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On Some Peculiarities of Implementation of Instability of Flat Charged Surface of Electroconductive Liquid 关于实现导电液体平坦带电表面不稳定性的一些特性
IF 0.9 Q3 Engineering Pub Date : 2023-10-17 DOI: 10.3103/S1068375523050083
A. I. Grigor’ev

The characteristic sizes and charges of droplets formed during the realization of the electrostatic instability of a uniformly charged, charge-induced flat surface of an electrically conductive liquid are calculated on the base of the principle of the least energy dissipation in the Onsager nonequilibrium processes. It was found that the droplets of the same size and charges are emitted when the electrostatic instability of a flat liquid surface is realized. The surface should be infinitely extended along both axes of the Cartesian coordinate system of the liquid, and the axes should be perpendicular to the direction of gravity. If to compare the same characteristics of the charged droplet disintegration, unstable to its own charge, then there will be a number of differences, i.e., in the number of emitted progeny droplets, in their sizes and charges, and in the tendency of all parameters to change with an increase in the ordinal number of the progeny droplet. The paper considers the progeny droplets to be initially unstable to the electric charge which is located on them.

基于Onsager非平衡过程中的最小能量耗散原理,计算了在实现均匀带电、电荷诱导的导电液体平坦表面的静电不稳定性过程中形成的液滴的特征尺寸和电荷。研究发现,当实现平坦液体表面的静电不稳定性时,会发射出相同大小和电荷的液滴。表面应沿着液体笛卡尔坐标系的两个轴无限延伸,并且这些轴应垂直于重力方向。如果比较带电液滴崩解的相同特征,对其自身的电荷不稳定,那么将存在许多差异,即发射的子代液滴的数量、它们的大小和电荷,以及所有参数随子代液滴滴序数量的增加而变化的趋势。本文认为子代液滴最初对其上的电荷不稳定。
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引用次数: 0
Dielectric Properties of Layered MnGaInSe4 Single Crystals in an Alternating Electric Field 层状MnGaInSe4单晶在交变电场中的介电特性
IF 0.9 Q3 Engineering Pub Date : 2023-10-17 DOI: 10.3103/S1068375523050137
N. N. Niftiev, A. O. Dashdemirov, F. M. Mamedov, M. B. Muradov

In this paper we present the results of studies into the frequency and temperature dependences of the dielectric loss tangent and the real and imaginary parts of the permittivity in MnGaInSe4 single crystals in an alternating electric field. The main type of dielectric losses in MnGaInSe4 single crystals in the frequency range of 8 × 103–3 × 105 Hz is established to be electrical conductivity losses, while the conductivity is characterized by the zone-hopping mechanism. The activation energies of current carriers of single crystals are determined. The real and imaginary parts of the permittivity are found to undergo significant dispersion, which is of a relaxation nature.

本文给出了MnGaInSe4单晶在交变电场中介电损耗正切和介电常数实部和虚部的频率和温度依赖性的研究结果。在8×103–3×105 Hz的频率范围内,MnGaInSe4单晶的主要介电损耗类型被确定为电导率损耗,而电导率的特征是区域跳跃机制。测定了单晶载流子的活化能。发现介电常数的实部和虚部经历显著的色散,这具有弛豫性质。
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引用次数: 0
Voltammetric Determination of Dopamine in the Presence of Caffeine Using a Modified Glassy Carbon Electrode 修饰玻碳电极在咖啡因存在下伏安法测定多巴胺
IF 0.9 Q3 Engineering Pub Date : 2023-10-17 DOI: 10.3103/S1068375523050071
Maryam Ebrahimi,  Hadi Beitollahi

Abstract

In this work, an electrochemical sensor based on CuO nanoflowers modified glassy carbon electrode (GCE) was developed for the voltammetric determination of dopamine. The CuO nanoflowers modified GCE showed good catalytic ability for the determination of dopamine. The differential pulse voltammetry investigation showed a linear relation between the dopamine current and its concentration within the range of 0.1–800.0 μM, with a limit of detection of 0.03 ± 0.001 μM. Also, the modified electrode was used for the simultaneous determination of dopamine and caffeine. Both dopamine and caffeine exhibited non-overlapping voltammetric peaks at 235 and 1390 mV, respectively, using CuO nanoflowers/GCE. Finally, the analytical performance of the developed sensor was evaluated for the analysis of dopamine and caffeine in real samples, which showed satisfactory results.

