lines is continuously monitored via the SEM until failure. In addition, the real-time electrical resistance variations of the printed silver lines are measured in-situ with a multimeter during tensile tests conducted outside of the SEM. The protocol is shown to be effective in assessing print quality and aiding process tuning. Finally, it is revealed that samples appearing identical under the SEM can have significant different tendencies to delaminate.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100171"},"PeriodicalIF":0.0,"publicationDate":"2023-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49765622","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of interlayer temperature on melt-pool morphology in laser powder bed fusion 层间温度对激光粉末床熔池形貌的影响
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-08-22 DOI: 10.1016/j.addlet.2023.100169
Qian Wang , Panagiotis Michaleris Pan , Yong Ren , Corey Dickman , Edward Reutzel

Considering the high correlation of melt-pool size and build quality of a part fabricated by a laser power bed fusion (L-PBF) process, it is important to understand what are the major thermal factors that affect melt-pool size during the build process. This paper conducts an experimental investigation on how interlayer temperature affects the melt-pool morphology through a case study of a square-canonical part of Inconel 718 built with the EOS M280 system. Interlayer temperature is the layer temperature after powder spreading but before scanning a new layer. This paper examines variations in melt-pool morphology across representative layers with a large difference in interlayer temperature. It also investigates how the melt-pool size variation is affected by local temperature change caused by switching the laser scanning direction from hatch-to-hatch within a single layer. It is observed that the melt-pool half-width has increased by 40% - 100% when the interlayer temperature has increased from 100 °C to 300 °C. On the other hand, the variation of melt-pool dimensions due to local temperature change is less significant under a low interlayer temperature at 100 °C. The difference in melt-pool dimensions due to laser turnaround gets amplified when the interlayer temperature reaches high at 300 °C. Moreover, a trend of melt-pool morphology transitioning from a conduction to a convective heat transfer mode is observed at the interlayer temperature of 300 °C. Results of this paper demonstrate that interlayer temperature plays a critical role in thermal effects on melt-pool morphology, indicating a need of controlling interlayer temperature to improve build quality.

考虑到熔池尺寸与激光动力床熔融(L-PBF)工艺制造的零件的构建质量高度相关,了解在构建过程中影响熔池尺寸的主要热因素是很重要的。本文以EOS M280系统构建的英科耐尔718方形正截面为例,对层间温度对熔池形貌的影响进行了实验研究。层间温度是粉末扩散后扫描新层之前的层间温度。本文考察了具有代表性的层间温度差异较大的熔池形态的变化。本文还研究了当激光扫描方向在单层内从一个舱口切换到另一个舱口时所引起的局部温度变化对熔池尺寸变化的影响。观察到,当层间温度从100℃升高到300℃时,熔池半宽增加了40% ~ 100%。另一方面,当层间温度较低(100°C)时,由于局部温度变化引起的熔池尺寸变化不太显著。当层间温度达到300°C时,由于激光旋转引起的熔池尺寸差异被放大。此外,在层间温度为300℃时,熔池形态有由传导传热向对流传热转变的趋势。研究结果表明,层间温度对熔池形态的热效应起着至关重要的作用,表明需要控制层间温度以提高熔池质量。
{"title":"Effect of interlayer temperature on melt-pool morphology in laser powder bed fusion","authors":"Qian Wang ,&nbsp;Panagiotis Michaleris Pan ,&nbsp;Yong Ren ,&nbsp;Corey Dickman ,&nbsp;Edward Reutzel","doi":"10.1016/j.addlet.2023.100169","DOIUrl":"10.1016/j.addlet.2023.100169","url":null,"abstract":"<div><p>Considering the high correlation of melt-pool size and build quality of a part fabricated by a laser power bed fusion (L-PBF) process, it is important to understand what are the major thermal factors that affect melt-pool size during the build process. This paper conducts an experimental investigation on how interlayer temperature affects the melt-pool morphology through a case study of a square-canonical part of Inconel 718 built with the EOS M280 system. Interlayer temperature is the layer temperature after powder spreading but before scanning a new layer. This paper examines variations in melt-pool morphology across representative layers with a large difference in interlayer temperature. It also investigates how the melt-pool size variation is affected by local temperature change caused by switching the laser scanning direction from hatch-to-hatch within a single layer. It is observed that the melt-pool half-width has increased by 40% - 100% when the interlayer temperature has increased from 100<!--> <!-->°C to 300<!--> <!-->°C. On the other hand, the variation of melt-pool dimensions due to local temperature change is less significant under a low interlayer temperature at 100<!--> <!-->°C. The difference in melt-pool dimensions due to laser turnaround gets amplified when the interlayer temperature reaches high at 300<!--> <!-->°C. Moreover, a trend of melt-pool morphology transitioning from a conduction to a convective heat transfer mode is observed at the interlayer temperature of 300<!--> <!-->°C. Results of this paper demonstrate that interlayer temperature plays a critical role in thermal effects on melt-pool morphology, indicating a need of controlling interlayer temperature to improve build quality.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100169"},"PeriodicalIF":0.0,"publicationDate":"2023-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45196800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correlating the microstructure and hardness of AlSi10Mg powder with additively-manufactured parts upon in-situ heat-treatments in laser beam powder bed fusion 激光束粉末床聚变原位热处理AlSi10Mg粉末与添加零件的微观结构和硬度的相关性
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-08-13 DOI: 10.1016/j.addlet.2023.100168
Chinmay Phutela , Federico Bosio , Peifeng Li , Nesma T. Aboulkhair

