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Properties of graphene: a theoretical perspective 石墨烯的性质:一个理论视角
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2010-03-01 DOI: 10.1080/00018732.2010.487978
D. Abergel, V. Apalkov, J. Berashevich, K. Ziegler, T. Chakraborty
The electronic properties of graphene, a two-dimensional crystal of carbon atoms, are exceptionally novel. For instance, the low-energy quasiparticles in graphene behave as massless chiral Dirac fermions which has led to the experimental observation of many interesting effects similar to those predicted in the relativistic regime. Graphene also has immense potential to be a key ingredient of new devices, such as single molecule gas sensors, ballistic transistors and spintronic devices. Bilayer graphene, which consists of two stacked monolayers and where the quasiparticles are massive chiral fermions, has a quadratic low-energy band structure which generates very different scattering properties from those of the monolayer. It also presents the unique property that a tunable band gap can be opened and controlled easily by a top gate. These properties have made bilayer graphene a subject of intense interest. In this review, we provide an in-depth description of the physics of monolayer and bilayer graphene from a theorist's perspective. We discuss the physical properties of graphene in an external magnetic field, reflecting the chiral nature of the quasiparticles near the Dirac point with a Landau level at zero energy. We address the unique integer quantum Hall effects, the role of electron correlations, and the recent observation of the fractional quantum Hall effect in the monolayer graphene. The quantum Hall effect in bilayer graphene is fundamentally different from that of a monolayer, reflecting the unique band structure of this system. The theory of transport in the absence of an external magnetic field is discussed in detail, along with the role of disorder studied in various theoretical models. Recent experminental observations of a metal–insulator transition in hydrogenated graphene is discussed in terms of a self-consistent theory and compared with related numerical simulations. We highlight the differences and similarities between monolayer and bilayer graphene, and focus on thermodynamic properties such as the compressibility, the plasmon spectra, the weak localization correction, quantum Hall effect and optical properties. Confinement of electrons in graphene is non-trivial due to Klein tunnelling. We review various theoretical and experimental studies of quantum confined structures made from graphene. The band structure of graphene nanoribbons and the role of the sublattice symmetry, edge geometry and the size of the nanoribbon on the electronic and magnetic properties are very active areas of research, and a detailed review of these topics is presented. Also, the effects of substrate interactions, adsorbed atoms, lattice defects and doping on the band structure of finite-sized graphene systems are discussed. We also include a brief description of graphane–gapped material obtained from graphene by attaching hydrogen atoms to each carbon atom in the lattice.
石墨烯是一种碳原子的二维晶体,它的电子特性非常新颖。例如,石墨烯中的低能准粒子表现为无质量手性狄拉克费米子,这导致了许多有趣的实验观察,类似于在相对论体系中预测的效应。石墨烯也有巨大的潜力成为新器件的关键成分,如单分子气体传感器、弹道晶体管和自旋电子器件。双层石墨烯由两个堆叠的单层石墨烯组成,其中准粒子是大质量手性费米子,具有二次低能带结构,与单层石墨烯产生的散射特性非常不同。它还具有独特的特性,即可以通过顶栅轻松打开和控制可调谐的带隙。这些特性使得双层石墨烯成为人们非常感兴趣的课题。在这篇综述中,我们从理论的角度对单层和双层石墨烯的物理学进行了深入的描述。我们讨论了石墨烯在外磁场中的物理性质,反映了零能量朗道能级狄拉克点附近准粒子的手性性质。我们讨论了独特的整数量子霍尔效应,电子相关性的作用,以及最近在单层石墨烯中观察到的分数量子霍尔效应。双层石墨烯中的量子霍尔效应与单层石墨烯的量子霍尔效应有着根本的不同,这反映了该体系独特的能带结构。详细讨论了在没有外加磁场的情况下的输运理论,以及各种理论模型中研究的无序的作用。根据自一致理论讨论了氢化石墨烯中金属-绝缘体过渡的最新实验观察结果,并与相关的数值模拟进行了比较。我们重点分析了单层石墨烯和双层石墨烯的异同点,并重点研究了其热力学性质,如可压缩性、等离激元光谱、弱局域校正、量子霍尔效应和光学性质。由于克莱因隧道效应,电子在石墨烯中的约束是非平凡的。我们回顾了由石墨烯制成的量子限制结构的各种理论和实验研究。石墨烯纳米带的能带结构以及亚晶格对称性、边缘几何形状和纳米带的尺寸对其电子和磁性能的影响是目前研究的热点,本文对这些问题进行了详细的综述。此外,还讨论了衬底相互作用、吸附原子、晶格缺陷和掺杂对有限尺寸石墨烯体系能带结构的影响。我们还简要介绍了通过将氢原子连接到晶格中的每个碳原子上而获得的石墨烯间隙材料。
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引用次数: 873
Boron-nitride and boron-carbonitride nanotubes: synthesis, characterization and theory 氮化硼和碳氮化硼纳米管:合成、表征和理论