摘要——本工作开发了一种基于CuO纳米花修饰玻碳电极(GCE)的电化学传感器,用于多巴胺的伏安测定。CuO纳米花修饰GCE对多巴胺的测定显示出良好的催化能力。微分脉冲伏安法研究表明,多巴胺电流与其浓度在0.1–800.0μM范围内呈线性关系,检测限为0.03±0.001μM。同时,将修饰电极用于多巴胺和咖啡因的同时测定。使用CuO纳米花/GCE,多巴胺和咖啡因分别在235和1390 mV处显示出不重叠的伏安峰。最后,对所开发的传感器的分析性能进行了评估,用于真实样品中多巴胺和咖啡因的分析,结果令人满意。
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引用次数: 0
Application of Optical Emission Spectroscopy for Predicting the Composition of Films in Reactive Magnetron Sputtering of Ti–Al Composite Targets 光发射光谱法在Ti–Al复合靶材反应磁控溅射薄膜成分预测中的应用
IF 0.9 Q3 Engineering Pub Date : 2023-10-17 DOI: 10.3103/S106837552305006X
H. T. Doan, D. A. Golosov, J. Zhang, S. N. Melnikov, S. M. Zavadski

Abstract

The processes of reactive magnetron sputtering of Ti–Al composite targets with varying Al/Ti ratios were studied. Dependences of deposition rate, discharge voltage, elemental composition, and intensity of reference plasma emission lines were determined as functions of the oxygen concentration in the Ar–O2 gas mixture. It was demonstrated that, in reactive sputtering of Ti–Al composite targets, the discharge voltage is determined by the effective ion–electron emission coefficient (IEEC), which depends on the area occupied by the metals on the target, their oxidation states, and the IEEC of the metals and their oxides. The deposition rate of TixAl1 – xOy films both in the metallic and transitional sputtering modes increases proportionally to the fraction of Al in the target, and the relative concentration of the metals in the deposited films depends on the oxygen concentration in the Ar–O2 gas mixture and is determined by the reactivity of the constituent materials in the target. By optical emission spectroscopy (OES), it was shown that the ratio of the atomic concentrations of Al and Ti in the deposited TixAl1 – xOy films uniquely depends on the ratio of the intensities of the aluminum emission line (AlI) and the titanium emission line (TiI) in the plasma. This allows using OES for predicting the metal contents in the films in reactive magnetron sputtering of Ti–Al targets.

摘要——研究了不同Al/Ti比的Ti–Al复合靶材的反应磁控溅射工艺。沉积速率、放电电压、元素组成和参考等离子体发射线强度的依赖性被确定为Ar–O2气体混合物中氧浓度的函数。研究表明,在Ti–Al复合靶材的反应溅射中,放电电压由有效离子-电子发射系数(IEEC)决定,该系数取决于金属在靶材上占据的面积、金属的氧化态以及金属及其氧化物的IEEC。TixAl1–xOy薄膜在金属和过渡溅射模式下的沉积速率与靶材中Al的比例成比例增加,沉积薄膜中金属的相对浓度取决于Ar–O2气体混合物中的氧浓度,并由靶材中组成材料的反应性决定。通过光学发射光谱(OES)研究表明,沉积的TixAl1–xOy薄膜中Al和Ti的原子浓度之比独特地取决于等离子体中铝发射线(AlI)和钛发射线(TiI)强度之比。这允许在Ti–Al靶的反应磁控溅射中使用OES来预测膜中的金属含量。
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引用次数: 0
Development and Creation of a New Class of Graded-Gap Structures Based on Silicon with the Participation of Zn and Se Atoms Zn和Se原子参与的一类新型硅梯度间隙结构的研制
IF 0.9 Q3 Engineering Pub Date : 2023-10-17 DOI: 10.3103/S1068375523050198
N. F. Zikrillaev, O. B. Tursunov, G. A. Kushiev

The possibility of the formation of structures such as compounds of elements between chalcogenides and the transition group of metals in the crystal lattice of silicon is studied. This is an urgent problem in electronics. It is shown that, under certain technological conditions, a sufficient concentration of unit cells is formed, which leads to a change in the band structure of silicon itself; i.e., a micro- and nanoscale inclusion in silicon with a direct-gap structure is obtained. The possibilities of creating a fundamentally new class of photocells with an extended spectral sensitivity region, as well as light-emitting devices, light-emitting diodes, and lasers based on them, are shown.