Laser beam powder bed fusion (PBF-LB) of AlSi10Mg has attained technology maturity in various industries. Nevertheless, the manufactured components often require thermal treatments to tailor their microstructures and mechanical properties. Experimental development of suitable thermal cycles for the printed parts is time and energy intensive. However, the characteristic microstructure of parts produced by PBF-LB resembles that of gas-atomised powder. Therefore, this study presents an in-depth investigation on the correlation between the properties of the powder and PBF-LB samples. In-situ heat treatment methodology was deployed to consistently heat-treat the powder and PBF-LB samples using elevated build-plate temperatures (220 - 500 ºC). Scanning electron microscopy revealed Si atoms’ diffusion, followed by eutectic network's disruption and Si particles’ coarsening, with increased build plate temperatures, in both parts and powder. X-ray diffraction and differential scanning calorimetry showed a strong correlation between the powder and parts treated at the same build-plate temperatures. A 500 ºC in-situ heat-treatment temperature reduced the hardness by ∼43% (powder) and ∼52% (printed samples). Nano- and micro-hardness values on the powder and printed samples also exhibited high correlation. Similarities between the powder and part's microstructural changes with temperature were attributed to the similar scale of cooling rates in gas-atomisation and PBF-LB, respectively. The findings in this study pave a clear pathway that experimentation on small batches of powder via ex-situ heat treatments could be efficiently used as a high-throughput method to predict the effect of thermal treatments on printed parts and to design new heat treatment protocols, specifically for PBF-LB materials.

