A dual-band ultra-wideband rectenna is being designed to work from 1.8 GHz to 2.7 GHz with a bandwidth of 900 MHz, and 3.4 GHz to 7.5 GHz with a bandwidth of 4.1 GHz. The projected antenna can operate over the lower, medium, and upper frequency bands of the Unlicensed National Information Infrastructure (UNII), as well as the frequency band utilized by the Universal Mobile Telecommunication System (UTMS) at 2100 MHz. The antenna used operates within the specified frequency bands and has an octagonal shape. A defective ground structure is incorporated into an octagonal-shaped antenna to enable its operation within the prescribed frequency ranges. The antenna gains for UTMS-2100 MHz and UNII band are 3 decibels isotropic (dBi) and 5.5 dBi, respectively. The rectifier consists of two branches, and the DC combining technique is chosen to achieve enhanced conversion efficiency (CE). The CE, evaluated at an input power level (IPL) of 0 dBm and a frequency of 2.1 GHz, is 52%. At a frequency of 5.8 GHz, the conversion efficiency is 35%. Nevertheless, the recorded conversion efficiency stands at 85% when operating at a frequency of 2.1 GHz, with an input power level (IPL) of 15 dBm. The highest recorded conversion efficiency at a frequency of 5.8 GHz is 80%, achieved with an IPL of 15 dBm. The optimum value for the load resistor is 330 Ω.