研究了在硅晶格中硫族化物和金属过渡基团之间形成诸如元素化合物之类的结构的可能性。这是电子领域的一个紧迫问题。结果表明,在一定的工艺条件下,形成了足够浓度的晶胞,从而导致硅本身的能带结构发生变化;即获得具有直接间隙结构的硅中的微米级和纳米级夹杂物。展示了创建一类具有扩展光谱灵敏度区域的全新光电管的可能性,以及基于它们的发光器件、发光二极管和激光器。
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引用次数: 0
Heat Transfer during Boiling of a Magnetic Fluid in a Magnetic Field on a Horizontal Surface with Single-Point Heat Supply 磁流体在水平面上磁场沸腾时的传热及单点供热
IF 0.9 Q3 Engineering Pub Date : 2023-09-04 DOI: 10.3103/S1068375523040178
A. A. Yanovskii, A. Ya. Simonovskii

Abstract

An experimental study was made of the influence of a homogeneous magnetic field on heat transfer during nucleate boiling of a nanodispersed magnetizable fluid (magnetic fluid) on a horizontal surface with single-point heat supply. The boiling curves were obtained for magnetic fluids with volume concentrations of the solid phase of 12, 8, and 5.5% in magnetic fields ranging from 0.7 to 4.2 kA/m. The curves are nonmonotonic, and the value of the magnetic field intensity at which the heat flux is maximum was determined. It was found that, with an increase in the solid-phase concentration, the effect of the magnetic field on the heat flux increases. Based on the theory of approximate heat transfer during boiling of fluids, an expression was derived that satisfactorily describes the influence of the magnetic field on the heat flux in the nucleate boiling regime.

摘要研究了均匀磁场对纳米分散可磁化流体(磁性流体)在单点热源水平表面沸腾过程中传热的影响。得到了固相体积浓度分别为12.8和5.5%的磁流体在0.7 ~ 4.2 kA/m范围内的沸腾曲线。曲线是非单调的,并确定了热流最大时的磁场强度值。研究发现,随着固相浓度的增加,磁场对热流密度的影响增大。根据流体沸腾过程的近似传热理论,导出了一个满意地描述了磁场对核沸腾状态下热流密度影响的表达式。
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引用次数: 1
Consideration of the Synergy of Vitamins E and C in the Kinetic Model of Lipid Peroxidation 脂质过氧化动力学模型中维生素E和C协同作用的探讨
IF 0.9 Q3 Engineering Pub Date : 2023-09-04 DOI: 10.3103/S1068375523040038
E. Yu. Kanarovskii, O. V. Yaltychenko

Abstract

A theoretical model of the kinetics of lipid peroxidation is considered in which the synergy effect of vitamins E and C is taken into account. Approximations simplifying the model system with consideration of the features of the process of lipid peroxidation are analyzed. The obtained model is minimal and sufficiently adequately describes lipid peroxidation at the stages that are significant for effective control of this process as a whole.

摘要:脂质过氧化动力学的理论模型,其中维生素E和C的协同效应被考虑在内。考虑到脂质过氧化过程的特点,分析了简化模型系统的近似方法。所获得的模型是最小的,充分地描述了脂质过氧化的阶段,这对整个过程的有效控制是重要的。
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引用次数: 0
Effect of a Constant Magnetic Field on Electrodeposition of CoMo, CoRe, and CoMoRe Alloys from a Citrate Electrolyte 恒定磁场对柠檬酸盐电解液中CoMo、CoRe和CoMoRe合金电沉积的影响
IF 0.9 Q3 Engineering Pub Date : 2023-09-04 DOI: 10.3103/S106837552304018X
Yu. S. Yapontseva, V. N. Zaichenko, V. S. Kublanovsky, O. Yu. Gorobets, Yu. M. Troshchenkov, O. A. Vyshnevskyi

Abstract

Electrodeposition of CoMo and CoRe binary alloys and CoMoRe ternary alloys from a citrate electrolyte (pH 3.5) was studied depending on the presence of a magnetostatic field and the direction of the magnetic induction vector relative to the surface of the working electrode. It was shown that magnetoelectrolysis significantly increases the current efficiency of all investigated alloys, especially the CoMoRe ternary alloy. The forces acting in the liquid and on bubbles of hydrogen evolved during a reaction in a magnetostatic field were modeled. It was demonstrated that the generation of convective flows by magnetohydrodynamic effect is neither single, nor determining factor. In the case of intense gas evolution, the force balance varies depending on the size of the bubbles: the conduction force and the buoyancy force dominate for large bubbles (about 100 μm), whereas the magnetic gradient force is predominant for small bubbles (less than 1 μm).