AlSi10Mg的激光粉末床熔炼(PBF-LB)技术在各行业已达到成熟。然而,制造的部件通常需要热处理以调整其微观结构和机械性能。为打印件设计合适的热循环是一项耗时耗力的工作。然而,PBF-LB生产的零件的特征微观结构类似于气体雾化粉末。因此,本研究对粉末性能与PBF-LB样品之间的相关性进行了深入的研究。采用原位热处理方法,通过提高构建板温度(220 - 500℃)对粉末和PBF-LB样品进行持续热处理。扫描电子显微镜显示,随着制版温度的升高,零件和粉末中Si原子的扩散、共晶网络的破坏和Si颗粒的粗化。x射线衍射和差示扫描量热法表明,粉末和在相同铸板温度下处理的零件之间存在很强的相关性。500℃的原位热处理温度使硬度降低了~ 43%(粉末)和~ 52%(印刷样品)。粉末和印刷样品的纳米和显微硬度值也表现出高度的相关性。粉末和零件微结构随温度变化的相似性分别归因于气体雾化和PBF-LB中相似的冷却速率。本研究的发现为通过非原位热处理对小批量粉末进行实验铺平了一条清晰的道路,这可以有效地用作高通量方法来预测热处理对打印部件的影响,并设计新的热处理方案,特别是针对PBF-LB材料。
{"title":"Correlating the microstructure and hardness of AlSi10Mg powder with additively-manufactured parts upon in-situ heat-treatments in laser beam powder bed fusion","authors":"Chinmay Phutela ,&nbsp;Federico Bosio ,&nbsp;Peifeng Li ,&nbsp;Nesma T. Aboulkhair","doi":"10.1016/j.addlet.2023.100168","DOIUrl":"10.1016/j.addlet.2023.100168","url":null,"abstract":"<div><p>Laser beam powder bed fusion (PBF-LB) of AlSi10Mg has attained technology maturity in various industries. Nevertheless, the manufactured components often require thermal treatments to tailor their microstructures and mechanical properties. Experimental development of suitable thermal cycles for the printed parts is time and energy intensive. However, the characteristic microstructure of parts produced by PBF-LB resembles that of gas-atomised powder. Therefore, this study presents an in-depth investigation on the correlation between the properties of the powder and PBF-LB samples. In-situ heat treatment methodology was deployed to consistently heat-treat the powder and PBF-LB samples using elevated build-plate temperatures (220 - 500 ºC). Scanning electron microscopy revealed Si atoms’ diffusion, followed by eutectic network's disruption and Si particles’ coarsening, with increased build plate temperatures, in both parts and powder. X-ray diffraction and differential scanning calorimetry showed a strong correlation between the powder and parts treated at the same build-plate temperatures. A 500 ºC in-situ heat-treatment temperature reduced the hardness by ∼43% (powder) and ∼52% (printed samples). Nano- and micro-hardness values on the powder and printed samples also exhibited high correlation. Similarities between the powder and part's microstructural changes with temperature were attributed to the similar scale of cooling rates in gas-atomisation and PBF-LB, respectively. The findings in this study pave a clear pathway that experimentation on small batches of powder via <em>ex-situ</em> heat treatments could be efficiently used as a high-throughput method to predict the effect of thermal treatments on printed parts and to design new heat treatment protocols, specifically for PBF-LB materials.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100168"},"PeriodicalIF":0.0,"publicationDate":"2023-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48348212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Automatic in-situ error correction for 3D printed electronics 3D打印电子产品的自动原位误差校正
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-07-28 DOI: 10.1016/j.addlet.2023.100164
Daniel Ahlers , Florens Wasserfall , Johannes Hörber , Jianwei Zhang

Defects are a major issue in 3D printed electronics because even a tiny inaccuracy will lead to a faulty electronic circuit. This article presents a novel approach to correct printing defects with a neural network based automatic error correction. The errors are detected during printing by recording images of each wire with a high-resolution camera and segmenting the wires using convolutional neural networks. The neural network is trained with a dataset of printed wires with marked wire positions. A novel error detection algorithm then identifies connection breaks and generates repair paths for every connection break in the circuit, which are then executed by the printer. Multiple objects with deliberately inserted defects were printed and automatically repaired on different substrates using a Neotech AMT PJ15X printer to evaluate the performance. The algorithm detected all connection breaks, generated repair paths, and successfully repaired the faulty wires. This article also shows this approach's limitations and areas for future research, like complex circuits printed on 5-axis machines. The automatic error correction is highly reliable and is an important step towards a first-time-right production.

缺陷是3D打印电子产品的主要问题,因为即使是微小的不准确也会导致电子电路故障。本文提出了一种基于神经网络的印刷缺陷自动纠错方法。在打印过程中,用高分辨率相机记录每根电线的图像,并使用卷积神经网络对电线进行分割,从而检测出错误。神经网络是用带有标记导线位置的印刷导线数据集来训练的。然后,一种新的错误检测算法识别连接中断,并为电路中的每个连接中断生成修复路径,然后由打印机执行。使用Neotech AMT PJ15X打印机在不同的基板上打印并自动修复带有故意插入缺陷的多个对象,以评估性能。该算法检测所有断开的连接,生成修复路径,并成功修复故障导线。本文还展示了这种方法的局限性和未来研究的领域,如在5轴机器上打印复杂电路。自动纠错是高度可靠的,是实现首次正确生产的重要一步。
{"title":"Automatic in-situ error correction for 3D printed electronics","authors":"Daniel Ahlers ,&nbsp;Florens Wasserfall ,&nbsp;Johannes Hörber ,&nbsp;Jianwei Zhang","doi":"10.1016/j.addlet.2023.100164","DOIUrl":"10.1016/j.addlet.2023.100164","url":null,"abstract":"<div><p>Defects are a major issue in 3D printed electronics because even a tiny inaccuracy will lead to a faulty electronic circuit. This article presents a novel approach to correct printing defects with a neural network based automatic error correction. The errors are detected during printing by recording images of each wire with a high-resolution camera and segmenting the wires using convolutional neural networks. The neural network is trained with a dataset of printed wires with marked wire positions. A novel error detection algorithm then identifies connection breaks and generates repair paths for every connection break in the circuit, which are then executed by the printer. Multiple objects with deliberately inserted defects were printed and automatically repaired on different substrates using a Neotech AMT PJ15X printer to evaluate the performance. The algorithm detected all connection breaks, generated repair paths, and successfully repaired the faulty wires. This article also shows this approach's limitations and areas for future research, like complex circuits printed on 5-axis machines. The automatic error correction is highly reliable and is an important step towards a first-time-right production.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100164"},"PeriodicalIF":0.0,"publicationDate":"2023-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41315233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Multi-material laser powder bed fusion additive manufacturing of concentrated wound stator teeth 多材料激光粉末床融合增材制造集中缠绕定子齿
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-07-27 DOI: 10.1016/j.addlet.2023.100165
Marcus Oel , Johannes Rossmann , Behrend Bode , Ina Meyer , Tobias Ehlers , Christoph M. Hackl , Roland Lachmayer