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2010-02-15 DOI: 10.1080/00018730903562033
R. Arenal, X. Blase, Annick Loiseau
We present in this review a joint experimental and theoretical overview of the synthesis techniques and properties of boron-nitride (BN) and boron-carbonitride (BCN) nanotubes. While their tubular structure is similar to that of their carbon analogues, we show that their electronic properties are significantly different. BN tubes are wide band gap insulators while BCN systems can be semiconductors with a band gap in the visible range.
本文对氮化硼(BN)和碳氮化硼(BCN)纳米管的合成技术和性能进行了实验和理论综述。虽然它们的管状结构与它们的碳类似物相似,但我们发现它们的电子性质有显著不同。BN管是宽带隙绝缘体,而BCN系统可以是半导体,带隙在可见范围内。
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引用次数: 134
Dynamics of a quantum phase transition and relaxation to a steady state 量子相变和弛豫到稳态的动力学
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2009-12-20 DOI: 10.1080/00018732.2010.514702
J. Dziarmaga
We review recent theoretical work on two closely related issues: excitation of an isolated quantum condensed matter system driven adiabatically across a continuous quantum phase transition or a gapless phase, and apparent relaxation of an excited system after a sudden quench of a parameter in its Hamiltonian. Accordingly, the review is divided into two parts. The first part revolves around a quantum version of the Kibble–Zurek mechanism including also phenomena that go beyond this simple paradigm. What they have in common is that excitation of a gapless many-body system scales with a power of the driving rate. The second part attempts a systematic presentation of recent results and conjectures on apparent relaxation of a pure state of an isolated quantum many-body system after its excitation by a sudden quench. This research is motivated in part by recent experimental developments in the physics of ultracold atoms with potential applications in the adiabatic quantum state preparation and quantum computation.
我们回顾了最近在两个密切相关的问题上的理论工作:一个孤立的量子凝聚态系统在连续量子相变或无间隙相变中绝热驱动的激发,以及一个激发态系统在其哈密顿量参数突然猝灭后的表观弛豫。因此,审查分为两个部分。第一部分围绕着Kibble-Zurek机制的量子版本,包括超越这个简单范例的现象。它们的共同之处在于,无间隙多体系统的激励以驱动率的功率为尺度。第二部分试图系统地介绍孤立量子多体系统在突然猝灭激发后纯态的表观弛豫的最新结果和猜想。这项研究的部分动机是由于最近超冷原子物理学的实验发展,在绝热量子态制备和量子计算中具有潜在的应用。
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引用次数: 437
Mixed-valence manganites – ten years on 混合价锰矿石——十年过去了
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2009-11-01 DOI: 10.1080/00018730903303370
J. Coey, M. Viret, S. von Molnár
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引用次数: 13
Coherent methods in the X-ray sciences x射线科学中的相干方法
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2009-08-21 DOI: 10.1080/00018730903270926
K. Nugent
X-ray sources are developing rapidly and their coherent output is growing correspondingly. The increased coherent flux from modern X-ray sources is being matched with an associated development in experimental methods. This article reviews the literature describing the ideas that utilize the increased brilliance from modern X-ray sources. It explores how ideas in coherent X-ray science are leading to developments in other areas, and vice versa. The article describes measurements of coherence properties and uses this discussion as a base from which to describe partially coherent diffraction and X-ray phase-contrast imaging, with applications in materials science, engineering and medicine. Coherent diffraction imaging methods are reviewed along with associated experiments in materials science. Proposals for experiments to be performed with the new X-ray free-electron lasers are briefly discussed. The literature on X-ray photon-correlation spectroscopy is described and the features it has in common with other coherent X-ray methods are identified. Many of the ideas used in the coherent X-ray literature have their origins in the optical and electron communities and these connections are explored. A review of the areas in which ideas from coherent X-ray methods are contributing to methods for the neutron, electron and optical communities is presented.