摘要/ abstract摘要:研究了CoMo、CoRe二元合金和CoMoRe三元合金在柠檬酸盐(pH为3.5)电解液中静电场的存在和相对于工作电极表面的磁感应矢量方向的电沉积。结果表明,磁电解显著提高了所有合金的电流效率,特别是CoMoRe三元合金。模拟了在静磁场中反应过程中作用于液体和氢气气泡的力。结果表明,磁流体动力效应对流的产生既不是单一因素,也不是决定性因素。在气体演化强度较大的情况下,作用力的平衡随气泡的大小而变化:大气泡(约100 μm)以导流力和浮力为主,小气泡(小于1 μm)以磁梯度力为主。
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引用次数: 0
On the Interaction of Azimuthal Modes of Capillary Waves on the Surface of an Elliptic Jet in a Homogeneous Electrostatic Field 均匀静电场中椭圆射流表面毛细波方位角模的相互作用
IF 0.9 Q3 Engineering Pub Date : 2023-09-04 DOI: 10.3103/S1068375523040130
S. O. Shiryaeva, A. I. Grigor’ev

A study was made of the interaction of the first azimuthal modes of capillary waves on the surface of an elliptic jet in a homogeneous electrostatic field that is perpendicular to the axis of the jet. The interaction is nonlinear in the product of two independent small parameters. The interaction arises due to the ellipticity of the perpendicular cross-section of the jet and involves three azimuthal modes: either even or odd. The stability of the jet in the perpendicular homogeneous electrostatic field is lower than that of a jet in a radial electrostatic field. The characteristic destabilization time decreases with increasing initial amplitudes of the interacting modes and intensity of the external electrostatic field, and also depends on the wavenumber.

本文研究了垂直于射流轴线的均匀静电场中椭圆射流表面毛细波第一方位模态的相互作用。这种相互作用是两个独立的小参数的非线性乘积。这种相互作用是由于射流垂直截面的椭圆性引起的,涉及三种方位角模式:偶模或奇模。射流在垂直均质静电场中的稳定性低于径向静电场中的稳定性。特征失稳时间随相互作用模式的初始振幅和外部静电场强度的增加而减小,也与波数有关。
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引用次数: 0
Features of Deformation of Droplets of Magnetic Emulsions in an Alternating Electric Field 交变电场作用下磁乳液滴的变形特征
IF 0.9 Q3 Engineering Pub Date : 2023-09-04 DOI: 10.3103/S1068375523040026
E. S. Beketova, O. A. Nechaeva, Yu. I. Dikanskii

Abstract

Features of deformation of microdroplets of magnetic emulsions in an alternating electric field were experimentally investigated. It was shown that the deformation behavior can vary depending on the frequency of the electric field: at low frequencies, the droplets flatten along the field direction, and at higher frequencies, they elongate. It was found that the frequency value corresponding to the transition from the flattened to the elongated droplet shape depends on the electrical conductivity of the droplet, the intensity of the electric field, and temperature. It was demonstrated that the droplet deformation caused by the electric field can be compensated for by the additional application of a magnetic field. Analysis of the obtained results took into account the movement of liquid phases due to the accumulation of free charge at the interfaces of the droplets and the electrodes creating the field.

摘要:实验研究了交变电场作用下磁乳微滴的变形特征。结果表明,液滴的变形行为随电场频率的变化而变化:在低频时,液滴沿着电场方向变平,而在高频时,液滴则拉长。结果表明,液滴由扁平形状向细长形状转变所对应的频率值与液滴的电导率、电场强度和温度有关。结果表明,电场引起的液滴变形可以通过外加磁场来补偿。对所得结果的分析考虑了由于液滴和产生电场的电极界面上自由电荷的积累而引起的液相运动。
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引用次数: 0
期刊
Surface Engineering and Applied Electrochemistry
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