Additive manufacturing using Powder Bed Fusion by Laser Beam (PBF-LB) enables products with high design freedom. In addition, the ability to process more than one material in all three spatial directions makes it possible to produce highly functional components in one single process. This article investigates whether multi-material manufacturing using PBF-LB is suitable for producing coils for electric motors, which are designed with integrated cooling channels to increase the power density. For this purpose, the copper alloy CuCr1Zr for the coils and the stainless steel 1.4404 (316L) for the core are processed simultaneously. The component designs were verified using 2D and 3D finite element analysis and then manufactured in a multi-material PBF-LB process. While good electrical conductivity of the copper alloy was achieved by heat treatment, it was found that thermal distortion caused deviations from the nominal geometry. The measurement of the electrical properties showed that this distortion leads to short-circuit currents within the coils and the teeth. On this basis, ideas for solutions were developed, with the help of which the functionality of the coils can be ensured or the power density can also be increased. In addition to adapting the design of the component, this includes processing additional or other materials, such as soft magnetic composites.

使用激光粉末床融合(PBF-LB)的增材制造使产品具有高设计自由度。此外,在所有三个空间方向上加工一种以上材料的能力使得在单一工艺中生产高功能部件成为可能。本文研究了PBF-LB多材料制造是否适用于电机线圈的生产,这些线圈设计有集成的冷却通道以提高功率密度。为此,线圈的铜合金CuCr1Zr和铁芯的不锈钢1.4404 (316L)同时加工。通过二维和三维有限元分析验证了零件设计,然后在多材料PBF-LB工艺中制造。虽然铜合金通过热处理获得了良好的导电性,但发现热变形导致了与标称几何形状的偏差。电学性能的测量表明,这种变形导致线圈和齿内的短路电流。在此基础上,开发了解决方案的想法,借助它可以确保线圈的功能或也可以增加功率密度。除了适应组件的设计外,这还包括加工其他材料,如软磁复合材料。
{"title":"Multi-material laser powder bed fusion additive manufacturing of concentrated wound stator teeth","authors":"Marcus Oel ,&nbsp;Johannes Rossmann ,&nbsp;Behrend Bode ,&nbsp;Ina Meyer ,&nbsp;Tobias Ehlers ,&nbsp;Christoph M. Hackl ,&nbsp;Roland Lachmayer","doi":"10.1016/j.addlet.2023.100165","DOIUrl":"10.1016/j.addlet.2023.100165","url":null,"abstract":"<div><p>Additive manufacturing using Powder Bed Fusion by Laser Beam (PBF-LB) enables products with high design freedom. In addition, the ability to process more than one material in all three spatial directions makes it possible to produce highly functional components in one single process. This article investigates whether multi-material manufacturing using PBF-LB is suitable for producing coils for electric motors, which are designed with integrated cooling channels to increase the power density. For this purpose, the copper alloy CuCr1Zr for the coils and the stainless steel 1.4404 (316L) for the core are processed simultaneously. The component designs were verified using 2D and 3D finite element analysis and then manufactured in a multi-material PBF-LB process. While good electrical conductivity of the copper alloy was achieved by heat treatment, it was found that thermal distortion caused deviations from the nominal geometry. The measurement of the electrical properties showed that this distortion leads to short-circuit currents within the coils and the teeth. On this basis, ideas for solutions were developed, with the help of which the functionality of the coils can be ensured or the power density can also be increased. In addition to adapting the design of the component, this includes processing additional or other materials, such as soft magnetic composites.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100165"},"PeriodicalIF":0.0,"publicationDate":"2023-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44026910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Additive manufacturing of carbon steels by materials extrusion of oxide precursors and hydrogen reduction 用氧化物前驱体挤压和氢还原的材料增材制造碳钢
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-07-22 DOI: 10.1016/j.addlet.2023.100166
Collin Stiers, Katie Koube, Ethan Sinclair, Hyoungjun Sim, Elias Winterscheidt, Josh Kacher