x射线源发展迅速,相干输出也相应增加。现代x射线源相干通量的增加与实验方法的相关发展相匹配。本文回顾了文献描述的想法,利用增加的亮度从现代x射线源。它探讨了相干x射线科学的思想如何引领其他领域的发展,反之亦然。本文描述了相干特性的测量,并以此为基础描述了部分相干衍射和x射线相衬成像在材料科学、工程和医学中的应用。综述了材料科学中的相干衍射成像方法及其相关实验。简要讨论了用新型x射线自由电子激光器进行实验的建议。介绍了有关x射线光子相关光谱学的文献,并指出了它与其他相干x射线方法的共同特点。相干x射线文献中使用的许多想法都起源于光学和电子社区,并探讨了这些联系。综述了相干x射线方法的思想对中子、电子和光学界方法的贡献。
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引用次数: 432
Multiferroicity: the coupling between magnetic and polarization orders 多铁性:磁阶和极化阶之间的耦合
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2009-06-30 DOI: 10.1080/00018730902920554
Kefeng Wang, Jun-Ming Liu, Zhifeng Ren
Multiferroics, defined for those multifunctional materials in which two or more kinds of fundamental ferroicities coexist, have become one of the hottest topics of condensed matter physics and materials science in recent years. The coexistence of several order parameters in multiferroics brings out novel physical phenomena and offers possibilities for new device functions. The revival of research activities on multiferroics is evidenced by some novel discoveries and concepts, both experimentally and theoretically. In this review, we outline some of the progressive milestones in this stimulating field, especially for those single-phase multiferroics where magnetism and ferroelectricity coexist. First, we highlight the physical concepts of multiferroicity and the current challenges to integrate the magnetism and ferroelectricity into a single-phase system. Subsequently, we summarize various strategies used to combine the two types of order. Special attention is paid to three novel mechanisms for multiferroicity generation: (1) the ferroelectricity induced by the spin orders such as spiral and E-phase antiferromagnetic spin orders, which break the spatial inversion symmetry; (2) the ferroelectricity originating from the charge-ordered states; and (3) the ferrotoroidic system. Then, we address the elementary excitations such as electromagnons, and the application potentials of multiferroics. Finally, open questions and future research opportunities are proposed.
多铁性是指两种或两种以上基本铁性共存的多功能材料,是近年来凝聚态物理和材料科学研究的热点之一。多铁性中多个序参量的共存带来了新的物理现象,为器件的新功能提供了可能。多铁学研究活动的复兴是由一些实验和理论上的新发现和新概念所证明的。在这篇综述中,我们概述了这一激励领域的一些进展里程碑,特别是在磁性和铁电共存的单相多铁性材料中。首先,我们强调了多铁性的物理概念以及将磁性和铁电性集成到单相系统中的当前挑战。随后,我们总结了用于结合两种类型的顺序的各种策略。特别关注了三种新的多铁性产生机制:(1)自旋顺序(如螺旋和e相反铁磁自旋顺序)引起的铁电性破坏了空间反演对称性;(2)由电荷有序态产生的铁电性;(3)环铁系。然后,我们讨论了电子介子等基本激发,以及多铁性材料的应用潜力。最后,提出了有待解决的问题和未来的研究机会。
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引用次数: 1143
Keldysh technique and non-linear σ-model: basic principles and applications Keldysh技术与非线性σ模型:基本原理与应用
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2009-01-23 DOI: 10.1080/00018730902850504
A. Kamenev, A. Levchenko
The purpose of this review is to provide a comprehensive pedagogical introduction into Keldysh technique for interacting out-of-equilibrium fermionic and bosonic systems. The emphasis is placed on a functional integral representation of the underlying microscopic models. A large part of the review is devoted to derivation and applications of the non-linear σ-model for disordered metals and superconductors. We discuss topics such as transport properties, mesoscopic effects, counting statistics, interaction corrections, kinetic equations, etc. The section devoted to disordered superconductors includes the Usadel equation, fluctuation corrections, time-dependent Ginzburg–Landau theory, proximity and Josephson effects, etc.
本文的目的是对非平衡费米子和玻色子系统相互作用的Keldysh技术进行全面的教学介绍。重点放在微观模型的功能积分表示上。这篇综述的很大一部分是关于无序金属和超导体的非线性σ-模型的推导和应用。我们讨论的主题包括输运性质、介观效应、计数统计、相互作用修正、动力学方程等。无序超导体部分包括Usadel方程、涨落修正、时变金兹堡-朗道理论、邻近和约瑟夫森效应等。
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引用次数: 296
Lattice symmetry breaking in cuprate superconductors: stripes, nematics, and superconductivity 铜超导体中的晶格对称性破缺:条纹、向列线和超导性
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2009-01-21 DOI: 10.1080/00018730903122242
M. Vojta
This article gives an overview of both theoretical and experimental developments concerning states with lattice symmetry breaking in the cuprate high-temperature superconductors. Recent experiments have provided evidence for states with broken rotation as well as translation symmetry, and will be discussed in terms of nematic and stripe physics. Of particular importance here are results obtained using the techniques of neutron and X-ray scattering and scanning tunnelling spectroscopy. Ideas on the origin of lattice-symmetry-broken states will be reviewed, and effective models accounting for various experimentally observed phenomena will be summarized. These include both weak-coupling and strong-coupling approaches, with a discussion of their distinctions and connections. The collected experimental data indicate that the tendency toward uni-directional stripe-like ordering is common to underdoped cuprates, but becomes weaker with increasing number of adjacent CuO2 layers.
本文综述了铜高温超导体中晶格对称性破缺态的理论和实验进展。最近的实验已经为旋转破碎以及平移对称的状态提供了证据,并将在向列和条纹物理方面进行讨论。这里特别重要的是用中子和x射线散射和扫描隧穿光谱技术得到的结果。本文将回顾关于晶格对称破缺状态起源的观点,并对各种实验观察到的现象的有效模型进行总结。这些方法包括弱耦合和强耦合方法,并讨论了它们的区别和联系。实验数据表明,欠掺杂铜酸盐普遍具有单向条状有序的趋势,但随着相邻CuO2层数的增加而减弱。
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引用次数: 347
Two-dimensional matter: order, curvature and defects 二维物质:秩序、曲率和缺陷
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2008-12-16 DOI: 10.1080/00018730903043166
M. Bowick, L. Giomi
Many systems in nature and the synthetic world involve ordered arrangements of units on two-dimensional surfaces. We review here the fundamental role payed by both the topology of the underlying surface and its Gaussian curvature. Topology dictates certain broad features of the defect structure of the ground state but curvature-driven energetics control the detailed structure of the ordered phases. Among the surprises are the appearance in the ground state of structures that would normally be thermal excitations and thus prohibited at zero temperature. Examples include excess dislocations in the form of grain boundary scars for spherical crystals above a minimal system size, dislocation unbinding for toroidal hexatics, interstitial fractionalization in spherical crystals and the appearance of well-separated disclinations for toroidal crystals. Much of the analysis leads to universal predictions that do not depend on the details of the microscopic interactions that lead to order in the first place. These predictions are subject to test by the many experimental soft- and hard-matter systems that lead to curved ordered structures such as colloidal particles self-assembling on droplets of one liquid in a second liquid. The defects themselves may be functionalized to create ligands with directional bonding. Thus, nano- to meso-scale superatoms may be designed with specific valency for use in building supermolecules and novel bulk materials. Parameters such as particle number, geometrical aspect ratios and anisotropy of elastic moduli permit the tuning of the precise architecture of the superatoms and associated supermolecules. Thus, the field has tremendous potential from both a fundamental and materials science/supramolecular chemistry viewpoint.