A hydrogen reduction-based method for additive manufacturing of carbon steels from low cost and stable oxide powders is presented. This method uses materials extrusion processes to extrude inks composed of oxide powders, plastic binders, and solvents. Oxide powders are synthesized into viscous inks and extruded under ambient conditions into three-dimensional architectures. The three-dimensional printed green bodies are reduced at elevated temperatures in hydrogen-rich environments to burn off the polymer binder and reduce the oxide powders, yielding metal alloys with controlled compositions. While this approach has been demonstrated in previous publications for various alloys, the addition of carbon, an important element in most industrial steels, has been a persistent challenge. This paper demonstrates an approach to introduce carbon during the reduction process, resulting in through-thickness carburization of the final parts.

提出了一种以氢还原为基础的低成本稳定氧化物粉末增材制造碳钢的方法。该方法采用材料挤出工艺,挤出由氧化物粉末、塑料粘合剂和溶剂组成的油墨。氧化物粉末被合成成粘性油墨,并在环境条件下挤压成三维结构。三维打印的绿体在富氢环境中的高温下被还原,以燃烧掉聚合物粘合剂并减少氧化物粉末,产生具有控制成分的金属合金。虽然这种方法已经在以前的出版物中用于各种合金,但添加碳(大多数工业钢中的重要元素)一直是一个持续的挑战。本文演示了在还原过程中引入碳的方法,从而使最终零件的渗碳达到全厚渗碳。
{"title":"Additive manufacturing of carbon steels by materials extrusion of oxide precursors and hydrogen reduction","authors":"Collin Stiers,&nbsp;Katie Koube,&nbsp;Ethan Sinclair,&nbsp;Hyoungjun Sim,&nbsp;Elias Winterscheidt,&nbsp;Josh Kacher","doi":"10.1016/j.addlet.2023.100166","DOIUrl":"10.1016/j.addlet.2023.100166","url":null,"abstract":"<div><p>A hydrogen reduction-based method for additive manufacturing of carbon steels from low cost and stable oxide powders is presented. This method uses materials extrusion processes to extrude inks composed of oxide powders, plastic binders, and solvents. Oxide powders are synthesized into viscous inks and extruded under ambient conditions into three-dimensional architectures. The three-dimensional printed green bodies are reduced at elevated temperatures in hydrogen-rich environments to burn off the polymer binder and reduce the oxide powders, yielding metal alloys with controlled compositions. While this approach has been demonstrated in previous publications for various alloys, the addition of carbon, an important element in most industrial steels, has been a persistent challenge. This paper demonstrates an approach to introduce carbon during the reduction process, resulting in through-thickness carburization of the final parts.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100166"},"PeriodicalIF":0.0,"publicationDate":"2023-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42644875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stability of vacancies in β-type Ti-15Mo-5Zr-3Al alloy fabricated via laser powder bed fusion 激光粉末床熔合β型Ti-15Mo-5Zr-3Al合金中空位的稳定性
Q2 ENGINEERING, MANUFACTURING Pub Date : 2023-07-13 DOI: 10.1016/j.addlet.2023.100162
Masataka Mizuno , Kazuki Sugita , Kousuke Do , Takuya Ishimoto , Takayoshi Nakano , Hideki Araki