自然界和合成世界中的许多系统都涉及二维表面上单位的有序排列。我们在这里回顾下表面的拓扑结构及其高斯曲率所起的基本作用。拓扑决定了基态缺陷结构的某些广泛特征,但曲率驱动的能量学控制了有序相的详细结构。令人惊讶的是,在基态中出现的结构通常是热激发,因此在零温度下是禁止的。例如,在最小系统尺寸以上的球形晶体中,以晶界疤痕形式出现的过量位错,在环面六边形中,位错脱离束缚,在球形晶体中,间隙分异,在环面晶体中,出现分离良好的位错。许多分析得出的普遍预测并不依赖于最初导致秩序的微观相互作用的细节。这些预测将受到许多实验软物质和硬物质系统的检验,这些系统会导致弯曲的有序结构,比如胶体粒子在一种液体的水滴上自组装到另一种液体中。缺陷本身可以被功能化以产生具有定向键的配体。因此,纳米到中观尺度的超原子可以被设计成具有特定的价电子,用于构建超分子和新型块状材料。粒子数、几何长宽比和弹性模量的各向异性等参数允许超原子和相关超分子的精确结构调整。因此,从基础和材料科学/超分子化学的角度来看,该领域具有巨大的潜力。
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引用次数: 254
Rapidly rotating atomic gases 快速旋转的原子气体
1区 物理与天体物理 Q1 PHYSICS, CONDENSED MATTER Pub Date : 2008-10-24 DOI: 10.1080/00018730802564122
N. Cooper
In this article, we review developments in the theory of rapidly rotating degenerate atomic gases. The main focus is on the equilibrium properties of a single-component atomic Bose gas, which (at least at rest) forms a Bose–Einstein condensate. Rotation leads to the formation of quantized vortices which order into a vortex array, in close analogy with the behaviour of superfluid helium. Under conditions of rapid rotation, when the vortex density becomes large, atomic Bose gases offer the possibility to explore the physics of quantized vortices in novel parameter regimes. First, there is an interesting regime in which the vortices become sufficiently dense that their cores, as set by the healing length, start to overlap. In this regime, the theoretical description simplifies, allowing a reduction to single-particle states in the lowest Landau level. Second, one can envisage entering a regime of very high vortex density, when the number of vortices becomes comparable to the number of particles in the gas. In this regime, theory predicts the appearance of a series of strongly correlated phases, which can be viewed as bosonic versions of fractional quantum Hall states. In this article, we describe the equilibrium properties of rapidly rotating atomic Bose gases in both the mean-field and the strongly correlated regimes, and related theoretical developments for Bose gases in lattices, for multi-component Bose gases and for atomic Fermi gases. The current experimental situation and outlook for the future are discussed in light of these theoretical developments.
本文综述了快速旋转简并原子气体理论的研究进展。主要的焦点是单组分原子玻色气体的平衡特性,它(至少是静止的)形成了玻色-爱因斯坦凝聚体。旋转导致量子化漩涡的形成,这些漩涡排列成漩涡阵列,与超流氦的行为非常相似。在快速旋转的条件下,当涡旋密度变大时,原子玻色气体提供了在新的参数体系中探索量子化涡旋物理的可能性。首先,有一个有趣的现象,在这个现象中,漩涡变得足够密集,以至于它们的核心,正如愈合长度所设定的那样,开始重叠。在这种情况下,理论描述简化了,允许在最低朗道能级上还原到单粒子状态。其次,当涡旋的数量与气体中的粒子数量相当时,人们可以设想进入一个非常高涡旋密度的状态。在这种状态下,理论预测了一系列强相关相的出现,这些相可以被视为分数量子霍尔态的玻色子版本。在本文中,我们描述了快速旋转原子玻色气体在平均场和强相关状态下的平衡特性,以及晶格中玻色气体、多组分玻色气体和原子费米气体的相关理论发展。根据这些理论的发展,讨论了目前的实验情况和对未来的展望。
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引用次数: 420
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