The structural instability in the β-type titanium alloys could affect the stability of vacancies. The stability of vacancies in a β-type Ti-15Mo-5Zr-3Al alloy, fabricated via laser powder bed fusion (LPBF), was investigated using positron annihilation spectroscopy and first-principles calculations. The observed positron lifetimes were close to the experimental and calculated bulk lifetime of Ti-15Mo-5Zr-3Al, which indicates that vacancies were not detected in Ti-15Mo-5Zr-3Al by positron lifetime measurements. Therefore, for the first time, it has been confirmed that quenched-in vacancies are not introduced in the LPBF-manufactured β-type Ti-15Mo-5Zr-3Al despite the fast cooling rate in LPBF process. This feature is preferable for the structural stability in biomedical and industrial applications. The calculated atomic displacement from the ideal bcc lattice positions decreased in β-type Ti-Mo alloys with increasing Mo concentration, indicating that the bcc structure was stabilized by the added Mo. The calculated vacancy formation energies of Ti atoms in β-type Ti-14.5Mo and Ti-27.0Mo alloys exhibited an increasing trend with an increasing number of neighboring Mo atoms. Mo atoms also increased the migration energies of the neighboring paths of vacancies. The calculated results for Ti-15Mo-5Zr-3Al suggest that, while the bcc structure was stabilized by the Mo atoms in Ti-15Mo-5Zr-3Al, the migration and formation energies were still low enough for the diffusion of vacancies.

β型钛合金的结构不稳定性会影响空位的稳定性。利用正电子湮没谱和第一性原理计算研究了激光粉末床聚变(LPBF)制备的β型Ti-15Mo-5Zr-3Al合金中空位的稳定性。观察到的正电子寿命接近Ti-15Mo-5Zr-3Al的实验和计算体寿命,这表明通过正电子寿命测量在Ti-15Mo-54Zr-3Al中没有检测到空位。因此,首次证实,尽管在LPBF工艺中冷却速度很快,但在LPBF制造的β型Ti-15Mo-5Zr-3Al中没有引入空位淬火。该特征对于生物医学和工业应用中的结构稳定性是优选的。β型Ti-Mo合金中理想bcc晶格位置的原子位移随着Mo浓度的增加而减少,表明添加Mo使bcc结构稳定。β型Ti-14.5Mo和Ti-27.0Mo合金中Ti原子的空位形成能随着相邻Mo原子数的增加而呈增加趋势。Mo原子还增加了空位相邻路径的迁移能。Ti-15Mo-5Zr-3Al的计算结果表明,尽管Ti-15Mo-54Zr-3Al中的Mo原子稳定了bcc结构,但迁移能和形成能仍然足够低,足以使空位扩散。
{"title":"Stability of vacancies in β-type Ti-15Mo-5Zr-3Al alloy fabricated via laser powder bed fusion","authors":"Masataka Mizuno ,&nbsp;Kazuki Sugita ,&nbsp;Kousuke Do ,&nbsp;Takuya Ishimoto ,&nbsp;Takayoshi Nakano ,&nbsp;Hideki Araki","doi":"10.1016/j.addlet.2023.100162","DOIUrl":"https://doi.org/10.1016/j.addlet.2023.100162","url":null,"abstract":"<div><p>The structural instability in the β-type titanium alloys could affect the stability of vacancies. The stability of vacancies in a β-type Ti-15Mo-5Zr-3Al alloy, fabricated via laser powder bed fusion (LPBF), was investigated using positron annihilation spectroscopy and first-principles calculations. The observed positron lifetimes were close to the experimental and calculated bulk lifetime of Ti-15Mo-5Zr-3Al, which indicates that vacancies were not detected in Ti-15Mo-5Zr-3Al by positron lifetime measurements. Therefore, for the first time, it has been confirmed that quenched-in vacancies are not introduced in the LPBF-manufactured β-type Ti-15Mo-5Zr-3Al despite the fast cooling rate in LPBF process. This feature is preferable for the structural stability in biomedical and industrial applications. The calculated atomic displacement from the ideal bcc lattice positions decreased in β-type Ti-Mo alloys with increasing Mo concentration, indicating that the bcc structure was stabilized by the added Mo. The calculated vacancy formation energies of Ti atoms in β-type Ti-14.5Mo and Ti-27.0Mo alloys exhibited an increasing trend with an increasing number of neighboring Mo atoms. Mo atoms also increased the migration energies of the neighboring paths of vacancies. The calculated results for Ti-15Mo-5Zr-3Al suggest that, while the bcc structure was stabilized by the Mo atoms in Ti-15Mo-5Zr-3Al, the migration and formation energies were still low enough for the diffusion of vacancies.</p></div>","PeriodicalId":72068,"journal":{"name":"Additive manufacturing letters","volume":"7 ","pages":"Article 100162"},"PeriodicalIF":0.0,"publicationDate":"2023-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49727096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Additive manufacturing letters
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1